WO1991005595A1 - Method and apparatus for producing hollow yarn film knitted article - Google Patents

Method and apparatus for producing hollow yarn film knitted article Download PDF

Info

Publication number
WO1991005595A1
WO1991005595A1 PCT/JP1989/001053 JP8901053W WO9105595A1 WO 1991005595 A1 WO1991005595 A1 WO 1991005595A1 JP 8901053 W JP8901053 W JP 8901053W WO 9105595 A1 WO9105595 A1 WO 9105595A1
Authority
WO
WIPO (PCT)
Prior art keywords
hollow fiber
fiber membrane
needle
warp
guide
Prior art date
Application number
PCT/JP1989/001053
Other languages
French (fr)
Japanese (ja)
Inventor
Osami Kato
Seiko Ishikana
Tsutomu Iriyama
Tatsujiro Mori
Original Assignee
Mitsubishi Rayon Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co., Ltd. filed Critical Mitsubishi Rayon Co., Ltd.
Priority to EP19890911398 priority Critical patent/EP0450068A4/en
Priority to PCT/JP1989/001053 priority patent/WO1991005595A1/en
Publication of WO1991005595A1 publication Critical patent/WO1991005595A1/en
Priority to KR91700590A priority patent/KR0138507B1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • B01D63/0231Manufacturing thereof using supporting structures, e.g. filaments for weaving mats
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B23/00Flat warp knitting machines
    • D04B23/12Flat warp knitting machines with provision for incorporating unlooped wefts extending from selvedge to selvedge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/021Manufacturing thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D69/00Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08Hollow fibre membranes

Definitions

  • the present invention relates to a method for producing a hollow fiber membrane knitted fabric suitable for producing a hollow fiber membrane module used in artificial lung, artificial dialysis, plasmapheresis, pure water production, gas filtration, water purifiers and the like. Fight for manufacturing equipment. Background art
  • a hollow fiber membrane module is manufactured by cutting a bundle of hollow fiber membranes into a predetermined length, storing them in a container, and fixing the ends of the hollow fiber membranes to the container with epoxy resin or urethane resin. You. However, if the opening at the end of the hollow fiber membrane is fixed in the open state, the resin enters through the opening and cannot be used as a module. Therefore, a method has been adopted in which the bundle end of the hollow fiber membrane is fixed in a state where it is temporarily sealed with a resin or the like in advance, and after fixing, the fixed part is cut to open the bundle end of the hollow fiber membrane.
  • the temporary sealing part is a part that is discarded when the module is completed, but is an indispensable part in the temporary sealing process. Material costs and processing costs for that purpose had to be extra.
  • the opening of some hollow fiber membranes may be blocked by the fixing resin, the required membrane area cannot be secured in the module, and the module that has been manufactured must be discarded as a defective product. There are cases.
  • a method of winding the hollow fiber membrane into a total frame such as a tetragon, hexagon, or octagon several tens to several hundred times to obtain a bundle (total) Method In this method, before cutting to obtain a bundle, it is necessary to bundle the hollow fiber membrane single yarn forming the bundle with paper or thread so that the yarn does not fall apart, and the handling is troublesome.
  • Knitted hollow fiber membranes are disclosed in JP-A-62-57965 and JP-A-1-92203. However, these documents do not disclose any specific knitting device or knitting method for processing the hollow fiber membrane into a knit without damaging it. In a normal Russell knitting machine, the interval between the needles that determines the interval for the weft is usually about 1.6, and the upper limit of the weft movement width is about 16. Disclosure of the invention
  • the present inventors have conducted intensive studies on a method of manufacturing a hollow fiber membrane module having no above-mentioned disadvantages, and have reached the present invention.
  • An object of the present invention is to solve the problems of the prior art and to provide a manufacturing method and an apparatus capable of obtaining a hollow fiber membrane bundle which can be easily processed by a membrane module.
  • a hollow fiber membrane supply member traveling on a plane around the hollow fiber membrane guide bar with respect to a pair of vertically movable hollow fiber membrane guide bars standing upright and left at predetermined intervals.
  • a hollow fiber membrane is supplied from the upper part of the lancing needle, and the hollow fiber membrane is endlessly supplied to the lancing needle moving up and down in a region surrounded by the traveling path.
  • the hollow fiber membrane guide bar and the needle are simultaneously moved up and down by two reciprocations.
  • the movement of the hollow fiber membrane supply member is temporarily stopped to form a knitted portion using only the warp, or the number of the latch needles is set to two or more, and at least one latch needle is used for the other. It is more preferable to supply a warp of a different color from the warp supplied to the lancing needle.
  • a pair of hollow fiber membrane guide bars that are erected on the left and right at least at an interval of 50 mm because a module of an appropriate length can be formed.
  • An apparatus for manufacturing a knitted hollow fiber membrane comprises: a pair of vertically movable hollow fiber membrane guide bars erected at predetermined intervals on the left and right; and a hollow fiber traveling on a plane around the hollow fiber membrane guide bar.
  • the hollow fiber membrane supply member is configured to move up and down two reciprocations in synchronization with the hollow fiber membrane guide bar and the lever.
  • FIG. 1 is a schematic perspective view showing a knitting state of a hollow fiber membrane knitted fabric by a preferred apparatus for carrying out the production method of the present invention
  • FIG. 2 is a traveling of a traverse guide viewed from the top of the apparatus shown in FIG.
  • FIG. 3 is a perspective view showing an enlarged main part of the knitting state of FIG. 1, and
  • FIGS. 4 (a) to 4 (d) show the knitting method according to the present invention.
  • FIGS. 5A and 5B are diagrams sequentially explaining the stitch forming process of FIG.
  • FIG. 5 is a plan view corresponding to FIG. 2, showing a state in which the traverse guide travels in a figure eight shape.
  • FIG. 6 is a schematic diagram of a hollow fiber membrane knit including a knitted fabric portion of warp only
  • FIG. 7 is a schematic perspective view of a hollow fiber membrane bundle in which the hollow fiber membrane knit is spirally bundled.
  • FIG. 1 shows an outline of knitting in a hollow fiber membrane feed production apparatus of the present invention
  • FIG. 2 is a plan view of the apparatus shown in FIG. This shows the travel path of the traverse guide.
  • guide bars 1 and 1 'and guide bars 2 and 2' are vertically arranged on the left and right sides of the knitting apparatus at an interval of about 50 to 1000, preferably about 50 to 500 m. It is moved up and down by a driving device (not shown).
  • a corresponding number of warp yarns are above each of the needles 3, 3 '; 4, 4'.
  • each hook is turned in a slightly U-shape so as to go around. Move and provide warp 8, 8 '; 9, 9' inside each hook.
  • Numeral 10 is a traverse guide (hollow) in which one or a plurality of hollow fiber membranes (hereinafter referred to as hollow fiber membrane group), which are constituent elements of the hollow fiber membrane module of the present invention, are provided as weft yarns and guided to warp stitches.
  • the traverse guide 10 travels around the outside of each of the guide bars 1 ', 1; 2, 2' without crossing on a plane as shown by arrows in FIG. That is, the traverse guide 10 wraps around the two guide bars 1 ′, 1 from the point ⁇ ⁇ in the center of the drawing, passes through the hook side of the left hand 3 ′, 3, and wraps around the two guide bars 1, 1. , And around the guide bars 2 and 2 ′ through the non-hook sides of the latch needles 4 and 4 ′ arranged on the right side of the drawing. Run on the hook side of 4 and reach point A above to complete the round.
  • each of the guide bars 1, 1 '; 2, 2' and each of the needles 3, 3 '; 4, 4' move up and down in synchronization.
  • the guide bars 1, 1 '; 2, 2' and the lancing needles 3, 3 '; 4, 4' also start descending, and the traverse guide 10 is moved. It keeps descending until it reaches point C, and becomes the lowest point (bottom dead center) at point C.
  • the guide bars 1, 1 '; 2, 2' and the lancing needles 3, 3 '; 4, 4' also start descending, and the traverse guide 10 is moved. It continues descending until it reaches point A, and becomes the lowest point (bottom dead center) at point A.
  • reference numerals 12 and 13 denote left and right hand needles 3, 3 '; 4,
  • Fixed guide guides 12 'and 13' are provided horizontally to protrude from the tips of the fixed guide guides 12 and 13 in order to prevent the sticks from jumping up when 4 'rises. It is a bar-shaped fixed projection bar.
  • the protruding bars 12 'and 13' should cross the upper surface of the trick plate 5 between the left and right hand pins 3, 3 '; 4, 4' and the right and left guide bars 1, 1 '; 2, 2'. It is installed as close as possible to the sticks 3, 3 '; 4, 4'.
  • the hollow fiber membrane group 11 supplied from above is moved from the outside to one of the right and left guide bars of the guide bar rising at the same time by the traverse guide 10 running in the left-right direction. It is wound. At this time, the other guide bar is also rising, but is not involved in the guide of the hollow fiber membrane group 11 at all, and the hollow fiber membrane group 11 is replaced by the one guide bar at the next rise. Wrap and guide.
  • the needles 3, 3 '; 4, 4' are all at the same time at the top dead center, and the warp supply guides 6, 6, 7 ', 7' are slightly above the plane.
  • the warp yarns 8, 8'9, 9 ' are wound around the hooks and supplied in a U-shape.
  • FIG. Fig. 3 shows the position of the member between the members when the hollow fiber membrane group 11 reaches point p from point C.
  • the curve shown by the two-dot chain line in the figure The line is the traverse guide 10 runway.
  • the hollow fiber membrane group that was drafted by the movement of the traverse guide 10 passing through the arrow A ⁇ B-C at the previous stage and wound on the guide bars 1 and 1 ′ on the left side 11 is disengaged from guide bars 1 and 1 ', the part A-B is inserted into the stitch as A'-B', and the part B-C is inserted into the stitch needle 3 and 3 '.
  • the state moves to the hook side and the state is passed over the warp loop formed in the previous stage, and becomes B'-C '.
  • the hollow fiber membranes at B'-C'—D are successively wound when the hollow fiber membranes wound on the right traverse guides 2 and 2 'are removed from the guide bar. It is inserted in the stitch.
  • the hollow fiber membrane group 11 in the uppermost stage is passed over the warp loop formed in the previous stage, and is inserted and knitted into the stitch at the time of forming the warp loop in the next stage.
  • Fig. 4 (a) to Fig. 4 (d) show the state of the lancing needle 3 as a representative example.
  • a warp thread is wound around the hook 14 of the bevel needle 3 by a warp supply guide.
  • a warp loop 16 formed in the preceding stage is formed below the hanging bevel 15.
  • the hollow fiber membrane group 11 is passed through a space surrounded by the warp 8, the warp loop 16, and the lancing needle 3 wound around the hook 14.
  • Fig. 4 (b) shows the state where the spatula needle 3 descends and the loop 16 formed at the previous stage lifts the spatula 15 and closes the hook 14.
  • the guide bar also descends and the hollow fiber membrane group
  • Fig. 4 (c) shows the state just before the needle 3 further descends to reach the bottom dead center, and a new warp loop 16 is formed.
  • Fig. 4 shows a state in which the spatula needle 3 is being lifted, and at this time, the next-stage hollow fiber membrane group 11 is passed above the warp loop 16. In this way, a hollow fiber membrane knit is continuously formed. Will be done.
  • the hollow fiber membrane group 11 In order to form a knitted fabric, a minimum tension is required for the hollow fiber membrane group 11 which is a weft as well as for the warp yarns 8 and 8 ′; and 9 and 9 ′. A limited tension is also required. These tensions fluctuate somewhat during knitting.
  • the hollow fiber membrane group 11 comes off from the guide bars 1, 1 '; 2, 2'. At the moment, the tension of the hollow fiber membrane group 11 drops to the maximum. At that moment, the warp tension is applied to the hollow fiber membrane group 11. On the contrary, if the hollow fiber membrane group 11 is not supported by any means, the hollow fiber membrane group 11 will be drawn into the grooves of the trick plates 5, 5 '.
  • the fixing protrusion bars 12 'and 13' are for preventing the hollow fiber membrane group 11 coming off the left and right guide bars 1, 1 '; 22' from entering the groove of the trick plate 55 '. In order to exert the effect sufficiently, it is preferable that the distance between the fixed protrusion bar 13 'and the key of the trick plate 5 is short.
  • the height of guide bars 1, 1 ′; 2 2 ′ and spatula needles 3, 3 ′; 4 4 ′ can be set as appropriate depending on the distance between the guide bar and the spatula needle.
  • the hollow fiber membranes come into contact with each guide bar 11'2, 2 ', the fixed guide guides 12, 13 and the fixed protrusion bars 12'; In order to avoid the damage of the group 11 as much as possible, it is preferable to make the surface of these materials smooth, so that, for example, those made of ceramics can be used.
  • the plurality of guide bars 1, 1 ′; 2, 2 ′ are arranged so that the hollow fiber membrane group 11 is smoothly removed when the guide bars 1, 1 ′; Therefore, for example, when two pairs of guide bars 1, 1 ′; 2, 2 ′ are arranged on the left and right, as shown in FIG. 2, the guide bars 1, 2 on the near side are changed to the guide bars 1 ′, 2 on the rear. It is better to place it slightly inside.
  • the guide bars 1, 1 ′ ′, 2, 2 ′ are arranged two by two on the left and right. However, basically only one guide bar is required on each of the left and right. There are more than books. However, when arranging the needles one by one on the left and right, it is necessary to secure enough space for the lancet to be placed in the part of the traverse guide 10 that is surrounded by the travel path. Furthermore, in the above embodiment, two spatula needles are arranged on each of the left and right sides, but any number of one or more can be set. In general, when making a wide knitted fabric, it is preferable to increase the number of warps by increasing the number of knurls, and the interval between the knurls is appropriately set.
  • the fixed guides 12 and 13 remove the hollow fiber membrane from the guide bar and jump up the stick of the stick needle. It has the two functions of preventing the occurrence of a problem, and may be a plate-shaped object as shown in FIG. 1 or a rod-shaped object as shown in FIG. In FIG. 2, the side 12a of the fixed guide guide serves to remove the hollow fiber membrane from the guide bar, and the front side Ub prevents the needle from jumping up.
  • these fixed plan guides 12 and 13 may separate the above two functions, and may be divided into two elements having the respective functions.
  • the hollow fiber membrane group 11 comes off the guide bar when the lint needle is in the state shown in Fig. 4 (b), but the distance from the guide bar to the lint needle causes the hollow fiber membrane group 11 to move away from the guide bar.
  • the detached hollow fiber membrane group 11 does not come into direct contact with the lancet needle.
  • a structure in which the traverse guide travels on the same plane in a figure eight shape as shown in FIG. 5 may be used. In this case, the traverse guide 10 wraps around the two guide bars 1, 1 ′ from the point E at the center of the drawing, passes through the anti-hook side of the left hand 3, 3 ′, and goes around the two guide bars 1, 1 ′.
  • the knitted hollow fiber membrane is manufactured by the above-described apparatus.
  • the hollow fiber membrane knitted fabric is a continuous knitted fabric
  • the knitted fabric is cut to an appropriate length, the hollow fiber membrane near the cut portion is damaged or the knitted fabric near the cut portion is frayed. There is.
  • FIG. 6 shows a knitted hollow fiber membrane obtained by this method, and the length of a portion forming the knitted hollow fiber membrane is shown short for simplification of the drawing.
  • the number of stitches of the knitted fabric consisting of only warp yarns is not particularly limited, but may be usually about 2 to 10.
  • the supply of the hollow fiber membrane is stopped when a knitted fabric consisting of only warp yarns is formed.
  • the traverse guide be run on a specific guide bar on either the left or right side. In this way, the knitted fabric consisting of only the warp yarns shown in Fig. 6 was formed.
  • the opening end (cut portion) of the hollow fiber membrane is on the same side, which facilitates the work of manufacturing the membrane module. That is, the cut hollow fiber membrane knit is wound as shown in FIG. 7 and one end or both ends of the hollow fiber membrane bundle are fixed with resin, but since the cut portion of the hollow fiber membrane is on the same side, one end is formed.
  • the cut side is fixed with resin.
  • the hollow fiber membrane knitted fabric of the present invention it is preferable to supply a warp of a color different from that of the warp supplied to at least one other hand.
  • a warp of a color different from that of the warp supplied to at least one other hand.
  • the warp yarns supplied to the spatula needles 3 and 3 'and the spatula needles 4 and 4' are made of different colors, when fabricating the membrane module, the operator will be able to use the color of the warp yarns at both ends. By looking at the side, it is possible to determine the cut portion side (open end side) of the hollow fiber membrane.
  • a continuous hollow fiber membrane knitted product obtained by folding the hollow fiber membrane without being cut at the ear can be obtained extremely efficiently. Also, by appropriately setting the knitting width, a hollow fiber membrane knitted product having an arbitrary width can be easily obtained.
  • the spacing between the left and right guide bars was set to 100, and the number of spatula needles was set to two for each of the left and right.
  • a knitting machine was manufactured by modifying the Russell knitting machine shown in Fig. 13.
  • hollow fiber membrane a bundle of 16 polyethylene hollow fiber membranes (EHF270T manufactured by Mitsubishi Rayon Co., Ltd.) with an outer diameter is used, and black (for right) and light brown (for left) warps are used. Polyester yarn (300d / 96f) was used.
  • the movement of the guide bar and the hand was synchronized, and it was moved up and down twice while the traverse guide circulated.
  • the moving speed of the traverse guide was set at 55 reciprocations / min, and the warp tension was set at 25 to 30 s.
  • the knitting device was operated under these conditions, and the traverse guide starting from the left end made 130 traverse guides. This movement was stopped for three reciprocations to form a chain knit consisting of only warp yarns.This operation was then repeated to produce 10 hollow fiber membrane knits formed by 130 reciprocations of the traverse guide, consisting of only warp yarns.
  • the chain stitches (X-X ', ⁇ -Y' in Fig. 6) were cut.
  • the knitted hollow fiber membrane obtained in this manner is spirally wound as shown in FIG. 7 and housed in a cylindrical polycarbonate container, one end of which is fixed with an epoxy resin to obtain a membrane area of 0.3. It was fabricated membrane module of m 2. When a water flow test (after hydrophilization treatment with alcohol) was performed on this membrane module in a leak test, good results were obtained, and it was confirmed that the hollow fiber membrane was not damaged during knitting.
  • the distance between the left and right guide bars is 450 m
  • the moving speed of the traverse guide is 30 reciprocations Zmin
  • the number of reciprocations of the traverse guide for one batch is 240 times
  • the other conditions are the same as in Example 1.
  • the knitted hollow fiber membrane produced by the method or the apparatus of the present invention is remarkably excellent in handleability as compared with a bundle of hollow fiber membranes obtained by a conventional reeling method.
  • Hollow fiber membrane modules manufactured from this hollow fiber membrane knit are used in fields such as artificial lung, artificial dialysis, plasma pheresis, pure water production, water purifiers, gas filtration, liquid filtration, gas separation, and cell culture. It is possible.

Abstract

This invention relates to a hollow yarn film knitted article obtained by disposing at least one warp knitting line consisting of ordinary fiber filaments (8, 8'; 9, 9') with a gap and passing hollow yarn films (11) in a weft direction over and under the stitches of the warp line, and to a production method of the knitted article. The knitted article production apparatus comprises hollow yarn film guide bars (1, 1'; 2, 2') disposed with gaps between them to the right and left and capable of moving up and down; a feed member (10) for supplying the hollow yarn film around the guide bars (1, 1'; 2, 2'), latch needles capable of knitting the hollow yarn film, (3, 3'; 4, 4') capable of moving up and down, and warp supply members (6, 6'; 7, 7') for the latch needles.

Description

明 細 書 中空糸膜編物の製造方法及び製造装置 技術分野  Description Manufacturing method and manufacturing apparatus for hollow fiber membrane knitted fabric
本発明は人工肺、 人工透析、 プラズマフェレシス、 純水製 造、 気体攄過の各分野、 浄水器等に用いられる中空糸膜モジ ユールを製造するに好適な中空糸膜編物の製造方法及び製造 装置に鬨する。 背景技術  The present invention relates to a method for producing a hollow fiber membrane knitted fabric suitable for producing a hollow fiber membrane module used in artificial lung, artificial dialysis, plasmapheresis, pure water production, gas filtration, water purifiers and the like. Fight for manufacturing equipment. Background art
一般に中空糸膜モジュールは中空糸膜の認束を所定の長さ にカッ ト して容器内に収納し、 エポキシ樹脂又はウレタン樹 脂等で中空糸膜端部を容器に固定することによって製作され る。 しかしながら、 中空糸膜端部の開口部を開口状態のまま 固定すると開口部から樹脂が侵入してモジュールと して使用 できないものになる。 したがってあらかじめ中空糸膜の束端 部を樹脂等で仮封鎖した状態で固定し、 固定後にその固定部 分を切断して中空糸膜の束端部を開口状態にする方法が採用 されている。  Generally, a hollow fiber membrane module is manufactured by cutting a bundle of hollow fiber membranes into a predetermined length, storing them in a container, and fixing the ends of the hollow fiber membranes to the container with epoxy resin or urethane resin. You. However, if the opening at the end of the hollow fiber membrane is fixed in the open state, the resin enters through the opening and cannot be used as a module. Therefore, a method has been adopted in which the bundle end of the hollow fiber membrane is fixed in a state where it is temporarily sealed with a resin or the like in advance, and after fixing, the fixed part is cut to open the bundle end of the hollow fiber membrane.
従来は、 主にモジュール製作時における仮封鎖時の加工コ スト、 該仮封鎖の信頼性、 固定時の中空糸膜の束の乱れ及び 固定の信頼性について問題があった。  Conventionally, there have been problems mainly with regard to processing costs at the time of temporary sealing during module production, reliability of the temporary sealing, disturbance of the bundle of hollow fiber membranes at the time of fixing, and reliability of fixing.
即ち、 仮封鎖部分はモジュール完成時には廃棄される部分 でありながら、 仮封鎖工程には無くてはならない部分であり そのための材料費と加工費を余分にかけざるを得なかった。 また、 この仮封鎖が支障なく行われているかどうかは仮封鎖 時点では判別がし難く、 モジュール製作後の固定部切断面を 観察することによってはじめて仮封鎖の良否が判別できる。 更に、 一部の中空糸膜の開口部が固定用樹脂により封鎖され ることがあるため、 モジュールに所定の膜面積が確保できず せっかく製作したモジュールを不良品と して廃棄しなければ ならなくなる場合がある。 In other words, the temporary sealing part is a part that is discarded when the module is completed, but is an indispensable part in the temporary sealing process. Material costs and processing costs for that purpose had to be extra. In addition, it is difficult to determine whether or not the temporary sealing is performed without any trouble at the time of the temporary sealing, and the quality of the temporary sealing can be determined only by observing the cut surface of the fixed portion after the module is manufactured. Furthermore, since the opening of some hollow fiber membranes may be blocked by the fixing resin, the required membrane area cannot be secured in the module, and the module that has been manufactured must be discarded as a defective product. There are cases.
また、 この方法では中空糸膜の束を容器内に収納する方法 をとるために、 中空糸膜の束をきつちり揃えて容器内に収納 する必要がある。 このようにしないと周辺部の中空糸膜が乱 れてその中空糸膜の端部が固定用樹脂内に埋没し、 その結果 中空糸膜が有効に使用できなくなるという欠点があった。 更に、 中空糸膜を束と して使用するために、 中空糸膜が比 較的密に充塽されることが多く 、 固定時において中空糸膜束 の中央部における中空糸膜間に固定用樹脂が侵入し難く、 そ の結果、 固定不良による不良品が発生し易いという欠点があ つた。  In addition, in this method, since a method of storing a bundle of hollow fiber membranes in a container is required, it is necessary to tightly align the bundles of hollow fiber membranes and store them in the container. Otherwise, the hollow fiber membrane in the peripheral part is disturbed, and the end of the hollow fiber membrane is buried in the fixing resin. As a result, the hollow fiber membrane cannot be used effectively. Furthermore, since the hollow fiber membranes are used as a bundle, the hollow fiber membranes are often filled relatively densely, and are fixed between the hollow fiber membranes at the center of the hollow fiber membrane bundle during fixing. There is a drawback that the resin does not easily penetrate, and as a result, defective products are easily generated due to improper fixing.
一方、 この中空糸膜を束とする手段と しては、 通常中空糸 膜を 4角形、 6角形、 8角形等の総枠に数 10〜数 100回捲回 して束を得る方法(総法)を用いる。 この方法は切断して束を 得る前に、 束を形成する中空糸膜単糸がバラバラにならない 様に紙又は糸等で集束しておく必要があり、 その取扱いが面 倒である。  On the other hand, as means for forming the hollow fiber membrane into a bundle, a method of winding the hollow fiber membrane into a total frame such as a tetragon, hexagon, or octagon several tens to several hundred times to obtain a bundle (total) Method). In this method, before cutting to obtain a bundle, it is necessary to bundle the hollow fiber membrane single yarn forming the bundle with paper or thread so that the yarn does not fall apart, and the handling is troublesome.
更に、 この総法では 1回の総繰りによって得られる中空糸 膜の束数が限定され、 極めて生産能率が低い等の問題点を有 している。 Furthermore, in this total method, hollow fibers obtained by one total It has problems such as the limited number of membrane bundles and extremely low production efficiency.
中空糸膜編物については特開昭 62— 57965号公報や実開平 1— 92203号公報に開示されている。 しかしながらこれらの明 細書中には中空糸膜を損傷させることなく編物に加工するた めの具体的な編成装置や編成方法については何も開示されて いない。 又、 通常のラッセル編機は緯糸用の間隔を決めるベ ら針の間隔は通常 1 . 6關程度であり、 緯糸の移動幅も 16 程 度が上限とされている。 発明の開示  Knitted hollow fiber membranes are disclosed in JP-A-62-57965 and JP-A-1-92203. However, these documents do not disclose any specific knitting device or knitting method for processing the hollow fiber membrane into a knit without damaging it. In a normal Russell knitting machine, the interval between the needles that determines the interval for the weft is usually about 1.6, and the upper limit of the weft movement width is about 16. Disclosure of the invention
本発明者等はこのような現状に鑑み、 上記欠点のない中空 糸膜モジュールの製法につき鋭意検討した結果、 本発明に到 達した。  In view of such a situation, the present inventors have conducted intensive studies on a method of manufacturing a hollow fiber membrane module having no above-mentioned disadvantages, and have reached the present invention.
本発明は従来技術の有する問題点を解消して、 膜モジユ ー ル加工の容易な中空糸膜束を得ることができる製造方法と装 置を提供することを目的とする。  An object of the present invention is to solve the problems of the prior art and to provide a manufacturing method and an apparatus capable of obtaining a hollow fiber membrane bundle which can be easily processed by a membrane module.
本発明により、 左右に所定の間隔をもって立設された一対 の上下動可能な中空糸膜ガイ ドバーに対して、 該中空糸膜ガ ィ ドバーを巡って平面上を走行する中空糸膜供耠部材から中 空糸膜を供給すると共に、 前記走行路で囲まれた領域内を上 下動するベら針に対して、 該ベら針のほぼ上方から経糸を供 耠する、 中空糸膜がエンドレス状態で折り返えされて配置さ れている中空糸膜編物の 4造方法が提供される。  According to the present invention, a hollow fiber membrane supply member traveling on a plane around the hollow fiber membrane guide bar with respect to a pair of vertically movable hollow fiber membrane guide bars standing upright and left at predetermined intervals. A hollow fiber membrane is supplied from the upper part of the lancing needle, and the hollow fiber membrane is endlessly supplied to the lancing needle moving up and down in a region surrounded by the traveling path. Four methods for producing a hollow fiber membrane knitted fabric that is folded and arranged in a state are provided.
本発明の製造方法において中空糸膜供耠部材がー巡する間 に中空糸膜ガイ ドバーとベら針とを同期して 2往復上下動さ せると好ましい。 In the production method of the present invention, while the hollow fiber membrane supply member It is preferable that the hollow fiber membrane guide bar and the needle are simultaneously moved up and down by two reciprocations.
更に一時的に中空糸膜供耠部材の運動を止め経糸のみによ る編部を形成させたり、 あるいはベら針の数を 2以上と して 少なく とも 1つのベら針に対して他のベら針に供耠される経 糸とは異なる色の経糸を供耠するとより好ましい。  Further, the movement of the hollow fiber membrane supply member is temporarily stopped to form a knitted portion using only the warp, or the number of the latch needles is set to two or more, and at least one latch needle is used for the other. It is more preferable to supply a warp of a different color from the warp supplied to the lancing needle.
又、 少なく とも 50M Mの間隔をもって左右に立設された一対 の中空糸膜ガイ ドバーを用いれば適切な長さのモジュールを 形成できるので好ましい。  In addition, it is preferable to use a pair of hollow fiber membrane guide bars that are erected on the left and right at least at an interval of 50 mm because a module of an appropriate length can be formed.
本発明による中空糸膜編物製造装置は、 左右に所定の間隔 をもって立設された一対の上下動可能な中空糸膜ガイ ドバー と、 該中空糸膜ガイ ドバーを巡って平面上を走行する中空糸 膜供耠部材と、 前記走行路で囲まれる領域內を上下動するべ ら針と、 該ベら針のほぼ上方に配設され、 経糸を該ベら針に 供耠する経糸供耠部材とを有し、 前記中空糸膜供耠部材がー 巡する閤に前記中空糸膜ガイ ドバーと前記ベら針とが同期し て 2往復の上下動をするように構成することを特徴とする。 図面の簡単な説明  An apparatus for manufacturing a knitted hollow fiber membrane according to the present invention comprises: a pair of vertically movable hollow fiber membrane guide bars erected at predetermined intervals on the left and right; and a hollow fiber traveling on a plane around the hollow fiber membrane guide bar. A membrane supply member, a torsion needle that moves up and down in a region surrounded by the traveling path, and a warp supply member that is disposed substantially above the lather needle and supplies a warp to the lather needle. The hollow fiber membrane supply member is configured to move up and down two reciprocations in synchronization with the hollow fiber membrane guide bar and the lever. BRIEF DESCRIPTION OF THE FIGURES
第 1図は本発明の製造方法を実施するのに好ましい装置に よる中空糸膜編物の編成状態を示す概略斜視図、 第 2図は第 1図に示す装置の上面からみたトラバースガイ ドの走行路を 示す平面図、 第 3図は第 1図の編成状態を拡大して示す要部 斜視図、 第 4図(a)〜第 4図(d)は本発明による編成方法を実 施する際の編目形成工程を順次説明する図である。 又、 第 5図はトラバースガイ ドが 8の字状に走行する状態 を示す第 2図に対応する平面図である。 FIG. 1 is a schematic perspective view showing a knitting state of a hollow fiber membrane knitted fabric by a preferred apparatus for carrying out the production method of the present invention, and FIG. 2 is a traveling of a traverse guide viewed from the top of the apparatus shown in FIG. FIG. 3 is a perspective view showing an enlarged main part of the knitting state of FIG. 1, and FIGS. 4 (a) to 4 (d) show the knitting method according to the present invention. FIGS. 5A and 5B are diagrams sequentially explaining the stitch forming process of FIG. FIG. 5 is a plan view corresponding to FIG. 2, showing a state in which the traverse guide travels in a figure eight shape.
第 6図は経糸のみの編地部分を含んだ中空糸膜編物の概略 図、 第 7図は中空糸膜編物を渦卷き状に束ねた中空糸膜束の 概略斜視図である。 発明を実施するための最良の形態  FIG. 6 is a schematic diagram of a hollow fiber membrane knit including a knitted fabric portion of warp only, and FIG. 7 is a schematic perspective view of a hollow fiber membrane bundle in which the hollow fiber membrane knit is spirally bundled. BEST MODE FOR CARRYING OUT THE INVENTION
以下、 本発明を、 本発明の方法を実施するために好ま しい 装置を示す添付図面を参照して以下詳述する。  The invention will be described in more detail hereinafter with reference to the accompanying drawings, which show a preferred device for carrying out the method of the invention.
第 1図に本発明の中空糸膜攝物の製造装置における編成時 の概要を示し、 第 2図は第 1図に示した装置を上面からみた 平面図であって、 中空糸膜を供給するためのトラバースガイ ドの走行路を示す。  FIG. 1 shows an outline of knitting in a hollow fiber membrane feed production apparatus of the present invention, and FIG. 2 is a plan view of the apparatus shown in FIG. This shows the travel path of the traverse guide.
第 1図においてガイ ドバー 1 , 1 ' およびガイ ドバー 2 , 2 ' は編物製造装置の左右側部におよそ 50〜: 1000關程度好ま しくは 50〜 500«m程度の間隔をおいて垂直に配置され、 駆動 装置(図示せず)によって上下動する。  In FIG. 1, guide bars 1 and 1 'and guide bars 2 and 2' are vertically arranged on the left and right sides of the knitting apparatus at an interval of about 50 to 1000, preferably about 50 to 500 m. It is moved up and down by a driving device (not shown).
この左右ガイ ドバー 1 , 1 ' ; 2 , 2 ' の内側には、 それ ぞれ 2本ずつのベら針 3 , 3 ' ; 4 , 4 ' が垂直に且つ左右 ガイ ドの方向に沿って並設されている。 各 2本一組のベ A針 3 , 3 ' ; 4 , 4 ' はそれぞれトリ ックプレート 5 , 5 に 形成されている搆に沿って上下に移動可能であり、 それらの 上下動は前記ガイ ドバー 1 , 1 ' ; 2 , 2 ' の上下動に同期 する。  Inside the left and right guide bars 1, 1 '; 2, 2', two spatula needles 3, 3 '; 4, 4' are arranged vertically and in the direction of the left and right guide bars. Has been established. Each pair of needles A, 3, 3 '; 4, 4' can be moved up and down along a key formed on a trick plate 5, 5, respectively. , 1 '; Synchronizes with the vertical movement of 2, 2'.
各ベら針 3 , 3 ' ; 4 , 4 ' の上方には対応する数の経糸 供給ガイ ド 6 , 6 ' ; 7 , 7 ' が配置され、 各ベら針 3 , 3 ' ; 4 , 4 ' が上死点位置にあるとき、 各フックを回り込 むようにして僅かに U字状に動き、 各フックの内側に経糸 8 , 8 ' ; 9 , 9 ' を供耠する。 A corresponding number of warp yarns are above each of the needles 3, 3 '; 4, 4'. When the supply guides 6, 6 '; 7, 7' are arranged, and each of the needles 3, 3 '; 4, 4' is at the top dead center position, each hook is turned in a slightly U-shape so as to go around. Move and provide warp 8, 8 '; 9, 9' inside each hook.
10は本発明における中空糸膜モジュールの構成要素である 1本又は複数本の中空糸膜(以下中空糸膜群という) 11を緯糸 と して経糸の編目に案内供耠する トラバースガイ ド (中空糸 膜供耠部材) であり、 該トラバースガイ ド 10は第 2図に矢印 で示すごとく各ガイ ドバー 1 ' , 1 ; 2 , 2 ' の外側をまわ つて平面上を交差することなく走行する。 即ち、 トラバース ガイ ド 10は図面中央の点 Αから左側のベら針 3 ' , 3のフ ッ ク側を通って 2本のガイ ドバー 1 ' , 1をまわり込み、 同べ ら針 3 , 3 ' の反フック側を走行し、 次に図面右側に配設さ れたべら針 4 , 4 ' の反フック側を通って 2本のガイ ドバー 2, 2 ' をまわり、 同ベら針 4 ' , 4のフック側を走行して 上記 A点に達し一巡を終える。  Numeral 10 is a traverse guide (hollow) in which one or a plurality of hollow fiber membranes (hereinafter referred to as hollow fiber membrane group), which are constituent elements of the hollow fiber membrane module of the present invention, are provided as weft yarns and guided to warp stitches. The traverse guide 10 travels around the outside of each of the guide bars 1 ', 1; 2, 2' without crossing on a plane as shown by arrows in FIG. That is, the traverse guide 10 wraps around the two guide bars 1 ′, 1 from the point 図 面 in the center of the drawing, passes through the hook side of the left hand 3 ′, 3, and wraps around the two guide bars 1, 1. , And around the guide bars 2 and 2 ′ through the non-hook sides of the latch needles 4 and 4 ′ arranged on the right side of the drawing. Run on the hook side of 4 and reach point A above to complete the round.
一方、 このトラバースガイ ド 10が走行している間に、 上記 各ガイ ドバー 1 , 1 ' ; 2 , 2 ' と各ベら針 3 , 3 ' ; 4 , 4 ' が同期して上下動する。  On the other hand, while the traverse guide 10 is traveling, each of the guide bars 1, 1 '; 2, 2' and each of the needles 3, 3 '; 4, 4' move up and down in synchronization.
そのタイ ミングを第 2図によ り説明する。 第 2図の中央の 点 Aにトラバースガイ ド 10があるとき、 ガイ ドバー 1 , 1 ' 2 , 2 ' とべら針 3 , 3 ' ; 4 , 4 ' はすべてが最下位 (下 死点〉 まで下降しており、 トラバースガイ ド 10が同点 Aを通 過する時点からガイ ドバー 1 , 1 ' ; 2 , 2 ' とべら針 3 , 3 ' ; 4 , 4 ' のすべてが上昇を開始し トラバースガイ ド 10がガイ ドバー 1 ' を通過するときには全ガイ ドバー 1 , 1 ' ; 2 , 2 ' の先端はトラバースガイ ド 10の走行平面よ り 上方に位置し、 その後も全ガイ ドバー 1 , 1 ' ; 2 , 2 ' 及 び全ベら針 3 , 3 ' ; 4 , 4 ' は上昇を続け左にあるガイ ド バー 1 ' , 1の中間点 Bにおいて最上位(上死点)に達する。 そして、 トラバースガイ ド 10がこの中間点 Bを通過すると、 ガイ ドバー 1 , 1 ' ; 2 , 2 ' 及びベら針 3 , 3 ' ; 4 , 4 ' も下降を開始し、 トラバースガイ ド 10が C点に達するま で下降を続け、 C点において最下位(下死点)となる。 The timing will be described with reference to FIG. When traverse guide 10 is located at point A in the center of Fig. 2, guide bars 1, 1'2, 2 'and needles 3, 3'; 4, 4 'are all to the lowest position (bottom dead center). When the traverse guide 10 passes through the tie point A, the guide bars 1, 1 '; 2, 2' and the needles 3, 3 '; 4, 4' start rising and the traverse guide 10 Do When 10 passes through guide bar 1 ', the tips of all guide bars 1, 1'; 2, 2 'are located above the travel plane of traverse guide 10, and thereafter all guide bars 1, 1'; 2 , 2 ′ and all needles 3, 3 ′; 4, 4 ′ continue to rise and reach the highest point (top dead center) at the midpoint B of guide bar 1 ′, 1 on the left. Then, when the traverse guide 10 passes through the intermediate point B, the guide bars 1, 1 '; 2, 2' and the lancing needles 3, 3 '; 4, 4' also start descending, and the traverse guide 10 is moved. It keeps descending until it reaches point C, and becomes the lowest point (bottom dead center) at point C.
次に、 トラバースガイ ド 10が C点を通過する時点からガイ ドバー 1 , 1 ' ; 2 , 2 ' とべら針 3 , 3 ' ; 4 , 4 ' のす ベてが上昇を開始し、 トラバースガイ ド 10がガイ ドバー 2を 通過するときには全ガイ ドバー 1 , 1 ' ; 2 , 2 ' の先端は トラバースガイ ド 10の走行平面より上方に位置し、 その後も 全ガイ ドバー 1 , 1 ' ; 2 , 2 ' 及び全ベら針 3 , 3 ' ; 4 4 ' は上昇を続け右にあるガイ ドバ一 2 , 2 ' の中間点 Dに おいて最上位(上死点)に達する。 そして、 トラバースガイ ド 10がこの中間点 Dを通過すると、 ガイ ドバー 1 , 1 ' ; 2 , 2 ' 及びベら針 3 , 3 ' ; 4 , 4 ' も下降を開始し、 トラバ ースガイ ド 10が A点に達するまで下降を続け、 A点において 最下位(下死点)となる。  Next, from the point when the traverse guide 10 passes through the point C, all the guide bars 1, 1 '; 2, 2' and the spatula needles 3, 3 '; 4, 4' start rising, and the traverse guide 10 When guide 10 passes through guide bar 2, the tips of all guide bars 1, 1 '; 2, 2' are located above the travel plane of traverse guide 10, and thereafter all guide bars 1, 1 '; 2, 2 'and all needles 3, 3'; 4 4 'continue to rise and reach the highest point (top dead center) at the midpoint D of guide bars 1 and 2' on the right. Then, when the traverse guide 10 passes through the intermediate point D, the guide bars 1, 1 '; 2, 2' and the lancing needles 3, 3 '; 4, 4' also start descending, and the traverse guide 10 is moved. It continues descending until it reaches point A, and becomes the lowest point (bottom dead center) at point A.
したがって、 トラバ一スガイ ド 10の一周回毎に全ガィ ドバ 一 1 , 1 ' ; 2 , 2 ' と全ベら針 3 , 3 ' ; 4 , 4 ' は 2回 の上下動をすることになる。  Therefore, every one turn of the traversing guide 10, all the guides 1, 1 '; 2, 2' and all the needles 3, 3 '; 4, 4' move up and down twice. Become.
第 1図及び第 2図で 12 , 13は左右のベら針 3 , 3 ' ; 4 , 4 ' の上昇時においてベらの跳ね上がりを防止するために配 設された固定案内ガイ ドであり、 12' , 13' は各固定案内ガ ィ ド 12, 13の先端部から水平に突設される棒状の固定突起バ 一である。 同突起バー 12' , 13' は左右のベら針 3 , 3 ' ; 4 , 4 ' と左右のガイ ドバー 1 , 1 ' ; 2 , 2 ' の間で上記 トリックプレート 5の上面を横切るようにして突設されるも ので、 可能な限りベら針 3 , 3 ' ; 4 , 4 ' に近付けて設置 される。 In FIGS. 1 and 2, reference numerals 12 and 13 denote left and right hand needles 3, 3 '; 4, Fixed guide guides 12 'and 13' are provided horizontally to protrude from the tips of the fixed guide guides 12 and 13 in order to prevent the sticks from jumping up when 4 'rises. It is a bar-shaped fixed projection bar. The protruding bars 12 'and 13' should cross the upper surface of the trick plate 5 between the left and right hand pins 3, 3 '; 4, 4' and the right and left guide bars 1, 1 '; 2, 2'. It is installed as close as possible to the sticks 3, 3 '; 4, 4'.
以上の構成において、 上方から供給される中空糸膜群 11は 左右方向に走行する トラバースガイ ド 10により、 タイ ミング を合わせて上昇しているガイ ドバーのうち左右いずれか一方 のガイ ドバーに外側から卷き付けられる。 このとき他方のガ ィ ドバーも上昇はしているが、 中空糸膜群 11のガイ ドと して 何ら関与しておらず、 次回の上昇時に前記一方のガイ ドバー に代わり中空糸膜群 11を卷き付けてガイ ドする。  In the above configuration, the hollow fiber membrane group 11 supplied from above is moved from the outside to one of the right and left guide bars of the guide bar rising at the same time by the traverse guide 10 running in the left-right direction. It is wound. At this time, the other guide bar is also rising, but is not involved in the guide of the hollow fiber membrane group 11 at all, and the hollow fiber membrane group 11 is replaced by the one guide bar at the next rise. Wrap and guide.
また、 このとき殆ど同時に全ベら針 3 , 3 ' ; 4 , 4 ' も 上死点の位置にあり、 その上方を各経糸供耠ガイ ド 6 , 6 ' 7 , 7 ' が平面上を僅かに U字状に往復動して経糸 8 , 8 ' 9 , 9 ' を各フックに卷き付け供給する。  At this time, the needles 3, 3 '; 4, 4' are all at the same time at the top dead center, and the warp supply guides 6, 6, 7 ', 7' are slightly above the plane. The warp yarns 8, 8'9, 9 'are wound around the hooks and supplied in a U-shape.
一方のガイ ドバーに中空糸膜群 11が卷き付けられると、 全 ガイ ドバー 1 , 1 ' ; 2 , 2 ' 及び全ベら針 3 , 3 ' ; 4 , 4 ' は下降を開始する。  When the hollow fiber membrane group 11 is wound around one of the guide bars, all the guide bars 1, 1 '; 2, 2' and all the needles 3, 3 '; 4, 4' start descending.
これらの動きを第 3図を参照しながら具体的に説明する。 第 3図は中空糸膜群 11が C点から p点に達した時点における 各部材間の鬨係位置を示したもので、 図中二点鎖線で示す曲 線はトラバースガイ ド 10の走行路である。 These movements will be specifically described with reference to FIG. Fig. 3 shows the position of the member between the members when the hollow fiber membrane group 11 reaches point p from point C. The curve shown by the two-dot chain line in the figure The line is the traverse guide 10 runway.
いま、 トラバースガイ ド 10が C点にあるとき、 左右のガイ ドバー 1 , 1 ' ; 2 , 2 ' とべら針 3 , 3 ' ; 4 , 4 ' は最 下降位置(下死点)にある。 トラバースガイ ド 10が C点を通過 すると、 全ガイ ドバー 1 , 1 ' ; 2 , 2 ' 及びベら針 3 , 3 ' ; 4 , 4 ' が上昇を開始する。 第 3図の例はトラバース ガイ ド 10が C点を通過してから右側手前のガイ ドバー 2を外 側から回り込んで右側後方のガイ ドバー 2 ' との中間点 に 達した時点を示している。 この時点では、 その前段階の矢印 A→B— Cを通る トラバースガイ ド 10の動きによつて案.内さ れ、 左方のガイ ドバー 1 , 1 ' に卷きつけられていた中空糸 膜群 11は、 ガイ ドバー 1 , 1 ' からはずされて、 A— Bにあ つた部分は A ' - B ' と して編目に挿入され、 B— Cにあつ た部分はべら針 3 , 3 ' の反フック側に移行すると共に前段 で形成された経糸ループ上にかけ渡された状態 B ' — C ' と なる。 そしてこの図で B ' -C ' — Dにある中空糸膜膜群は 続いて右方のトラバースガイ ド 2 , 2 ' に卷きつけられた中 空糸膜群がガイ ドバーからはずされる時に経糸の編目に挿入 される。 その結果、 最上段にある中空糸膜群 11は前段で形成 された経糸ループ上にかけ渡されて、 次段の経糸ループ形成 時に編目の中に挿入され編み込まれることになる。  Now, when the traverse guide 10 is located at the point C, the right and left guide bars 1, 1 '; 2, 2' and the spatula needles 3, 3 '; 4, 4' are at the lowest position (bottom dead center). When the traverse guide 10 passes through the point C, all the guide bars 1, 1 '; 2, 2' and the latch needles 3, 3 '; 4, 4' start rising. The example in Fig. 3 shows the point at which the traverse guide 10 passes point C and then wraps around the guide bar 2 on the right side from the outside to reach the middle point with the guide bar 2 'on the right rear. . At this point, the hollow fiber membrane group that was drafted by the movement of the traverse guide 10 passing through the arrow A → B-C at the previous stage and wound on the guide bars 1 and 1 ′ on the left side 11 is disengaged from guide bars 1 and 1 ', the part A-B is inserted into the stitch as A'-B', and the part B-C is inserted into the stitch needle 3 and 3 '. The state moves to the hook side and the state is passed over the warp loop formed in the previous stage, and becomes B'-C '. Then, in this figure, the hollow fiber membranes at B'-C'—D are successively wound when the hollow fiber membranes wound on the right traverse guides 2 and 2 'are removed from the guide bar. It is inserted in the stitch. As a result, the hollow fiber membrane group 11 in the uppermost stage is passed over the warp loop formed in the previous stage, and is inserted and knitted into the stitch at the time of forming the warp loop in the next stage.
編目形成時には、 ガイ ドバー 2 , 2 ' に卷き付けられた中 空糸膜群 11はガイ ドバー 2 , 2 ' と共に下降するが、 中空糸 膜走行路の下方に配置された固定案内ガイ ド 13及び固定突起 バー 13' (第 2図)により中空糸膜群 11は下降運動が阻止され ガイ ドバー 2 , 2 ' のみが下降し、 中空糸膜群 11はガイ ドバ - 2 , 2 ' から外れる。 このとき同時にベら針 3 , 3 ' ; 4 4 ' も下降して鑷目を形成する。 ベら針 3を代表させてその 状態を示したものが第 4図 (a〉〜第 4図 (d )である。 第 4図 (a)はべら針 3が上死点にあるときの状態を示し、 上死点に あるベら針 3のフック 14には経糸供耠ガイ ドにより経糸が卷 き付けられ、 このとき垂下しているベら 15の下方には前段で 形成された経糸ループ 16が卷き付けられている。 フック 14に 卷き付けられた経糸 8、 経糸ループ 16及びベら針 3本体で囲 まれる空間には中空糸膜群 11が揷通された状態にある。 . 第 4図 (b)はべら針 3が下降して前段で形成されたループ 16がベら 15を持ち上げ、 フック 14を閉じた状態を示す。 この とき、 同時にガイ ドバーも下降し、 中空糸膜群 11はガイ ドバ 一から外れる。 第 4図 (c )はべら針 3が更に下降し下死点に 達する直前の状態を示し、 新たな経糸ループ 16が形成される 第 4図 ( はべら針 3の上昇途中を示し、 このとき次段の 中空糸膜群 11が前記経糸ループ 16の上方に通される。 こう し て連続的に中空糸膜編物が形成されていく。 At the time of forming the stitch, the hollow fiber membrane group 11 wound around the guide bars 2 and 2 'descends together with the guide bars 2 and 2', but the fixed guide guide 13 arranged below the hollow fiber membrane travel path 13 And the fixed protrusion bar 13 '(Fig. 2) prevents the hollow fiber membrane group 11 from descending. Only the guide bars 2 and 2 'are lowered, and the hollow fiber membrane group 11 comes off the guide bars -2 and 2'. At this time, the sticks 3, 3 '; 4 4' also descend to form forceps. Fig. 4 (a) to Fig. 4 (d) show the state of the lancing needle 3 as a representative example. At the top dead center, a warp thread is wound around the hook 14 of the bevel needle 3 by a warp supply guide. At this time, a warp loop 16 formed in the preceding stage is formed below the hanging bevel 15. The hollow fiber membrane group 11 is passed through a space surrounded by the warp 8, the warp loop 16, and the lancing needle 3 wound around the hook 14. Fig. 4 (b) shows the state where the spatula needle 3 descends and the loop 16 formed at the previous stage lifts the spatula 15 and closes the hook 14. At this time, the guide bar also descends and the hollow fiber membrane group Fig. 4 (c) shows the state just before the needle 3 further descends to reach the bottom dead center, and a new warp loop 16 is formed. Fig. 4 shows a state in which the spatula needle 3 is being lifted, and at this time, the next-stage hollow fiber membrane group 11 is passed above the warp loop 16. In this way, a hollow fiber membrane knit is continuously formed. Will be done.
編物を形成させるためには緯糸である中空糸膜群 11にも、 経糸 8 , 8 ' ; 9 , 9 ' にも最低限度の張力が必要であり、 更には形成された編地を引取る最低限度の張力も必要である これらの張力は編成時に多少は変動するものであるが、 特に 本発明の装置においては、 ガイ ドバー 1 , 1 ' ; 2 , 2 ' か ら中空糸膜群 11が外れた瞬間に中空糸膜群 11の張力が最高に 低下する。 その瞬間において中空糸膜群 11に対し経糸張力が 勝る場合に、 中空糸膜群 11を何らかの手段で支持しないと中 空糸膜群 11がトリ ックプレート 5 , 5 ' の溝に引き込まれる ことになる。 In order to form a knitted fabric, a minimum tension is required for the hollow fiber membrane group 11 which is a weft as well as for the warp yarns 8 and 8 ′; and 9 and 9 ′. A limited tension is also required. These tensions fluctuate somewhat during knitting. In particular, in the apparatus of the present invention, the hollow fiber membrane group 11 comes off from the guide bars 1, 1 '; 2, 2'. At the moment, the tension of the hollow fiber membrane group 11 drops to the maximum. At that moment, the warp tension is applied to the hollow fiber membrane group 11. On the contrary, if the hollow fiber membrane group 11 is not supported by any means, the hollow fiber membrane group 11 will be drawn into the grooves of the trick plates 5, 5 '.
固定突起バー 12' , 13' は左右のガイ ドバー 1 , 1 ' ; 2 2 ' から外れた中空糸膜群 11がトリ ックプレート 5 5 ' の 溝に入るのを防止するためのものであり、 そ 効果を充分に 発揮させるためには固定突起バー 13' と トリックプレート 5 の搆との間の距離は近い方が好ま しい。  The fixing protrusion bars 12 'and 13' are for preventing the hollow fiber membrane group 11 coming off the left and right guide bars 1, 1 '; 22' from entering the groove of the trick plate 55 '. In order to exert the effect sufficiently, it is preferable that the distance between the fixed protrusion bar 13 'and the key of the trick plate 5 is short.
また、 ガイ ドバー 1 , 1 ' ; 2 2 ' とべら針 3 , 3 ' ; 4 4 ' の高さはガイ ドバーとベら針の間の距離との鬨係で 適宜設定が可能 あるが、 ガイ ドバーから外れた中空糸膜群 Uをベら針に接触させないためには、 通常、 ベら針の先端部 の高さをガイ ドバーの先端都の高さよ り低く設定することが 好ま しい。  The height of guide bars 1, 1 ′; 2 2 ′ and spatula needles 3, 3 ′; 4 4 ′ can be set as appropriate depending on the distance between the guide bar and the spatula needle. In order to prevent the hollow fiber membrane group U coming off the bar from coming into contact with the knurled needle, it is usually preferable to set the height of the tip of the knurled needle to be lower than the height of the tip of the guide bar.
以上の説明によ り明らかなごとく、 各ガイ ドバー 1 1 ' 2 , 2 ' 、 固定案内ガイ ド 12, 13及び固定突起バー 12' ; 13 には中空糸膜群が接触するため、 中空糸膜群 11の損傷を可能 なかぎり回避するには、 これらの都材表面を滑らかにするこ とが好ましく 、 そのため例えばセラミ ックス製のものを使用 することができる。  As is clear from the above description, the hollow fiber membranes come into contact with each guide bar 11'2, 2 ', the fixed guide guides 12, 13 and the fixed protrusion bars 12'; In order to avoid the damage of the group 11 as much as possible, it is preferable to make the surface of these materials smooth, so that, for example, those made of ceramics can be used.
また、 複数本のガイ ドバー 1 , 1 ' ; 2 , 2 ' はその下降 時に中空糸膜群 11がスムースに外れるように配置されている ことが好ましい。 そのため、 例えば 2本一対のガイ ドバー 1 , 1 ' ; 2 , 2 ' を左右に配置する場合は、 第 2図に示す ごと く手前のガイ ドバー 1 , 2を後方のガイ ドバー 1 ' , 2 のやや内側に配置するのがよい。 It is preferable that the plurality of guide bars 1, 1 ′; 2, 2 ′ are arranged so that the hollow fiber membrane group 11 is smoothly removed when the guide bars 1, 1 ′; Therefore, for example, when two pairs of guide bars 1, 1 ′; 2, 2 ′ are arranged on the left and right, as shown in FIG. 2, the guide bars 1, 2 on the near side are changed to the guide bars 1 ′, 2 on the rear. It is better to place it slightly inside.
以上の実施例ではガイ ドバー 1 , 1 ' '、 2 , 2 ' を左右に 2本ずつ配置しているが、 基本的には左右に各 1本ずつあれ ばよく 、 場合によつては各 3本以上のこともある。 ただ、 左 右に 1本ずつを配置するときは、 トラバースガイ ド 10の走行 路で囲まれる部分にベら針を配置するに充分なスペースを確 保する必要がある。 更に上記実施例ではべら針を左右に各 2 本ずつ配置しているが、 各 1本以上の任意の数に設定するこ とができる。 一般に幅の広い編物を作る場合にはべら針の本 数を増加させて経糸の本数を多くすることが好ましく 、 また 各ベら針の間隔は適宜設定する。 また、 横方向にこれらの機 構を複数組並置すれば同時に複数の編物を得ることができる 固定案内ガイ ド 12, 13はガイ ドバーから中空糸膜を外すこ ととべら針のベらの跳ね上がりを防止することの 2つの機能 を有するものであり、 第 1図に示すように板状物であっても よく 、 第 2図に示すように棒状物を加工したものであっても よい。 第 2図において固定案内ガイ ドの側面側 12 aがガイ ド バーから中空糸膜を外す役割を果し、 前面側 U bがベら針の 跳ね上がりを防止している。 また、 これらの固定案內ガイ ド 12, 13は上記 2つの機能を分離し、 各々の機能を有する 2つ の素子に分割して配置してもよい。  In the above embodiment, the guide bars 1, 1 ′ ′, 2, 2 ′ are arranged two by two on the left and right. However, basically only one guide bar is required on each of the left and right. There are more than books. However, when arranging the needles one by one on the left and right, it is necessary to secure enough space for the lancet to be placed in the part of the traverse guide 10 that is surrounded by the travel path. Furthermore, in the above embodiment, two spatula needles are arranged on each of the left and right sides, but any number of one or more can be set. In general, when making a wide knitted fabric, it is preferable to increase the number of warps by increasing the number of knurls, and the interval between the knurls is appropriately set. If multiple sets of these mechanisms are juxtaposed in the lateral direction, multiple knitted fabrics can be obtained at the same time. The fixed guides 12 and 13 remove the hollow fiber membrane from the guide bar and jump up the stick of the stick needle. It has the two functions of preventing the occurrence of a problem, and may be a plate-shaped object as shown in FIG. 1 or a rod-shaped object as shown in FIG. In FIG. 2, the side 12a of the fixed guide guide serves to remove the hollow fiber membrane from the guide bar, and the front side Ub prevents the needle from jumping up. In addition, these fixed plan guides 12 and 13 may separate the above two functions, and may be divided into two elements having the respective functions.
前述のようにベら針が第 4図 (b)の状態にある頃に中空糸 膜群 11がガイ ドバーから外れるが、 ガイ ドバーとベら針との 間に距離があるためにガイ ドバーから外れた中空糸膜群 11が ベら針に直接接触することがない。 以上第 1〜4図に基づいて説明してきたが、 トラバースガ ィ ドを第 5図に示すように同一平面上を 8の字状に走行する 構造にしてもよい。 この場合は、 トラバースガイ ド 10は図面 中央の点 Eから左側のベら針 3 , 3 ' の反フック側を通って 2本のガイ ドバー 1 , 1 ' をまわり込み、 同ベら針 3 , 3 ' のフック側を走行し、 再び E点に戻って図面右側に配設され たべら針 4 , 4 ' の反フック側を通って 2本のガイ ドバー 2 2 ' をまわり、 同ベら針 4 , 4 ' のフック側を走行して上記 E点に達し一巡を終える。 As described above, the hollow fiber membrane group 11 comes off the guide bar when the lint needle is in the state shown in Fig. 4 (b), but the distance from the guide bar to the lint needle causes the hollow fiber membrane group 11 to move away from the guide bar. The detached hollow fiber membrane group 11 does not come into direct contact with the lancet needle. Although described above with reference to FIGS. 1 to 4, a structure in which the traverse guide travels on the same plane in a figure eight shape as shown in FIG. 5 may be used. In this case, the traverse guide 10 wraps around the two guide bars 1, 1 ′ from the point E at the center of the drawing, passes through the anti-hook side of the left hand 3, 3 ′, and goes around the two guide bars 1, 1 ′. After traveling on the hook side of 3 ', return to point E again, pass around the two guide bars 2 2' through the anti-hook side of spatula needles 4 and 4 'arranged on the right side of the drawing, and Travel on the hook side of 4 and 4 'to reach the above point E and complete the round.
本発明において中空糸膜編物は前述のような装置で製造さ れる。 しかし、 中空糸膜編物が連続した編地になっていると 編地を適当な長さに切断する際に、 切断部近傍の中空糸膜が 損傷されたり切断部近傍の編地がほつれる場合がある。  In the present invention, the knitted hollow fiber membrane is manufactured by the above-described apparatus. However, when the hollow fiber membrane knitted fabric is a continuous knitted fabric, when the knitted fabric is cut to an appropriate length, the hollow fiber membrane near the cut portion is damaged or the knitted fabric near the cut portion is frayed. There is.
本発明においてはかかる問題点を解消するため、 所定長さ の編物を形成した時点で中空糸膜の供耠を停止し、 経糸のみ の編地を形成した後再度中空糸膜編物を形成する方法を採用 することができる。 第 6図はこの方法によって得られた中空 糸膜編物であり、 図面の簡略化のため中空糸膜編物を形成す る部分の長さは短かく示されている。 経糸のみからなる編地 の編目の数は特に限定されないが通常 2〜10程度であればよ い。  In the present invention, in order to solve such a problem, supply of the hollow fiber membrane is stopped when a knitted fabric of a predetermined length is formed, and a knitted fabric of warp only is formed, and then a hollow fiber membrane knitted fabric is formed again. Can be adopted. FIG. 6 shows a knitted hollow fiber membrane obtained by this method, and the length of a portion forming the knitted hollow fiber membrane is shown short for simplification of the drawing. The number of stitches of the knitted fabric consisting of only warp yarns is not particularly limited, but may be usually about 2 to 10.
経糸のみの編地を形成する場合に中空糸膜の供給は停止さ れるが、 その際トラバースガイ ドは左右いずれかの特定のガ イ ドバー側を走行させ ことが好ましい。 このよ うにすると 第 6図の経糸のみからなる編地が形成された X— X ' 部分及 び Y— Y ' 部分が切断された場合に、 中空糸膜の開口端 (切 断部) が同一の側になるため、 膜モジュール製作の作業が容 易となる。 即ち、 切断された中空糸膜編物は第 7図に示すよ うに卷かれて中空糸膜束の一端もしくは両端が樹脂で固定さ れるが、 中空糸膜の切断部が同一の側になるため一端のみを 樹脂固定する場合はその切断部側が樹脂固定される。 The supply of the hollow fiber membrane is stopped when a knitted fabric consisting of only warp yarns is formed. At this time, it is preferable that the traverse guide be run on a specific guide bar on either the left or right side. In this way, the knitted fabric consisting of only the warp yarns shown in Fig. 6 was formed. When the Y-Y 'portion is cut, the opening end (cut portion) of the hollow fiber membrane is on the same side, which facilitates the work of manufacturing the membrane module. That is, the cut hollow fiber membrane knit is wound as shown in FIG. 7 and one end or both ends of the hollow fiber membrane bundle are fixed with resin, but since the cut portion of the hollow fiber membrane is on the same side, one end is formed. When only resin is fixed with resin, the cut side is fixed with resin.
本発明の中空糸膜編物の製造においては、 少なく とも 1つ のべら針に対して他のベら針に供給される経糸とは異なる色 の経糸を供耠することが好ましい。 たとえば第 2図において ベら針 3 , 3 ' とべら針 4 , 4 ' に供耠する経糸をそれぞれ 異なる色の糸とすれば、 膜モジュール製作の際、 作業者は両 端部の経糸の色を見ることによって、 中空糸膜の切断部側 (開口端側)を判断することができる。  In the production of the hollow fiber membrane knitted fabric of the present invention, it is preferable to supply a warp of a color different from that of the warp supplied to at least one other hand. For example, in Fig. 2, if the warp yarns supplied to the spatula needles 3 and 3 'and the spatula needles 4 and 4' are made of different colors, when fabricating the membrane module, the operator will be able to use the color of the warp yarns at both ends. By looking at the side, it is possible to determine the cut portion side (open end side) of the hollow fiber membrane.
以上、 詳細に説明した如く本発明の装置によれば、 耳部に おいて中空糸膜が切断されることなく折り返えされた連続し た中空糸膜編物が極めて能率よく得ることが出来る。 また、 編幅を適宜設定することによ り容易に任意の幅の中空糸膜編 物を得ることができる。  As described in detail above, according to the apparatus of the present invention, a continuous hollow fiber membrane knitted product obtained by folding the hollow fiber membrane without being cut at the ear can be obtained extremely efficiently. Also, by appropriately setting the knitting width, a hollow fiber membrane knitted product having an arbitrary width can be easily obtained.
実施例 1 Example 1
左右のガイ ドバーの閬隔を 100 と し、 ベら針の数を左右 各 2本と して第 1 3図で示される構造のラッセル編機を改 造した編物装置を製作した。  The spacing between the left and right guide bars was set to 100, and the number of spatula needles was set to two for each of the left and right. A knitting machine was manufactured by modifying the Russell knitting machine shown in Fig. 13.
中空糸膜と して外径 のポリエチレン中空糸膜 (三菱 レイヨン(株)製、 EHF270T )を 16本束ねたものを用い、 経糸と して黒色(右側用)と、 薄茶色(左側用)のボリエステル加工糸 (300d/96f)を用いた。 As the hollow fiber membrane, a bundle of 16 polyethylene hollow fiber membranes (EHF270T manufactured by Mitsubishi Rayon Co., Ltd.) with an outer diameter is used, and black (for right) and light brown (for left) warps are used. Polyester yarn (300d / 96f) was used.
ガイ ドバーとベら針の動きは同期させ、 トラバースガイ ド がー巡する間に、 2回上下動させた。 トラバースガイ ドの移 動速度を 55往復/ min と し、 経糸張力は 25〜30s 本と した この条件で編物装置を作動させ、 左端を起点とする トラバ ースガイ ドが 130往復した時点でトラバースガイ ドの動きを 3往復分停止させて、 経糸のみからなる鎖編みを形成させた 以下この動作を繰り返し、 トラバースガイ ド 130往復で形成 された中空糸膜編物を 10個分製造し、 経糸のみからなる鎖編 み部(第 6図の X— X ' , Υ— Y ' )を切断した。  The movement of the guide bar and the hand was synchronized, and it was moved up and down twice while the traverse guide circulated. The moving speed of the traverse guide was set at 55 reciprocations / min, and the warp tension was set at 25 to 30 s.The knitting device was operated under these conditions, and the traverse guide starting from the left end made 130 traverse guides. This movement was stopped for three reciprocations to form a chain knit consisting of only warp yarns.This operation was then repeated to produce 10 hollow fiber membrane knits formed by 130 reciprocations of the traverse guide, consisting of only warp yarns. The chain stitches (X-X ', Υ-Y' in Fig. 6) were cut.
このようにして得られた中空糸膜編物を第 7図に示すよう に渦卷き状に卷いてボリカーボネート製円筒容器内に収納し てその一方の端部をエポキシ樹脂で固定し膜面積 0.3m2の膜 モジュールを製作した。 この膜モジュールについてリークテ ストに通水テスト(アルコールでの親水化処理後)を実施した ところ良好な結果が得られ、 編物製造時に中空糸膜が損傷さ れていないことが確認された。 The knitted hollow fiber membrane obtained in this manner is spirally wound as shown in FIG. 7 and housed in a cylindrical polycarbonate container, one end of which is fixed with an epoxy resin to obtain a membrane area of 0.3. It was fabricated membrane module of m 2. When a water flow test (after hydrophilization treatment with alcohol) was performed on this membrane module in a leak test, good results were obtained, and it was confirmed that the hollow fiber membrane was not damaged during knitting.
実施例 2 Example 2
左右のガイ ドバーの間隔を 450»m、 トラバースガイ ドの移 動速度を 30往復 Zmin と し 1バッチ分のトラバースガイ ドの 往復回数を 240回と しその他の条件は実施例 1 と同様にして 中空糸膜編物を製造したところ損傷のない中空糸膜織物が得 られた。 産業上の利用可能性 The distance between the left and right guide bars is 450 m, the moving speed of the traverse guide is 30 reciprocations Zmin, the number of reciprocations of the traverse guide for one batch is 240 times, and the other conditions are the same as in Example 1. When the hollow fiber membrane knit was manufactured, a hollow fiber membrane fabric without damage was obtained. Industrial applicability
本発明の方法又は装置によって製造される中空糸膜編物は 従来の認繰り法によって得られる中空糸膜の束と比較すると 取扱い性が著しく優れている。 この中空糸膜編物から製造さ れる中空糸膜モジュールは人工肺、 人工透析、 プラズマフエ レーシス、 純水製造、 浄水器、 気体滤過、 液体攄過、 気体分 離、 細胞培養等の分野に使用可能である。  The knitted hollow fiber membrane produced by the method or the apparatus of the present invention is remarkably excellent in handleability as compared with a bundle of hollow fiber membranes obtained by a conventional reeling method. Hollow fiber membrane modules manufactured from this hollow fiber membrane knit are used in fields such as artificial lung, artificial dialysis, plasma pheresis, pure water production, water purifiers, gas filtration, liquid filtration, gas separation, and cell culture. It is possible.

Claims

請求の範囲 The scope of the claims
1 . 左右に所定の間隔をもって立設された一対の上下動可 能な中空糸膜ガイ ドバーに対して、 該中空糸膜ガイ ドバーを 巡って平面上を走行する中空糸膜供耠部材から中空糸膜を供 耠すると共に、 前記走行路で囲まれた領域内を上下動するべ ら針に対して、 該ベら針のほぼ上方から経糸を供耠する、 中 空糸膜がェンドレス状態で折り返えされて配置されている中 空糸膜編物の製造方法。 1. With respect to a pair of vertically movable hollow fiber membrane guide bars that are erected at predetermined intervals on the left and right sides, a hollow fiber membrane supply member that travels on a plane around the hollow fiber membrane guide bar is hollow. In addition to supplying a yarn membrane, a warp yarn is supplied to the needle moving up and down in an area surrounded by the traveling path from almost above the needle, and the hollow yarn membrane is in an endless state. A method for producing a hollow fiber knitted fabric that is folded back.
2 . 中空糸膜供耠部材がー巡する間に中空糸膜ガイ ドバー とべら針とを同期して 2往復上下動させる第 1項記載の方法 2. The method according to Item 1, wherein the hollow fiber membrane guide bar and the needle are synchronously moved up and down two times while the hollow fiber membrane supply member goes around.
3 . —時的に中空糸膜供耠部材の運動を止め経糸のみによ る編部を形成させる第 1項又は第 2項記載の方法。 3. The method according to paragraph 1 or paragraph 2, wherein the movement of the hollow fiber membrane supply member is stopped occasionally to form a knitted portion solely by the warp.
4 . ベら針の数を 2以上と して、 少なく とも 1つのベら針 に対して、 他のベら針に供耠される経糸とは異なる色の経糸 を供給する第 1項又は第 2項記載の方法。  4. The number of lapped needles shall be 2 or more, and at least one lapped needle shall be supplied with a warp of a different color from the warp supplied to other lapped needles. The method according to paragraph 2.
5 . 少なく とも 50mmの間隔をもって左右に立設された一対 の中空糸膜ガイ ドバーを用いることを特徴とする第 1項又は 第 2項記載の方法。  5. The method according to paragraph 1 or 2, characterized by using a pair of hollow fiber membrane guide bars erected on the left and right at least 50 mm apart.
6 . 左右に所定の間隔をもって立設された一対の上下動可 能な中空糸膜ガイ ドバーと、 該中空糸膜ガイ ドバーを迩つて 平面上を走行する中空糸膜供耠部材と、 前記走行路で囲まれ る領域内を上下動するベら針と、 該ベら針のほぼ上方に配設 され、 経糸を該ベら針に供耠する経糸供耠部材とを有し、 前 記中空糸膜供耠部材がー巡する間に前記中空糸膜ガイ ドバー と前記ベら針とが同期して 2往復の上下動をする中空糸膜編 物製造装置。 6. A pair of vertically movable hollow fiber membrane guide bars vertically erected on the left and right sides, a hollow fiber membrane supply member traveling on a plane through the hollow fiber membrane guide bars, and the traveling A hollow needle that moves up and down in a region surrounded by a road, and a warp supply member that is disposed substantially above the needle and supplies a warp to the needle. While the fiber membrane supply member is in circulation, the hollow fiber membrane guide bar is The hollow fiber membrane knitting production apparatus in which the needle and the needle move synchronously and reciprocate up and down two times.
PCT/JP1989/001053 1989-10-13 1989-10-13 Method and apparatus for producing hollow yarn film knitted article WO1991005595A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP19890911398 EP0450068A4 (en) 1989-10-13 1989-10-13 Method and apparatus for producing hollow yarn film knitted article
PCT/JP1989/001053 WO1991005595A1 (en) 1989-10-13 1989-10-13 Method and apparatus for producing hollow yarn film knitted article
KR91700590A KR0138507B1 (en) 1989-10-13 1991-06-12 Method and apparatus for producing hollow yarn film knitted article

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1989/001053 WO1991005595A1 (en) 1989-10-13 1989-10-13 Method and apparatus for producing hollow yarn film knitted article

Publications (1)

Publication Number Publication Date
WO1991005595A1 true WO1991005595A1 (en) 1991-05-02

Family

ID=13958890

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1989/001053 WO1991005595A1 (en) 1989-10-13 1989-10-13 Method and apparatus for producing hollow yarn film knitted article

Country Status (3)

Country Link
EP (1) EP0450068A4 (en)
KR (1) KR0138507B1 (en)
WO (1) WO1991005595A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012201999A (en) * 2011-03-25 2012-10-22 Mitsubishi Rayon Co Ltd Warp knitting machine and method for manufacturing fabric

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0598909B1 (en) * 1992-02-12 1998-01-14 Mitsubishi Rayon Co., Ltd. Hollow yarn membrane module
US5922201A (en) * 1992-02-12 1999-07-13 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module
DE4308850A1 (en) * 1993-03-19 1994-09-22 Akzo Nv Hollow-thread mat
DE4322278A1 (en) * 1993-07-05 1995-01-19 Alfred Steinforth Process for producing capillary membrane bundles
JP5919672B2 (en) * 2011-08-09 2016-05-18 三菱レイヨン株式会社 Method and apparatus for producing hollow fiber membrane sheet
FR3041663B1 (en) * 2015-09-28 2018-04-27 Mdb Texinov METHOD AND DEVICE FOR PRODUCING A TEXTILE TUBULAR TEXTILE STRUCTURE

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6118143U (en) * 1984-07-05 1986-02-01 泉工医科工業株式会社 Hollow fiber membrane oxygenator
JPS6257965A (en) * 1985-09-09 1987-03-13 三菱レイヨン株式会社 Hollow yarn membrane knitted fabric
JPH0192203U (en) * 1987-12-08 1989-06-16

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1585118A1 (en) * 1962-12-24 1969-09-25 Heinrich Kalbskopf Fa Device on a chain chair, in particular on a Raschel machine
GB967570A (en) * 1963-03-04 1964-08-26 Rimoldi C Spa Virginio Fabric more particularly resilient band manufacturing method and machine
WO1988002038A1 (en) * 1986-09-16 1988-03-24 Textilma Ag Warp knit fabric and weft knitting machine for production of a warp knit fabric

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6118143U (en) * 1984-07-05 1986-02-01 泉工医科工業株式会社 Hollow fiber membrane oxygenator
JPS6257965A (en) * 1985-09-09 1987-03-13 三菱レイヨン株式会社 Hollow yarn membrane knitted fabric
JPH0192203U (en) * 1987-12-08 1989-06-16

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012201999A (en) * 2011-03-25 2012-10-22 Mitsubishi Rayon Co Ltd Warp knitting machine and method for manufacturing fabric

Also Published As

Publication number Publication date
KR0138507B1 (en) 1998-04-25
EP0450068A4 (en) 1992-07-08
KR920702823A (en) 1992-10-28
EP0450068A1 (en) 1991-10-09

Similar Documents

Publication Publication Date Title
US3774662A (en) Production of high soft stretch tapes of reinforcing cords for molded elastomeric articles
JPH0586537A (en) Hollow fiber woven tape, preparation thereof and device therefor
WO1985004838A1 (en) Method and apparatus for production of bias fabrics
JPS6357478A (en) Silver exchange method in fine spinning machine
WO1991005595A1 (en) Method and apparatus for producing hollow yarn film knitted article
JP2777140B2 (en) Hollow fiber membrane knitting equipment
KR101576346B1 (en) Loom and weaving method using said loom
ITMI941827A1 (en) METHOD TO OBTAIN A MULTIBAVE YARN STRETCHED DURING THE INTERLACING PHASE STARTING FROM THERMOPLATIC YARNS PARTIALLY ORIENTED
JPH0649734A (en) Method for weaving reinforcing material provided with a lot of non-releasable layers for composite material and weaving machine for executing said method
JP2906064B2 (en) Hollow fiber membrane knitting equipment
SU1324588A3 (en) Method of producing warp or sectional warp from synthetic yarn
RU2106441C1 (en) Method and apparatus for manufacture of multiaxial nonwoven structure, multiaxial nonwoven structure and versions of structure
JPS6043460B2 (en) knitting machine
JP5210679B2 (en) Knitting method and apparatus for knitting
JPS6399345A (en) Method and apparatus for producing plural separable fiber packages and fiber package produced
JPH059063Y2 (en)
US2552680A (en) Method and apparatus for producing twisted yarn-like structures
JPH05247715A (en) Method for direct spinning and drawing of combined filament yarn
US2587877A (en) Textile intermediate product and method of manufacturing the same
JP3392273B2 (en) Looms and hollow fiber membrane yarn bundle manufacturing equipment
JPH0336165A (en) Continuous drawing single-filament-yarn separating method and device thereof
HU205633B (en) Device for introducing flexible yarns for producing flexible ribbons in galloon-machine
SU130604A1 (en) Fundamentals zalnaya machine for making tulle jacquard linen
RU2162492C1 (en) Combing-twisting-winding unit
KR200187066Y1 (en) Interlace rewinder

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): KR US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): DE FR GB IT NL

WWE Wipo information: entry into national phase

Ref document number: 1989911398

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1989911398

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: 1989911398

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1989911398

Country of ref document: EP