WO1996013351A1 - Production of granules of reactive metals, for example magnesium and magnesium alloy - Google Patents
Production of granules of reactive metals, for example magnesium and magnesium alloy Download PDFInfo
- Publication number
- WO1996013351A1 WO1996013351A1 PCT/CA1995/000605 CA9500605W WO9613351A1 WO 1996013351 A1 WO1996013351 A1 WO 1996013351A1 CA 9500605 W CA9500605 W CA 9500605W WO 9613351 A1 WO9613351 A1 WO 9613351A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal
- process according
- bed
- granules
- particles
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/10—Making spheroidal graphite cast-iron
- C21C1/105—Nodularising additive agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/16—Metallic particles coated with a non-metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/06—Making metallic powder or suspensions thereof using physical processes starting from liquid material
- B22F9/08—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/06—Making metallic powder or suspensions thereof using physical processes starting from liquid material
- B22F9/08—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
- B22F9/082—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
- B22F2009/086—Cooling after atomisation
- B22F2009/0864—Cooling after atomisation by oil, other non-aqueous fluid or fluid-bed cooling
Definitions
- TITLE PRODUCTION OF GRANULES OF REACTIVE METALS, FOR EXAMPLE MAGNESIUM AND MAGNESIUM ALLOY
- This invention relates to the production of solid metallic granules from molten metal and, in particular, to the production of granules of a reactive metal such as magnesium or a magnesium alloy.
- US Patent 4,457,775 issued on July 3, 1984 to Legge et al discloses a method for producing Mg granules by mixing Mg into a salt bath of specific composition with agitation, then partially separating the product from the bath to obtain a salt/granule mixture. Because of the production method, the composition is somewhat variable. Metal granules or shot from less reactive metals (iron, steel, copper, etc.) have been produced by injection from a nozzle into liquid baths or into counter- current gas streams. The former process is a difficult operation for a reactive metal and the latter process requires a spray tower of substantial height, and is limited in practice to granules of small diameter because of cooling considerations.
- An object of the present invention is to provide a method for producing acceptably uniform metal granules, preferably of a reactive metal, with substantially no surface contamination
- Another object of the invention is to provide a method for producing acceptably uniform metal granules, preferably of a reactive metal, of a size range suitable for alloying with metals, for example steel or aluminum.
- Still another object of the invention is to provide a novel magnesium granule product for use in metal alloying applications .
- a process whereby a molten metal is divided into discrete droplets, the droplets are immersed while still substantially molten in a bed of solid particles operated as a fluidized bed at a temperature below the solidus point of the metal, and the droplets are frozen in the bed as discrete granules of metal .
- the invention is particularly suited for the production of reactive metal granules but may, if desired, be used for producing granules of other metals, e.g. non-reactive metals of many different kinds.
- apparatus for producing granules of a metal comprising: a source of molten metal having a solidus temperature; a droplet forming device for forming discrete droplets of molten metal from said source; a fluidized bed of particles for receiving droplets of molten metal from said droplet forming device while said droplets are still substantially molten; cooling equipment for maintaining said fluidized bed at a temperature substantially below the solidus temperature of the metal; and a separator for separating solidified granules of said metal from particles of said fluidized bed.
- a magnesium-containing alloying additive for use in aluminum alloying, comprising granules of a magnesium-containing metal having a solidus temperature, said granules being at least partially coated with a chloride salt and having a granule size in the range of 1 to 10 millimetres.
- the magnesium containing metal may be either magnesium or a magnesium alloy.
- the reactive metals to which the present invention preferably relates are characterized as being sufficiently reactive with air or water such that the use of water or large quantities or air to quench and cool the metal granules would give rise to substantial oxidation of the product.
- Many metals in Group la, Ila or Ilia are of this type, e.g. lithium, sodium, potassium, cesium, magnesium, calcium, beryllium, aluminum, and strontium, and most importantly aluminum and magnesium and their alloys.
- Discrete droplets of the metal can be formed in a number of ways, e.g. by the use of a vibrating nozzle, or by the use of a fixed nozzle or array of fixed nozzles. It is particularly preferred because of cheapness and reliability to use an array of fixed nozzles.
- the droplet size may be controlled not only by the nozzle diameter but also by the differential pressure of the molten metal applied to the upstream side of the nozzle, and by the nozzle geometry.
- the fluidized bed of particles may consist of a wide range of particulate materials, for example, metals (e.g. as metal shot) , carbon or graphite, refractory materials or salts.
- the particle sizes are selected to be substantially smaller than the desired product granule size, and of a size that can be readily fluidized. Suitable particle sizes are typically in the range 30 to 200 Tyler mesh (74 to 500 microns) . Particles of refractory materials and salts, and mixtures of the two are particularly useful.
- Fluidized bed particles may be selected to have a composition and size such that they react at a slow rate with the metal granules to form surface coatings.
- Particles may alternatively be selected to be non-reactive with the metal granules.
- bed particles can be chosen that adhere to the metal granule surface as it solidifies within the bed to form a full or partial coating of non-reactive particles, at least partially embedded in the surface of the granule. If non-reactive bed particles have a melting point near or below the temperature of the metal used to form the granules, partial melting of the particles can occur as the metal granules contact the particles, further improving the coating quality.
- the fluidized bed is operated at an average temperature below the solidus temperature of the metal and preferably at least 100°C below the solidus temperature of the metal and most preferably at least 200°C below the solidus temperature.
- the temperature of the bed is preferably selected to provide adequate cooling of the solidifying metal granules, but also to control the degree of reaction when reactive bed particles are used or the quality and extent of coating when non-reactive bed particles are used.
- the fluidized bed is fluidized by a gas or gas mixture that is preferably substantially non-reactive with the metal.
- the gas mixture may, however, contain small quantities of gases that are reactive with the metal granules to form solid salts on the metal surface to impart protection against oxidation or other useful properties.
- salts such as AlF 3 , CaF 2 , etc.
- salts when used in the fluidized bed, allow chemical reactions with the magnesium to take place, which result in the formation of a full or partial layer of a compounds (eg MgF 2 ) on the surface of the granule, providing protection from oxidation or other useful properties.
- a refractory material such as alumina
- chemical reactions with the magnesium can result in full or partial layers of compounds, such as spinel, on the surface of the granule.
- Magnesium granules produced with non-reactive salt coatings are particularly useful for subsequent injection into baths of aluminum for alloying purposes.
- Salts which melt below the temperature of the aluminum bath are effective for this purpose, particularly salts which melt below 750°C. It is preferred that such salts melt below the temperature of the magnesium metal used in forming the granules and in particular it is preferred that the salts melt below 700°C.
- a preferred salt for this application is a NaCl-KCl mixture. Coatings of this type will melt on contact with the aluminum melt and thus offer a low heat transfer resistance to the melting of the magnesium granules. Moreover, the liquid salt layer or zone does not offer any mechanical resistance to mixing and therefore allows easy dispersion of the liquid magnesium droplets.
- the fluidized bed is preferably operated using non-reactive gases such as argon, nitrogen or carbon dioxide.
- Gas mixtures containing a small quantity of reactive component such as sulphur hexafluoride may be used to form small and controlled quantities of salts (magnesium fluoride) on the surface of the granule.
- Gas mixtures in which the minor component stabilizes the granule surface chemistry and thereby permits a normally reactive major component to be used are also useful.
- a mixture of air with sulphur hexafluoride can be used.
- the fluidized bed is operated at a temperature of less than 500°C and preferably less than 350°C. For practical purposes it is usual to operate the bed above ambient temperature and preferably above 50°C.
- the average bed temperature is normally at least about 100°C less than the melting point of the salt, and the actual bed temperature may be selected based on the degree of coating desired on the granules.
- the bed materials are substantially non-reactive and do not adhere strongly when in contact with the granules, and therefore, by adjusting the bed temperature, not only can the degree of reaction or coating be adjusted, but at the lowest temperatures, the bed permits substantially contamination free granules to be produced.
- the fluid bed conditions are controlled to give a partial coating of chloride salts on the granule surface, and minimal surface oxides.
- the amount of chloride salt on the magnesium granule surfaces is ideally less than 5% by weight and preferably less than 2% by weight to ensure the rapid melting and mixing required by the product .
- the fluidized bed may be cooled by any convenient method of indirect cooling.
- the preferred cooling method is to have heat exchanger coils inserted within and around the bed.
- bed material may be removed in a continuous manner, cooled in a secondary fluidized bed unit, and then returned to the main bed.
- the solidified granules form regular shapes, usually spheres or flattened spheres. They do not usually have elongated tails or contain substantial shrinkage cavities. The lack of tails or large shrinkage cavities is particularly useful when the granules are used for alloying purposes.
- the fluidized bed provides a form of contact with the molten metal droplets that does not distort the liquid in any way, and because of the presence of particles at a temperature within the preferred range, the rate of cooling of the granules permits the formation of relatively large granules (1 to 10 mm, for example) without significant shrinkage cavities or other such features.
- Granules prepared by the process of the present invention may be removed from the bed by any convenient method, provided the removal method does not introduce reactive gases into the bed.
- the process may be run as a batch process by operating the fluid bed until a layer of metal granules is produced at the bottom of the bed and then stopping the process to remove the granules .
- Figure 1 shows a vertical cross-section of a fluidized bed apparatus used to carry out the process of the present invention in a preferred embodiment
- Figure 2 shows a horizontal cross section of the apparatus of Figure 1 taken through one of the cooling coils, along line II-II;
- Figure 3 is a cross-section of part of the apparatus of Figure 1 taken along the line III-III;
- Figure 4 shows a vertical cross-section of a nozzle within the nozzle plate of the apparatus of Figure 1;
- Figure 5 is a view similar to Figure 4 of an alternative nozzle plate; and Figure 6 shows a molten metal feeding furnace that may be used in this invention.
- a preferred fluidized bed apparatus is shown in Figure 1.
- a bed of particles 12 is contained within a vessel 10.
- a cooling jacket 11, with coolant inlet 55 and coolant outlet 56, is provided around the outer surface of the vessel 10 and cooling channels 11a (shown more clearly in Fig. 2) are provided within the interior of the vessel.
- the particles 12 to be fluidized are supported on a fluidization plate 13. Behind this plate is a plenum chamber 14 formed between the fluidization plate and the bottom of the vessel, and this chamber is fed by a fluidization gas via a connecting pipe 15 and control valve 16.
- a horizontal screen filter 19 Within the particle bed 12, and supported from the vessel walls, is a horizontal screen filter 19 with openings of size 13x13 mm or as required to trap oversized granules which might block the granule removal system.
- a second screen 17 with openings of 2 mm diameter, or as required to provide a lower size cutoff for the product granules, is located lower in the vessel and is sloped towards an outlet 18 (shown in greater detail in Fig. 3) in the side of the vessel at the bottom.
- Outlet 18 is approximately semi-circular with a radius of about 50mm.
- This outlet communicates with a vertical gas channel 20 on the side of the vessel 10 entraining an upward flow of gas as shown by the arrow, and together these features form a pneumatic knife for separation of product granules from the particles of the fluidized bed.
- the vertical gas channel terminates in a duct 21 in which is positioned a pressure control valve 22.
- the vessel 10 has an opening 23 above the surface of the particle bed 12 also communicating the gas channel 20.
- the bottom of the gas channel 20 communicates via a passage 30 leading to a product collection bin 31.
- the bed particles are periodically removed and returned to the fluidized bed and the product granules are also periodically removed.
- a source of gas for the pneumatic knife is provided via the feed pipe 33 and the flow of gas is controlled by a valve 34.
- a molten metal feed trough 40 is provided, which is fed with molten metal 41 from an external source (not shown in Figure 1, but see Figure 6) .
- a metal level sensor 42 is provided which is used to control the external feed to maintain the metal surface 43 at a constant level in the trough.
- the metal feed trough is covered by a cover 44 which contains a cover gas inlet 45 and control valve 46.
- the bottom surface 50 of the molten metal feed trough forms a nozzle plate containing a multiplicity of nozzles.
- An individual nozzle formed in the bottom surface 50 of the molten metal feed trough is shown in Figure 4 and consists of an upper cylindrical opening 51 and a smaller lower cylindrical orifice 52. Molten metal flows through the opening 51 and the orifice 52 under the effect of gravity (and possibly differential gas pressure) to form individual droplets 53 (see Fig. 1) .
- FIG. 5 An alternative nozzle design is shown in Figure 5 in which the underside of the nozzle plate 50 has a nozzle extension or tip 54 (that is preferably inwardly tapering and optimally frustoconical) surrounding the lower outlet of each orifice 52 and projecting downwardly from the underside of the nozzle plate 50.
- the nozzle tips 54 improve the reproducibility of metal droplet formation by reducing any tendency of the metal to flow along the underside of the nozzle plate rather than to remain concentrated around the outlets of the orifices 52.
- the lengths and angles of taper of these tips may vary considerably, but may be chosen to optimize the reproducibility of droplet formation without unduly complicating the design of the nozzle plate 50.
- Figure 6 shows one embodiment of a molten metal source for use with the apparatus of Fig. 1.
- a cover 65 is provided and contains a port 66 and valve 67 through which a cover gas may be fed.
- a covered port 68 is provided for adding metal ingots.
- a displacement block 70 is provided which can be adjusted vertically (as shown by the arrow) by an external actuator (not shown) which in turn responds to the metal level sensor 42 in the fluid bed apparatus.
- the molten metal source provides the metal 41 for the trough 40 of the fluid bed apparatus.
- the fluidized bed 12 preferably consists of particles in the size range 30 to 200 mesh (74 to 500 microns) .
- the bed is fluidized by a gas (generally argon) entering via feed pipe 15 and valve 16.
- the gas is preferably regulated to give an average velocity of 0.01 to 0.1 m/second, sufficient to fluidize the bed.
- the bed consists typically of aluminum fluoride, alumina, calcium fluoride or NaCl-KCl.
- the pneumatic knife channel 20 is preferably fed by gas at a gas velocity (in channel 20) of between 0.02 to 1 m/sec in order to generate a bubbling fluidized bed mode of operating at the bed exit location. Argon or air may be used since there is little leakage into the bed from the channel 20.
- the pressure control valve 22 in the exhaust duct 21 controls the pressure in the bed 12 and the duct 20 and maintains it at a preset level generally slightly in excess of atmospheric pressure. These conditions cause any bed particles escaping by the opening 18 to be suspended in the gas flow whilst the larger product granules fall into the collection bin 31 via the passage 30. The suspended bed particles then return to the bed via opening 23, or may be collected and returned periodically to the bed. Some bed particles may fall into the collection bin 31 along with the product granules, and the screen 32 ensures that these are separated from the product granules and they may be collected and may returned to the fluidized bed when required.
- the bed is heated in operation by the inflow of molten metal, but the temperature is controlled by flowing coolant through the channels 11 at a rate sufficient to maintain the bed temperature at a preset level within the range 50 to 350°C or more preferably 50 to 150°C.
- the lower range is used when reaction between the bed particles and the molten metal is to be avoided.
- molten metal 41 is supplied to the metal trough 40 at a rate sufficient to maintain the metal level at a constant level.
- the metal flow through the nozzle plate 50 and the size of the droplets 53 formed is then controlled by the nozzle geometry the differential pressure across the nozzle plate. This differential pressure is the difference between the metal head and the pressure in the bed controlled by valve 22.
- a nozzle plate will have 25 to 30 nozzles for a throughput of 90 kg/hr of molten metal.
- a metal head of about 50 mm and a bed pressure of 1 inch of water gives suitable metal droplet flow and sizes.
- a cover gas is added via port 45 and valve 46. The feed rate is maintained to create a very slight positive pressure in the area above the molten metal 41, but because the cover on the trough is not tight fitting the pressure above the metal is substantially atmospheric.
- a variety of non-reactive cover gases may be used, but in the case of molten magnesium, a mixture containing SF 6 is particularly useful.
- a metal head preferably between 25 and 75 mm and a number of different sources of molten metal may be used with this invention provided that they can ensure a constant metal head in the metal trough 40.
- a tilting furnace can be used, where the tilt control and hence metal feed rate is controlled by the metal level sensor 42.
- FIG 6 Another method is shown in Figure 6 where, in operation, the crucible 61 is charged with ingots (for example of magnesium) and these are heated to above the melting point (680 to 700°C for magnesium) .
- the metal displacement block 70 is then adjusted to maintain the level of metal constant in the metal trough. As the metal in the furnace is consumed, more ingots can be added at the port 68.
- the bed was fluidized with argon at a flowrate sufficient to ensure a velocity of 0.02 m/sec within the bed.
- the pneumatic knife operated with argon at a flow velocity of 0.05 m/sec, corresponding to a flow rate of 3.5 m 3 /hr.
- magnesium granules of generally spherical shape were produced with 92% in the size range 4.7 to 6.7 mm.
- the spherical granules formed in the process had only small shrinkage cavities and had a shiny appearance.
- the granules had a thin surface coating of MgF 2 and no strongly adhering salt particles.
- Magnesium granules were fabricated in a manner identical to Example 1 except that the bed temperature was maintained at 150 ⁇ 5°C. In this case the granules had a black appearance and were more substantially coated with a layer of magnesium fluoride than in Example 1.
- the granules produced had a metallic-like finish with a discontinuous coating of NaCl/KCl particles anchored to the surface.
- the amount of chloride salt adhering to the final product after screening was about 1% by weight of the product .
- the melting behaviour of these granules was tested on a small scale by immersing the granules below the surface of an aluminum melt and determining the time required for the granules to melt. No agitation was used.
- the melting times of the granules coated with chloride salts of this invention were compared to the melting times for other coatings produced by the apparatus and method of this example. Results are shown in Table 1, and indicated that the chloride coated granules of this invention melted substantially faster in this test than other granules. The granules of this invention melted sufficiently fast that, on injection below the surface of a commercial aluminum bath, they would be expected to be fully melted and dispersed before buoyancy forces caused them to reach the surface of the aluminum bath and oxidize.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA 2202742 CA2202742C (en) | 1994-10-28 | 1995-10-27 | Production of granules of reactive metals, for example magnesium and magnesium alloy |
GB9708275A GB2309465B (en) | 1994-10-28 | 1995-10-27 | Production of granules of reactive metals,for example magnesium and magnesium alloy |
AU36954/95A AU704321B2 (en) | 1994-10-28 | 1995-10-27 | Production of granules of reactive metals, for example magnesium and magnesium alloy |
DE19581818T DE19581818T1 (en) | 1994-10-28 | 1995-10-27 | Production of granules from reactive metals, for example magnesium and magnesium alloy |
US08/809,018 US5951738A (en) | 1995-10-27 | 1995-10-27 | Production of granules of reactive metals, for example magnesium and magnesium alloy |
JP8514206A JPH10506434A (en) | 1994-10-28 | 1995-10-27 | Production of granules of active metals such as magnesium and magnesium alloys |
NO971896A NO971896L (en) | 1994-10-28 | 1997-04-24 | Preparation of granules of reactive metals, for example magnesium and magnesium alloy |
US09/347,049 US6251158B1 (en) | 1995-10-27 | 1999-07-02 | Production of granules of reactive metals, for example magnesium and magnesium alloy |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US33090494A | 1994-10-28 | 1994-10-28 | |
US330,904 | 1994-10-28 | ||
US08346488 US5549732B1 (en) | 1994-11-29 | 1994-11-29 | Production of granules of reactive metals for example magnesium and magnesium alloy |
US346,488 | 1994-11-29 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US08/809,018 Continuation US5951738A (en) | 1995-10-27 | 1995-10-27 | Production of granules of reactive metals, for example magnesium and magnesium alloy |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996013351A1 true WO1996013351A1 (en) | 1996-05-09 |
Family
ID=26987506
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA1995/000605 WO1996013351A1 (en) | 1994-10-28 | 1995-10-27 | Production of granules of reactive metals, for example magnesium and magnesium alloy |
Country Status (7)
Country | Link |
---|---|
JP (1) | JPH10506434A (en) |
AU (1) | AU704321B2 (en) |
DE (1) | DE19581818T1 (en) |
GB (1) | GB2309465B (en) |
IL (1) | IL115780A (en) |
NO (1) | NO971896L (en) |
WO (1) | WO1996013351A1 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110465673B (en) * | 2019-09-28 | 2020-07-28 | 南阳裕泰隆粉体材料有限公司 | Dust protected metal powder apparatus for producing |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1637377A (en) * | 1926-01-22 | 1927-08-02 | Armour & Co | Pellet-forming apparatus |
FR2150710A1 (en) * | 1971-08-31 | 1973-04-13 | Mannesmann Ag | |
AU6886674A (en) * | 1974-05-13 | 1975-11-13 | Vni I Proketny I Titana And I | Producing granules of magnesium |
EP0066305A1 (en) * | 1981-05-27 | 1982-12-08 | Metallgesellschaft Ag | Additive in wire form for treating molten metals |
WO1986006013A1 (en) * | 1985-04-16 | 1986-10-23 | Battelle Memorial Institute | Process for the manufacture of metallic powders |
WO1994017941A1 (en) * | 1993-02-06 | 1994-08-18 | Osprey Metals Limited | Production of powder |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3969104A (en) * | 1974-02-19 | 1976-07-13 | Ivan Andreevich Barannik | Granules of magnesium and its alloys |
NO148061C (en) * | 1981-02-05 | 1986-05-13 | Norsk Hydro As | PROCEDURE FOR THE PREPARATION OF SALT COATED METAL PARTICLES. |
-
1995
- 1995-10-26 IL IL11578095A patent/IL115780A/en not_active IP Right Cessation
- 1995-10-27 AU AU36954/95A patent/AU704321B2/en not_active Ceased
- 1995-10-27 DE DE19581818T patent/DE19581818T1/en not_active Withdrawn
- 1995-10-27 WO PCT/CA1995/000605 patent/WO1996013351A1/en active Application Filing
- 1995-10-27 JP JP8514206A patent/JPH10506434A/en active Pending
- 1995-10-27 GB GB9708275A patent/GB2309465B/en not_active Expired - Fee Related
-
1997
- 1997-04-24 NO NO971896A patent/NO971896L/en not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1637377A (en) * | 1926-01-22 | 1927-08-02 | Armour & Co | Pellet-forming apparatus |
FR2150710A1 (en) * | 1971-08-31 | 1973-04-13 | Mannesmann Ag | |
AU6886674A (en) * | 1974-05-13 | 1975-11-13 | Vni I Proketny I Titana And I | Producing granules of magnesium |
EP0066305A1 (en) * | 1981-05-27 | 1982-12-08 | Metallgesellschaft Ag | Additive in wire form for treating molten metals |
WO1986006013A1 (en) * | 1985-04-16 | 1986-10-23 | Battelle Memorial Institute | Process for the manufacture of metallic powders |
WO1994017941A1 (en) * | 1993-02-06 | 1994-08-18 | Osprey Metals Limited | Production of powder |
Also Published As
Publication number | Publication date |
---|---|
JPH10506434A (en) | 1998-06-23 |
DE19581818T1 (en) | 1997-10-16 |
IL115780A0 (en) | 1996-01-19 |
GB9708275D0 (en) | 1997-06-18 |
NO971896D0 (en) | 1997-04-24 |
IL115780A (en) | 1999-08-17 |
NO971896L (en) | 1997-04-24 |
AU3695495A (en) | 1996-05-23 |
GB2309465A (en) | 1997-07-30 |
AU704321B2 (en) | 1999-04-22 |
GB2309465B (en) | 1998-07-08 |
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