WO1994002750A1 - Bearings - Google Patents

Bearings Download PDF

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Publication number
WO1994002750A1
WO1994002750A1 PCT/GB1993/001537 GB9301537W WO9402750A1 WO 1994002750 A1 WO1994002750 A1 WO 1994002750A1 GB 9301537 W GB9301537 W GB 9301537W WO 9402750 A1 WO9402750 A1 WO 9402750A1
Authority
WO
WIPO (PCT)
Prior art keywords
bearing
nickel
race
titanium
fluorocarbon
Prior art date
Application number
PCT/GB1993/001537
Other languages
French (fr)
Inventor
Richard Newley
Paul Raymond Smith
Alun Davies-Jones
Original Assignee
Dowty Aerospace Gloucester Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dowty Aerospace Gloucester Limited filed Critical Dowty Aerospace Gloucester Limited
Priority to US08/373,255 priority Critical patent/US5660482A/en
Priority to JP50429294A priority patent/JP3431152B2/en
Priority to DE69307321T priority patent/DE69307321T2/en
Priority to EP93917881A priority patent/EP0651862B1/en
Publication of WO1994002750A1 publication Critical patent/WO1994002750A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C23/00Bearings for exclusively rotary movement adjustable for aligning or positioning
    • F16C23/02Sliding-contact bearings
    • F16C23/04Sliding-contact bearings self-adjusting
    • F16C23/043Sliding-contact bearings self-adjusting with spherical surfaces, e.g. spherical plain bearings
    • F16C23/045Sliding-contact bearings self-adjusting with spherical surfaces, e.g. spherical plain bearings for radial load mainly, e.g. radial spherical plain bearings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121Use of special materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/20Sliding surface consisting mainly of plastics
    • F16C33/201Composition of the plastic
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2204/00Metallic materials; Alloys
    • F16C2204/40Alloys based on refractory metals
    • F16C2204/42Alloys based on titanium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2204/00Metallic materials; Alloys
    • F16C2204/40Alloys based on refractory metals
    • F16C2204/44Alloys based on chromium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2326/00Articles relating to transporting
    • F16C2326/43Aeroplanes; Helicopters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S384/00Bearings
    • Y10S384/90Cooling or heating
    • Y10S384/909Plastic
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S384/00Bearings
    • Y10S384/90Cooling or heating
    • Y10S384/913Metallic compounds

Definitions

  • This invention relates to bearings, especially sliding contact bearings used in aircraft landing gear and incorporating titanium components in surface-to-surface sliding contact.
  • Titanium is used in aircraft construction because it is lightweight compared with steel, but when used in bearings such as landing gear trunnion bearings that experience large shock loads, there can be problems with galling and seizure between titanium surfaces sliding on one another. It has been proposed in US 4848934 to overcome this problem by coating the surface of one titanium bearing component with chromium oxide and forming the other component of copper. Although chromium oxide is a brittle material, it is considered . satisfactory provided the complementary bearing surface with which it cooperates includes copper or copper alloys.
  • a sliding contact bearing comprises two bearing members composed of titanium or a titanium alloy with cooperating sliding surfaces, characterised in that a first one of said surfaces is chromium plated and the second one of said surfaces is coated with nickel and fluorocarbon polymer.
  • the nickel is preferably applied by an electroless plating process and provides a high level of wear and corrosion resistance.
  • the fluorocarbon polymer is deposited on the metal surface so as to provide permanent lubrication between the two surfaces.
  • a suitable nickel/fluorocarbon polymer coating may be provided by the General agnaplate Corporation under their trade mark "NEDOX" .
  • bearing according to the invention offers comparable performance and durability to that of conventional bearings comprising a chromium plated steel member in sliding cooperation with an aluminium bronze member and superior performance compared to bearings involving chromium plated, or chromium oxide coated or bronze coated bearing surfaces. Further, bearings according to the invention offer the advantage of limiting the friction between the bearing surfaces due to the effect of the fluorocarbon polymer used.
  • Figure 1 is a diametral cross-section through an aircraft landing gear trunnion bearing according to the invention.
  • Figure 2 is a graph of friction against bearing life for a bearing as shown in Figure 1 compared with a similar bearing in which the outer race is aluminium bronze and the inner spherical member is chromium plated steel.
  • the aircraft landing gear trunnion bearing of Figure 1 comprises an outer ring-shaped bearing race 1 with an inner bearing surface 2 formed on a sphere, and an inner ring-shaped bearing member 3 located within the outer bearing race 1 with an outer bearing surface 4 formed on a sphere so as to cooperate with the inner bearing surface 2 of the race 1 and allow relative rotary and sliding contact between the two bearing members 1, 3.
  • the outer bearing race 1 is adapted for connection to one part of aircraft landing gear
  • the inner bearing member 3 is formed with a bore 5 to receive the journal of a trunnion on the leg of the landing gear.
  • the two bearing members 1 and 3 are composed of titanium or titanium alloy, and to avoid galling between the cooperating surfaces of these bearing members, the inner surface 2 of the outer bearing race 1 is chromium plated, and the outer surface 4 of the inner bearing member 3 is coated with nickel and fluorocarbon polymer.
  • the nickel is applied by an electroless plating process and the fluorocarbon polymer is subsequently infused into pores in the plating, and the coating is heat treated to create a smooth surface.
  • This nickel/polymer coating is typically that provided by General Magnaplate Corporation under their trade mark "NEDOX" .
  • the coating is 0.025 to 0.041mm thick and has a hardness in the range 750-1000 VPN.
  • the bearing as described above and a similar "standard" bearing with the outer bearing race 1 composed of chromium plated steel and the inner bearing 3 composed of aluminium bronze were subjected to successive simulated flight tests with a maximum load of 214 KN.
  • the cooperating surfaces of the bearing were in good condition after 30,000 flight tests, and were still in good condition after 60,000 flight tests with the bearing according to the invention, but were showing slight wear with the "standard” bearing having aluminium bronze and s eel/chromium plated members.
  • the friction between the cooperating surfaces of both bearings were measured at regular intervals and the results shown in Figure 2 obtained, the friction units shown being dimensionless scaled friction coefficient units used for ease of comparison.

Abstract

A sliding contact bearing, especially an aircraft landing gear trunnion bearing, comprises two bearing members (1, 3) composed of titanium or titanium alloy with cooperating sliding surfaces (2, 4), a first one of which is chromium plated and the second one of which is coated with nickel and fluorocarbon polymer. Preferably, the nickel coating is applied by an electroless plating process, and the fluorocarbon is infused into pores in the nickel plating. Preferably, the nickel and fluorocarbon coating is 0.025 to 0.041 mm thick, and has a hardness in the range 750-1000 VPN.

Description

BEARINGS Technical Field
This invention relates to bearings, especially sliding contact bearings used in aircraft landing gear and incorporating titanium components in surface-to-surface sliding contact.
Titanium is used in aircraft construction because it is lightweight compared with steel, but when used in bearings such as landing gear trunnion bearings that experience large shock loads, there can be problems with galling and seizure between titanium surfaces sliding on one another. It has been proposed in US 4848934 to overcome this problem by coating the surface of one titanium bearing component with chromium oxide and forming the other component of copper. Although chromium oxide is a brittle material, it is considered . satisfactory provided the complementary bearing surface with which it cooperates includes copper or copper alloys.
Disclosure of the Invention
According to the present invention a sliding contact bearing comprises two bearing members composed of titanium or a titanium alloy with cooperating sliding surfaces, characterised in that a first one of said surfaces is chromium plated and the second one of said surfaces is coated with nickel and fluorocarbon polymer.
The nickel is preferably applied by an electroless plating process and provides a high level of wear and corrosion resistance. The fluorocarbon polymer is deposited on the metal surface so as to provide permanent lubrication between the two surfaces. A suitable nickel/fluorocarbon polymer coating may be provided by the General agnaplate Corporation under their trade mark "NEDOX" .
Comparative tests indicate that a bearing according to the invention offers comparable performance and durability to that of conventional bearings comprising a chromium plated steel member in sliding cooperation with an aluminium bronze member and superior performance compared to bearings involving chromium plated, or chromium oxide coated or bronze coated bearing surfaces. Further, bearings according to the invention offer the advantage of limiting the friction between the bearing surfaces due to the effect of the fluorocarbon polymer used. Description of the Drawings
Figure 1 is a diametral cross-section through an aircraft landing gear trunnion bearing according to the invention, and
Figure 2 is a graph of friction against bearing life for a bearing as shown in Figure 1 compared with a similar bearing in which the outer race is aluminium bronze and the inner spherical member is chromium plated steel.
Mode of Carrying Out the Invention The aircraft landing gear trunnion bearing of Figure 1 comprises an outer ring-shaped bearing race 1 with an inner bearing surface 2 formed on a sphere, and an inner ring-shaped bearing member 3 located within the outer bearing race 1 with an outer bearing surface 4 formed on a sphere so as to cooperate with the inner bearing surface 2 of the race 1 and allow relative rotary and sliding contact between the two bearing members 1, 3. The outer bearing race 1 is adapted for connection to one part of aircraft landing gear, and the inner bearing member 3 is formed with a bore 5 to receive the journal of a trunnion on the leg of the landing gear.
The two bearing members 1 and 3 are composed of titanium or titanium alloy, and to avoid galling between the cooperating surfaces of these bearing members, the inner surface 2 of the outer bearing race 1 is chromium plated, and the outer surface 4 of the inner bearing member 3 is coated with nickel and fluorocarbon polymer. The nickel is applied by an electroless plating process and the fluorocarbon polymer is subsequently infused into pores in the plating, and the coating is heat treated to create a smooth surface. This nickel/polymer coating is typically that provided by General Magnaplate Corporation under their trade mark "NEDOX" . Typically, the coating is 0.025 to 0.041mm thick and has a hardness in the range 750-1000 VPN.
For comparison purposes, the bearing as described above and a similar "standard" bearing with the outer bearing race 1 composed of chromium plated steel and the inner bearing 3 composed of aluminium bronze, were subjected to successive simulated flight tests with a maximum load of 214 KN. In each case, the cooperating surfaces of the bearing were in good condition after 30,000 flight tests, and were still in good condition after 60,000 flight tests with the bearing according to the invention, but were showing slight wear with the "standard" bearing having aluminium bronze and s eel/chromium plated members. Furthermore, the friction between the cooperating surfaces of both bearings were measured at regular intervals and the results shown in Figure 2 obtained, the friction units shown being dimensionless scaled friction coefficient units used for ease of comparison. This clearly shows that the friction in the bearing according to the invention (curve A) increases to a maximum level after 200 flight tests and remains substantially constant thereafter, whereas the friction in the "standard" bearing (curve B) continues to increase beyond this point and eventually exceeds the maximum level of the bearing according to the invention.
Another series of comparative tests were conducted employing smaller diameter bearings than in the previous tests and in which the outer bearing race 1 was composed of chromium plated titanium and the inner bearing 3 was composed of titanium with different surface finishes as indicated below. In each case, a test load of 69 MPa was applied and the inner bearing was made to rotate back and forth through an angle of 50° at a frequency of 0.25 Hz. The relative distance of sliding between the two members 1 and 3 was 25mm each cycle. The life of the bearings as determined from wear between their cooperating surfaces were assessed as follows:
CYCLES
Chromium plate Chromium oxide Tungsten carbide Aluminium bronze Bronze "NEDOX"
Figure imgf000008_0001
These results clearly demonstrate the superior life achieved when using a "NEDOX" surface finish as compared with the other surface finishes.

Claims

1. A sliding contact bearing comprising two bearing members composed of titanium or a titanium alloy with cooperating sliding surfaces, a first one of which is chromium plated and the second one of which is coated with nickel and fluorocarbon polymer.
2. A bearing as claimed in claim 1 in which the nickel coating is applied by an electroless plating process.
3. A bearing as claimed in claims 1 or 2 in which the fluorocarbon is infused into pores in the nickel plating.
4. A bearing as claimed in any one of claims 1 to 5 in which the coating has a hardness 750 - 1000 VPN.
5. An aircraft landing gear trunnion bearing comprising two bearing members as claimed in any one of the preceding claims, one bearing member being an outer ring-shaped bearing race, and the other being an inner ring-shaped bearing member located within the outer bearing race with their respective cooperating sliding surfaces formed on a sphere.
6. A bearing as claimed in claim 5 in which the sliding surface of the outer bearing race is chromium plated and the sliding surface of the inner bearing race is coated with nickel and fluorocarbon polymer.
7. A bearing substantially as herein described with reference to the accompanying drawings.
PCT/GB1993/001537 1992-07-21 1993-07-21 Bearings WO1994002750A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US08/373,255 US5660482A (en) 1992-07-21 1993-07-21 Bearings
JP50429294A JP3431152B2 (en) 1992-07-21 1993-07-21 bearing
DE69307321T DE69307321T2 (en) 1992-07-21 1993-07-21 CAMP
EP93917881A EP0651862B1 (en) 1992-07-21 1993-07-21 Bearings

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9215470.7 1992-07-21
GB9215470A GB2268982B (en) 1992-07-21 1992-07-21 Bearings

Publications (1)

Publication Number Publication Date
WO1994002750A1 true WO1994002750A1 (en) 1994-02-03

Family

ID=10719042

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1993/001537 WO1994002750A1 (en) 1992-07-21 1993-07-21 Bearings

Country Status (6)

Country Link
US (1) US5660482A (en)
EP (1) EP0651862B1 (en)
JP (1) JP3431152B2 (en)
DE (1) DE69307321T2 (en)
GB (1) GB2268982B (en)
WO (1) WO1994002750A1 (en)

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IT1264662B1 (en) * 1993-07-05 1996-10-04 Ausimont Spa PERFLURODIOSSOLS THEIR HOMOPOLYMERS AND COPOLYMERS AND THEIR USE FOR THE COATING OF ELECTRIC CABLES
US5961218A (en) * 1996-02-20 1999-10-05 Ebara Corporation Water lubricated machine component having contacting sliding surfaces
WO1999060847A1 (en) * 1998-05-27 1999-12-02 Berkley Inc. Metallic fishing line guides
JP2001193741A (en) * 2000-01-05 2001-07-17 Minebea Co Ltd Spherical sliding bearing and manufacturing method
US6520703B1 (en) 2000-09-13 2003-02-18 Honeywell International, Inc. Coupling with tribological coating system
US20020173853A1 (en) * 2001-05-17 2002-11-21 Corl Harry E. Movable joint and method for coating movable joints
US20030234183A1 (en) * 2001-05-17 2003-12-25 Noble Medical Coatings, Llc Movable joint and method for coating movable joints
US20050211562A1 (en) * 2001-05-17 2005-09-29 Rowe Thomas G Method for coating joint surfaces of metals used to form prostheses
DE10220611A1 (en) * 2002-02-15 2003-08-28 Brueninghaus Hydromatik Gmbh rotary bearings
WO2003069174A1 (en) * 2002-02-15 2003-08-21 Brueninghaus Hydromatik Gmbh Swivel slide bearing
US6619758B1 (en) * 2002-02-25 2003-09-16 Amara Ross Wheel and bearing assembly
GB2406622B (en) * 2003-10-02 2005-08-17 Minebea Co Ltd Self-lubricating bearings
GB2412701B (en) * 2004-03-31 2006-03-22 Minebea Co Ltd A metal-to-metal spherical bearing
US20070164151A1 (en) * 2006-01-13 2007-07-19 Luce William E Aircraft shock strut and improved bearings therefor
DE602007011406D1 (en) * 2006-01-13 2011-02-03 Goodrich Corp PLANE SPRING LEG WITH IMPROVED CYLINDER AND IMPROVED STORAGE
US20090010580A1 (en) * 2006-07-19 2009-01-08 Roller Bearing Company Of America, Inc. Spherical plain bearing with spread sealing means
US20080019625A1 (en) * 2006-07-19 2008-01-24 Roller Bearing Company Of America, Inc. Spherical plain bearing with contoured lubrication grooves
US8926185B2 (en) 2006-07-19 2015-01-06 Roller Bearing Company Of America, Inc. Spherical plain bearing with lubrication groove
US20090003743A1 (en) * 2007-06-26 2009-01-01 Roller Bearing Company Of America, Inc. Bearing for kingpin or other shaft assembly
US9192975B2 (en) * 2009-01-30 2015-11-24 Larry John Verbowski Vehicle suspension module
DE102011077735B4 (en) 2011-06-17 2019-02-28 Schaeffler Technologies AG & Co. KG Spherical plain bearings
GB2508043B (en) 2013-04-17 2015-07-22 Messier Dowty Ltd Dynamic bearing
FR3018322B1 (en) * 2014-03-10 2016-11-04 Skf Aerospace France PERMANENT LUBRICATING JOINT BONDING MEMBER
US10724575B2 (en) * 2017-06-15 2020-07-28 Schaublin Sa Metallic lined trunnion bearing for aircraft landing gear
US10480569B2 (en) * 2017-06-15 2019-11-19 Schaublin Sa Hybrid lined trunnion bearing for aircraft landing gear

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FR2218797A5 (en) * 1973-02-16 1974-09-13 Metallisation Ste Nle Self-lubricating surface mfr. - by flame spraying a layer of metal and filling the pores with polymer
US4846122A (en) * 1985-09-26 1989-07-11 Sycon Corporation Pneumatic starter for internal combustion engine
US4848934A (en) * 1985-01-11 1989-07-18 The Boeing Company Lightweight high performance titanium sliding contact bearing
US4938850A (en) * 1988-09-26 1990-07-03 Hughes Aircraft Company Method for plating on titanium

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FR2218797A5 (en) * 1973-02-16 1974-09-13 Metallisation Ste Nle Self-lubricating surface mfr. - by flame spraying a layer of metal and filling the pores with polymer
US4848934A (en) * 1985-01-11 1989-07-18 The Boeing Company Lightweight high performance titanium sliding contact bearing
US4846122A (en) * 1985-09-26 1989-07-11 Sycon Corporation Pneumatic starter for internal combustion engine
US4938850A (en) * 1988-09-26 1990-07-03 Hughes Aircraft Company Method for plating on titanium

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PATENT ABSTRACTS OF JAPAN vol. 13, no. 420 (M-872)19 September 1989 *

Also Published As

Publication number Publication date
GB2268982A (en) 1994-01-26
DE69307321T2 (en) 1997-04-24
GB2268982B (en) 1996-03-13
EP0651862B1 (en) 1997-01-08
JPH07509298A (en) 1995-10-12
JP3431152B2 (en) 2003-07-28
EP0651862A1 (en) 1995-05-10
DE69307321D1 (en) 1997-02-20
GB9215470D0 (en) 1992-09-02
US5660482A (en) 1997-08-26

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