WO1996006073B1 - Liquid crystal materials - Google Patents
Liquid crystal materialsInfo
- Publication number
- WO1996006073B1 WO1996006073B1 PCT/PL1995/000016 PL9500016W WO9606073B1 WO 1996006073 B1 WO1996006073 B1 WO 1996006073B1 PL 9500016 W PL9500016 W PL 9500016W WO 9606073 B1 WO9606073 B1 WO 9606073B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- formulae
- denote
- group
- denotes
- atom
- Prior art date
Links
- 239000000463 material Substances 0.000 title claims 2
- 239000004973 liquid crystal related substance Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 5
- 239000007788 liquid Substances 0.000 claims abstract 5
- 125000000596 cyclohexenyl group Chemical class C1(=CCCCC1)* 0.000 claims abstract 3
- 239000000203 mixture Substances 0.000 claims abstract 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims 4
- 125000001153 fluoro group Chemical group F* 0.000 claims 4
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 2
- 239000002178 crystalline material Substances 0.000 claims 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 2
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 claims 2
- -1 (2) Chemical class 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical class [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
Abstract
The invention relates to novel compounds of formula R1-A1-Z1-A2-Z2-A3-R2 in which Z1 and Z2 are laterally substituted cyclohexane and cyclohexene rings such as (2), (3), (4), (5), (6), (7), (8), (9). The compounds are useful as components of liquid crystalline mixtures for display applications.
Claims
1. Liquid crystalline compounds represented by general formula 1 in which R1 and R~ are the same or different and represent a terminal group Y-(CH2)n-(O)m-(CH2)1(-(O)r(CH2)p- or Y-(CH2)n-CH=CH-(CH2)p-, where Y is an H, F, or Cl atom or a CN or OCF3 group, n, p and k assume values from 0 to 7, while m and I denote 0 or 1; Z1 denotes a ring of the formula chosen from the set comprising formulae 4,5,8, 9, ∑2 denotes a single bond or a ring chosen from the set comprising formulae 4,5,8, 9 and at the same time the position of cyclohexene rings Z, and Z-. in relation to other neighboring rings is always such that their double bond is not conjugated with an aromatic ring; Y, in formulae 4,5,8 and 9 denotes a F, Cl atom or a CN group; A, A2, A, denote a single bond or a fragment from the set comprising formulae from 10 to 18, where X,, X2, Xa and X4 are independent and denote an H or F atom, while B and B, denote a single bond or a CH2-CH2, C=C, CH=CH, OCH2, CH2O bridge group.
2. Liquid crystalline mixtures containing at least two compounds and at least one of them is a compound of general formula 1,
R*ι-Aι---.^-A2---^-A3-K2 1 in which R1 and R2 are the same or different and represent a terminal group Y-tCH^O^-CCH^^OHCHjJp- or Y-(CH2)n-CH-=CH-(CH2)p-, where Y is an H, F, or Cl atom or CN, OCF3 group, n, p and k assume values from 0 to 7, while m and I denote 0 or 1; Tr. denotes a ring of formula chosen from the set comprising formulae 4,5,8, 9, Z2 denotes a single bond or a ring chosen from the set comprising formulae 4,5,8, 9 and a position of cyclohexene rings Z, and Z-. in relation to other neighboring rings is always such that their double bond is not conjugated with an aromatic ring; Y1 in formulae 4,5,8 and 9 denotes a F, Cl atom or a CN group; A, A2< A3 denote a single bond or the fragment of a formula from the set comprising formulae from 10 to 18, where X„ X2, X3 and X4 are independent and denote an H or F atom, while B and B1 denote a single bond or a CH2- CH2, C≡C, CH=CH, OCH2 or CH2O bridge group.
3. A display consisting of two parallel plates, at least one of which is made of transparent material, supporting the electrodes, aligning and/or isolating layers and/or colored filters, between which a liquid crystalline material is used, characterized by the fact that said liquid crystalline material is a mixture as descriebed in claim 2.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PLP.304748 | 1994-08-18 | ||
PL30474894A PL304748A1 (en) | 1994-08-18 | 1994-08-18 | Liquid-crystalline compounds, mixes containing them and lc display employing such mixes |
PLP.310027 | 1995-08-16 | ||
PL31002795A PL310027A1 (en) | 1995-08-16 | 1995-08-16 | Derivatives of cyclohexane and liquid crystal mixes containing them |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1996006073A1 WO1996006073A1 (en) | 1996-02-29 |
WO1996006073B1 true WO1996006073B1 (en) | 1996-03-14 |
Family
ID=26653129
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/PL1995/000016 WO1996006073A1 (en) | 1994-08-18 | 1995-08-18 | Liquid crystal materials |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO1996006073A1 (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19607996B4 (en) * | 1996-03-04 | 2008-07-03 | Merck Patent Gmbh | Liquid-crystalline medium containing at least one substituted cyclohex-3-en-yl derivative |
DE19723276B4 (en) * | 1997-06-04 | 2008-11-27 | Merck Patent Gmbh | Liquid-crystalline medium containing cyclohexane derivatives |
KR20110015605A (en) * | 2008-06-09 | 2011-02-16 | 짓쏘 가부시끼가이샤 | Pentacyclic liquid crystal compound having cyclohexane ring, liquid crystal composition and liquid crystal display element |
KR102176450B1 (en) * | 2013-04-11 | 2020-11-09 | 스미또모 가가꾸 가부시키가이샤 | Composition for forming optically anisotropic layer |
KR102651756B1 (en) * | 2016-08-11 | 2024-03-29 | 삼성디스플레이 주식회사 | Liquid crystal display and liquid crystal composition comprised thereof |
CN114106850B (en) * | 2021-12-17 | 2022-11-18 | 重庆汉朗精工科技有限公司 | Positive liquid crystal composition and application thereof in liquid crystal display device |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3510434A1 (en) * | 1985-03-22 | 1986-09-25 | Merck Patent Gmbh, 6100 Darmstadt | CYCLOHEXANDERIVATE |
DE3510432A1 (en) * | 1985-03-22 | 1986-09-25 | Merck Patent Gmbh, 6100 Darmstadt | CYCLOHEXANDERIVATE |
JP3151929B2 (en) * | 1992-05-15 | 2001-04-03 | 大日本インキ化学工業株式会社 | Fluorocyclohexene derivative |
DE4227772C2 (en) * | 1992-08-23 | 2002-01-24 | Merck Patent Gmbh | 2-fluoro-perfluoroalkylcyclohexene derivatives and their use |
DE4427266A1 (en) * | 1993-08-06 | 1995-02-09 | Merck Patent Gmbh | 2-Fluorocyclohexene derivatives |
-
1995
- 1995-08-18 WO PCT/PL1995/000016 patent/WO1996006073A1/en active Search and Examination
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