WO1993011082A1 - Method for manufacturing cement - Google Patents

Method for manufacturing cement Download PDF

Info

Publication number
WO1993011082A1
WO1993011082A1 PCT/DK1992/000310 DK9200310W WO9311082A1 WO 1993011082 A1 WO1993011082 A1 WO 1993011082A1 DK 9200310 W DK9200310 W DK 9200310W WO 9311082 A1 WO9311082 A1 WO 9311082A1
Authority
WO
WIPO (PCT)
Prior art keywords
gypsum
clinker
cooler
clinker cooler
cement
Prior art date
Application number
PCT/DK1992/000310
Other languages
French (fr)
Inventor
Jan Folsberg
Original Assignee
F.L. Smidth & Co. A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by F.L. Smidth & Co. A/S filed Critical F.L. Smidth & Co. A/S
Priority to DE69203096T priority Critical patent/DE69203096T2/en
Priority to KR1019930703504A priority patent/KR970001241B1/en
Priority to PL92303922A priority patent/PL168754B1/en
Priority to EP92923699A priority patent/EP0614451B1/en
Priority to BR9206503A priority patent/BR9206503A/en
Publication of WO1993011082A1 publication Critical patent/WO1993011082A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/14Acids or salts thereof containing sulfur in the anion, e.g. sulfides
    • C04B22/142Sulfates
    • C04B22/143Calcium-sulfate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/47Cooling ; Waste heat management

Definitions

  • the present invention relates to a method for manufacturing cement.
  • the added gypsum usually contains water which is required to be removed to avoid setting of the cement, and in grinding plants comprising a tube mill, the dehydration and drying of the gypsum often take place in the mill, in which the temperature is relatively high.
  • Tube mills are, however, relatively much energy-demanding, and in fact the tendency today is that roller mills are used instead for finish-grinding of cement due to their higher efficiency.
  • Another proposed solution to the problem consists of heating the material during the grinding by means of gas from a heat generator or by means of excess air from a clinker cooler, but as the retention time in, e.g., a roller mill is very short, the possibilities of obtaining a sufficient drying of the gypsum are very small.
  • the object of the invention is therefore to provide for a method for manufacturing cement, by which method the abovementioned disadvantages by the known methods are avoided.
  • this object is obtained by a method of the kind mentioned in the introduction, and which is characterized in that at least a part of the gypsum required for the cement manufacturing is added to the clinker in the clinker cooler.
  • the gypsum can be dehydrated and dried in a simple manner by means of the heated air resulting from the cooling of the clinker, and which usually is directed into the atmosphere via i.a. a filter.
  • the retention time of the gypsum in the cooler may furthermore be adapted to fine as well as coarse types of gypsum so that these can be dried and dehydrated without previous grinding.
  • the mixture of clinker and gypsum is transported from the clinker cooler onto a grinding plant where the finish grinding into cement takes place.
  • the amount of gypsum charged into the cooler is smaller than or equal to the smallest amount of gypsum required in the finished cement.
  • any fine adjustment of the gypsum percentage may be performed in the usual manner by adding gypsum during the finish grinding.
  • the temperature of the gypsum and its retention time in the clinker cooler may be regulated to the required dehydration degree by charging the gypsum into the clinker cooler at one or several different positions along the longitudinal direction of the cooler.
  • the gypsum is charged into the last section of the clinker cooler.
  • the cooling air from the last section of the clinker cooler with its content of gypsum dust is passed to a separator in which the gypsum dust is separated from the air and returned to the clinker/gypsum mixture somewhere after the clinker cooler.
  • the plant comprises a rotary kiln 1, a clinker cooler 3 with an outlet 4, and an air duct 5 for supply of hot air from the clinker cooler 3 to a preheater not shown.
  • Clinker material leaving the clinker cooler 3 via the outlet 4 drops onto a feed conveyor 7 conveying the material to a roller press 9.
  • gypsum may be charged into the clinker cooler 3 at charging points 11 distributed along the longitudinal direction of the clinker cooler.
  • the clinker cooler 3 may include a screen 12 which reduces the air flow from the last section 13 of the clinker cooler in the direction towards the kiln 1.
  • the air from the last section of the clinker cooler can, therefore, with its content of gypsum dust, be passed via a separate duct 15 to a separator 17, which, e.g., may be a separation cyclone, a bag filter or an electrostatic precipitator, from which the separated dust is returned via a line 19 to the clinker/gypsum mixture, e.g., on the feeding belt conveyor 7.
  • the gypsum When charging the gypsum into the clinker cooler 3 as proposed according to the invention, the gypsum is dehydrated and dried during its transport together with the hot clinker material through the cooler, and any additional gypsum to be 15 added for adjustment of the gypsum percentage may, e.g., be added from a gypsum container 21 via a line 23.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Crushing And Grinding (AREA)

Abstract

A method for manufacturing cement is described, by which gypsum is added to the clinker in the clinker cooler (3). Hereby it is obtained that the gypsum is dried in a safe, simple and inexpensive manner without substantial additional costs for establishment and operation.

Description

Method for manufacturing cement
The present invention relates to a method for manufacturing cement.
Hitherto, in manufacturing cement it has been common practice that the finish-burnt and cooled clinker material is mixed with gypsum and possibly other additives and subsequently finish-ground in a grinding plant.
The added gypsum usually contains water which is required to be removed to avoid setting of the cement, and in grinding plants comprising a tube mill, the dehydration and drying of the gypsum often take place in the mill, in which the temperature is relatively high.
Tube mills are, however, relatively much energy-demanding, and in fact the tendency today is that roller mills are used instead for finish-grinding of cement due to their higher efficiency.
However, the temperature in roller mills is rarely so high that a sufficient drying of the added gypsum is obtained, which has an adverse influence on the cement properties.
This problem have been solved by adding gypsum which, before the addition, is dehydrated and dried in a separate drying installation, but this increases the preliminary expenses as well as the operating costs.
Another proposed solution to the problem consists of heating the material during the grinding by means of gas from a heat generator or by means of excess air from a clinker cooler, but as the retention time in, e.g., a roller mill is very short, the possibilities of obtaining a sufficient drying of the gypsum are very small.
The object of the invention is therefore to provide for a method for manufacturing cement, by which method the abovementioned disadvantages by the known methods are avoided.
According to the invention, this object is obtained by a method of the kind mentioned in the introduction, and which is characterized in that at least a part of the gypsum required for the cement manufacturing is added to the clinker in the clinker cooler.
Hereby the gypsum can be dehydrated and dried in a simple manner by means of the heated air resulting from the cooling of the clinker, and which usually is directed into the atmosphere via i.a. a filter. By being able to vary the charging point for the gypsum into the cooler, the retention time of the gypsum in the cooler may furthermore be adapted to fine as well as coarse types of gypsum so that these can be dried and dehydrated without previous grinding.
By the method according to the invention it is thus obtained in relation to the methods using dehydration and drying in the actual grinding installation or in a separate drying installation, that the gypsum is dried in a safe, simple and inexpensive manner without subtantial additional costs for establishment and operation.
The mixture of clinker and gypsum is transported from the clinker cooler onto a grinding plant where the finish grinding into cement takes place. To be able to manufacture different cement types containing different amounts of gypsum, it is preferred that the amount of gypsum charged into the cooler is smaller than or equal to the smallest amount of gypsum required in the finished cement. Subsequently, any fine adjustment of the gypsum percentage may be performed in the usual manner by adding gypsum during the finish grinding.
Dependent on the required dehydration degree of the gypsum, the temperature of the gypsum and its retention time in the clinker cooler may be regulated to the required dehydration degree by charging the gypsum into the clinker cooler at one or several different positions along the longitudinal direction of the cooler.
To reduce the amount of gypsum dust which can enter the cement kiln, and/or preheater and calciner, together with the cooling air, it is preferred that the gypsum is charged into the last section of the clinker cooler.
However, it cannot be avoided that a part of the gypsum dust is entrained in the cooling air from the clinker cooler, and it is therefore preferred that the cooling air from the last section of the clinker cooler with its content of gypsum dust is passed to a separator in which the gypsum dust is separated from the air and returned to the clinker/gypsum mixture somewhere after the clinker cooler.
The invention will now be described in further details, with reference to the drawing, being diagrammatical and showing a part of a cement manufacturing plant, where the method according to the invention can be practised.
The plant comprises a rotary kiln 1, a clinker cooler 3 with an outlet 4, and an air duct 5 for supply of hot air from the clinker cooler 3 to a preheater not shown. Clinker material leaving the clinker cooler 3 via the outlet 4 drops onto a feed conveyor 7 conveying the material to a roller press 9.
In the plant shown, gypsum may be charged into the clinker cooler 3 at charging points 11 distributed along the longitudinal direction of the clinker cooler.
The clinker cooler 3 may include a screen 12 which reduces the air flow from the last section 13 of the clinker cooler in the direction towards the kiln 1. The air from the last section of the clinker cooler can, therefore, with its content of gypsum dust, be passed via a separate duct 15 to a separator 17, which, e.g., may be a separation cyclone, a bag filter or an electrostatic precipitator, from which the separated dust is returned via a line 19 to the clinker/gypsum mixture, e.g., on the feeding belt conveyor 7.
When charging the gypsum into the clinker cooler 3 as proposed according to the invention, the gypsum is dehydrated and dried during its transport together with the hot clinker material through the cooler, and any additional gypsum to be 15 added for adjustment of the gypsum percentage may, e.g., be added from a gypsum container 21 via a line 23.

Claims

PATENT CLAIMS
1. Method for manufacturing cement in a plant comprising a clinker cooler (3), c h a r a c t e r i z e d in, that at least a part of the gypsum required for the cement manufacturing is added to the clinker in the clinker cooler (3).
2. Method according to claim 1, c h a r a c t e r i z e d i n, that the amount of gypsum charged into the clinker cooler (3) is smaller than or equal to the smallest amount of gypsum required in the finished cement.
3. Method according to claims 1 or 2, c h a r a c t e - r i z e d i n, that the gypsum is charged into the clinker cooler (3) at one or several positions (11) along the longitudinal direction of the cooler.
4. Method according to claims 1, 2 or 3, c h a r a c - t e r i z e d i n, that the gypsum is charged into the last section (13) of the clinker cooler.
5. Method according to any of claims 1-4, c h a r a c ¬ t e r i z e d , that the cooling air from the last section (13) of the clinker cooler with its content of gypsum dust is passed to a separator (17) in which the gypsum dust is separated from the air and returned to the clinker/gypsum mixture somewhere after the clinker cooler (3).
PCT/DK1992/000310 1991-11-27 1992-10-26 Method for manufacturing cement WO1993011082A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
DE69203096T DE69203096T2 (en) 1991-11-27 1992-10-26 METHOD FOR PRODUCING CEMENT.
KR1019930703504A KR970001241B1 (en) 1991-11-27 1992-10-26 Method for manufacturing cement
PL92303922A PL168754B1 (en) 1991-11-27 1992-10-26 Cement manufacturing method
EP92923699A EP0614451B1 (en) 1991-11-27 1992-10-26 Method for manufacturing cement
BR9206503A BR9206503A (en) 1991-11-27 1992-10-26 Method for the manufacture of cement

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DK1922/91 1991-11-27
DK192291A DK169177B1 (en) 1991-11-27 1991-11-27 Process for making cement

Publications (1)

Publication Number Publication Date
WO1993011082A1 true WO1993011082A1 (en) 1993-06-10

Family

ID=8108990

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DK1992/000310 WO1993011082A1 (en) 1991-11-27 1992-10-26 Method for manufacturing cement

Country Status (14)

Country Link
US (1) US5449404A (en)
EP (1) EP0614451B1 (en)
KR (1) KR970001241B1 (en)
CN (1) CN1072911A (en)
BR (1) BR9206503A (en)
CZ (1) CZ281923B6 (en)
DE (1) DE69203096T2 (en)
DK (1) DK169177B1 (en)
ES (1) ES2073937T3 (en)
MX (1) MX9206777A (en)
PL (1) PL168754B1 (en)
TW (1) TW203576B (en)
WO (1) WO1993011082A1 (en)
ZA (1) ZA928823B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19647484A1 (en) * 1996-11-16 1998-05-20 Deutz Ag Cement manufacturing process with reduced costs

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL328166A1 (en) * 1995-10-31 1999-01-18 Joseph E Doumet Method of and apparatus for obtaining cement clinker
US5837052A (en) * 1997-04-10 1998-11-17 Lafarge Canada Inc. Process for producing cement clinker containing coal ash
DE10333361A1 (en) * 2003-07-23 2005-02-10 Gebr. Pfeiffer Ag Process for preparation of cement e.g. Portland cement involves milling cement clinker with sulfate containing carrier material and other components in a roller mill
CN103085171A (en) * 2013-01-17 2013-05-08 倪文龙 Secondary burdening process for desulfurized gypsum
CN103322818A (en) * 2013-05-29 2013-09-25 中信重工机械股份有限公司 Cement clinker cooling system and method

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1551269A (en) * 1975-08-27 1979-08-30 Perlmooser Zementwerke Ag Process for the production of a mixture to be utilised in the production of building materials and a device for carrying out the process
DE3424170A1 (en) * 1984-06-30 1986-02-27 Metallgesellschaft Ag, 6000 Frankfurt CLINKER COOLER WITH DEDUSTING DEVICE IN A METHOD FOR THE PRODUCTION OF CEMENT

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD201137A1 (en) * 1981-08-07 1983-07-06 Bernd Gerstner METHOD FOR PRODUCING BELITIOUS CEMENT
SU1313821A1 (en) * 1986-12-04 1987-05-30 Грузинский политехнический институт им.В.И.Ленина Method for cooling cement clinker
JP3016567B2 (en) * 1989-12-28 2000-03-06 住友大阪セメント株式会社 Method for producing spherical cement and apparatus for producing spherical cement

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1551269A (en) * 1975-08-27 1979-08-30 Perlmooser Zementwerke Ag Process for the production of a mixture to be utilised in the production of building materials and a device for carrying out the process
DE3424170A1 (en) * 1984-06-30 1986-02-27 Metallgesellschaft Ag, 6000 Frankfurt CLINKER COOLER WITH DEDUSTING DEVICE IN A METHOD FOR THE PRODUCTION OF CEMENT

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DERWENT'S ABSTRACT, No. 88-12997/02, Week 8802; & SU,A,1 313 821 (GEOR POLY), 30 May 1987. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19647484A1 (en) * 1996-11-16 1998-05-20 Deutz Ag Cement manufacturing process with reduced costs

Also Published As

Publication number Publication date
CZ117394A3 (en) 1995-01-18
DK192291A (en) 1993-05-28
KR970001241B1 (en) 1997-02-04
ZA928823B (en) 1993-05-13
MX9206777A (en) 1993-05-01
US5449404A (en) 1995-09-12
CZ281923B6 (en) 1997-04-16
DE69203096D1 (en) 1995-07-27
EP0614451B1 (en) 1995-06-21
ES2073937T3 (en) 1995-08-16
TW203576B (en) 1993-04-11
DK192291D0 (en) 1991-11-27
CN1072911A (en) 1993-06-09
DE69203096T2 (en) 1996-02-29
BR9206503A (en) 1995-11-21
EP0614451A1 (en) 1994-09-14
DK169177B1 (en) 1994-09-05
PL168754B1 (en) 1996-04-30

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