WO1995035036A2 - Low fat spread - Google Patents
Low fat spread Download PDFInfo
- Publication number
- WO1995035036A2 WO1995035036A2 PCT/EP1995/002354 EP9502354W WO9535036A2 WO 1995035036 A2 WO1995035036 A2 WO 1995035036A2 EP 9502354 W EP9502354 W EP 9502354W WO 9535036 A2 WO9535036 A2 WO 9535036A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- spread
- carrageenan
- gelling
- water
- pectin
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/015—Reducing calorie content; Reducing fat content, e.g. "halvarines"
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/005—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by ingredients other than fatty acid triglycerides
- A23D7/0056—Spread compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/231—Pectin; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/256—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin from seaweeds, e.g. alginates, agar or carrageenan
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/269—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of microbial origin, e.g. xanthan or dextran
- A23L29/272—Gellan
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/275—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of animal origin, e.g. chitin
- A23L29/281—Proteins, e.g. gelatin or collagen
- A23L29/284—Gelatin; Collagen
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/30—Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
- A23L29/35—Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L35/00—Food or foodstuffs not provided for in groups A23L5/00 – A23L33/00; Preparation or treatment thereof
- A23L35/20—No-fat spreads
Definitions
- the present invention is concerned with spread products, in particular with spread products having a continuous aqueous phase and a low fat content, and processes for their preparation.
- EP-A-298 561 (Unilever) describes the preparation of edible plastic dispersions not having a continuous fat phase, said composition including at least two gelling agents forming two gel-forming compositions.
- Gelatin and gelling hydrolysed starch are exemplified as preferred gelling agents.
- O-A-93/17565 (Unilever) describes low fat water-continuous 30 spread in the form of an edible plastic dispersion comprising gelatin, gelling, hydrolysed starch and low levels of fat.
- EP-A-355 908 (Unilever) relates to thermoreversible microgels of polysaccharides being substantially less rigid than a gel of the same composition formed under quiescent conditions. These gels can be used in stable water-in-oil dispersions EP-A-432 835 (Unilever) relates to chemically set gels prepared under shear, said gels being substantially less rigid than the same composition prepared under quiescent conditions. Fat continuous low fat spreads based thereon are also disclosed.
- a problem with spreads which are water continuous, of low fat content and containing a combination of gelatin and gelling starch is that under normal processing conditions the product is liquid at the end of the production line. This creates the need for liquid filling of the spread when the viscosity is still low. This filling route is less preferred, because it often leads to sloshing in the tub which leads to a less desired appearance of the product.
- the conveyor belt of a filling machine displaces a tub just filled with liquid product, movement of the liquid product in the tub occurs, causing the liquid product to adhere to the walls of the tub and sometimes the lid and generally causes a skinning effect of the product due to drying and this results in an unappetizing and often glossy appearance for the customer.
- an aspect of the present invention relates to a method for producing a spread comprising 0 to 40% of a fatty phase and an aqueous phase comprising water and: (A) from 0.1 to 7 wt% of gelatin;
- (C) from 0.3 to 5 wt%, and preferably 0.5 to 5 wt%, of a gelling polysaccharide selected from the group of agar, kappa-carrageenan, iota-carrageenan, gellan, furcelleran, alginate, pectin and mixtures thereof; wherein the levels of (A) , (B) and (C) are based on the weight of the water; said method comprising the preparation of a premix comprising (A) , (B) and (C) in water by gelling (C) optionally together with (B) in the presence of shear, said premix having a temperature of more than 50°C and cooling said premix to a temperature below 30°C.
- a gelling polysaccharide selected from the group of agar, kappa-carrageenan, iota-carrageenan, gellan, furcelleran, alginate, pectin and mixtures thereof; wherein the levels of
- the method comprises the preparation of a premix comprising (A) , (B) and (C) in water by gelling (C) in the presence of shear, said premix having a temperature of more than 50°C and cooling said premix to a temperature below 30°C.
- a method for producing a spread comprising 0 to 40% of a fatty phase, an aqueous phase comprising water and: (A) from 0.1 to 7 wt% of gelatin;
- (C) from 0.3 to 5 wt%, and preferably 0.5 to 5 wt%, of a gelling polysaccharide selected from the group of agar, kappa-carrageenan, iota-carrageenan, gellan, furcelleran, alginate, pectin and mixtures thereof; wherein the levels of (A) , (B) and (C) are based on the weight of the water; said method comprising the filling of the spread in a tub, whereby the viscosity of the spread at the moment of filling is more than 1.5 Pa.s when measured at 5°C and 20 s "1 .
- a spread in a tub comprising 0 to 40% of a fatty phase, an aqueous phase comprising water and:
- (B) from 2 to 30 wt% of gelling hydrolysed starch; and (C) from 0.5 to 3 wt% of a gelling polysaccharide selected from the group of agar, kappa-carrageenan, iota- carrageenan, gellan, furcelleran, alginate, pectin and mixtures thereof; wherein the levels of (A) , (B) and (C) are based on the weight of the water, wherein the upper surface of the spread is provided with a cover leaf.
- the good quality and quick thickening properties of the product may be caused by the fact that ingredient (C) in water forms polysaccharide "globules" at a temperature and time within the process.
- ingredient (C) in water forms polysaccharide "globules" at a temperature and time within the process.
- the hydrolysed starch phase forms the continuous phase, the gelatin phase being discontinuous.
- the total product hence would contain three gelled phases, one being continuous and two being dispersed in this continuous phase.
- the thickening effect leading to an increased viscosity upon filling is believed to be caused by the quick formation of the discrete polysaccharide "globules" upon cooling under shear.
- the discrete "globules” then are believed to form a network type structure in the product, providing the desired rigidity upon filling. After filling the other two condensed phases will become gelled, providing the final rigidity and plasticity to the product.
- the invention also relates to a spread product containing three gelled phases, one being a continuous phase and two being dispersed phases, wherein one dispersed phase comprises a gelled polysaccharide selected from the group of agar, kappa- carrageenan, iota-carrageenan, gellan, furcelleran, alginate, pectin and mixtures thereof.
- the ability of the gelling agents to form three gelled phases may be detected by any suitable method.
- a convenient method involves the preparation of an intimate mixture of water and the gelling agents, above the gel-forming temperature of these materials, followed by cooling to ambient temperature. The presence of the two phases may then be detected by conventional methods e.g.
- the average particle sizes of the dispersed phases are from 0.1 to 100 ⁇ , more preferred 0.5 to 20 ⁇ m.
- the mean size of of the aggretaes is suitably determined from microphotographs. By another method, the size can be determined by NMR methods as e.g. described in J. of Colloid and Interface Science, Vol. 140. No.l 105-113 (1990) .
- the gelatin level in spreads of the invention is from 0.1 to 7 wt% based on the weight of the water, more preferred from 0.5 to 6 wt%, most preferred from 2 to 5 wt%.
- Any commercially available gelatin may be used, although it is preferred to have a gelatin having a bloom strength between 100 and 300, such as 120, 150 and 250. Especially preferred is the use of gelatin having a bloom strength of about 200 to 270.
- the level of gelling hydrolysed starch is from 2 to 30 wt% based on the weight of the water, preferably it is maltodextrin. Generally these materials will have a low DE value, for example less than 10, more preferred 1-7, most preferred 1.5 to 4. DE stands for Dextrose Equivalent which is a measure for the degree of hydrolysis.
- the level of gelling hydrolysed starch is preferably from 5 to 30 wt%, more preferred 7-25 wt%, most preferred from 10-20 wt%.
- Especially preferred is the use of Paselli SA2 (ex AVEBE, Foxhol, The Netherlands) and N-oil2 (ex National Starch and Chemical Corporation, Bridgewater USA) as gelling hydrolysed starch materials. Also preferred is the use of a rapidly gelling starch as marketed by National Starch and Chemical Corp. under the code number 97-2.
- the level of a gelling polysaccharide selected from the group of agar, kappa-carrageenan, iota-carrageenan, gellan, furcelleran, alginate, pectin and mixtures thereof is between 0.5 and 5 wt%.
- pectin, agar and carrageenan (kappa and iota) are commercially available.
- Agar is generally obtained from Gracilaria and/or Gelidium species.
- Commercially available carrageenan often is a mixture of iota- and kappa carrageenan.
- the gelling polysaccharide is pectin, especially a calcium sensitive pectin meaning that it gels in the presence of alkaline earth ions, more in particular calcium ions.
- M represents a divalent metal, preferably calcium or magnesium.
- the R-value is of between 0.3 and 1.5, more preferably between 0.4 and 1. of course it is the total calcium concentration which counts which includes calcium salt added, calcium from tap water and from dairy products.
- pectin as used herein also includes esterified pectins with 5-50% of the hydroxyl groups esterified, furthermore amidated and methoxylated pectins.
- the preferred level of pectin is from 0.3 to 4 wt% based on the water, more preferred 0.5 to 3 wt%. and further preferred between 0.6 and 3 wt%.
- the preferred level of agar and carrageenan is 1.0 to 5 wt% based on the water, more preferred 1.5 to 4 wt%, and most preferred 1.7 to 4 wt%.
- the water level in the product will generally be more than 50 wt%, for example 70 to 99 wt%, especially 75 to 95 wt%.
- Preferably spreads of the invention are water-continuous i.e. they contain a continuous water-phase. The presence of a continuous water-phase can for example be evidenced by conductivity measurements.
- compositions of the invention preferably comprise less than 40 wt% of fat, more preferred the level of fat is less than 30 wt%, most preferably below 20% or even below 5 wt%.
- the product is substantially free from fat.
- flavour or appearance enhancement it may be preferred to use low amounts of fat for example 0.5 to 6 wt%, more preferred from 1.2 to 4 wt%.
- oil and fat are used interchangeably. They are meant to include triglycerides of natural or synthetic origin such as soybean oil, sunflower oil, palm oil, fish oil, rapeseed oil, coconut oil, and hydrogenated, fractionated and/or interesterified triglyceride mixtures as well as edible substances that are physically similar to triglycerides such as waxes, e.g. jojoba oil and poly fatty acid esters of mono- or di-saccharides, and that can be used as replacement for or in admixture with triglycerides.
- triglycerides of natural or synthetic origin such as soybean oil, sunflower oil, palm oil, fish oil, rapeseed oil, coconut oil, and hydrogenated, fractionated and/or interesterified triglyceride mixtures as well as edible substances that are physically similar to triglycerides such as waxes, e.g. jojoba oil and poly fatty acid esters of mono- or di-saccharides, and that can be used as replacement
- the fat is present in the form of small fat globules, having an average volume weighted mean diameter of less than 20 ⁇ m, more preferred from 0.1 to 5 ⁇ m, most preferred from 0.5 to 2 ⁇ m.
- the presence of these small fat globules in low fat spreads of the invention has the distinct advantage of providing an improved appearance to the product.
- At least part of the fat is dairy fat.
- dairy fat Preferably at least 10 wt% based on the total weight of the fat is dairy fat, more preferred more than 50 wt%, most preferred more than 90 wt% or even 100 wt%.
- the dairy fat can be derived from any dairy source such as whole milk, semi-skimmed milk, skimmed milk, (cultured) buttermilk, butter milk powder, skimmed milk powder, (Greek) yoghurt, quark, (low fat) fromage frais, (low fat) cottage cheese, butter, cream cheese (Philadelphia) , (double) cream, Ricotta cheese etc.
- all of the fat is non-hardened, highly unsaturated oil such as, e.g. sunflower oil, low erucic acid rapeseed oil, soya or the like.
- Preferably spreads of the invention are plastic in the sense that they can be spread onto bread without tearing the bread.
- plastic spreads will have a stress strain relation with a maximum stress occurri at strain of 0.001-0.3, the maximum stress at this strain being 0.01-100 kPa and with a ratio of plastic stress and the maximum stress of 0.1 to 1 kPa.
- a suitable method for determining these values is given in EP 298 561 which is incorporated by reference.
- ingredients may comprise a number of optional traditional ingredients such as proteins, flavouring, salt, preservatives, acidifiers, vitamins, colouring materials etc.
- the total level of these ingredients is preferably from 0 to 10 wt%, for example 0.1 to 5 wt%.
- the level of flavouring materials is less than 5 wt%, for example 0.01 to 2 wt% or 0.01 to 0.5 wt%. In a preferred embodiment of the invention, however, spreads are free from flavouring ingredients other than those incorporated through the dairy ingredients.
- the level of salt sodium chloride
- the level of salt is from 0- 4 wt%, more preferred 0.1 to 3 wt%, most preferred 0.5 to 1.2 wt%.
- Preservatives are preferably incorporated at a level of 0 - 4 wt%, more preferred 0.01 to 1 wt%, most preferred 0.05 to 0.3 wt%. Especially preferred is the use of potassium sorbate.
- a preferred colouring material is carotene; preferred levels of colouring material are from 0 - 1 wt%, more preferred 0.01 to 0.2 wt%.
- Acidifiers may be incorporated to bring the pH of the product to the desired level, preferably the pH of the product is from 3 to 10, more preferred 3.5 to 7.
- a suitable acidifier is for example lactic acid or citric acid.
- the spread may further containing small particles such as herbs and vegetables.
- the total level thereof will generally be less than 10 wt%.
- Spreads of the invention can suitably be used as bread spreads to replace e.g. margarine or halvarine, but they can also suitable be used as flavoured spread, for example cheese spreads, meat spreads, nut spreads, sweet spreads or vegetable spreads.
- spreads are prepared by cooling under shear.
- the premix temperature is more than 60°C, more preferred 65 to 95°C.
- the cooling is carried out under shear. Any suitable method for applying shear can be used, for example the spread can be cooled in a homogeniser or a votator unit.
- the shear during cooling is sometimes above the critical shear rate (see the experiment below) , sometimes the shear rate is 10% above the critical shear rate.
- Cooling is to a temperature of below 30°C. Generally the filling temperature will be from 0 to 30°C, e.g. from 5 to 25°C.
- the viscosity of the spread at the moment of filling is more than 1.6 Pa.s when measured at 5°C and 20 s "1 , more preferably 1.8 to 10 Pa.s, most preferred 1.8 to 8 Pa.s after shearing for one minute.
- the viscosity can e.g. be determined with a Haake RV20 viscometer with a coaxial cylinder geometry.
- the critical shear rate can be determined as follows: For a certain production line, wherein the shear is applied e.g. in a homogeniser or votator all conditions such as throughput, cooling rate etc except for the shear rate are set at the values as to be used in the actual production process of the spread.
- a reference formulation is prepared of 1.3 wt% carrageenan 15 (70 : 30 kappa : iota), 0.41 % sodium chloride and 0.15 % potassium sorbate in deionised water at 80 C. The mixture is passed through the production line as described above while the shear rate is varied.
- the shear modulus G' of the composition is measured as described in EP 355 908.
- the shear modulus is compared with the shear modulus of the same composition when prepared under quiescent conditions.
- the critical shear rate is the rate at which the shear modulus for the material that was processed is at least 5 times as low as the shear modulus of the material gel led under quiescent conditions.
- the method of preparation was as follows: the water was pre-heated to 91°C, 97-2 was added and mixed with a Silverson for 10 minutes. The cream was added under continuous mixing and at 60°C the remaining ingredients except for the flavour were added. Mixing was continued for 5 minutes after which the flavours were added. The pH was adjusted to 5.0 using 40% lactic acid. The tub surfaces above the fill level were not coated.
- the resulting composition had a fill viscosity of 2.0 Pa.s at 5°C and 20 s "1 .
- the spread could be filled into a tub without sloshing.
- the resulting spread had a good appearance and taste.
- the upper surface of the spread was generally non-horizontal and the outer edge (5 mm area from the rim) was a few millimetres lower than the rest of the upper surface. The amount of sloshing observed was low.
- the tub surfaces above the fill level were not coated.
- the fill viscosity was about 1.7 Pa.s at 5 °C and 20 s "1
- the taste and appearance were similar to example I. No skinned surface was observed on the surfaces of the tub.
- Example I was repeated with the following formulations:
- the fill viscosities as measured at 5 C and 20 s "1 were 1.7, 2.2, 5.2 and 6.8 Pa.s respectively.
- the taste and appearance was similar to the spreads of example I.
- the amount of sloshing observed was minimal. No surface coverage above the fill level was observed.
- the R-value used was 1 and the viscosity was determined one minute after filling the tubs was 5 000 mPa.s at 5°C and 20 at 20 "1 . Sloshing in an automatic filling machine was reduced and the product had an excellent appearance.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Molecular Biology (AREA)
- Zoology (AREA)
- Jellies, Jams, And Syrups (AREA)
- Confectionery (AREA)
- Edible Oils And Fats (AREA)
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95924270A EP0753996A1 (en) | 1994-06-22 | 1995-06-19 | Low fat spread |
AU28850/95A AU703513B2 (en) | 1994-06-22 | 1995-06-19 | Low fat spread |
CA002193372A CA2193372A1 (en) | 1994-06-22 | 1995-06-19 | Low fat spread |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94304538 | 1994-06-22 | ||
EP94304538.5 | 1994-06-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1995035036A2 true WO1995035036A2 (en) | 1995-12-28 |
WO1995035036A3 WO1995035036A3 (en) | 1996-02-01 |
Family
ID=8217746
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1995/002354 WO1995035036A2 (en) | 1994-06-22 | 1995-06-19 | Low fat spread |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0753996A1 (en) |
AU (1) | AU703513B2 (en) |
CA (1) | CA2193372A1 (en) |
WO (1) | WO1995035036A2 (en) |
ZA (1) | ZA955181B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001005248A1 (en) * | 1999-07-20 | 2001-01-25 | Schreiber Foods, Inc. | Multi-stage thickening composition for use with packaged food items and process for using same |
WO2003053151A1 (en) * | 2001-12-21 | 2003-07-03 | Unilever N.V. | Oil in water emulsions comprising a blend of biopolymers |
WO2013049449A1 (en) * | 2011-09-28 | 2013-04-04 | Persico, Inc. | Stabilized edible emulsions, acidifi-cation methods of preparation, and beverages |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0298561A2 (en) * | 1987-07-08 | 1989-01-11 | Unilever N.V. | Edible plastic dispersion |
DE3907676A1 (en) * | 1989-03-09 | 1990-11-22 | Kraft Europ R & D Inc | METHOD FOR PRODUCING A MARGARINE WITH A REDUCED FAT CONTENT |
EP0509707A1 (en) * | 1991-04-08 | 1992-10-21 | Petrella Limited | 0-40% fat spread |
EP0574973A1 (en) * | 1992-06-16 | 1993-12-22 | Unilever N.V. | Low fat food products |
-
1995
- 1995-06-19 WO PCT/EP1995/002354 patent/WO1995035036A2/en not_active Application Discontinuation
- 1995-06-19 CA CA002193372A patent/CA2193372A1/en not_active Abandoned
- 1995-06-19 AU AU28850/95A patent/AU703513B2/en not_active Ceased
- 1995-06-19 EP EP95924270A patent/EP0753996A1/en not_active Withdrawn
- 1995-06-22 ZA ZA955181A patent/ZA955181B/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0298561A2 (en) * | 1987-07-08 | 1989-01-11 | Unilever N.V. | Edible plastic dispersion |
DE3907676A1 (en) * | 1989-03-09 | 1990-11-22 | Kraft Europ R & D Inc | METHOD FOR PRODUCING A MARGARINE WITH A REDUCED FAT CONTENT |
EP0509707A1 (en) * | 1991-04-08 | 1992-10-21 | Petrella Limited | 0-40% fat spread |
EP0574973A1 (en) * | 1992-06-16 | 1993-12-22 | Unilever N.V. | Low fat food products |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001005248A1 (en) * | 1999-07-20 | 2001-01-25 | Schreiber Foods, Inc. | Multi-stage thickening composition for use with packaged food items and process for using same |
US7037545B2 (en) * | 1999-07-20 | 2006-05-02 | Schreiber Technologies, Inc. | Multi-stage thickening composition for use with packaged food items and process for using same |
WO2003053151A1 (en) * | 2001-12-21 | 2003-07-03 | Unilever N.V. | Oil in water emulsions comprising a blend of biopolymers |
WO2013049449A1 (en) * | 2011-09-28 | 2013-04-04 | Persico, Inc. | Stabilized edible emulsions, acidifi-cation methods of preparation, and beverages |
WO2013049447A1 (en) * | 2011-09-28 | 2013-04-04 | Pepsico, Inc. | Stabilized edible emulsions, methods of preparation, and beverages |
Also Published As
Publication number | Publication date |
---|---|
AU2885095A (en) | 1996-01-15 |
CA2193372A1 (en) | 1995-12-28 |
WO1995035036A3 (en) | 1996-02-01 |
AU703513B2 (en) | 1999-03-25 |
ZA955181B (en) | 1996-12-23 |
EP0753996A1 (en) | 1997-01-22 |
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