WO1995015368A1 - Lubrication oil composition - Google Patents

Lubrication oil composition Download PDF

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Publication number
WO1995015368A1
WO1995015368A1 PCT/US1994/013767 US9413767W WO9515368A1 WO 1995015368 A1 WO1995015368 A1 WO 1995015368A1 US 9413767 W US9413767 W US 9413767W WO 9515368 A1 WO9515368 A1 WO 9515368A1
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WO
WIPO (PCT)
Prior art keywords
group
carbon atoms
weight
lubricating oil
oil composition
Prior art date
Application number
PCT/US1994/013767
Other languages
French (fr)
Inventor
Hirotaka Tomizawa
Michihide Tokashiki
Original Assignee
Exxon Research & Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research & Engineering Company filed Critical Exxon Research & Engineering Company
Priority to EP95904189A priority Critical patent/EP0731829A4/en
Publication of WO1995015368A1 publication Critical patent/WO1995015368A1/en

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/16—Amides; Imides
    • C—CHEMISTRY; METALLURGY
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    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/38—Heterocyclic nitrogen compounds
    • C10M133/44—Five-membered ring containing nitrogen and carbon only
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    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/56—Amides; Imides
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    • C10M135/08—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium containing a sulfur-to-oxygen bond
    • C10M135/10—Sulfonic acids or derivatives thereof
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    • C10M135/12—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M135/14—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond
    • C10M135/18—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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    • C10M159/12—Reaction products
    • C10M159/18—Complexes with metals
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    • C10M159/24—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
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    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026—Butene
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    • C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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Definitions

  • the present invention concerns a novel lubricating oil composition and, more particularly, it relates to a lubricating oil composition which is suitable, for example, as engine oils (lubricat ⁇ ing oil for internal combustion engines), gear oils, automatic trans ⁇ mission fluids (ATF), power steering oils (PS oil), spindle oils, hydraulic fluids and industrial lubricating oils, excellent in wear resistance, exhibiting a low friction coefficient, capable of improv ⁇ ing fuel economy and with improved copper corrosion property, as well as a lubricating oil composition having the above-mentioned character ⁇ istics and capable of exhibiting a low friction coefficient already from an initial stage of operation (conditioning driving).
  • a lubricating oil composition excellent, particularly, in the reduction of mechanical friction loss for 4-cycle engines, there has been proposed a lubricating oil composition com ⁇ prising a mineral oil and/or synthetic oil having a kinematic viscosity at 100°C of 3 to 20 cSt and blended therewith, (a) 0.2 to 5% by weight of sulfurized oxymolybdenum organophosphorodithioate (here ⁇ inafter referred to simply as MoDTP) and/or sulfurized oxymolybdenum dithiocarbamate (hereinafter referred simply as MoDTC), (b) 0.1 to 7% by weight of zinc dithiophosphate, (c) 0.1 to 20% by weight of calcium alkylbenzene sulfonate and (d) 1 to 15% by weight of alkenyl succinimide and/or boron compound derivative of alkenyl succinimide (Japanese Patent Publication No. 23595/1991). According to this lubricating oil
  • One of the important features of the lubricating oil is that it does not attack a metal within the engine during use. It is considered that corrosion may be caused by free sulfur, sulfur com ⁇ pounds or acidic substances. Since a copper plate is most sensitive to these substances, the corrosion of a copper plate when exposed to lubricating oil is evaluated as a measure of the corrosiveness of the lubricating oil. It is a common practice to add nitrogeneous metal deactivators, such as benzotriazole, to the lubricating oil for the purpose of reducing the copper corrosiveness. However, the addition of these metal deactivators in a large amount results in hardening of sealing rubbers. Further, if MoDTP or MoDTC is added in a relatively great amount as 0.2 to 5% by weight as disclosed in the above-cited patent publication for reducing the friction, it results in a problem of causing a strong corrosive effective to copper.
  • nitrogeneous metal deactivators such as benzotriazole
  • a lubricating oil composition having an organo- molybdenum compound such as MoDTP or MoDTC added thereto involves a problem that a friction coefficient at an initial stage (during conditioning driving) is high.
  • Lubricating oil additives have an effect of reducing the boundary friction by adsorption to metal surface to form boundary lubricating film but the organomolybdenum compounds described above require a relatively long period of time until they are adsorbed on the metal surface to develop the friction reducing effect.
  • the present invention has been made under such circumstances with a view to provide a lubricating oil composition excellent in wear resistance, exhibiting low friction coefficient, capable of improving fuel economy, and with improved copper corrosiveness, as well as a lubricating oil composition having the foregoing characteristics and, in addition, capable of developing a low coefficient of friction from the initial stage of operation.
  • the present inventors have made earnest studies for develop ⁇ ing a lubricating oil composition having desired properties as described above, as a result, have noted that oxymolybdenum mono- glyceride or oxymolybdenum diethylate amide, not containing sulfur atoms in the molecule, does not increase the copper corrosiveness as in the case of MoDTP or MoDTC and have found that a lubricating oil composition of excellent wear resistance, exhibiting low coefficient of friction and with reduced copper corrosiveness can be obtained by combining the above-mentioned compound with a metal dithiocarbamate having a secondary alkyl group and blending them each at a predeter ⁇ mined ratio to a lubricating oil basestock and, further, a lubricating oil composition having the foregoing characteristics and, in addition, capable of reducing the friction coefficient at the initial stage of driving can be obtained by further blending an organic amide compound at a predetermined ratio.
  • the present invention has been accomplished based
  • the present invention provides a lubricating oil composition
  • a lubricating oil composition comprising a lubricating oil basestock and, based on the oil composition
  • R 1 , R 2 , R 3 and R 4 represent independently an oleophilic group of 1 to 30 carbon atoms in which at least one of the four oleophilic groups is a secondary oleophilic group.
  • Another embodiment relates to a lubricating oil composition comprising a lubricating oil basestock and, based on the oil composition, 0.01 to 10% by weight of the ingredient (A) described above, 0.5 to 7% by weight of the ingredient (B) described above, and (C) 0.01 to 5% by weight of an organic amide compound.
  • basestocks used in the lubricating oil composition according to the present invention there is no particular restriction for the basestocks used in the lubricating oil composition according to the present invention and those proposed so far as the basestock for the lubricating oil, for example, mineral oils or synthetic oils can be used.
  • mineral oil there can be mentioned, for example, 50 neutral oil, 100 neutral oil, 150 neutral oil, 300 neutral oil, 500 neutral oil and bright stock obtained by solvent refining or hydro- genation, which may be used alone or as a mixture of two or more of them at an appropriate ratio.
  • synthetic oil there can be mentioned, for example, poly ⁇ -olefin oligomer, polybutene, alkylbenzene, alkyldiphenyl, polyol ester, polyglycol ester, dibasic acid ester, phosphoric acid ester and silicone oil, which may be used alone or as a mixture of two or more of them at an appropriate ratio.
  • mineral oil and the synthetic oil described above may be used in admixture.
  • the base oil used in the lubricating oil composition according to the present invention those having a kinematic viscosity at a temperature of 100°C within a range from 3 to 20 mm 2 /s, prefer ⁇ ably 4 to 15 mm 2 /s are preferred.
  • oxymolybdenum monoglyceride or oxymolybdenum diethylate amide (hereinafter referred to "MoOxide type compound") is used as the ingredient (A) in the composition according to the present invention.
  • MoOxide type compound oxymolybdenum monoglyceride or oxymolybdenum diethylate amide
  • R is hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or a hydrocarbon group containing ester bond, ether bond, alcohol group or carboxyl group.
  • Preferred R is alkyl group of 6 to 18 carbon atoms, alkenyl group of 6 to 18 carbon atoms, cycloalkyl group or 12 to 24 carbon atoms or alkylaryl group of 12 to 24 carbon atoms.
  • alkyl or alkenyl groups of 6 to 18 carbon atoms such as n-hexyl group, 2- ethylhexyl group, n-octyl group, nonyl group, decyl group, lauryl group, tridecyl group, oleyl group and linoleyl group, and alkylaryl group having an alkyl group of 3 to 18 carbon atoms such as nonyl- phenyl group.
  • the MoOxide type compound for the ingredient (A) may be used alone or two or more of them may be combined for use. Further, it is necessary that the blending amount is selected within a range from 0.01 to 10% by weight, preferably, 0.05 to 8% by weight based on the entire weight of the oil composition. No sufficient friction reducing effect can be obtained if the blending amount is less than 0.01% by weight whereas no corresponding improvement for the friction reducing effect can be observed if it exceeds 10% by weight.
  • a metal dithiocarbamate (herein ⁇ after referred to ⁇ "M-DTC * ") represented by the general formula (1) is used.
  • M is zinc, copper, nickel, iron, cadmium, silver, lead, antimony, tin or bismuth.
  • R 1 , R 2 , R 3 and R 4 is an oleophilic group of 1 to 30 carbon atoms in which at least one of them is a secondary oleophilic group, preferably, at least two of them are secondary oleophilic groups and the residue includes primary oleophilic groups. Further preferred oleophilic group are those in which at least three of them are secondary alkyl groups.
  • Rl, R 2 , R 3 and R 4 may be identical or different with each other.
  • oleophilic group of 1 to 30 carbon atoms there can be mentioned for example, alkyl group of 1 to 30 carbon atoms, alkenyl group of 2 to 30 carbon atoms, cycloalkyl group of 6 to 30 carbon atoms, aryl group of 6 to 30 carbon atoms, alkylaryl group of 7 to 30 carbon atoms, arylalkyl group of 7 to 30 carbon atoms or hydrocarbon group having ester bond, ether bond, alcohol group or carboxyl group.
  • M-DTC represented by the general formula (1) in the oil composition according to the present invention having four oleophilic groups with the average number of carbon atoms between 1 and 5 are desirably reacted with an oil soluble amine compound for complexing treatment in order to increase the solubility to the lubricating oil basestock and improve the wear resistance.
  • M-DTC having four oleophilic groups with an average number of carbon atoms of 1 cannot provide a homo ⁇ geneous lubricating oil composition even if it is reacted with the oil soluble amine compound since the solubility of the resultant complex to the lubricating oil basestock is poor.
  • the lower limit for the average number of carbon atoms of the oleophilic group is preferably two or more in view of both functions of the solubility and the wear resistance. If the average number of carbon atoms of the four oleophilic groups is 5 or more, solubility to the lubricating oil basestock is satisfactory with no complexing treatment but it may be used after complexing if neces ⁇ sary.
  • all the four oleophilic groups are identical hydrocarbon groups, more suitably, the four oleophilic groups are alkyl groups of 3 to 6 carbon atoms in view of easy produc ⁇ tion and wear resistance.
  • More preferred oleophilic group is alkyl group of 3 to 4 carbon atoms.
  • metal atom (M) zinc is preferred in view of easy availability and wear resistance.
  • M-DTC can be produced by a known method.
  • zinc diisopropyl dithiocarbamate can be produced by reacting diisopropyl- amine, carbon disulfide and sodium hydroxide to prepare sodium diisopropyl dithiocarbamate which is then reacted with zinc nitrate.
  • oil soluble amine compound used for complexing M-DTC there can be mentioned, for example, ashless detergent dispersant such as polyalkenyl succinimide or alkylbenzylamine or alkylamine, alkyldi- amine and alkylpolyamine.
  • a method of adding both of them to a lubricating oil basestock at a ratio of providing a high concentration and heating them For instance, when a lubricating oil composition containing 2 to 7% by weight of M-DTC and 2 to 25% by weight of oil soluble amine compound, at a ratio of 1 to 10 parts by weight of the oil soluble amine compound based on 1 part of weight of M-DTC is stirred at a temperature of 100 to 230°C, more preferably, 150 to 200°C, preferably for 1 to 60 minutes, more preferably, 1 to 30 minutes, both of the compounds form a complex which is uniformly dissolved in the lubricating oil basestock.
  • heating tempera ⁇ ture As the heating tempera ⁇ ture is higher, they form a complex in a shorter period of time and are dissolved more uniformly. A homogeneous lubricating oil composi ⁇ tion containing both of the compounds at a desired ratio can be obtained easily by diluting the resultant complex solution at high concentration with the lubricating oil basestock.
  • M-DTC as the ingredient (B) may be used alone or as a combination of two or more of them. It is necessary to blend M-DTC by 0.5 to 7% by weight, preferably, 1 to 5% by weight based on the oil composition. No sufficient wear resistant effect can be obtained if the blending amount is less than 0.5% by weight, whereas the solu ⁇ bility tends to be lowered if it exceeds 7% by weight.
  • secM-DTC has a function of an extreme pressure agent, as well as a function as an antioxidant, a corrosion inhibitor or the like.
  • the organic amide compound as the ingredient (C) can be used as required.
  • the organic amide compound is a compound repre ⁇ sented by the general formula (4):
  • R 5 and R 6 each represents hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl groups of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl group or arylalkyl group of 7 to 26 carbon atoms or alkylene oxide group of 2 to 30 carbon atoms which may be identical or different with each other.
  • R 7 represents hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or hydrocarbon group containing ester bond, ether bond, alcohol group or carboxyl group.
  • the alkylene oxide group mentioned herein is a group repre ⁇ sented by general formula (5) or (6).
  • R' wherein R' represents hydrogen atom or methyl group and n is an integer of 1 to 10.
  • Preferred R 5 and R 6 in the general formula (4) are hydrogen atom, alkyl group of 2 to 8 carbon atoms, cycloalkyl group of 8 to 14 carbon atoms, alkylaryl group of 8 to 14 carbon atoms, and alkylene oxide group in which n is 1 to 5.
  • Preferred R 7 can include alkyl group of 6 to 18 carbon atoms, alkenyl group of 6 to 18 carbon atoms, cycloalkyl group of 12 to 24 carbon atoms and alkylaryl group of 12 to 24 carbon atoms.
  • the organic amide compound there can be mentioned, for example, oleamide or lauramide, which may be used alone or as a combination of two or more of them.
  • the organic amide compound as the ingredient (C) is blended by 0.01 to 5% by weight, preferably, 0.05 to 2% by weight based on the oil composition. Blending of the organic amide compound can reduce the friction coefficient already from the initial stage of driving while suppressing the copper corrosiveness. No sufficient effect for reducing the friction coefficient from the initial stage of driving can be attained if the blending amount is less than 0.01% by weight, whereas no corresponding improvement for the effect can be recognized if the amount exceeds 5% by weight.
  • lubricating oil composition there can be properly added various kinds of additives used customarily in the lubricating oils, for example, other extreme pressure agents, ashless detergent dispersant, antioxidant, metallic detergent, metal deactivator, viscosity index improver, pour point depressor, rust inhibitor, antifoamer and corrosion inhibitor within such a range as not deteriorating the purpose of the present inven ⁇ tion.
  • additives used customarily in the lubricating oils, for example, other extreme pressure agents, ashless detergent dispersant, antioxidant, metallic detergent, metal deactivator, viscosity index improver, pour point depressor, rust inhibitor, antifoamer and corrosion inhibitor within such a range as not deteriorating the purpose of the present inven ⁇ tion.
  • organomolybdenum compounds such as MoDTC or MoDTP.
  • the ashless detergent dispersant there can be mentioned, for example, succinimide, succinamide, benzylamine or ester type, as well as boron-containing ashless detergent dispersant can be used. They are used usually at a ratio of 0.5 to 7% by weight.
  • antioxidant there can be mentioned, for example, amine-based antioxidant such as alkylated diphenylamine, phenyl- ⁇ -naphthylamine, alkylated- ⁇ -naphthylamine, and phenolic antioxidant such as 2,6-di-tertiary-butylphenol, and 4,4'-methylene- bis-(2,6-di-tertiary-butylphenyl) and it is usually used at a ratio of 0.05 to 2.0% by weight.
  • amine-based antioxidant such as alkylated diphenylamine, phenyl- ⁇ -naphthylamine, alkylated- ⁇ -naphthylamine
  • phenolic antioxidant such as 2,6-di-tertiary-butylphenol, and 4,4'-methylene- bis-(2,6-di-tertiary-butylphenyl) and it is usually used at a ratio of 0.05 to 2.0% by weight.
  • the metallic detergent there can be mentioned, for example, Ca-sulfonate, Mg-sulfonate, Ba-sulfonate, Ca-phenate, Mg- phenate, Ba-phenate, Ca-salicylate, Mg-salicylate and Ba-salicylate which is generally used at a ratio of 0.1 to 5.0% by weight.
  • the metal deactivator there can be mentioned, for example, benzotriazole, benzotriazole derivative, benzothiazole, benzothiazole derivative, triazole, triazole derivative, dithiocarbamate, dithiocarbamate derivative, indazole and indazole derivative, which may be used usually at a ratio of 0.005 to 0.3% by weight.
  • viscosity index improver there can be mentioned, for example, polymethacrylate, polyisobutylene, ethylene-propylene co- polymer and styrene-butadiene hydrogenated copolymer type improver, which may be used usually at a ratio of 0.5 to 35% by weight.
  • rust inhibitor there can be mentioned, for example, alkenyl succinic acid or its partial ester and as the antifoamer, there can be mentioned, for example, dimethyl polysiloxane and poly- acrylate, which may be added properly.
  • the lubricating oil composition according to the present invention can be prepared by blending each of the various kinds of additives described above at a predetermined amount with a basestock and uniformly mixing them.
  • the lubricating oil composition according to the present invention can be used suitably, for example, to auto ⁇ mobile engine oil, gear oils, ATF oils, PS oils, spindle oils, hydraulic fluids or industrial lubricating oils.
  • the performance of the lubricating oil composition was determined by the method shown below.
  • the coefficient of friction was measured by using a reciprocal vibration friction tester (SRV).
  • SRV tester a steel ball of 1/2 inch diameter (SUJ-2 specified in JIS G-4805) was used as the upper test piece, and a steel disc (SUJ-2 specified in JIS G-4805) was used as the lower test piece.
  • a sample oil was dropped on the lower test piece, a load was applied to the upper piece from the top, and the upper test piece was vibrated parallel to the lower test piece with the upper test piece being passed against the lower test piece.
  • the lateral load applied to the lower test piece was measured to calculate the coefficient of friction ( ⁇ ).
  • the coefficient of friction was measured twice, that is, 5 minutes and 20 minutes after the initiation of the vibration of the upper test piece. Testing conditions are as follows:
  • Corrosiveness was tested in accordance with JIS K2513 "Copper Strip Corrosion Test Method for Petroleum Products” at a test tempera ⁇ ture of 100°C for a test period of 8 hours by the test method, in which the state of discoloration of the copper strip was observed in accordance with "the Standard for Copper Corrosion” and the corrosive ⁇ ness was evaluated by subdivision symbols la-4c. The corrosiveness is lower as the numerical value of the subdivisional mark is smaller and the corrosiveness is increased in the alphabetical order.
  • Lubricating oil compositions were prepared by blending 4% by weight of Ca-sulfonate, 5% by weight of succinimide, 0.5% by weight of alkylated diphenylamine, 0.3% by weight of 2,6-di-t-butylphenol and 0.02% by weight of 5-methyl-benzotriazole to a mineral oil (150 neutral mineral oil having kinematic viscosity at 100°C of 5.1 mm 2 /s) based on the entire weight of the oil composition, and blending each of the ingredients shown in Table 1, and the performances were evaluated. The results of measurement of properties are shown in Table 1.
  • PiB polyisobutylene
  • MoOxide (wt%) 0.7 3.0 0.7 3.0 0.7 3.0 0.7 0.7 0.7 0.7 0.3
  • Alkyl group comprises mixture of isopropyl group and secondary hexyl group.
  • the present invention can provide a lubricating oil composi ⁇ tion excellent in wear resistance, exhibiting a low coefficient of friction, capable of improving fuel economy and having improved copper corrosiveness, as well as a lubricating oil composition having the above-mentioned characteristics and, in addition, capable of attaining a low coefficient of friction already from the initial stage of driving.

Abstract

A lubricating oil composition comprising a basestock oil and, based on the oil composition, (A) 0.01 to 10 % by weight of oxymolybdenum monoglyceride or oxymolybdenum diethylate amide and (B) 0.5 to 7 % by weight of a metal dithiocarbamate represented by general formula (I), where M represents metal such as zinc, R1 to R4 represent C¿1?-C30 oleophilic group at least one of which is a secondary oleophilic group. The composition may also contain (C) 0.01 to 5 % by weight of an organic amide compound. The lubricating oil composition is excellent in wear resistance, exhibiting a low coefficient of friction, capable of improving fuel economy and improved for copper corrosiveness, as well as capable of providing a low coefficient of friction already from the initial stage of operation.

Description

LUBRICATING OIL COMPOSITION
BACKGROUND OF THE INVENTION
Field of the Invention
The present invention concerns a novel lubricating oil composition and, more particularly, it relates to a lubricating oil composition which is suitable, for example, as engine oils (lubricat¬ ing oil for internal combustion engines), gear oils, automatic trans¬ mission fluids (ATF), power steering oils (PS oil), spindle oils, hydraulic fluids and industrial lubricating oils, excellent in wear resistance, exhibiting a low friction coefficient, capable of improv¬ ing fuel economy and with improved copper corrosion property, as well as a lubricating oil composition having the above-mentioned character¬ istics and capable of exhibiting a low friction coefficient already from an initial stage of operation (conditioning driving).
2. Description of the Related Art
An increase in the output of internal combustion engines such as automobile engines has caused individual parts of engines, for example valve train systems or cylinders, to be exposed to high temperatures. Moreover, the number of contacts per unit time of metal with each other has been increased, thus placing the internal combus¬ tion engine under severe operating conditions. Lubricating oils for internal combustion engines must function under severe conditions. With a reduction of size and increase in the performance which results in an increase in the number of revolutions and an increase in the output, engine oils are required to be versatile and possess high levels of performance.
As fundamental performances required for the engine oils, there can be mentioned reduction of friction, prevention of wear and seizure, reduction of thermal and oxidative degradation, detergency and dispersancy, inhibition of corrosion and cooling and sealing functions, and use of various kinds of additives has been studied for satisfying such functions.
For instance, as a lubricating oil composition excellent, particularly, in the reduction of mechanical friction loss for 4-cycle engines, there has been proposed a lubricating oil composition com¬ prising a mineral oil and/or synthetic oil having a kinematic viscosity at 100°C of 3 to 20 cSt and blended therewith, (a) 0.2 to 5% by weight of sulfurized oxymolybdenum organophosphorodithioate (here¬ inafter referred to simply as MoDTP) and/or sulfurized oxymolybdenum dithiocarbamate (hereinafter referred simply as MoDTC), (b) 0.1 to 7% by weight of zinc dithiophosphate, (c) 0.1 to 20% by weight of calcium alkylbenzene sulfonate and (d) 1 to 15% by weight of alkenyl succinimide and/or boron compound derivative of alkenyl succinimide (Japanese Patent Publication No. 23595/1991). According to this lubricating oil composition, the friction coefficient in the mixed/boundary region can be reduced to about 1/3 of that for the conventional engine oil.
One of the important features of the lubricating oil is that it does not attack a metal within the engine during use. It is considered that corrosion may be caused by free sulfur, sulfur com¬ pounds or acidic substances. Since a copper plate is most sensitive to these substances, the corrosion of a copper plate when exposed to lubricating oil is evaluated as a measure of the corrosiveness of the lubricating oil. It is a common practice to add nitrogeneous metal deactivators, such as benzotriazole, to the lubricating oil for the purpose of reducing the copper corrosiveness. However, the addition of these metal deactivators in a large amount results in hardening of sealing rubbers. Further, if MoDTP or MoDTC is added in a relatively great amount as 0.2 to 5% by weight as disclosed in the above-cited patent publication for reducing the friction, it results in a problem of causing a strong corrosive effective to copper.
Further, a lubricating oil composition having an organo- molybdenum compound such as MoDTP or MoDTC added thereto involves a problem that a friction coefficient at an initial stage (during conditioning driving) is high. Lubricating oil additives have an effect of reducing the boundary friction by adsorption to metal surface to form boundary lubricating film but the organomolybdenum compounds described above require a relatively long period of time until they are adsorbed on the metal surface to develop the friction reducing effect.
Accordingly, when a lubricating oil composition having the organomolybdenum compound added thereto is used as an engine oil, the effect of reducing the friction develops after running a distance of 2,000 to 3,000 km, although this depends on the running condition of automobiles. However, after the above-described running, the time for the development of the effect of the friction often overlaps with the time for the replacement of the engine oil. In such a case, an increase in the amount of addition of MoDTP or MoDTC does not lead to the development of the effect of reducing the friction at an earlier stage and rather increases the copper corrosiveness.
SUMMARY OF THE INVENTION
The present invention has been made under such circumstances with a view to provide a lubricating oil composition excellent in wear resistance, exhibiting low friction coefficient, capable of improving fuel economy, and with improved copper corrosiveness, as well as a lubricating oil composition having the foregoing characteristics and, in addition, capable of developing a low coefficient of friction from the initial stage of operation.
The present inventors have made earnest studies for develop¬ ing a lubricating oil composition having desired properties as described above, as a result, have noted that oxymolybdenum mono- glyceride or oxymolybdenum diethylate amide, not containing sulfur atoms in the molecule, does not increase the copper corrosiveness as in the case of MoDTP or MoDTC and have found that a lubricating oil composition of excellent wear resistance, exhibiting low coefficient of friction and with reduced copper corrosiveness can be obtained by combining the above-mentioned compound with a metal dithiocarbamate having a secondary alkyl group and blending them each at a predeter¬ mined ratio to a lubricating oil basestock and, further, a lubricating oil composition having the foregoing characteristics and, in addition, capable of reducing the friction coefficient at the initial stage of driving can be obtained by further blending an organic amide compound at a predetermined ratio. The present invention has been accomplished based on such findings.
That is, the present invention provides a lubricating oil composition comprising a lubricating oil basestock and, based on the oil composition,
(A) 0.01 to 10% by weight of at least one of organomolybdenum com¬ pounds selected from oxymolybdenum monoglyceride and oxy¬ molybdenum diethylate amide, and
(B) 0.5 to 7% by weight of a metal dithiocarbamate represented by the general formula (1) :
R1 S S R3
\ II II /
N - C - M - S - C - N (1)
/ \
R2
where M represents zinc, copper, nickel, iron, cadmium, silver, lead, antimony, tin or bismuth; R1, R2, R3 and R4 represent independently an oleophilic group of 1 to 30 carbon atoms in which at least one of the four oleophilic groups is a secondary oleophilic group. Another embodiment relates to a lubricating oil composition comprising a lubricating oil basestock and, based on the oil composition, 0.01 to 10% by weight of the ingredient (A) described above, 0.5 to 7% by weight of the ingredient (B) described above, and (C) 0.01 to 5% by weight of an organic amide compound. DETAILED DESCRIPTION OF THE INVENTION
There is no particular restriction for the basestocks used in the lubricating oil composition according to the present invention and those proposed so far as the basestock for the lubricating oil, for example, mineral oils or synthetic oils can be used.
As the mineral oil, there can be mentioned, for example, 50 neutral oil, 100 neutral oil, 150 neutral oil, 300 neutral oil, 500 neutral oil and bright stock obtained by solvent refining or hydro- genation, which may be used alone or as a mixture of two or more of them at an appropriate ratio.
As the synthetic oil, there can be mentioned, for example, poly α-olefin oligomer, polybutene, alkylbenzene, alkyldiphenyl, polyol ester, polyglycol ester, dibasic acid ester, phosphoric acid ester and silicone oil, which may be used alone or as a mixture of two or more of them at an appropriate ratio. In addition, mineral oil and the synthetic oil described above may be used in admixture.
As the base oil used in the lubricating oil composition according to the present invention, those having a kinematic viscosity at a temperature of 100°C within a range from 3 to 20 mm2/s, prefer¬ ably 4 to 15 mm2/s are preferred.
As the ingredient (A) in the composition according to the present invention, oxymolybdenum monoglyceride or oxymolybdenum diethylate amide (hereinafter referred to "MoOxide type compound") is used. The oxymolybdenum monoglyceride is represented by the general formula (2):
O
II
R - C - O - CH - CH - CH
I I
O O (2)
\ / Mo
// \\ O O while oxymolybdenum diethylate amide is represented by the general formula (3):
O CH2 - CH2 - O O
II / \ //
R - C - N Mo (3)
\ / \\
CH2 - CH - O O
In the general formulae (2) and (3), R is hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or a hydrocarbon group containing ester bond, ether bond, alcohol group or carboxyl group. Preferred R is alkyl group of 6 to 18 carbon atoms, alkenyl group of 6 to 18 carbon atoms, cycloalkyl group or 12 to 24 carbon atoms or alkylaryl group of 12 to 24 carbon atoms. As preferred specific examples of them, there can be mentioned alkyl or alkenyl groups of 6 to 18 carbon atoms such as n-hexyl group, 2- ethylhexyl group, n-octyl group, nonyl group, decyl group, lauryl group, tridecyl group, oleyl group and linoleyl group, and alkylaryl group having an alkyl group of 3 to 18 carbon atoms such as nonyl- phenyl group.
The MoOxide type compound for the ingredient (A) may be used alone or two or more of them may be combined for use. Further, it is necessary that the blending amount is selected within a range from 0.01 to 10% by weight, preferably, 0.05 to 8% by weight based on the entire weight of the oil composition. No sufficient friction reducing effect can be obtained if the blending amount is less than 0.01% by weight whereas no corresponding improvement for the friction reducing effect can be observed if it exceeds 10% by weight.
As the ingredient (B) in the lubricating oil composition according to the present invention, a metal dithiocarbamate (herein¬ after referred to ■"M-DTC*") represented by the general formula (1) is used. R1 S S R3
\ II II /
N - C - M - S - C - N ( 1 )
/ \
R2 R4
In the above general formula (1), M is zinc, copper, nickel, iron, cadmium, silver, lead, antimony, tin or bismuth. Each of R1, R2, R3 and R4 is an oleophilic group of 1 to 30 carbon atoms in which at least one of them is a secondary oleophilic group, preferably, at least two of them are secondary oleophilic groups and the residue includes primary oleophilic groups. Further preferred oleophilic group are those in which at least three of them are secondary alkyl groups. Rl, R2, R3 and R4 may be identical or different with each other.
As the oleophilic group of 1 to 30 carbon atoms, there can be mentioned for example, alkyl group of 1 to 30 carbon atoms, alkenyl group of 2 to 30 carbon atoms, cycloalkyl group of 6 to 30 carbon atoms, aryl group of 6 to 30 carbon atoms, alkylaryl group of 7 to 30 carbon atoms, arylalkyl group of 7 to 30 carbon atoms or hydrocarbon group having ester bond, ether bond, alcohol group or carboxyl group.
M-DTC represented by the general formula (1) in the oil composition according to the present invention having four oleophilic groups with the average number of carbon atoms between 1 and 5 are desirably reacted with an oil soluble amine compound for complexing treatment in order to increase the solubility to the lubricating oil basestock and improve the wear resistance. M-DTC having four oleophilic groups with an average number of carbon atoms of 1 (in which all the oleophilic groups are methyl) cannot provide a homo¬ geneous lubricating oil composition even if it is reacted with the oil soluble amine compound since the solubility of the resultant complex to the lubricating oil basestock is poor. Since M-DTC exhibits its function by adsorption to metal surface, no sufficient effect can be expected if it dissolves excessively but it will be quite useless unless it is soluble. The lower limit for the average number of carbon atoms of the oleophilic group is preferably two or more in view of both functions of the solubility and the wear resistance. If the average number of carbon atoms of the four oleophilic groups is 5 or more, solubility to the lubricating oil basestock is satisfactory with no complexing treatment but it may be used after complexing if neces¬ sary.
In M-DTC, it is preferred that all the four oleophilic groups are identical hydrocarbon groups, more suitably, the four oleophilic groups are alkyl groups of 3 to 6 carbon atoms in view of easy produc¬ tion and wear resistance.
More preferred oleophilic group is alkyl group of 3 to 4 carbon atoms. For the metal atom (M), zinc is preferred in view of easy availability and wear resistance.
M-DTC can be produced by a known method. For instance, zinc diisopropyl dithiocarbamate can be produced by reacting diisopropyl- amine, carbon disulfide and sodium hydroxide to prepare sodium diisopropyl dithiocarbamate which is then reacted with zinc nitrate.
As the oil soluble amine compound used for complexing M-DTC, there can be mentioned, for example, ashless detergent dispersant such as polyalkenyl succinimide or alkylbenzylamine or alkylamine, alkyldi- amine and alkylpolyamine.
For previously forming a complex of M-DTC and the oil soluble amine compound, it is preferred to employ a method of adding both of them to a lubricating oil basestock at a ratio of providing a high concentration and heating them. For instance, when a lubricating oil composition containing 2 to 7% by weight of M-DTC and 2 to 25% by weight of oil soluble amine compound, at a ratio of 1 to 10 parts by weight of the oil soluble amine compound based on 1 part of weight of M-DTC is stirred at a temperature of 100 to 230°C, more preferably, 150 to 200°C, preferably for 1 to 60 minutes, more preferably, 1 to 30 minutes, both of the compounds form a complex which is uniformly dissolved in the lubricating oil basestock. As the heating tempera¬ ture is higher, they form a complex in a shorter period of time and are dissolved more uniformly. A homogeneous lubricating oil composi¬ tion containing both of the compounds at a desired ratio can be obtained easily by diluting the resultant complex solution at high concentration with the lubricating oil basestock.
In the lubricating oil composition according to the present invention, M-DTC as the ingredient (B) may be used alone or as a combination of two or more of them. It is necessary to blend M-DTC by 0.5 to 7% by weight, preferably, 1 to 5% by weight based on the oil composition. No sufficient wear resistant effect can be obtained if the blending amount is less than 0.5% by weight, whereas the solu¬ bility tends to be lowered if it exceeds 7% by weight.
secM-DTC has a function of an extreme pressure agent, as well as a function as an antioxidant, a corrosion inhibitor or the like.
In the lubricating oil composition according to the present invention, the organic amide compound as the ingredient (C) can be used as required. The organic amide compound is a compound repre¬ sented by the general formula (4):
R5
R7 - C - N <4>
R6
In the general formula (4), R5 and R6 each represents hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl groups of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl group or arylalkyl group of 7 to 26 carbon atoms or alkylene oxide group of 2 to 30 carbon atoms which may be identical or different with each other. R7 represents hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or hydrocarbon group containing ester bond, ether bond, alcohol group or carboxyl group. The alkylene oxide group mentioned herein is a group repre¬ sented by general formula (5) or (6).
CH2CHO 'n H
(5)
CHCH20 H
(6)
R' wherein R' represents hydrogen atom or methyl group and n is an integer of 1 to 10.
Preferred R5 and R6 in the general formula (4) are hydrogen atom, alkyl group of 2 to 8 carbon atoms, cycloalkyl group of 8 to 14 carbon atoms, alkylaryl group of 8 to 14 carbon atoms, and alkylene oxide group in which n is 1 to 5. Preferred R7 can include alkyl group of 6 to 18 carbon atoms, alkenyl group of 6 to 18 carbon atoms, cycloalkyl group of 12 to 24 carbon atoms and alkylaryl group of 12 to 24 carbon atoms. As specific examples of the organic amide compound, there can be mentioned, for example, oleamide or lauramide, which may be used alone or as a combination of two or more of them.
In the lubricating oil composition according to the present invention, the organic amide compound as the ingredient (C) is blended by 0.01 to 5% by weight, preferably, 0.05 to 2% by weight based on the oil composition. Blending of the organic amide compound can reduce the friction coefficient already from the initial stage of driving while suppressing the copper corrosiveness. No sufficient effect for reducing the friction coefficient from the initial stage of driving can be attained if the blending amount is less than 0.01% by weight, whereas no corresponding improvement for the effect can be recognized if the amount exceeds 5% by weight.
In the lubricating oil composition according to the present invention, there can be properly added various kinds of additives used customarily in the lubricating oils, for example, other extreme pressure agents, ashless detergent dispersant, antioxidant, metallic detergent, metal deactivator, viscosity index improver, pour point depressor, rust inhibitor, antifoamer and corrosion inhibitor within such a range as not deteriorating the purpose of the present inven¬ tion.
For other extreme expressure agent, there can be mentioned, for example, organomolybdenum compounds such as MoDTC or MoDTP. However, if the amount of the organomolybdenum compound used is increased, the copper corrosion becomes conspicuous. As the ashless detergent dispersant, there can be mentioned, for example, succinimide, succinamide, benzylamine or ester type, as well as boron-containing ashless detergent dispersant can be used. They are used usually at a ratio of 0.5 to 7% by weight.
Further, as the antioxidant, there can be mentioned, for example, amine-based antioxidant such as alkylated diphenylamine, phenyl-α-naphthylamine, alkylated-α-naphthylamine, and phenolic antioxidant such as 2,6-di-tertiary-butylphenol, and 4,4'-methylene- bis-(2,6-di-tertiary-butylphenyl) and it is usually used at a ratio of 0.05 to 2.0% by weight.
As the metallic detergent, there can be mentioned, for example, Ca-sulfonate, Mg-sulfonate, Ba-sulfonate, Ca-phenate, Mg- phenate, Ba-phenate, Ca-salicylate, Mg-salicylate and Ba-salicylate which is generally used at a ratio of 0.1 to 5.0% by weight. As the metal deactivator, there can be mentioned, for example, benzotriazole, benzotriazole derivative, benzothiazole, benzothiazole derivative, triazole, triazole derivative, dithiocarbamate, dithiocarbamate derivative, indazole and indazole derivative, which may be used usually at a ratio of 0.005 to 0.3% by weight.
As the viscosity index improver, there can be mentioned, for example, polymethacrylate, polyisobutylene, ethylene-propylene co- polymer and styrene-butadiene hydrogenated copolymer type improver, which may be used usually at a ratio of 0.5 to 35% by weight. •*
Further, as the rust inhibitor, there can be mentioned, for example, alkenyl succinic acid or its partial ester and as the antifoamer, there can be mentioned, for example, dimethyl polysiloxane and poly- acrylate, which may be added properly.
The lubricating oil composition according to the present invention can be prepared by blending each of the various kinds of additives described above at a predetermined amount with a basestock and uniformly mixing them. The lubricating oil composition according to the present invention can be used suitably, for example, to auto¬ mobile engine oil, gear oils, ATF oils, PS oils, spindle oils, hydraulic fluids or industrial lubricating oils.
The present invention will now be described more in details by way of preferred examples but the invention is not restricted at all to such examples.
Examples 1-9 and Comparative Examples 1-3
The performance of the lubricating oil composition was determined by the method shown below.
1. Coefficient of Friction
The coefficient of friction was measured by using a reciprocal vibration friction tester (SRV). In the SRV tester, a steel ball of 1/2 inch diameter (SUJ-2 specified in JIS G-4805) was used as the upper test piece, and a steel disc (SUJ-2 specified in JIS G-4805) was used as the lower test piece. A sample oil was dropped on the lower test piece, a load was applied to the upper piece from the top, and the upper test piece was vibrated parallel to the lower test piece with the upper test piece being passed against the lower test piece. The lateral load applied to the lower test piece was measured to calculate the coefficient of friction (μ). The coefficient of friction was measured twice, that is, 5 minutes and 20 minutes after the initiation of the vibration of the upper test piece. Testing conditions are as follows:
Load: 100N
Temperature: 130°C
Frequency: 8 Hz
Amplitude: 4 mm
2. Copper Corrosiveness
Corrosiveness was tested in accordance with JIS K2513 "Copper Strip Corrosion Test Method for Petroleum Products" at a test tempera¬ ture of 100°C for a test period of 8 hours by the test method, in which the state of discoloration of the copper strip was observed in accordance with "the Standard for Copper Corrosion" and the corrosive¬ ness was evaluated by subdivision symbols la-4c. The corrosiveness is lower as the numerical value of the subdivisional mark is smaller and the corrosiveness is increased in the alphabetical order.
Specific evaluation examples are as follows:
la: pale orange color which is substantially identical color with that of polished copper plate upon finishing,
lb: deep orange color, and
3a: reddish brown pattern on bronze color.
Examples 1-4, Comparative Examples 1-3
Lubricating oil compositions were prepared by blending 4% by weight of Ca-sulfonate, 5% by weight of succinimide, 0.5% by weight of alkylated diphenylamine, 0.3% by weight of 2,6-di-t-butylphenol and 0.02% by weight of 5-methyl-benzotriazole to a mineral oil (150 neutral mineral oil having kinematic viscosity at 100°C of 5.1 mm2/s) based on the entire weight of the oil composition, and blending each of the ingredients shown in Table 1, and the performances were evaluated. The results of measurement of properties are shown in Table 1.
Each of the ingredients are as shown below.
(1) MoOxide compound
0
II n - C6H13 - c - 0 - CH - CH - CH
/ \ O O
\ /
Mo
// \\ 0 O
(2) MoDTC (Sakura-Lube® manufactured by Asahi Denka Kogyo K.K.)
(2EH) S 0 S C S (2EH)
\ II II / \ II II /
N - C - S - Mo Mo - S - C - N
/ \ / \
(2EH) S (2EH)
2EH : 2-ethylhexyl group, here and hereinafter
(3) MoDTP (Molyvan L® manufactured by R.T. Vanderbilt)
(2EH) - O S O S O S O - (2EH)
Ml II / \ II 11/
P - S - Mo Mo - S - P
/ \ / \
(2EH) - O S O - (2EH)
(4) sec-ZnDTC
R1 S S R3
\ II II /
N - C - M - S - C - N
/ \
R2 R4
wherein two groups of R^-R4 are isopropyl groups and the residues are n-propyl group) . (5) Ca-sulfonate
Figure imgf000017_0001
(6) Succinimide
Figure imgf000017_0002
PiB : polyisobutylene
TABLE 1
COMPARATIVE
EXAMPLES EXAMPLES
1 2 3 4 5 6 7 8 9 1 2 3
MoOxide (wt%) 0.7 3.0 0.7 3.0 0.7 3.0 0.7 0.7 0.7 0.7 0.3
MoDTC (wt%) ___ 0.3 i-C3ZnDTC (wt%) 1.0 1.0 1.0 1.0 1.0 1.0 n-C3ZnDTC (wt%) — — — 1.0 1.0 i-C3/n-C3ZnDTC 1.0 1.0 1.0 (wt%) (1)
1-methylnonyl 1.9 1.9 ZnDTC (wt%) i-C3/s-C5ZnDTP — — 2#o (wt%) (2)
Oleamide (wt%) — 0.5 — — 0.5 0.5
Lauramide (wt%) — 0.5 —
Coefficient of Friction
After 5 minutes 0.12 0.12 0.05 0.06 0.12 0.12 0.06 0.13 0.07 0.14 0.14 0.13
After 20 minutes 0.06 0.05 0.05 0.04 0.06 0.06 0.06 0.07 0.06 0.10 0.09 0.11
Copper Corrosiveness la la la la la la la la la la la 3a
Notes: (1) iC3/nC3 molar ratio is 1/1.
(2) Alkyl group comprises mixture of isopropyl group and secondary hexyl group.
The present invention can provide a lubricating oil composi¬ tion excellent in wear resistance, exhibiting a low coefficient of friction, capable of improving fuel economy and having improved copper corrosiveness, as well as a lubricating oil composition having the above-mentioned characteristics and, in addition, capable of attaining a low coefficient of friction already from the initial stage of driving.

Claims

CLAIMS :
1. A lubricating oil composition comprising a lubricating oil basestock and, based on the oil composition,
(A) 0.01 to 10% by weight of at least one of organomolybdenum com¬ pound selected from the group consisting of oxymolybdenum mono¬ glyceride and oxymolybdenum diethylate amide, and
(B) 0.5 to 7% by weight of a metal dithiocarbamate represented by the general formula (1):
R1 S S R3
\ II II /
N - C - M - S - C - N (1)
/ \
R2 R4
where M represents zinc, copper, nickel, iron, cadmium, silver, lead, antimony, tin or bismuth, R1, R2, R3 and R4 represent independently an oleophilic group of 1 to 30 carbon atoms in which at least one of the four oleophilic groups is a secondary oleophilic group.
2. The composition of claim 1 further comprising form 0.01 to 5% by weight of an organic amide compound.
3. The composition of claim 1 wherein the oxomolybdenum monoglyceride has the formula
O
II
R - C - O - CH - CH - CH
I I
O O (2)
\ / Mo
// \\ O O where R is hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or a hydrocarbon group containing ester bond, ether bond, alcohol group or carboxyl group.
4. The composition of claim 1 wherein the oxomolybdenum diethyate amide has the formula
O CH2 - CH2 - O O
II / \ //
R - C - N Mo (3)
\ / \\
CH2 - CH2 - O O
wherein R is hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or a hydrocarbon group con¬ taining ester bond, ether bond, alcohol group or carboxyl group.
5. The composition of claim 2 wherein the organic amide has the formula
O R5
II /
R7 - C - N (4)
\ R6
wherein R^ and R^ each represents hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl groups of 2 to 20 carbon atoms, cycloalkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl group or arylalkyl group of 7 to 26 carbon atoms or alkylene oxide group of 2 to 30 carbon atoms which may be identical or dif¬ ferent with each other and R7 represents hydrogen atom, alkyl group of 1 to 20 carbon atoms, alkenyl group of 2 to 20 carbon atoms, cyclo¬ alkyl group of 6 to 26 carbon atoms, aryl group of 6 to 26 carbon atoms, alkylaryl or arylalkyl group of 7 to 26 carbon atoms or hydro¬ carbon group containing ester bond, ether bond, alcohol group or carboxyl group.
PCT/US1994/013767 1993-11-30 1994-11-29 Lubrication oil composition WO1995015368A1 (en)

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EP0874040A1 (en) * 1997-04-22 1998-10-28 R. T. Vanderbilt, Inc. Synergistic organomolybdenum compositions and lubricating compositions containing same
EP0882781A2 (en) * 1997-06-04 1998-12-09 Idemitsu Kosan Co., Ltd. Lubricating oil composition providing anti-shudder properties
WO2010122070A1 (en) * 2009-04-22 2010-10-28 Shell Internationale Research Maatschappij B.V. Lubricating composition
US9909081B2 (en) 2014-10-31 2018-03-06 Basf Se Alkoxylated amides, esters, and anti-wear agents in lubricant compositions
WO2020023437A1 (en) * 2018-07-24 2020-01-30 Exxonmobil Research And Engineering Company Lubricating oil compositions with engine corrosion protection
EP2550346B1 (en) * 2010-03-25 2020-11-04 Vanderbilt Chemicals, LLC Ultra low phosphorus lubricant compositions

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JP4612393B2 (en) * 2004-10-29 2011-01-12 Ｊｘ日鉱日石エネルギー株式会社 Lubricating oil composition suitable for lead-containing metal materials
US20080020952A1 (en) * 2004-10-19 2008-01-24 Kazuhiro Yagishita Lubricant Composition
JP2006117720A (en) * 2004-10-19 2006-05-11 Nippon Oil Corp Copper-lead corrosion inhibitor and lubricating oil composition
WO2010005720A1 (en) 2008-07-11 2010-01-14 Basf Se Composition and method to improve the fuel economy of hydrocarbon fueled internal combustion engines
US10767134B1 (en) * 2019-05-17 2020-09-08 Vanderbilt Chemicals, Llc Less corrosive organomolybdenum compounds as lubricant additives

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* Cited by examiner, † Cited by third party
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EP0874040A1 (en) * 1997-04-22 1998-10-28 R. T. Vanderbilt, Inc. Synergistic organomolybdenum compositions and lubricating compositions containing same
CN1098348C (en) * 1997-04-22 2003-01-08 R·T·范德比尔特公司 Synergistic organomolybdenum compositions and lubricating compositions containing same
EP0882781A2 (en) * 1997-06-04 1998-12-09 Idemitsu Kosan Co., Ltd. Lubricating oil composition providing anti-shudder properties
EP0882781A3 (en) * 1997-06-04 1999-06-30 Idemitsu Kosan Co., Ltd. Lubricating oil composition providing anti-shudder properties
US6048826A (en) * 1997-06-04 2000-04-11 Idemitsu Kosan Co., Ltd. Lubricating oil composition
WO2010122070A1 (en) * 2009-04-22 2010-10-28 Shell Internationale Research Maatschappij B.V. Lubricating composition
EP2550346B1 (en) * 2010-03-25 2020-11-04 Vanderbilt Chemicals, LLC Ultra low phosphorus lubricant compositions
US9909081B2 (en) 2014-10-31 2018-03-06 Basf Se Alkoxylated amides, esters, and anti-wear agents in lubricant compositions
US9920275B2 (en) 2014-10-31 2018-03-20 Basf Se Alkoxylated amides, esters, and anti-wear agents in lubricant compositions and racing oil compositions
US10246661B2 (en) 2014-10-31 2019-04-02 Basf Se Alkoxylated amides, esters, and anti-wear agents in lubricant compositions and racing oil compositions
WO2020023437A1 (en) * 2018-07-24 2020-01-30 Exxonmobil Research And Engineering Company Lubricating oil compositions with engine corrosion protection

Also Published As

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EP0731829A1 (en) 1996-09-18
JPH07150177A (en) 1995-06-13
CA2174931A1 (en) 1995-06-08
EP0731829A4 (en) 1997-01-22

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