WO1993005876A1 - Support for liner elements consisting of the assembly of a plurality of strands, threads or filaments, and plant for treating fluid made from such supports - Google Patents

Support for liner elements consisting of the assembly of a plurality of strands, threads or filaments, and plant for treating fluid made from such supports Download PDF

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Publication number
WO1993005876A1
WO1993005876A1 PCT/FR1992/000888 FR9200888W WO9305876A1 WO 1993005876 A1 WO1993005876 A1 WO 1993005876A1 FR 9200888 W FR9200888 W FR 9200888W WO 9305876 A1 WO9305876 A1 WO 9305876A1
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WO
WIPO (PCT)
Prior art keywords
envelope
support according
strands
support
filaments
Prior art date
Application number
PCT/FR1992/000888
Other languages
French (fr)
Inventor
Alain Christian Berganton
Original Assignee
Aquaculture Et Traitement De L'eau En Armagnac
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Aquaculture Et Traitement De L'eau En Armagnac filed Critical Aquaculture Et Traitement De L'eau En Armagnac
Publication of WO1993005876A1 publication Critical patent/WO1993005876A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30207Sphere
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30Details relating to random packing elements
    • B01J2219/302Basic shape of the elements
    • B01J2219/30269Brush
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • the invention relates to a support for packing elements intended to be introduced into a reaction medium with a view to promoting exchanges or reactions between chemical, biological reagents ... brought into contact, and each consisting of the assembly of 'a plurality of strands, threads or filaments. It extends to a fluid treatment installation comprising such supports and such packing elements. At the present time, there are mainly two types of design relating to fluid installations using packing elements constituted by the assembly of strands, threads or filaments.
  • these elements are arranged in bulk, in any directions so that the strands constituting two neighboring elements are entangled.
  • An installation produced according to this principle is described in particular in US patent. 2,229,386.
  • the drawback of such installations lies in the fact that they do not make it possible to obtain a good compromise between a specific useful surface area for significant exchange and a low risk of clogging.
  • any increase in the exchange surface and therefore in the potential yield leads to an increase in pressure drops and, consequently, increases the risks of clogging.
  • the only solution to reach a satisfactory compromise actually lies in playing on the hydraulic regime.
  • this solution is generally expensive in energy and, on the other hand, it is the source of hydraulic problems such as preferential passages ...
  • the packing elements are fixed on supports adapted to maintain them, with respect to each other, at a distance such that the strands constituting these packing elements have no risk of getting tangled.
  • An installation according to this principle is described in particular in European patent EP 165,862 and comprises, as a support system for the lining elements, a plurality of tensioning wires arranged inside a reactor, at a distance from each other, and on which are hung these trim elements.
  • the present invention aims to overcome this drawback of installations carried out according to the principle mentioned above, and has the main objective of providing a support system for packing elements which is very easy to use and has a very low cost price allowing the realization of large volume installations.
  • the invention relates to a support for packing elements intended to be introduced into a reaction medium with a view to promoting exchanges or reactions between chemical, biological reagents ... brought together, and each consisting of a plurality of strands, son or filaments assembled so as to deploy freely when they are immersed in a fluid medium.
  • this support is characterized in that it comprises, for each lining element:
  • the main objective of the invention has therefore been to produce supports, on the one hand, whose envelope has the largest vacuum index and the smallest possible exchange surface, and on the other hand, designed to to maintain the packing elements so that they are completely independent of each other.
  • the invention therefore makes it possible to produce, at low cost, installations having a large specific useful exchange surface and which are not likely to become clogged.
  • the fluid flow is exploded in such a way that it cannot create preferential paths.
  • the envelope has a shape and delimits an internal volume suitable for the filling elements to fill substantially all of said internal volume, in their deployed state.
  • each envelope preferably has a percentage of empty area greater than 90%.
  • the envelope of the latter is advantageously consisting of two half-shells provided with latching means for their assembly or intended to be assembled by heat welding.
  • a support is thus particularly suitable for housing packing elements with very high specific surface, as described in patent EP 165,862, and comprising a plurality of strands, threads or filaments joined in their middle so as to form a pompom.
  • the envelope then preferably has a spherical shape, and the holding means are adapted to hold a lining element so that the meeting point of the strands, son or filaments is located in the center of the 'envelope.
  • the holding means preferably comprise an internal candle extending orthogonally to the envelope and having a length substantially equal to the radius of said envelope, said candle having a free end provided with means for holding a packing element.
  • the free end of this candle can thus have a longitudinal slot capable of accommodating the meeting point of a lining element, the holding means being adapted to wedge said filling element in said slot.
  • the envelope is then advantageously made up of two half-shells of identical semi-spherical shape, the candle being provided with one end, opposite its free end, provided with a longitudinal hole suitable for allowing the attachment of said candle to a half-shell by means of a fixing element.
  • the invention also extends to a fluid treatment installation of the type comprising an enclosure provided with means for supplying fluid and evacuation means after treatment, and packing elements arranged inside the enclosure and each consisting of a plurality of strands, son or filaments assembled so as to deploy freely when said enclosure is filled with fluid.
  • each lining element is disposed inside a support comprising: - a rigid envelope hollowed out over its largest surface and delimiting an internal volume capable of housing the lining element in its deployed state ,
  • FIG. 1 is a perspective view, in exploded mode, of a support and of a packing element according to the invention
  • FIG. 2 is a longitudinal section of this support containing a packing element in the deployed state
  • FIG. 3 is a schematic section of one of the possible configurations of fluid treatment installation equipped with supports according to the invention.
  • the support shown in Figures 1 and 2 is intended to individually accommodate a packing element 1 held inside this support so that it can deploy freely.
  • This packing element 1, shown in FIG. 1 which is not deployed, is a pompom as described in European patent EP 165,862. It is made up of a plurality of strands, threads or filaments joined in their middle and assembled at this point by means of a ring 2.
  • Each of the supports intended to house these pompoms 1 comprises, first of all, two strictly identical half-shells 3 . 4 of semi-spherical shape. These half-shells 3, 4 are provided with latching means 5, 6 making it possible to assemble them so that they form a spherical envelope delimiting an internal volume equivalent to the volume of a pompon 1 in its deployed state.
  • each spherical envelope thus has a diameter of sixteen centimeters.
  • each half-shell 3, 4 is composed of arcs such as 7 extending along meridians uniformly distributed around the axis of revolution. These arcs 7, eight in number, further form, at the pole of the half-shell 3 ⁇ 4, a small circular cap 8, for example three centimeters in diameter, pierced with an orifice 8a.
  • Each half-shell 3, 4 further comprises a hoop 9 forming a large circle connecting the end of the arcs 7 and carrying the latching means 5, 6.
  • an intermediate hoop 10 for reinforcement also connects the arcs 7 away from their ends.
  • such half-shells 3, 4 are provided with a surface having a very high percentage of vacuum, greater than 90%.
  • the latching means of these two half-shells are made up of male 6 and female 5 organs arranged in conjugate positions on the hoops 9 so that a male organ 6 of a half-shell (3 or 4) corresponds to a female member 5 of the other half-shell (4 or
  • the female organs consist of a slide 5 formed on the external face of the hoop 9. These slides 5 are two in number per half-shells 3 . 4 and are arranged to be diametrically opposed.
  • the male members consist of a locking ring 6 adapted to snap into a slide 5 so as to bring the hoops 9 of the half-shells 3, 4 to 'contact one another.
  • These heels 6 are also two in number per half-shells 3, 4 and are arranged so as to be diametrically opposite, according to a diameter orthogonal to the diameter connecting the slides 5.
  • each support comprises means for holding the pompom 1 capable of maintaining the meeting point of the strands of this pompom positioned at the center of the spherical envelope, after assembly of the half-shells 3, 4.
  • These holding means consist of a candle 11 of length substantially greater than that of the radius of the sphere comprising, firstly, a hollow tubular rod 12 split longitudinally and over a given length from one of its ends 12a. This rod 12 also has an opposite end 12b flared outwardly.
  • This candle further comprises a first sleeve 13 adapted to abut against the flared end 12b of the rod 12 and to house the latter over a length corresponding substantially to its unsplit length. It finally comprises a second sleeve 14 capable of accommodating the rod 12 over a length of the latter substantially less than its split length.
  • a candle 11 makes it possible to maintain a pompom 1 housed in the slot 12a of the rod 12 by wedging the latter between the two sleeves 13, 14, the longitudinal locking of the second sleeve 14 being ensured, for example, by thermo-deformation of the end of said sleeve and of the rod.
  • This candle 11 has the advantage of leaving a maximum internal volume of the support free of obstacles opposing the deployment of the pompom 1. It also has the advantage of being able to be introduced in the support once the half-shells 3 > 4 are assembled, its fixing then being ensured by means of a simple screw 15 housed in the orifice 8a of one of said half-shells.
  • the main advantage of the supports described above resides in the fact that they can be introduced in bulk into a reactor, thus making the production of large reactors easily accessible.
  • FIG. 3 schematically represents such a reactor of the bottom feed type and overflow discharge.
  • This reactor conventionally comprises a closed enclosure 16 comprising a perforated intermediate floor 17, supply means 18 disposed under the perforated floor of the enclosure, and consisting of a pipe pierced, for example in the shape of a star, and an outlet d 'evacuation 19 disposed in the upper part of the enclosure.
  • This enclosure 16 is filled over a given height above the floor 17 with a plurality of supports 3, 4 arranged in bulk, each containing a pompon 1 and adapted so that said pompoms can deploy freely without coming to become entangled so occupy the maximum volume of the enclosure and thus provide a maximum specific exchange surface.
  • This enclosure further comprises a perforated floor 20 disposed in the upper part above the last layer of supports 3, 4. This floor 20 is intended to trap all of the supports in the reaction medium.
  • a recirculation loop 21 provided with a pump 22, intended to collect the effluent in the upper part of the enclosure 16, just below the level of the discharge outlet 19, and to reinject the latter. in the lower part of the enclosure 16 by means of a distribution ramp 23.
  • a recirculation loop 21 has, conventionally, the role of diluting the effluent as it enters the reactor.

Abstract

Support for liner elements (1) inserted into a rective medium for the purpose of promoting exchanges or reactions between chemical, biological and similar reagents. Each liner element consists of a plurality of strands, threads or filaments assembled in order to be freely deployed when immersed in a fluid medium. The support comprises, for each liner element, a rigid frame (3, 4) having openings provided therein, delimiting an inner volume capable of receiving the liner element (1) in its deployed state, and means (11, 12) for retaining said liner element (1) adapted to enable the latter to be deployed within the volume delimited by the frame.

Description

SUPPORT POUR ELEMENTS DE GARNISSAGE CONSTITUES PAR L'ASSEMBLAGE D'UNE PLURALITE DE BRINS, FILS OU FILAMENTS, ET INSTALLATION DE TRAITEMENT DE FLUIDE REALISEE A PARTIR DE TELS SUPPORTS. SUPPORT FOR TRIM ELEMENTS CONSISTING OF THE ASSEMBLY OF A PLURALITY OF STRANDS, WIRES OR FILAMENTS, AND FLUID TREATMENT INSTALLATION MADE FROM SUCH SUPPORTS.
L'invention concerne un support pour éléments de garnissage destinés à être introduits dans un milieu réactionnel en vue de favoriser des échanges ou des réactions entre des réactifs chimiques, biologiques... mis en présence, et constitués, chacun, par l'assemblage d'une pluralité de brins, fils ou filaments. Elle s'étend à une installation de traitement de fluide comportant de tels supports et de tels éléments de garnissage. II existe principalement à l'heure actuelle deux types de conception concernant les installations de fluide utilisant des éléments de garnissage constitués par l'assemblage de brins, fils ou filaments.The invention relates to a support for packing elements intended to be introduced into a reaction medium with a view to promoting exchanges or reactions between chemical, biological reagents ... brought into contact, and each consisting of the assembly of 'a plurality of strands, threads or filaments. It extends to a fluid treatment installation comprising such supports and such packing elements. At the present time, there are mainly two types of design relating to fluid installations using packing elements constituted by the assembly of strands, threads or filaments.
Selon une première conception, ces éléments sont disposés en vrac, dans des directions quelconques de façon que les brins constitutifs de deux éléments voisins viennent s'enchevêtrer. Une installation réalisée selon ce principe est notamment décrite dans le brevet US ..229.386. L'inconvénient de telles installations réside dans le fait qu'elles ne permettent pas d'obtenir un bon compromis entre une surface spécifique utile d'échange importante et un risque de colmatage faible. En effet, toute augmentation de la surface d'échange et donc du rendement potentiel entraîne une augmentation des pertes de charge et, par conséquent, augmente les risques de colmatage. La seule solution pour parvenir à un compromis satisfaisant réside en fait à jouer sur le régime hydraulique. Toutefois, d'une part, cette solution coûte généralement cher en énergie et, d'autre part, elle est la source de problèmes hydrauliques tels que passages préférentiels...According to a first design, these elements are arranged in bulk, in any directions so that the strands constituting two neighboring elements are entangled. An installation produced according to this principle is described in particular in US patent. 2,229,386. The drawback of such installations lies in the fact that they do not make it possible to obtain a good compromise between a specific useful surface area for significant exchange and a low risk of clogging. In fact, any increase in the exchange surface and therefore in the potential yield leads to an increase in pressure drops and, consequently, increases the risks of clogging. The only solution to reach a satisfactory compromise actually lies in playing on the hydraulic regime. However, on the one hand, this solution is generally expensive in energy and, on the other hand, it is the source of hydraulic problems such as preferential passages ...
Selon une deuxième conception, les éléments de garnissage sont fixés sur des supports adaptés pour les maintenir, les uns par rapport aux autres, à une distance telle que les brins constituant ces éléments de garnissage n'ont aucun risque de s'emmêler. Une installation selon ce principe est notamment décrite dans le brevet européen EP 165.862 et comporte, comme système de support des éléments de garnissage, une pluralité de fils tendeurs disposés à l'intérieur d'un réacteur, à distance les uns des autres, et sur lesquels sont accrochés ces éléments de garnissage.According to a second design, the packing elements are fixed on supports adapted to maintain them, with respect to each other, at a distance such that the strands constituting these packing elements have no risk of getting tangled. An installation according to this principle is described in particular in European patent EP 165,862 and comprises, as a support system for the lining elements, a plurality of tensioning wires arranged inside a reactor, at a distance from each other, and on which are hung these trim elements.
Cette solution permet, grâce au mouvement que prennent les brins autour de leur point d'attache, d'obtenir un garnissage présentant une surface spécifique utile importante qui ne risque pas de se colmater. Elle résout donc les inconvénients des installations évoquées en premier lieu. Toutefois, et en premier lieu, il s'avère qu'il se crée fréquemment des chemins préférentiels entre les lignes d'éléments de garnissage. De plus, la mise en oeuvre du système de support de telles installations s'avère beaucoup trop complexe et coûteuse pour que l'on puisse envisager de façon réaliste la réalisation de réacteurs d'un volume supérieur à quelques mètres cubes.This solution makes it possible, thanks to the movement taken by the strands around their point of attachment, to obtain a filling having a large specific useful surface which is not likely to become clogged. It therefore resolves the drawbacks of the installations mentioned first. However, and first of all, it turns out that preferential paths are frequently created between the lines of packing elements. In addition, the implementation of the support system for such installations proves to be far too complex and costly for one to realistically envisage the production of reactors with a volume greater than a few cubic meters.
La présente invention vise à pallier cet inconvénient des installations réalisées selon le principe ci-dessus évoqué, et a pour principal objectif de fournir un système de support pour éléments de garnissage de mise en oeuvre très facile et d'un coût de revient très faible permettant la réalisation d'installations de grands volumes.The present invention aims to overcome this drawback of installations carried out according to the principle mentioned above, and has the main objective of providing a support system for packing elements which is very easy to use and has a very low cost price allowing the realization of large volume installations.
A cet effet, l'invention vise un support pour éléments de garnissage destinés à être introduits dans un milieu reactionnel en vue de favoriser des échanges ou réactions entre des réactifs chimiques, biologiques... mis en présence, et constitués, chacun, d'une pluralité de brins, fils ou filaments assemblés de façon à se déployer librement lorsqu'ils sont plongés dans un milieu fluide. Selon l'invention, ce support se caractérise en ce qu'il comprend, pour chaque élément de garnissage :To this end, the invention relates to a support for packing elements intended to be introduced into a reaction medium with a view to promoting exchanges or reactions between chemical, biological reagents ... brought together, and each consisting of a plurality of strands, son or filaments assembled so as to deploy freely when they are immersed in a fluid medium. According to the invention, this support is characterized in that it comprises, for each lining element:
- une enveloppe rigide évidée sur sa plus grande surface et délimitant un volume interne apte à loger l'élément de garnissage dans son état déployé,- a rigid shell hollowed out over its larger surface and delimiting an internal volume capable of accommodating the packing element in its deployed state,
- des moyens de maintien dudit élément de garnissage adaptés pour permettre à ce. dernier de se déployer à l'intérieur du volume délimité par l'enveloppe.- means for retaining said packing element adapted to allow this. last to deploy within the volume delimited by the envelope.
L'objectif principal de l'invention a donc été de réaliser des supports, d'une part, dont l'enveloppe présente le plus grand indice de vide et la plus faible surface d'échange possibles, et d'autre part, conçus afin de maintenir les éléments de garnissage de façon que ces derniers soient totalement indépendants les uns des autres.The main objective of the invention has therefore been to produce supports, on the one hand, whose envelope has the largest vacuum index and the smallest possible exchange surface, and on the other hand, designed to to maintain the packing elements so that they are completely independent of each other.
Les principaux avantages de tels supports sont que, d'une part, ils ne constituent pas un obstacle au transfert entre les éléments de garnissage et le milieu reactionnel, et que, d'autre part, ces éléments de garnissage sont individualisés et peuvent être utilisés en vrac tout en gardant le principe de maintenir lesdits éléments de garnissage à une distance les uns par rapport aux autres telle que les brins de deux éléments voisins ne s'entremêlent pas.The main advantages of such supports are that, on the one hand, they do not constitute an obstacle to transfer between the lining elements and the reaction medium, and that, on the other hand, these lining elements are individualized and can be used in bulk while keeping the principle of maintaining said packing elements at a distance from each other such that the strands of two neighboring elements do not intermingle.
L'invention permet donc de réaliser, à un faible coût de revient, des installations présentant une surface spécifique utile d'échange importante et qui ne risquent pas de se colmater. En outre, selon ce principe, le flux de fluide se trouve éclaté de telle façon qu'il ne peut se créer de chemins préférentiels.The invention therefore makes it possible to produce, at low cost, installations having a large specific useful exchange surface and which are not likely to become clogged. In addition, according to this principle, the fluid flow is exploded in such a way that it cannot create preferential paths.
Selon une caractéristique de l'invention visant à fournir une installation dont la surface utile d'échange est maximale, l'enveloppe présente une forme et délimite un volume interne adaptés pour que les éléments de remplissage remplissent sensiblement la totalité dudit volume interne, dans leur état déployé.According to a characteristic of the invention aimed at providing an installation whose useful exchange surface is maximum, the envelope has a shape and delimits an internal volume suitable for the filling elements to fill substantially all of said internal volume, in their deployed state.
En outre, afin de minimiser au mieux les pertes de charge et les passages préférentiels, chaque enveloppe présente préf erentiellement un pourcentage de surface vide supérieur à 90 %.In addition, in order to minimize pressure losses and preferential passages as much as possible, each envelope preferably has a percentage of empty area greater than 90%.
Par ailleurs, en vue de faciliter la mise en place des éléments de garnissage à l'intérieur des supports, l'enveloppe de ces derniers est avantageusement constituée de deux demi-coques dotées de moyens d'encliquetage en vue de leur assemblage ou destinées à être assemblées par thermo-soudage. Un tel support est ainsi notamment adapté pour loger des éléments de garnissage à très forte surface spécifique, tels que décrits dans le brevet EP 165.862, et comportant une pluralité de brins, fils ou filaments réunis en leur milieu de façon à former un pompon. Selon l'invention, l'enveloppe présente alors , préf erentiellement, une forme sphérique, et les moyens de maintien sont adaptés pour maintenir un élément de garnissage de façon que le point de réunion des brins, fils ou filaments soit situé au centre de l'enveloppe. Dans ce cas, en outre, les moyens de maintien comportent préférentiellement une chandelle interne s'étendant orthogonalement à l'enveloppe et présentant une longueur sensiblement égale au rayon de ladite enveloppe, ladite chandelle présentant une extrémité libre dotée de moyens de maintien d'un élément de garnissage.Furthermore, in order to facilitate the fitting of the lining elements inside the supports, the envelope of the latter is advantageously consisting of two half-shells provided with latching means for their assembly or intended to be assembled by heat welding. Such a support is thus particularly suitable for housing packing elements with very high specific surface, as described in patent EP 165,862, and comprising a plurality of strands, threads or filaments joined in their middle so as to form a pompom. According to the invention, the envelope then preferably has a spherical shape, and the holding means are adapted to hold a lining element so that the meeting point of the strands, son or filaments is located in the center of the 'envelope. In this case, moreover, the holding means preferably comprise an internal candle extending orthogonally to the envelope and having a length substantially equal to the radius of said envelope, said candle having a free end provided with means for holding a packing element.
L'extrémité libre de cette chandelle peut ainsi présenter une fente longitudinale apte à loger le point de réunion d'un élément de garnissage, les moyens de maintien étant adaptés pour coincer ledit élément de remplissage dans ladite fente.The free end of this candle can thus have a longitudinal slot capable of accommodating the meeting point of a lining element, the holding means being adapted to wedge said filling element in said slot.
De plus, selon une autre caractéristique de l'invention, l'enveloppe est alors avantageusement constituée de deux demi-coques de formes semi-sphériques identiques, la chandelle étant dotée d'une extrémité, opposée à son extrémité libre, dotée d'un trou longitudinal apte à permettre la fixation de ladite chandelle à une demi-coque au moyen d'un élément de fixation.In addition, according to another characteristic of the invention, the envelope is then advantageously made up of two half-shells of identical semi-spherical shape, the candle being provided with one end, opposite its free end, provided with a longitudinal hole suitable for allowing the attachment of said candle to a half-shell by means of a fixing element.
Selon une variante, il peut être envisagé d'intégrer la chandelle à une des deux demi-coques lors du moulage de celle-ci.According to a variant, it can be envisaged to integrate the candle into one of the two half-shells during the molding of the latter.
L'invention s'étend également à une installation de traitement de fluide du type comprenant une enceinte dotée de moyens d'alimentation en fluide et de moyens d'évacuation après traitement, et des éléments de garnissage disposés à l'intérieur de l'enceinte et consistant chacun en une pluralité de brins, fils ou filaments assemblés de façon à se déployer librement lorsque ladite enceinte est remplie de fluide.The invention also extends to a fluid treatment installation of the type comprising an enclosure provided with means for supplying fluid and evacuation means after treatment, and packing elements arranged inside the enclosure and each consisting of a plurality of strands, son or filaments assembled so as to deploy freely when said enclosure is filled with fluid.
Cette installation se caractérise en ce que chaque élément de garnissage est disposé à l'intérieur d'un support comportant : - une enveloppe rigide évidée sur sa plus grande surface et délimitant un volume interne apte à loger l'élément de garnissage dans son état déployé,This installation is characterized in that each lining element is disposed inside a support comprising: - a rigid envelope hollowed out over its largest surface and delimiting an internal volume capable of housing the lining element in its deployed state ,
- des moyens de maintien dudit élément de garnissage adaptés pour permettre à ce dernier de se déployer à l'intérieur du volume délimité par l'enveloppe,means for holding said lining element adapted to allow the latter to deploy inside the volume delimited by the envelope,
- lesdits supports étant disposés en vrac dans l'enceinte de façon à être indépendants les uns des autres et à venir au contact les uns des autres par leur enveloppe. D'autres caracté istiques, buts et avantages de l'invention ressortiront de la description détaillée qui suit en référence aux dessins annexés qui en représentent à titre d'exemple non limitatif un mode de réalisation préférentiel. Sur ces dessins qui font partie intégrante de la présente description :- Said supports being arranged in bulk in the enclosure so as to be independent of each other and to come into contact with each other by their envelope. Other characteristics, objects and advantages of the invention will emerge from the detailed description which follows, with reference to the appended drawings which show by way of nonlimiting example a preferred embodiment. On these drawings which form an integral part of this description:
- la figure 1 est une vue en perspective, en mode éclaté, d'un support et d'un élément de garnissage conformes à l'invention,FIG. 1 is a perspective view, in exploded mode, of a support and of a packing element according to the invention,
- la figure 2 est une coupe longitudinale de ce support renfermant un élément de garnissage à l'état déployé,FIG. 2 is a longitudinal section of this support containing a packing element in the deployed state,
- la figure 3 est une coupe schématique d'une des configurations possibles d'installation de traitement de fluide équipée de supports conformes à l'invention.- Figure 3 is a schematic section of one of the possible configurations of fluid treatment installation equipped with supports according to the invention.
Le support représenté aux figures 1 et 2 est destiné à loger de façon individuelle un élément de garnissage 1 maintenu à l'intérieur de ce support de façon à pouvoir se déployer librement. Cet élément de garnissage 1, représenté à la figure 1 non déployé, est un pompon tel que décrit dans le brevet européen EP 165.862. Il se compose d'une pluralité de brins, fils ou filaments réunis en leur milieu et assemblés en ce point au moyen d'une bague 2.The support shown in Figures 1 and 2 is intended to individually accommodate a packing element 1 held inside this support so that it can deploy freely. This packing element 1, shown in FIG. 1 which is not deployed, is a pompom as described in European patent EP 165,862. It is made up of a plurality of strands, threads or filaments joined in their middle and assembled at this point by means of a ring 2.
Chacun des supports destinés à loger ces pompons 1 comporte, en premier lieu, deux demi-coques strictement identiques 3. 4 de forme semi-sphérique. Ces demi-coques 3, 4 sont dotées de moyens d'encliquetage 5, 6 permettant de les assembler de façon qu'elles forment une enveloppe sphérique délimitant un volume interne équivalent au volume d'un pompon 1 dans son état déployé. En l'exemple, chaque enveloppe sphérique présente ainsi un diamètre de seize centimètres.Each of the supports intended to house these pompoms 1 comprises, first of all, two strictly identical half-shells 3 . 4 of semi-spherical shape. These half-shells 3, 4 are provided with latching means 5, 6 making it possible to assemble them so that they form a spherical envelope delimiting an internal volume equivalent to the volume of a pompon 1 in its deployed state. In the example, each spherical envelope thus has a diameter of sixteen centimeters.
En premier lieu, chaque demi-coque 3, 4 se compose d'arcs tels que 7 s'étendant selon des méridiens uniformément répartis autour de l'axe de révolution. Ces arcs 7, au nombre de huit, forment, en outre, au niveau du pôle de la demi-coque 3ι 4, une petite calotte circulaire 8, par exemple de trois centimètres de diamètre, percée d'un orifice 8a.First, each half-shell 3, 4 is composed of arcs such as 7 extending along meridians uniformly distributed around the axis of revolution. These arcs 7, eight in number, further form, at the pole of the half-shell 3 ι 4, a small circular cap 8, for example three centimeters in diameter, pierced with an orifice 8a.
Chaque demi-coque 3, 4 comporte, en outre, une cerce 9 formant un grand cercle reliant l'extrémité des arcs 7 et portant les moyens d'encliquetage 5, 6. De plus, une cerce intermédiaire 10 de renfort relie également les arcs 7 à distance de leurs extrémités.Each half-shell 3, 4 further comprises a hoop 9 forming a large circle connecting the end of the arcs 7 and carrying the latching means 5, 6. In addition, an intermediate hoop 10 for reinforcement also connects the arcs 7 away from their ends.
Ainsi constituées, de telles demi-coques 3, 4 sont dotées d'une surface présentant un pourcentage de vide très important, supérieur à 90 %.Thus formed, such half-shells 3, 4 are provided with a surface having a very high percentage of vacuum, greater than 90%.
Les moyens d'encliquetage de ces deux demi- coques sont quant à eux constitués d'organes mâles 6 et femelles 5 agencés en positions conjuguées sur les cerces 9 de façon qu'à un organe mâle 6 d'une demi-coque (3 ou 4) corresponde un organe femelle 5 de l'autre demi-coque (4 ouThe latching means of these two half-shells are made up of male 6 and female 5 organs arranged in conjugate positions on the hoops 9 so that a male organ 6 of a half-shell (3 or 4) corresponds to a female member 5 of the other half-shell (4 or
3).3).
Les organes femelles sont constitués d'une glissière 5 ménagée sur la face externe de la cerce 9- Ces glissières 5 sont au nombre de deux par demi-coques 3. 4 et sont disposées de façon à être diamétralement opposées.The female organs consist of a slide 5 formed on the external face of the hoop 9. These slides 5 are two in number per half-shells 3 . 4 and are arranged to be diametrically opposed.
Les organes mâles sont constitués d'un talon d'encliquetage 6 apte à venir s'encliqueter dans une glissière 5 de façon à amener les cerces 9 des demi-coques 3, 4 au' contact l'une de l'autre. Ces talons 6 sont également au nombre de deux par demi-coques 3, 4 et sont disposés de façon à être diamétralement opposés, selon un diamètre orthogonal par rapport au diamètre reliant les glissières 5.The male members consist of a locking ring 6 adapted to snap into a slide 5 so as to bring the hoops 9 of the half-shells 3, 4 to 'contact one another. These heels 6 are also two in number per half-shells 3, 4 and are arranged so as to be diametrically opposite, according to a diameter orthogonal to the diameter connecting the slides 5.
En second lieu, chaque support comporte des moyens de maintien du pompon 1 aptes à maintenir le point de réunion des brins de ce pompon positionné au centre de l'enveloppe sphérique, après assemblage des demi- coques 3, 4.Secondly, each support comprises means for holding the pompom 1 capable of maintaining the meeting point of the strands of this pompom positioned at the center of the spherical envelope, after assembly of the half-shells 3, 4.
Ces moyens de maintien se composent d'une chandelle 11 de longueur sensiblement supérieure à celle du rayon de la sphère comportant, en premier lieu, une tige tubulaire creuse 12 fendue longitudinalement et sur une longueur donnée à partir d'une de ses extrémités 12a. Cette tige 12 comporte, de plus, une extrémité opposée 12b évasée extérieurement.These holding means consist of a candle 11 of length substantially greater than that of the radius of the sphere comprising, firstly, a hollow tubular rod 12 split longitudinally and over a given length from one of its ends 12a. This rod 12 also has an opposite end 12b flared outwardly.
- Cette chandelle comporte, en outre, un premier manchon 13 apte à venir en butée contre l'extrémité évasée 12b de la tige 12 et à loger cette dernière sur une longueur correspondant sensiblement à sa longueur non fendue. Elle comprend, enfin, un deuxième manchon 14 apte à loger la tige 12 sur une longueur de cette dernière sensiblement inférieure à sa longueur fendue. Une telle chandelle 11 permet de maintenir un pompon 1 logé dans la fente 12a de la tige 12 en coinçant ce dernier entre les deux manchons 13, 14, le blocage longitudinal du deuxième manchon 14 étant assuré, par exemple, par thermo-déformation de l'extrémité dudit manchon et de la tige.- This candle further comprises a first sleeve 13 adapted to abut against the flared end 12b of the rod 12 and to house the latter over a length corresponding substantially to its unsplit length. It finally comprises a second sleeve 14 capable of accommodating the rod 12 over a length of the latter substantially less than its split length. Such a candle 11 makes it possible to maintain a pompom 1 housed in the slot 12a of the rod 12 by wedging the latter between the two sleeves 13, 14, the longitudinal locking of the second sleeve 14 being ensured, for example, by thermo-deformation of the end of said sleeve and of the rod.
Cette chandelle 11 présente l'avantage de laisser un maximum de volume interne du support dépourvu d'obstacles s'opposant au déploiement du pompon 1. Elle présente également l'avantage de pouvoir être introduite dans le support une fois les demi-coques 3> 4 assemblées, sa fixation étant ensuite assurée au moyen d'une simple vis 15 logée dans l'orifice 8a d'une desdites demi-coques. Le principal avantage des supports décrits ci-dessus réside dans le fait qu'ils peuvent être introduits en vrac dans un réacteur, rendant ainsi facilement accessible la réalisation de réacteurs de taille importante. La figure 3 représente de façon schématique un tel réacteur du type à alimentation par le bas et à évacuation par surverse.This candle 11 has the advantage of leaving a maximum internal volume of the support free of obstacles opposing the deployment of the pompom 1. It also has the advantage of being able to be introduced in the support once the half-shells 3 > 4 are assembled, its fixing then being ensured by means of a simple screw 15 housed in the orifice 8a of one of said half-shells. The main advantage of the supports described above resides in the fact that they can be introduced in bulk into a reactor, thus making the production of large reactors easily accessible. FIG. 3 schematically represents such a reactor of the bottom feed type and overflow discharge.
Ce réacteur comprend classiquement une enceinte fermée 16 comportant un plancher intermédiaire perforé 17, des moyens d'alimentation 18 disposés sous le plancher perforé de l'enceinte, et constitués d'un tuyau percé par exemple en forme d'étoile, et une sortie d'évacuation 19 disposée en partie haute de l'enceinte.This reactor conventionally comprises a closed enclosure 16 comprising a perforated intermediate floor 17, supply means 18 disposed under the perforated floor of the enclosure, and consisting of a pipe pierced, for example in the shape of a star, and an outlet d 'evacuation 19 disposed in the upper part of the enclosure.
Cette enceinte 16 est remplie sur une hauteur donnée au-dessus du plancher 17 d'une pluralité de supports 3, 4 disposés en vrac, renfermant chacun un pompon 1 et adaptés pour que lesdits pompons puissent se déployer librement sans venir s'entremêler de façon à occuper le maximum de volume de l'enceinte et offrir ainsi une surface spécifique d'échange maximale.This enclosure 16 is filled over a given height above the floor 17 with a plurality of supports 3, 4 arranged in bulk, each containing a pompon 1 and adapted so that said pompoms can deploy freely without coming to become entangled so occupy the maximum volume of the enclosure and thus provide a maximum specific exchange surface.
Cette enceinte comporte, en outre, un plancher perforé 20 disposé en partie haute au-dessus de la dernière couche de supports 3, 4. Ce plancher 20 est destiné à emprisonner l'ensemble des supports dans le milieu reactionnel.This enclosure further comprises a perforated floor 20 disposed in the upper part above the last layer of supports 3, 4. This floor 20 is intended to trap all of the supports in the reaction medium.
Elle comprend, enfin, une boucle de recirculation 21 dotée d'une pompe 22, destinée à capter l'effluent en partie haute de l'enceinte 16, juste au- dessousdu niveau de la sortie d'évacuation 19, et à réinjecter ce dernier en partie basse de l'enceinte 16 par l'intermédiaire d'une rampe de répartition 23. Une telle boucle de recirculation 21 a, de façon classique, pour rôle de diluer l'effluent à son entrée dans le réacteur.Finally, it includes a recirculation loop 21 provided with a pump 22, intended to collect the effluent in the upper part of the enclosure 16, just below the level of the discharge outlet 19, and to reinject the latter. in the lower part of the enclosure 16 by means of a distribution ramp 23. Such a recirculation loop 21 has, conventionally, the role of diluting the effluent as it enters the reactor.
En sus des avantages précités d'une telle installation, un avantage supplémentaire découle du fait qu'un lit de boue a tendance à se former sous le plancher perforé. Un tel lit de boue constitue, en effet, une réserve à bactéries souvent différentes de celles se fixant sur les pompons, dans laquelle va barboter le flux au départ.In addition to the aforementioned advantages of such installation, an additional advantage arises from the fact that a mud bed tends to form under the perforated floor. Such a mud bed constitutes, in fact, a reserve of bacteria often different from those settling on the pompoms, in which the flow will bubble at the start.
Il est à noter que l'on peut de la même manière réaliser avec ce type d'éléments de garnissage des installations à flux vertical descendant et à flux horizontal.It should be noted that it is similarly possible to produce with this type of packing elements installations with vertical downflow and horizontal flow.
En ce qui concerne les applications et les avantages spécifiques de pompons 1 ainsi maintenus à distance les uns des autres, il convient notamment de se reporter au brevet EP 165.862. With regard to the specific applications and advantages of pompons 1 thus kept at a distance from one another, it is in particular advisable to refer to patent EP 165,862.

Claims

REVENDICATIONS 1/ - Support pour éléments de garnissage (1) destinés à être introduits dans un milieu reactionnel en vue de favoriser des échanges ou réactions entre des réactifs chimiques, biologiques... mis en présence, et constitués, chacun, d'une pluralité de brins, fils ou filaments assemblés de façon à se déployer librement lorsqu'ils sont plongés dans un milieu fluide, ledit support étant caractérisé en ce qu'il comprend, pour chaque élément de garnissage :CLAIMS 1 / - Support for packing elements (1) intended to be introduced into a reaction medium with a view to promoting exchanges or reactions between chemical, biological reagents ... brought into contact, and each consisting of a plurality strands, son or filaments assembled so as to deploy freely when they are immersed in a fluid medium, said support being characterized in that it comprises, for each lining element:
- une enveloppe rigide (3, 4) évidée sur sa plus grande surface et délimitant un volume interne apte à loger l'élément de garnissage (1) dans son état déployé, - des moyens de maintien (11-15) dudit élément de garnissage (1) adaptés pour permettre à ce dernier de se déployer à l'intérieur du volume délimité par l'enveloppe (3, 4).- a rigid envelope (3, 4) hollowed out over its larger surface and delimiting an internal volume capable of accommodating the lining element (1) in its deployed state, - holding means (11-15) of said lining element (1) adapted to allow the latter to deploy inside the volume delimited by the envelope (3, 4).
2/ - Support selon la revendication 1, caractérisé en ce que l'enveloppe (3, 4) présente une forme et délimite un volume interne adaptés pour que les éléments de remplissage (1) remplissent sensiblement la totalité dudit volume interne, dans leur état déployé.2 / - Support according to claim 1, characterized in that the envelope (3, 4) has a shape and defines an internal volume adapted so that the filling elements (1) fill substantially all of said internal volume, in their state deployed.
3/ - Support selon l'une des revendications 1 ou 2, caractérisé en ce que l'enveloppe (3, 4) présente un pourcentage de surface vide supérieur à 90 %.3 / - Support according to one of claims 1 or 2, characterized in that the envelope (3, 4) has a percentage of empty area greater than 90%.
4/ - Support selon l'une des revendications 1 à 3, caractérisé en ce que l'enveloppe (1) est constituée de deux demi-coques (3, 4) dotées de moyens d'encliquetage (5, 6) en vue de leur assemblage.4 / - Support according to one of claims 1 to 3, characterized in that the envelope (1) consists of two half-shells (3, 4) provided with latching means (5, 6) for their assembly.
5/ - Support selon l'une des revendications 1 à 4 pour éléments de garnissage constitués, chacun, d'une pluralité de brins, de fils ou filaments réunis en leur milieu de façon à former un pompon (1), caractérisé en ce que l'enveloppe (3, 4) présente une forme sphérique, et les moyens de maintien (11-15) sont adaptés pour maintenir le pompon (1) de façon que le point de réunion des brins, fils ou filaments soit situé au centre de l'enveloppe.5 / - Support according to one of claims 1 to 4 for packing elements each consisting of a plurality of strands, son or filaments joined in their middle so as to form a pompom (1), characterized in that the envelope (3, 4) has a spherical shape, and the holding means (11-15) are adapted to hold the pompom (1) so that the meeting point of the strands, threads or filaments is located in the center of the envelope.
6/ - Support selon la revendication 5, caractérisé en ce que les moyens de maintien comportent une chandelle interne 11 s'étendant o thogona le m en t à l'enveloppe (3, 4) et présentant une longueur sensiblement égale au rayon de ladite enveloppe, ladite chandelle (11) présentant une extrémité libre (12a) dotée de moyens de maintien (13, 14) d'un élément de garnissage (1).6 / - Support according to claim 5, characterized in that the holding means comprise an internal candle 11 extending o thogona the m at t to the envelope (3, 4) and having a length substantially equal to the radius of said envelope, said candle (11) having a free end (12a) provided with holding means (13, 14) of a packing element (1).
7/ - Support selon la revendication 6, caractérisé en ce que l'extrémité libre de la chandelle (11) présente une fente longitudinale (12a) apte à loger le point de réunion d'un élément de garnissage (1), les moyens de maintien (13. 1*0 étant adaptés pour coincer ledit élément de garnissage dans ladite fente.7 / - Support according to claim 6, characterized in that the free end of the candle (11) has a longitudinal slot (12a) adapted to accommodate the meeting point of a packing element (1), the means of maintaining (13. 1 * 0 being adapted for clamping said packing member into said slot.
8/ - Support selon les revendications 4 et 7 prises ensemble, caractérisé en ce que l'enveloppe est constituée de deux demi-coques (3, 4) de formes semi- sphériques identiques, la chandelle (11) étant dotée d'une extrémité (12b), opposée à son extrémité libre (12a), dotée d'un trou longitudinal apte à permettre la fixation de ladite chandelle à une demi-coque (3, 4) au moyen d'un élément de fixation (15).8 / - Support according to claims 4 and 7 taken together, characterized in that the envelope consists of two half-shells (3, 4) of identical semi-spherical shapes, the candle (11) being provided with one end (12b), opposite its free end (12a), provided with a longitudinal hole able to allow the fixing of said candle to a half-shell (3, 4) by means of a fixing element (15).
9/ - Support selon la evendication 8, caractérisé en ce que chaque demi-coque (3, 4) comprend des arcs (7) s'étendant selon des méridiens uniformément répartis autour de l'axe de révolution, et une cerce (9) formant un grand cercle reliant l'extrémité desdits arcs et portant les moyens d'encliquetage (5, 6).9 / - Support according to claim 8, characterized in that each half-shell (3, 4) comprises arcs (7) extending along meridians uniformly distributed around the axis of revolution, and a hoop (9) forming a large circle connecting the end of said arcs and carrying the latching means (5, 6).
10/ - Support selon la revendication 9, caractérisé en ce que les moyens d'encliquetage comprennent des organes mâles (6) et femelles (5) agencés en positions conjuguées sur chacune des demi-coques (3, 4) de façon qu'à un organe mâle (6) d'une demi-coque (3 ou 4) corresponde un organe femelle (5) de l'autre demi-coque (4 ou 3), chaque organe femelle étant constitué d'une glissière (5) ménagée sur la face externe de la cerce (9), et chaque organe mâle étant constitué d'un talon d'encliquetage (6) apte à venir s'encliqueter dans une glissière (5).10 / - Support according to claim 9, characterized in that the latching means comprise male (6) and female (5) organs arranged in conjugate positions on each of the half-shells (3, 4) so that a male member (6) of a half-shell (3 or 4) corresponds to a female member (5) of the other half-shell (4 or 3), each female member consisting of a slide (5) provided on the external face of the hoop (9), and each male member consisting of a snap-on heel (6) capable of snapping into a slide (5).
11/ - Installation de traitement de fluide du type comprenant une enceinte (16) dotée de moyens d'alimentation en fluide (18) et de moyens d'évacuation (19) après traitement, et des éléments de garnissage (1) disposés à l'intérieur de l'enceinte (16) et consistant chacun en une pluralité de brins, fils ou filaments assemblés de façon à se déployer librement lorsque ladite enceinte est remplie de fluide, ladite installation étant caractérisée en ce que chaque élément de garnissage (1) est disposé à l'intérieur d'un support comportant : - une enveloppe rigide (3, 4) évidée sur sa plus grande surface et délimitant un volume interne apte à loger l'élément de garnissage (1) dans son état déployé,11 / - Fluid treatment installation of the type comprising an enclosure (16) provided with means fluid supply (18) and evacuation means (19) after treatment, and packing elements (1) arranged inside the enclosure (16) and each consisting of a plurality of strands, wires or filaments assembled so as to unfold freely when said enclosure is filled with fluid, said installation being characterized in that each lining element (1) is disposed inside a support comprising: - a rigid envelope (3, 4) hollowed out over its largest surface and delimiting an internal volume capable of housing the lining element (1) in its deployed state,
- des moyens de maintien (11-15) dudit élément de garnissage (1) adaptés pour permettre à ce dernier de se déployer à l'intérieur du volume délimité par l'enveloppe (3, 4),- holding means (11-15) of said lining element (1) adapted to allow the latter to deploy inside the volume delimited by the envelope (3, 4),
- lesdits supports étant disposés en vrac dans l'enceinte (16) de façon à être indépendants les uns des autres, et à venir au contact les uns des autres par leur enveloppe (3, 4). - Said supports being arranged in bulk in the enclosure (16) so as to be independent of each other, and to come into contact with each other by their envelope (3, 4).
PCT/FR1992/000888 1991-09-26 1992-09-25 Support for liner elements consisting of the assembly of a plurality of strands, threads or filaments, and plant for treating fluid made from such supports WO1993005876A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR91/11975 1991-09-26
FR9111975A FR2681798A1 (en) 1991-09-26 1991-09-26 SUPPORT FOR FILLING ELEMENTS CONSISTING OF THE ASSEMBLY OF A PLURALITY OF STRANDS, WIRES OR FILAMENTS, AND FLUID TREATMENT INSTALLATION MADE FROM SUCH SUPPORTS.

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FR (1) FR2681798A1 (en)
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US6631890B1 (en) * 2000-06-30 2003-10-14 Apollo Separation Technologies, Inc Packing for column
US6811147B2 (en) 2002-08-30 2004-11-02 Apollo Separation Technologies, Inc. Structured random packing for column
US7014175B2 (en) * 2003-11-07 2006-03-21 Honnell Marvin A Packing for column
WO2018073498A1 (en) * 2016-10-20 2018-04-26 Footshake Play device intended for juggling

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DE19636593A1 (en) * 1996-09-10 1998-03-12 Kaesch Trenntechnik Gmbh Plant for the biological treatment of waste water in particular
EP1801077A1 (en) * 2005-12-21 2007-06-27 Kang Na Hsiung Enterprise Co., Ltd. Method for treating a contaminated fluid, system for treating a contaminated fluid, and method for making a biomass carrier suitable for treating a contaminated fluid
EP1923133B1 (en) 2006-10-23 2017-07-26 Vereinigte Füllkörper-Fabriken GmbH & Co. KG Grid like packing elements for use in mass and/or heat exchange columns

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EP0165862A1 (en) * 1984-06-14 1985-12-27 Institut National De Recherche Chimique Appliquee Material with a large specific surface and its use in favourizing the contact between environments or reactants involving physical and/or chemical and/or biological phenomena
WO1989005688A1 (en) * 1987-12-21 1989-06-29 Envicon Luft- Und Wassertechnik Gmbh & Co. Kg Spherical packing element made of plastic for mass and heat transfer columns

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Publication number Priority date Publication date Assignee Title
EP0165862A1 (en) * 1984-06-14 1985-12-27 Institut National De Recherche Chimique Appliquee Material with a large specific surface and its use in favourizing the contact between environments or reactants involving physical and/or chemical and/or biological phenomena
WO1989005688A1 (en) * 1987-12-21 1989-06-29 Envicon Luft- Und Wassertechnik Gmbh & Co. Kg Spherical packing element made of plastic for mass and heat transfer columns

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6631890B1 (en) * 2000-06-30 2003-10-14 Apollo Separation Technologies, Inc Packing for column
US6811147B2 (en) 2002-08-30 2004-11-02 Apollo Separation Technologies, Inc. Structured random packing for column
US7014175B2 (en) * 2003-11-07 2006-03-21 Honnell Marvin A Packing for column
WO2018073498A1 (en) * 2016-10-20 2018-04-26 Footshake Play device intended for juggling

Also Published As

Publication number Publication date
AU2762092A (en) 1993-04-27
FR2681798A1 (en) 1993-04-02
FR2681798B1 (en) 1994-12-30

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