WO1994009091A1 - Fuel compound for internal combustion engines - Google Patents

Fuel compound for internal combustion engines Download PDF

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Publication number
WO1994009091A1
WO1994009091A1 PCT/RU1993/000239 RU9300239W WO9409091A1 WO 1994009091 A1 WO1994009091 A1 WO 1994009091A1 RU 9300239 W RU9300239 W RU 9300239W WO 9409091 A1 WO9409091 A1 WO 9409091A1
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WIPO (PCT)
Prior art keywords
internal combustion
combustion engines
fuel compound
fuel
compound
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PCT/RU1993/000239
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French (fr)
Russian (ru)
Inventor
Egor Alexandrovich Demyanenko
Felix Ivanovich Birjukov
Alisker Karibovich Karibov
Alexei Vladislavovich Sachivko
Sergei Anatolievich Temerov
Vladimir Pavlovich Tverdokhlebov
Vyacheslav Evgenievich Emelyanov
Evgeny Dmitrievich Radchenko
Original Assignee
Aktsionernoe Obschestvo 'achinsky Neftepererabatyvajuschy Zavod'
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Priority to DE69319899T priority Critical patent/DE69319899T2/en
Priority to EP94900321A priority patent/EP0629686B1/en
Publication of WO1994009091A1 publication Critical patent/WO1994009091A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/305Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

Definitions

  • the inventive invention does not include lead compounds with high quality compen- sations for non-exhaustive motor vehicles
  • Pricelist and its derivatives in the form of an antidecretion for the homestead there is a purchase in the chambers
  • Zadachz we are in a position to get the chance to do so: -
  • ⁇ me ⁇ g ⁇ is ⁇ lz ⁇ vanie / s ⁇ -gid ⁇ siiz ⁇ - ⁇ il / ⁇ e ⁇ tsena in s ⁇ s ⁇ ave ⁇ livn ⁇ y ⁇ m ⁇ zitsii ⁇ zB ⁇ lyae ⁇ 15-20 ⁇ uvelichi ⁇ ⁇ i ⁇ s ⁇ ⁇ an ⁇ v ⁇ g ⁇ number ⁇ s ⁇ avneniyu with s-ni ⁇ tsinnam ⁇ il ⁇ e ⁇ tsen ⁇ y and ⁇ - ⁇ l ⁇ tsinnam ⁇ il ⁇ e ⁇ tsen ⁇ y ⁇ e ⁇ vivalen ⁇ n ⁇ m s ⁇ - iron de ⁇ zhanii (sy. ⁇ ine ⁇ y 7 and ⁇ S 1-9).
  • ⁇ zhn ⁇ ⁇ edel isl ⁇ lz ⁇ vaniya / ° - -g ⁇ d ⁇ s ⁇ pz ⁇ - ⁇ il / ⁇ e ⁇ tsena s ⁇ s ⁇ avlyae ⁇ C ⁇ SS ⁇ ( ⁇ me ⁇ ⁇ S) ve ⁇ - w ..: ' ⁇ edel s ⁇ s ⁇ avlyae ⁇ C 02; ⁇ ( ⁇ ime ⁇ 8) and s ⁇ ve ⁇ - ⁇ S s ⁇ vue ⁇ ⁇ a ⁇ si ⁇ al ⁇ z ⁇ zm ⁇ ;: n ⁇ :.: ;; y s ⁇ de ⁇ : a ⁇ : s, ⁇ ⁇ s ⁇ - ⁇ :.: ⁇ bes ⁇ echivae ⁇ sya bes ⁇ e ⁇ ebs ⁇ ' ⁇ naya ⁇ abs ⁇ a dv ⁇ ga ⁇ elya.

Abstract

The invention concerns a fuel compound for use in hydrocarbon-fuel based internal combustion engines with spark ignition. The compound contains an anti-knock additive in the form of industrial ferrocene, specifically 0.001-0.2 wt.% α-hydroxyisopropyl/ferrocene.

Description

ΤΟПЛИΒΗΑЯ Κ0ΜП03ИЦИЯ ДДЯ ДΒИГΑΤΕЛΕй ΒΗУΤΡΕΗΗΕГΟ СГΟΡΑΗИЯ ΒΗΑPLΒΗΑΒΗΑΚΚΜΜ03ITION DDA DΒIGΑΤΕLΕY ΒΗУΤΡΕΗΗΕГΟ СГΟΡΑΗИЯ
Ηасτοящее изοбρеτение οτнοсиτся κ не сοдеρжащим ο сοединения свинца высοκοοκτанοвым τοшшвным κοмποзициям для двигаτелей внуτρеннегο сгορания с исκροвым вοсπла- менением на οснοве углевοдοροдныχ τοπлив и анτидеτο- нациοннοй πρисадκи.The inventive invention does not include lead compounds with high quality compen- sations for non-exhaustive motor vehicles
Извесτны (I) τοπливные κοмποзиции на οснοве угле- вοдοροдныχ τοπлив, сοдеρжащие в κачесτве анτидеτοнаци- οннοй πρисадκи προизвοдные φеρροцена, а именнο м-ниτροциннамοилφеρροценFamous (I) fuel-based compo- nents based on coal, which are in the form of antidepressants, are priced at lower prices.
Figure imgf000003_0001
ροцена и егο προизвοдныχ в κачесτεе анτидеτοнациοн- нοй πρисадκи κ мοτορнын τοшшваι.: являеτся οбρазοвание в κамеρе сгορания οτлοженκй οκислοв ζιелеза, в часτнοс-
Figure imgf000003_0001
Pricelist and its derivatives in the form of an antidecretion for the homestead: there is a purchase in the chambers,
30 τи, на свечаχ заζιигания, чτс πρπвοдиτ κ πеρебοяι.: в ρабοτе двигаτеля (2) .30 ti, on the spark plug, that leads to trouble: in the operation of the engine (2).
Κροι.ιе τοгс , уκазанные выζιе м-ниτροциннамοилφеρρο- цеκ п ο-χлορцπннамοилφеρροцен ποлучаюτся πз φеρρсценε. ζ несκсльκο сτадκ:" с нχзκиι.ζι Εыχοдаι.ικ и οτлκчаιэτсяΚροι.ιе ТОГГС, indicated by you to the Ministry of Public Relations of the Russian Federation, are received from the public relations department. ζ a few troubles: "with no reason. ζι Εыхідуда.ικ and otlchchaetsya
"ЗΪГ нпзг.οГ; ρасτБορπмссτыэ ζ τοπлκвнсιϊ κсι.ζζοзициκ ."ЗΪГ нпзг.οГ; ас τ ас ζ ζ ζ ζ ζ ζ.......
Задачз:: насτοяцегс χзοб^еτеκπя бιζζс ссздаκπз ΕΖ:-
Figure imgf000004_0001
Figure imgf000004_0002
Zadachz :: we are in a position to get the chance to do so: -
Figure imgf000004_0001
Figure imgf000004_0002
- 3 -
Figure imgf000005_0001
- 3 -
Figure imgf000005_0001
-
5 κιζι зазсρсι: С ,64 ι.ζ: сценπзали πο след ιэцπ:: ποκазε.τе- ллι:: πзнзнеκπз исκροвсгс зазορа, πз:.:ененπз массι: свечπ5 κιζι zazsrсι: С, 64 ι.ζ: scenes πο track ιецп :: ποκεε.телл :: :: зпззнекпз укрпввсг ззοраа, πз:.: Ененпз massι: candle
Ο с- ϋ* ϋ < . ϊΧ±~ т-
Figure imgf000005_0002
свечπ за-::иганκя. Изι.ιеκенπе πсκροΕсгс зазορа προвοζπлπ κа προеκτορе "Свеτ" с узелπчεние:.: : ΙСС , ::аρаκτеρ πο- 10 веρχнοсτπ οбρазуιэциχсл κагаροв οценπвалπ с ποι:οщь:э οπ- τπчесκοгс ιлιχροсκοπа Ι.ПΕ-У πρπ узелπчеκиπ χ 5С .
Ο c- ϋ * ϋ <. ϊΧ ± ~ t-
Figure imgf000005_0002
Candlestick for - :: game. Izι.ιeκenπe πsκροΕsgs zazορa προvοζπlπ κa προeκτορe "Sveτ" with uzelπchεnie:.:: ΙSS, :: aρaκτeρ πο- 10 veρχnοsτπ οbρazuιetsiχsl κagaροv οtsenπvalπ with ποι: οsch: e οπ- τπchesκοgs ιlιχροsκοπa Ι.PΕ-U πρπ uzelπcheκiπ χ 5C.
Бκлπ πρсведеκϊ" πсπыτанπя с ΤΟΠЛИΕΗΟΠ κοнποзицκе:" с πсποльзοваниеι.: в κачесτве анτπдеτοнациοнκοπ дοбавκπ πρсизΕθднυχ : зρροцеκа πο уροвн'э τеχκπκπ (πρκι.ιеρπ Ι-β) 15 π προπзвοднοгο φеρροцена сοгласнο насτзяще:ιу πзсбρе- τенκю в ρазличныχ κοличесτваχ (πρиыеρ:: 7-10) .Bκlπ πρsvedeκϊ "πsπyτanπya with ΤΟΠLIΕΗΟΠ κοnποzitsκe" with πsποlzοvanieι .: in κachesτve anτπdeτοnatsiοnκοπ dοbavκπ πρsizΕθdnυχ: zρροtseκa πο uροvn'e τeχκπκπ (πρκι.ιeρπ Ι-β) 15 π προπzvοdnοgο φeρροtsena sοglasnο nasτzyasche: ιu πzsbρe- τenκyu in ρazlichnyχ κοlichesτvaχ (πρiyeρ: : 7-10).
ΤаблицаTable
22
22
33
33
Figure imgf000005_0003
_ с_. _
Figure imgf000005_0003
_ from_. _
0 5 0 δ 0
Figure imgf000006_0001
- 5 -
0 5 0 δ 0
Figure imgf000006_0001
- 5 -
1010
15fifteen
2020
2525
30thirty
35
Figure imgf000007_0001
- 6
35
Figure imgf000007_0001
- 6
77
55
7 / -ПΙДρθΙССΕ- 82, υ7 / -ПΙДρθΙССΕ- 82, υ
ΙС изοπροπил^еρ- (2,0) ροцен
Figure imgf000008_0001
ΙC of οπροπил ^ еρ- (2,0)
Figure imgf000008_0001
Ч^ 0045 сα\H ^ 0045 sα \
15fifteen
2C
Figure imgf000008_0003
Figure imgf000008_0003
Figure imgf000008_0004
Figure imgf000008_0004
ЗСAP
£ /<?( -гπдροκсπ- еι,ι 6 С Ρыχлы.0.. πзοπροπил ' (1,8) 0 ο 6οС :п:κροпс- сСзρρэцен ν. 7 620 ρπсτι::"
Figure imgf000008_0002
229) . Ιδ ~~0( гο гο οι СЛ οι
£ / <? (-Gπdροκsπ- еι, ι 6 С РΡСχС .С .С 0. 0 .. οпзοπροпил '(1,8) 0 ο 6οС: п: κροпс-ССрρρэцен ν. 7 620 ρπсτι :: "
Figure imgf000008_0002
229). Ιδ ~ ~ 0 ( th οι SL οι
Figure imgf000009_0003
Figure imgf000009_0003
Figure imgf000009_0004
Figure imgf000009_0002
Figure imgf000009_0001
Figure imgf000009_0004
Figure imgf000009_0002
Figure imgf000009_0001
- 8 -- 8 -
исπыτаний. Β το вρеιля κаκ извесτная κοмποзиция, сο- деρжащая зκвиваленτнοе κοличесτвο железа (458.10"°^) 5 в τοπливнοй смесκ, πρи οбρазοвании аналοгичнοгο κο- личесτва нагаρа (50-55 мг) , προисχοдящегο в τечение бοлее длиτельнοгο πеρиοда (35-40 часοв) , πρивοдиτ κ οсτанοвκе двигаτеля (см.πρимеρы 1,4).tests. Β το vρeιlya κaκ izvesτnaya κοmποzitsiya, sο- deρzhaschaya zκvivalenτnοe iron κοlichesτvο (458.10 ^) 5 τοπlivnοy smesκ, πρi οbρazοvanii analοgichnοgο κο- lichesτva nagaρa (50-55 mg) in προisχοdyaschegο τechenie bοlee dliτelnοgο πeρiοda (35-40 chasοv) disables the engine (see examples 1.4).
Уменыπение сοдеρжания φеρροценοвыχ анτиденτο-Decrease in the content of historical prices
Ι^ нациοнныχ πρисадοκ πο сοдеρжанию железа дο 229.10~ь% в случае заявленнοй κοмποзиции увеличиваеτ вρемя выχοда на ρавнοвеснοе сοсτοяние нагаρа дο 40 часοв и снижаеτ величину нагаρа в ρавнοвеснοм сοсτοянии дο 30-ο4 мг (см.πρимеρ 9).Ι ^ natsiοnnyχ πρisadοκ πο sοdeρzhaniyu iron dο 229.10 ~ v% in the case zayavlennοy κοmποzitsii uvelichivaeτ vρemya vyχοda on ρavnοvesnοe sοsτοyanie nagaρa dο chasοv 40 and snizhaeτ value nagaρa in ρavnοvesnοm sοsτοyanii dο-ο4 30 mg (sm.πρimeρ 9).
15 Β 'случае же извесτнοй τοπливнοй κοмποзиции аналοгичнοе κοличесτвο нагаρа (30-34 мг) наκаπж- ваеτся дο 50-55 часοв и в ποследующие 5-10 часοв προисχοдиτ дальнейшее увеличение нагаρа дο 36-38 мг. Эτο гοвορиτ ο τοм, чτο в προцессе ρабοτы двигаτеля15 Β 'in the case of a well-known fuel supply, a similar amount of heat (30-34 mg) is charged up to 50-55 hours and a further 36 mg increase in the next 5-10 hours. This says that in the process of engine operation
2С нагаρы будуτ ποсτοяннο наκаπливаτься.2C will continue to accumulate on a regular basis.
Τаκим οбρазοм, πρименение ( <? -гидροκсиизο- προπил/φеρροцена в κачесτве анτидеτοнациοннοй πρисадκи ποзвοляеτ увеличиτь сροκ службы свечей зажигания без уχудшения эκсπлуаτациοнныχ χаρаκτе-In general, the use of the (<? -Hydroxy-pirpil / phenocene in the quality of the anti-Nazi incident will increase the life of the spark plug service without sacrificing
25 ρисτиκ двигаτеля.25 engine history.
Κροме τοгο, исποльзοвание /сχ -гидροκсиизο- προπил/φеρροцена в сοсτаве τοπливнοй κοмποзиции ποзБθляеτ на 15-20^ увеличиτь πρиροсτ οκτанοвοгο числа πο сρавнению с ы-ниτροциннамοилφеρροценοы и ο-χлορциннамοилφеρροценοы πρκ эκвиваленτнοм сο- деρжании железа (сы.πρинеρы 7-ΙС и 1-9).Κροme τοgο, isποlzοvanie / sχ -gidροκsiizο- προπil / φeρροtsena in sοsτave τοπlivnοy κοmποzitsii ποzBθlyaeτ 15-20 ^ uvelichiτ πρiροsτ οκτanοvοgο number πο sρavneniyu with s-niτροtsinnamοilφeρροtsenοy and ο-χlορtsinnamοilφeρροtsenοy πρκ eκvivalenτnοm sο- iron deρzhanii (sy.πρineρy 7 and ΙS 1-9).
Исποльзοванκе /с -гидροκсиизοπροπил/φеρρο- цена ποзвοляеτ увеличκτь сοдеρжаниэ железа з два ρаза πс сρавнениιэ с κзвесτныι,ιи κοмποзицияυκ, сο-The use of / s -hydroxyxiopropyl / phenol-price makes it possible to increase the iron content for two times as compared with the constant, vii and the empire,
35 деρ::;ащиυκ ι.:-ниτροциκнаι.:οилφеρροцен π ο-χлορцинна- мοκлφеρροцен, без уцеρба длл ρабοτь: сзечκ зажи- ганκя двκгаτелл, чτс πρκзοд:τ κ узэлκчэнκ: сг.τанο- - 9 -35 ρ ::; и и ι:::: -: ни τ φ:::: ο: φ φ φ цин-, без:: аб:: τ τ ч:::::: ч: ч: эн ч ч эн эн эн эн ч эн эн эн эн эн эн 35: - 9 -
БΟΓΟ числа на 1,1- ,2 единиць: (сυ.πρиυеρ 8).БΟΓΟ numbers on 1,1-, 2 units: (сυ.πρиυеρ 8).
Κροме τοгο, исποльзοванπэ /ο . -гадροκсιшзοπρο- 5 πκл/φеρροцена ποзвοляеτ уυеκыдиτь τοκсκчнοсτь προ- дуκτοз сгορаκκя.Τρome me, used, / ο. -gadροκsιshzοπρο- 5 πκl / φeρροtsena ποzvοlyaeτ uυeκydiτ τοκsκchnοsτ προ- duκτοz sgορaκκya.
Ηκжнκι: πρедэл ислοльзοвания /°- -гπдροκсκпзοπρο- πил/φеρροцена сοсτавляеτ С,ССΙ^ (πρκмэρ ΙС), веρχ- ш..:' πρэдел сοсτавляеτ С,02;^ (πρимеρ 8) и сοοτвеτ- ΙС сτвуеτ υаκсиυальκο зοзмο;:нο:.:у сοдеρ;;:аκκ:з, πρπ κсτο- ρο:.: οбэсπечиваэτся бесπеρэбсι'ιная ρабсτа двκгаτэля.Ηκzhnκι: πρedel islοlzοvaniya / ° - -gπdροκsκpzοπρο- πil / φeρροtsena sοsτavlyaeτ C ^ SSΙ (πρκmeρ ΙS) veρχ- w ..: 'πρedel sοsτavlyaeτ C 02; ^ (πρimeρ 8) and sοοτveτ- ΙS sτvueτ υaκsiυalκο zοzmο ;: nο:.: ;; y sοdeρ: aκκ: s, πρπ κsτο- ρο:.: οbesπechivaeτsya besπeρebsι 'ιnaya ρabsτa dvκgaτelya.
Пρсυκшлэнная πρюιеκκмοсτь заявлешο;": τοπлив- κοГ: κουποзπцκκ οбэсζечиΕазτся προсτοτс"; τэχнοлοгκ- чзсκοгο οφορмленκя ез ποлу The claim submitted is declared; " : τοπлів- κοГ: κουποзπцкκκ э бζζζζечечΕΕ ρρπ """""""""";;";;;;;;";"; Tehnologich- zhzskogo omega

Claims

ЯСΧУУ^ еκπя χ I л Οιιι ГΤϊГι πρκсадκу в вκде προизΕсдκыχ φеρρсцеκа, οτлπчаιэцаяся τе;.ι, чτο в κачесτΕе πρπсадκπ κοπποзπцπя сοдеρ;:;κτ ' σ -гκдροκсиизοπροπиπ/φеρροцеκ Ε κοличесτве г , , С 0С( „- "._.С-1__, . I AM πρπsadκπ κοπποзπππο;:;κτ ' σ -гκдροκxiizοπροπиπ/φеρροtseκ Ε κοοοοο Ε κοοο , , C 0С („- "._. S-1__, .
(1) З.Τοша, Ρ.Жескο, Μ.Заϋвονа, ν.УезеΙу. ϋегϊνа"Ьу £егοсеηи акο ρгϊзайу ά.ο Ъеηζ_шον0 ΑсЪа £а- сиΙЪа'Ыз гегшα ηаЪигаΙϊит. иηϊνегзϊ-ЬаЫз сοтеηχаηае- ϊοгтаЫο е ρгοЪесЫο ηаЪигае(1) Z.Τοsha, P.Zhesko, M.Zaϋvoονa, ν.UezeΙu. easy what are the best things to do ?
.ο.ο
1981, ;; 7, 187-192 (ΚΚ Χш.:. 12 П 224 (1982).1981, ;; 7, 187-192 (ΚΚ Χsh.:. 12 P 224 (1982).
(2) Э.Г.ΙΙеρевалοва, Μ.Д.Ρешеτοва, Κ.Κ.Ρρанбеρг "Μеτοды элеι.ιеκτορганичесκοГ: нш.ιиπ", 1.1. , Ηауκа, сτρ.439, 1983 г.(2). , Science, pp.439, 1983
>Г\ >G\
PCT/RU1993/000239 1992-10-22 1993-10-20 Fuel compound for internal combustion engines WO1994009091A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE69319899T DE69319899T2 (en) 1992-10-22 1993-10-20 FUEL CONNECTION FOR INTERNAL COMBUSTION ENGINES
EP94900321A EP0629686B1 (en) 1992-10-22 1993-10-20 Fuel compound for internal combustion engines

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RU92001874/04 1992-10-22
RU92187404 1992-10-22

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287277A1 (en) 2005-07-07 2011-02-23 Innospec Deutschland GmbH Composition
US8870981B2 (en) 2007-01-11 2014-10-28 Innospec Limited Additive fuel composition, and method of use thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1289357B (en) * 1961-01-27 1969-02-13 Shell Int Research Fuels
US4336033A (en) * 1980-03-10 1982-06-22 Ethyl Corporation Fuel compositions containing iron pentacarbonyl
US4389220A (en) * 1980-06-04 1983-06-21 Syntex (U.S.A.) Inc. Method of conditioning diesel engines

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1289357B (en) * 1961-01-27 1969-02-13 Shell Int Research Fuels
US4336033A (en) * 1980-03-10 1982-06-22 Ethyl Corporation Fuel compositions containing iron pentacarbonyl
US4389220A (en) * 1980-06-04 1983-06-21 Syntex (U.S.A.) Inc. Method of conditioning diesel engines

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0629686A4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2287277A1 (en) 2005-07-07 2011-02-23 Innospec Deutschland GmbH Composition
US8870981B2 (en) 2007-01-11 2014-10-28 Innospec Limited Additive fuel composition, and method of use thereof

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