WO1993004781A1 - Method for dry concentration of metal in a metal containing ore or slag - Google Patents
Method for dry concentration of metal in a metal containing ore or slag Download PDFInfo
- Publication number
- WO1993004781A1 WO1993004781A1 PCT/FI1992/000239 FI9200239W WO9304781A1 WO 1993004781 A1 WO1993004781 A1 WO 1993004781A1 FI 9200239 W FI9200239 W FI 9200239W WO 9304781 A1 WO9304781 A1 WO 9304781A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- slag
- ore
- metal
- weight
- grinder
- Prior art date
Links
- 239000002893 slag Substances 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 26
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- 239000012141 concentrate Substances 0.000 claims abstract description 15
- 239000007787 solid Substances 0.000 claims abstract description 13
- 239000002245 particle Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 230000001133 acceleration Effects 0.000 claims abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 4
- 239000011707 mineral Substances 0.000 claims abstract description 4
- 238000007670 refining Methods 0.000 claims abstract description 4
- 239000004411 aluminium Substances 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 13
- 229910000510 noble metal Inorganic materials 0.000 claims description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 3
- 241001676573 Minium Species 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 239000011133 lead Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 2
- 239000012467 final product Substances 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 241000237074 Centris Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000727 fraction Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B7/00—Selective separation of solid materials carried by, or dispersed in, gas currents
- B07B7/08—Selective separation of solid materials carried by, or dispersed in, gas currents using centrifugal force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/04—General arrangement of separating plant, e.g. flow sheets specially adapted for furnace residues, smeltings, or foundry slags
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- This invention relates to a method for dry concentration of metal in a metal containing ore, a concentrate sepa ⁇ rated therefrom or slag, in which method the ore, the ore concentrate or the slag batch is fed to a pressurized feeding device of a counterjet grinder and fluidized by means of a working gas flow, the fluidized gas-solids mixture is accelerated by means of pressure via two main ⁇ ly oppositely directed acceleration nozzles to a grinding chamber, whereby the fragile mineral or slag material portion of the solids particles colliding with each other decomposes and loosens from poorly grinding metal-con- taining particles, and the produced pulverized gas solids material mixture is immediately led by means of an over ⁇ pressure prevailing in the grinding chamber (12) of the counterjet grinder to a centrifugal classifier (13), in which the metallically poor fine fraction is removed from the classifier via an axial opening (13a) and the metal ⁇ lically rich coarse fraction is returned to the feeding device (3) of the counterjet grinder for
- the object of the present invention is to remove the abo- ve-mentioned disadvantages by using a counterjet grinder such that the recirculation is repeated, until a desired portion of the initial weight of the ore, ore-concentrate or the slag batch has left the centrifugal classif er as a fine fraction, whereby the metallically rich coarse fraction left in the equipment is led via a product out ⁇ let opening to a next refining step.
- a slag is e.g. a slag produced in the melting of aluminium, whose aluminium concentration is low to such an extent that it cannot be utilized by conventional ways, but it is yet so high that it causes serious envi- romental problems e.g. due to the occurrence of hydrogen.
- Fig. 1 shows the equipment to be used in the method, seen from one side
- Fig. 2 shows the equipment of Fig. 1 seen from the right.
- the inventive method is performed step-wise.
- the ore, the ore concentrate or the slag batch is fed via a feeding funnel 1 and a screw conveyor 2 to another feeding funnel 3 of a counterjet grinder and therefrom further via a double-valve feeder 4 to a pressurized distributing cham ⁇ ber 5.
- the quantity of the batch fed to the equipment is observed by means of a scale weighing the weight of the equipment.
- the ore or slag batch drops from the feeding funnel 3 to an intermediate container 4b of the double- valve feeder 4 when a top valve 4a is open and a bottom valve 4c is closed.
- the top valve 4a When the intermediate container 4b is filled to a predetermined level, the top valve 4a is clo- sed and the intermediate chamber 4b is pressurized by means of gas, fed via a gas feeding line 6. As the pres ⁇ sure has risen to a desired level, a valve 6a in the gas feeding line is closed and the bottom valve 4c is opened, whereby the ore or slag batch in the intermediate con- tainer 4b drops to the distributing chamber 5 located below the double-valve feeder. The bottom valve 4c is then closed and a valve 7a located in a pressure reducti ⁇ on pipe 7 extending from the upper end of the interme ⁇ diate container 4b is opened and maintained open, until the pressure of the intermediate chamber has decreased to normal air pressure. The valve 7a is then closed and the top valve 4a is opened for a new batch. These feeding functions are repeated, until the total quantity of a dry concentration step is fed to the equipment.
- the material batch in the pressurized distributing cham ⁇ ber 5 is fed at an even rate by means of the screw con ⁇ veyor 5a to a fluidization chamber 8, in which the ore or slag material is fluidized by means of a high-pressure working gas flow fed via a working gas pipe 9.
- the flui ⁇ dized gas-solids mixture is led via a bipartition device 10, in which it is divided into two equivalent partial flows. Each partial flow is accelerated in response to the overpressure prevailing in the fluidization chamber 8 via its own acceleration pipe 11 to a grinding chamber 12 of the counterjet grinder, where gas-solids materials jets surging from mainly oppositely directed acceleration nozzles collide with each other.
- the fragile mineral or slag fraction then decomposes ja loosens from poorly grinding metal-containing particles.
- the pulverized gas- solids mixture produced in the grinding is immediately led by means of a afterpressure prevailing in the grin ⁇ ding chamber 12 of the counterjet grinder to a centrifu ⁇ gal classifier 13, which is either a static or dynamic centrifugal grinder, depending of the required classifi ⁇ cation accuracy.
- the metallically poor fine fraction is removed from an axial outlet opening 13a of the classi ⁇ fier and led either to an intermediate or waste storage.
- the metallically rich coarse fraction is removed to a pocket 13b located on the shell surface of the classi ⁇ bomb, from which it is fed batchwise, by means of a com- partment feeder 13c or a double valve device to a two- directional screw conveyor 14, which, when rotating in one direction, is arranged to return the coarse fraction to the second feeding funnel 3 of the jet grinder for recirculation, which recirculation is repeated, until a desired portion of the initial weight of the ore, ore concentrate or slag batch has been removed as a fine fraction from the centrifugal classifier 13.
- the screw conveyor 14 is then caused to rotate in the other direc ⁇ tion, whereby the metallically rich coarse fraction that has remained in the equipment is led via a product outlet opening 15 to a next refining step.
- the inventive method is especially suitable for dry con ⁇ centration of aluminium in the slag produced in the mel- ting of aluminium.
- the aluminium content of such a slag is generally in the range 15-25% by weight. If the dry concentration method is performed such that the slag batch is circulated in the equipment, until ca. 50% by weight of the initial weight of the slag batch has been removed from the axial outlet opening 13a of the centri ⁇ fugal classifier 13, an end product is obtained, whose aluminium content is ca. 35-50% by weight, which is suf ⁇ ficiently high such that the aluminium of the end product may be used in a conventional melting process. The alu ⁇ minium content of the fine fraction that has left the dry concentration process is then ca. 5-15% by weight, which considerably reduces the environmental problems caused by the slag.
- the invention may also be utilized when it is necessary to remove from a blast furnace slag the iron contained therein.
- the iron content of the blast furnace slag is less than 1% by weight, and in the inventive treatment, it accumulates in the coarse fraction.
- the inventive method may be used for concentrating a me ⁇ tal from such an ore or an ore concentrate, which is com ⁇ prised of a fragile and/or light component as well of a tough and/or heavy metal-containing component.
- Such com ⁇ ponents include e.g. copper, tin, nickel and lead ores and ore concentrates as well as noble-metal ores.
- the noble metal may be dry concentrated also from a noble-metal ore or some other waste.
- a working gas is generally used oil-free pressurized air, but in case the metal to be dry concentrated is e.g. easily oxidable, also nitrogen, argon or some other inert gas may be used.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FI914270 | 1991-09-10 | ||
FI914270A FI914270A (fi) | 1991-09-10 | 1991-09-10 | Foerfarande foer torranrikning av metall i en metallhaltig malm eller slagg |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1993004781A1 true WO1993004781A1 (en) | 1993-03-18 |
Family
ID=8533099
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FI1992/000239 WO1993004781A1 (en) | 1991-09-10 | 1992-09-09 | Method for dry concentration of metal in a metal containing ore or slag |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU2509892A (fi) |
FI (1) | FI914270A (fi) |
WO (1) | WO1993004781A1 (fi) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105018719A (zh) * | 2015-08-10 | 2015-11-04 | 中国瑞林工程技术有限公司 | 精矿处理方法和系统 |
CN112901171A (zh) * | 2021-01-22 | 2021-06-04 | 安徽马钢张庄矿业有限责任公司 | 一种特大型金属矿山绿色安全高效开采方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3086718A (en) * | 1959-04-06 | 1963-04-23 | W E Plechaty Co | Method and apparatus for separating metallic particles |
WO1990006179A1 (en) * | 1988-11-28 | 1990-06-14 | Oy Finnpulva Ab | Method and equipment for processing of particularly finely divided material |
WO1991008836A1 (en) * | 1989-12-07 | 1991-06-27 | Tarco Vej A/S | A method and an apparatus for crushing slags resulting from steel production |
-
1991
- 1991-09-10 FI FI914270A patent/FI914270A/fi not_active Application Discontinuation
-
1992
- 1992-09-09 AU AU25098/92A patent/AU2509892A/en not_active Abandoned
- 1992-09-09 WO PCT/FI1992/000239 patent/WO1993004781A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3086718A (en) * | 1959-04-06 | 1963-04-23 | W E Plechaty Co | Method and apparatus for separating metallic particles |
WO1990006179A1 (en) * | 1988-11-28 | 1990-06-14 | Oy Finnpulva Ab | Method and equipment for processing of particularly finely divided material |
WO1991008836A1 (en) * | 1989-12-07 | 1991-06-27 | Tarco Vej A/S | A method and an apparatus for crushing slags resulting from steel production |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105018719A (zh) * | 2015-08-10 | 2015-11-04 | 中国瑞林工程技术有限公司 | 精矿处理方法和系统 |
CN112901171A (zh) * | 2021-01-22 | 2021-06-04 | 安徽马钢张庄矿业有限责任公司 | 一种特大型金属矿山绿色安全高效开采方法 |
Also Published As
Publication number | Publication date |
---|---|
FI914270A (fi) | 1993-03-11 |
AU2509892A (en) | 1993-04-05 |
FI914270A0 (fi) | 1991-09-10 |
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