WO1996013680B1 - Multi-layer fuel and vapor tube - Google Patents

Multi-layer fuel and vapor tube

Info

Publication number
WO1996013680B1
WO1996013680B1 PCT/US1995/013570 US9513570W WO9613680B1 WO 1996013680 B1 WO1996013680 B1 WO 1996013680B1 US 9513570 W US9513570 W US 9513570W WO 9613680 B1 WO9613680 B1 WO 9613680B1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
fluoride
thermoplastic
tubing
vinylidine
Prior art date
Application number
PCT/US1995/013570
Other languages
French (fr)
Other versions
WO1996013680A1 (en
Filing date
Publication date
Priority claimed from US08/329,900 external-priority patent/US5743304A/en
Application filed filed Critical
Priority to JP51465596A priority Critical patent/JP3356288B2/en
Priority to EP95939555A priority patent/EP0788589B1/en
Priority to DE69526741T priority patent/DE69526741T2/en
Priority to AT95939555T priority patent/ATE217692T1/en
Priority to BR9509437A priority patent/BR9509437A/en
Publication of WO1996013680A1 publication Critical patent/WO1996013680A1/en
Publication of WO1996013680B1 publication Critical patent/WO1996013680B1/en

Links

Abstract

A layered tubing (10) for use in a motor vehicle composed of a thick outer layer (12) having an inner and an outer face, the outer layer (12) made of an extrudable thermoplastic elastomer; a thin intermediate bonding layer (14) bonded to the inner face of the thick outer layer (12), the bonding layer (14) composed of an extrudable melt-processible thermoplastic capable of sufficiently permanent laminar adhesion with the thick outer layer (12); an interior layer (16) bonded to the intermediate bonding layer (14), the interior layer (16) composed of a fluoroplastic which is resistant to permeation by and interaction with short-chain aliphatic and aromatic compounds; and an innermost electrostatic dissipation layer (18).

Claims

AMENDED CLAIMS
[received by the International Bureau on 5 June 1996 (05.06.96); original claim 16 cancelled; original claims 1,14,17 and 19 amended; remaining claims unchanged (7 pages)] 1. A layered tubing for use in a motor vehicle, the tubing comprising: a thick flexible outer layer having a given thickness and an inner and an outer face, the outer layer consisting essentially of an extrudable thermoplastic; an intermediate bonding layer bonded to the inner face of the thick outer layer, the bonding layer consisting essentially of an extrudable melt processible thermoplastic material capable of sufficiently permanent laminar adhesion to the inner face of the outer layer, wherein the thermoplastic material employed in the bonding layer consists essentially of: a thermoplastic elastomeric compound selected from the group consisting of alloys of rubber and polyvinyl chloride, alloys of rubber and polyolefin and mixtures thereof; and a fluoropolymer selected from the group consisting of polyvinylidine fluoride, polyvinyl fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinylidine fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinyl fluoride, and mixtures thereof; an interior layer bonded to the intermediate bonding layer, the interior layer consisting essentially of an extrudable, melt-processible thermoplastic material capable of sufficiently permanent laminar adhesion with the intermediate bonding layer, the melt-processible thermoplastic which is chemically dissimilar to the thermoplastic employed in the outer layer, the chemically dissimilar thermoplastic being resistant to permeation by the interaction with short-chain aliphatic and aromatic hydrocarbon compounds; and an innermost electrostatic dissipation layer integrally bonded to the interior layer, the electrostatic dissipation layer consisting of an extrudable, melt-processible thermoplastic material the intermediate bonding layer and of dissipating electrostatic energy, the electrostatic dissipation capacity being in a range between about 104 to 109 ohm/cm2.
2. The layered tubing of claim 1 wherein the thick flexible outer layer consists essentially of a thermoplastic elastomer selected from the group consisting of alloys, rubber and polyvinyl chloride, alloys of rubber and polyolefins and mixtures thereof.
ED SHEET ARTICLE 1fl - 26 - 3. The layered tubing of claim 3 wherein the thermoplastic elastomer has an ability to withstand impacts of at least 2 foot pounds at temperatures below about -20°C.
4. The layered tubing of claim 4 wherein the thermoplastic elastomer has an elongation value of 150% at 23°C.
5. The layered tubing of claim 2 wherein the interior layer is a composed of thermoplastic material consisting essentially of a fluoroplastic material selected from the group consisting of polyvinylidine fluoride, polyvinyl fluoride, and mixtures thereof.
6. The layered tubing of claim 5 wherein the fluoroplastic material further consists of copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinylidine fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinyl fluoride, and mixtures thereof.
7. The layered tubing of claim 5 wherein the interior layer has a thickness between about 10% and about 20% of the thick outer layer.
8. The layered tubing of claim 2 wherein the innermost electrostatic dissipation layer consists of a thermoplastic material which is chemically dissimilar to the thick outer layer.
9. The layered tubing of claim 8 wherein the innermost electrostatic dissipation layer is composed of a thermoplastic material consisting essentially of: a copolymer of a vinyl fluoride and chlorotrifluoroethylene, the vinyl fluoride material - 27 - selected from the group consisting of polyvinylidine fluoride, polyvinyl fluoride, and mixtures thereof; a copolymer of a vinyl fluoride material and ethylene tetrafluoroethylene; and a non-fluorinated elastomer comprising polyurethane.
10. The layered tubing of claim 9 wherein the electrostatic dissipation layer consists essentially of: between about 10% and about 18% by weight of a vinylidine fluoride-chlorotrifluoroethylene copolymer, the copolymer having between about 40% and 60% by weight vinylidine fluoride; between about 50% and about 70% by weight of a vinylidine fluoride-tetrafluoroethylene copolymer, the copolymer having between about 40% and about 60% by weight vinylidine fluoride; and between about 10% and about 25% by weight polyurethane.
11. The layered tubing of claim 8 wherein the innermost electrostatic dissipation has a thickness between about 10% and about 20% of the thick outer layer.
12. The layered tubing of claim 11 wherein the innermost electrostatic dissipation layer further contains quantities of a conductive material sufficient to provide electrostatic dissipation capability in a range between about 104 and about 109 of ohm/cm2.
13. The layered tubing of claim 9 wherein the conductive material is selected from a group consisting of elemental carbon, copper, silver, gold, nickel, silicon, and mixtures thereof.
14. The layered tubing of claim 9 wherein the conductive material is present in an amount less than - 28 - about 5% by volume of the electrostatic dissipation layer thermoplastic material.
15. The layered tubing of claim 9 wherein the conductive material is interstitially integrated into the electrostatic dissipation layer thermoplastic material.
Claim 16 is cancelled.
17. The layered tubing of claim 17 wherein the thermoplastic elastomeric compound employed in the bonding layer is a thermoplastic vulcanate present in an amount between about 30% and 70% by volume of the total thermoplastic material, the balance being the fluoropolymer.
18. The tubing of claim 1 further comprising an exterior jacket overlying the thick outer tubing, the exterior jacket composed of a material consisting essentially of a thermoplastic material selected from the group consisting of Nylon 11, Nylon 12, zinc chloride resistant Nylon 6, polypropylene, thermoplastic elastomers and mixtures thereof.
19. A layered tubing for use in a motor vehicle, the tubing comprising:
- 29 - a thick flexible outer tubing having a given thickness and an inner and an outer face, the outer tubing consisting essentially of an extrudable thermoplastic elastomer selected from the group consisting of alloys of rubber and polyolefin, alloys of rubber and polyvinyl chloride, and mixtures thereof; an intermediate bonding layer having a thickness between about 0.05 mm and about 0.1 mm bonded to the inner face of the thick outer layer, the bonding layer consisting essentially of an extrudable thermoplastic capable of sufficiently permanent laminar adhesion to the thick flexible outer tubing; an interior layer bonded to the intermediate bonding layer, the interior layer having a thickness between about 0.05 mm and about 0.15 mm and consisting essentially of an extrudable, melt-processible thermoplastic material capable of sufficiently permanent laminar adhesion with the intermediate bonding layer, the melt-processible thermoplastic resistant to permeation by and interaction with short-chain aliphatic and aromatic hydrocarbon compounds selected from the group consisting of polyvinylidine fluoride, polyvinyl fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinylidine fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinyl fluoride, and mixtures thereof; and an innermost electrostatic dissipation layer integrally bonded to the interior layer, the electrostatic discharge layer having a thickness between about 0.1 mm and about 0.2 mm and consisting essentially of an extrudable, melt-processible thermoplastic material capable of sufficiently permanent laminar adhesion with the intermediate bonding layer and of dissipating electrostatic energy, the electrostatic dissipation capacity being in a range between about 104 and about - 30 - 109 ohm/cm2, the melt-processible thermoplastic employed in the innermost electrostatic dissipation layer consisting essentially of: between about 10% and about 18% by weight of a vinylidine fluoride-chlorotrifluoroethylene copolymer, the copolymer having between about 40% and 60% by weight vinylidine fluoride; between about 50% and about 70% by weight of a vinylidine fluoride-tetrafluoroethylene copolymer, the copolymer having between about 40% and about 60% by weight vinylidine fluoride; and between about 10% and about 25% by weight polyurethane.
20. The layered tubing of claim 19 wherein the intermediate bonding layer consists essentially of: a thermoplastic elastomer selected from the group consisting of alloys of rubber and polyvinyl chloride, alloys of rubber and polyolefins, and mixtures thereof; and a fluoroplastic selected from the group consisting of polyvinylidine fluoride, polyvinyl fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinylidine fluoride, copolymers of vinylidine difluoride and chlorotrifluoroethane copolymerized with polyvinyl fluoride, and mixtures thereof.
- 31 -
STATEMENT UNDER ARTICLE 19
Claims l and 12 have been amended to clarify the electrostatic dissipation capacity defined therein. This electrostatic dissipation capacity as now expressed conforms with the disclosure in the specification of the amount of conductive material which can be employed in the thermoplastic material. Analogous, correction of the specification will be presented in due course during prosecution.
Claim 1 has been further amended to more particularly define the material employed in the intermediate bonding layer; defining this material away from that disclosed in the cited references.
PCT/US1995/013570 1994-10-27 1995-10-11 Multi-layer fuel and vapor tube WO1996013680A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP51465596A JP3356288B2 (en) 1994-10-27 1995-10-11 Multilayer fuel and steam tubes
EP95939555A EP0788589B1 (en) 1994-10-27 1995-10-11 Multi-layer fuel and vapor tube
DE69526741T DE69526741T2 (en) 1994-10-27 1995-10-11 MULTILAYER FUEL AND STEAM PIPE
AT95939555T ATE217692T1 (en) 1994-10-27 1995-10-11 MULTI-LAYER FUEL AND STEAM PIPE
BR9509437A BR9509437A (en) 1994-10-27 1995-10-11 Multi-layered steam and fuel pipe

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/329,900 US5743304A (en) 1992-04-14 1994-10-27 Multi-layer fuel and vapor tube
US08/329,900 1994-10-27

Publications (2)

Publication Number Publication Date
WO1996013680A1 WO1996013680A1 (en) 1996-05-09
WO1996013680B1 true WO1996013680B1 (en) 1996-07-18

Family

ID=23287504

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/013570 WO1996013680A1 (en) 1994-10-27 1995-10-11 Multi-layer fuel and vapor tube

Country Status (7)

Country Link
US (1) US5743304A (en)
EP (3) EP1120240B2 (en)
JP (1) JP3356288B2 (en)
AT (3) ATE285539T1 (en)
BR (1) BR9509437A (en)
DE (3) DE69533880T9 (en)
WO (1) WO1996013680A1 (en)

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