WO1996005055B1 - Barrier films - Google Patents
Barrier filmsInfo
- Publication number
- WO1996005055B1 WO1996005055B1 PCT/US1995/008664 US9508664W WO9605055B1 WO 1996005055 B1 WO1996005055 B1 WO 1996005055B1 US 9508664 W US9508664 W US 9508664W WO 9605055 B1 WO9605055 B1 WO 9605055B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- layer
- film
- heat sealable
- polymeric material
- ethylene
- Prior art date
Links
- 239000010410 layer Substances 0.000 claims abstract 18
- 239000000463 material Substances 0.000 claims abstract 9
- 239000002131 composite material Substances 0.000 claims abstract 6
- 239000002365 multiple layer Substances 0.000 claims abstract 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052799 carbon Inorganic materials 0.000 claims abstract 3
- 229920000642 polymer Polymers 0.000 claims 8
- 239000004711 α-olefin Substances 0.000 claims 4
- 239000002253 acid Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 150000008064 anhydrides Chemical class 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 2
- 230000035699 permeability Effects 0.000 claims 2
- 239000011449 brick Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000000806 elastomer Substances 0.000 claims 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 230000001939 inductive effect Effects 0.000 claims 1
- 238000010030 laminating Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 229920005638 polyethylene monopolymer Polymers 0.000 claims 1
- 238000004381 surface treatment Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
Abstract
A multiple-layer composite film comprising: a layer comprising a polymeric base film (12), a barrier layer (13) comprising a carbon-rich material adhered to the base layer, and a heat sealable layer (14) comprising a heat sealable, active gas treated, polymeric material containing ethylene monomeric units adhered to the carbon-rich barrier layer (13).
Claims
1. A multiple-layer composite film comprising:
(a) a base layer comprising a polymeric material;
(b) a barrier layer comprising a carbon-rich material adhered to the base layer, and
(c) a heat sealable layer comprising an active gas treated, heat sealable, polymeric material containing cthylene monomeric units adhered to the barrier layer.
2. The film of claim 1 wherein the heat sealable layer is corona-treated.
3. The film of claims 1 or 2 having a peel strength between the heat sealable layer and the barrier layer of at least about 15 ounces/inch (167 grams/cm).
4. The film of claims 1 or 2 wherein the base layer is directly adhered to the barrier layer, which is directly adhered lo the heat sealable layer.
5. The films of any one of claims 1-4 wherein ϋie heat sealable polymeric material comprises a heat sealable polymer selected from the group consisting of an cthylene-α-olefin polymer; an acid or anhydride modified ethylene-α-olefin polymer, an ethylene-conlaining polymer having -C(O)OR groups, -OC(O)R groups; an acid or anhydride modified ethylene-containing polymer having -C(O)OR groups, -OC(O)R groups; an acid or anhydride modified polyethylene homopolymer; and mixtures thereof; wherein R represents a monovalent hydrocarbyl group.
6. The film of any one of claims 1-5 having an oxygen permeability of less than about 2.0 cubic centimeters of oxygen per 1 square meter of film per day, and a moisture permeability of less than about 2.0 grams of water vapor per 1 square meter of film per day.
7. The film of any one of claims 1-6 wherein the heat sealable polymeric material further includes about 10-40% elastomeric polymer.
8. The film of claim 1 wherein the heat sealable polymeric material comprises a single-site, ethylene-α-olefin polymer containing a total α- olcfin content of about 10-30% having a density of less than about 0.930 g/cm3 and a polydispersity of less than about 3.5.
9. A process for preparing the multiple-layer composite film of claims 1 or 2; the process comprising treating the heat sealable layer with an active gas surface treatment technique and laminating it to the barrier layer at a temperature of at least about 82ºC.
10. The process of claim 9 wherein the step of corona treating comprises air corona treating.
11. A container comprising a body having an opening therein and a covering over the opening, the covering comprising the multiple-layer composite film of claims 1 or 2.
12. The container of claim 11 wherein the heat sealable polymeric material comprises a single-site, ethylene-α-olefin polymer or an ethylene propylene elastomer.
13. The container of claims 11 or 12 wherein the multiple-layer composite film is part of an induction innerseal, a tabbed innerseal, a one-piece innerseal, a two-piece innerseal, a lidding film, or a blister pack.
14. A container comprising a body having therein the multiple- layer composite film of claims 1 or 2.
15. The container of claim 13 wherein the body is in the form of a gable-top carton, a brick pack, or a pouch.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU29686/95A AU2968695A (en) | 1994-08-16 | 1995-07-12 | Barrier films |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US29102594A | 1994-08-16 | 1994-08-16 | |
US08/291,025 | 1994-08-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1996005055A1 WO1996005055A1 (en) | 1996-02-22 |
WO1996005055B1 true WO1996005055B1 (en) | 1996-03-21 |
Family
ID=23118515
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1995/008664 WO1996005055A1 (en) | 1994-08-16 | 1995-07-12 | Barrier films |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU2968695A (en) |
WO (1) | WO1996005055A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2797433B1 (en) * | 1999-08-13 | 2001-08-31 | Cebal | TUBE HAVING A FLEXIBLE SKIRT COATED EXTERNALLY WITH A BARRIER LAYER AND METHOD FOR CONTINUOUSLY DEPOSITING THE SAME |
US6866926B1 (en) | 2000-05-09 | 2005-03-15 | Illinois Tool Works Inc. | Polymer lined sealing member for a container |
WO2003066465A1 (en) | 2002-02-07 | 2003-08-14 | Illinois Tool Works Inc. | Container closure |
DE10252553B4 (en) * | 2002-11-08 | 2006-10-19 | Sig Combibloc Systems Gmbh | Plastic-coated composite material for heat-sealable packages and method for its production |
FR2871446B1 (en) * | 2004-06-11 | 2007-06-22 | Pechiney Capsules Soc Par Acti | JOINTS FOR SEALING IN MULTILAYER MATERIAL FOR MEANS OF CLOGGING, TYPICALLY FOR A CAPSULE OF CLOSURE |
SE528260C2 (en) * | 2004-12-14 | 2006-10-03 | Tetra Laval Holdings & Finance | Packaging laminate and packaging container |
DE602006006791D1 (en) | 2006-03-20 | 2009-06-25 | Selig Sealing Products Inc | Multi-layer film for closing of vessels |
CN101992888B (en) * | 2009-08-21 | 2014-01-15 | 翁文桂 | Laminated material without metal foil for blocking package |
CN104527180B (en) * | 2015-01-08 | 2017-01-04 | 苏州鼎九新材料科技有限公司 | A kind of polyamide five-layer co-squeezing composite membrane and preparation method thereof |
JP7404752B2 (en) * | 2019-07-18 | 2023-12-26 | Toppanホールディングス株式会社 | Laminates for highly resistant packaging materials |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3481041D1 (en) * | 1983-05-31 | 1990-02-22 | Idemitsu Petrochemical Co | METHOD FOR TREATING THERMOPLASTIC PLASTIC. |
US4756964A (en) * | 1986-09-29 | 1988-07-12 | The Dow Chemical Company | Barrier films having an amorphous carbon coating and methods of making |
US4855183A (en) * | 1986-11-17 | 1989-08-08 | W. R. Grace & Co.-Conn. | Multiple-layer, cook-in film |
US4853287A (en) * | 1987-10-19 | 1989-08-01 | W. R. Grace & Co. | Highly formable laminates |
JPH0675955B2 (en) * | 1988-07-30 | 1994-09-28 | 出光石油化学株式会社 | Resin laminate |
US5093194A (en) * | 1989-11-01 | 1992-03-03 | Mobil Oil Corporation | Oriented multilayer heat sealable packaging film |
CA2040064C (en) * | 1990-11-16 | 2000-06-13 | Gloria G. Toney | Barrier film with improved extensibility for cheese packaging |
US5523136A (en) * | 1993-04-30 | 1996-06-04 | Cypress Packaging | Packaging film, packages and methods for using them |
-
1995
- 1995-07-12 AU AU29686/95A patent/AU2968695A/en not_active Abandoned
- 1995-07-12 WO PCT/US1995/008664 patent/WO1996005055A1/en active Application Filing
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