WO1995021709A1 - Method and device for cleaning polluted soil - Google Patents

Method and device for cleaning polluted soil Download PDF

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Publication number
WO1995021709A1
WO1995021709A1 PCT/NL1995/000057 NL9500057W WO9521709A1 WO 1995021709 A1 WO1995021709 A1 WO 1995021709A1 NL 9500057 W NL9500057 W NL 9500057W WO 9521709 A1 WO9521709 A1 WO 9521709A1
Authority
WO
WIPO (PCT)
Prior art keywords
soil
organic solvent
heated medium
solvent
polluted
Prior art date
Application number
PCT/NL1995/000057
Other languages
French (fr)
Inventor
Henricus Jozef Hubertus Brouwers
Original Assignee
Universiteit Twente
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universiteit Twente filed Critical Universiteit Twente
Priority to AU15918/95A priority Critical patent/AU1591895A/en
Publication of WO1995021709A1 publication Critical patent/WO1995021709A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09C—RECLAMATION OF CONTAMINATED SOIL
    • B09C1/00—Reclamation of contaminated soil
    • B09C1/02—Extraction using liquids, e.g. washing, leaching, flotation

Definitions

  • the present invention relates to a method for cleaning polluted soil and the like, more particularly for removing not easily removable substances from the soil, such as hexachlorocyclohexane and polycyclic aromatic hydrocarbons, referred to hereafter as HCH and PAHs respectively.
  • HCH and PAHs hexachlorocyclohexane and polycyclic aromatic hydrocarbons
  • the term 'soil' should be understood in the broad sense. It covers, among other things, also sand-like residues such as construction waste, which often contain PAHs in particular.
  • the present invention provides a method for cleaning polluted soil, resulting in very thorough cleaning in an effective and relatively cheap way.
  • the method includes at least two steps, i.e. a first step in which the soil is treated with an organic solvent and a subsequent step in which the same soil is treated with a heated medium.
  • Treatment of the soil in this way enables the choice of a solvent for the treatment of the soil that effectively removes particular pollutants from the ground.
  • the solvent itself constitutes a pollution of the soil that can only be removed from the soil through heating.
  • the organic solvent used is an apolar organic solvent, such as hexane, pentane, or mixtures of alkanes (for example cleaning spirit) of which it is known that they are very effective for removing particular apolar pollutants such as mineral oil, HCH and PAHs from the soil.
  • the organic solvent can be introduced -into the soil in the form of a fluid. However, it is also possible and under certain circumstances preferable to introduce the solvent into the soil in the form of vapour (heated) .
  • the heated medium can be water in the form of hot water and/or steam, and it is also possible to use hot air as the medium.
  • the method according to the present invention is suitable for the removal of mineral oil, HCH and/or PAHs from polluted soil.
  • the method permits application at the polluted site, i.e. without the soil being dug off.
  • a plurality of pipes is inserted into the soil which introduce both the organic solvent and the heated medium into the soil successively. This introduction can occur below or slightly above the groundwater table, and is itself a known technique and disclosed in GB-A-2 098 644 for example.
  • the present invention relates to the device for applying the method for cleaning polluted soil, which device can be provided with a tubing system to be disposed in the non-dug off soil or with means for introducing an organic solvent and subsequently a heated medium into the dug-off soil.
  • HCH was produced particularly in the 1948-1952 period, during which period much production waste was dumped, usually in the environs of the production site.
  • HCH is associated with various problems. Firstly, it is a toxic substance which is a public health threat. Further, this substance causes stench. Yet another problem is that HCH is difficult to remove from the soil, which is caused by its poor solubility in water and in many other solvents and the relatively high boiling points of the various HCHs. Soil polluted with HCH will ultimately not only contain HCH but also, for example, chlorobenzene and other products created by the slow disintegration of HCH in the soil. This occurs particularly in calcareous soil .
  • hexane After the hexane treatment a certain amount of hexane remains in the soil, which in itself constitutes a new pollution of the soil.
  • hexane has a low boiling point, far below 100 °C, it appears that the hexane is completely removable from the soil by treating the soil with water in the form of steam. Because of the difference between the boiling point of water and the boiling point of hexane the steam and hexane mixture can be easily separated, so that the hexane is reusable. Because of the poor miscibility of hexane and water and because of the difference in densities, the two substances can be easily separated in the fluid phase also.
  • the intensity of cleaning can be increased by carrying out the treatments of the soil under pressure, for example a pressure of 1.5 to 3 bar.
  • the method disclosed herein first replaces the existing pollution in the polluted soil by another pollutant, after which the other pollutant is removed from the soil during subsequent treatment.

Abstract

Method for cleaning polluted soil and such, comprising at least the steps of treating the soil with an organic solvent and subsequently treating the same soil with a heated medium. The solvent may be an apolar organic solvent, for example hexane or pentane or a mixture of alkanes, and may be introduced into the soil in the form of liquid or vapour (heated). The heated medium may be water in the form of hot water and/or steam, or hot air.

Description

METHOD AND DEVICE FOR CLEANING POLLUTED SOIL
The present invention relates to a method for cleaning polluted soil and the like, more particularly for removing not easily removable substances from the soil, such as hexachlorocyclohexane and polycyclic aromatic hydrocarbons, referred to hereafter as HCH and PAHs respectively. A problem arising with this kind of pollution is that it has a high boiling point and dissolves poorly in water.
Within the scope of the present invention, the term 'soil' should be understood in the broad sense. It covers, among other things, also sand-like residues such as construction waste, which often contain PAHs in particular.
The present invention provides a method for cleaning polluted soil, resulting in very thorough cleaning in an effective and relatively cheap way. According to the present invention the method includes at least two steps, i.e. a first step in which the soil is treated with an organic solvent and a subsequent step in which the same soil is treated with a heated medium. Treatment of the soil in this way enables the choice of a solvent for the treatment of the soil that effectively removes particular pollutants from the ground. However, the solvent itself constitutes a pollution of the soil that can only be removed from the soil through heating.
Preferably, the organic solvent used is an apolar organic solvent, such as hexane, pentane, or mixtures of alkanes (for example cleaning spirit) of which it is known that they are very effective for removing particular apolar pollutants such as mineral oil, HCH and PAHs from the soil. The organic solvent can be introduced -into the soil in the form of a fluid. However, it is also possible and under certain circumstances preferable to introduce the solvent into the soil in the form of vapour (heated) .
According to the present invention, the heated medium can be water in the form of hot water and/or steam, and it is also possible to use hot air as the medium.
More particularly, the method according to the present invention is suitable for the removal of mineral oil, HCH and/or PAHs from polluted soil. In further accordance with the present invention, the method permits application at the polluted site, i.e. without the soil being dug off. In that case, a plurality of pipes is inserted into the soil which introduce both the organic solvent and the heated medium into the soil successively. This introduction can occur below or slightly above the groundwater table, and is itself a known technique and disclosed in GB-A-2 098 644 for example.
It is also possible to dig off the polluted soil and deposit it in special containers, which containers are suitable for treating the soil according to the present invention. The treatment according to the present invention can also occur in a purpose-built processing device to which the soil must be transported.
Further, the present invention relates to the device for applying the method for cleaning polluted soil, which device can be provided with a tubing system to be disposed in the non-dug off soil or with means for introducing an organic solvent and subsequently a heated medium into the dug-off soil.
The invention will now be explained in more detail, more particularly in relation to the cleaning of soil polluted with HCH .
HCH was produced particularly in the 1948-1952 period, during which period much production waste was dumped, usually in the environs of the production site.
The substance HCH is associated with various problems. Firstly, it is a toxic substance which is a public health threat. Further, this substance causes stench. Yet another problem is that HCH is difficult to remove from the soil, which is caused by its poor solubility in water and in many other solvents and the relatively high boiling points of the various HCHs. Soil polluted with HCH will ultimately not only contain HCH but also, for example, chlorobenzene and other products created by the slow disintegration of HCH in the soil. This occurs particularly in calcareous soil .
.An effective way to remove HCH and, if necessary, other substances from polluted soil is treating the soil with an apolar organic solvent, such as hexane, which has a high dissolving power for HCH, is relatively non-toxic, is cheap, can be recycled and can be used in conventional steaming equipment, so that it can be passed through the soil at high temperatures in the form of steam. In practice, it appears that the HCH concentration in polluted soil can be reduced to a minimum by treating this soil with hexane.
After the hexane treatment a certain amount of hexane remains in the soil, which in itself constitutes a new pollution of the soil. However, because hexane has a low boiling point, far below 100 °C, it appears that the hexane is completely removable from the soil by treating the soil with water in the form of steam. Because of the difference between the boiling point of water and the boiling point of hexane the steam and hexane mixture can be easily separated, so that the hexane is reusable. Because of the poor miscibility of hexane and water and because of the difference in densities, the two substances can be easily separated in the fluid phase also.
In practice, it appears that an eight-hour treatment with hexane and a subsequent eight-hour treatment with water in the form of steam produces excellent results, and reduces the pollution of the soil to a minimum.
The intensity of cleaning can be increased by carrying out the treatments of the soil under pressure, for example a pressure of 1.5 to 3 bar.
Essentially, the method disclosed herein first replaces the existing pollution in the polluted soil by another pollutant, after which the other pollutant is removed from the soil during subsequent treatment.

Claims

1. Method for cleaning polluted soil and such, comprising at least the steps of :
(a) treating the soil with an organic solvent, and
(b) subsequently treating the same soil with a heated medium.
2. The method according to claim 1, characterized in that the solvent is an apolar organic solvent, for example hexane or pentane or a mixture of alkanes .
3. The method according to claim 1 or 2, characterized in that the solvent is introduced into the soil in the form of a fluid.
4. The method according to any of the preceding claims, characterized in that the solvent is introduced into the soil in the form of vapour (heated) .
5. The method according to any of the preceding claims, characterized in that the heated medium is water in the form of hot water and/or steam.
6. The method according to any of the preceding claims, characterized in that the heated medium is hot air.
7. The method according to any of the preceding claims, characterized in that the method is applied for removing hexachlorocyclohexane (HCH) and/or polycyclic aromatic hydrocarbons (PAHs) and/or mineral oil from polluted soil.
The method according to any of the preceding claims, characterized in that the organic solvent and the heated medium are introduced into the soil at the polluted site.
9. The method according to claim 8, characterized in that the introduction occurs below the groundwater table.
10. The method according to claim 8, characterized in that the introduction occurs slightly above the groundwater table.
11. The method according to any of the preceding claims, characterized in that the cleaning occurs in containers at the site where the soil has been dug off.
12. A device for cleaning polluted soil and such, the device comprising means for introducing an organic solvent into the soil and means for subsequently introducing a heated medium into the same soil.
13. The device according to claim 12 for applying the method according to any of the conclusions 1 - 11.
14. The device according to claim 12 or 13, characterized by a container in which the soil or such can be deposited for treatment .
PCT/NL1995/000057 1994-02-14 1995-02-10 Method and device for cleaning polluted soil WO1995021709A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU15918/95A AU1591895A (en) 1994-02-14 1995-02-10 Method and device for cleaning polluted soil

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL9400226 1994-02-14
NL9400226A NL9400226A (en) 1994-02-14 1994-02-14 Method and device for cleaning contaminated soil.

Publications (1)

Publication Number Publication Date
WO1995021709A1 true WO1995021709A1 (en) 1995-08-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL1995/000057 WO1995021709A1 (en) 1994-02-14 1995-02-10 Method and device for cleaning polluted soil

Country Status (3)

Country Link
AU (1) AU1591895A (en)
NL (1) NL9400226A (en)
WO (1) WO1995021709A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997045212A1 (en) * 1996-05-24 1997-12-04 Firma Dr. Ralf Schenke Floor-sanitation process and device
CN102451830A (en) * 2010-10-18 2012-05-16 中国科学技术大学苏州研究院 Method for restoring polycyclic aromatic hydrocarbons (PAHs) contaminated soil by utilizing artificial wetland
CN108655168A (en) * 2018-04-13 2018-10-16 江苏大学 g-C3N4/Fe3O4Purposes of the composite material in repairing polycyclic aromatic hydrocarbon pollution

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0059020A1 (en) * 1981-02-23 1982-09-01 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO Method for removing undesired components from the soil
GB2098644A (en) * 1981-05-18 1982-11-24 Shell Int Research Method of cleaning polluted subsoil and apparatus for carrying out the method
EP0070593A1 (en) * 1981-07-10 1983-01-26 Dirk Jan Blonk Process for the purification of soil by the introduction of a heating medium as well as vacuum bell and apparatus therefor
US4606774A (en) * 1984-07-30 1986-08-19 The Dow Chemical Company Process for removing contaminants from soils
DE3610199A1 (en) * 1986-03-26 1987-10-01 Wessling Erwin Chem Lab Process for cleaning soils contaminated with pollutants
EP0323649A2 (en) * 1988-01-05 1989-07-12 As Phonix Contractors A method for decontaminating a material and an assembly for carrying out said method
EP0327896A2 (en) * 1988-02-06 1989-08-16 LEONHARD WEISS GmbH & Co. Method for cleaning soil or the like, contaminated by extractable organic pollutants

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0059020A1 (en) * 1981-02-23 1982-09-01 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO Method for removing undesired components from the soil
GB2098644A (en) * 1981-05-18 1982-11-24 Shell Int Research Method of cleaning polluted subsoil and apparatus for carrying out the method
EP0070593A1 (en) * 1981-07-10 1983-01-26 Dirk Jan Blonk Process for the purification of soil by the introduction of a heating medium as well as vacuum bell and apparatus therefor
US4606774A (en) * 1984-07-30 1986-08-19 The Dow Chemical Company Process for removing contaminants from soils
DE3610199A1 (en) * 1986-03-26 1987-10-01 Wessling Erwin Chem Lab Process for cleaning soils contaminated with pollutants
EP0323649A2 (en) * 1988-01-05 1989-07-12 As Phonix Contractors A method for decontaminating a material and an assembly for carrying out said method
EP0327896A2 (en) * 1988-02-06 1989-08-16 LEONHARD WEISS GmbH & Co. Method for cleaning soil or the like, contaminated by extractable organic pollutants

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997045212A1 (en) * 1996-05-24 1997-12-04 Firma Dr. Ralf Schenke Floor-sanitation process and device
CN102451830A (en) * 2010-10-18 2012-05-16 中国科学技术大学苏州研究院 Method for restoring polycyclic aromatic hydrocarbons (PAHs) contaminated soil by utilizing artificial wetland
CN102451830B (en) * 2010-10-18 2013-01-16 中国科学技术大学苏州研究院 Method for restoring polycyclic aromatic hydrocarbons (PAHs) contaminated soil by utilizing artificial wetland
CN108655168A (en) * 2018-04-13 2018-10-16 江苏大学 g-C3N4/Fe3O4Purposes of the composite material in repairing polycyclic aromatic hydrocarbon pollution

Also Published As

Publication number Publication date
AU1591895A (en) 1995-08-29
NL9400226A (en) 1995-09-01

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