WO1994022308A1 - Melange fongicide - Google Patents

Melange fongicide Download PDF

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Publication number
WO1994022308A1
WO1994022308A1 PCT/EP1994/000806 EP9400806W WO9422308A1 WO 1994022308 A1 WO1994022308 A1 WO 1994022308A1 EP 9400806 W EP9400806 W EP 9400806W WO 9422308 A1 WO9422308 A1 WO 9422308A1
Authority
WO
WIPO (PCT)
Prior art keywords
active ingredient
acid
mixture
plants
mixtures
Prior art date
Application number
PCT/EP1994/000806
Other languages
German (de)
English (en)
Inventor
Bernd Mueller
Hubert Sauter
Manfred Hampel
Reinhold Saur
Klaus Schelberger
Eberhard Ammermann
Gisela Lorenz
Original Assignee
Basf Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Aktiengesellschaft filed Critical Basf Aktiengesellschaft
Priority to AU64261/94A priority Critical patent/AU6426194A/en
Publication of WO1994022308A1 publication Critical patent/WO1994022308A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines

Definitions

  • the present invention relates to fungicidal mixtures with a synthetic fungicidal action and to methods for combating fungi with these mixtures.
  • the mixing ratio (weight ratio) of the compounds a) and b) is chosen so that a synergistic fungicidal action occurs, for example compound a): compound b) such as 10: 1 to 1:10, for example 5: 1 to 1 : 5, in particular 3: 1 to 1: 3, preferably 2: 1 to 1: 2.
  • the synergistic effect of the mixture is evident in the fact that the fungicidal action of the mixture a) + b) is greater than the sum of the fungicidal ones Effects of a) and b).
  • the fenpropimorph component can be present in two stereoisomeric forms (morpholine ring), the cis isomer being preferred.
  • the invention includes mixtures which contain the pure isomers of the compound fenpropimorph, in particular the cis isomer, and mixtures which contain mixtures of the isomers.
  • the active ingredient a) can also be in the form of its salts. These mixtures are also encompassed by the invention.
  • Salts are prepared by reaction with acids, for example hydrohalic acids such as hydrofluoric acid, hydrochloric acid, hydrobromic acid or hydroiodic acid or sulfuric acid, phosphoric acid, nitric acid or organic acids such as acetic acid, trifluoroacetic acid, trichloroacetic acid.
  • acetic acid, propionic acid glycolic acid, lactic acid, succinic acid, citric acid, benzoic acid, cinnamic acid, oxalic acid, formic acid, benzenesulfonic acid, p-toluenesulfonic acid, methanesulfonic acid, salicylic acid, p-aminosalicylic acid or 1,2-naphthalenedisulfonic acid.
  • the pure active substances a) and b) are advantageously used, to which further active substances such as insecticides, acaricides, nematicides, herbicides, further fungicides, growth regulators and / or fertilizers can be added.
  • the fungicidal mixtures according to the invention can be, for example, in the form of directly sprayable solutions, powders, suspensions, and also high-strength aqueous, oily or other suspensions or dispersions, emulsions, old dispersions, pastes, dusts, scattering agents or granules by spraying, atomizing, dusting, scattering or Pouring can be applied.
  • the forms of application depend on the purposes of use; in any case, they should ensure the fine distribution of the active compounds according to the invention.
  • the plants are normally sprayed or dusted with the mixtures or the seeds of the plants are treated with the mixtures.
  • the formulations are prepared in a known manner, e.g. by stretching the mixture with solvents and / or carriers, if desired using emulsifiers and dispersants, where in the case of water as diluent other organic solvents can also be used as auxiliary solvents.
  • auxiliaries solvents such as aromatics (eg xylene), chlorinated aromatics (eg chlorobenzenes), paraffins (eg petroleum fractions), alcohols (eg methanol, butanol), ketones (eg cyclohexanone), Amines (eg ethanolamine, dimethylformamide) and water; Carriers such as natural stone powder (e.g.
  • kaolins kaolins, clays, talc, chalk
  • synthetic stone powder e.g. highly disperse silica, silicates
  • Emulsifiers such as non-ionogenic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkyl sulfonates and aryl sulfonates) and dispersants such as lignin sulfite liquors and methyl cellulose.
  • alkali metal, alkaline earth metal and ammonium salts of aromatic sulfonic acids for example lignin, phenol, naphthalene and dibutylnaphthalenesulfonic acid, and of fatty acids, alkyl and alkylarylsulfonates, alkyl, lauryl ether and fatty alcohol sulfates come as surface-active substances , and salts of sulfated hexa-, hepta- and Octadecanols and fatty alcohol glycol ethers, condensation products of sulfonated naphthalene and its derivatives with formaldehyde, condensation products of naphthalene or naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octyl phenol ethers, ethoxylated isooctyl, octyl or nonol phenol, and Tributylphenyl polyglycol ether
  • Powders, materials for broadcasting and dusts can be prepared by mixing or grinding the active substances together with a solid carrier.
  • Granules e.g. Coated, impregnated and homogeneous granules can be produced by binding the active ingredients to solid carriers.
  • Solid carriers are mineral soils such as silica gel, silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bolus, loess, clay, dolomite, diatomaceous earth, calcium and magnesium sulfate, magnesium oxide, ground plastics, fertilizers , such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas and vegetable products, such as cereal flour, tree bark, wood and nutshell flour, cellulose powder or other solid carriers.
  • the mixtures are distinguished by excellent activity against a broad spectrum of phytopathogenic fungi, in particular from the classes of the Ascomycetes and Basidiomycetes. Some of them are systemically effective and can be used as foliar and soil fungicides.
  • the compounds are used by treating the fungi or the seeds, plants, materials or the soil to be protected against fungal attack with a fungicidally effective amount of the mixtures.
  • the mixtures are particularly suitable for combating the following plant diseases:
  • Erysiphe graminis (powdery mildew) in cereals, Erysiphe cichoracearum and Sphaerotheca fuliginea on pumpkin plants,
  • Botrytis cinerea (gray mold) on strawberries, vines,
  • the new mixtures can also be used in material protection (wood protection), e.g. against Paecilomyces variotii.
  • the fungicidal compositions generally contain between 0.1 and 95, preferably between 0.5 and 90% by weight of active ingredient.
  • the application rates of the mixtures according to the invention are between 0.01 and 3 kg of active compound mixture per ha.
  • the values for the fungicidal action fluctuate between the individual tests because the plants have different levels of attack in the individual tests and therefore the numerical values of the fungicidal action also differ. It is therefore only possible to compare the results within the same experiment.
  • E expected efficiency, expressed in% of the untreated control, when using active ingredients A and B in the concentrations of m and n
  • x the efficiency, expressed in% of the untreated control, when using the active ingredient A in a concentration of m
  • y the efficiency, expressed in% of the untreated control, when using the active ingredient B in a concentration of n

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Mélange fongicide constitué de (a) 4-(2-méthyle-3-[4-butylphényle tertiaire]-propyle)-2,6-diméthylmorpholine (fenpropimorphe) ayant la formule (I) ou les principes actifs tridémorphe ou fenpropidine et de (b) 2-[2-(6-(2-cyanophénoxy)-pyrimidin-4-yloxy)-phényl]-3-méthoxy-méthylester d'acide acrylique ayant la formule (II), et procédé de lutte contre des champignons au moyen de ce mélange.
PCT/EP1994/000806 1993-03-26 1994-03-15 Melange fongicide WO1994022308A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU64261/94A AU6426194A (en) 1993-03-26 1994-03-15 Fungicidal mixture

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4309856.8 1993-03-26
DE4309856A DE4309856A1 (de) 1993-03-26 1993-03-26 Fungizide Mischung

Publications (1)

Publication Number Publication Date
WO1994022308A1 true WO1994022308A1 (fr) 1994-10-13

Family

ID=6483928

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/000806 WO1994022308A1 (fr) 1993-03-26 1994-03-15 Melange fongicide

Country Status (4)

Country Link
AU (1) AU6426194A (fr)
DE (1) DE4309856A1 (fr)
IL (1) IL108932A0 (fr)
WO (1) WO1994022308A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006040123A3 (fr) * 2004-10-12 2006-06-29 Bayer Cropscience Ag Combinaisons d'agents fongicides
CN101999375A (zh) * 2010-12-08 2011-04-06 陕西美邦农药有限公司 一种含十三吗啉的杀菌组合物
CN102919243A (zh) * 2012-10-17 2013-02-13 陕西美邦农药有限公司 一种含十三吗啉的杀菌组合物

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11511145A (ja) * 1995-08-17 1999-09-28 ビーエーエスエフ アクチェンゲゼルシャフト 殺菌剤混合物
AU2696697A (en) * 1996-04-26 1997-11-19 Novartis Ag Pesticidal compositions
AU734568B2 (en) * 1996-04-26 2001-06-14 Basf Aktiengesellschaft Fungicidal mixtures
DE19710760A1 (de) * 1997-03-14 1998-09-17 Basf Ag Fungizide Mischung

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2656747A1 (de) * 1976-12-15 1978-06-29 Basf Ag Morpholinderivate
GB2110934A (en) * 1981-11-17 1983-06-29 Ici Plc Fungicidal compositions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2656747A1 (de) * 1976-12-15 1978-06-29 Basf Ag Morpholinderivate
GB2110934A (en) * 1981-11-17 1983-06-29 Ici Plc Fungicidal compositions

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
ANONYMOUS: "Fungicidal mixtures", RESEARCH DISCLOSURE, vol. 229, no. 001, May 1983 (1983-05-01), pages 177 - 179 *
ANONYMOUS: "Mixtures of fungicides and insecticides.", RESEARCH DISCLOSURE, vol. 338, no. 093, June 1992 (1992-06-01), pages 506 - 510 *
BRIGHTON CROP PROT. CONF. PESTS DIS., no. 1, 1992, pages 435 - 442 *
CHEMICAL ABSTRACTS, vol. 118, no. 2, 24 May 1993, Columbus, Ohio, US; abstract no. 207410j, J.R. GODWIN ET AL.: "ICI A5504" *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006040123A3 (fr) * 2004-10-12 2006-06-29 Bayer Cropscience Ag Combinaisons d'agents fongicides
EP2319312A3 (fr) * 2004-10-12 2011-06-08 Bayer CropScience AG Compositions fongicides comprenant fluoxastrobin et un fongicide du type morpholine
CN101999375A (zh) * 2010-12-08 2011-04-06 陕西美邦农药有限公司 一种含十三吗啉的杀菌组合物
CN102919243A (zh) * 2012-10-17 2013-02-13 陕西美邦农药有限公司 一种含十三吗啉的杀菌组合物

Also Published As

Publication number Publication date
AU6426194A (en) 1994-10-24
IL108932A0 (en) 1994-06-24
DE4309856A1 (de) 1994-09-29

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