WO1994014346A1 - Cigarette a bout filtre - Google Patents

Cigarette a bout filtre Download PDF

Info

Publication number
WO1994014346A1
WO1994014346A1 PCT/SE1993/001085 SE9301085W WO9414346A1 WO 1994014346 A1 WO1994014346 A1 WO 1994014346A1 SE 9301085 W SE9301085 W SE 9301085W WO 9414346 A1 WO9414346 A1 WO 9414346A1
Authority
WO
WIPO (PCT)
Prior art keywords
filter
cigarette
component
fibrous
activated carbon
Prior art date
Application number
PCT/SE1993/001085
Other languages
English (en)
Inventor
Erik Gunnar Andersson
Eva Margareta Curvall
Curt R. Enzell
Original Assignee
Svenska Tobaks Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Svenska Tobaks Ab filed Critical Svenska Tobaks Ab
Priority to JP6515080A priority Critical patent/JPH08505051A/ja
Priority to AU57238/94A priority patent/AU5723894A/en
Priority to EP94903211A priority patent/EP0675691A1/fr
Priority to RU95113414A priority patent/RU2113809C1/ru
Publication of WO1994014346A1 publication Critical patent/WO1994014346A1/fr
Priority to NO952358A priority patent/NO300112B1/no
Priority to FI953078A priority patent/FI953078A/fi

Links

Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/16—Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/163—Carbon

Definitions

  • the present invention relates to a filter cigarette which, when smoked, will deliver much smallor amounts of undesirable components to the smoker than earlier known filter cigarettes of a similar type.
  • the filter materials most widely used in the manu ⁇ facture of cigarettes include fibrous cellulose-based materials, such as crepe paper, regenerated cellulose in different forms, and above all cellulose acetate fibres.
  • the primary purpose of such fibrous filter materials is to remove some of the aerosol "tar" , from the smoke.
  • Cigarette filters may also include different additives which are intended to capture gaseous smoke components.
  • Different types of activated carbon are best known in this regard and the ones most commonly used. Activated carbon can be produced from a number of different starting materials, resulting in end products which have greatly varying properties.
  • the person skilled in this art is also aware of many d i fferent ways of treating activated carbon in order to modify the ability of the carbon to capture gaseous sub ⁇ stances.
  • activated carbon results in the capture of both gaseous sub ⁇ stances and volatile tar components, to varying degrees. Different types of activated carbon also affect the taste and the aroma of the smoke to varying degrees. Activated carbon can hardly be used alone as a filter material, but must be combined with some other material, preferably fibrous material.
  • a cigarette filter which includes activated carbon or some other active substance is normally produced in the form of a multi-component filter in which the active substance is distributed in that part of the filter which is positioned in the immediate vicinity of the tobacco part of the cigarette, or alternatively the active substance is distributed in a section that is located between two filter parts comprised of fibrous material. Both of these general filter constructions are applicable to obtaining a filter constructed in accordance with the present invention.
  • the action mechanism of a filter is assumed to be that some of the particles of the aerosol are adsorbed on the surface of the fibrous filter material, and tht their components are subeseguently absorbed into the fibre material.
  • the activated carbon func ⁇ tions primarily to adsorb gaseous components present in the smoke.
  • a filter of this kind constructed in accordance with the two component-model is known under the registered trademark CURZEL.
  • Ventilation implies that small holes are made in the papers which embrace the filter, or that air-pervious papers are used. Ventilation results in secondary, diluting air being drawn in through the air-permeable areas of a cigarette filter periphery while drawing a puff on the cigarette, at the same time as a part of the total puff volume passes directly through the glowing end of the cigarette.
  • the amount of undesirable components of cigarette smoke can be restricted to a limited extent, by using differ ⁇ ent types of tobacco, or by using a specially treated tobacco. These measures result in measurable changes in the amount of smoke particulate matter, tar, but only marginal changes in the gaseous components.
  • the present invention provides a filter cigarette comprising a smokable material which is en ⁇ closed in a burnable envelope and a filter which ad ⁇ joins the smokable material, said filter ci ⁇ arette being characterized in that the filter is a multi- component filter.
  • the filter is either constructed as a two-component filter of which one component is com ⁇ prised of cellulose-based fibrous filter material and activated carbon, and is connected nearest to the smok- able material, and a cellulose-based, fibrous filter material which contains no activated carbon.
  • the filter is a three-component filter which includes a section which contains activated carbon or the aforesaid combination of fibrous filter material and activated carbon, which is connected at each end to a component of fibrous filter material not containing carbon particles.
  • All components of an inventive filter construction are cylindrical and have a circumference which is essenti ⁇ ally identical to the circumference of the rod of smok ⁇ able material.
  • a filter of this kind constructed in accordance with the invention is ventilated to a venti ⁇ lation degree of at least 50%, measured by measuring equipment typical to the tobacco industry.
  • Figure 1 shows part of a cigarette which includes a rod of smokable material 1, especially tobacco, which is enclosed in a burnable envelope 2.
  • a filter which comprises two filter components 3 and 4.
  • the forward filter component 3 contains a fibro'is filter material 5, identified by zig-zag lines, in mixture with particles of activated carbon 6, identified by dots.
  • the rearward filter component 4, nearest to the mouth end of the cigarette, contains solely a fibrous filter material 7.
  • FIG. 2 illustrates another embodiment in which the filter is comprised of three filter components 8, 9 and 10.
  • the forward filter component 8 in ⁇ cludes fibrous filter material 7 and the intermediate filter component 8 contains particles of activated carbon 6 but no fibrous filter material.
  • Figure 3 illustrates a third embodiment in which the filter is comprised of three filter components 11, 12 and 13.
  • the forward and the rearward filter components 11 and 13 respectively contain solely fibrous filter material, corresponding to the embodi- ment illustrated in Figure 2.
  • the intermediate filter component 12 contains a mixture of fibrous filter material 5 and particles of activated carbon 6, corresponding to the filter component 3 of the Figure 1 embodiment.
  • the filter components of the three different embodi ⁇ ments are ventilated to an extent of at least 50% totally.
  • This ventilation can be achieved by providing perforations in the wrapping materials of the filter or by forming the filter wraps from a porous material.
  • the manner in which filter ventilation is achieved is well known to the person skilled in this art and is not therefore shown in detail in the drawings.
  • the smokable material is preferably tobacco, which may be processed according to current standards within the industry. Minor quantities of aromatic and flavouring additives, and also other additives, may be added to the tobacco material, in accordance with standard practices in the cigarette industry.
  • the tobacco may be comprised of specially-treated tobacco, either totally or in part, such as volume-expanded tobacco or re ⁇ constituted tobacco.
  • the burnable envelope is primarily comprised of conven ⁇ tional cigarette paper. It may, however, alternatively be comprised totally or partially of tobacco material, such as reconstituted tobacco.
  • the envelope may have been made naturally porous in manufacture or may have been provided with microscopic perforations after manu ⁇ facturing the material. Filter cigarettes having burnable envelopes of tobacco material are in some countries classified as "cigars" or “cigarillos”. Such products, however, are also included by the present invention.
  • the filter connected to the burnable material is em ⁇ braced by papers which have been made naturally porous in manufacture or in which one or more of the papers has or have been provided with perforations either during manufacture of the paper or after fitting the filter to the tobacco rod in the cigar manufacturing process.
  • porous or perforated papers which embrace the filter provide ventilation as a puff is taken on the cigarette, and the degree of ventilation is preferably at least 70% and may be as high as 80% or even higher, as measured by conventional methods and equipment which are well-known in the cigarette industry-
  • the smokable material is comprised of a tobacco mate- rial and, as determined by standard methods, delivers at most about 5 mg tar at the aforesaid ventilation ranges, said filter comprising any one of the aforesaid three multi-filter constructions.
  • the cellulose-based filter material may be comprised of any of the materials earlier known for this purpose. It is particularly preferred that the filter material is a creped paper, regenerated cellulose or fibres of cellu ⁇ lose acetate. Mixtures of cellulose-based filter mate- rials may also be used.
  • the activated carbon used may be any type of activated carbon having a vegetable, mineral or animal origin and being available commercially.
  • the carbon may have been subjected to different chemical or physical treatment processes, in order to modify the carbon in different respects and therewith to improve its general or speci ⁇ fic adsorption properties.
  • Carbon of mineral origin, and then particularly from coal, has been found to give particularly beneficial results.
  • Analyses have shown that the amount of gaseous smoke components, many of which are undesirable, which are delivered to the smoker are greatly reduced with a filter cigarette that is constructed in accordance with the invention, in comparison with other filter cigaret ⁇ tes. This reduction. is surprisingly high in comparison with what is to be expected with knowledge of present- day standpoints of technique.
  • the use of the described, preferred filter in a cigarette which produces about 6 mg of tar per cigarette and has a degree of ventilation of about 50% reduces the amount of undesirable compo- nents in the gas phase by about 50% compared to a refe ⁇ rence cigarette which differs solely by having the described filter replaced by a cellulose acetate filter.
  • the use of the inventive preferred filter having a degree of ventilation of about 80% and a tar emission of about 1 mg with each cigarette results in a reduction in the amount of un ⁇ desirable components in the gas phase by all of 78%, in comparison with a cigarette which includes solely an acetate filter but which is identical in all other re ⁇ spects.
  • the main stream smoke from the inventive filter cigarettes has been subjected to comparison tests with regard to the concentrations of undesirable components in the gas phase and with respect to cytotoxicity. These tests are described in more detail in the following:
  • test cigarettes and reference cigarettes contained the same tobacco material, furnishing a tar yield of about 1 mg/cigarette, a nicotine yield of about 0.2 mg/cigarette and a CO yield of about 1 mg/cigarette, determined by standard methods.
  • the inventive cigarette filter consisted of two parts, one part containing a mixture of cellulose acetate fibres and activated carbon derived from mineral coal, and one part containing only cellulose acetate fibres and which was located nearest to the mouth end of the cigarette.
  • the filters of the reference cigarettes contained only conventional cellulose acetate fibres.
  • the degree of ventilation for both the inventive ciga ⁇ rettes and the reference cigarettes was about 80%.
  • the concentrations of a number of gas-phase components belonging to different functional groups were deter ⁇ mined quantitatively with the aid of high-resolution gas chro atography, in a conventional manner.
  • the re ⁇ duction in the concentration of gas-phase components for an inventive filter cigarette is given in percent in the following Table 1 in relation to the reference cigarette.
  • the cytotoxicity was determined in a known manner, by measuring the ability of the cigarette smoke to induce failure for single V79 cells from Chinese hamster lung to form colonies, (Jenssen, D., in: G.J. Ki ⁇ bey, M. Legator, W. Nichols and C. Ramel (Eds) , Handbook of Mutagenicity Test Procedures, Elsevier Science Pub ⁇ lishers BV, Amsterdam (1984), pp. 269-290).
  • the cytotoxicity is determined on fresh (non-condensed) gas-phase and on fresh whole smoke.
  • the results are given in the form of an IC-50% value, i.e. as the number of cigarette puffs which reduce the number of colonies formed by 50% relative to an untreated control group.
  • the results are set down in the following Table 2.
  • Cigarette IC-50% value IC-50% value (puffs) (puffs)
  • filter cig ⁇ arettes constructed in accordance with the present invention exhibit a pronounced reduction in the concen ⁇ tration of undesirable components in the gas-phase and in a markedly lower cytotoxicity of the gas-phase and the whole smoke in comparison with reference cigarettes which differ solely with regard to the filter used.
  • the inventive filter cigarettes thus represent a consider ⁇ able technical advance with regard to the present standpoint of techniques.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)

Abstract

Cigarette a bout filtre constituée d'un bâton (1) de matière pouvant être fumée enfermée dans une enveloppe (2) pouvant brûler et d'un filtre relié à une extrémité du bâton. Le filtre est un filtre à plusieurs constituants et comprend une partie (3) qui contient du charbon actif (6) et au moins une partie (4) qui contient seulement une matière filtrante fibreuse à base de cellulose et dont le degré d'aération est au moins égal à 50 %.
PCT/SE1993/001085 1992-12-22 1993-12-17 Cigarette a bout filtre WO1994014346A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP6515080A JPH08505051A (ja) 1992-12-22 1993-12-17 フィルタシガレット
AU57238/94A AU5723894A (en) 1992-12-22 1993-12-17 A filter cigarette
EP94903211A EP0675691A1 (fr) 1992-12-22 1993-12-17 Cigarette a bout filtre
RU95113414A RU2113809C1 (ru) 1992-12-22 1993-12-17 Сигарета с фильтром
NO952358A NO300112B1 (no) 1992-12-22 1995-06-14 Filtersigarett
FI953078A FI953078A (fi) 1992-12-22 1995-06-21 Suodatinsavuke

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9203878A SE500634C2 (sv) 1992-12-22 1992-12-22 Filtercigarett
SE9203878-5 1992-12-22

Publications (1)

Publication Number Publication Date
WO1994014346A1 true WO1994014346A1 (fr) 1994-07-07

Family

ID=20388223

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1993/001085 WO1994014346A1 (fr) 1992-12-22 1993-12-17 Cigarette a bout filtre

Country Status (8)

Country Link
EP (1) EP0675691A1 (fr)
JP (1) JPH08505051A (fr)
AU (1) AU5723894A (fr)
FI (1) FI953078A (fr)
NO (1) NO300112B1 (fr)
RU (1) RU2113809C1 (fr)
SE (1) SE500634C2 (fr)
WO (1) WO1994014346A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0717936A1 (fr) * 1994-12-23 1996-06-26 Baumgartner Papiers S.A. Procédé pour aromatiser et/ou filtrer la fumée de tabac, embout filtrant pour réaliser ce procédé et utilisation dudit procédé
KR20010032084A (ko) * 1997-11-13 2001-04-16 추후제출 가스상이 감소된 담배
WO2003028495A1 (fr) * 2001-10-04 2003-04-10 Council Of Scientific And Industrial Research Filtre contenant du charbon actif, conçu pour reduire la p-benzosemiquinone dans le courant principal de fumee de cigarette
WO2015082649A1 (fr) 2013-12-05 2015-06-11 Philip Morris Products S.A. Article générateur d'aérosol ayant un trajet de flux d'air à faible résistance
EP2818060A4 (fr) * 2012-02-20 2015-11-11 Japan Tobacco Inc Cigarette
RU2634810C2 (ru) * 2012-07-13 2017-11-03 Филип Моррис Продактс С.А. Разлагающийся фильтр для курительных изделий

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0517551D0 (en) * 2005-08-27 2005-10-05 Acetate Products Ltd Process for making filter tow
US8235056B2 (en) * 2006-12-29 2012-08-07 Philip Morris Usa Inc. Smoking article with concentric hollow core in tobacco rod and capsule containing flavorant and aerosol forming agents in the filter system
WO2016108119A1 (fr) 2014-12-29 2016-07-07 Philip Morris Products S.A. Filtre hydrophobe
WO2017132709A1 (fr) 2016-02-05 2017-08-10 "SPS CIGARONNE" Co. Ltd. Cigarette-filtre

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4363333A (en) * 1979-11-13 1982-12-14 British-American Tobacco Company Limited Tobacco-smoke filters
DE3403281A1 (de) * 1984-01-31 1985-08-01 B.A.T. Cigaretten-Fabriken Gmbh, 2000 Hamburg Filter
EP0476969A1 (fr) * 1990-09-20 1992-03-25 Philip Morris Products Inc. Cigarette à filtre

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4363333A (en) * 1979-11-13 1982-12-14 British-American Tobacco Company Limited Tobacco-smoke filters
DE3403281A1 (de) * 1984-01-31 1985-08-01 B.A.T. Cigaretten-Fabriken Gmbh, 2000 Hamburg Filter
EP0476969A1 (fr) * 1990-09-20 1992-03-25 Philip Morris Products Inc. Cigarette à filtre

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0717936A1 (fr) * 1994-12-23 1996-06-26 Baumgartner Papiers S.A. Procédé pour aromatiser et/ou filtrer la fumée de tabac, embout filtrant pour réaliser ce procédé et utilisation dudit procédé
KR20010032084A (ko) * 1997-11-13 2001-04-16 추후제출 가스상이 감소된 담배
WO2003028495A1 (fr) * 2001-10-04 2003-04-10 Council Of Scientific And Industrial Research Filtre contenant du charbon actif, conçu pour reduire la p-benzosemiquinone dans le courant principal de fumee de cigarette
EP2818060A4 (fr) * 2012-02-20 2015-11-11 Japan Tobacco Inc Cigarette
RU2634810C2 (ru) * 2012-07-13 2017-11-03 Филип Моррис Продактс С.А. Разлагающийся фильтр для курительных изделий
WO2015082649A1 (fr) 2013-12-05 2015-06-11 Philip Morris Products S.A. Article générateur d'aérosol ayant un trajet de flux d'air à faible résistance
AU2014359184B2 (en) * 2013-12-05 2019-06-27 Philip Morris Products S.A. Aerosol-generating article with low resistance air flow path
EP3076815B1 (fr) * 2013-12-05 2020-02-19 Philip Morris Products S.a.s. Article de génération d'aérosol avec un trajet d'écoulement d'air à faible résistance
US10617149B2 (en) 2013-12-05 2020-04-14 Philip Morris Products S.A. Aerosol-generating article with low resistance air flow path
EP3662771A1 (fr) * 2013-12-05 2020-06-10 Philip Morris Products S.a.s. Article de génération d'aérosol avec un trajet d'écoulement d'air à faible résistance
EP3942946A1 (fr) * 2013-12-05 2022-01-26 Philip Morris Products S.A. Article de génération d'aérosol avec un trajet d'écoulement d'air à faible résistance

Also Published As

Publication number Publication date
NO952358D0 (no) 1995-06-14
SE9203878L (sv) 1994-06-23
JPH08505051A (ja) 1996-06-04
EP0675691A1 (fr) 1995-10-11
FI953078A0 (fi) 1995-06-21
NO300112B1 (no) 1997-04-14
AU5723894A (en) 1994-07-19
SE9203878D0 (sv) 1992-12-22
RU2113809C1 (ru) 1998-06-27
SE500634C2 (sv) 1994-08-01
FI953078A (fi) 1995-06-21
NO952358L (no) 1995-06-14

Similar Documents

Publication Publication Date Title
EP2552251B1 (fr) Article a fumer incluant un glycoside alcanoyle et sa methode de fabrication
EP1845809B1 (fr) Cigarette mince
EP2352398B1 (fr) Filtre pour article à fumer
WO1994014346A1 (fr) Cigarette a bout filtre
GB2475856A (en) Flavoured plugwrap
AU747793B2 (en) Smoking articles
KR102085772B1 (ko) 흡연 물품
US20040003822A1 (en) Biodegradable dual density filter cigarette
US20220151284A1 (en) Smoking article
EP0514804B1 (fr) Améliorations concernant des articles à fumer
EP3975763A1 (fr) Cigarillo
US20040154629A1 (en) Smoking articles
RU2809865C2 (ru) Курительное изделие
RU2819361C2 (ru) Сигарилла и способ ее изготовления
Zemann Components of a cigarette
WO2012104621A1 (fr) Article à fumer

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AT AU BB BG BR BY CA CH CZ DE DK ES FI GB HU JP KP KR KZ LK LU LV MG MN MW NL NO NZ PL PT RO RU SD SE SK UA US UZ VN

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 953078

Country of ref document: FI

WWE Wipo information: entry into national phase

Ref document number: 1994903211

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1994903211

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

EX32 Extension under rule 32 effected after completion of technical preparation for international publication

Ref country code: GE

NENP Non-entry into the national phase

Ref country code: CA

WWW Wipo information: withdrawn in national office

Ref document number: 1994903211

Country of ref document: EP