WO1993004781A1 - Method for dry concentration of metal in a metal containing ore or slag - Google Patents

Method for dry concentration of metal in a metal containing ore or slag Download PDF

Info

Publication number
WO1993004781A1
WO1993004781A1 PCT/FI1992/000239 FI9200239W WO9304781A1 WO 1993004781 A1 WO1993004781 A1 WO 1993004781A1 FI 9200239 W FI9200239 W FI 9200239W WO 9304781 A1 WO9304781 A1 WO 9304781A1
Authority
WO
WIPO (PCT)
Prior art keywords
slag
ore
metal
weight
grinder
Prior art date
Application number
PCT/FI1992/000239
Other languages
English (en)
French (fr)
Inventor
Jouko Niemi
Original Assignee
Oy Finnpulva Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oy Finnpulva Ab filed Critical Oy Finnpulva Ab
Publication of WO1993004781A1 publication Critical patent/WO1993004781A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07BSEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
    • B07B7/00Selective separation of solid materials carried by, or dispersed in, gas currents
    • B07B7/08Selective separation of solid materials carried by, or dispersed in, gas currents using centrifugal force
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • B03B9/04General arrangement of separating plant, e.g. flow sheets specially adapted for furnace residues, smeltings, or foundry slags
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00Preliminary treatment of ores or scrap
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Definitions

  • This invention relates to a method for dry concentration of metal in a metal containing ore, a concentrate sepa ⁇ rated therefrom or slag, in which method the ore, the ore concentrate or the slag batch is fed to a pressurized feeding device of a counterjet grinder and fluidized by means of a working gas flow, the fluidized gas-solids mixture is accelerated by means of pressure via two main ⁇ ly oppositely directed acceleration nozzles to a grinding chamber, whereby the fragile mineral or slag material portion of the solids particles colliding with each other decomposes and loosens from poorly grinding metal-con- taining particles, and the produced pulverized gas solids material mixture is immediately led by means of an over ⁇ pressure prevailing in the grinding chamber (12) of the counterjet grinder to a centrifugal classifier (13), in which the metallically poor fine fraction is removed from the classifier via an axial opening (13a) and the metal ⁇ lically rich coarse fraction is returned to the feeding device (3) of the counterjet grinder for
  • the object of the present invention is to remove the abo- ve-mentioned disadvantages by using a counterjet grinder such that the recirculation is repeated, until a desired portion of the initial weight of the ore, ore-concentrate or the slag batch has left the centrifugal classif er as a fine fraction, whereby the metallically rich coarse fraction left in the equipment is led via a product out ⁇ let opening to a next refining step.
  • a slag is e.g. a slag produced in the melting of aluminium, whose aluminium concentration is low to such an extent that it cannot be utilized by conventional ways, but it is yet so high that it causes serious envi- romental problems e.g. due to the occurrence of hydrogen.
  • Fig. 1 shows the equipment to be used in the method, seen from one side
  • Fig. 2 shows the equipment of Fig. 1 seen from the right.
  • the inventive method is performed step-wise.
  • the ore, the ore concentrate or the slag batch is fed via a feeding funnel 1 and a screw conveyor 2 to another feeding funnel 3 of a counterjet grinder and therefrom further via a double-valve feeder 4 to a pressurized distributing cham ⁇ ber 5.
  • the quantity of the batch fed to the equipment is observed by means of a scale weighing the weight of the equipment.
  • the ore or slag batch drops from the feeding funnel 3 to an intermediate container 4b of the double- valve feeder 4 when a top valve 4a is open and a bottom valve 4c is closed.
  • the top valve 4a When the intermediate container 4b is filled to a predetermined level, the top valve 4a is clo- sed and the intermediate chamber 4b is pressurized by means of gas, fed via a gas feeding line 6. As the pres ⁇ sure has risen to a desired level, a valve 6a in the gas feeding line is closed and the bottom valve 4c is opened, whereby the ore or slag batch in the intermediate con- tainer 4b drops to the distributing chamber 5 located below the double-valve feeder. The bottom valve 4c is then closed and a valve 7a located in a pressure reducti ⁇ on pipe 7 extending from the upper end of the interme ⁇ diate container 4b is opened and maintained open, until the pressure of the intermediate chamber has decreased to normal air pressure. The valve 7a is then closed and the top valve 4a is opened for a new batch. These feeding functions are repeated, until the total quantity of a dry concentration step is fed to the equipment.
  • the material batch in the pressurized distributing cham ⁇ ber 5 is fed at an even rate by means of the screw con ⁇ veyor 5a to a fluidization chamber 8, in which the ore or slag material is fluidized by means of a high-pressure working gas flow fed via a working gas pipe 9.
  • the flui ⁇ dized gas-solids mixture is led via a bipartition device 10, in which it is divided into two equivalent partial flows. Each partial flow is accelerated in response to the overpressure prevailing in the fluidization chamber 8 via its own acceleration pipe 11 to a grinding chamber 12 of the counterjet grinder, where gas-solids materials jets surging from mainly oppositely directed acceleration nozzles collide with each other.
  • the fragile mineral or slag fraction then decomposes ja loosens from poorly grinding metal-containing particles.
  • the pulverized gas- solids mixture produced in the grinding is immediately led by means of a afterpressure prevailing in the grin ⁇ ding chamber 12 of the counterjet grinder to a centrifu ⁇ gal classifier 13, which is either a static or dynamic centrifugal grinder, depending of the required classifi ⁇ cation accuracy.
  • the metallically poor fine fraction is removed from an axial outlet opening 13a of the classi ⁇ fier and led either to an intermediate or waste storage.
  • the metallically rich coarse fraction is removed to a pocket 13b located on the shell surface of the classi ⁇ bomb, from which it is fed batchwise, by means of a com- partment feeder 13c or a double valve device to a two- directional screw conveyor 14, which, when rotating in one direction, is arranged to return the coarse fraction to the second feeding funnel 3 of the jet grinder for recirculation, which recirculation is repeated, until a desired portion of the initial weight of the ore, ore concentrate or slag batch has been removed as a fine fraction from the centrifugal classifier 13.
  • the screw conveyor 14 is then caused to rotate in the other direc ⁇ tion, whereby the metallically rich coarse fraction that has remained in the equipment is led via a product outlet opening 15 to a next refining step.
  • the inventive method is especially suitable for dry con ⁇ centration of aluminium in the slag produced in the mel- ting of aluminium.
  • the aluminium content of such a slag is generally in the range 15-25% by weight. If the dry concentration method is performed such that the slag batch is circulated in the equipment, until ca. 50% by weight of the initial weight of the slag batch has been removed from the axial outlet opening 13a of the centri ⁇ fugal classifier 13, an end product is obtained, whose aluminium content is ca. 35-50% by weight, which is suf ⁇ ficiently high such that the aluminium of the end product may be used in a conventional melting process. The alu ⁇ minium content of the fine fraction that has left the dry concentration process is then ca. 5-15% by weight, which considerably reduces the environmental problems caused by the slag.
  • the invention may also be utilized when it is necessary to remove from a blast furnace slag the iron contained therein.
  • the iron content of the blast furnace slag is less than 1% by weight, and in the inventive treatment, it accumulates in the coarse fraction.
  • the inventive method may be used for concentrating a me ⁇ tal from such an ore or an ore concentrate, which is com ⁇ prised of a fragile and/or light component as well of a tough and/or heavy metal-containing component.
  • Such com ⁇ ponents include e.g. copper, tin, nickel and lead ores and ore concentrates as well as noble-metal ores.
  • the noble metal may be dry concentrated also from a noble-metal ore or some other waste.
  • a working gas is generally used oil-free pressurized air, but in case the metal to be dry concentrated is e.g. easily oxidable, also nitrogen, argon or some other inert gas may be used.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)
PCT/FI1992/000239 1991-09-10 1992-09-09 Method for dry concentration of metal in a metal containing ore or slag WO1993004781A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI914270 1991-09-10
FI914270A FI914270A (fi) 1991-09-10 1991-09-10 Foerfarande foer torranrikning av metall i en metallhaltig malm eller slagg

Publications (1)

Publication Number Publication Date
WO1993004781A1 true WO1993004781A1 (en) 1993-03-18

Family

ID=8533099

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1992/000239 WO1993004781A1 (en) 1991-09-10 1992-09-09 Method for dry concentration of metal in a metal containing ore or slag

Country Status (3)

Country Link
AU (1) AU2509892A (fi)
FI (1) FI914270A (fi)
WO (1) WO1993004781A1 (fi)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105018719A (zh) * 2015-08-10 2015-11-04 中国瑞林工程技术有限公司 精矿处理方法和系统
CN112901171A (zh) * 2021-01-22 2021-06-04 安徽马钢张庄矿业有限责任公司 一种特大型金属矿山绿色安全高效开采方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3086718A (en) * 1959-04-06 1963-04-23 W E Plechaty Co Method and apparatus for separating metallic particles
WO1990006179A1 (en) * 1988-11-28 1990-06-14 Oy Finnpulva Ab Method and equipment for processing of particularly finely divided material
WO1991008836A1 (en) * 1989-12-07 1991-06-27 Tarco Vej A/S A method and an apparatus for crushing slags resulting from steel production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3086718A (en) * 1959-04-06 1963-04-23 W E Plechaty Co Method and apparatus for separating metallic particles
WO1990006179A1 (en) * 1988-11-28 1990-06-14 Oy Finnpulva Ab Method and equipment for processing of particularly finely divided material
WO1991008836A1 (en) * 1989-12-07 1991-06-27 Tarco Vej A/S A method and an apparatus for crushing slags resulting from steel production

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105018719A (zh) * 2015-08-10 2015-11-04 中国瑞林工程技术有限公司 精矿处理方法和系统
CN112901171A (zh) * 2021-01-22 2021-06-04 安徽马钢张庄矿业有限责任公司 一种特大型金属矿山绿色安全高效开采方法

Also Published As

Publication number Publication date
FI914270A (fi) 1993-03-11
AU2509892A (en) 1993-04-05
FI914270A0 (fi) 1991-09-10

Similar Documents

Publication Publication Date Title
CA2791123C (en) Preparation method for stainless steel slags and steelworks slags for recovery of metal
JP2579885B2 (ja) 粉粒体原料の粉砕方法と粉砕装置および分級機
Matinde et al. Dephosphorization treatment of high phosphorus iron ore by pre-reduction, air jet milling and screening methods
US3770424A (en) Process for recovery of aluminum from furnace skim
ZA944315B (en) Method and apparatus for crushing material of different grain size
US4325514A (en) Comminution of minerals
Stehr Recent developments in stirred ball milling
WO1993004781A1 (en) Method for dry concentration of metal in a metal containing ore or slag
EP0267170B1 (en) Treatment of middlings
EP0506638B1 (en) Method and arrangement for finely grinding minerals intended for use as fillers
US4860957A (en) Treatment of middlings
JPS63501776A (ja) 圧力室粉砕機の粉砕効率改良のための方法と装置
GB2108006A (en) Process for pulverising raw coal with the aid of an impact pulveriser and apparatus for carrying out the process
US5058813A (en) Method for comminuting brittle material to be ground
EP0211117A2 (en) Method and apparatus for providing finely divided powder
WO1987003220A1 (en) Procedure and apparatus for producing classified fines product
CA1084469A (en) Comminution of minerals
US3462262A (en) Process for the recovery of excess carbon from the product of an iron ore direct reduction
CN217313905U (zh) 浮选设备
RU2044565C1 (ru) Ударно-центробежная мельница
WO1998036840A1 (en) Equipment and method for producing ultra fine dry powders by means of a high-energy power gas
Lawry et al. Laboratory studies in comminution. III. Effect of mill parameters on grinding a tin ore
US6082641A (en) Dross processing
US548377A (en) lovett
JPH0642738Y2 (ja) 竪型ローラミル

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU CA CS HU JP NO RU US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA