WO1992004284A1

WO1992004284A1 - Method for purification of wastewater

Info

Publication number: WO1992004284A1
Application number: PCT/SE1991/000582
Authority: WO
Inventors: Kurt Alfred JÖNSSON
Original assignee: Axel Johnson Engineering Ab
Priority date: 1990-09-07
Filing date: 1991-09-04
Publication date: 1992-03-19
Also published as: SE468985B; SE9002864L; US5372720A; KR960004304B1; CA2090604A1; CA2090604C; EP0594623A1; JPH06500729A; AU651379B2; SE9002864D0; AU8506591A; KR930702233A

Abstract

In a method of treating wastewater trickling through a granular filter bed activated by bacteria, there is first carried out simultaneous precipitation of phosphor and denitrification, subsequent to which there is carried out a reduction of excess (BOD) in the wastewater, preferably by blowing in an oxygen-containing gas.

Description

Method for Purification of Waste Water

It is known in the art to remove nitrogen and phosphor simul- taneously from wastewater with the use of an active sludge that contains aerobic bacteria. It is also known from the Swedish patent No 456 990 to add the sludge in anaerobic conditions, so that the aerobic bacteria are urged to liberate phosphor, which the anaerobic bacteria can then take up. The process takes place in treatment basins under heavy agitation.

It is known from the French patent No 2619 804 to denitrify drinking water using a granular filter bed, to which are added sources of phosphor and carbon. Here, the majority of the phosphor is taken up by anaerobic bacteria.

In contradistinction to the known art as cited above, waste¬ water is treated, in the method according to the invention, in a granular filter bed that has been activated by bacteria, preferably heterotrophic bacteria. According to the invention, there then occurs simultaneous precipitation of phosphor and denitrification in the wastewater during the first part of its percolation through the filter bed, and later on in the bed an excess biological oxygen demand (BOD) is reduced, preferably close to zero.

It should be noted that before the mentioned inventive method is applied, the water has been first subjected to nitrifi¬ cation according to the known art, such that the nitrogen compounds in the wastewater have been converted to nitrates or to nitrites.

In a preferred method according to the invention, the BOD reduction takes place with the addition of oxygen, and, espe- cially, in a simple and advantageous method, by blowing an oxygen-containing gas, preferably air.

SUBSTITUTESHEET A precipitation/flocking agent for precipitating phosphor is added to the wastewater immediately before the latter enters the filter bed.

The quantity of organic substances in wastewater that can function as sources of carbon for the bacterium strain is often not enough to provide sufficient denitrification. It may be necessary to add a further source of carbon, cheap hydro¬ carbons such as methanol, starch or molasses being selected for this purpose. These carbon sources may suitably be added to the wastewater immediately before it enters the filter bed. It is probable that the founding strain of bacteria adhere to the grains, usually sand, of the filter' bed. Here they come into intimate contact with the carbon source, and nitrates present are reduced to nitrogen gas. A typical formula for such denitrification is:

Nθ + 1.08 CH₃OH + H⁺ = 0.065 C₅H₇0₂N + 0.47 N₂ + 0.76 C0₂ + 2.44 H₂0

where 0.065 C₅H₇0₂N corresponds to the production of new bac¬ teria.

If the amount of sludge is increased by relatively large and voluminous precipitates or floccules of phosphor, e.g. iron phosphate, then it is reasonable to asssume that denitrifi¬ cation will be disturbed unfavorably by these precipitations. However, no negative effect at all by the phosphates on the denitrification process in different types of filter bed has been found. There thus exists the basic condition for enabling simultaneously the reduction of nitrogen, precipitation of phosphor, reduction of excessive BOD and filtration in a single process step, which requires two or three steps accor¬ ding to the present art.

Iron chloride is a suitable precipitation agent for phosphor. Other suitable precipitation/flocculation agents in use, e.g.

SUBSTITUTESHEET aluminium sulphate with or without polyeletrolyte additives, lime etc, have been found not to affect the denitrification process either.

A factor supposed to affect denitrification is washing the filter bed. Practically, it is quite possible to wash the bed so thoroughly that the bacterium strain is unfavorably reduced. Heavy counter-flushing of a stationary filter appear to be particularly injurious. However, it has been found that the washing sufficient for removing sludge and contaminants from the sand does not notably impoverish the bacterium strain. All the nitrogen gas that may be entrained in the san and sludge is also removed in such washing. The so-called con tinous sand filters are particularly favorable for use in a method according to the present invention, only a small por¬ tion of the filter bed at a time being subjected to such washing. In these sand filters, where most contaminated sand is taken away for washing, and then returned to the filter bed, there are great possibilities for regulating both the intensity and periodicity of washing, such as sand filter, which is very suitable for denitrification and purification from phosphor, is described in the Swedish patent specifi¬ cation No 7602999-0.

Denitrification is directly proportional to the total surface of the sand grains in the filter bed. Its capacity may be improved by reducing the size of the grains and/or by increa¬ sing its height. At the same time, the period of active resi¬ dence between washings of each grain in the bed can thus be extended also.

The result obtained, i.e. nitrogen and phosphor reductions, is mainly controlled by the added quantities of carbon source and phosphor precipitation agents. By a well-balanced selection of these factors, a simultaneous nitrogen and phosphor reduction of over 90% may be obtained for a surface load on the filter bed of 15 m/h. In the practical operation of a filter described above, there may be large variations in the composition of the incoming wastewater. The amount of sludge as well as the nitrogen and phosphor contents may vary heavily within relatively short preiods of time. The addition of carbon source should not be of the order of magnitude enabling an unnecessarily large BOD load to be achieved in the departing water, neither should it be too low for achieving an optimum result.

Continuous monotoring of the incoming and/or outgoing water with respect to the content of nitrogen, phosphor and its BOD/COD (biological/chemical oxygen demand) can be arranged to control, in accordance with the known art, the amounts of the additives such as to obtain optimum conditions.

In a granular filter bed, denitrification and phosphor preci¬ pitation are both rapid, compared with corresponding processes in a basin. The residence time for wastewater in a continously operating filter bed, for example, is of the order of magni- tude 10 min, compared with several hours in a basin. This makes it particularly advantegous, in carrying out simultanous nitrogen and phosphor reduction in a continously operating filter bed, to regulate the additions of carbon source and/or precipitating agent on the basis of measured values of nitro- gen and/or BOD/COD, preferably in the outgoing wastewater. This control of the additives can also be used to advantage when the invention is applied to the stationary filter beds.

In certain cases it may, however, be su'itable to dispense with regulation of the carbon source, and knowingly add exessive amounts thereof insted, thus creating a high BOD. But even with regulation of the carbon source additive, it would in most cases be impossible to meet the ever more severe require¬ ments for low BOD in the outgoing wastewater now being deman- ded. The invention thus gives directions, not only with respect to the simultaneous phosphor precipitation and deni¬ trification, but also how to reduce the invention, the reduc- tion of BOD excess is accomplished by blowing an oxygen-con¬ taining gas, usually air, into the upper part of a filter bed. This may be performed by blowing the gas through a row of nozzles or jets, for example.

Claims

1. A method of reducing nitrogen, phosphor and excessive BOD in wastewater supplied to, and for trickling through, a granular filter bed activated with bacteria, characterized in that in the flow direction of the wastewater through the bed there first take place simultaneous precipitation of phosphor and denitrification, subsequent to which there is a reduction of the excess BOD.

2. Method as claimed in claim 1, characterized in that the excess BOD is reduced with the aid of supplied oxygen.

3. Method as claimed in claim 2, characterized in that the oxygen is supplied by blowing in an oxygen-containing gas, preferably air.

4. Method as claimed in any one of the preceeding claims, characterized in that immediately before wastewater enters the filter bed a precipitation/flocculation agent is added for precipitation phosphor.

5. Method as claimed in any one of the preceeding claims, characterized in that a further source of carbon is added for denitrification, in addition to the amount of organic material functioning as a carbon source in the wastewater.

6. Method as claimed in claim 5, characterized in that the extra carbon source is added to the wastewater immediately prior to the entry of the latter into the filter bed.

7. Method as claimed in any one of the preceeding claims, characterized in that precipitation of phosphor and denitrifi- cation are carried out in a continously operating filter bed.

8. Method as claimed in any one of the preceeding claims, characterized in that the nitrogen content in the outgoing wastewater causes regulation of the amount of the added carbon source.

9. Method as claimed in any one of the preceeding claims, characterized in that the phosphor content in the outgoing wastewater causes regulation of the amount of added precipi- tation agent.

10. Method as claimed in any one of the preceeding claims, characterized in that the BOD/COD value in the outgoing waste¬ water causes regulation of the amount of added carbon source.