WO1991008117A1 - Process for applying pictorial designs to the surfaces of articles - Google Patents

Process for applying pictorial designs to the surfaces of articles Download PDF

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Publication number
WO1991008117A1
WO1991008117A1 PCT/CH1990/000255 CH9000255W WO9108117A1 WO 1991008117 A1 WO1991008117 A1 WO 1991008117A1 CH 9000255 W CH9000255 W CH 9000255W WO 9108117 A1 WO9108117 A1 WO 9108117A1
Authority
WO
WIPO (PCT)
Prior art keywords
transfer
printer
printing device
printing
paper
Prior art date
Application number
PCT/CH1990/000255
Other languages
German (de)
French (fr)
Inventor
Hans Jörg MÜLLER
Original Assignee
Strico Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Strico Ag filed Critical Strico Ag
Publication of WO1991008117A1 publication Critical patent/WO1991008117A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means

Definitions

  • the invention relates to a method for applying pictorial representations such as e.g. Decorations or barcodes in the transfer process on objects, which are then subjected to a processing process in a higher temperature range.
  • pictorial representations such as e.g. Decorations or barcodes
  • Such pictorial representations are also generally referred to as transfer decorations because they are transferred from a printing medium by means of a pull-off process to the object to be provided with the pictorial representation and are applied thereon in a permanent form.
  • the term pictorial representations or images are understood to mean illustrations and decorative motifs as well as figurative and word marks, signs, logos, operating instructions, numbers, bar codes or combinations of the aforementioned types.
  • objects go through a further processing process at a higher temperature, this involves, for example, a heat treatment of approximately 400 ° C.
  • Glass components are understood to mean, for example, picture tubes for television sets or office equipment, and also glass casting molds for spectacle lenses, in which temperatures of up to 500 ° C. are used as well as for drinking and laboratory glasses, in which even higher temperatures up to around 700 C are used.
  • temperatures of 700 ° C. to almost 1300 ° C. are used during the firing.
  • transfer decorations has hitherto been a relatively complex process, in which a representative template must first be produced following the design and a photographic reprofilm is then produced, with the aid of which a printing form such as a stencil is then used is produced for screen printing or a plate for offset printing. Finally, a printing machine must be set up in order to print on a special paper by means of screen or offset printing.
  • This special paper is a printing medium with a water-soluble separating layer, also referred to as "decal paper”.
  • Printing inks based on glass pigments are generally used, the melting point of which is matched to the temperature range of the planned heat application.
  • overprint varnish which is colorless or varnished, which is referred to as "over-filming”.
  • over-filming a so-called “overprint varnish” is applied, which is colorless or varnished, which is referred to as "over-filming”.
  • the printing ink and the surface of the object to be provided with the transfer decor are then firmly bonded by sintering when the intended temperature of the heat application has been reached.
  • This conventional method is relatively complex and too expensive if only a few copies of the individual transfer decor are required or if each individual is to differ from the other, which is particularly the case when transfer decorations in the form of continuous ⁇ fend numbered barcodes to be produced. As a rule, only a single copy is to be produced for each number, which is only a purely functional task Has .
  • the present invention was therefore based on the object, instead of the previously conventional way of using a reprofile template and a reprofilm and a printing form, to develop a much more economical and quicker method leading to the result, in particular for unequal transfer decorations such as continuously barcodes.
  • the desired transfer decor such as, for example, a consecutively numbered bar code
  • this program is used to control the printing device, which transfers -Decor applied directly to the water-soluble separating layer of a special paper for ceramic printing.
  • special paper or decal paper a material is preferably used which is matched to this method and in particular to the heat during the fixing of the printing ink in the stoving station of the printing device.
  • xerographic laser printers as well as ion deposit printers and magnetographic printers as well as thermal transfer printers and similar computer-controlled devices can be used.
  • the toner used in the respective printer for the usual office use ie the mostly powdery color
  • toner which contains the color pigments suitable for high temperatures and adapted to the heat effect used.
  • These can either simply be added to the toner or added in the form of resin-coated pigments.
  • these measures relate to the color of the ink ribbon, in the coloring of which the special alpi gmente have to be processed.
  • the prints made directly on the special paper are then "over-filmed" using an overprint varnish.
  • An overprint varnish is used which is suitable for the respective printing method, in particular for the effects of the printing method, such as the change in the water-soluble separating layer of the decal paper due to the action of heat when passing through the fixing station in the printer.
  • a so-called grid pattern can also be used, with the result that any air and water inclusions that are present can escape through small holes in the varnish layer when the decal is applied and when the decal is baked, so that the transfer decor produced does not get through explosive expansion of such inclusions is destroyed under the influence of heat.

Abstract

For the production of transfer designs, the invention uses a printing device which applies various designs, such as bar codes, directly to a sheet of transfer paper, design selection being electronically controlled and for instance computer-programmed. The design is then transferred, by a transfer peeling process, to the surface of an article, on which it is fixed permanently by heating. The special paper and printing ink used in the process must therefore be heat-resistant at the temperatures used in the particular application. This also applies to the varnish coating applied to the special paper after the design has been printed.

Description

Verfahren zum Aufbringen von bildlichen Darstellungen auf Gegenstände Process for applying images to objects
Die Erfindung betrifft ein Verfahren zum Aufbrin¬ gen von bildlichen Darstellungen wie z.B. Dekors oder Strichcodes im Transferverfahren auf Gegenstände, welche anschl iessend einem Verarbeitungsprozess in einem höheren Temperaturbereich unterzogen werden.The invention relates to a method for applying pictorial representations such as e.g. Decorations or barcodes in the transfer process on objects, which are then subjected to a processing process in a higher temperature range.
Man bezeichnet derartige bildliche Darstellungen auch allgemein als Transfer-Dekors, weil sie von einem Druckträger mittels eines Abzi eh-Verfahrens auf den mit der bildlichen Darstellung zu versehenen Gegenstand über¬ tragen und auf diesem in dauerhafter Form aufgebracht werden. Unter dem Begriff bildliche Darstellungen oder Bilder werden Illustrationen und Dekorationsmotive sowie ferner Bild- und Wortmarken, Signete, Logos, Bedienungs¬ anleitungen, Zahlen, Strichcodes oder Kombinationen der vorgenannten Arten verstanden.Such pictorial representations are also generally referred to as transfer decorations because they are transferred from a printing medium by means of a pull-off process to the object to be provided with the pictorial representation and are applied thereon in a permanent form. The term pictorial representations or images are understood to mean illustrations and decorative motifs as well as figurative and word marks, signs, logos, operating instructions, numbers, bar codes or combinations of the aforementioned types.
Wenn Gegenstände nach dem Aufbringen des soge¬ nannten Transfer-Dekors einen Weiterverarbeitungsprozess bei höherer Temperatur durchlaufen, so handelt es sich beispielsweise um eine Hitzebehandlung von etwa 400° C bei. Glaskomponenten oder von nahezu 1300° C bei Produkten der Sanitärkeramik, die gebrannt werden, wobei diese Gegenstände je nach Produkt nur wenige Minuten bis zu mehreren Stunden oder sogar während mehrerer Tage der Hitzebehandlung ausgesetzt werden. Unter Glaskomponenten versteht man beispielsweise Bildröhren für Fernsehgeräte oder Bürogeräte, ferner Glas-Gussformen für Brillenglä¬ ser, bei denen Temperaturen bis über 500° C zur Anwendung gelangen, sowie für Trink- und Laborgläser, bei denen noch höhere Temperaturen bis gegen 700 C zur Anwendung gelangen. Bei Porzellan- und Keramikwaren wie beispiels¬ weise Sanitärkeramik kommen je nach Artikel beim Brennen Temperaturen von 700° C bis nahezu 1300° C zur Anwendung.If, after the so-called transfer decoration has been applied, objects go through a further processing process at a higher temperature, this involves, for example, a heat treatment of approximately 400 ° C. Glass components or of almost 1300 ° C for sanitary ware products, which are fired, depending on the product, these objects are only subjected to heat treatment for a few minutes to several hours or even for several days. Glass components are understood to mean, for example, picture tubes for television sets or office equipment, and also glass casting molds for spectacle lenses, in which temperatures of up to 500 ° C. are used as well as for drinking and laboratory glasses, in which even higher temperatures up to around 700 C are used. In the case of porcelain and ceramic goods such as sanitary ware, depending on the article, temperatures of 700 ° C. to almost 1300 ° C. are used during the firing.
Die Herstellung von Transfer-Dekors ist bisher ein relativ aufwendiges Verfahren, bei dem zunächst an- schliessend an den Entwurf eine reprofähige Vorlage her¬ gestellt werden muss und anschl i essend ein fotografischer Reprofilm hergestellt wird, mit dessen Hilfe dann eine Druckform wie beispielsweise eine Schablone für den Sieb¬ druck oder eine Platte für den Offsetdruck hergestellt wird. Schliesslich muss eine Druckmaschine eingestellt werden, um mittels Sieb- oder Offsetdruck ein Spezialpa¬ pier zu bedrucken. Dieses Spezialpapier ist ein Druckträ¬ ger mit einer wasserlöslichen Trennschicht, auch als so¬ genanntes "Abziehbilder-Papier" bezeichnet. Für den Druck verwendet man allgemein auf Glaspigmenten basierende Druckfarben, deren Schmelzpunkt auf den Temperaturbereich der geplanten Hitzeanwendung abgestimmt ist. Anschliess- end wird noch ein sogenannter "Überdruck-Lack" aufge¬ bracht, der farblos oder lasierend bunt ist, was als "Überfilmen" bezeichnet wird. Anschl iessend erfolgt dann durch Sinterung eine feste Verbindung der Druckfarbe und der Oberfläche des mit dem Transfer-Dekor zu versehenen Gegenstandes, wenn die vorgesehene Temperatur der Hitze¬ anwendung erreicht ist.The production of transfer decorations has hitherto been a relatively complex process, in which a representative template must first be produced following the design and a photographic reprofilm is then produced, with the aid of which a printing form such as a stencil is then used is produced for screen printing or a plate for offset printing. Finally, a printing machine must be set up in order to print on a special paper by means of screen or offset printing. This special paper is a printing medium with a water-soluble separating layer, also referred to as "decal paper". Printing inks based on glass pigments are generally used, the melting point of which is matched to the temperature range of the planned heat application. Then a so-called "overprint varnish" is applied, which is colorless or varnished, which is referred to as "over-filming". Subsequently, the printing ink and the surface of the object to be provided with the transfer decor are then firmly bonded by sintering when the intended temperature of the heat application has been reached.
Dieses herkömmliche Verfahren ist relativ aufwen¬ dig und zu teuer, wenn von dem einzelnen Transfer-Dekor nur wenige Exemplare benötigt werden bzw. sich jedes ein¬ zelne vom anderen unterscheiden soll, was insbesondere der Fall ist, wenn Transfer-Dekors in Form von fortlau¬ fend numerierten Strichcodes herzustellen sind. Dabei ist je Nummer in der Regel nur ein einziges Exemplar her¬ zustellen, welches nur eine rein funktionelle Aufgabe hat .This conventional method is relatively complex and too expensive if only a few copies of the individual transfer decor are required or if each individual is to differ from the other, which is particularly the case when transfer decorations in the form of continuous ¬ fend numbered barcodes to be produced. As a rule, only a single copy is to be produced for each number, which is only a purely functional task Has .
Der vorliegenden Erfindung lag daher die Aufgabe zugrunde, statt des bisher herkömmlichen Wegs über eine reprofähige Vorlage sowie einen Reprofilm und eine Druck¬ form eine wesentlich wirtschaftlichere und schneller zum Ergebnis führende Methode zu entwickeln, insbesondere für unter sich ungleiche Transfer-Dekors wie fortlaufend nu¬ merierte Strichcodes.The present invention was therefore based on the object, instead of the previously conventional way of using a reprofile template and a reprofilm and a printing form, to develop a much more economical and quicker method leading to the result, in particular for unequal transfer decorations such as continuously barcodes.
Zur Lösung dieser Aufgabe dient das Verfahren gemäss Patentanspruch 1. In bevorzugter Weise wird dabei mittels eines EDV-Programms das gewünschte Transfer-Dekor wie beispielsweise ein fortlaufend numerierter Strichcode als Software hergestellt und dieses Programm zur Steue¬ rung der Druckeinrichtung verwendet, wobei diese das Transfer-Dekor direkt auf die wasserlösliche Trennschicht eines Spezi al papiers für den Keramikdruck aufbringt. Als Spezialpapier oder Abziehbilder-Papier wird vorzugsweise ein Material verwendet, das auf dieses Verfahren und insbesondere auf die Hitze während der Fixierung der Druckfarbe in der Einbrennstation der Druckeinrichtung abgestimmt ist. Als Druckeinrichtung können xerografische Laserdrucker sowie Ionen-Deposit-Drucker und magnetogra¬ fische Drucker sowie ferner Thermo-Transfer-Drucker und ähnliche computergesteuerte Geräte verwendet werden. Dabei muss der bei dem jeweiligen Drucker für den übli¬ chen Bürogebrauch verwendete Toner, d.h. die meistens pulverförmige Farbe, ersetzt oder durch Toner ergänzt werden, welcher die auf die zur Anwendung kommende Hitzeeinwirkung abgestimmten, hochtemperaturtaugl ichen Farbpigmente enthält. Diese können dem Toner entweder einfach beigegeben werden oder die Beimischung erfolgt in Form von harzummantelten Pigmenten. Bei einem Thermo- Transfer-Drucker betreffen diese Massnahmen die Farbe des Farbbandes, bei dessen Einfärben die Spezi alpi gmente mit- zuverarbeiten sind. Die direkt auf dem Spezialpapier hergestellten Drucke werden anschl i essend mittels eines Uberdruck-Lak- kes "überfilmt". Dabei wird ein Überdruck-Lack verwendet, der für die jeweilige Druckmethode geeignet ist, insbe¬ sondere auf die Auswirkungen der Druckmethode wie die Veränderung der wasserlöslichen Trennschicht des Abzieh¬ bild-Papiers durch Hitzeeinwirkung beim Durchlaufen der Fixierstation im Drucker abgestimmt ist.The method according to claim 1 serves to achieve this object. In a preferred manner, the desired transfer decor, such as, for example, a consecutively numbered bar code, is produced as software by means of an EDP program, and this program is used to control the printing device, which transfers -Decor applied directly to the water-soluble separating layer of a special paper for ceramic printing. As special paper or decal paper, a material is preferably used which is matched to this method and in particular to the heat during the fixing of the printing ink in the stoving station of the printing device. As a printing device, xerographic laser printers as well as ion deposit printers and magnetographic printers as well as thermal transfer printers and similar computer-controlled devices can be used. In this case, the toner used in the respective printer for the usual office use, ie the mostly powdery color, must be replaced or supplemented with toner which contains the color pigments suitable for high temperatures and adapted to the heat effect used. These can either simply be added to the toner or added in the form of resin-coated pigments. In the case of a thermal transfer printer, these measures relate to the color of the ink ribbon, in the coloring of which the special alpi gmente have to be processed. The prints made directly on the special paper are then "over-filmed" using an overprint varnish. An overprint varnish is used which is suitable for the respective printing method, in particular for the effects of the printing method, such as the change in the water-soluble separating layer of the decal paper due to the action of heat when passing through the fixing station in the printer.
Beim Aufbringen des Überdruck-Lackes kann ferner ein sogenanntes Rastermuster verwendet werden, mit dem erreicht wird, dass beim Aufbringen und beim Einbrennen des Abziehbildes etwa vorhandene Luft- und Wassereinschlüsse durch kleine Löcher in der Lackschicht entweichen können, damit das hergestellte Transfer-Dekor nicht durch explosionsartige Ausdehnung solcher Einschlüsse unter Hitzeeinwirkung zerstört wird. When applying the overprint varnish, a so-called grid pattern can also be used, with the result that any air and water inclusions that are present can escape through small holes in the varnish layer when the decal is applied and when the decal is baked, so that the transfer decor produced does not get through explosive expansion of such inclusions is destroyed under the influence of heat.

Claims

P a t e n t a n s p r ü c h e Patent claims
1. Verfahren zum Aufbringen von bildlichen Dar¬ stellungen wie z.B. Transfer-Dekors oder Strichcodes im Transferverfahren auf Gegenstände, welche anschl i essend einem Verarbeitungsprozess in einem höheren Temperaturbe¬ reich unterzogen werden, dadurch gekennzeichnet, dass die zu übertragende bildliche Darstellung mittels einer elek¬ tronisch steuerbaren und gegebenenfalls programmierbaren Druckeinrichtung erstellt und von der Druckeinrichtung direkt auf einen Papierträger aufgebracht und dann im Abzieh-Verfahren auf den Gegenstand übertragen wird, wobei der Papierträger und die Druckfarbe so ausgewählt werden, dass sie im jeweils vorgesehenen Temperaturbe¬ reich während des anschl iessenden Verarbeitungsprozesses hitzebeständig sind.1.Method for applying visual representations such as e.g. Transfer decorations or bar codes in the transfer process to objects which are subsequently subjected to a processing process in a higher temperature range, characterized in that the pictorial representation to be transmitted is created by means of an electronically controllable and optionally programmable printing device and directly by the printing device applied to a paper carrier and then transferred to the object in the peeling process, the paper carrier and the printing ink being selected such that they are heat-resistant in the temperature range provided in each case during the subsequent processing process.
2. Verfahren nach Anspruch 1, dadurch gekenn¬ zeichnet, dass als Papierträger Abziehbilder-Papier mit Widerstandsf higkeit gegenüber der Hitze während der Fixierung der Druckfarbe in der Einbrennstation der Druckeinrichtung verwendet wird.2. The method according to claim 1, characterized in that decal paper with resistance to heat is used as the paper carrier during the fixing of the printing ink in the stoving station of the printing device.
3. Verfahren nach Anspruch 1, dadurch gekenn¬ zeichnet, dass als Druckeinrichtung xerografi sehe Laser¬ drucker, Ionen-Deposit-Drucker, magnetografische Drucker oder Thermotransfer-Drucker verwendet werden.3. The method according to claim 1, characterized gekenn¬ characterized in that the printer xerografi see laser printer, ion deposit printer, magnetographic printer or thermal transfer printer are used.
4. Verfahren nach Anspruch 1, dadurch gekenn¬ zeichnet, dass die bildliche Darstellung mittels eines EDV-Programms erstellt und dieses Programm zur Steuerung der Druckeinrichtung verwendet wird, der die bildliche4. The method according to claim 1, characterized gekenn¬ characterized in that the visual representation created by means of an EDP program and this program is used to control the printing device, which is the pictorial
Darstellung direkt auf den Papierträger aufbringt. Application directly onto the paper carrier.
PCT/CH1990/000255 1989-11-24 1990-11-01 Process for applying pictorial designs to the surfaces of articles WO1991008117A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH4231/89-8 1989-11-24
CH423189 1989-11-24

Publications (1)

Publication Number Publication Date
WO1991008117A1 true WO1991008117A1 (en) 1991-06-13

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WO (1) WO1991008117A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0746461A1 (en) * 1994-02-10 1996-12-11 Sawgrass Systems, Inc. A printing method of applying a polymer surface preparation to a substrate
ES2156658A1 (en) * 1997-11-27 2001-07-01 Jurado Jose Luis Pujol Ruling system for flat surfaces designed for writing and drawing
WO2015178965A1 (en) * 2014-05-19 2015-11-26 Avery Dennison Retail Information Services Llc Composite image heat transfer with scannable mark

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FR2318741A1 (en) * 1975-07-25 1977-02-18 Sublistatic Holding Sa TRANSFER PRINTING MEDIA AND THEIR MANUFACTURING METHODS
DE3422286A1 (en) * 1984-06-15 1985-12-19 Wilhelm Hammann GmbH & Co KG, 4000 Düsseldorf Process for printing materials by means of transfer-printing paper
JPS6127278A (en) * 1984-07-17 1986-02-06 Inter Technical Indasutorii Kk Transfer method using computer graphics
JPS61211076A (en) * 1985-03-15 1986-09-19 Kyodo Printing Co Ltd Production of transfer paper
EP0202902A1 (en) * 1985-05-23 1986-11-26 Royal Doulton (UK) Limited Marking of articles
GB2189436A (en) * 1986-04-25 1987-10-28 Oliveira Amanda Uchoa D Printed transfer sheet for fabric decorating
US4758952A (en) * 1986-11-24 1988-07-19 P & S Industries, Inc. Process for heat transfer printing
DE3733205A1 (en) * 1987-10-01 1989-04-13 Guenther Stahl Marking film
US4870427A (en) * 1986-11-19 1989-09-26 Brother Kogyo Kabushiki Kaisha Method of preparing dry transfer sheets by printing via ink ribbon
WO1990000473A1 (en) * 1988-07-06 1990-01-25 Hare Donald S Transferring a creative design to a fabric

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2318741A1 (en) * 1975-07-25 1977-02-18 Sublistatic Holding Sa TRANSFER PRINTING MEDIA AND THEIR MANUFACTURING METHODS
DE3422286A1 (en) * 1984-06-15 1985-12-19 Wilhelm Hammann GmbH & Co KG, 4000 Düsseldorf Process for printing materials by means of transfer-printing paper
JPS6127278A (en) * 1984-07-17 1986-02-06 Inter Technical Indasutorii Kk Transfer method using computer graphics
JPS61211076A (en) * 1985-03-15 1986-09-19 Kyodo Printing Co Ltd Production of transfer paper
EP0202902A1 (en) * 1985-05-23 1986-11-26 Royal Doulton (UK) Limited Marking of articles
GB2189436A (en) * 1986-04-25 1987-10-28 Oliveira Amanda Uchoa D Printed transfer sheet for fabric decorating
US4870427A (en) * 1986-11-19 1989-09-26 Brother Kogyo Kabushiki Kaisha Method of preparing dry transfer sheets by printing via ink ribbon
US4758952A (en) * 1986-11-24 1988-07-19 P & S Industries, Inc. Process for heat transfer printing
DE3733205A1 (en) * 1987-10-01 1989-04-13 Guenther Stahl Marking film
WO1990000473A1 (en) * 1988-07-06 1990-01-25 Hare Donald S Transferring a creative design to a fabric

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PATENT ABSTRACTS OF JAPAN vol. 10, no. 176 (M-491)(2232) 20 Juni 1986, & JP-A-61 27278 (INTER TECHNICAL INDASUTORII K.K.) 06 Februar 1986, siehe das ganze Dokument *
PATENT ABSTRACTS OF JAPAN vol. 11, no. 48 (M-561)(2495) 10 September 1986, & JP-A-61 211076 (KYODO PRINTING CO. LTTD.) 13 Februar 1987, siehe das ganze Dokument *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0746461A1 (en) * 1994-02-10 1996-12-11 Sawgrass Systems, Inc. A printing method of applying a polymer surface preparation to a substrate
EP0746461A4 (en) * 1994-02-10 1997-01-29 Sawgrass Systems Inc A printing method of applying a polymer surface preparation to a substrate
ES2156658A1 (en) * 1997-11-27 2001-07-01 Jurado Jose Luis Pujol Ruling system for flat surfaces designed for writing and drawing
WO2015178965A1 (en) * 2014-05-19 2015-11-26 Avery Dennison Retail Information Services Llc Composite image heat transfer with scannable mark
CN106457859A (en) * 2014-05-19 2017-02-22 艾利丹尼森零售信息服务公司 Composite image heat transfer with scannable mark
US10399317B2 (en) 2014-05-19 2019-09-03 Avery Dennison Retail Information Services, Llc Composite image heat transfer with scannable mark
EP3666539A1 (en) * 2014-05-19 2020-06-17 Avery Dennison Retail Information Services, LLC Composite image heat transfer with scannable mark
US11298929B2 (en) 2014-05-19 2022-04-12 Avery Dennison Retail Information Services Llc Composite image heat transfer with scannable mark
US11931994B2 (en) 2014-05-19 2024-03-19 Avery Dennison Retail Information Services Llc Composite image heat transfer with scannable mark

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Publication number Publication date
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