WO1996007955A1 - Imaging apparatus and photoreceptor therefor - Google Patents

Imaging apparatus and photoreceptor therefor Download PDF

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Publication number
WO1996007955A1
WO1996007955A1 PCT/NL1995/000201 NL9500201W WO9607955A1 WO 1996007955 A1 WO1996007955 A1 WO 1996007955A1 NL 9500201 W NL9500201 W NL 9500201W WO 9607955 A1 WO9607955 A1 WO 9607955A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
edge
photoreceptor
conductive
photoconductive
Prior art date
Application number
PCT/NL1995/000201
Other languages
French (fr)
Inventor
Haim Belinkov
Alon Gazit
Ilan Kander
Yakov Krumberg
Ilan Meiri
Yehuda Niv
Yossi Rosen
Ami Shiff
Shlomo Yitzhaik
Original Assignee
Indigo N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/301,775 external-priority patent/US5508790A/en
Priority claimed from IL11378795A external-priority patent/IL113787A0/en
Application filed by Indigo N.V. filed Critical Indigo N.V.
Priority to JP50938896A priority Critical patent/JP4101288B2/en
Priority to AU25797/95A priority patent/AU2579795A/en
Priority to EP95920303A priority patent/EP0779997B1/en
Priority to DE69535470T priority patent/DE69535470T2/en
Priority to IL11520795A priority patent/IL115207A0/en
Publication of WO1996007955A1 publication Critical patent/WO1996007955A1/en

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/65Apparatus which relate to the handling of copy material
    • G03G15/6597Apparatus which relate to the handling of copy material the imaging being conformed directly on the copy material, e.g. using photosensitive copy material, dielectric copy material for electrostatic printing
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G15/00Apparatus for electrographic processes using a charge pattern
    • G03G15/75Details relating to xerographic drum, band or plate, e.g. replacing, testing
    • G03G15/751Details relating to xerographic drum, band or plate, e.g. replacing, testing relating to drum
    • G03G15/752Details relating to xerographic drum, band or plate, e.g. replacing, testing relating to drum with renewable photoconductive layer
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/10Bases for charge-receiving or other layers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/10Bases for charge-receiving or other layers
    • G03G5/101Paper bases
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/10Bases for charge-receiving or other layers
    • G03G5/102Bases for charge-receiving or other layers consisting of or comprising metals
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/10Bases for charge-receiving or other layers
    • G03G5/105Bases for charge-receiving or other layers comprising electroconductive macromolecular compounds
    • G03G5/108Bases for charge-receiving or other layers comprising electroconductive macromolecular compounds the electroconductive macromolecular compounds being anionic

Definitions

  • the present invention relates to image forming and image transfer apparatus especially for use in electrostatic imaging using a sheet type photoreceptor.
  • Organic photoreceptor materials for use in toner imaging are well known.
  • the organic photoreceptor is coated onto a drum or endless belt on which an electrostatic image is formed.
  • a sheet of photoreceptor material is mounted onto a drum to provide the same function.
  • the present invention seeks to provide, in a first aspect thereof, improved image forming apparatus utilizing a new sheet photoreceptor configuration.
  • imaging apparatus including: a substantially rectangular organic photoreceptor sheet including a backing layer, a conductive layer and a photoconductive layer, wherein along one edge of the sheet there is an exposed conductive area, preferably an exposed portion of the conductive layer; a drum having a longitudinal cavity formed therein and including a slot formed between the cavity and the cylindrical surface of the drum into which the one edge of the photoreceptor sheet is inserted; and a rotatable element within the cavity which, in a locking position, presses the sheet, and preferably the conductive area thereof against a wall of the cavity, fixedly and removably holding the photoreceptor sheet in place.
  • the conductive area is pressed against the rotatable element.
  • the drum is at substantially ground electrical potential .
  • both the photoconductive and conductive layers are not present and wherein the portion of the photoreceptor sheet overlies the slot .
  • the chargeable photoreceptor includes a dust masking layer, preferably of paper, between the backing layer and the drum .
  • the dust absorbing is attached to the backing layer only along an edge of the paper layer, preferably adj acent to the slot .
  • a substantially rectangular organic photoreceptor sheet including a backing layer , a conductive layer and a photoconductive layer wherein along one edge thereof the photoconductive layer is not present such that the conductive layer is exposed .
  • a substantially rectangular organic photoreceptor sheet including a backing layer , a conductive layer and a photoconductive layer wherein along one edge thereo f there is an exposed conductive area.
  • both the photoconductive and conductive layers are not present.
  • the photoreceptor sheet includes a dust masking layer , preferably of paper , proximate the backing layer .
  • the dust absorbing is attached to the backing layer only along an edge of the dust absorbing layer, preferably adjacent to exposed conductive edge.
  • a substantially rectangular organic photoreceptor sheet including a backing layer , a conductive layer and a photoconductive layer wherein along one edge thereof the photoconductive layer and the conductive layers are not present .
  • the photoreceptor sheet includes a dust masking layer , preferably of paper, proximate the backing layer .
  • the dust absorbing is attached to the backing layer only along an edge of the dust absorbing layer .
  • the dust masking layer i s attached adjacent to and displaced from an edge of the photoreceptor opposite the one edge thereof at which the photoconductive layer and the conductive layers are not present .
  • a substantially rectangular organic photoreceptor sheet including a backing layer, a conductive layer and a photoconductive layer and further including a dust masking layer, preferably a paper layer, proximate the backing layer.
  • the dust masking layer is attached to the backing layer only along an edge of the dust masking layer, preferably , adj acent to and displaced from an edge of the photoreceptor.
  • a substantially rectangular organic photoreceptor sheet including a backing layer, a conductive layer and a photoconductive layer, wherein an edge of the backing layer extends beyond an edge of the photoconductive layer and beyond an edge of the conductive layer and wherein the edge of the conductive layer is coated with a layer of substantially insulating material .
  • the insulating material preferably includes a dielectric material .
  • the insulating material includes HumiSeal type 1A24.
  • the respective edges of the photoconductive layer and the conductive layer are substantially aligned .
  • the edge of the conductive layer extends slightly beyond the respective edge of the photoconductive layer.
  • FIGS. 1A and IB are cross-sectional, simplified, overall and expanded, partial drawings, respectively of a drum on which a photoreceptor is mounted, showing a mounting method for photoreceptors in accordance with a preferred embodiment of the invention
  • Figs. 1C and ID show an alternative method for mounting photoreceptors in respective open and gripping configurations
  • Fig. 2A and 2B are respective top and side views of a photoreceptor in accordance with a preferred embodiment of the invention
  • Figs . 2C and 2D are cross-sectional partial side views of the photoreceptor of Figs . 2A and 2B; Fig .
  • FIG. 2E is a cross-sectional partial side view of a photoreceptor in accordance with another , pre ferred , embodiment of the present invention
  • Fig . 3A and 3B are cross-sectional partial side views of two, respective, types of insulated-edge photoreceptors, constructed in accordance with a further pre ferred embodiment of the present invention
  • Figs . 4A, 4B, and 4C are respective side view, top view , and side view illustrations of three , respective , steps in a preferred method of forming the insulated edge photoreceptor of Fig. 3A.
  • FIG. 1A - ID and 2A - 2D A novel photoreceptor sheet 12 and apparatus and a method for mounting the sheet on a drum 10 are shown in Figs. 1A - ID and 2A - 2D.
  • Photoreceptor sheet 12 is preferably mounted on drum 10 using the mechanisms shown in Figs. 1A and IB or 1C and ID. As shown most clearly in Fig. IB, one end of photoconductive sheet is inserted into a slot 140 which forms the entryway to a cavity 142 formed in drum 10. An eccentric cylindrical 1 cam 144 which is situated in the cavity can be rotated to
  • the photoreceptor can be any photoreceptor 3 shown by dotted lines in Fig. IB, the photoreceptor can be
  • cam 144 is rotated to the position shown by the
  • FIGS. 1C and ID show a rotating member 20 having a
  • the photoreceptor can be inserted into slot 140
  • resilient element 22 is
  • Photoreceptor sheet 12 consists essentially of an
  • 29 photoreceptor sheet 12 comprises four layers, a paper layer
  • a backing layer 152 such as of Mylar
  • the photoconductive layer comprises a
  • a photoconductive layer for simplicity of the discussion, since the exact construction of the photoconductive layer or layers does not form a part of the present invention.
  • a preferred photoreceptor is, for example, Emerald 2 (manufactured by Lexmark) .
  • the photoconductor should preferably be treated by one of the treatments specified in PCT publication WO 91/17485 which corresponds to copending U.S. Application 07/946,411, the disclosure of which is incorporated by reference. In general these applications describe several processes. In one process, the photoreceptor sheet is mounted on a drum with the photoconductive surface facing outwards.
  • the sheet is subjected to heat treatment which removes stress from the photoconductive layer without removing it from the backing layer.
  • the photoreceptor is now cooled, without removing it from the drum.
  • the photoconductive layer is in compression and the backing layer is in tension.
  • the photoreceptor sheet is subjected to tension and heated to a temperature at which the photoconductive layer is stress released but at which the backing is not stress released.
  • the sheet is cooled and then the tension is removed. This process also results in a photoreceptor sheet in which the photoconductive layer is in compression and the backing layer is in tension.
  • the surface of the photoconductive layer is chemically treated to remove stress from the layer and make it more plastic or elastic than it previously was.
  • Figs. IB-ID Preferably materials such as cyclohexanone are used to chemically treat the photoconductive layer.
  • the end of the sheet which is inserted into slot 140 has only two layers, i.e. , backing layer 152 and conducting layer 154. This assures that the conducting layer, when pressed against the interior of cavity 140 by cam 144 or member 22, will make good electrical contact with the cavity wall. This provides convenient grounding of the conductive layer, even when the backing layer and the paper layer are not conducting.
  • the photoreceptor can be provided with a conductive edge which is electrically connected with the conductive layer and either the cavity wall or resilient member 22, or both.
  • the paper layer as indicated above, is not attached to the back of the backing layer over the length of the photoreceptor. However, in a preferred embodiment of the invention, the paper is attached to the backing layer near the leading edge of the photoreceptor and at the end of the paper, i.e., at reference numeral 158.
  • the function of the paper layer is to reduce the effect of dust or other particles which may be on the drum (or possibly between the photoreceptor and the paper) from effecting the imaging process by causing pressure points on the surface of the photoreceptor.
  • the other end of the photoreceptor (its trailing edge), which is shown in detail in Fig. 2D preferably comprises only the backing layer, and, as shown in Figs. IB -ID, the backing layer extension is long enough to overlay slot 140 so as to avoid liquid toner entering cavity 142.
  • the outer surface of drum 10 is shaped near slot 140 (at reference numeral 160) to provide a slope so that the contact between the photoreceptor and surfaces which it contacts is smooth, i.e., such that the overall diameter of the drum and the photoreceptor and, if present, the overlaying trailing edge, remains independent of the angular position on the drum. All the layers other than the backing layer are removed at the trailing edge mainly to obviate any chance that the conducting surface will touch a charging device such as a scorotron which is normally present in electrostatic imaging apparatus.
  • a charging device such as a scorotron which is normally present in electrostatic imaging apparatus.
  • the generally dielectric backing layer 152 remains substantially constantly charged, at the trailing edge, when the photoreceptor sheet is in operative use. This results in electrostatic attraction between drum 10 and the charged trailing edge of sheet 12, assisting in the adherence of sheet 12 to drum 10. It should be noted that sheet 12 is generally not attached to drum 10 by mechanical means, other than at the leading edge, to account for possible variations in the length of sheet 12 during operation. The electrostatic force provided by the dielectric trailing edge of sheet 12 allows circumferential relative motion between sheet 12 and drum 10.
  • the trailing edge of the photoreceptor is cut at a slight angle to square, of about 1 in 35. This angle is used to provide a smooth transition of contact, at the edge, for a cleaner blade, used to clean untransferred toner from the photoreceptor, prior to the next imaging cycle.
  • a photoreceptor sheet having square cut ends or having one or both edges cut at a slight angle is referred to herein as a "substantially rectangular" photoreceptor sheet. All edges and transitions are preferably smooth without jagged margins. For clarity, the overlapping end of the photoreceptor sheet is not shown in Figs. 1C and ID.
  • leading and trailing edges of the photoreceptor can be varied to suit the particular application.
  • the present inventors have found that the leading, conductive edge (inserted into slot 140) of the photoreceptor is preferably about 13 mm wide and the trailing edge (for overlap) is preferably about 20 mm wide.
  • the direction of rotation of drum 10 is shown by an arrow 162.
  • Fig. 2D Unfortunately, these desired arrangements of the trailing edges have been found to be extremely difficult to implement.
  • FIG. 2E illustrates an alternative, more practical, embodiment of the trailing edge of photoreceptor sheet 12 in which conductive layer 154 extends slightly beyond photoreceptor layer 156.
  • the above described photoreceptor sheet 12 may be used in any known electrostatic imaging device.
  • liquid toner imaging apparatus is used, preferably of the type described in U.S. Patent application 08/371117, filed January 11, 1995, the disclosure of which is incorporated herein by reference.
  • an electrically biased squeegee roller (not shown) is used for squeegeeing a layer of liquid toner which is developed onto the photoreceptor surface.
  • the squeegee roller is typically electrically biased, preferably to a negative voltage of 1300-1600 Volts, and urged against the photoreceptor with a predetermined pressure, typically approximately 90 grams per centimeter along the length of the squeegee roller.
  • a predetermined pressure typically approximately 90 grams per centimeter along the length of the squeegee roller.
  • This breakdown of voltage may occur during actual contact between the squeegee roller and the trailing edge of layer 154 or by arcing between the squeegee roller and the conductive layer. Actual contact between the edge of layer 154 and the squeegee roller is possible, particularly in the embodiment of Fig. 2E, due to slight compliance of the generally resilient sheet 12 when urged by the generally rigid squeegee roller. It is appreciated that the above described breakdown results in gradual , accumulative, deterioration of both photoreceptor surface 12 and the squeegee rol ler .
  • the trailing edge of layer 154 is insulated to prevent breakdown, as described in detai l below . I t should be noted that insulation of the trailing edge of layer 154 is preferred also in the desired , yet not readi ly implemented , arrangement (not shown in the drawings ) in which the trailing edge of layer 156 extends beyond the trailing edge of layer 154. Figs.
  • FIG. 3A and 3B which schematically illustrate two types of trailing edges, analogous to the two types of trailing edges shown in Figs. 2D and 2E, respectively, whose conductive layers 154 are electrically insulated at edges 170 and 172, respectively, in accordance with a preferred embodiment of the present invention.
  • a layer 175 of, preferably dielectric, insulating material is applied to trailing edge 170 (Fig. 3A) or trailing edge 172 (Fig. 3B), preventing electrical breakdown thereat.
  • layer 175 preferably extends slightly beyond edges 170 or 172, both on photoreceptor layer 156 and on backing layer 152.
  • extension 176 is preferably made extremely thin to avoid damage to the scraper. This is because the scrapers used by such imaging systems are generally extremely sensitive to protrusions in the direction of scraping.
  • insulating layer 175 is formed of HumiSeal type 1A24, a vinyl-modified- epoxy based dielectric material, available from Columbia Chase Corporation, New York, USA.
  • This insulating material is provided in a solids concentration of 20-24 percent by weight and a viscosity of 100-130 centipoise and has a drying/handling time of 15 minutes and a recommended curing time of 24 hours in room temperature.
  • the material can be thinned, for example using acetone, to adjust the viscosity of the material for a given method of application.
  • the cured layer is generally transparent, highly adhesive, very flexible and very durable to varying temperature and humidity conditions.
  • the cured layer has a dielectric withstand voltage of approximately 3,900 Volts, a dielectric constant of approximately 2.88 at 1MHz and 25 degrees centigrade, a dissipation factor of 0.002, an insulation resistance of approximately 350,000,000 Megohms and a moisture resistance of approximately 30,000 Megohms.
  • the material is also highly resistant to solvents and various chemicals.
  • layer 175 may be formed of any other suitable dielectric material.
  • layer 175 may be formed of HumiSeal type 1A33, a polyurethane based dielectric material, or the layer may be formed of a material based on polyvinyl alcohol (88% hydrolyzed), as described in copending U.S.
  • FIG. 4A-4C schematically illustrate a preferred method of applying layer 175 to edge 170, by metered brushing. It should be appreciated that the same application method can be used for applying layer 175 to edge 172 if sheet 12 is constructed as in Fig. 2E. Although the method of Figs. 4A-4C has been found effective, it should be appreciated that other application methods, such as spraying or dipping, may also suitable.
  • Fig. 4A illustrates a first step in the metered application method, in which a series of drops 178 of the insulating material are guided along the surface of an 1 application blade 177 to a portion of backing layer 152
  • Drops 178 are preferably
  • Fig. 4C illustrates a preferred brushing technique
  • Brushing sheet 180 may be formed of any suitable rubber or
  • brushing sheet 180 is formed of the material used for the

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  • Spectroscopy & Molecular Physics (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Abstract

Imaging apparatus incorporating a substantially rectangular organic photoreceptor sheet having a backing layer, a conductive layer and a photoconductive layer, wherein along one edge of the sheet there is an exposed conductive area, a drum having a longitudinal cavity formed therein and including a slot formed between the cavity and the cylindrical surface of the drum into which the one edge of the photoreceptor sheet is inserted and a rotatable element within the cavity which, in a locking position, presses the sheet against a wall of the cavity, fixedly and removably holding the photoreceptor sheet in place.

Description

- 1 -
IMAGING APPARATUS AND PHOTORECEPTOR THEREFOR FIELD OF THE INVENTION The present invention relates to image forming and image transfer apparatus especially for use in electrostatic imaging using a sheet type photoreceptor. BACKGROUND OF THE INVENTION Organic photoreceptor materials for use in toner imaging are well known. In some systems the organic photoreceptor is coated onto a drum or endless belt on which an electrostatic image is formed. In other systems a sheet of photoreceptor material is mounted onto a drum to provide the same function. SUMMARY OF THE INVENTION The present invention seeks to provide, in a first aspect thereof, improved image forming apparatus utilizing a new sheet photoreceptor configuration. The present invention further seeks to provide, in a second aspect thereof, an improved sheet photoreceptor for use in such apparatus. There is thus provided, in accordance with a preferred embodiment of the invention imaging apparatus including: a substantially rectangular organic photoreceptor sheet including a backing layer, a conductive layer and a photoconductive layer, wherein along one edge of the sheet there is an exposed conductive area, preferably an exposed portion of the conductive layer; a drum having a longitudinal cavity formed therein and including a slot formed between the cavity and the cylindrical surface of the drum into which the one edge of the photoreceptor sheet is inserted; and a rotatable element within the cavity which, in a locking position, presses the sheet, and preferably the conductive area thereof against a wall of the cavity, fixedly and removably holding the photoreceptor sheet in place. Alternatively, the conductive area is pressed against the rotatable element. In a preferred embodiment of the invention, the drum is at substantially ground electrical potential . In a preferred embodiment of the invention on a portion of the photoreceptor sheet , along a second edge thereof opposite the one edge , both the photoconductive and conductive layers are not present and wherein the portion of the photoreceptor sheet overlies the slot . Preferably, the chargeable photoreceptor includes a dust masking layer, preferably of paper, between the backing layer and the drum . Preferably , the dust absorbing is attached to the backing layer only along an edge of the paper layer, preferably adj acent to the slot . There i s f urther provided , in accordance wi th a preferred embodiment of the invention , a substantially rectangular organic photoreceptor sheet including a backing layer , a conductive layer and a photoconductive layer wherein along one edge thereof the photoconductive layer is not present such that the conductive layer is exposed . There i s f urther provided , in accordance wi th a preferred embodiment of the invention , a substantially rectangular organic photoreceptor sheet including a backing layer , a conductive layer and a photoconductive layer wherein along one edge thereo f there is an exposed conductive area. Preferably, along a second edge opposite the one edge, both the photoconductive and conductive layers are not present. Preferably the photoreceptor sheet includes a dust masking layer , preferably of paper , proximate the backing layer . Preferably, the dust absorbing is attached to the backing layer only along an edge of the dust absorbing layer, preferably adjacent to exposed conductive edge. There i s further provided , in accordance with a preferred embodiment of the invention, a substantially rectangular organic photoreceptor sheet including a backing layer , a conductive layer and a photoconductive layer wherein along one edge thereof the photoconductive layer and the conductive layers are not present . Preferably the photoreceptor sheet includes a dust masking layer , preferably of paper, proximate the backing layer . Preferably, the dust absorbing is attached to the backing layer only along an edge of the dust absorbing layer . Preferably the dust masking layer i s attached adjacent to and displaced from an edge of the photoreceptor opposite the one edge thereof at which the photoconductive layer and the conductive layers are not present . There i s further provided , in accordance wi th a preferred embodiment of the invention , a substantially rectangular organic photoreceptor sheet including a backing layer, a conductive layer and a photoconductive layer and further including a dust masking layer, preferably a paper layer, proximate the backing layer. Preferably, the dust masking layer is attached to the backing layer only along an edge of the dust masking layer, preferably , adj acent to and displaced from an edge of the photoreceptor. In accordance with a further, preferred, embodiment of the present invention, there is provided a substantially rectangular organic photoreceptor sheet including a backing layer, a conductive layer and a photoconductive layer, wherein an edge of the backing layer extends beyond an edge of the photoconductive layer and beyond an edge of the conductive layer and wherein the edge of the conductive layer is coated with a layer of substantially insulating material . The insulating material preferably includes a dielectric material . In a preferred embodiment of the present invention, the insulating material includes HumiSeal type 1A24. I n a pref erred embodiment o f the invention , the respective edges of the photoconductive layer and the conductive layer are substantially aligned . Alternatively, in a preferred embodiment of the invention, the edge of the conductive layer extends slightly beyond the respective edge of the photoconductive layer. BRIEF DESCRIPTION OF THE DRAWINGS The present invention wi l l be understood and appreciated more f ul ly f rom the fol lowing detai led description, taken in conj unction with the drawings in which: Fig. 1A and IB are cross-sectional, simplified, overall and expanded, partial drawings, respectively of a drum on which a photoreceptor is mounted, showing a mounting method for photoreceptors in accordance with a preferred embodiment of the invention; Figs. 1C and ID show an alternative method for mounting photoreceptors in respective open and gripping configurations; Fig. 2A and 2B are respective top and side views of a photoreceptor in accordance with a preferred embodiment of the invention; Figs . 2C and 2D are cross-sectional partial side views of the photoreceptor of Figs . 2A and 2B; Fig . 2E is a cross-sectional partial side view of a photoreceptor in accordance with another , pre ferred , embodiment of the present invention; Fig . 3A and 3B are cross-sectional partial side views of two, respective, types of insulated-edge photoreceptors, constructed in accordance with a further pre ferred embodiment of the present invention; and Figs . 4A, 4B, and 4C are respective side view, top view , and side view illustrations of three , respective , steps in a preferred method of forming the insulated edge photoreceptor of Fig. 3A. DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS A novel photoreceptor sheet 12 and apparatus and a method for mounting the sheet on a drum 10 are shown in Figs. 1A - ID and 2A - 2D. Photoreceptor sheet 12 is preferably mounted on drum 10 using the mechanisms shown in Figs. 1A and IB or 1C and ID. As shown most clearly in Fig. IB, one end of photoconductive sheet is inserted into a slot 140 which forms the entryway to a cavity 142 formed in drum 10. An eccentric cylindrical 1 cam 144 which is situated in the cavity can be rotated to
2 one of two positions. With the cam in a first position
3 shown by dotted lines in Fig. IB, the photoreceptor can be
4 inserted into the slot and between the cam and a wall of
5 cavity 142. After the photoreceptor is in the position shown
6 in Fig. IB, cam 144 is rotated to the position shown by the
7 solid lines, thereby pressing the cam against the
8 photoreceptor and holding it in position on the drum.
9 Figs. 1C and ID show a rotating member 20 having a
10 resilient element 22, such as a row of spring fingers
11 attached thereto and facing toward the outside of the drum.
12 When the rotating member is in an open position as shown in
13 Fig. 1C, the photoreceptor can be inserted into slot 140
14 past resilient element 22. Preferably, resilient element 22
15 guides the inserted end of the photoreceptor to position 141
16 which acts to assure that the photoreceptor is positioned
17 without skew relative to the rotating direction.
18 When the rotating element is turned as shown in Fig. ID
19 the resilient fingers press against the photoreceptor and
20 hold it firmly against the outer wall of cavity 142.
21 A preferred embodiment of the photoreceptor sheet 12
22 which is especially suitable for mounting in accordance with
23 the method illustrated in Figs. 1A to ID is shown in Figs.
24 2A-2D.
25 Photoreceptor sheet 12 consists essentially of an
26 especially configured photoreceptor and an attached sheet of
27 paper or other dust encasing material such as rubber. As
28 shown most clearly in Figs. 2B-2D, a central portion 150 of
29 photoreceptor sheet 12 comprises four layers, a paper layer
30 151, which is shown bottom most on Figs. 2B-2D and is in
31 contact with drum 10, a backing layer 152, such as of Mylar
32 or the like adjacent to the paper layer, preferably attached
33 thereto and preferably not attached thereto over its entire
34 surface, a conducting layer 154 overlying the backing layer
35 and a photoconductive layer 156 overlying the conducting
36 layer. In general the photoconductive layer comprises a
37 charge transport layer and a charge generation layer;
38 however, these are referred to herein as a "photoconductive layer" for simplicity of the discussion, since the exact construction of the photoconductive layer or layers does not form a part of the present invention. A preferred photoreceptor is, for example, Emerald 2 (manufactured by Lexmark) . To improve compatibility of the photoreceptor when it is used with liquid toner, the photoconductor should preferably be treated by one of the treatments specified in PCT publication WO 91/17485 which corresponds to copending U.S. Application 07/946,411, the disclosure of which is incorporated by reference. In general these applications describe several processes. In one process, the photoreceptor sheet is mounted on a drum with the photoconductive surface facing outwards. The sheet is subjected to heat treatment which removes stress from the photoconductive layer without removing it from the backing layer. The photoreceptor is now cooled, without removing it from the drum. When the photoreceptor is removed from the drum, the photoconductive layer is in compression and the backing layer is in tension. In a second process the photoreceptor sheet is subjected to tension and heated to a temperature at which the photoconductive layer is stress released but at which the backing is not stress released. The sheet is cooled and then the tension is removed. This process also results in a photoreceptor sheet in which the photoconductive layer is in compression and the backing layer is in tension. In a third process the surface of the photoconductive layer is chemically treated to remove stress from the layer and make it more plastic or elastic than it previously was. Preferably materials such as cyclohexanone are used to chemically treat the photoconductive layer. What should be noted in Figs. IB-ID is that not all of the layers extend to the ends of photoreceptor sheet 12. In particular, the end of the sheet which is inserted into slot 140 (the "leading edge" of the sheet), as shown in Figs. 1B- ID, has only two layers, i.e. , backing layer 152 and conducting layer 154. This assures that the conducting layer, when pressed against the interior of cavity 140 by cam 144 or member 22, will make good electrical contact with the cavity wall. This provides convenient grounding of the conductive layer, even when the backing layer and the paper layer are not conducting. Alternatively, the photoreceptor can be provided with a conductive edge which is electrically connected with the conductive layer and either the cavity wall or resilient member 22, or both. The paper layer, as indicated above, is not attached to the back of the backing layer over the length of the photoreceptor. However, in a preferred embodiment of the invention, the paper is attached to the backing layer near the leading edge of the photoreceptor and at the end of the paper, i.e., at reference numeral 158. The function of the paper layer is to reduce the effect of dust or other particles which may be on the drum (or possibly between the photoreceptor and the paper) from effecting the imaging process by causing pressure points on the surface of the photoreceptor. The optimum thickness of the paper layer has been found, for the particular photoreceptor described above, to be between about 50 micrometers and 300 micrometers and a soft, open weave paper such as Nordland Woodtree uncoated white bond printing paper (120g/m2, =150 micrometers thick, manufactured by Nordland, Germany) is preferred. The other end of the photoreceptor (its trailing edge), which is shown in detail in Fig. 2D preferably comprises only the backing layer, and, as shown in Figs. IB -ID, the backing layer extension is long enough to overlay slot 140 so as to avoid liquid toner entering cavity 142. Further, the outer surface of drum 10 is shaped near slot 140 (at reference numeral 160) to provide a slope so that the contact between the photoreceptor and surfaces which it contacts is smooth, i.e., such that the overall diameter of the drum and the photoreceptor and, if present, the overlaying trailing edge, remains independent of the angular position on the drum. All the layers other than the backing layer are removed at the trailing edge mainly to obviate any chance that the conducting surface will touch a charging device such as a scorotron which is normally present in electrostatic imaging apparatus. Due to the absence of grounded conducting layer 154 at the trailing edge of the photoreceptor sheet, the generally dielectric backing layer 152 remains substantially constantly charged, at the trailing edge, when the photoreceptor sheet is in operative use. This results in electrostatic attraction between drum 10 and the charged trailing edge of sheet 12, assisting in the adherence of sheet 12 to drum 10. It should be noted that sheet 12 is generally not attached to drum 10 by mechanical means, other than at the leading edge, to account for possible variations in the length of sheet 12 during operation. The electrostatic force provided by the dielectric trailing edge of sheet 12 allows circumferential relative motion between sheet 12 and drum 10. Finally, if the photoreceptor is pressed against another surface, the trailing edge of the photoreceptor is cut at a slight angle to square, of about 1 in 35. This angle is used to provide a smooth transition of contact, at the edge, for a cleaner blade, used to clean untransferred toner from the photoreceptor, prior to the next imaging cycle. A photoreceptor sheet having square cut ends or having one or both edges cut at a slight angle is referred to herein as a "substantially rectangular" photoreceptor sheet. All edges and transitions are preferably smooth without jagged margins. For clarity, the overlapping end of the photoreceptor sheet is not shown in Figs. 1C and ID. The dimensions of the leading and trailing edges of the photoreceptor can be varied to suit the particular application. The present inventors have found that the leading, conductive edge (inserted into slot 140) of the photoreceptor is preferably about 13 mm wide and the trailing edge (for overlap) is preferably about 20 mm wide. For reference the direction of rotation of drum 10 is shown by an arrow 162. To avoid possible voltage breakdown, for reasons described in detail below, it is generally desired that the trailing edge of photoconductive layer 156 extend beyond the trailing edge of conductive layer 154 or, at least, that the two edges be substantially aligned, as shown in Fig. 2D. Unfortunately, these desired arrangements of the trailing edges have been found to be extremely difficult to implement. Fig. 2E illustrates an alternative, more practical, embodiment of the trailing edge of photoreceptor sheet 12 in which conductive layer 154 extends slightly beyond photoreceptor layer 156. The above described photoreceptor sheet 12 may be used in any known electrostatic imaging device. However, in a preferred embodiment of the present invention, liquid toner imaging apparatus is used, preferably of the type described in U.S. Patent application 08/371117, filed January 11, 1995, the disclosure of which is incorporated herein by reference. In such imaging apparatus, an electrically biased squeegee roller (not shown) is used for squeegeeing a layer of liquid toner which is developed onto the photoreceptor surface. The squeegee roller is typically electrically biased, preferably to a negative voltage of 1300-1600 Volts, and urged against the photoreceptor with a predetermined pressure, typically approximately 90 grams per centimeter along the length of the squeegee roller. This provides both electrical and mechanical squeegeeing of the layer of liquid toner on the photoreceptor. It has been found that the large difference in electric potential between the squeegee roller and conductive layer 154 of sheet 12, which is typically grounded as described above, may result in electrical breakdown at the trailing edge of layer 154. This breakdown of voltage may occur during actual contact between the squeegee roller and the trailing edge of layer 154 or by arcing between the squeegee roller and the conductive layer. Actual contact between the edge of layer 154 and the squeegee roller is possible, particularly in the embodiment of Fig. 2E, due to slight compliance of the generally resilient sheet 12 when urged by the generally rigid squeegee roller. It is appreciated that the above described breakdown results in gradual , accumulative, deterioration of both photoreceptor surface 12 and the squeegee rol ler . Consequently, the cumulative damage to the squeegee roller results in degraded performance of the imaging apparatus due to less effective and inhomogeneous squeegeeing of the liquid toner on the photoreceptor surface . Thus , in a preferred embodiment of the present invention, the trailing edge of layer 154 is insulated to prevent breakdown, as described in detai l below . I t should be noted that insulation of the trailing edge of layer 154 is preferred also in the desired , yet not readi ly implemented , arrangement ( not shown in the drawings ) in which the trailing edge of layer 156 extends beyond the trailing edge of layer 154. Figs. 3A and 3B which schematically illustrate two types of trailing edges, analogous to the two types of trailing edges shown in Figs. 2D and 2E, respectively, whose conductive layers 154 are electrically insulated at edges 170 and 172, respectively, in accordance with a preferred embodiment of the present invention. According to this preferred embodiment, a layer 175 of, preferably dielectric, insulating material is applied to trailing edge 170 (Fig. 3A) or trailing edge 172 (Fig. 3B), preventing electrical breakdown thereat. To ensure complete coverage of edge 170 or edge 172, layer 175 preferably extends slightly beyond edges 170 or 172, both on photoreceptor layer 156 and on backing layer 152. The extension of layer 175 on layer 156 is indicated by reference numeral 176. For imaging systems using a scraper, such as a doctor blade, extension 176 is preferably made extremely thin to avoid damage to the scraper. This is because the scrapers used by such imaging systems are generally extremely sensitive to protrusions in the direction of scraping. In a preferred embodiment of the invention, insulating layer 175 is formed of HumiSeal type 1A24, a vinyl-modified- epoxy based dielectric material, available from Columbia Chase Corporation, New York, USA. This insulating material is provided in a solids concentration of 20-24 percent by weight and a viscosity of 100-130 centipoise and has a drying/handling time of 15 minutes and a recommended curing time of 24 hours in room temperature. The material can be thinned, for example using acetone, to adjust the viscosity of the material for a given method of application. The cured layer is generally transparent, highly adhesive, very flexible and very durable to varying temperature and humidity conditions. The cured layer has a dielectric withstand voltage of approximately 3,900 Volts, a dielectric constant of approximately 2.88 at 1MHz and 25 degrees centigrade, a dissipation factor of 0.002, an insulation resistance of approximately 350,000,000 Megohms and a moisture resistance of approximately 30,000 Megohms. The material is also highly resistant to solvents and various chemicals. Although the use of HumiSeal type 1A24 is preferred, layer 175 may be formed of any other suitable dielectric material. For example, layer 175 may be formed of HumiSeal type 1A33, a polyurethane based dielectric material, or the layer may be formed of a material based on polyvinyl alcohol (88% hydrolyzed), as described in copending U.S. Patent application 08/371117, filed January 11, 1995, the disclosure of which is incorporated herein by reference. Reference is now made to Figs. 4A-4C which schematically illustrate a preferred method of applying layer 175 to edge 170, by metered brushing. It should be appreciated that the same application method can be used for applying layer 175 to edge 172 if sheet 12 is constructed as in Fig. 2E. Although the method of Figs. 4A-4C has been found effective, it should be appreciated that other application methods, such as spraying or dipping, may also suitable. Fig. 4A illustrates a first step in the metered application method, in which a series of drops 178 of the insulating material are guided along the surface of an 1 application blade 177 to a portion of backing layer 152
2 close to edge 170 of layer 154. Drops 178 are preferably
3 separated from edge 170 by a gap of approximately 3-4
4 millimeters. The series of drops formed on layer 152 in
5 parallel with edge 170 is shown in Fig. 4B. Sheet 12 is
6 preferably positioned on a detachable base layer, preferably
7 formed of paper or the like, which extends beyond sheet 12
8 at least at the portion indicated by reference numeral
9 179. This enables application of at least one drop of
10 insulating outside the boarders of sheet 12, allowing
11 complete coverage of edge 170 by the brushing described
12 below.
13 Fig. 4C illustrates a preferred brushing technique,
14 wherein a smooth and straight edge of a brushing sheet 180,
15 preferably formed of a resilient material, is urged against
16 the sheet 12 and moved in a brushing motion along edge 170.
17 Brushing sheet 180 may be formed of any suitable rubber or
18 plastic material having a suitable resilience and surface
19 smoothness. In one preferred embodiment of the invention,
20 brushing sheet 180 is formed of the material used for the
21 intermediate transfer blanket described in U.S. Patent
22 application 08/371117, the disclosure of which is
23 incorporated herein by reference. In the configuration of
24 drops 178 shown in Fig. 4B, the brushing action is from
25 bottom to top, starting from region 179 outside sheet 12.
26 To ensure complete coverage of edge 170, the total
27 amount of insulating material in drops 178 is equal to at
28 least the volume enclosed by the trailing edges of layers
29 154 and 156, protruding layer 152 and the brushing plane
30 defined by the action of brushing sheet 180. The resilience
31 of the edge of brushing sheet 180 ensures gap-free
32 application of insulating layer 175 to edge 170 and
33 maintains the thickness of extension 176 of layer 175 at a
34 minimum.
35 It will be appreciated by persons skilled in the art
36 that the present invention is not limited by the description
37 and example provided hereinabove. Rather, the scope of this
38 invention is defined only by the claims which follow:

Claims

CLAIMS 1. A substantially rectangular organic photoreceptor sheet comprising a backing layer, a conductive layer and a photoconductive layer wherein along one edge thereof the photoconductive layer is not present such that the conductive layer is exposed.
2. A substantially rectangular organic photoreceptor sheet comprising a backing layer, a conductive layer and a photoconductive layer wherein along one edge thereof there is an exposed conductive area.
3. A organic photoreceptor sheet according to claim 1 or claim 2 wherein along one edge thereof the photoconductive layer and the conductive layers are not present such that the backing layer extends beyond the edge of the photoconductive and conductive layers.
4. A substantially rectangular organic photoreceptor sheet comprising a backing layer, a conductive layer and a photoconductive layer wherein along one edge thereof the photoconductive layer and the conductive layers are not present such that the backing layer extends beyond the edge of the photoconductive and conductive layers.
5. An organic photoreceptor sheet according to claim 4 or claim 5, wherein the edge of the conductive layer is coated with a layer of substantially insulating material.
6. A photoreceptor sheet according to claim 5 wherein the insulating material comprises a dielectric material.
7. A photoreceptor sheet according to claim 5 or claim 6 wherein the insulating material comprises HumiSeal type 1A24.
8. A photoreceptor sheet according to any of claims 3-7 wherein the respective edges of the photoconductive layer 1 and the conductive layer are substantially aligned. 2
3 9. A photoreceptor sheet according to any of claims 3-7
4 wherein the edge of the conductive layer extends slightly
5 beyond the respective edge of the photoconductive layer. 6
7 10. A photoreceptor sheet according to any claims 3-9
8 wherein the edge of the photoreceptor at which the
9 photoconductive layer and the conductive layer is not
10 present is somewhat out of square with adjoining edges of
11 the photoreceptor.
12
13 11. A photoreceptor sheet according to any of claims 1-10
14 and further comprising a dust masking layer proximate the
15 backing layer.
16
17 12. A substantially rectangular organic photoreceptor sheet
18 comprising a backing layer, a conductive layer and a
19 photoconductive layer and further comprising a dust masking
20 layer proximate the backing layer.
21
22 13. A photoreceptor sheet according to claim 11 or claim 12
23 wherein the dust masking layer is a paper layer. 24
25 14. A photoreceptor sheet according to any of claims 11-13
26 wherein the dust masking layer is attached to the backing
27 layer only along an edge of the dust masking layer. 28
29 15. A photoreceptor sheet according to any of claims 11-14
30 wherein the dust masking layer is attached adjacent to the
31 one edge of the photoreceptor having the exposed conductor
32 layer. 33
34 16. A photoreceptor sheet according to any of claims 11-15
35 wherein the dust masking layer is attached adjacent to and
36 displaced from an edge of the photoreceptor opposite the one
37 edge thereof at which the photoconductive layer and the
38 conductive layers are not present. 1
2 17. Imaging apparatus comprising:
3 a substantially rectangular organic photoreceptor sheet
4 comprising a backing layer, a conductive layer and a
5 photoconductive layer, wherein along one edge of the sheet
6 there is an exposed conductive area;
7 a drum having a longitudinal cavity formed therein and
8 including a slot formed between the cavity and the
9 cylindrical surface of the drum into which the one edge of
10 the photoreceptor sheet is inserted; and
11 a rotatable element within the cavity which, in a
12 locking position, presses the sheet against a wall of the
13 cavity, fixedly and removably holding the photoreceptor
14 sheet in place. 15
16 18. Apparatus according to claim 17 wherein the conductive
17 area is an exposed portion of the conductive layer, the
18 photoconductive layer being absent. 19
20 19. Apparatus according to claim 17 or claim 18 wherein the
21 conductive area is pressed against the wall of the cavity. 22
23 20. Apparatus according to claim 17 or claim 18 wherein the
24 conductive area is pressed against the rotatable element. 25
26 21. Imaging apparatus according to any of claims 17-20 the
27 drum is at substantially ground electrical potential. 28
29 22. Imaging apparatus according to any of claims 17-21
30 wherein, on a portion of the photoreceptor sheet, along a
31 second edge thereof opposite the one edge, both the
32 photoconductive and conductive layers are not present and
33 wherein said portion of the photoreceptor sheet overlies the
34 slot. 35
36 23. Imaging apparatus according to any of claims 17-22
37 wherein the chargeable photoreceptor comprises a dust
38 masking layer between the backing layer and the drum. 24. Imaging apparatus according to any of claims 23 wherein the dust absorbing layer is attached to the backing layer adjacent to the slot.
25. Imaging apparatus according to any of claims 17-24 wherein the photoreceptor sheet comprises a photoreceptor sheet according to any of claims 1-16.
PCT/NL1995/000201 1994-09-07 1995-06-06 Imaging apparatus and photoreceptor therefor WO1996007955A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP50938896A JP4101288B2 (en) 1994-09-07 1995-06-06 Image forming apparatus and its photoreceptor
AU25797/95A AU2579795A (en) 1994-09-07 1995-06-06 Imaging apparatus and photoreceptor therefor
EP95920303A EP0779997B1 (en) 1994-09-07 1995-06-06 Imaging apparatus and photoreceptor therefor
DE69535470T DE69535470T2 (en) 1994-09-07 1995-06-06 A PHOTO RECEPTOR PAPER
IL11520795A IL115207A0 (en) 1994-09-07 1995-09-07 Imaging apparatus and photoreceptor therefor

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/301,775 US5508790A (en) 1994-09-07 1994-09-07 Photoreceptor sheet and imaging system utilizing same
US08/301,775 1994-09-07
IL11378795A IL113787A0 (en) 1995-05-18 1995-05-18 Imaging apparatus and photoreceptor therefor
IL113787 1995-05-18

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Publication Number Publication Date
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AU (1) AU2579795A (en)
CA (1) CA2199374A1 (en)
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WO (1) WO1996007955A1 (en)

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US6163676A (en) * 1995-09-08 2000-12-19 Indigo N.V. Imaging apparatus and improved exit device therefor
WO2003019296A1 (en) * 2001-08-30 2003-03-06 Hewlett-Packard Indigo B.V. Scratch resistant organic photoreceptor
US6562539B1 (en) 1999-07-05 2003-05-13 Indigo N.V. Printers and copiers with pre-transfer substrate heating

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JP6354218B2 (en) * 2014-03-07 2018-07-11 三菱ケミカル株式会社 Sheet-like electrophotographic photoreceptor and method for producing sheet-like electrophotographic photoreceptor

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WO2003019296A1 (en) * 2001-08-30 2003-03-06 Hewlett-Packard Indigo B.V. Scratch resistant organic photoreceptor

Also Published As

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DE69535470D1 (en) 2007-05-31
EP0779997A1 (en) 1997-06-25
JP4101288B2 (en) 2008-06-18
CA2199374A1 (en) 1996-03-14
AU2579795A (en) 1996-03-27
DE69535470T2 (en) 2008-01-03
EP0779997B1 (en) 2007-04-18
JPH10505434A (en) 1998-05-26

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