WO1992019686A2 - Treatment and recycling of overspray from the spray application of waterborne coatings - Google Patents
Treatment and recycling of overspray from the spray application of waterborne coatings Download PDFInfo
- Publication number
- WO1992019686A2 WO1992019686A2 PCT/EP1992/000996 EP9200996W WO9219686A2 WO 1992019686 A2 WO1992019686 A2 WO 1992019686A2 EP 9200996 W EP9200996 W EP 9200996W WO 9219686 A2 WO9219686 A2 WO 9219686A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water
- stream
- concentrated
- overspray
- waterborne coating
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D57/00—Separation, other than separation of solids, not fully covered by a single other group or subclass, e.g. B03C
- B01D57/02—Separation, other than separation of solids, not fully covered by a single other group or subclass, e.g. B03C by electrophoresis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B14/00—Arrangements for collecting, re-using or eliminating excess spraying material
- B05B14/40—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths
- B05B14/46—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by washing the air charged with excess material
- B05B14/462—Arrangements for collecting, re-using or eliminating excess spraying material for use in spray booths by washing the air charged with excess material and separating the excess material from the washing liquid, e.g. for recovery
Definitions
- the present invention relates generally to a process for spray coating an. object with a waterborne coating and, more particularly, to a process for the treatment and recycling of overspray resulting from such spray coating.
- the present process is applicable in general industry and, especially, in the automotive industry where car bodies and a wide variety of other larger objects are spray coated.
- overspray occurring, for example, during automobile coating with waterborne coatings is normally removed from the spray booth by an exhaust air stream and/or absorbed in water (water curtains or cascades) circulated from a catchment tank.
- water curtains or cascades water curtains or cascades
- water-insoluble e.g. pigments
- water-dispersible e.g., emulsifiers, stabilizers and rheological additives
- water-soluble e.g. lower molecular weight polar organic co-solvents, acids and amines
- the currently practiced recycling procedures for waterborne coatings require the addition of coagulating agents and/or detackifiers to the collected overspray.
- the resulting coagulate is extracted by sedimentation, flotation, filtration and/or similar separation processes, and subsequently removed from the spraying area. Due to the presence of the added chemicals, and due to the coagulated form of the recovered product, recycling is a costly and complex process.
- the chemical additives often affect the properties of any reclaimed product, and separation of many water-soluble materials, such as low molecular weight organic cosolvents, acids and amines, remains a problem.
- W082/02543 describes a method for recovery and recycling of waterborne coating overspray, whereby the overspray is collected and separated (e.g. by a traveling screen filter or a settling tank) into a low and high solids (e.g. 10-50Z solids) fraction.
- the solids content of the high solids fraction is preferably adjusted to fall within the range of 5-30Z solids (e.g. by the addition of water), then passed in the form of a slurry to a decanter centrifuge, of a type well-known in the art, which further separates the liquid from the solids.
- the solid component is said to comprise about 75wtZ solids, which can be utilized as a base for a reclaimed paint product, or can be further dried for disposal at a landfill.
- the liquid component which can be recycled back to the spray booth, is said to typically comprise less than 1 wtZ solids.
- US4607592 discloses a method of processing overspray in conjunction with the use of a complicated apparatus and a burdensome procedure. Separation is accomplished via a complex and special filter and filtration technique into concentrated and clear water fraction. The concentrated fraction is said to contain the solids and water-soluble components of the overspray, with the composition of the concentrated fraction being automatically adjusted to meet the composition of the fresh paint. The reclaimed paint is then recycled by adding it to the fresh paint feed.
- a process for treating overspray collected from the spray coating of an object with a waterborne coating which waterborne coating comprises:
- (C) optionally, an additive part including at least one of a water-insoluble, water-dispersible and/or water-soluble component, characterized in that the process results in a recyclable waterborne coating stream of substantially the same composition as the waterborne coating and a recyclable water stream containing substantially none of the resin or additive parts of the waterborne coating, which process comprises the steps of:
- step (6) generating the recyclable waterborne coating stream by mixing the so-recovered concentrated phase of step (2a), concentrated fraction of step (2b) and concentrated residue stream of step (3) in a manner and with other components necessary to result in a mixture having substantially the same composition as the waterborne coating.
- step (2a) is generally considered to be optional, especially in the case of waterborne clearcoats which contain very small amounts of water-insoluble components.
- step (2a) is not utilized, the process in accordance with the present invention comprises the steps of:
- electrophoresis has been utilized as a means for recovery and recycling of waste solutions generated from the application of waterborne coatings by electrodeposition (see, for example, JP-LO-100135/1974).
- the application of electrodeposition to the recycling of overspray from spray applied waterborne coatings is not known from this literature nor is it readily apparent because of the vastly different considerations in formulating and utilizing spray coatings versus electrodeposition coatings.
- an apparatus for treating overspray produced from the spray coating of an object with a waterborne coating comprises: (la) means for collecting at least a portion of overspray; (lb) a catchment tank for holding the collected overspray; (2) electrophoretic separating means, connected to the catchment tank, for electrophoretically separating the collected overspray into (i) a concentrated fraction comprising
- mixing means for generating a recyclable waterborne coating stream from the concentrated fraction, the concentrated residue stream and other components necessary to result in a mixture having substantially the same composition as the waterborne coating, wherein the recyclable waterborne coating stream comprises substantially the same composition as the waterborne coating, and the recyclable water stream contains substantially none of the resin or additive parts of the waterborne coating.
- the apparatus For treating overspray containing relatively large amounts of water-insoluble components, the apparatus preferably comprises:
- (la) means for collecting at least a portion of the overspray; (lb) a catchment tank for holding the collected overspray; (2a) means, interposed between the catchment tank and an electrophoretic separation means, for separating the collected overspray into (i) a concentrated phase comprising
- mixing means for generating the recyclable waterborne coating stream from the concentrated phase, the concentrated fraction, the concentrated residue stream and other components necessary to result in a mixture having substantially the same composition as the waterborne coating.
- a process for spray coating an object with a waterborne coating wherein overspray is generated by the spray coating, characterized in that the overspray is treated as described above to t generate the recyclable waterborne coating stream and the recyclable water stream, at least a portion of the so-generated recyclable waterborne coating stream is recycled for spray application onto the object, and at least a portion of the recyclable water stream is recycled for use in collecting the overspray.
- an apparatus for spray coating an object with a waterborne coating which comprises a spray booth, the apparatus for treating overspray as described above, a means for recycling at least a portion of the so-generated recyclable waterborne coating stream for spray application onto the object, and a means for recycling at least a portion of the recyclable water stream for use in collecting the overspray.
- Figure 1 is an overall schematic of a spray coating and overspray treating process and apparatus in accordance with the present invention.
- FIG. 2 is a more detailed schematic of a spray coating and overspray treating process and apparatus in accordance with the present invention.
- Figures 3-5 are schematic representations of various electrophoretic separation means for use in the spray coating and overspray treating process and apparatus in accordance with the present invention.
- waterborne coatings intended for spray application can comprise a wide variety of solid and liquid components in significantly varying amounts. These components can generally be classified into one of three well-known groups - (A) water, (B) a resin part and (C) an additive part.
- the resin part (B) includes those materials which ultimately form the polymer network of the film resulting from application and drying of the waterborne coating.
- the resin part comprises materials which are generally (but not always) organic in nature, which may be solid or liquid, which are substantially non-volatile under formulation and application conditions, and which may be water-insoluble, water-dispersible or water-soluble.
- binder components can comprise, for example, a variety of monomeric, oligomeric and polymeric materials which can be physically drying but preferably contain reactive functionality for crosslinking.
- these binders are crosslinked with the aid of relatively large amounts of preferably multifunctional compounds which react with tr_ .-? functionality and are, consequently, significantly incorporated into the resulting crosslinked polymer network.
- crosslinking agents include a wide variety of known monomeric, oligomeric and polymeric compounds and, for the purposes of the present description, are considered included in the resin part.
- the additive part (C) can include a wide variety of organic and inorganic, solid and liquid, water-insoluble, water-dispersible and water-soluble components such as, for example, pigments, water-miscible organic cosolvents, volatile neutralizing agents (e.g. acids and amines), biocides, rheology modifiers, non-reactive emulsifiers and stabilizers, etc.
- waterborne coatings intended for spray application will comprise the resin ⁇ ⁇ ) and additive (C) par 4 - in combined amounts ranging from about 25 wtZ to about 70 wtZ based upon the total weight of the waterborne coating, with water consequently making up the remaining wtZ.
- additive (C) par 4 - in combined amounts ranging from about 25 wtZ to about 70 wtZ based upon the total weight of the waterborne coating, with water consequently making up the remaining wtZ.
- the water feed line 14 may be connected, for example, to a water curtain (not pictured) or other similar means for collecting overspray, which collection means are in general common and well-known in this type of spray application.
- a water curtain not pictured
- the ' spray application of waterborne coatings is in general well-known to those skilled in the art, and this aspect need not be discussed in further detail.
- the collected overspray is passed via lines 16 and 18 to a catchment tank 20, where it is held for further processing as discussed below.
- concentration of the various components can vary widely depending upon the actual operation of the spray booth and means utilized to collect the overspray.
- at least water curtains or similar collection means are utilized, which results in a substantial dilution of the resin and additive parts of the overspray. In the present system, this dilution is preferred because a portion of the content of catchment tank 20 is supplied via line 22 to spray booth 10 for use in the collection of the overspray.
- the concentration of the resin (B) and additive (C) parts in catchment tank 20 should be maintained within the range of from about 0.5 wtZ to about 20 wtZ based upon the total weight contained therein.
- the proportions of the resin and additive parts relative to each other should not significantly vary from that of the fresh waterborne coating, with the possible exception of certain volatile components (e.g. low molecular weight co-solvents, acids and amines) which may evaporate prior to further treatment.
- the overspray is optionally first passed through a rough separation means (not pictured), such as a 1000 mesh sieve, to remove any large particulate or other foreign matter.
- the overspray is passed via lines 24a and 24 directly to an electrophoretic separation means 26.
- the overspray is passed via line 28 into a first separation means interposed between catchment tank 20 and electrophoretic separation means 26.
- First separation means 30 can take any one of a number of forms well-known for separating solids from liquids such as, for example, settling tanks, centrifuges, sedimentation filters and the like, as well as combinations thereof. Of these various well-known options, it is preferred to utilize at least a centrifuge, such as a horizontal centrifuge equipped with a screw conveyor. The result of this first separation step is
- the concentrated phase is then passed via line 32 to a recovery means 34 (e.g. a mixing tank), which in Figure 1 is utilized for recovery of the various components of (B) and (C) separated from the overspray, as well as the reformulation of these so-recovered components into a recycle stream 36 which can be recycled in combination with a fresh waterborne coating stream 38 as the paint feed (paint feed line 12).
- a recovery means 34 e.g. a mixing tank
- the dilute phase which may still contain significant amounts of many of the components of (B) and (C), is then passed via lines 24b and 24 to electrophoretic separation means 26.
- Electrophoretic separationmeans 26 is based upon electrophoresis coatings principles which are well-known to those skilled in the art and need not be explained here in detail. Further detailed information in this respect can be found by reference to any number of well-known literature sources such as, for example, Willibald Machu, Elektrotauchlacktechnik. Verlag Chemie, Weinheim 1974.
- electrophoretic separation means 26 comprises a bath 26a which is provided with an electrode 26b and a source of electric current 26c.
- electrode 26b can be utilized as an anode (for components containing anionic groups such as carboxyl groups) or a cathode (for components containing cationic groups such as amine groups).
- anode for components containing anionic groups such as carboxyl groups
- a cathode for components containing cationic groups such as amine groups.
- the result of the electrophoretic separation step is a concentrated fraction comprising:
- the concentrated fraction from the electrophoretic separation step can be recovered, for example, by removing electrode 26b from bath 26a, then cleaning the deposited material from the surface of electrode 26b. This can be accomplished in any number of ways, such as by scraping and/or soaking the electrode in a diluted solution of the original waterborne coating.
- the so-recovered concentrated fraction is then passed via line 40 to recovery means 34 for further processing.
- the water fraction now comprising only very small amounts of (B) and (C) contained in the original overspray, and preferably less than 1.0 wtZ based upon the total weight of the water fraction, is then further processed by passing it via line 42 to a second separation means 44, where substantially the rest of these other components are removed leaving a relative high purity water stream 46 which can, for example, be recycled back via line 48 to catchment tank 20, or which can be safely and easily disposed of.
- a relative high purity water stream 46 Prior to recycling of water stream 46, it is preferably passed by an ultra-violet light source 50 to prevent bacteria build-up in the system.
- Second separation means 44 can take any one of a number of forms well-known for separation of solutions (separation on a molecular level) such as, for example, ultra- or reverse osmosis filtration. Again, these separation means are well-known to those skilled in the relevant art, and need not be discussed further here.
- the concentrated residue stream produced from this separation step is passed via line 52 to recovery means 34.
- Recovery means 34 will contain all of the recovered components of (B) and (C) from the overspray plus some water carried therewith. Because there has been no chemical treatment of the overspray, the recovered components are essentially in the same state as contained in the original waterborne coating, although relative concentrations may var . In order to make the mixture suitable for recycling, that is, substantially the same composition as the original waterborne coating, the necessary components can be added via make-up line 54 and mixed into the system by well-known waterborne coating formulating techniques.
- FIG. 2 there is shown a more detailed representation of a recycling process and apparatus in which a spray booth 60 is connected to a catchment tank 62 to hold the collected overspray 69, catchment tank 62 being provided with a stirring means 61.
- Catchment tank 62 is further connected to a separation means 65 such as a centrifuge as mentioned earlier, which substantially separates the solid components of the overspray from the other components thereof.
- the resulting stream which is substantially free of solid components is then passed to an intermediate tank 66 and then to a concentrate tank 64 equipped with a stirrer 61.
- Concentration tank 64 is in turn connected to an ultrafiltration means 63 and an electrophoretic separation means 70.
- the electrophoretic separation means 70 in accordance with Figure 2 also utilizes the well-known principle of electrophoretic coating, the deposition process being controlled to such an extent that on the deposition surface 73 of electrophoretic separation means 70 a loose paint layer forms which is easily removable, e.g., via mechanical means 74 such as a scraper.
- the particular construction of the electrophoretic separation means 70 of Figure 2 is generally characterized by an electrophoresis bath 71 (equipped with a stirrer 61) for receiving the stream 70a from concentrate tank 64, an electrode 67 (72) suspended in bath 71 and, as the reciprocal electrode 68, a rotating deposition surface 73 which has in adjoining arrangement one or more mechanical scraper elements 74 to remove the paint material adhering to deposition surface 73, such removed paint material 59 being consigned to a separate recovery tank 71a.
- the liquid currents in the electrophoresis bath 71 are influenced to such an extent that in the area of the electrodes 67 and 68 neither foam formation nor an accumulation of paint material results, and that electrophoresis bath 71 be cooled at least in the area of electrodes 67 and 68. Since practice has shown that optimum paint deposition conditions are material-specific, the relevant settings and/or adjustments must be made for the deposition time, the amount of and allowed ripple in the applied direct current as well as the current limits and pH-value control by amine addition or the like.
- Demineralized water is preferably utilized in the process (e.g., for the water curtain) for the reasons and advantages as described in DE-OS- 3428300 (which is incorporated by reference).
- a number of alternative constructions can be provided for the deposition surface 73 and mechanical scraper elements 74 including the following; a. A parallel arrangement of e.g. plates 75 which periodically immerse in bath 71 and which pivot together with the scraper 74 to the recovery tank 71a ( Figure 3). b. Rotating discs 75a immersed in bath 71 according to Fig. 4, whereby the scraper 74 also acts as a run-off surface for paint material 59. c. Configuration as described under b.; utilizing however a rotating roller as alternative deposition surface (not pictured). d.
- a degree of surface roughness on the deposition surfaces to improve adhesion of the paint material can be advantageous, as can also the provision of (not pictured) drying elements such as warm-air jets, infra-red lamps or the like in the area of the deposition elements not immersed in the electrophoresis bath.
- cooling elements assigned to the area of the deposition electrodes 67,68 this can be carried out by, for example, internal cooling when using a roller 75b as deposition element, or by cooling coils on or in bath 71.
- the systems described can be further supplemented by a subsequent de- watering of the paint material after the mechanical scraping procedure, for example by squeegee rollers with possible further transport of the separated paint material by means of a screw conveyor or the like to a recovery and/or storage tank (not pictured).
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- Chemical & Material Sciences (AREA)
- Molecular Biology (AREA)
- Engineering & Computer Science (AREA)
- Electrochemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Details Or Accessories Of Spraying Plant Or Apparatus (AREA)
- Prevention Of Fouling (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP92909688A EP0583314B1 (en) | 1991-05-08 | 1992-05-07 | Treatment and recycling of overspray from the spray application of waterborne coatings |
DE69220665T DE69220665T2 (en) | 1991-05-08 | 1992-05-07 | GET TREATMENT AND RECOVERY OF OVERSPRAY WHEN SPRAYING ON WATER-SOLUBLE COATINGS |
US08/140,209 US5393390A (en) | 1991-05-08 | 1992-05-07 | Treatment and recycling of overspray from the spray application of waterborne coatings |
JP4509157A JPH09506908A (en) | 1991-05-08 | 1992-05-07 | Treatment and reuse of overspray from spray application of waterborne paints |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP91201107 | 1991-05-08 | ||
EP91201107.9 | 1991-05-08 | ||
DEP4207425.8 | 1992-03-09 | ||
DE4207425A DE4207425A1 (en) | 1992-03-09 | 1992-03-09 | Treating over-spray collected from coating of object with waterborne coating |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1992019686A2 true WO1992019686A2 (en) | 1992-11-12 |
WO1992019686A3 WO1992019686A3 (en) | 1996-09-26 |
Family
ID=25912627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1992/000996 WO1992019686A2 (en) | 1991-05-08 | 1992-05-07 | Treatment and recycling of overspray from the spray application of waterborne coatings |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPH09506908A (en) |
AT (1) | ATE154894T1 (en) |
DE (1) | DE69220665T2 (en) |
WO (1) | WO1992019686A2 (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5393390A (en) * | 1991-05-08 | 1995-02-28 | Akzo Nobel Nv | Treatment and recycling of overspray from the spray application of waterborne coatings |
WO1995035350A1 (en) * | 1994-06-20 | 1995-12-28 | Bollig & Kemper Kg | Water-dilutable stone impact protection paint and compensation paint, their use and processes for their production |
EP0755723A2 (en) * | 1995-07-27 | 1997-01-29 | Haden, Inc., | Spray booth paint reclamation apparatus and method |
EP0839859A3 (en) * | 1996-10-31 | 1999-01-07 | GRUNDIG Aktiengesellschaft | Method and apparatus for treating overspray |
WO2005058993A2 (en) * | 2003-12-17 | 2005-06-30 | Dsm Ip Assets B.V. | A polyurethane and vinyl polymer based recyclable aqueous coating composition |
WO2018010836A1 (en) | 2016-07-10 | 2018-01-18 | Wenker Gmbh & Co. Kg | Method and device for recovering spray mist from spray-painting booths |
EP1736442B1 (en) | 2005-06-23 | 2018-09-12 | Eisenmann SE | Air treatment device and surface-treatment plant with such an air treatment device |
WO2018162113A1 (en) | 2017-03-10 | 2018-09-13 | Wenker Gmbh & Co. Kg | Method and device for recovering spray paint from spray mists of spray-painting booths |
WO2019025020A1 (en) | 2017-08-04 | 2019-02-07 | Wenker Gmbh & Co. Kg | Method and device for recovering spray paint from spray mists of spray-painting booths |
EP3505259A1 (en) * | 2017-12-28 | 2019-07-03 | Vestel Elektronik Sanayi ve Ticaret A.S. | A system for paint recycling and a method of operation |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1533226A (en) * | 1967-01-24 | 1968-07-19 | Manufactures De Carrelages Cer | Firming and drying process for ceramic pastes |
US3748244A (en) * | 1971-07-27 | 1973-07-24 | Scm Corp | Process and apparatus for electric cell treatment of liquor |
FR2519874A1 (en) * | 1982-01-18 | 1983-07-22 | Exteral | Electrostatic sepn. of particles from clay slurries etc. - uses rotating disc partly immersed in slurry to gather polarised particles |
FR2548039A1 (en) * | 1983-06-15 | 1985-01-04 | Ags Bmp Argiles Mineraux | Apparatus for concentrating solids in suspension in a liquid |
EP0141171A2 (en) * | 1983-09-08 | 1985-05-15 | Wolfgang Dipl. Ing. Richter | Process for recovering lacquer material from overspray produced by lacquer spraying, and device for carrying out the process |
WO1987004638A1 (en) * | 1986-02-07 | 1987-08-13 | W. Schmidt Gmbh & Co. Kg | Filter, in particular for a paint recycling installation |
-
1992
- 1992-05-07 DE DE69220665T patent/DE69220665T2/en not_active Expired - Fee Related
- 1992-05-07 JP JP4509157A patent/JPH09506908A/en active Pending
- 1992-05-07 WO PCT/EP1992/000996 patent/WO1992019686A2/en active IP Right Grant
- 1992-05-07 AT AT92909688T patent/ATE154894T1/en not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1533226A (en) * | 1967-01-24 | 1968-07-19 | Manufactures De Carrelages Cer | Firming and drying process for ceramic pastes |
US3748244A (en) * | 1971-07-27 | 1973-07-24 | Scm Corp | Process and apparatus for electric cell treatment of liquor |
FR2519874A1 (en) * | 1982-01-18 | 1983-07-22 | Exteral | Electrostatic sepn. of particles from clay slurries etc. - uses rotating disc partly immersed in slurry to gather polarised particles |
FR2548039A1 (en) * | 1983-06-15 | 1985-01-04 | Ags Bmp Argiles Mineraux | Apparatus for concentrating solids in suspension in a liquid |
EP0141171A2 (en) * | 1983-09-08 | 1985-05-15 | Wolfgang Dipl. Ing. Richter | Process for recovering lacquer material from overspray produced by lacquer spraying, and device for carrying out the process |
WO1987004638A1 (en) * | 1986-02-07 | 1987-08-13 | W. Schmidt Gmbh & Co. Kg | Filter, in particular for a paint recycling installation |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5393390A (en) * | 1991-05-08 | 1995-02-28 | Akzo Nobel Nv | Treatment and recycling of overspray from the spray application of waterborne coatings |
WO1995035350A1 (en) * | 1994-06-20 | 1995-12-28 | Bollig & Kemper Kg | Water-dilutable stone impact protection paint and compensation paint, their use and processes for their production |
JPH09503548A (en) * | 1994-06-20 | 1997-04-08 | ボリッヒ ウント ケンパー カーゲー | Water-dilutable stone impact protection paints and compensating paints, their uses and methods of making them |
EP1186621A1 (en) * | 1994-06-20 | 2002-03-13 | Bollig & Kemper GmbH & Co. KG | Multilayer coating and its use in the car industry |
EP0755723A2 (en) * | 1995-07-27 | 1997-01-29 | Haden, Inc., | Spray booth paint reclamation apparatus and method |
EP0755723A3 (en) * | 1995-07-27 | 1997-11-26 | Haden, Inc., | Spray booth paint reclamation apparatus and method |
EP0839859A3 (en) * | 1996-10-31 | 1999-01-07 | GRUNDIG Aktiengesellschaft | Method and apparatus for treating overspray |
WO2005058993A3 (en) * | 2003-12-17 | 2005-11-24 | Dsm Ip Assets Bv | A polyurethane and vinyl polymer based recyclable aqueous coating composition |
WO2005058993A2 (en) * | 2003-12-17 | 2005-06-30 | Dsm Ip Assets B.V. | A polyurethane and vinyl polymer based recyclable aqueous coating composition |
EP1736442B1 (en) | 2005-06-23 | 2018-09-12 | Eisenmann SE | Air treatment device and surface-treatment plant with such an air treatment device |
WO2018010836A1 (en) | 2016-07-10 | 2018-01-18 | Wenker Gmbh & Co. Kg | Method and device for recovering spray mist from spray-painting booths |
WO2018162113A1 (en) | 2017-03-10 | 2018-09-13 | Wenker Gmbh & Co. Kg | Method and device for recovering spray paint from spray mists of spray-painting booths |
WO2019025020A1 (en) | 2017-08-04 | 2019-02-07 | Wenker Gmbh & Co. Kg | Method and device for recovering spray paint from spray mists of spray-painting booths |
DE102017007329A1 (en) | 2017-08-04 | 2019-02-07 | Wenker Gmbh & Co. Kg | Process and apparatus for the recovery of spray paints from spray mist spray booths |
DE102017007329B4 (en) | 2017-08-04 | 2023-07-27 | Wenker Gmbh & Co. Kg | Method and device for recovering spray paint from spray mist from spray painting booths |
EP3505259A1 (en) * | 2017-12-28 | 2019-07-03 | Vestel Elektronik Sanayi ve Ticaret A.S. | A system for paint recycling and a method of operation |
Also Published As
Publication number | Publication date |
---|---|
WO1992019686A3 (en) | 1996-09-26 |
DE69220665D1 (en) | 1997-08-07 |
DE69220665T2 (en) | 1997-12-18 |
JPH09506908A (en) | 1997-07-08 |
ATE154894T1 (en) | 1997-07-15 |
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