WO1991006499A1 - Improved roller - Google Patents

Improved roller Download PDF

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Publication number
WO1991006499A1
WO1991006499A1 PCT/GB1990/001700 GB9001700W WO9106499A1 WO 1991006499 A1 WO1991006499 A1 WO 1991006499A1 GB 9001700 W GB9001700 W GB 9001700W WO 9106499 A1 WO9106499 A1 WO 9106499A1
Authority
WO
WIPO (PCT)
Prior art keywords
sleeve
core
forming
bore
fibre
Prior art date
Application number
PCT/GB1990/001700
Other languages
French (fr)
Inventor
James Harold Charles Rowan
Beverly Dawn Groome
Simon Charles Martin
Keith Ward
Original Assignee
Courtaulds Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Courtaulds Plc filed Critical Courtaulds Plc
Publication of WO1991006499A1 publication Critical patent/WO1991006499A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C13/00Rolls, drums, discs, or the like; Bearings or mountings therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C37/00Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape
    • B21C37/06Manufacture of metal sheets, bars, wire, tubes or like semi-manufactured products, not otherwise provided for; Manufacture of tubes of special shape of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
    • B21C37/15Making tubes of special shape; Making tube fittings
    • B21C37/154Making multi-wall tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P11/00Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for 
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P11/00Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for 
    • B23P11/005Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for  by expanding or crimping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P11/00Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for 
    • B23P11/02Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for  by first expanding and then shrinking or vice versa, e.g. by using pressure fluids; by making force fits
    • B23P11/025Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for  by first expanding and then shrinking or vice versa, e.g. by using pressure fluids; by making force fits by using heat or cold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/56Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
    • B29C65/565Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits involving interference fits, e.g. force-fits or press-fits
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1222Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1224Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a butt joint-segment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/13Single flanged joints; Fin-type joints; Single hem joints; Edge joints; Interpenetrating fingered joints; Other specific particular designs of joint cross-sections not provided for in groups B29C66/11 - B29C66/12
    • B29C66/131Single flanged joints, i.e. one of the parts to be joined being rigid and flanged in the joint area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/432Joining a relatively small portion of the surface of said articles for making tubular articles or closed loops, e.g. by joining several sheets ; for making hollow articles or hollow preforms
    • B29C66/4322Joining a relatively small portion of the surface of said articles for making tubular articles or closed loops, e.g. by joining several sheets ; for making hollow articles or hollow preforms by joining a single sheet to itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/433Casing-in, i.e. enclosing an element between two sheets by an outlined seam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/534Joining single elements to open ends of tubular or hollow articles or to the ends of bars
    • B29C66/5344Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially annular, i.e. of finite length, e.g. joining flanges to tube ends
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/534Joining single elements to open ends of tubular or hollow articles or to the ends of bars
    • B29C66/5346Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/61Joining from or joining on the inside
    • B29C66/612Making circumferential joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/721Fibre-reinforced materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/834General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools moving with the parts to be joined
    • B29C66/8341Roller, cylinder or drum types; Band or belt types; Ball types
    • B29C66/83411Roller, cylinder or drum types
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/0032Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions
    • B29D99/0035Producing rolling bodies, e.g. rollers, wheels, pulleys or pinions rollers or cylinders having an axial length of several times the diameter, e.g. for embossing, pressing, or printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65HHANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
    • B65H27/00Special constructions, e.g. surface features, of feed or guide rollers for webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/112Single lapped joints
    • B29C66/1122Single lap to lap joints, i.e. overlap joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/721Fibre-reinforced materials
    • B29C66/7212Fibre-reinforced materials characterised by the composition of the fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/32Wheels, pinions, pulleys, castors or rollers, Rims
    • B29L2031/324Rollers or cylinders having an axial length of several times the diameter, e.g. embossing, pressing or printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/32Wheels, pinions, pulleys, castors or rollers, Rims
    • B29L2031/324Rollers or cylinders having an axial length of several times the diameter, e.g. embossing, pressing or printing
    • B29L2031/326Rollers or cylinders having an axial length of several times the diameter, e.g. embossing, pressing or printing made wholly of plastics

Definitions

  • This invention relates to a lightweight roller (cap ⁇ able of conveying thin sheet material in a high speed processing plant) and to a method of making such a roller.
  • FRP fibre reinforced plastic
  • CFRP carbon FRP
  • the surface properties of FRP are not usually suitable for contact with thin sheet materials being processed, because of, for example, its micro-finish, abrasion resistance and cleanliness. It is thus normally necessary to provide a coating of a metal or other surface material on the outside of the FRP roller.
  • the present invention concerns the manufacture of such a coated roller, and in particular, the method of providing the metal or other coating on the outside of the FRP roller.
  • Previously described processes to provide a metal coating have mainly involved the gradual deposition of one or more metal layers by, for example, -metal spraying, electroless plating or electrolytic plating. These proces ⁇ ses all depend critically on adhesion at the FRP/ etal interface. This adhesion is dependent on many variables, such as fibre type, matrix resin type, fibre distribution at the surface, surface roughness etc. and on less con- trollable factors such as contamination. Many solutions have been proposed to this problem of coating adhesion.
  • a roller for use in a given operating temperature range comprises a core made of a fibre-reinforced plastics material having an outer surface and a sleeve of a different material having an inner surface engaging the outer surface of the core in such a manner as to place the sleeve material in hoop tension in the vicinity of said inner surface and leave the core non-rotatable with respect to the sleeve within said operating temperature range.
  • the core is a hollow tube of FRP and the sleeve is a hollow tube of metal.
  • the core can include end plates (e.g. in the form of metallic discs) which preferably are also contained within the sleeve.
  • the core can be moulded (e.g. on a supporting mandrel) extruded, pultruded or machined from a solid piece of suitable non-metallic material and may or may not include filament reinforcement.
  • a preferred core would be formed from matrix impregnated filaments applied around a support- ing mandrel.
  • the matrix could be a thermosettable or thei— moplastic material and the filaments could be mineral fibres (e.g. glass), textile fibres (e.g. polyester or polyamide) or a specialist reinforcing fibre known in FRP techniques (e.g. aramid or carbon).
  • a method of making a composite roller which comprises a cylindrical core of a fibre-reinforced plastics material and an outer tubular sleeve of a second material, charac- terised in that the method comprises the step of forming an interference fit between the core and the sleeve which leaves the sleeve in hoop tension thereby to retain the core non-rotatable in the bore of the sleeve.
  • the hoop tensioning of the sleeve is caused by forming an interference fit between the core and the sleeve.
  • One way of doing this is to force the core mechanically into the bore of a sleeve which has a smaller diameter bore than the diameter of the core, but preferably is occasioned by shrink fitting the component parts of the roller together using a temperature difference caused by heating the sleeve and/or cooling the core.
  • An alternative to heat shrinking the sleeve on to the core is to mechanically squeeze the sleeve on to the core, such as for example, by using a swaging technique.
  • the method according to this invention permits a metal coating to be tensioned around an FRP core without en ⁇ countering the major problem of FRP/metal adhesion by securing a preformed metal sleeve over an FRP tube by means of the hoop tension generated in the sleeve causing an interference fit.
  • the metal may be, for example, Al or Cu, but other metals may be used.
  • the outer surface of the sleeve may then be polished, etched, electroplated, ano- dised, electroless-plated, or sprayed with other metals or materials, to provide the final surface properties required for the roller.
  • the interference fit coating principle embodied in this invention may also be applied to other coating materials including, but not limited to, polymers and composite materials, for example.
  • a particular example of providing a coating held by hoop tension in an interference fit on a core would be to shrink-fit a metal tube over the tubular FRP core.
  • Figure 1 shows the creation of a precursor of an FRP core for a roller in accordance with the invention.
  • Figure 2 diagrammatically illustrates how a metal sleeve is prepared for engagement with an FRP core
  • Figure 3 is a partially sectioned view of the com ⁇ pleted roller
  • Figure 4 is a view of a swaged composite roller according to the invention.
  • Figure 3 shows a completed roller in accordance with the invention which is made up of four parts, an FRP core tube 1, a metal sleeve 2 and two end fittings 3 (only one of which is shown).
  • the core tube 1 can be formed as shown in Figure 1.
  • a tow 4 of fibres is impregnated with a hardenable liquid matrix material at a station 5 and is wrapped on a mandrel 6 in a series of plies some of which are angle plies 7 and others are hoop plies S.
  • a drive unit 9 and tailstock unit 10 support the mandrel while it is rotated by a driven chuck 11 of the unit 9.
  • the matrix After winding the fibres on the mandrel to the re ⁇ quired thickness, the matrix is hardened to form a rigid tubular core having a precisely sized mandrel-defined internal bore 12 (see Figure 3). After matrix hardening the FRP core tube is removed from the mandrel 6.
  • tows of carbon fibre having a tensile modulus of 230 GPa were impregnated with thermosetting resin, for example a low viscosity liquid epoxy resin, and were filament wound at an angle of 30° to its axis, onto a 100 mm diameter steel mandrel 6 treated with a release agent.
  • thermosetting resin for example a low viscosity liquid epoxy resin
  • other wind ⁇ ings were incorporated almost at right angles to the axis.
  • the resin was cured by rotating the mandrel and CFRP in an oven at 150°C for 4 hours.
  • the CFRP tube which had a carbon fibre content of some 60% by volume, was then removed from the mandrel .
  • a section having the required roller length (e.g. of 400 mm) is cut from the tube.
  • the inner surface of a filament wound tube being a direct moulding of the mandrel 5, is dimensional ly accurate and the end fittings 3 (e.g. aluminium alloy end plugs) are bonded into each end of the tube.
  • the outer surface of the CFRP core is then ground to give the required wall thickness (e.g. of 4 mm).
  • a sleeve tube 2 (e.g. of aluminium) was bored out so that its internal diameter was slightly less (e.g. 0.05 mm less) than the outside diameter of the CFRP core tube at room temperature. This determined the level of hoop tension which would secure the sleeve 2 around the core tube 1.
  • the sleeve 2 was next heated to 100°C at which temper ⁇ ature a radial clearance of about 0.06 mm existed between the inner surface of the sleeve 2 and the outer surface of the core 1, enabling the sleeve 2 to be slipped over the CFRP core 1.
  • Figure 2 shows the CFRP core 1 and sleeve tube 2 before the shrink-fitting procedure had been ef ⁇ fected. The assembly of core 1 and sleeve 2 was allowed to cool to room temperature.
  • the outer surface of the sleeve 2 can now be machined to the required diameter and surface finish.
  • the final wall thickness of the sleeve 2 was 0.5 mm.
  • the outer surface of the sleeve 2 can -be treated in a variety of different ways and in the case of an aluminium sleeve, anodising can be desirable.
  • the roller illustrated could use other reinforcing fibres such as aramid or glass, for example.
  • thermosetting resins such as phenolic, bismaleimide etc.
  • Thermoplastic matrix materials such as polyethei— imide and polyetheretherketone may also be used.
  • CFRP rollers such as fabric wrapping, prepreg moulding and filament winding.
  • the present invention is applicable to rollers made by these and other processes.
  • filament winding e.g. as shown in Figure 1 is the preferred method.
  • the filament winding can be performed as an automated process, laying resin-impregnated continuous fibres onto the rotating mandrel 6 at precise angles to its axis, and in patterns which eventually form complete layers of fibre.
  • Sheet handling rollers in process machinery may be required to rotate very rapidly, and balance is therefore an important characteristic. Accurate machining is there ⁇ fore required in producing such rollers.
  • the hoop tensioning of the sleeve on the core can be generated in ways other than thermal shrink fitting.
  • an ovei—sized sleeve can be swaged down on-oo a cylindrical core using a rotary hammer- (or ball-) swager.
  • Such a swaging operation is illustrated scnematical ly in Figure 3 by the arrows 13 and in further detail with reference to Figure 4.
  • a sleeve tube 22 e.g. of aluminium was bored out so that its internal diameter was slightly more (e.g. 0.05 mm more) than the outside diameter of an FRP core tube 21 at room temperature.
  • the core 21 is a sliding fit in the bore of sleeve 22.
  • the sleeve 22 is mechanically worked down onto the core 21.
  • One way of doing this is to use a rotating hammer swage 23, which is well known per se.
  • Such a hammer swage comprises a die which is split into two or more segments.,, which cooperate to define a circular opening of the same diameter as the finished size of the outer diameter of the sleeve 22.
  • the segments are assembled around the circumference of the sleeve 22 and hammered radially inwards whilst effecting relative rotation and longitudinal movement between the segments and the sleeve 22.
  • the hammer blows contract the sleeve 22 down onto the core 21 to form an interference fit which places the core 21 in compression and the sleeve 22 in hoop tension.
  • An alternative swaging process is to use a rotary-ball swage, known per se, which comprises a ball race in which hardened balls are rotated relative to the sleeve 22 and S moved along the length of the tube so as to work the metal on a helical line and deform the metal radially inwards to reduce the diameter of the sleeve 22 and form an intei— ference fit which places the core 21 in compression and the sleeve 22 in hoop tension.
  • ball swage There are two versions of ball swage that can be used. In one version the balls are equispaced around a fixed common pitch circle diameter to work the sleeve 22 to a preset diameter.
  • the balls run on the inside of a hardened conical bore which is movable axially to adjust the -radial position of the balls relative to the sleeve 22.
  • This second version enables one to reduce the outer diameter of the sleeve 22 in a number of passes if one wishes.
  • the outer surface of the swaged sleeve 22 can be machined or ground to the required diameter and electro ⁇ plated as described above.
  • FRP end fittings can be used in place of the metal ones described and can be provided with stub shafts rather than bores to receive a shaft.
  • Rollers in accordance with this invention have pai— ticular utility for the processing of very thin plastics film (e.g. polyester film) and could be made to lengths up to a few metres long.
  • plastics film e.g. polyester film

Abstract

A roller (e.g. for use in high speed sheet processing) comprises an FRP core (1) and a metal sleeve (2) non-rotatably held on the core by an interference fit caused by hoop tension in the sleeve.

Description

IMPROVED ROLLER
This invention relates to a lightweight roller (cap¬ able of conveying thin sheet material in a high speed processing plant) and to a method of making such a roller.
In certain processes it is necessary to convey sheet material on and/or between smooth-faced circular cylindri¬ cal rollers and metallic rollers (e.g. hollow metallic rollers) are a common choice. However in h-igh speed sheet processing it is desirable for the moment of inertia of all components which move with the sheet to be maintained at a minimum value and to this end it is known to replace a substantial proportion of the mass of a hollow metal roller by a lower density core material. Where a metallic surface is required in contact with the sheet material a composite roller must be constructed and the problem then has to be faced of securely retaining an outer layer of metallic material on an inner core of non-metallic material. The present invention addresses this problem.
Various methods have been described for producing fibre reinforced plastic (FRP) rollers, especially carbon FRP (CFRP) rollers, to replace conventional metal rollers. The advantages offered include:
(i) reduction in mass because of the high specific stiff¬ ness of FRP compared with metals; this allows higher acceleration and deceleration of sheet material during processing; also handling of lightweight rollers is easier, and
(ii) improved dimensional stability because of the small coefficient of thermal expansion of FRP.
However, the surface properties of FRP are not usually suitable for contact with thin sheet materials being processed, because of, for example, its micro-finish, abrasion resistance and cleanliness. It is thus normally necessary to provide a coating of a metal or other surface material on the outside of the FRP roller. The present invention concerns the manufacture of such a coated roller, and in particular, the method of providing the metal or other coating on the outside of the FRP roller.
Previously described processes to provide a metal coating have mainly involved the gradual deposition of one or more metal layers by, for example, -metal spraying, electroless plating or electrolytic plating. These proces¬ ses all depend critically on adhesion at the FRP/ etal interface. This adhesion is dependent on many variables, such as fibre type, matrix resin type, fibre distribution at the surface, surface roughness etc. and on less con- trollable factors such as contamination. Many solutions have been proposed to this problem of coating adhesion.
According to one aspect of this invention a roller for use in a given operating temperature range comprises a core made of a fibre-reinforced plastics material having an outer surface and a sleeve of a different material having an inner surface engaging the outer surface of the core in such a manner as to place the sleeve material in hoop tension in the vicinity of said inner surface and leave the core non-rotatable with respect to the sleeve within said operating temperature range.
Suitably the core is a hollow tube of FRP and the sleeve is a hollow tube of metal. The core can include end plates (e.g. in the form of metallic discs) which preferably are also contained within the sleeve.
The core can be moulded (e.g. on a supporting mandrel) extruded, pultruded or machined from a solid piece of suitable non-metallic material and may or may not include filament reinforcement. A preferred core would be formed from matrix impregnated filaments applied around a support- ing mandrel. The matrix could be a thermosettable or thei— moplastic material and the filaments could be mineral fibres (e.g. glass), textile fibres (e.g. polyester or polyamide) or a specialist reinforcing fibre known in FRP techniques (e.g. aramid or carbon).
According to a further aspect of the invention a method of making a composite roller which comprises a cylindrical core of a fibre-reinforced plastics material and an outer tubular sleeve of a second material, charac- terised in that the method comprises the step of forming an interference fit between the core and the sleeve which leaves the sleeve in hoop tension thereby to retain the core non-rotatable in the bore of the sleeve.
The hoop tensioning of the sleeve is caused by forming an interference fit between the core and the sleeve. One way of doing this is to force the core mechanically into the bore of a sleeve which has a smaller diameter bore than the diameter of the core, but preferably is occasioned by shrink fitting the component parts of the roller together using a temperature difference caused by heating the sleeve and/or cooling the core. An alternative to heat shrinking the sleeve on to the core is to mechanically squeeze the sleeve on to the core, such as for example, by using a swaging technique.
The method according to this invention permits a metal coating to be tensioned around an FRP core without en¬ countering the major problem of FRP/metal adhesion by securing a preformed metal sleeve over an FRP tube by means of the hoop tension generated in the sleeve causing an interference fit. The metal may be, for example, Al or Cu, but other metals may be used. The outer surface of the sleeve may then be polished, etched, electroplated, ano- dised, electroless-plated, or sprayed with other metals or materials, to provide the final surface properties required for the roller. The interference fit coating principle embodied in this invention may also be applied to other coating materials including, but not limited to, polymers and composite materials, for example.
A particular example of providing a coating held by hoop tension in an interference fit on a core would be to shrink-fit a metal tube over the tubular FRP core.
The invention will now be further described, by way of example, with reference to the accompanying drawings, in which:
Figure 1 shows the creation of a precursor of an FRP core for a roller in accordance with the invention.
Figure 2 diagrammatically illustrates how a metal sleeve is prepared for engagement with an FRP core,
Figure 3 is a partially sectioned view of the com¬ pleted roller, and
Figure 4 is a view of a swaged composite roller according to the invention.
Figure 3 shows a completed roller in accordance with the invention which is made up of four parts, an FRP core tube 1, a metal sleeve 2 and two end fittings 3 (only one of which is shown).
The core tube 1 can be formed as shown in Figure 1. A tow 4 of fibres is impregnated with a hardenable liquid matrix material at a station 5 and is wrapped on a mandrel 6 in a series of plies some of which are angle plies 7 and others are hoop plies S. A drive unit 9 and tailstock unit 10 support the mandrel while it is rotated by a driven chuck 11 of the unit 9. After winding the fibres on the mandrel to the re¬ quired thickness, the matrix is hardened to form a rigid tubular core having a precisely sized mandrel-defined internal bore 12 (see Figure 3). After matrix hardening the FRP core tube is removed from the mandrel 6.
In a typical example of CFRP roller manufacture, tows of carbon fibre having a tensile modulus of 230 GPa were impregnated with thermosetting resin, for example a low viscosity liquid epoxy resin, and were filament wound at an angle of 30° to its axis, onto a 100 mm diameter steel mandrel 6 treated with a release agent. To provide a CFRP tube with a calculated balance of properties, other wind¬ ings were incorporated almost at right angles to the axis. When the required wall thickness of 5 mm had been reached, the resin was cured by rotating the mandrel and CFRP in an oven at 150°C for 4 hours. The CFRP tube, which had a carbon fibre content of some 60% by volume, was then removed from the mandrel .
A section having the required roller length (e.g. of 400 mm) is cut from the tube. The inner surface of a filament wound tube, being a direct moulding of the mandrel 5, is dimensional ly accurate and the end fittings 3 (e.g. aluminium alloy end plugs) are bonded into each end of the tube. The outer surface of the CFRP core is then ground to give the required wall thickness (e.g. of 4 mm).
A sleeve tube 2 (e.g. of aluminium) was bored out so that its internal diameter was slightly less (e.g. 0.05 mm less) than the outside diameter of the CFRP core tube at room temperature. This determined the level of hoop tension which would secure the sleeve 2 around the core tube 1.
The sleeve 2 was next heated to 100°C at which temper¬ ature a radial clearance of about 0.06 mm existed between the inner surface of the sleeve 2 and the outer surface of the core 1, enabling the sleeve 2 to be slipped over the CFRP core 1. Figure 2 shows the CFRP core 1 and sleeve tube 2 before the shrink-fitting procedure had been ef¬ fected. The assembly of core 1 and sleeve 2 was allowed to cool to room temperature.
The outer surface of the sleeve 2 can now be machined to the required diameter and surface finish. In one example, the final wall thickness of the sleeve 2 was 0.5 mm. The outer surface of the sleeve 2 can -be treated in a variety of different ways and in the case of an aluminium sleeve, anodising can be desirable.
Although carbon fibre would usually be used for the tow 4 (because it can conveniently provide the stiffness of metal with much reduced weight) the roller illustrated could use other reinforcing fibres such as aramid or glass, for example.
Similarly, whilst epoxy resins are widely used as the matrix in CFRP roller manufacture, other thermosetting resins such as phenolic, bismaleimide etc. can be used in the station 5, depending on the material properties re¬ quired. Thermoplastic matrix materials such as polyethei— imide and polyetheretherketone may also be used.
Several processes exist for producing CFRP rollers, such as fabric wrapping, prepreg moulding and filament winding. The present invention is applicable to rollers made by these and other processes. In particular, where high specific stiffness combined with high productivity is required, filament winding (e.g. as shown in Figure 1) is the preferred method.
The filament winding can be performed as an automated process, laying resin-impregnated continuous fibres onto the rotating mandrel 6 at precise angles to its axis, and in patterns which eventually form complete layers of fibre. Sheet handling rollers in process machinery may be required to rotate very rapidly, and balance is therefore an important characteristic. Accurate machining is there¬ fore required in producing such rollers.
The hoop tensioning of the sleeve on the core can be generated in ways other than thermal shrink fitting. Thus, for example an ovei—sized sleeve can be swaged down on-oo a cylindrical core using a rotary hammer- (or ball-) swager. Such a swaging operation is illustrated scnematical ly in Figure 3 by the arrows 13 and in further detail with reference to Figure 4.
In the embodiment of the invention shown in Figure 4 a sleeve tube 22 e.g. of aluminium was bored out so that its internal diameter was slightly more (e.g. 0.05 mm more) than the outside diameter of an FRP core tube 21 at room temperature. In this state the core 21 is a sliding fit in the bore of sleeve 22. To achieve an interference fit between the core 21 and the sleeve 22, the sleeve 22 is mechanically worked down onto the core 21. One way of doing this is to use a rotating hammer swage 23, which is well known per se. Such a hammer swage comprises a die which is split into two or more segments.,, which cooperate to define a circular opening of the same diameter as the finished size of the outer diameter of the sleeve 22. The segments are assembled around the circumference of the sleeve 22 and hammered radially inwards whilst effecting relative rotation and longitudinal movement between the segments and the sleeve 22. The hammer blows contract the sleeve 22 down onto the core 21 to form an interference fit which places the core 21 in compression and the sleeve 22 in hoop tension.
An alternative swaging process is to use a rotary-ball swage, known per se, which comprises a ball race in which hardened balls are rotated relative to the sleeve 22 and S moved along the length of the tube so as to work the metal on a helical line and deform the metal radially inwards to reduce the diameter of the sleeve 22 and form an intei— ference fit which places the core 21 in compression and the sleeve 22 in hoop tension. There are two versions of ball swage that can be used. In one version the balls are equispaced around a fixed common pitch circle diameter to work the sleeve 22 to a preset diameter. In the second version the balls run on the inside of a hardened conical bore which is movable axially to adjust the -radial position of the balls relative to the sleeve 22. This second version enables one to reduce the outer diameter of the sleeve 22 in a number of passes if one wishes.
The outer surface of the swaged sleeve 22 can be machined or ground to the required diameter and electro¬ plated as described above.
The hoop tensioning processes described in general, and the shrink-fitting example particularised above, yield a precision lightweight roller comprising a non-metallic core with a surface coating of metal attached by means of hoop tensioning which has the following advantages when compared with previously described processes for production of such rollers:
a) formation of the coating is not dependent on adhesion to the core surface, which is difficult to achieve in the case of FRP cores;
b) the number of manufacturing variables to be controlled can be reduced;
c) the porosity which is always obtained with sprayed coatings (and sometimes with plated coatings) is avoided; and
d) small defects in the outer surface of the core, such as voids, do not affect the outer surface of the roller.
FRP end fittings can be used in place of the metal ones described and can be provided with stub shafts rather than bores to receive a shaft.
Rollers in accordance with this invention have pai— ticular utility for the processing of very thin plastics film (e.g. polyester film) and could be made to lengths up to a few metres long.

Claims

1. A roller for use in a given operating temperature range comprising a core made of a fibre-reinforced plastics material having an outer surface, and a sleeve of a dif- ferent material having an inner surface engaging the outer surface of the core, characterised in that the engagement is arranged in such a manner as to place the sleeve mater¬ ial in hoop tension in the vicinity of said inner surface and leave the core non-rotatable with respect to the sleeve within said operating temperature range.
2. A roller according to claim 1, characterised in that the sleeve is of metal.
3. A roller according to claim 1, characterised in that the sleeve is a polymeric material.
4. A roller according to claim 1, characterised in that the core is reinforced with a fibre selected from the group consisting of glass fibre, polyester fibre, polyamide fibre, aramid fibre and carbon fibre.
5. A roller according to claim 4, characterised in that the sleeve is of metal and has an outer surface treated, to provide the final surface properties required, by a process selected from the group consisting of polish¬ ing, etching, electroplating, anodising, electroless- plating and spraying with other materials.
6. A method of making a composite roller which comprises a cylindrical core of a fibre-reinforced plastics material and an outer tubular sleeve of a second material, characterised in that the method comprises the step of forming an interference fit between the core and the sleeve which leaves the sleeve in hoop tension thereby to retain the core non-rotatable in the bore of the sleeve.
7. The method according to claim 6, characterised in that the step of forming the interference fit comprises the steps of forming the core with a predetermined outer diameter, forming the sleeve with a bore having a diameter which is slightly smaller than the outer diameter of the core, and mechanically forcing the core axially into the bore.
8. The method according to claim 6, characterised in that the step of forming the interference fit comprises the steps of forming the core with a predetermined outer diameter, forming the sleeve with a bore having a diameter which is slightly smaller than the outer diameter of the core, subjecting the core and the sleeve to differential thermal treatment which causes the diameter of the bore to exceed the outer diameter of the core, locating the core in the bore of the sleeve, and allowing the core and the sleeve to stabilise at a common temperature thereby to place the sleeve in hoop tension and the core in compres¬ sion.
9. The method according to claim 6, characterised in that the step of forming the interference fit comprises the steps of forming the core with a predeterm ned outer diameter, forming the sleeve with a bore,having a diameter which is slightly larger than said outer diameter, locating the core in the bore of the sleeve, and working the sleeve down on to the core thereby to place the sleeve in hoop tension and the core in compression.
10. The method according to claim 9, characterised in that the sleeve is worked down on to the core by a swaging technique.
11. The method according to claim 10, characterised in that the swaging technique makes use of a rotary hammer swage technique which hammers the sleeve radially inwards.
12. The method .according to claim 10, characterised in that the swaging technique makes use of a rotary ball swage technique which deforms the sleeve radially inwards.
PCT/GB1990/001700 1989-11-07 1990-11-06 Improved roller WO1991006499A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8925103.7 1989-11-07
GB898925103A GB8925103D0 (en) 1989-11-07 1989-11-07 Improved roller

Publications (1)

Publication Number Publication Date
WO1991006499A1 true WO1991006499A1 (en) 1991-05-16

Family

ID=10665860

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1990/001700 WO1991006499A1 (en) 1989-11-07 1990-11-06 Improved roller

Country Status (4)

Country Link
EP (1) EP0502856A1 (en)
AU (1) AU6627790A (en)
GB (1) GB8925103D0 (en)
WO (1) WO1991006499A1 (en)

Cited By (7)

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Publication number Priority date Publication date Assignee Title
DE4226789A1 (en) * 1992-08-13 1994-02-17 Sigri Great Lakes Carbon Gmbh Fiber-reinforced plastic roller with outer, wear-resistant, filler-containing plastic layer
WO1996011100A1 (en) * 1994-10-07 1996-04-18 Urenco Deutschland Gmbh Process for producing composite fibre pipes with metal surfaces
US5523833A (en) * 1991-10-09 1996-06-04 Canon Kabushiki Kaisha Delivery member and apparatus making use of the same
EP0747310A2 (en) * 1995-06-05 1996-12-11 Heidelberger Druckmaschinen Aktiengesellschaft Rotating cylindrical body with low mass inertia
EP0763667A1 (en) * 1995-09-13 1997-03-19 Idemitsu Petrochemical Co., Ltd. Multi-layer structure roller and a method for producing the same
EP1068926A1 (en) * 1999-07-13 2001-01-17 Aerospatiale Matra CCR Process of introducing a metallic ring into a compound material having an organic matrix and element obtained by the method
EP1990195A2 (en) * 2007-05-05 2008-11-12 manroland AG Printing press cylinder

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FR2102908A5 (en) * 1970-08-11 1972-04-07 Takata Kojyo Co Multilayer tube of reinforced synthetic - material
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CA1147133A (en) * 1980-08-29 1983-05-31 Denis Thibault Method for manufacturing rollers or idlers
JPS5973239A (en) * 1982-10-20 1984-04-25 Michio Yoshikawa Composite material manufacturing method by shrink fitting
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5523833A (en) * 1991-10-09 1996-06-04 Canon Kabushiki Kaisha Delivery member and apparatus making use of the same
DE4226789A1 (en) * 1992-08-13 1994-02-17 Sigri Great Lakes Carbon Gmbh Fiber-reinforced plastic roller with outer, wear-resistant, filler-containing plastic layer
WO1996011100A1 (en) * 1994-10-07 1996-04-18 Urenco Deutschland Gmbh Process for producing composite fibre pipes with metal surfaces
EP0747310A2 (en) * 1995-06-05 1996-12-11 Heidelberger Druckmaschinen Aktiengesellschaft Rotating cylindrical body with low mass inertia
EP0747310A3 (en) * 1995-06-05 1997-11-05 Heidelberger Druckmaschinen Aktiengesellschaft Rotating cylindrical body with low mass inertia
EP0763667A1 (en) * 1995-09-13 1997-03-19 Idemitsu Petrochemical Co., Ltd. Multi-layer structure roller and a method for producing the same
US5895344A (en) * 1995-09-13 1999-04-20 Idemitsu Petrochemical Co., Ltd. Multi-layer structure roller and a method for producing the same
EP1068926A1 (en) * 1999-07-13 2001-01-17 Aerospatiale Matra CCR Process of introducing a metallic ring into a compound material having an organic matrix and element obtained by the method
FR2796425A1 (en) * 1999-07-13 2001-01-19 Aerospatiale Matra Ccr METHOD FOR INTRODUCING A METALLIC RING INTO A PART MADE OF COMPOSITE MATERIAL WITH AN ORGANIC MATRIX AND PART OBTAINED BY THIS PROCESS
EP1990195A2 (en) * 2007-05-05 2008-11-12 manroland AG Printing press cylinder
EP1990195A3 (en) * 2007-05-05 2010-09-29 manroland AG Printing press cylinder

Also Published As

Publication number Publication date
AU6627790A (en) 1991-05-31
EP0502856A1 (en) 1992-09-16
GB8925103D0 (en) 1989-12-28

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