WO1994025409A1 - Glass having a holographic grating pattern and a single pure metal membrane - Google Patents

Glass having a holographic grating pattern and a single pure metal membrane Download PDF

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Publication number
WO1994025409A1
WO1994025409A1 PCT/CN1994/000030 CN9400030W WO9425409A1 WO 1994025409 A1 WO1994025409 A1 WO 1994025409A1 CN 9400030 W CN9400030 W CN 9400030W WO 9425409 A1 WO9425409 A1 WO 9425409A1
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WO
WIPO (PCT)
Prior art keywords
glass
film layer
metal film
resin
layer
Prior art date
Application number
PCT/CN1994/000030
Other languages
French (fr)
Chinese (zh)
Inventor
Dening Yang
Original Assignee
Dening Yang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dening Yang filed Critical Dening Yang
Priority to AU65624/94A priority Critical patent/AU6562494A/en
Publication of WO1994025409A1 publication Critical patent/WO1994025409A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
    • B44F1/04—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10247—Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material

Definitions

  • the present invention relates to a holographic grating pattern glass used as a decorative material, and more particularly to a single-sided pure metal film type holographic grating pattern glass suitable for wall, door, window, and curtain wall decoration.
  • the prior art holographic grating decorative material is nothing more than a thermoplastic resin film made by a thermal indentation process, such as the Chinese patent application CNni (i 41A) filed on June 19, 19
  • the disclosed "holographic decorative tiles” and the holographic grating solar film disclosed in the Chinese patent application CNni HDOA filed by the applicant on August 28, 19, 19) are made of glass with grating relief.
  • Crosslinked molecular structure resin film (see the issued Chinese utility model patent of the applicant
  • the present invention aims at providing the above-mentioned overcoming the prior art.
  • Defective grating decorative material which can not only provide a more colorful appearance than the existing products, to meet the beautiful sense required to decorate specific occasions, but also to meet the indoor occasions such as offices, living rooms, etc. Decorations such as a less bright, elegant and quiet atmosphere have greatly expanded the scope of application of the product, that is, further increased the practical value of the grating product. more specifically:
  • An object of the present invention is to provide a decorative pattern composed of a mirror surface showing a pure gold coating layer and a pure metal film layer on a holographic grating relief viewed from the front, and the back surface is a single-sided pure gold coating with any opaque color.
  • Layer of holographic grating glass that is, to provide a decorative mirror surface, so that beautiful colorful diffracted light appears on the mirror glass, like a mirror inlaid with a pattern of crystal or diamond, can also be used as the veneer on the outer wall or elevator car Material to overcome the lack of mirrorless effect of the existing "printed glass".
  • a second object of the present invention is to provide a single-sided pure metal with a pattern composed of transparent glass and a pure metal film layer with a holographic grating relief when viewed from the front, and a single-sided pure metal with a pattern composed of any color and transparent glass when viewed from the front Film layer of holographic grating glass. That is to say, it can be used as a living room, office curtain wall, or window glass to control the color of one side of the room to overcome the existing "laminated transparent glass”.
  • a third object of the present invention is to provide a pattern composed of a metal film layer showing a certain light transmittance and a pure gold film layer with a holographic grating relief when viewed from the front side, and the back side showing an arbitrary color and heat reflecting metal
  • the diffractive colorful light reflected by the golden film layer on the grating relief is blocked and partially reflected by the surface heat reflection film, so that the colorful light formed when the transmitted light passes through the metal reflection film of the grating is not as strong as the product of the second object mentioned above.
  • a fourth object of the present invention is to provide a pattern composed of a metal film grating behind a light-transmissive planar reflective metal film on one side, and a pattern composed of a resin layer and a light-transmissive interlayer reflective metal film layer on the other side. . That is, it provides a grating product that has both the strong diffractive colorful light when viewed from the front of the second object of the present invention and the effect of the third object of the present invention that has the effect of a heat reflecting mirror metal film layer.
  • the structure of the holographic grating pattern glass composed of a single-sided pure metal film layer embodying the first object of the present invention includes: flat glass, a gold-plated layer such as aluminum, a resin layer such as acrylic, and a transparent interlayer such as Resin layers such as epoxy, gold reflective coatings on grating reliefs, and resin layers such as PYC.
  • the structure of the holographic grating pattern glass composed of a single-sided pure metal film layer embodying the second object of the present invention includes, in order, a flat sloping glass, a transparent resin layer, a metal coating layer with a holographic grating relief, and a resin coating such as acrylic acid. , A transparent composite resin layer and another flat glass layer.
  • the structure of the holographic grating pattern glass composed of a single-sided pure metal film layer embodying the third object of the present invention includes: flat glass, a metal film layer with a certain reflectivity, a transparent resin layer, a metal plating layer with a holographic grating relief, and a resin. Coating, transparent composite resin layer and another flat glass layer.
  • the structure of the holographic grating pattern glass composed of a single-sided pure gold film layer reflecting the fourth object of the present invention includes, in order: flat glass, a transparent resin layer, a gold film layer with a holographic grating relief, and a resin layer with opaque color And another resin layer which is bonded to another flat glass layer coated with a metal film layer having a reflectivity of 10-70%.
  • the appearance is mirror-like; the mirror effect, the colorful effect of the grating and the characteristics of the heat-reflecting glass can be combined to different degrees according to different requirements of different applications And to meet different needs.
  • a strong grating effect and a mirror effect can be combined to form a very colorful exterior wall surface.
  • Another example is to make the reflected colorful light weaker and form a curtain wall glass with a mirror effect stronger than the grating effect.
  • FIG. 1 is a front plan view of a holographic grating pattern glass composed of a single-sided pure metal film layer according to a first embodiment of the present invention
  • FIG. 2 is a schematic cross-sectional view of the product of the embodiment shown in FIG. 1;
  • FIG. 3 is an enlarged schematic plan view of a grating plane in a holographic grating pattern glass composed of a single-sided pure metal film layer according to an embodiment of the present invention
  • FIG. 4 is a back plan view of a holographic grating pattern glass composed of a single-sided pure metal film layer according to a first embodiment of the present invention
  • FIG. 5 is a front plan view of a second embodiment of a holographic grating pattern glass composed of a single-sided pure gold film according to the present invention
  • FIG. 6 is a schematic cross-sectional view of a holographic grating pattern glass composed of a single-sided pure metal film shown in FIG. 5;
  • FIG. 7 is a second embodiment of a holographic grating pattern glass composed of a single-sided ⁇ gold film according to the present invention;
  • FIG. 8 is a rear plan view of a second embodiment of a holographic grating pattern glass composed of a single-sided pure gold film according to the present invention.
  • FIG. 10 is a schematic cross-sectional view of a fourth embodiment of a holographic grating pattern glass composed of a single-sided pure metal film layer according to the present invention; the best way to implement the present invention is now shown in FIGS. 1-4, which show the single-sided pure metal of the present invention.
  • the transparent plate 1 is a 5 mm thick substrate.
  • the white part in FIG. 1 is a pattern composed of silver-white metal film (2) seen through the flat glass, and the black part is composed of a metal reflective film layer on a square grating that can be seen through the flat glass and transparent resin. pattern.
  • Figure 3 shows the grating plane under a transparent resin (4) covered with a regular grating with a pitch of 3 ⁇ m and a metal film layer embossed with H under black.
  • the white color in Figure 4 indicates that a layer of white PVC resin is attached to it.
  • the single-sided pure metal film holographic grating glass according to the first embodiment of the present invention is made of flat glass 1 with aluminized metal film layer, gray acrylic resin layer 4, interlayer transparent resin layer 2, and plating on the grating relief.
  • the aluminum metal reflective film layer 3 and the resin coating layer 8 are composed.
  • the specific manufacturing process is as follows: a pattern 7 composed of a metal film layer is plated on the back of the flat glass 1, and a protective resin 4 is added behind the metal film layer, and then a layer of metal is adhered with a transparent adhesive 2
  • the grating embossed resin layer ⁇ and the transparent resin layer 2 with the metal reflective layer 3 may be a thermoplastic resin such as polycarbonate or a pressure-sensitive adhesive resin or PVC, or may be an acrylic, epoxy, poly A resin such as a cross-linked molecular structure such as melamine may be a photosensitive thermosetting resin or a thermosetting two-component curing resin.
  • an adhesive layer can also be added to the back of the grating relief resin layer ⁇ with a metal reflective layer to adhere the back glass or other fixed plate. This product is especially suitable for decorating mirror surface, veneering of exterior wall and elevator car, etc., in order to present the comprehensive effect of metal film layer and grating pattern.
  • the pattern glass in this embodiment is composed of flat glass 1, transparent epoxy resin layer 2, aluminized metal film layer 3 with holographic grating relief, gray acrylic acid coating 4, and transparent acrylic glass.
  • the dilute acid composite resin layer 5 is composed of another flat glass 6.
  • Figure 5 shows the front surface of the product.
  • the base material is two 5 mm- thick flat glass plates.
  • a pattern consisting of a pure metal film with a holographic grating relief and transparent laminated glass appears on it.
  • the black part indicates the laminated glass.
  • the glass has a pure gold film with holographic grating relief, and the white part indicates transparent laminated glass.
  • FIG. 7 is an enlarged schematic plan view of the pure gold film layer with the holographic grating relief, as in FIG.
  • Figure 8 This is a rear plan view of the product of this embodiment, in which the white part is transparent laminated glass, and the black part of the figure shows a light gray resin layer in the middle of the laminated glass.
  • the production process of the product of this embodiment is as follows: a transparent resin layer 2 with a holographic or grating relief composed of a certain pattern is bonded to the flat glass 1, and then a metal reflective film layer is plated on the resin grating relief. 3. Then apply an opaque resin layer 4 with any color on the embossed gold film layer of the grating, and then use another resin layer 5 to bond it with another flat glass 6 and then clamp it.
  • the conventional heating and pressurizing process of colloidal glass eliminates the air bubbles in the interlayer, that is, a pattern composed of a grating with a metal film layer and transparent laminated glass on one side is made, and the other side is a product composed of opaque resin and transparent laminated glass of other colors.
  • the product of this embodiment is made of flat glass 1, a transparent metal film layer 7 (such as aluminum with a reflectivity of 30 ° / °), a transparent resin layer 2, and a metal with a holographic grating relief (such as aluminum). ) Film layer 3, acrylic acid (such as gray) coating 4, transparent composite resin layer 5, flat glass 6.
  • the production process of the product of this embodiment is: plating the flat glass 1 with a reflectance of 10%-! 1 (1% of a metal film layer 7 and then bonding a layer of grating with a certain pattern on it An embossed transparent resin layer 2, and then a gold reflective film layer 3 is plated on the grating relief, and then an opaque colored resin layer 4 is coated on the metal reflective film, and another transparent resin layer 5 is placed on It is bonded with another flat slope glass 6 and the air bubbles in the interlayer are discharged through the conventional heating and pressing process of laminated glass to obtain a metal with a light-transmitting flat reflective metal film on one side.
  • the product of the present invention is a pattern composed of a film grating, and the other side is a pattern composed of a resin layer and a light-transmissive interlayer reflective metal film layer.
  • a holographic grating pattern glass product composed of a single-sided pure metal film layer according to a fourth embodiment of the present invention
  • the product of this example is made of flat glass 1, transparent epoxy layer 2, gold-aluminum aluminum film with holographic grating relief, gray acrylic coating 4, colorless and transparent resin layer 5, reflection It is composed of an aluminized metal film layer 6 and a flat glass 7 with a rate of 30%.
  • the manufacturing process of the product of this example is the same as the manufacturing process of Embodiment 3 of the present invention except that the process sequence is different due to different structures (see Figures 10 and 9), so it is not repeated here.
  • the pattern of the grating product made in this example can show a pattern composed of a light-transmitting metal film layer and a metal grating reflection film layer on the front side, and the back side has the effect of ordinary thermally reflective M glass.
  • the product provided according to the first object of the present invention can decorate a mirror surface; can be used as various building exterior walls, can be used as various A veneer material in an elevator car; a product provided according to the second object of the present invention can be used as a veneer for a living room, an office curtain wall, and can be used as a window glass of various buildings; a product provided according to the third object of the present invention It can be used as window glass and curtain wall glass of various buildings; the products provided according to the fourth object of the present invention can be used as exterior wall veneers of various buildings; partitions of offices or living rooms. In short, the product of the present invention can be applied to the building decoration industry.
  • the flat glass (1, 6) in the above embodiments may be colorless, or any color such as blue, tea, green, gray, etc., or may be reinforced glass or a resin film sandwiched with red, yellow, or other color resin films. Glue safety glass.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

A glass having a holographic pattern and a single pure metal membrane was disclosed, which can be used as a wall of mirror and decoration for doors, windows and walls. The said glass mainly comprises glass sheet (1), metal membrane thereon (7), protective resin layer (4), transparent adhesive layer (2) and resin layer (8) of grating sculptures with metal reflecting layer (3). According to various application environments and needs of customers, the components in the construct and the order of the manufacturing procedure of the glass can be modified, so as to achieve the purpose of the invention - substantially enhancing the practical value and extending the application coverage for grating articles.

Description

说 明 书  Explanation book
单面纯金属膜层的 Single-sided pure metal film
全息光栅图案玻璃  Holographic grating pattern glass
术领域 本发明涉及用作装饰材料的全息光栅图案玻璃， 尤其涉及适用于墙面， 门窗， 幕墙装饰的单面纯金属膜式的全息光栅图案玻璃。 背景技术 先有技术的全息光栅装饰材料， 不外乎一种为采用热压痕工艺制成的热塑 性树脂膜， （ 如本申请人于 19Π年 6月 日提交的中国专利申请 CNni(i 41A中 所揭示的 "全息装饰砖"和本申请人于 19 Π年 8月 28日所提交的中国专利申请 CNni HDOA所揭示的全息光栅太阳膜。 ） 一种为在玻璃上制成带有光栅浮雕 的交联型分子结构树脂膜， （ 见已颁布的本申请人的中国实用新型专利  FIELD OF THE INVENTION The present invention relates to a holographic grating pattern glass used as a decorative material, and more particularly to a single-sided pure metal film type holographic grating pattern glass suitable for wall, door, window, and curtain wall decoration. BACKGROUND OF THE INVENTION The prior art holographic grating decorative material is nothing more than a thermoplastic resin film made by a thermal indentation process, such as the Chinese patent application CNni (i 41A) filed on June 19, 19 The disclosed "holographic decorative tiles" and the holographic grating solar film disclosed in the Chinese patent application CNni HDOA filed by the applicant on August 28, 19, 19) are made of glass with grating relief. Crosslinked molecular structure resin film, (see the issued Chinese utility model patent of the applicant
NO. 所揭示的 "压铸全息光栅彩色玻璃"） 。 但以上产品不是经不住日晒 雨淋， 使用一段时间后膜层就会变形（ "太阳膜"） 就是因全息或光栅图象太 单调， 以致应用范围窄， 而基本未得到实际应用。 于是， 又有本申请人近年的 全息光栅夹层透光玻璃和采用丝网印刷工艺制成的 "印刷琥璃光栅装饰板" 的 问世， （ 分别详见 1 1年 10月 2!)日提交中国专利申请 及 !)1年 11月 2 曰提交的中国专利申请 911G8448.7。 这两种新产品克服了前述产品的缺点， 并 已应用于酒店， 馆的柱面， 外墙， 歌舞厅等文化娱乐场所的顶面， 地面、 商 店门面等的装饰。 但在应用中发现主要用作门窗和格断的所述 "夹层透光玻璃 "在用作办公室或居室等的门窗坡璃时， 由于其两面都由光栅与透明玻璃组成 的图案， 故当其室外一面具有光栅衍射的美丽光学效果的同时， 室内一面特别 在阳光或灯光下有过于耀眼等不适之感， 而不易为人们所接受。 另一方面， 作 装饰用的印刷玻璃光栅装饰板却不能应用于诸如镜子表面、 电梯轿箱壁面等处 的装饰， 也没有犹如镜面玻璃那样亮堂的外观。 也就是说， 这两种最近产品在 实用方面仍有一定的局限性。  NO. "Diecasting Holographic Grating Stained Glass"). However, the above products are not able to withstand the sun and rain, and the film will be deformed after a period of use ("sun film"), or because the holographic or grating image is too monotonous, the application range is narrow, and it has not been practically used. Therefore, the applicant's recent years of holographic grating laminated transparent glass and the "printed Huli grating decorative plate" made by screen printing technology came out, (see details on October 2, 2011!) And submitted to China Patent applications and!) Chinese patent application 911G8448.7 filed on November 2, 1st. These two new products overcome the shortcomings of the aforementioned products and have been applied to the decoration of hotels, pavilions, exterior walls, the top surfaces of cultural and entertainment venues such as dance halls, floors, and store facades. However, it is found in the application that the "laminated transparent glass" mainly used as doors and windows and grids is used as a window and door glass for offices, living rooms, etc., because both sides are composed of a pattern of gratings and transparent glass. While the outdoor side has the beautiful optical effect of grating diffraction, the indoor side has an uncomfortable feeling such as being too dazzling under the sun or light, which is not easy for people to accept. On the other hand, the decorative glass grating decorative plate used for decoration cannot be applied to the decoration of mirror surfaces, elevator car wall surfaces, etc., nor does it have a bright appearance like mirror glass. That said, these two recent products still have some limitations in terms of practicality.
因此， 本发明旨在提供克服已有技术的上述  Therefore, the present invention aims at providing the above-mentioned overcoming the prior art.
缺陷的光栅装饰材料， 该材料不仅能提供较已有制品更为多姿的外观， 以满足 装饰特定场合所需的富丽堂皇感， 而且能满足办公室、 居室等室内场合要显现 不太亮的优雅宁静气氛等装饰要术， 从而大大扩大了产品的应用范围， 也就是 说， 进一步提高了光栅制品的实用价值。 更具体地说： Defective grating decorative material, which can not only provide a more colorful appearance than the existing products, to meet the magnificent sense required to decorate specific occasions, but also to meet the indoor occasions such as offices, living rooms, etc. Decorations such as a less bright, elegant and quiet atmosphere have greatly expanded the scope of application of the product, that is, further increased the practical value of the grating product. more specifically:
本发明的一个目的是提供一种从正面观看显现纯金厲镀膜层的镜面与全息 光栅浮雕上的纯金属膜层交错组成的装饰图案， 而其背面为任意不透明色彩的 单面纯金厲膜层的全息光栅玻璃， 也就是说提供可装饰镜面， 而使镜面玻璃上 出现美丽的七彩衍射光， 犹如镜子镶上了水晶或钻石的图案， 也可作外墙或电 梯轿箱内的贴面材料， 以克服已有 "印刷玻璃"无镜面效果的不足。  An object of the present invention is to provide a decorative pattern composed of a mirror surface showing a pure gold coating layer and a pure metal film layer on a holographic grating relief viewed from the front, and the back surface is a single-sided pure gold coating with any opaque color. Layer of holographic grating glass, that is, to provide a decorative mirror surface, so that beautiful colorful diffracted light appears on the mirror glass, like a mirror inlaid with a pattern of crystal or diamond, can also be used as the veneer on the outer wall or elevator car Material to overcome the lack of mirrorless effect of the existing "printed glass".
本发明的第二个目的是提供一种从正面观看时显现出透明玻璃与具有全息 光栅浮雕的纯金属膜层组成的图案， 而其背面为任意色彩与透明玻璃组成的图 案的单面纯金属膜层的全息光栅玻璃。 也就是说提供可用作居室， 办公室幕墙 贴面或窗玻璃时可控制室内一面的色彩， 以克服已有的 "夹层透光玻璃" 的不 足。  A second object of the present invention is to provide a single-sided pure metal with a pattern composed of transparent glass and a pure metal film layer with a holographic grating relief when viewed from the front, and a single-sided pure metal with a pattern composed of any color and transparent glass when viewed from the front Film layer of holographic grating glass. That is to say, it can be used as a living room, office curtain wall, or window glass to control the color of one side of the room to overcome the existing "laminated transparent glass".
本发明的第三个目的是提供一种从正面观看时， 显现一定透光率的金属膜 层与具有全息光栅浮雕的纯金厲膜层组成的图案， 而其背面显现任意色彩与热 反射金属膜平面相结合图案的单面纯金属膜层的全息光栅玻璃， 也就是说， 当 其用作窗玻璃及幕墙玻璃时， 正面观察， 能突出热反射玻璃效果， 当户外光线 较强时， 全息光栅浮雕上的金厲膜层反射的衍射七彩光受表层热反射膜的阻隔 ， 部分反射， 使透过的光经光栅金属反射膜时所形成的七彩光没有上述目的二 的产品那么强烈。  A third object of the present invention is to provide a pattern composed of a metal film layer showing a certain light transmittance and a pure gold film layer with a holographic grating relief when viewed from the front side, and the back side showing an arbitrary color and heat reflecting metal A single-sided pure metal film layered holographic grating glass with a combination of film planes, that is, when it is used as window glass or curtain wall glass, it can highlight the effect of heat reflection glass when viewed from the front. The diffractive colorful light reflected by the golden film layer on the grating relief is blocked and partially reflected by the surface heat reflection film, so that the colorful light formed when the transmitted light passes through the metal reflection film of the grating is not as strong as the product of the second object mentioned above.
本发明的第四个目的是提供一种其一面显现可透光的平面反射金属膜后面 的金属膜光栅组成的图案， 而另一面为树脂层与可透光的夹层反射金属膜层组 成的图案。 也就是说， 提供既有本发明目的二的正面观看时较强的衍射七彩光 ， 又兼有发明目的三的有热反射镜面金属膜层效果的光栅制品。 发明的公开 体现本发明第一目的的单面纯金属膜层组成的全息光栅图案玻璃的结构依 次包括： 平板玻璃， 诸如铝等金厲镀膜层， 诸如丙稀酸等树脂层， 夹层透明的 诸如环氧等树脂层， 光栅浮雕上的金厲反射膜镀层以及诸如 PYC等树脂层。  A fourth object of the present invention is to provide a pattern composed of a metal film grating behind a light-transmissive planar reflective metal film on one side, and a pattern composed of a resin layer and a light-transmissive interlayer reflective metal film layer on the other side. . That is, it provides a grating product that has both the strong diffractive colorful light when viewed from the front of the second object of the present invention and the effect of the third object of the present invention that has the effect of a heat reflecting mirror metal film layer. The structure of the holographic grating pattern glass composed of a single-sided pure metal film layer embodying the first object of the present invention includes: flat glass, a gold-plated layer such as aluminum, a resin layer such as acrylic, and a transparent interlayer such as Resin layers such as epoxy, gold reflective coatings on grating reliefs, and resin layers such as PYC.
体现本发明第二目的的单面纯金属膜层组成的全息光栅图案玻璃的结构依 次包括： 平板坡璃， 透明树脂层， 带有全息光栅浮雕的金属镀膜层， 如丙稀酸 等树脂涂层， 透明复合树脂层及另一平板玻璃层。 体现本发明第三目的的单面纯金属膜层组成的全息光栅图案玻璃的结构依 次包括： 平板玻璃， 一定反射率的金属膜层， 透明树脂层， 带有全息光栅浮雕 的金属镀膜层， 树脂涂层， 透明复合树脂层及另一平板玻璃层。 The structure of the holographic grating pattern glass composed of a single-sided pure metal film layer embodying the second object of the present invention includes, in order, a flat sloping glass, a transparent resin layer, a metal coating layer with a holographic grating relief, and a resin coating such as acrylic acid. , A transparent composite resin layer and another flat glass layer. The structure of the holographic grating pattern glass composed of a single-sided pure metal film layer embodying the third object of the present invention includes: flat glass, a metal film layer with a certain reflectivity, a transparent resin layer, a metal plating layer with a holographic grating relief, and a resin. Coating, transparent composite resin layer and another flat glass layer.
体现本发明第四个目的的单面纯金厲膜层组成的全息光栅图案玻璃的结构 依次包括： 平板玻璃， 透明树脂层， 带有全息光栅浮雕的金厲镀膜层， 带不透 明色彩的树脂层及将其与镀有反射率为 1 0—70 %的金属膜层的另一平板坡璃层 粘合在一起的另一树脂层。  The structure of the holographic grating pattern glass composed of a single-sided pure gold film layer reflecting the fourth object of the present invention includes, in order: flat glass, a transparent resin layer, a gold film layer with a holographic grating relief, and a resin layer with opaque color And another resin layer which is bonded to another flat glass layer coated with a metal film layer having a reflectivity of 10-70%.
本发明的上述制品分别具有先有技术制品所未能达到的如下效果： 外观似 镜面； 可按不同应用场合的不同要求将镜面效果， 光栅的七彩效果及热反射玻 璃特点， 以不同程度加以组合， 而适应不同需求。 例如可将强光栅效果与镜面 效果加以组合， 而形成十分艳丽的外墙面； 又如， 可使反射的七彩光较弱， 而 形成镜面效果强于光栅效果的幕墙玻璃。 附图的简要说明 现结合附图详细描述本发明的四个最佳实施例， 附图中， 诸相同标号表示 相同或类似的组成部分。  The above-mentioned products of the present invention each have the following effects that cannot be achieved by the prior art products: the appearance is mirror-like; the mirror effect, the colorful effect of the grating and the characteristics of the heat-reflecting glass can be combined to different degrees according to different requirements of different applications And to meet different needs. For example, a strong grating effect and a mirror effect can be combined to form a very colorful exterior wall surface. Another example is to make the reflected colorful light weaker and form a curtain wall glass with a mirror effect stronger than the grating effect. Brief Description of the Drawings The four preferred embodiments of the present invention will now be described in detail with reference to the accompanying drawings. In the drawings, the same reference numerals represent the same or similar components.
图 1为本发明第一实施例的单面纯金属膜层组成的全息光栅图案玻璃的正 面平面视图；  1 is a front plan view of a holographic grating pattern glass composed of a single-sided pure metal film layer according to a first embodiment of the present invention;
图 2为图 1所示实施例制品的截面示意图；  2 is a schematic cross-sectional view of the product of the embodiment shown in FIG. 1;
图 3为本发明笫一实施例的单面纯金属膜层组成的全息光栅图案玻璃中的 光栅平面放大示意图；  3 is an enlarged schematic plan view of a grating plane in a holographic grating pattern glass composed of a single-sided pure metal film layer according to an embodiment of the present invention;
图 4为本发明第一实施例的单面纯金属膜层组成的全息光栅图案玻璃的背 面平面视图；  4 is a back plan view of a holographic grating pattern glass composed of a single-sided pure metal film layer according to a first embodiment of the present invention;
图 5为本发明单面纯金厲膜组成的全息光栅图案玻璃的第二实施例的正面 平面视图；  5 is a front plan view of a second embodiment of a holographic grating pattern glass composed of a single-sided pure gold film according to the present invention;
图 6为图 5所示单面纯金属膜组成的全息光栅图案玻璃的截面示意图； 图 7为本发明单面^金厲膜组成的全息光栅图案玻璃第二实施例中， 具有 全息光栅浮雕的纯金厲膜层的正面平面放大示意图；  FIG. 6 is a schematic cross-sectional view of a holographic grating pattern glass composed of a single-sided pure metal film shown in FIG. 5; FIG. 7 is a second embodiment of a holographic grating pattern glass composed of a single-sided ^ gold film according to the present invention; An enlarged schematic plan view of the front surface of the pure gold film layer;
图 8为本发明单面纯金厲膜组成的全息光栅图案玻璃第二实施例的背面平 面图；  8 is a rear plan view of a second embodiment of a holographic grating pattern glass composed of a single-sided pure gold film according to the present invention;
图!)为本发明单面纯金属膜层组成的全息光栅图案玻璃第三实施例的截面 示意图； Figure!) Is a section of a third embodiment of a holographic grating pattern glass composed of a single-sided pure metal film layer according to the present invention Schematic
图 1 0为本发明单面纯金属膜层组成的全息光栅图案玻璃第四实施例的截 面示意图； 实现本发明的最佳方式 现参见图 1 -4， 这些图示出了本发明单面纯金属膜层组成的全息光栅图案 玻璃的第一实施例。 其中， 平板透明玻璃 1为 5 mm厚的基材。 图 1中白色部分为 透过平板玻璃所看到的银白色金属膜属（ 2 ) 组成的图案， 黑色部分为透过平 板玻璃与透明树脂能看到的正方形光栅上的金属反射膜层组成的图案。 图 3示 出了布满间距为 3 μ πι的正形光栅和黑色下 H浮雕的金属膜层的透明树脂（ 4 ) 下的光栅平面。 图 4中的白色表示其上附着一层白色的 PVC树脂。  FIG. 10 is a schematic cross-sectional view of a fourth embodiment of a holographic grating pattern glass composed of a single-sided pure metal film layer according to the present invention; the best way to implement the present invention is now shown in FIGS. 1-4, which show the single-sided pure metal of the present invention. A first embodiment of a holographic grating pattern glass composed of a metal film layer. The transparent plate 1 is a 5 mm thick substrate. The white part in FIG. 1 is a pattern composed of silver-white metal film (2) seen through the flat glass, and the black part is composed of a metal reflective film layer on a square grating that can be seen through the flat glass and transparent resin. pattern. Figure 3 shows the grating plane under a transparent resin (4) covered with a regular grating with a pitch of 3 μm and a metal film layer embossed with H under black. The white color in Figure 4 indicates that a layer of white PVC resin is attached to it.
正如图 2所示， 本发明第一实施例的单面纯金属膜层的全息光栅玻璃由平 板玻璃 1镀铝金属膜层， 灰色丙烯酸树脂层 4， 夹层透明树脂层 2， 光栅浮雕上 的镀铝金属反射膜层 3以及树脂涂层 8组成。 具体制作过程是： 在平板玻璃 1的 背面镀上一层金属膜层组成的图案 7， 再在金属膜层后面加一层保护树脂 4， 然后用透明粘结剂 2粘上一层带有金属反射层 3的光栅浮雕树脂层 8。  As shown in FIG. 2, the single-sided pure metal film holographic grating glass according to the first embodiment of the present invention is made of flat glass 1 with aluminized metal film layer, gray acrylic resin layer 4, interlayer transparent resin layer 2, and plating on the grating relief. The aluminum metal reflective film layer 3 and the resin coating layer 8 are composed. The specific manufacturing process is as follows: a pattern 7 composed of a metal film layer is plated on the back of the flat glass 1, and a protective resin 4 is added behind the metal film layer, and then a layer of metal is adhered with a transparent adhesive 2 The grating relief resin layer 8 of the reflective layer 3.
其中带有金属反射层 3的光栅浮雕的树脂层 ϋ和透明树脂层 2， 可为如聚碳 酸脂或压敏不干胶树脂或 PVC等热塑性树脂， 也可为诸如丙烯酸， 环氧树脂， 聚胺 密胺脂等交联型分子结构等树脂， 也可为光敏型热固化树脂或热固化 双组分固化树脂。 为方便使用， 也可在带有金属反射层的光栅浮雕树脂层 Ϊ的 背面， 再加一粘合层， 粘结背面玻璃或其它固定板材。 该产品特别适用于装 饰镜面， 作外墙和电梯轿箱贴面等， 以呈现金属膜层和光栅图案的综合效果。  The grating embossed resin layer ϋ and the transparent resin layer 2 with the metal reflective layer 3 may be a thermoplastic resin such as polycarbonate or a pressure-sensitive adhesive resin or PVC, or may be an acrylic, epoxy, poly A resin such as a cross-linked molecular structure such as melamine may be a photosensitive thermosetting resin or a thermosetting two-component curing resin. For convenience, an adhesive layer can also be added to the back of the grating relief resin layer Ϊ with a metal reflective layer to adhere the back glass or other fixed plate. This product is especially suitable for decorating mirror surface, veneering of exterior wall and elevator car, etc., in order to present the comprehensive effect of metal film layer and grating pattern.
现参见图 5至图 8， 说明本发明单面纯金属膜层组成的全息光栅图案玻 璃的第二实施例。  5 to 8, a second embodiment of a holographic grating pattern glass composed of a single-sided pure metal film layer according to the present invention will be described.
正如图 6所示， 本实施例的所述图案玻璃由平板玻璃 1， 透明环氧树脂层 2 ， 带有全息光栅浮雕的镀铝金属膜层 3， 灰色丙稀酸涂层 4， 透明的丙稀酸复合 树脂层 5以及另一平板玻璃 6组成。 图 5示出该制品的正面平面， 其基材为两块 5 mm厚的平板玻璃， 上面显现出由具有全息光栅浮雕的纯金属膜层与透明夹胶 玻璃组成的图案， 黑色部分表示夹胶玻璃中具有全息光栅浮雕的纯金厲膜层， 白色部分表示透明夹胶玻璃。 图 7为上述具有全息光栅浮雕的纯金厲膜层的平 面放大示意图， 与图 3—样， 其正形光栅间距为 3 μ m， 黑色表示下凹浮雕。 图 8 为本实施例制品的背面平面图， 其中白色部分为透明的夹胶玻璃， 该图黑色部 分显现了在该夹胶坡璃中间的浅灰色树脂层。 As shown in FIG. 6, the pattern glass in this embodiment is composed of flat glass 1, transparent epoxy resin layer 2, aluminized metal film layer 3 with holographic grating relief, gray acrylic acid coating 4, and transparent acrylic glass. The dilute acid composite resin layer 5 is composed of another flat glass 6. Figure 5 shows the front surface of the product. The base material is two 5 mm- thick flat glass plates. A pattern consisting of a pure metal film with a holographic grating relief and transparent laminated glass appears on it. The black part indicates the laminated glass. The glass has a pure gold film with holographic grating relief, and the white part indicates transparent laminated glass. FIG. 7 is an enlarged schematic plan view of the pure gold film layer with the holographic grating relief, as in FIG. 3, with a regular grating pitch of 3 μm, and black indicates a concave relief. Figure 8 This is a rear plan view of the product of this embodiment, in which the white part is transparent laminated glass, and the black part of the figure shows a light gray resin layer in the middle of the laminated glass.
本实施例产品的制作过程是： 在平板玻璃 1上粘接一层由一定图案组成的 带有全息或光栅浮雕的透明树脂层 2 , 然后在该树脂的光栅浮雕上面镀一层金 属反射膜层 3 , 再在该光栅浮雕的金厲膜层上涂一层不透明而带任意色彩的树 脂层 4， 然后用另一树脂层 5将其与另一块平板坡璃 6粘接在一起， 再经夹胶玻 璃的常规加热加压工艺， 排出夹层中的气泡， 即制成一面为金属膜层的光栅与 透明夹层玻璃组成的图案， 另一面为其他色彩的不透明树脂与透明夹层玻璃组 成的制品。  The production process of the product of this embodiment is as follows: a transparent resin layer 2 with a holographic or grating relief composed of a certain pattern is bonded to the flat glass 1, and then a metal reflective film layer is plated on the resin grating relief. 3. Then apply an opaque resin layer 4 with any color on the embossed gold film layer of the grating, and then use another resin layer 5 to bond it with another flat glass 6 and then clamp it. The conventional heating and pressurizing process of colloidal glass eliminates the air bubbles in the interlayer, that is, a pattern composed of a grating with a metal film layer and transparent laminated glass on one side is made, and the other side is a product composed of opaque resin and transparent laminated glass of other colors.
现结合图 兌明本发明第三实施例的单面纯金属膜层组成的全息光栅图案 玻璃。 正如该图所示， 本实施例制品由平板玻璃 1， 可透视的金属膜层 7 ( 如反 射率为 30 °/。的铝） ， 透明树脂层 2， 带有全息光栅浮雕的金属（ 如铝） 膜层 3， 丙稀酸（ 如灰色） 涂层 4， 透明复合树脂层 5， 平板玻璃 6组成。  The holographic grating pattern glass composed of the single-sided pure metal film layer according to the third embodiment of the present invention will now be described with reference to the drawings. As shown in the figure, the product of this embodiment is made of flat glass 1, a transparent metal film layer 7 (such as aluminum with a reflectivity of 30 ° / °), a transparent resin layer 2, and a metal with a holographic grating relief (such as aluminum). ) Film layer 3, acrylic acid (such as gray) coating 4, transparent composite resin layer 5, flat glass 6.
本实施例产品的制作过程是： 在平板玻璃 1上镀以反射率为 1 0 % - ! 1 (1 %的 金属膜层 7， 再在其上粘结一层由一定图案组成的带有光栅浮雕的透明树脂层 2 ， 然后在光栅浮雕上镀一层金厲反射膜层 3， 此后在该金属反射膜上涂一层不 透明的带色树脂层 4， 再将另一透明树脂层 5放在其与另一块平板坡璃 6中间， 使之粘接在一起， 并经夹胶玻璃的常规加热加压工艺排出夹层中的气泡， 便得 到一面显现出可透光的平面反射金属膜后的金属膜光栅组成的图案， 而另一面 为树脂层与可透光的夹层反射金属膜层组成的图案的本发明制品。  The production process of the product of this embodiment is: plating the flat glass 1 with a reflectance of 10%-! 1 (1% of a metal film layer 7 and then bonding a layer of grating with a certain pattern on it An embossed transparent resin layer 2, and then a gold reflective film layer 3 is plated on the grating relief, and then an opaque colored resin layer 4 is coated on the metal reflective film, and another transparent resin layer 5 is placed on It is bonded with another flat slope glass 6 and the air bubbles in the interlayer are discharged through the conventional heating and pressing process of laminated glass to obtain a metal with a light-transmitting flat reflective metal film on one side. The product of the present invention is a pattern composed of a film grating, and the other side is a pattern composed of a resin layer and a light-transmissive interlayer reflective metal film layer.
现参见图 1 0 , 说明本发明第四实施例的单面纯金属膜层组成的全息光栅图 案玻璃制品。 由该图可见， 本例制品由平板玻璃 1， 透明环氧树脂层 2， 带有全 息光栅浮雕的金厲铝铝膜， 灰色的丙稀酸涂层 4， 无色透明的树脂层 5， 反射率 为 30 %的镀铝金属膜层 6， 平板玻璃 7组成。  10, a holographic grating pattern glass product composed of a single-sided pure metal film layer according to a fourth embodiment of the present invention will be described. As can be seen from the figure, the product of this example is made of flat glass 1, transparent epoxy layer 2, gold-aluminum aluminum film with holographic grating relief, gray acrylic coating 4, colorless and transparent resin layer 5, reflection It is composed of an aluminized metal film layer 6 and a flat glass 7 with a rate of 30%.
本例产品的制作过程除了因结构不同引起的工艺次序不同以外（ 见图 1 0， 9 ) ， 与本发明实施例 3的制作过程完全相同， 故不在此重复。 本例制成的光栅 制品正面可显现透光的金属膜层与金属光栅反射膜层所组成的图案， 背面呈普 通热反 M玻璃效果。 工业应用性 按本发明第一目的提供的产品可装饰镜面； 可作各种建筑物外墙， 可作各 种电梯轿箱内的贴面材料； 按本发明第二目的提供的产品可作居室， 办公室的 幕墙贴面， 并可用来作各种建筑物的窗玻璃； 按本发明第三目的提供的产品可 作各种建筑物的窗玻璃及幕墙玻璃； 按本发明第四目的所提供的产品可作各种 建筑物的外墙贴面； 办公室或居室的隔断。 总之， 本发明产品可应用于建筑装 饰行业。 The manufacturing process of the product of this example is the same as the manufacturing process of Embodiment 3 of the present invention except that the process sequence is different due to different structures (see Figures 10 and 9), so it is not repeated here. The pattern of the grating product made in this example can show a pattern composed of a light-transmitting metal film layer and a metal grating reflection film layer on the front side, and the back side has the effect of ordinary thermally reflective M glass. Industrial applicability The product provided according to the first object of the present invention can decorate a mirror surface; can be used as various building exterior walls, can be used as various A veneer material in an elevator car; a product provided according to the second object of the present invention can be used as a veneer for a living room, an office curtain wall, and can be used as a window glass of various buildings; a product provided according to the third object of the present invention It can be used as window glass and curtain wall glass of various buildings; the products provided according to the fourth object of the present invention can be used as exterior wall veneers of various buildings; partitions of offices or living rooms. In short, the product of the present invention can be applied to the building decoration industry.
以上虽已对本发明诸最佳实施例作了描述， 但这仅为说明起见， 而并非对 本发明的限制。 事实上， 本领域的技术人员还可能对上述诸例作出未脱离本发 明精神和范围的种种变动或改型。 例如上述诸实施例中的平板玻璃（ 1， 6 ) 可 为无色， 或兰、 茶、 绿、 灰等任何色彩的， 也可为强化玻璃或夹有红， 黄等色 彩的树脂膜的夹胶安全玻璃。 又如在本发明第二实施例的平板玻璃（ 1 ) 与带 有全息或光栅浮雕的透明树脂层（ 2 ) 之间和 /或在另一平板玻璃（ 6 ) 与所述 夹在其与所述不透明树脂层 4中间的树脂层 5之间还可加一层 PYB树脂层。 因此， 本发明保护范围由权利要求书来确定。  Although the preferred embodiments of the present invention have been described above, this is only for the purpose of illustration and is not a limitation on the present invention. In fact, those skilled in the art may also make various changes or modifications to the above examples without departing from the spirit and scope of the present invention. For example, the flat glass (1, 6) in the above embodiments may be colorless, or any color such as blue, tea, green, gray, etc., or may be reinforced glass or a resin film sandwiched with red, yellow, or other color resin films. Glue safety glass. Another example is between the flat glass (1) of the second embodiment of the present invention and the transparent resin layer (2) with holographic or grating relief and / or between another flat glass (6) and said sandwiched between it and A PYB resin layer may be further added between the resin layers 5 in the middle of the opaque resin layer 4. Therefore, the protection scope of the present invention is determined by the claims.

Claims

94/25409 7 - 单面纯金属膜层的全息光栅图案玻璃 权 利 要 求 书 94/25409 7-Single-sided holographic grating pattern glass with pure metal film claims
1 .一种单面纯金厲膜层的全息光栅图案玻璃， 其结构包括： What is claimed is: 1. A holographic grating pattern glass with a single-sided pure gold film layer, the structure comprising:
透明平扳玻璃（1 ) ;  Transparent flat glass (1);
涂敷在该透明玻璃板上的有一定图案的金属膜层（ υ ；  A patterned metal film layer (υ) coated on the transparent glass plate;
涂敷在该金厲膜层上的树脂背衬层（ 4 ) ；  A resin backing layer (4) coated on the gold film layer;
在平扳玻璃背面及该树脂背衬层上用于粘合的透明树脂层（ 2) ； 该透明粘合树脂层背面的带有光栅浮雕金属膜层（ 3 ) 的树脂层（ 8 ) 。  A transparent resin layer (2) for bonding on the back of the flat glass and the resin backing layer; a resin layer (8) with a grating relief metal film layer (3) on the back of the transparent adhesive resin layer.
2 ·根据权利要求 1所述的单面纯金属膜层的全息光栅图案坡璃， 其特征在 所述透明平板玻璃（ 1 ) 为着有兰、 茶、 灰或绿等色彩的玻璃。 2. The holographic grating pattern sloping glass with a single-sided pure metal film layer according to claim 1, wherein the transparent flat glass (1) is glass having a color such as blue, tea, gray, or green.
3.根据杈利要求 1所述的单面纯金属膜层的全息光栅图案坡璃， 其特征在 所述透明平板玻璃为夹有带色树脂膜的夹胶安全玻璃。  3. The single-sided pure metal film layer holographic grating pattern slope glass according to claim 1, wherein the transparent flat glass is a laminated safety glass with a colored resin film sandwiched therebetween.
4.根据杈利要求 1所述的单面纯金属膜层的全息光栅图案玻璃， 其特征在 所述透明平板琥璃为强化玻璃。 ·  4. The holographic grating pattern glass with a single-sided pure metal film layer according to claim 1, wherein the transparent flat glass is a strengthened glass. ·
5.根据权利要求 1的单面纯金属膜层的全息光栅图案玻璃， 其特征在于： 所述带有光栅浮雕金属膜层（ 3 ) 的树脂层（ 8 ) 和所述透明树脂层（ 2) 是热 塑性树脂或交联型分子结构的树脂。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 1, characterized in that: said resin layer (8) with said grating relief metal film layer (3) and said transparent resin layer (2) It is a thermoplastic resin or a resin with a crosslinked molecular structure.
δ .根据权利要求 5的单面纯金属膜层的全息光栅图案坡璃， 其特征在于所 · 述热塑性树脂为聚碳酸脂， 或压敏不干胶树脂或 PJ.C树脂。  δ. The holographic grating pattern sloping glass with a single-sided pure metal film layer according to claim 5, characterized in that said thermoplastic resin is polycarbonate, or pressure-sensitive adhesive resin or PJ.C resin.
7.根据权利要求 5的单面纯金厲膜层的全息光栅图案玻璃， 其特征在于所 述交联型分子结构的树脂为丙烯酸， 环氧树脂,聚胺脂， 或密胺脂。  The holographic grating pattern glass with a single-sided pure gold film layer according to claim 5, characterized in that the resin of the cross-linked molecular structure is acrylic, epoxy, polyurethane, or melamine.
根据杈利要求 1的单面纯金属膜层的全息光栅图案玟璃， 其特征在于： 所述带有光栅浮雕金厲膜层（ 3 ) 的树脂层（ 8 ) 和透明树脂层（ 2 ) 是光敏型 热固化树脂或热固化双组分固化树脂。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 1 is characterized in that: the resin layer (8) and the transparent resin layer (2) with the grating relief gold film layer (3) are Photosensitive thermosetting resin or thermosetting two-component curing resin.
9.根据权利要求 1的单面纯金属膜层的全息光栅图案玻璃， 其特征在于： 所述带有光栅浮雕金属膜层的树脂层（ 8 ) 的背面又加一粘合层并粘合一块 ¾ 璃或其他固态板材。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 1, characterized in that: an adhesive layer is added to the back of the resin layer (8) with the grating relief metal film layer and a piece is bonded ¾ glass or other solid sheet.
10.一种单面纯金属膜层的全息光栅图案玻璃， 其结构包括：  10. A holographic grating pattern glass with a single-sided pure metal film layer, the structure comprising:
平扳玻璃（ 1 ) ；  Level the glass (1);
粘在该平板玻璃上， 由一定图案组成的带有全息或光栅浮雕的透明树脂层 94/25409 一 8 一 A transparent resin layer with a holographic or grating relief composed of a certain pattern adhered to the flat glass 94/25409 One 8 One
( 2) ；  ( 2) ;
镀在该光栅浮雕树脂层（ 2) 上的金厲膜层（ 3) ； A gold film layer (3) plated on the grating relief resin layer ( 2 );
涂布在该光栅浮雕金属膜层上的不透明带色树脂层（ υ ；  An opaque colored resin layer (υ) coated on the grating relief metal film layer;
另一平板玻璃（ 6) ；  Another plate glass (6);
夹在该不透明树脂层（ 4) 和另一平板玻璃（ 6) 中间的透明树脂层（ S) 。 A transparent resin layer (S) sandwiched between the opaque resin layer (4) and another plate glass (6).
11.根据权利要求 7所述单面纯金属膜层的全息光栅图案玻璃， 其特征在于 所述平板玻璃（ 1， 6) 为无色透明的或带任何色彩的透明玻璃。 The holographic grating pattern glass with a single-sided pure metal film layer according to claim 7, characterized in that the flat glass (1, 6) is colorless transparent or transparent glass with any color.
12.根据权利要求 7所述的单面纯金属膜层的全息光栅图案玻璃， 其特征在 于所述平板玻璃（ 1， 6) 为夹有带任何色彩的树脂膜的夹胶安全玻璃。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 7, characterized in that the flat glass (1, 6) is a laminated safety glass sandwiched with a resin film with any color.
13.根据权利要求 7所述的单面纯金属膜层的全息光栅图案玻璃， 其特征在 于还包括镀在所述一块平板玻璃（ 1) 上的一层金属膜层（ 7) ， 该金属膜层 ( 7) 的反射率为 1(Ι%— %， 而且所述平板坡璃（ 1， 6) 为无色或带有任何 色彩的玻璃。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 7, further comprising a metal film layer (7) plated on the piece of flat glass (1), the metal film The reflectance of the layer (7) is 1 (1-1%), and the flat glass (1, 6) is colorless or glass with any color.
Η.根据杈利要求 7所述的单面纯金厲膜层的全息光栅图案玻璃， 其特征在 于还包括镀在所述一块平板玻璃（ 1) 上的金属膜层（ 7) ， 该金属膜层的反射 率为 1()%- %， 而所述平板玻璃（ 1， 6) 为夹有任何色彩树脂膜的夹胶安全 玻璃， 或强化玻璃。  Η. The holographic grating pattern glass with a single-sided pure gold film layer according to claim 7, further comprising a metal film layer (7) plated on the piece of flat glass (1), the metal film The reflectivity of the layer is 1 ()%-%, and the flat glass (1, 6) is a laminated safety glass or a tempered glass sandwiched with any color resin film.
15.根据权利要求 7所述的单面纯金属膜层的全息光栅图案玻璃， 其特征在 于还包括所述另一平板玻璃（ 6) 上的一层金属膜层（ 7) ， 该金属膜层的反射 率为 10 %- 70%; 而且两块平板玻璃（ 1， 6) 是无色或带任何色彩的玻璃。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 7, further comprising a metal film layer (7) on the other flat glass (6), the metal film layer The reflectivity is 10% -70%; and the two flat glasses (1, 6) are colorless or any color glass.
16.根据权利要求 7所述的单面绝金属膜层的全息光栅图案玻璃， 其特征在 于还包括所述另一平板玻璃（ 6) 上的一层金属膜层（ 7) ， 该金属膜层的反射 率为 1Q %- 91) %; 而且两块平板玻璃为强化玻璃或为带有任何色彩的树脂膜的 夹膜安全玻璃。  16. The holographic grating pattern glass with a single-sided metal-insulated film layer according to claim 7, further comprising a metal film layer (7) on the other flat glass (6), the metal film layer The reflectivity is 1Q% -91)%; and the two flat glasses are tempered glass or laminated safety glass with resin film with any color.
17.根据权利要求 7所述的单面纯金属膜层的全息光栅图案玻璃， 其特征在 于： 所述透明树脂（ 2， 5) 为无色透明树脂或黄， 红， 兰， 绿、 灰等任何色彩 的透明树脂。  The holographic grating pattern glass with a single-sided pure metal film layer according to claim 7, wherein the transparent resin (2, 5) is a colorless transparent resin or yellow, red, blue, green, gray, etc. Transparent resin of any color.
1Γ根据权利要求 7所述的单面纯金厲膜层的全息光栅图案玻璃， 其特征在 于： 所述平板玻璃（ 1， 6) 的正面或背面， 制有深度立体雕花， 平雕花， 或平 磨砂图案， 与全息光栅浮雕上金厲膜层组成的各种图案相配合。  1Γ The holographic grating pattern glass with a single-sided pure gold film layer according to claim 7, characterized in that: the front or back of the flat glass (1, 6) is made with deep three-dimensional carving, flat carving, or flat The matte pattern is matched with various patterns composed of a gold film layer on the holographic grating relief.
19.根据权利要求 I。所述的单面纯金厲膜层的全息光栅图案玻璃， 其特征在 于： 在平板玻璃（ 1) 与所述带有全息或光栅浮雕的透明树脂层（ 2) 之间和 / 或在另一平板玻璃（ 6) 与所述夹在其与所述不透明树脂层（ 4) 中间的透明树 脂层（ 5) 之间还加有一层 MS树脂层。 19. According to claim 1. The holographic grating pattern glass with a single-sided pure gold film layer is characterized in that: between a flat glass (1) and the transparent resin layer (2) with a holographic or grating relief and / Or, another MS glass layer is added between another flat glass (6) and the transparent resin layer (5) sandwiched between it and the opaque resin layer (4).
PCT/CN1994/000030 1993-04-30 1994-04-27 Glass having a holographic grating pattern and a single pure metal membrane WO1994025409A1 (en)

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Application Number Priority Date Filing Date Title
CN93105495A CN1094381A (en) 1993-04-30 1993-04-30 The holographic-grating pattern glass of single-side pure metal film
CN93105495.8 1993-04-30

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CN110021226A (en) * 2018-01-08 2019-07-16 北京康得新功能材料有限公司 One kind having anti-fraud functional frosted film, frosted pre-coating film and preparation method thereof

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