WO1994016320A1 - Method and equipment for definition of foreign matter contents in gases - Google Patents
Method and equipment for definition of foreign matter contents in gases Download PDFInfo
- Publication number
- WO1994016320A1 WO1994016320A1 PCT/FI1994/000015 FI9400015W WO9416320A1 WO 1994016320 A1 WO1994016320 A1 WO 1994016320A1 FI 9400015 W FI9400015 W FI 9400015W WO 9416320 A1 WO9416320 A1 WO 9416320A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- led
- foreign matter
- cell
- ions
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/0004—Gaseous mixtures, e.g. polluted air
- G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
- G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
- G01N33/0031—General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array
- G01N33/0032—General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array using two or more different physical functioning modes
Definitions
- the invention relates to a method and equipment for defini- tion of foreign matter contents in gas.
- the most sensitive analysis devices are based on air ioniza- tion, e.g. by alpha- or beta radiation and by measuring the ions in different circumstances.
- he ions so formed are put to migrate through a particular abyrinth and the remaining ions are measured based on the ci-irent they cause.
- Another method analyzes the mobility of the formed ions through certain lattices and finally measures the ion current. These two methods generally detect very heavy molecules from the air, like most of the combat gases.
- the ionized molecules are led through chambers having different electric fields, after which the current is detected from the measuring electrodes, by which the quality and quantity of the foreign matter molecules are identified.
- the DE-patent publication 2028805 discloses a method for detecting trace vapors, which undergo ion-molecule reactions and for separating, concentrating and measuring of molecular quantities of trace substances in gaseous samples.
- the detection and measurement is accomplished by utilizing the difference in velocity or drift time of ions of different mass in the electric field applied to the gas stream.
- the electric field causes the primary ions to migrate towards a plurality of ion gates provided rectangular to the gas stream and in parallel between the electrodes, during which the primary ions react with molecules of a gas to be detect- ed, converting the molecules to secondary or product ions, thereby measuring and classifying the ions according to the particular mass.
- the CH-publication 550 399 discloses an air pollution mea- suring equipment comprising a first and a second air capaci ⁇ tor each having a suitable length through which ionized air containing pollution flows laminarily at a constant veloci ⁇ ty.
- the capacitors may have planar or cylindrical electrodes and may comprise two or more electrodes.
- the electrodes of the capacitors are supplied with different voltages.
- the output signals measured via the electrodes of the capacitors are applied to the inputs of dividing and summing circuit means, the output of which provide a final output signal which constitutes a measure of air pollution.
- One of the most important advantages of the invention is that the inaccuracy of the analysis due to gas or air mois ⁇ ture can be eliminated.
- the reliability of the analysis is improved.
- the sensitivity is great and the response time is short.
- Other organic substances or solvents or tobacco smoke do not disturb the foreign matter analysis.
- Fig. 1 presents a diagram of the measuring equipment of the subject invention.
- Fig. 2 presents a diagram of another implementation form of the equipment.
- Fig. 1 presents the equipment according to the invention.
- the gas to be analyzed is sucked into tube 1, filtered with the heatable filter 2 and led into the ionization cell 3, of which can as such be provided several in parallel or in sequence, and which can either be according to the FI patent 75055 or any gas ionization based gas analysis device, whereafter the gas is led to the semiconductor cell, which can be several in parallel or in sequence.
- the semiconductor cell can in the solution be any gas sensor based on the reaction between the semiconductor surface and the gas, which as such is based on the known technique.
- the signals of all measuring cells are utilized simultaneously for the perfor ⁇ mance of the gas analysis for calculations and other conclu ⁇ sions for improved separation of gases from each other in different circumstances.
- the gas is e.g. charged by the radiation transmitted from the alpha- or beta radiation source 4.
- the gas is led to a measuring tube 5.
- the field elec- trodes have the voltage V l V 2 ....V n .
- the back-plate voltage is V ⁇ .
- the light ions charged in the gas are collected into the field electrodes V n .
- the further advanced remaining heavy ions cause an ion current I n to the electrodes in the chamber border, which is registered. From each value I n , in which n is an integer, e.g. 1-6, is formed a diagram, the form of which depicts the substance to be analyzed. Normally the electric field of the ionization cell is stronger in the beginning of the chamber and weaker in the collecting zone.
- the gas is led further to the semiconductor cell 6, formed of e.g. a tin dioxide(Sn0 2 )crystal.
- a sensitive analyzing device can be obtained for different substances, e.g. for mustard gas.
- the signals obtained by the above method and the semiconductor cells are gathered together and analyzed together in e.g. a data processor 7.
- the gas analyzed by the semiconductor cell together is preferably such a gas, which analyzed as moist, does not give a signal with the above mentioned ionization method but only when measured by the semiconductor cell.
- An example of such a gas is the mustard gas.
- the tests for the gas streams having hazardous matter in it have been carried out in different humidities with both the ionization cell and the semiconductor cell mounted sequen ⁇ tially or parallel to each other.
- the relative humidities were 10, 50 and 90 %.
- the gas stream was conducted through the channel by a pump.
- test results show that the presence of the mustard gas will be detected most effectively using the combination of the ionization and semiconductor cell at low concentrations and at all the relative humidities and especially at the moderate or larger humidities.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Analytical Chemistry (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Sampling And Sample Adjustment (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP94904196A EP0679255A1 (en) | 1993-01-12 | 1994-01-12 | Method and equipment for definition of foreign matter contents in gases |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI930122 | 1993-01-12 | ||
FI930122A FI96903C (en) | 1993-01-12 | 1993-01-12 | Method for determining the content of foreign matter in gas and apparatus therefor |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994016320A1 true WO1994016320A1 (en) | 1994-07-21 |
Family
ID=8536692
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FI1994/000015 WO1994016320A1 (en) | 1993-01-12 | 1994-01-12 | Method and equipment for definition of foreign matter contents in gases |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0679255A1 (en) |
CA (1) | CA2153657A1 (en) |
FI (1) | FI96903C (en) |
WO (1) | WO1994016320A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003081224A1 (en) * | 2002-03-25 | 2003-10-02 | Lappeenrannan Teknillinen Yliopisto | A cell structure, device and methods for gas analysis |
DE102005007746A1 (en) * | 2005-02-18 | 2006-08-31 | Dräger Safety AG & Co. KGaA | Ion mobility spectrometer with parallel drift gas and ion carrier gas flow |
EP1724575A1 (en) * | 2005-05-20 | 2006-11-22 | Hitachi, Ltd. | Gas monitoring apparatus |
DE102005031048A1 (en) * | 2005-07-02 | 2007-01-04 | Dräger Safety AG & Co. KGaA | Ion mobility spectrometer uses unidirectional drift with larger dominant drift gas flow before detector electrode in separation area |
DE102007049350A1 (en) | 2007-10-15 | 2009-04-23 | Bruker Daltonik Gmbh | APCI ion source |
DE102008006208A1 (en) | 2008-01-26 | 2009-08-13 | Dräger Safety AG & Co. KGaA | Gas analysis device i.e. ion mobility spectrometer, for detecting smallest concentration of e.g. drug, has dosing unit operable in dilution operation in which dilution ratio of through flow resistance takes finite value different from zero |
DE102008028681A1 (en) * | 2008-06-17 | 2009-12-31 | Airbus Deutschland Gmbh | Method for operating a metal oxide gas sensor, sensor device for carrying out the method and use thereof |
WO2010089375A1 (en) * | 2009-02-06 | 2010-08-12 | Eads Deutschland Gmbh | Sensor device |
WO2011058200A1 (en) | 2009-11-11 | 2011-05-19 | Ramem, S.A. | Differential mobility analyser |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3342230A1 (en) * | 1983-02-21 | 1984-08-23 | Veb Kombinat Robotron, Ddr 8012 Dresden | Detector for testing for gases |
US5047723A (en) * | 1986-06-03 | 1991-09-10 | Pertti Puumalainen | Method for detection of foreign matter contents in gases |
WO1992010751A1 (en) * | 1990-12-06 | 1992-06-25 | Lehmann, Martin | Process for the automatic selection of containers amd measuring device therefor and an installation with such a measuring device |
-
1993
- 1993-01-12 FI FI930122A patent/FI96903C/en not_active IP Right Cessation
-
1994
- 1994-01-12 EP EP94904196A patent/EP0679255A1/en not_active Withdrawn
- 1994-01-12 WO PCT/FI1994/000015 patent/WO1994016320A1/en not_active Application Discontinuation
- 1994-01-12 CA CA 2153657 patent/CA2153657A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3342230A1 (en) * | 1983-02-21 | 1984-08-23 | Veb Kombinat Robotron, Ddr 8012 Dresden | Detector for testing for gases |
US5047723A (en) * | 1986-06-03 | 1991-09-10 | Pertti Puumalainen | Method for detection of foreign matter contents in gases |
WO1992010751A1 (en) * | 1990-12-06 | 1992-06-25 | Lehmann, Martin | Process for the automatic selection of containers amd measuring device therefor and an installation with such a measuring device |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2003216946B2 (en) * | 2002-03-25 | 2009-06-11 | Environics Oy | A cell structure, device and methods for gas analysis |
US7339162B2 (en) | 2002-03-25 | 2008-03-04 | Environics Oy | Cell structure, device and method for gas analysis |
US7586090B2 (en) | 2002-03-25 | 2009-09-08 | Environics Ov | Cell structure, device and method for gas analysis |
WO2003081224A1 (en) * | 2002-03-25 | 2003-10-02 | Lappeenrannan Teknillinen Yliopisto | A cell structure, device and methods for gas analysis |
DE102005007746B4 (en) * | 2005-02-18 | 2009-01-08 | Dräger Safety AG & Co. KGaA | Ion mobility spectrometer with parallel drift gas and ion carrier gas flow |
US7244931B2 (en) | 2005-02-18 | 2007-07-17 | Dräger Safety AG & Co. KGaA | Ion mobility spectrometer with parallel running drift gas and ion carrier gas flows |
DE102005007746A1 (en) * | 2005-02-18 | 2006-08-31 | Dräger Safety AG & Co. KGaA | Ion mobility spectrometer with parallel drift gas and ion carrier gas flow |
US7449685B2 (en) | 2005-05-20 | 2008-11-11 | Hitachi, Ltd. | Gas monitoring apparatus |
EP1724575A1 (en) * | 2005-05-20 | 2006-11-22 | Hitachi, Ltd. | Gas monitoring apparatus |
US7829848B2 (en) | 2005-05-20 | 2010-11-09 | Hitachi, Ltd. | Gas monitoring apparatus |
US7417224B2 (en) | 2005-07-02 | 2008-08-26 | Dräger Saftey AG & Co. KGaA | Ion mobility spectrometer with parallel drift gas and ion carrier gas flows |
DE102005031048A1 (en) * | 2005-07-02 | 2007-01-04 | Dräger Safety AG & Co. KGaA | Ion mobility spectrometer uses unidirectional drift with larger dominant drift gas flow before detector electrode in separation area |
DE102007049350A1 (en) | 2007-10-15 | 2009-04-23 | Bruker Daltonik Gmbh | APCI ion source |
US9214326B2 (en) | 2007-10-15 | 2015-12-15 | Bruker Daltonik Gmbh | Atmospheric pressure chemical ionization ion source |
DE102007049350B4 (en) * | 2007-10-15 | 2011-04-07 | Bruker Daltonik Gmbh | APCI ion source |
DE102008006208B4 (en) * | 2008-01-26 | 2016-05-04 | Dräger Safety AG & Co. KGaA | Device for gas analysis |
DE102008006208A1 (en) | 2008-01-26 | 2009-08-13 | Dräger Safety AG & Co. KGaA | Gas analysis device i.e. ion mobility spectrometer, for detecting smallest concentration of e.g. drug, has dosing unit operable in dilution operation in which dilution ratio of through flow resistance takes finite value different from zero |
DE102008028681A1 (en) * | 2008-06-17 | 2009-12-31 | Airbus Deutschland Gmbh | Method for operating a metal oxide gas sensor, sensor device for carrying out the method and use thereof |
WO2010089375A1 (en) * | 2009-02-06 | 2010-08-12 | Eads Deutschland Gmbh | Sensor device |
WO2011058200A1 (en) | 2009-11-11 | 2011-05-19 | Ramem, S.A. | Differential mobility analyser |
Also Published As
Publication number | Publication date |
---|---|
FI96903C (en) | 1996-09-10 |
FI930122A0 (en) | 1993-01-12 |
FI96903B (en) | 1996-05-31 |
CA2153657A1 (en) | 1994-07-21 |
FI930122A (en) | 1994-07-13 |
EP0679255A1 (en) | 1995-11-02 |
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