WO1994011575A1 - Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage - Google Patents
Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage Download PDFInfo
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- WO1994011575A1 WO1994011575A1 PCT/CA1992/000487 CA9200487W WO9411575A1 WO 1994011575 A1 WO1994011575 A1 WO 1994011575A1 CA 9200487 W CA9200487 W CA 9200487W WO 9411575 A1 WO9411575 A1 WO 9411575A1
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- polyethylene oxide
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- admixed
- aqueous
- naphthalene sulphonate
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/09—Sulfur-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
Definitions
- the present invention relates to a method and a use of naphthalene sulphonate salt(s), under granulated form or as a condensed or diluted solution , and a solution of polyethylene oxide having a molecular weight varying from 1 x 10 6 to 13 x 10 6 , allowing for a mixture comprising lignocellulosic particles and an aqueous medium to significantly improve the retention of particles such as fines and fibres, on a wire screen and the drainage of the aqueous medium.
- a particles retention especially a retention of fines and fibres can be achieved for kraft, sulphite (high and low yield), bisulphite, mechanical, OPCO, BTCMP, TCMP, BCMP, hard wood, such as oak, birch, maple, elm, wild-cherry, soft woods such as conifere trees, and TMP pulps and any mix in any proportion of two or more types of pulp.
- Application may be the followings: - any washer, thickener, save-all, disc filter or drum filter in any pulp making process;
- any clarifier or flotation or fibre separation unit in the effluent treatment process including krofta, posseidon, sedimentation clarifier, but not limited to these;
- polyethylene oxide to improve from a mixture comprising lignocellulosic fines and fibres, and an aqueous medium, a retention of fines and fibres on a wire screen and improve a drainage of the aqueous medium.
- a condensed naththalene sulphonate salt means a solution saturated with said, salt for example a condensed sodium naphthalene sulphonate salt means an aqueous solution containing about 41-46% of said salt.
- the invention relates to an improvement in a method for the production of paper and analogous products.
- This improvement is characterized by the fact that one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from
- 1 x 10 6 to 13 x 10 6 are admixed with a mixture comprising lignocellulosic particles such as fines and fibres, and an aqueous medium, being understood that polyethylene oxide is admixed with said mixture when this latter already contains at least a part of said naphthalene sulphonate salt(s).
- the invention also relates to the use of one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 10 6 to 13 x 10 6 , in admixture with a mixture comprising lignocellulosic particles, such as fines and fibres, and an aqueous medium, to improve a retention of said particles on a wire screen and a drainage of the aqueous medium.
- the naphthalene sulphonate salt(s), especially a sodium naphthalene sulphonate salt is (are) uniformly dispersed in the mixture before introducing one or several polyethylene oxide.
- sodium naphthalene sulphonate should be applied preferably 30 seconds before the salt(s) get(s) in contact with the polyethylene oxide to thus give enough time to the salt to condition particles, such as fines and fibres.
- the admixture of naphthalene sulphonate salt(s) with a mixture of lignocellulosic fines and fibres and aqueous medium may be applied anywhere in the system and advantageously not between fan pumps and a head box. It could have been applied in the white water system (wire pit), mixing tank, in the preparation of clay system or any tank that could be in contact with fibre giving on the machine. Preferably in the mixed pulp tank.
- the polyethylene oxide solution may be applied preferably between the fan pump and the head box, but it is also possible to apply it before the fan pump and remain efficient, like between the mix tank and the fan pump.
- one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 10 6 to 13 x 10 6 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define a pumpable pulp.
- one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 10 6 to 13 x 10 6 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define an aqueous suspension.
- said aqueous suspension is either of the type intended to be laid on a wire screen of a paper machine to form a sheet of paper or of a pulp machine, or of the type defining a white water collected in a wire pit of a paper machine or pulp machine.
- This white water may be partially or totally recycled as an affluent of a step for preparing a pumpable pulp comprising lignocellulosic fines and fibres and an aqueous medium, or passed at least in part with other waste water through a clarifier.
- This white water charged with naphthalene sulphonate salt(s) and polyethylene oxide contribute to make the clarifier more efficient.
- said aqueous suspension is of the type intended to be laid on a wire screen of a paper machine to form a sheet of paper or of pulp machine type, wherein a white water collected in a wire pit of the paper machine or of a pulp machine and essentially consisting of a part of said previous suspension not retained on the wire screen and still containing naphthalene sulphonate salt(s) and polyethylene oxide, is recycled to a step for preparing either a pumpable pulp or a fresh aqueous suspension intended to be laid on aforesaid wire screen, being understood that said recycled white water contributes to the admixture of a part of the sulphonate salt(s) and polyethylene oxide with the mixture.
- an equilibrium is set between the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained on the wire screen and the amount of naphthalene sulphonate salt(s) and polyethylene oxide collected in the white water in the wire pit and recycle to the preparation of either a pumpable pulp or a fresh aqueous suspension intended to be laid on the wire screen, to thus allow to admix to said pulp or fresh aqueous suspension intended to be laid on the wire screen, only the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained in the sheet of paper or in the pulp.
- naphthalene sulphonate salt(s) are selected from the group consisting of sodium, potassium, ammonium, calcium and aluminium salt(s).
- polyethylene oxide has a molecular weight varying from 4,5 x 10 6 to 12 x 10 6 .
- At least one enhancer selected from the group consisting of: - a polyaluminium silicate sulphate;
- polyethylene oxide may be admixed with the mixture of lignocellulosic particles, such as fines and fibres, and an aqueous medium to represent from 10 to 700 grams per ton of dry matter of said mixture, preferably from 30 to 100 grams per ton of dry matter of said mixture.
- a pulp resulting of a blend of 45% of sulphite pulp, 50% of mechanical pulp and 5% of kraft pulp was used.
- the example was carried out without and with a condensed solution of sodium naphthalene sulphonate and a solution of a mix polyethylene oxide having a mean molecular weight ranging between 7 to 8 x 10 6 , according to the invention.
- Figures 1 to 6 show variations of drainage without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide
- Figures 7 to 9 show the sheet strength without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
- Figure 10 shows retention of first press without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
- Figure 11 shows average consistency of wire without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide
- Figure 12 shows head box consistency without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide
- Figure 13 shows dosage of process with polyethylene oxide
- Figure 14 shows dosage of process with sodium naphthalene sulphonate salt
- Figures 15 to 22 show opacity and whiteness without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
- Figure 23 shows a sheet formation without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide
- Figure 24 shows consistencies of white water returns without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide
- Figures 25 and 26 show tonnage of white water transferred without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
- Figure 27 shows fibre losses in sewer without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide; and Figure 28 shows drainage related to temperature without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide.
- Figures 1 to 28 show several variations obtained by using a combined use of a condensed solution of sodium naphthalene sulphonate salt (identified process par 1169) and a solution of a mix of polyethylene oxide having the aforesaid mean molecular weight (identified process PND 1100), in aforesaid example.
- informations appearing at the left of a dark vertical line are without the use of naphthalene sulphonate salt(s) and polyethylene oxide, and information appearing at the right of the dark vertical line are according to the invention.
- TABLE V : OPTIC CHARACTERISTICS
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- Chemical Kinetics & Catalysis (AREA)
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- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
The present invention relates to a method and a use of naphthalene sulphonate salt(s) under granulated form or as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106, allowing for a mixture comprising lignocellulosic particles and an aqueous medium to significantly improve the retention of particles such as fines and fibers, on a wire screen and the drainage of the aqueous medium.
Description
METHOD AND USE INVOLVING NAPHTHALENE SULPHONATE SALT(S) AND
POLYETHYLENE OXIDE, TO IMPROVE RETENTION AND DRAINAGE
The present invention relates to a method and a use of naphthalene sulphonate salt(s), under granulated form or as a condensed or diluted solution , and a solution of polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106, allowing for a mixture comprising lignocellulosic particles and an aqueous medium to significantly improve the retention of particles such as fines and fibres, on a wire screen and the drainage of the aqueous medium.
Advantageously, a particles retention, especially a retention of fines and fibres can be achieved for kraft, sulphite (high and low yield), bisulphite, mechanical, OPCO, BTCMP, TCMP, BCMP, hard wood, such as oak, birch, maple, elm, wild-cherry, soft woods such as conifere trees, and TMP pulps and any mix in any proportion of two or more types of pulp.
Application may be the followings: - any washer, thickener, save-all, disc filter or drum filter in any pulp making process;
any pulp machine, board machine or paper machine in the production sector;
- any clarifier or flotation or fibre separation unit in the effluent treatment process, including krofta, posseidon, sedimentation clarifier, but not limited to these;
any equipment used in the deinking process, included or not above.
Up to now, it was known to use polyethylene oxide to improve from a mixture comprising lignocellulosic fines and fibres, and an aqueous medium, a retention of fines and fibres on a wire screen and improve a drainage of the aqueous medium.
The Applicant has now surprisingly found that a method
involving a combined use of one or several naphthalene sulphonate salt(s), under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106, in admixture with a mixture of lignocellulosic particles and an aqueous medium, allows to improve a retention of said particles on a wire screen and a drainage of said aqueous medium. This combined use shows a synergistic effect. A condensed naththalene sulphonate salt means a solution saturated with said, salt for example a condensed sodium naphthalene sulphonate salt means an aqueous solution containing about 41-46% of said salt.
More particularly, the invention relates to an improvement in a method for the production of paper and analogous products.
This improvement is characterized by the fact that one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from
1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic particles such as fines and fibres, and an aqueous medium, being understood that polyethylene oxide is admixed with said mixture when this latter already contains at least a part of said naphthalene sulphonate salt(s).
The invention also relates to the use of one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106, in admixture with a mixture comprising lignocellulosic particles, such as fines and fibres, and an aqueous medium, to improve a retention of said particles on a wire screen and a drainage of the aqueous medium.
Advantageously, the naphthalene sulphonate salt(s), especially a sodium naphthalene sulphonate salt, is (are) uniformly dispersed in the mixture before introducing one or several polyethylene oxide. Preferably, sodium naphthalene sulphonate should be applied preferably 30 seconds before the salt(s) get(s) in contact with the polyethylene oxide to thus give enough time to the salt to condition particles, such as fines and fibres. Preferably, in a pulp and paper plant, the admixture of naphthalene sulphonate salt(s) with a mixture of lignocellulosic fines and fibres and aqueous medium may be applied anywhere in the system and advantageously not between fan pumps and a head box. It could have been applied in the white water system (wire pit), mixing tank, in the preparation of clay system or any tank that could be in contact with fibre giving on the machine. Preferably in the mixed pulp tank. The polyethylene oxide solution may be applied preferably between the fan pump and the head box, but it is also possible to apply it before the fan pump and remain efficient, like between the mix tank and the fan pump.
Advantageously, one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define a pumpable pulp.
Advantageously, one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or advantageously as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic fines and fibres
and an aqueous medium to define an aqueous suspension.
Advantageously, said aqueous suspension is either of the type intended to be laid on a wire screen of a paper machine to form a sheet of paper or of a pulp machine, or of the type defining a white water collected in a wire pit of a paper machine or pulp machine. This white water may be partially or totally recycled as an affluent of a step for preparing a pumpable pulp comprising lignocellulosic fines and fibres and an aqueous medium, or passed at least in part with other waste water through a clarifier. This white water charged with naphthalene sulphonate salt(s) and polyethylene oxide contribute to make the clarifier more efficient. Advantageously, said aqueous suspension is of the type intended to be laid on a wire screen of a paper machine to form a sheet of paper or of pulp machine type, wherein a white water collected in a wire pit of the paper machine or of a pulp machine and essentially consisting of a part of said previous suspension not retained on the wire screen and still containing naphthalene sulphonate salt(s) and polyethylene oxide, is recycled to a step for preparing either a pumpable pulp or a fresh aqueous suspension intended to be laid on aforesaid wire screen, being understood that said recycled white water contributes to the admixture of a part of the sulphonate salt(s) and polyethylene oxide with the mixture.
Preferably, an equilibrium is set between the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained on the wire screen and the amount of naphthalene sulphonate salt(s) and polyethylene oxide collected in the white water in the wire pit and recycle to the preparation of either a pumpable pulp or a fresh aqueous suspension intended to be laid on the wire screen, to thus allow to admix to said pulp or fresh aqueous suspension intended to be laid on the
wire screen, only the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained in the sheet of paper or in the pulp. Advantageously, naphthalene sulphonate salt(s) are selected from the group consisting of sodium, potassium, ammonium, calcium and aluminium salt(s).
Advantageously, polyethylene oxide has a molecular weight varying from 4,5 x 106 to 12 x 106.
Advantageously, is further admixed to said mixture at least one enhancer selected from the group consisting of: - a polyaluminium silicate sulphate;
- a polyaluminium sulphate;
- a sodium aluminate;
- polyaluminium chloride;
- magnesium hydroxide; and
- bentonite.
Advantageously, polyethylene oxide may be admixed with the mixture of lignocellulosic particles, such as fines and fibres, and an aqueous medium to represent from 10 to 700 grams per ton of dry matter of said mixture, preferably from 30 to 100 grams per ton of dry matter of said mixture.
EXAMPLE
On a paper machine having a capacity of 600 T of newsprint per day (i.e. a paper machine known under the trade name BELBAE 3 - VERTICAL), a pulp resulting of a blend of 45% of sulphite pulp, 50% of mechanical pulp and 5% of kraft pulp was used. The example was carried out without and with a condensed solution of sodium naphthalene sulphonate and a solution of
a mix polyethylene oxide having a mean molecular weight ranging between 7 to 8 x 106, according to the invention.
The present invention will be better understood with reference to the following figures in which:
Figures 1 to 6 show variations of drainage without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figures 7 to 9 show the sheet strength without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide; Figure 10 shows retention of first press without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figure 11 shows average consistency of wire without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figure 12 shows head box consistency without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figure 13 shows dosage of process with polyethylene oxide;
Figure 14 shows dosage of process with sodium naphthalene sulphonate salt;
Figures 15 to 22 show opacity and whiteness without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figure 23 shows a sheet formation without and with a combined
use of sodium naphthalene sulphonate and polyethylene oxide;
Figure 24 shows consistencies of white water returns without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figures 25 and 26 show tonnage of white water transferred without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide;
Figure 27 shows fibre losses in sewer without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide; and Figure 28 shows drainage related to temperature without and with a combined use of sodium naphthalene sulphonate and polyethylene oxide.
The following results were obtained.
Figures 1 to 28 show several variations obtained by using a combined use of a condensed solution of sodium naphthalene sulphonate salt (identified process par 1169) and a solution of a mix of polyethylene oxide having the aforesaid mean molecular weight (identified process PND 1100), in aforesaid example. In those figures, informations appearing at the left of a dark vertical line are without the use of naphthalene sulphonate salt(s) and polyethylene oxide, and information appearing at the right of the dark vertical line are according to the invention.
TABLE V : OPTIC CHARACTERISTICS
* The wire consistencies dropped from 0.57% to 0.43% and 2.5 t/d of fines were retained in the sheet rather than lost to the clarifier yet it only cost 0.44$/ton to recover the brightness loss.
Therefore, a 0.6 point tone opacity gain was achieved on both 48 g/m2 and 45 g/m2
TABLE IV : WHITEWATER MANAGEMENT
Claims
1. In a method for the production of paper and analogous products, the improvement wherein one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic particles and an aqueous medium, being understood that polyethylene oxide is admixed in said mixture when this latter already contain at least a part of said naphthalene sulphonate salt(s).
2. A method according to claim 1, wherein one or several naphthalene sulphonate salt(s), said salt(s) defining a condensed or diluted solution, and a solution of one or several and polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define a pumpable pulp.
3. A method according to claim 1, wherein one or several naphthalene sulphonate salt(s), said salt(s) defining a condensed or diluted solution, and a solution of one or several and polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define an aqueous suspension.
4. A method according to claim 3, wherein said aqueous suspension is of the type intended to be laid on a wire screen of a paper machine to form a sheet of paper.
5. A method according to claim 3, wherein said aqueous suspension is of the type defining an effluent consisting of
waste water comprising for a part white water collected in a wire pit of a paper or pulp machine, and wherein said effluent is passed through a clarifier.
6. A method according to claim 3, wherein said aqueous suspension is of the type defining a white water collected in a wire pit of a paper or pulp machine, and wherein said white water is recycled at least in part as an affluent of a step for preparing a pumpable pulp comprising lignocellulosic fines and fibres and an aqueous medium.
7. A method according to claim 3, wherein said aqueous suspension is of the type intended to be laid on a wire screen of a paper machine or pulp machine, wherein a white water collected in a wire pit of the paper or pulp machine and essentially consisting of part of said previous suspension not retained on the wire screen to form the sheet of paper and still containing naphthalene sulphonate salt(s) and polyethylene oxide, is recycled to a step for preparing either a pumpable pulp or a fresh aqueous suspension intended to be laid on aforesaid wire screen, being understood that said recycled effluent contribute for a part to the admixture of the sulphonate salt(s) and polyethylene oxide with the aqueous suspension.
8. A method according to claim 7, wherein an equilibrium is set between the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained on the wire screen and the amount of naphthalene sulphonate salt(s) and polyethylene oxide collected in the white water in the wire pit and recycle to the preparation of either a pumpable pulp or a fresh aqueous suspension intended to be laid on the wire screen, to thus allow to admix to said pulp or fresh aqueous suspension intended to be laid on the wire screen, only the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained in the sheet of paper or in the pulp.
9. A method according to claim 1, 2, 3, 4, 5, 6, 7 or 8, wherein naphthalene sulphonate salt(s) are selected from the group consisting of sodium, potassium, ammonium, calcium and aluminium salt(s).
10. A method according to claim 1, 2, 3, 4, 5, 6, 7 or 8, wherein polyethylene oxide has a molecular weight varying from 4,5 x 106 to 12 x 106.
11. A method according to claim 9, wherein polyethylene oxide has a molecular weight varying from 4,5 x 106 to 12 x 106.
12. A method according to claim 11, wherein is further admixed to said aqueous mixture an enhancer consisting of a polyaluminium sulphate.
13. A method according to claim 11, wherein is further admixed to said aqueous mixture an enhancer consisting of a polyaluminium silicate sulphate.
14. A method according to claim 11, wherein is further admixed to said aqueous mixture an enhancer consisting of a sodium aluminate.
15. A method according to claim 11, wherein is further admixed to said aqueous mixture an enhancer consisting of polyaluminium chloride.
16. A method according to claim 11, wherein is further admixed to said aqueous mixture an enhancer consisting of magnesium hydroxide.
17. A method according to claim 11, wherein is further admixed to said aqueous mixture an enhancer consisting of bentonite.
18. A method according to claim 11, wherein polyethylene oxide is admixed with the aqueous mixture to represent from 10 to 700 grams per ton of dry matter of said mixture.
19. A method according to claim 11, wherein polyethylene oxide is admixed with the aqueous mixture to represent from 30 to 100 grams per ton of dry matter of said mixture.
20. A method according to claim 18 or 19, wherein naphthalene sulphonate salt(s) is (are) admixed with the aqueous mixture to represent an amount 50 to 1500 grams/ton of dry matter of said mixture.
21. A method according to claim 18 or 19, wherein naphthalene sulphonate salt(s) is(are) admixed with the aqueous mixture to represent an amount 50 to 500 grams/ton of dry matter of said mixture.
22. Use of one or several naphthalene sulphonate salt(s), said salt(s) being under granulated form or as a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106, in admixture with a mixture comprising lignocellulosic particles and an aqueous medium, to improve a retention of said particles on a wire screen and a drainage of the aqueous medium.
23. Use according to claim 22, wherein one or several naphthalene sulphonate salt(s), said salt(s) defining a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define a pumpable pulp.
24. Use according to claim 22, wherein one or several
naphthalene sulphonate salt(s), said salt(s) defining a condensed or diluted solution, and a solution of one or several polyethylene oxide having a molecular weight varying from 1 x 106 to 13 x 106 are admixed with a mixture comprising lignocellulosic fines and fibres and an aqueous medium to define an aqueous suspension.
25. Use according to claim 24, wherein said aqueous suspension is of the type intended to be laid on a wire screen of a paper machine to form a sheet of paper.
26. Use according to claim 24, wherein said aqueous suspension is of the type defining an effluent consisting of wastewater and comprising for a part, white water collected in a wire pit of a paper or pulp machine, and wherein said effluent is then passed through a clarifier.
27. Use according to claim 24, wherein said aqueous suspension is of the type defining a white water collected in a wire pit of a paper or pulp machine, and wherein said white water is recycled at least in part as an affluent of a step for preparing a pumpable pulp comprising lignocellulosic fines and fibres and an aqueous medium.
28. Use according to claim 24, wherein said aqueous suspension is of the type intended to be laid on a wire screen of a paper machine or pulp machine to form a sheet of paper, wherein a white water collected in a wire pit of the paper or pulp machine and essentially consisting of a part of said previous suspension not retained on the wire screen to form the sheet of paper and still containing naphthalene sulphonate salt(s) and polyethylene oxide, is recycled to a step for preparing either a pumpable pulp or a fresh aqueous suspension intended to be laid on aforesaid wire screen, being understood that said recycled white water contributes for a part to the admixture of sulphonate salt(s) and
polyethylene oxide with the aqueous suspension.
29. Use according to claim 28, wherein an equilibrium is set between the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained on the wire screen and the amount of naphthalene sulphonate salt(s) and polyethylene oxide collected in the white water in the wire pit and recycle to the preparation of either a pumpable pulp or a fresh aqueous suspension intended to be laid on the wire screen, to thus allow to admix to said pulp on fresh aqueous suspension intended to be laid on the wire screen, only the amount of naphthalene sulphonate salt(s) and polyethylene oxide retained in the sheet of paper or in the pulp.
30. Use according to claim 22, 23, 24, 25, 26, 27, 28 or 29, wherein naphthalene sulphonate salt(s) are selected from the group consisting of sodium, potassium, ammonium, calcium and aluminium salt(s).
31. Use according to claim 22, 23, 24, 25, 26, 27, 28 or 29, wherein polyethylene oxide has a molecular weight varying from 4,5 x 106 to 12 x 106.
32 Use according to claim 30 wherein polyethylene oxide has a molecular weight varying from 4,5 x 106 to 12 x 106.
33. Use according to claim 32, wherein is further admixed to said aqueous mixture an enhancer consisting of a polyaluminium sulphate.
34. Use according to claim 32, wherein is further admixed to said aqueous mixture an enhancer consisting of a polyaluminium silicate sulphate.
35. Use according to claim 32, wherein is further admixed to said aqueous mixture an enhancer consisting of a sodium
aluminate.
36. Use according to claim 32, wherein is further admixed to said aqueous mixture an enhancer consisting of polyaluminium chloride.
37. Use according to claim 32, wherein is further admixed to said aqueous mixture an enhancer consisting of magnesium hydroxide.
38. Use according to claim 32, wherein is further admixed to said aqueous mixture an enhancer consisting of bentonite.
39. Use according to claim 32, wherein polyethylene oxide is admixed with the aqueous mixture to represent from 10 to 700 grams per ton of dry matter of said mixture.
40. Use according to claim 32, wherein polyethylene oxide is admixed with the aqueous mixture to represent from 30 to 100 grams per ton of dry matter of said mixture.
41. Use according to claim 39 or 40, wherein naphthalene sulphonate salt(s) is(are) admixed with the aqueous mixture to represent an amount 50 to 1500 grams/ton of dry matter of said mixture.
42. Use according to claim 39 or 40, wherein naphthalene sulphonate salt(s) is(are) admixed with the aqueous mixture to represent an amount 100 to 500 grams/ton of dry matter of said mixture.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002127696A CA2127696C (en) | 1992-02-26 | 1992-11-09 | Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage |
| JP51153694A JP3149954B2 (en) | 1992-02-26 | 1992-11-09 | Methods and uses involving naphthalene sulfonates and polyethylene oxide to improve retention and drainage |
| PCT/CA1992/000487 WO1994011575A1 (en) | 1992-02-26 | 1992-11-09 | Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage |
| US08/256,455 US5554260A (en) | 1992-11-09 | 1992-11-09 | Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84180692A | 1992-02-26 | 1992-02-26 | |
| CA002127696A CA2127696C (en) | 1992-02-26 | 1992-11-09 | Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage |
| PCT/CA1992/000487 WO1994011575A1 (en) | 1992-02-26 | 1992-11-09 | Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1994011575A1 true WO1994011575A1 (en) | 1994-05-26 |
Family
ID=38595956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CA1992/000487 WO1994011575A1 (en) | 1992-02-26 | 1992-11-09 | Method and use involving naphthalene sulphonate salt(s) and polyethylene oxide, to improve retention and drainage |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP3149954B2 (en) |
| CA (1) | CA2127696C (en) |
| WO (1) | WO1994011575A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5674643A (en) * | 1995-02-14 | 1997-10-07 | Sanyo Electric Co., Ltd. | Non-sintered nickel electrode for alkaline storage cell |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4188446A (en) * | 1977-05-04 | 1980-02-12 | Johnson & Johnson | Paper having improved strength |
| CA1137261A (en) * | 1980-06-02 | 1982-12-14 | Ching-Hua Tay | Method of improving the retention of fines in paper making using polyethylene oxide |
| EP0203817A1 (en) * | 1985-05-31 | 1986-12-03 | Betz Europe, Inc. | Polymeric compositions |
| CA2040967A1 (en) * | 1991-04-23 | 1992-10-24 | M. Robin Brown | New system for reducing bod value in used water |
-
1992
- 1992-11-09 WO PCT/CA1992/000487 patent/WO1994011575A1/en active Application Filing
- 1992-11-09 CA CA002127696A patent/CA2127696C/en not_active Expired - Fee Related
- 1992-11-09 JP JP51153694A patent/JP3149954B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4188446A (en) * | 1977-05-04 | 1980-02-12 | Johnson & Johnson | Paper having improved strength |
| CA1137261A (en) * | 1980-06-02 | 1982-12-14 | Ching-Hua Tay | Method of improving the retention of fines in paper making using polyethylene oxide |
| EP0203817A1 (en) * | 1985-05-31 | 1986-12-03 | Betz Europe, Inc. | Polymeric compositions |
| CA2040967A1 (en) * | 1991-04-23 | 1992-10-24 | M. Robin Brown | New system for reducing bod value in used water |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPIL Section Ch, Week 9302, Derwent Publications Ltd., London, GB; Class A25, AN 93-009067 & CA,A,2 040 967 (RADU G.) 24 October 1992 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2127696A1 (en) | 1994-05-26 |
| JPH08504237A (en) | 1996-05-07 |
| CA2127696C (en) | 2005-10-25 |
| JP3149954B2 (en) | 2001-03-26 |
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