WO1992004491A1 - A process for preparing a unidirectional fiber web, the use thereof for preparing unidirectional composite materials - Google Patents
A process for preparing a unidirectional fiber web, the use thereof for preparing unidirectional composite materials Download PDFInfo
- Publication number
- WO1992004491A1 WO1992004491A1 PCT/EP1991/001748 EP9101748W WO9204491A1 WO 1992004491 A1 WO1992004491 A1 WO 1992004491A1 EP 9101748 W EP9101748 W EP 9101748W WO 9204491 A1 WO9204491 A1 WO 9204491A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- unidirectional
- rovings
- fiber web
- fibers
- continuous
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/06—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
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- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/18—Separating or spreading
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
- D04H1/74—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being orientated, e.g. in parallel (anisotropic fleeces)
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/002—Inorganic yarns or filaments
- D04H3/004—Glass yarns or filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
- D04H3/04—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/10—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
- D04H3/105—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by needling
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/02—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by mechanical methods, e.g. needling
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/06—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H5/00—Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
- D04H5/12—Glass fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/24—Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/10—Organic non-cellulose fibres
- D21H13/20—Organic non-cellulose fibres from macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H13/26—Polyamides; Polyimides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
- D21H27/32—Multi-ply with materials applied between the sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2305/00—Condition, form or state of the layers or laminate
- B32B2305/08—Reinforcements
Definitions
- the present invention essentially relates to a process for preparing a unidirectional fiber web, a unidirectional continuous fiber web obtained thereby, the use thereof for preparing unidirectional composite materials and unoirectional composite materials optained thereby.
- a main purpose of the present invention is to solve the technical problem of providing a unidirectional fiber web which can be adapted to a wide range of width, thickness, mechanical properties, in a reliable manner.
- Another main purpose of the present invention is to solve the technical problem of preparing unidirectional fiber webs, which can be used in the manufacture of unidirectional composite materials naving wide mecnanical properties while being adapted to the manufacture of said composite materials through a wet process, according to t he traditional paper technology.
- a furtner main purpose of the present invention is to solve the technical prcolem of providing a unidirectional fiber web, which is well adapted to the manufacture of laminated unidirectional composite materials comprising a wide type of thermoplastic resin and of reinforcing materials, thereby increasing the versatility of the use of said composite materials.
- the present invention provides a process for preparing a unidirectional fiber web comprising disposing several rovings side by side, each having a plurality of individual fiber filaments, and needling transversally said rovings, thereby opening the rovings and forming a continuous fiber web therefrom.
- the continuous fiber web is obtained through overlapping of filaments of adjacent rovings.
- said rovings comprise thousands of individual continuous fiber filaments bundling together.
- said needling is performed with hundreds of needles, each needle having an enlarged basis and being provided on the lateral surface thereof with protuberances, such as spikes.
- the rovings are continuous fiber glass rovings.
- Said rovings have preferably a width of some millimetres, for instance about 5 millimetres and the continuous fiber filaments have a diameter ranging between 10 and 50 micrometres, preferably between 15 and 25 micrometres.
- the needling provides an opening of the rovings from 2 to 6 times the width of the initial roving width.
- the needling is performed so as to reach a continuous unidirectional fiber web having a weight ranging between 50 and 1000 g/m 2 , more preferably from 500 g/m 2 to 700 g/m 2 .
- the invention also relates to a continuous unidirectional fiber web, which has been obtained from several rovings laid side by side and needled.
- the present invention relates to a process for preparing unidirectional composite material, comprising preparing a unidirectional fiber web and sandwiching this unidirectional fiber web between at least one reinforced thermoplastic sheet through a web process.
- said reinforced thermoplastic layer is laid en either side of the unidirectional fiber web on an inclined wire at the bottom part or at an intermediate part thereof.
- the composite structure will be found by sandwiching the above-said unidirectional continuous fiber web between two outer layers of reinforced thermoplastic sheets.
- two layers of unidirectional continuous web can be sandwiched between two outer layers of reinforced thermpplastic sheets.
- many comoinations of sheets can be performed at will.
- the thermoplastic material of the reinforced thermoplastic sheet can be selected from a polyolefine, in particular polyethylene, polypropylene and copolymers thereof, polyvynyl chloride, polystyrene and copolymers, polyamide, saturated polyesters, polyetnylene ether, a polycarbonate and any plastic alloy.
- a most preferred thermoplastic resin is polypropylene.
- the thermoplastic material is supplemented by a coupling agent which in the final product improves contact between the thermoplastic and the reinforcing material.
- Preferred coupling agents are acid or anhydride functionalized thermoplastics such as alpha, beta unsaturated carboxylic acid functionalized thermoplastics.
- One such example is maleic or itaconic anhydride grafted polypropylene.
- thermoplastic resin is advantageously under powder form having a mean particle size ranging between 200 micrometres and 1,000 micrometres, more preferaoly between 300 and 1,000 micrometres.
- the reinforcing material of the thermoplastic composite is under fiber form and is selected from glass fibers, carbon fibers, ceramic fibers, boron fibers, glass wool, rock wood, metallic fibers, hot melt organic synthetic fibers, notably aromatic polyamide, polyesters and others.
- the length of the reinforcing fibers preferably ranges between 5 mm and 25 mm, and the diameter between 5 and 20 micrometers.
- the reinforced thermoplastic composite sheets are prepared through a wet process according to the traditional paper making technology, from a dilute slurry, preferably having from 0.1 to 5 % by weight dry content, fed preferably onto an inclined wire.
- the slurry composition, on a dry content basis, of the thermoplastic composite sheet comprises :
- the slurry composition can contain a polyolefine pulp in a content from 2 to 20 %/
- each thermoplastic composite sheet has a basis weight which ranges between 400 g/m 2 and 5 kg/m 2 , and more preferably from 800 to 5000 g/m 2 , and most preferably around 2800 g/m 2 .
- the unidirectional fiber web according to the invention can be prepared from a continuous mineral roving, for instance a continuous fiber glass roving commercially available from Owens Corning Fiberglas Europe under the reference R16 EX3, having a 5 mm width, 2400TEX (g/1000 m), each filament having a diameter of 24 microns.
- This roving is composed of thousands of individual continuous fiber glass filament bundling together. Additional sizing is added by the fiber glass suppliers so that to ensure these filaments can stay bundled together.
- a needling machine commencially available, for instance from Asselin machine, usually used to produce non-woven can typically be provided with needles supplied by Singer reference 15*18*36/3.5BL 30A610 of triangular shape with protuberances such as spixes on each side of needle, said needle being held by a holder up to 4 metres wide.
- the principle of said needling machine is represented in the appended figures 1 and 2.
- figure 1 it is shown schematically the needling machine under reference number 10, which is fed with a plurality of continuous fiber rovings referenced 12 unrolled from rolls 14.
- FIG 2 it is shown a partial enlarged view of a needle 40 with protuberances 42 such as spikes, going through a roving 12 to provide an opened roving naving at least a double width referenced 16a since it is a part of the continuous web 16 of figure 1.
- the needling machine consists of hundreds of needles, each needle having many spikes 42 as shown on figure 2.
- the main factors, which affect how wide the rovings can be opened, are the type and sizes of needles, the number of needles per cm 2 , the speed of the machine and the penetration depth of the needles.
- the needling conditions are :
- typically 0.5 cm wide roving can be opened to a 1 to 3 cm wide continuous web, preferably 1.0 cm.
- the general conditions of prepa ri ng the composite sheets are as follows, with reference to figure 3 for instance with regard to the preparation of a sheet having 3 layers, a core or a central layer 16 made with the unidirectional continuous fiber web as obtained at the outlet of the needling machine sandwiched two outlet layers of reinforced thermcpiastic material referenced 19 and 21, which are clearly seen on the enlarged cross-section, according to the lines IV-IV of figure 4.
- Each reinforced thermoplastic sheet 19 and 21 is obtained through the wet method of the traditional paper making technology from a first head box 18 and a second head box 20 feeding a slurry containing the composite sheet components in suspension therein onto an inclined wire 30, whicn filtrates water 32 with the aid of a small air depression, as it will be more c l ea r ly understood in reference to the following examples.
- the mixture was then splitted into two streams. Each stream was admitted onto a wire screen 30 through a head box 18 or 20, dewatered then dried according to the conventional paper making technique.
- a roll of continuous glass web 16 with a basis weight of 480 g/m 2 and a width of 28 cm was also laid onto the wire 30 between the first and second head box 18, 20.
- the arrangement of the head boxes 18, 20 and the continuous glass web 16 feeding is schematically illustrated in figure 3.
- the composite sheet thus obtained, illustrated in figure 4 had a basis weight of 2700 g/m 2 and comprised sufficient cohesion to be handled, stored, transported and in which the various components of the formulation have been perfectly retained.
- three of such composite sheets may for example be superposed and, after having effected preheating up to a temperature of the order of 180oC to 201oC, the assembly may be moulded under pressures of 40 to 100 kg/cm 2 for a cycle less than 30 seconds.
- composition of the slurry contained 2.65 g of dispersant, 26.5 g of fiberglass, 6 g of polypropylene pulpex, 1 g of flocculent, 61.5 g of polypropylene and 6 g of coupling agent.
- dispersant 2.65 g of dispersant, 26.5 g of fiberglass, 6 g of polypropylene pulpex, 1 g of flocculent, 61.5 g of polypropylene and 6 g of coupling agent.
- two rolls of continuous glass web 16 were introduced.
- Example 4 differs from Example 1 in that the composition of the slurry contained 4.2 g of dispersant, 42 g of fiberglass, 6 g of polypropylene pulpex, 1 g of flocculent, 46 g of polypropylene and 6 g of coupling agent. No continuous glass web 16 was introduced.
- Example 4 the composition of the slurry contained 4.2 g of dispersant, 42 g of fiberglass, 6 g of polypropylene pulpex, 1 g of flocculent, 46 g of polypropylene and 6 g of coupling agent. No continuous glass web 16 was introduced.
- INVENTION EXAMPLE 4 No continuous glass web 16 was introduced.
- Example 1 400 g of the moulded industrial product as described in Example 1 was placed into a infrared oven heated at a temperature of 300-320°C for 4.5 minutes. This well heated product was then transferred to a mould set at 60-80 °C and shaped like a box. The sample was moulded under pressures of 100 to 200 kg/cm 2 for a cycle time of less than 5 minutes. The moulded box was cut into 24 pieces as well known to those skilled in the composite art. Ash content analyzes showed that the minimum and maximum ash contents were 34.17% and 42.56 % respectively.
- This example differs from Example 4 in that a competitive sample from Elastogran, Elastopreg R B100M45, was preheated and moulded. On close examination of the moulded box, some wall sections are not filled.
- Example 1 and 2 contain two levels of unidirectional web, the properties are much higher than comparative Example 3 which contains only random chopped fibers.
- a competitive sample from Elastogran, Elastopreg B100 M45 R was also analyzed and the properties are shown comparable to our Example 1, except the competitive sample contains 100 % unidirectional fibers versus only 18 % unidirectional fibers in the invention sample. When the sample was highly loaded with unidirectional fibers, poor fiberglass dispersion and incomplete filling of a mould are observed as shown by comparison of invention Example 4 versus comparative Example 5.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Paper (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9019774.0 | 1990-09-10 | ||
GB909019774A GB9019774D0 (en) | 1990-09-10 | 1990-09-10 | A process for preparing a unidirectional fiber web,unidirectional continuous fiber web obtained thereby |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1992004491A1 true WO1992004491A1 (en) | 1992-03-19 |
Family
ID=10681974
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1991/001748 WO1992004491A1 (en) | 1990-09-10 | 1991-09-10 | A process for preparing a unidirectional fiber web, the use thereof for preparing unidirectional composite materials |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0548198A1 (en) |
JP (1) | JPH06500831A (en) |
GB (1) | GB9019774D0 (en) |
WO (1) | WO1992004491A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5872067A (en) * | 1997-03-21 | 1999-02-16 | Ppg Industries, Inc. | Glass fiber strand mats, thermoplastic composites reinforced with the same and methods for making the same |
US5883021A (en) * | 1997-03-21 | 1999-03-16 | Ppg Industries, Inc. | Glass monofilament and strand mats, vacuum-molded thermoset composites reinforced with the same and methods for making the same |
US5883023A (en) * | 1997-03-21 | 1999-03-16 | Ppg Industries, Inc. | Glass monofilament and strand mats, thermoplastic composites reinforced with the same and methods for making the same |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6520662B2 (en) * | 2015-11-24 | 2019-05-29 | 王子ホールディングス株式会社 | Base material for fiber reinforced plastic molded body and fiber reinforced plastic molded body |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3242033A (en) * | 1962-02-21 | 1966-03-22 | Fiber Glass Ind Inc | Glass fiber mat |
GB1134401A (en) * | 1964-11-21 | 1968-11-20 | Ici Ltd | Nonwoven fabrics and methods of, and apparatus for, making them |
GB2045305A (en) * | 1979-03-28 | 1980-10-29 | Schuller Gmbh Glaswerk | Reinforced Non-woven Webs |
EP0296970A1 (en) * | 1987-06-26 | 1988-12-28 | Vetrotex Saint-Gobain | Method and apparatus for needling a glassfibre mat and composite article made from this mat |
-
1990
- 1990-09-10 GB GB909019774A patent/GB9019774D0/en active Pending
-
1991
- 1991-09-10 JP JP3514889A patent/JPH06500831A/en active Pending
- 1991-09-10 EP EP91916532A patent/EP0548198A1/en not_active Ceased
- 1991-09-10 WO PCT/EP1991/001748 patent/WO1992004491A1/en not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3242033A (en) * | 1962-02-21 | 1966-03-22 | Fiber Glass Ind Inc | Glass fiber mat |
GB1134401A (en) * | 1964-11-21 | 1968-11-20 | Ici Ltd | Nonwoven fabrics and methods of, and apparatus for, making them |
GB2045305A (en) * | 1979-03-28 | 1980-10-29 | Schuller Gmbh Glaswerk | Reinforced Non-woven Webs |
EP0296970A1 (en) * | 1987-06-26 | 1988-12-28 | Vetrotex Saint-Gobain | Method and apparatus for needling a glassfibre mat and composite article made from this mat |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5872067A (en) * | 1997-03-21 | 1999-02-16 | Ppg Industries, Inc. | Glass fiber strand mats, thermoplastic composites reinforced with the same and methods for making the same |
US5883021A (en) * | 1997-03-21 | 1999-03-16 | Ppg Industries, Inc. | Glass monofilament and strand mats, vacuum-molded thermoset composites reinforced with the same and methods for making the same |
US5883023A (en) * | 1997-03-21 | 1999-03-16 | Ppg Industries, Inc. | Glass monofilament and strand mats, thermoplastic composites reinforced with the same and methods for making the same |
Also Published As
Publication number | Publication date |
---|---|
EP0548198A1 (en) | 1993-06-30 |
JPH06500831A (en) | 1994-01-27 |
GB9019774D0 (en) | 1990-10-24 |
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