WO1990013810A1 - Systeme de contrôle et/ou d'identification de fluides - Google Patents

Systeme de contrôle et/ou d'identification de fluides Download PDF

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Publication number
WO1990013810A1
WO1990013810A1 PCT/US1989/001818 US8901818W WO9013810A1 WO 1990013810 A1 WO1990013810 A1 WO 1990013810A1 US 8901818 W US8901818 W US 8901818W WO 9013810 A1 WO9013810 A1 WO 9013810A1
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WIPO (PCT)
Prior art keywords
light
fluid
data
test
control sample
Prior art date
Application number
PCT/US1989/001818
Other languages
English (en)
Inventor
Jerry G. Ingrum
Douglas J. Littlejohn
Douglas Modlin
Original Assignee
International Integrated Systems, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Integrated Systems, Inc. filed Critical International Integrated Systems, Inc.
Priority to PCT/US1989/001818 priority Critical patent/WO1990013810A1/fr
Publication of WO1990013810A1 publication Critical patent/WO1990013810A1/fr

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N2021/3196—Correlating located peaks in spectrum with reference data, e.g. fingerprint data
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84—Systems specially adapted for particular applications
    • G01N21/85—Investigating moving fluids or granular solids
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84—Systems specially adapted for particular applications
    • G01N21/88—Investigating the presence of flaws or contamination
    • G01N21/94—Investigating contamination, e.g. dust

Definitions

  • the present invention relates generally to the field of spectrographic analysis of fluids and more particularly to the fields of contaminant detection and fluid identification, with emphasis on the bottling industry.
  • the bottling industry is faced with many problems in tlie control and maintenance of their bottling facilities and procedures; but specific problems or concern herein are problems related to the "contamination" of the bottled products.
  • the term "contamination” is used herein as meening that any substance other than the intended "non-contaminants” (for example, the pure product and non-con- taminating cleansers) is being, has been or will be introduced into the bottle or other container distributed to the consumer. A look at two, typical bottling procedures will help identify more clearly some example problems.
  • a first procedure which gives rise to concern about contamination is the actual bottle filling procedure. Probably more than a few bottlers have experienced the wasting of many hundreds of gallons of product because a container was filled with improper product. For example, some bottlers will, in the course of a day, utilize the same conveyor and piping systems to fill bottles or cans of two, three or more products. The system will first be used, for example, to fill product 1 containers, then product 2, then product 3, and so on. For example, some beer manufacturers have procedures of utilizing the same conveyor and piping system to ultimately fill containers of premium beers, non-premium beers, and low calorie (“light”) beers. If the wrong product is introduced into a particular container, then that product is "contaminated". This is one type of contamination problem. Such contamination can occur either by operator error, in which the operator simply directs product from the wrong storage tank into the piping system, or when there is "residue" from a prior product run remaining in the piping system.
  • a second procedure which gives rise to concern about contamination is the "refilling" procedure.
  • This is a procedure in which the bottler collects used bottles, refills and reuses these bottles to contain fresh products.
  • these containers were used by consumers to simply dispense of the original product and were then returned to a collection facility.
  • the consumer may have used the container to hold a substance other than the original product and then delivered the container at some later time to tlie collection center.
  • a bottler must be concerned about whether an incoming container has been used to hold any substance which would affect the quality (i.e. taste or smell) of it's product. This potential for contamination of "refi liable" bottles is of particular concern when refilling plastic bottles.
  • the present invention comprises a method, with accompanying apparatus, for inspecting a fluid and determining whether or not the fluid contains contaminants.
  • fluid is to be broadly interpreted and shall include, without limitation, liquids, solutions, slurries and mixtures.
  • the present invention spectrographically analyses control samples of a known fluid, which known fluid is considered by the user to be "non-contaminated". The spectrographic analysis of the control sample is utilized to identify relative intensities of light at a plurality of pre-selected wavelengths. Tlie relationship of relative light intensities at the given wavelength is used to identify the non- contaminated fluid.
  • the unknown fluid also referred to as the "on-line fluid”
  • the unknown fluid is tested by performing a spectrographic analysis of the unknown fluid to acquire data as to the relationship of relative light intensities at the same wavelengths used to identify the control samples.
  • a determination is made as to whether or not the on-line fluid is contaminated.
  • the invention addresses the problem of refillable, plastic containers.
  • the container such as a refillable plastic bottle, contains an on-Line fluid, the exact make-up of which is completely or partially unknown.
  • the bottle with the on-line fluid therein, is moved past a light source.
  • Light from the light source is absorbed by the bottle and the on-line fluid and resulting, unabsorbed light is collected either by transmission, reflection or transflection at a light detector.
  • the collected light is divided and filtered into a plurality of separate light beams, each at a different wavelength. In the preferred embodiment, collected light is divided into four or more wavelengths. Data relating to the relative intensity of light at each of the wavelengths is collected, processed and compared to similar data from control samples. If the on-line fluid does not compare favorably with the control sample data, the respective container is considered to have contained contaminant and is rejected.
  • the on-line fluid passes within a fluid container, such as a conduit, past an observation port within the conduit.
  • a light source directs light through the observation port and the light is absorbed by the transparent port and the passing test fluid. Unabsorbed light from the light source is collected by transmission, reflection or trans- flection at a light detector. The collected light is separated and filtered into a plurality of light beams, each at a different wavelength. Data is collected and processed relating to the relative intensity of the collected light at each of the wavelengths. The test data is compared to similarily collected and processed control data relating to and identifying the known fluid of a control sample.
  • test data does not favorably compare with the control data
  • the on-line fluid is considered contaminated and directed away from the containers to be filled or toward alternate containers if appropriate. If the test and control data favorably compare, on-line fluid is considered non-contaminated, is considered to be the "proper product", and is directed to the awaiting containers.
  • control data is taken from a plurality of control samples.
  • Each control sample varies from the other control samples in one or more of its properties, such as but not limited to concentration level, temperature, container condition (i.e. scratches), and dirt content.
  • an electro-optical sensing apparatus which includes, generally, a fluid transporting medianisim, a light emitting module, a light detector and transmission module, a plurality of filter/amplifier modules a data acquisition and storage device for acquiring and storing light intensity data related to each of the filter/amplifier modules; and computer device (1) for calculating relationships among the collected data, (2) for comparing on-line and control data, (3) for determining acceptability of the compared data, and (4) for activating appropriate reject or control mechanism.
  • an object of the present invention to provide a method of idenfifying contamination of a fluid.
  • Another object of the present invention is to provide a method for discriminating among the various substances that may or may not be present in transparent containers.
  • Still another object of the present invention is to provide a method of providing system control signals to effect rejection of a recycled container upon the discovery of contaminant present in the container.
  • Another object to the present invention is to provide systems control signals for affecting fluid flow to direct "contaminated" products away from awaiting containers and to direct "non-con- laminated” products into awaiting containers.
  • Still another object of the present invention is to provide an apparatus for performing the aforementioned methods.
  • Yet another object of the present invention is to provide method and apparatus for the purpose of "on-line" substance detection; and qualification, quantification or discrimination among various substances that may or may not be present in re-fi liable containers constructed of plastics, glass, ceramic, metal, latex cellulose or other materials of construction, such as, but not limited to, cans, bottles, jars, bowls, tubes, boxes or bags, and uniquely integrating the container into the system optics.
  • Another object of the present invention is to provide a fluid inspection and identification apparatus used as a primary sensing element in process control or quality control applications as a primary sensing element in servo feed-back or feed forward techniques and used to divert flows, control flows, meter additions and institute other process control or process logic functions.
  • Fig. 1 is a flow diagram representing an overview of a fluid inspection and/or identification method in accordance with the present invention.
  • Fig. 2 is a plotted representation of light absorption/scattering over a range of wavelengths showing spectrographic analysis utilized to choose profiling wavelengths in accordance with the present invention, showing specific curves for example purposes only.
  • Fig. 3 is a flow diagram representing one embodiment of the method steps associated with step "C" of Fig. 1, "Acquire Control Data
  • FIG. 4 is a flow diagram representing one embodiment of the method steps associated with step "D" of Fig. 1, "Acquire On-line Data - Process On-line Data”.
  • Fig. 5 is a schematic representation of a fluid inspection and/or identification apparatus in accordance with the present invention.
  • Fig. 6 is a schematic representation of the apparatus of Tig. 5, depicting one embodiment thereof, for application with a "refillable Container Species".
  • Fig. 6A is a schematic representation of the apparatus of Fig.
  • Fig. 7 is a plotted representation of light intensity data acquired from a fluid sample (either Control Sample or On-line Sample), over a period of time, at each of the selected, profiling wavelengths, in accordance with the present invention, as such data is generated by the Refillable Container Species embodiment of Fig. 6.
  • Fig. 7A is a plotted representation of light intensity Data acquired from a fluid sample (either Control Sample or On-line Sample), over a period of time, at each of the selected, profiling wavelengths, in accordance with the present invention, as such data is generated by the Flying Brand Species embodiment of Fig. 6A.
  • Fig. 8 is a schematic, top view representation of a trigger device in accordance with the embodiment of Fig. 6 of the present invention.
  • Fig. 9 is a schematic, side view, representation of a preferred orientation of an emitter module, container, and detector module in accordance with the embodiment of Fig. 6 of the present invention.
  • Fig. 9A is a schematic, side view, representation of a preferred orientation of an emitter module, conduit, and detector module in accordance with the embodiment of Tig. 6A of the present invention.
  • Figs. 10A-10F are plotted representations of Control Data acquired from a plurality of Control Samples, in accordance with the Refillable Container Species embodiment of Fig. 6, arid showing specific examples.
  • Figs. 11A-11D are plotted representations of processed, Control Data of the specific examples of Figs. 10A-10F.
  • Fig. 12 is a plotted representation of On-line Data acquired from an On-line Sample, in accordance with the Refillable Container Species embodiment of fig. 6, and showing a specific example.
  • Figs. 12A-12D are plotted representations of the processed
  • Fig. 13 is a plotted representation of Control Data acquired from a Control Sample, in accordance with the Flying Brand Species embodiment of Fig; 6A, and showing a s'pecific example.
  • Figs. 14A-14C are plotted representation of processed, Control
  • Fig. 15 is a plotted representation of On-line Data acquired from an On-line Sample, in accordance with the Flying Brand Species embodiment of Fig. 6A, and showing a specific example.
  • Figs. 15A-15C are plotted representations of the processed
  • Fig. 16 is a plotted representation of on-Line Data acquired from an on-Line fluid, in accordance with an alternate application of the Flying Brand Species embodiment of Fig.6A, and showing a specific example.
  • a first step in the process is to identify what the user will consider to be a non-contaminant (Step A). Substances other than such an identified non-contaminant are to be considered, for purposes of the invention, as contaminants.
  • the user will identify a group of substances or a single substance as the non-contaminant(s).
  • such a group of non-contaminants may include a family of nonalcoholic, carbonated beverages; such as, cola, grape, lemon-lime, diet cola, etc.
  • the non-contaminant may be a single product such as a specific nonalcoholic beverage or a specific beer.
  • the user may choose to include, in the group of non- contaminants, water, dirt or other substances subjectively determined to be non-contaminants.
  • the user selects a number of substances which, if present in fluid, will be considered contaminates.
  • such contaminants may include substances such as household chemicals, agricultural chemicals, alcohols, solvents and petroleum products, etc.
  • the contaminant may be a product such as a cola or a selected group of nonalcoholic beverages (such as when a lemon-lime beverage is the sole, identified non-contaminant) or low-calarie beer (such as when premium beer is the sole, identified non-contaminant). It is understood that the substances identified as non-contaminants will vary at the discretion of the user, and, what may be chosen as a non-contaminant in one circumstance may be chosen as a contaminant in another circumstance, and visa-versa.
  • Step B the user ascertains a plurality of wavelengths (Step B), preferably in the visible spectrum, which the user considers the most optimum in providing a unique spectral profile of each non-con- taminant.
  • Such "profiling wavelengths" ( ⁇ 1 - ⁇ n ) are chosen, for example, by determining wavelengths along the spectrum at which the absorption/ scattering curves of the various non-contaminants within the group are distinguishable from the absorption/scattering curves of all other non-contaminants within the group and/or are distinguishable from the absorption/scattering curves of all of the selected contaminants.
  • UV and IR wavelengths are used where necessary to augment. It is preferred that at least four profiling wavelengths be utilized and also that the number of profiling wavelengths be kept as low as possible, preferably four or five, in order to hold down costs of the associated apparatus while still clearly identifying those substances in question. If cost is of no consequence, a greater number of profiling wavelengths can be chosen.
  • Computer analysis performed in one of many manners known in the industry, is utilized in some embodiments to assist in optimally selecting the profiling wavelengths.
  • the depicted profiling wavelengths shown on Fig. 2 are by way of example only, for use in the specific examples (below) of this specification; and the scope of the invention is not limited to or by the depicted example.
  • Control Fluid is a fluid consisting of one of the identified non-contaminants in either full strength or in varied concentrations with one or more other acceptable non-contaminants. For a better understanding, attention is directed to the examples given below. A sample of the Control Fluid is prepared from which data is to be acquired.
  • the data to be acquired is data related to the absorption/scattering of light by the Control Fluid at each of the profiling wavelengths.
  • the Control Fluid sample is exposed to light from a light source 12 (refer to Fig. 5) and some of the light is absorbed by the Control Fluid as will naturally occur in nature.
  • the light which is not absorbed is scattered or continues through the fluid medium; and the non-absorbed light or a representative portion of the non-absorbed light is collected, as much as possible, by appropriate collectors 14.
  • the non- absorbed light collected is either transmitted light or reflected light or a combination thereof ("Transf lected light").
  • Transf lected light The collected light is then separated such that collected light at each of the profiling wavelengths is isolated.
  • the apparatus for accomplishing this is represented by block 16 of Fig.
  • this isolation of profiling wavelengths is accomplished by dividing the collected light into a plurality of light beams by one of numerous methods known in the art, including, but not limited to (1) focusing the collected light on a plurality of separate fibers 18- 1...18-n of a multifiber, fiber optic cable 17, each fiber representing one of the plurality of light beams, or (2) focusing the collected light on a single fiber optic cable 17 which is subsequently split, by known methods, into a plurality of strands 18-1...18-n, each communicating the collected light equally, or (3) by direct lens ing of the light information.
  • Each of the light beams of the embodiment of Fig. 6 is filtered at a separate filter module 20- 1...20-n to provide the preferred, isolated light at only one of the selected profiling wavelengths.
  • the intensity of the collected light at each of the profiling wavelengths is detected by a detector 22 detecting the intensity of the light isolated at the respective profiling wavelength.
  • This detecting of intensity is, in preferred embodiments, accomplished through conversion of the filtered light to an electrical signal representative of the intensity.
  • the absolute value of light intensity at the respective profiling wavelength is detectable and usable herein, preferred embodiments of the present invention detect relative values of the light intensity at each profiling wavelength, relative to an arbitrary base "0" and relative to one another.
  • the term "intensity”, when used throughout this specification and claims shall be understood to refer to relative intensity and/or absolute intensity.
  • the respective electrical signal of each prof i ling wavelength is separately amplified for calibration purposes and for providing adequate resolution for manipulation of acquired data.
  • Such amplification is represented in Fig. 5 by the signal conditioning assembly 24 and in Fig.6, by the amplifier 52-1...51-4.
  • the detected data of respective light intensity is recorded and then, preferably, stored by a device 26, such as a computer, functioning as a recording and storing device 26.
  • the intensity of collected light at each profiling wavelength is recorded at a plurality of points in time over a prescribed period of time.
  • Acquired Data both Control data and On-Line data, may be represented in tabulation form and/or plotted form. Representative examples of acquired data in plotted form are seen in Figs. 7 and 7A. This will be better understood with reference to the apparatus described below.
  • control data is provided from a single, properly prepared Control Fluid sample, it is preferred to obtain control data from a variety of different, revised Control Fluid samples and revised control conditions; that is, revised as to properties such as, but not limited to, concentration levels of chosen non-con- taminates, temperature of the Control Fluid, room temperature and/or room pressure, container color/tint, and dirty or scratched containers.
  • the "revising" is done in an effort to obtain data from at least some control samples which will more closely approximate the unpredictable properties and conditions of the on-line fluid when acquiring on-line test data in order to identify and isolate the effects of these properties.
  • Control Fluid sample is revised in one or more of its properties (concentration, temperature, etc.) and then steps C-2 through C-5 are performed on the revised control sample.
  • the Control Fluid sample is revised a number of different times, in a number of different ways, and, the intensity of collected light at each of the profiling wavelengths is detected and recorded and, preferably, stored along with indentifying parameters of each revision of the Control Sample.
  • Control Sample(s) shall refer individually and collectively to the originally prepared Control Fluid sample and each subsequent revision thereof. Examples of control data collected in accordance with two, below described applications (species) of the preferred embodiment are seen in graph form in Figs. 10A-10F and Fig. 13.
  • the acquired control data is processed by a device 26a such as a computer, functioning as a processing device 26a to provide a plurality of mathematical inter-relationships among the light intensity data associated with the respective, profiling wavelengths for each Control Sample.
  • the processing provides a number of interrelationships which include, but are not limited to, one or more of the following: peak intensities (P 1 ⁇ l ,...P1 ⁇ n ) for each profiling wavelength over the data acquisition period; max imum average intensity for each profiling wavelength (Avl ⁇ ,,...Avl ⁇ n ), which is acquired by summing the intensities over the acquisition period and then dividing by the number of data acquisition points in the data acquisition period; sum of the intensities over the acquisition period for each profiling wavelength ( ⁇ I ⁇ ,.... ⁇ I ⁇ n); the ratios of the aforementioned relationships for each prof i l ing wavelength to one of the profiling wavelengths, for example, but ⁇
  • the processed data is recorded (and stored) at the recording/storing device 26 in tabulated form or in graphic form for each Control Sample. It is noted that the tabulated, processed data translates in graph form to a collection of "topographies" which "fingerprint", “profile” or “signature” the Control Fluid across the varied, rev i sed properties of the control samples. For examples of such processed data, see graphs of Figs. 11A - 11D, 14A - 14C.
  • the "topographies" of Figs. 14A-14C contain only a single signature since, in that specific example, no revisions were made to control Fluid samples; as is an acceptable embodiment where conditions allow.
  • step "E” The process steps (C7, Fig. 3) are shown as performed as part of the step of acquiring data, but it is understood that the processing steps are performable, in alternate embodiments, at a later step, ie., in conjunction with the comparing step (step "E").
  • the next step of Fig. 1 is the step of acquiring on-line data (step "0") .
  • on-line data is, preferably, acquired by a method (see Fig. 4) similar to that used for acquiring control data, in the preferred embodiment, the on-line data is acquired utilizing apparatus identical to that apparatus utilized to acquire the control data.
  • To acquire on-line data means, herein, to acquire data associated with a fluid which is being tested, for example, in the course of user's daily business operation, to determine if it contains contaminants. That is, the "On-Line Fluid" is being tested to determine if substances other than the chosen non-contaminants of the control fluid are present in the On-Line Fluid.
  • the On-Line Fluid is first "prepared".
  • the fluid to be tested is prepared in some manner for the introduction of light (step D2).
  • Preparation will vary depending upon the particular application, and various preparations include, without limitation, placing of a fluid, as is, in a container or conduit and/or by adding a known non- contaminant (such as, for example, water) to substance(s) already in the container and/or simply checking the container to see if fluid already exists in the container in sufficient quantity to be acted on in the next step. See descriptions of the two, example applications (species) mentioned below.
  • a known non- contaminant such as, for example, water
  • the step of introducing light to the On-line Fluid is perFormed in a manner substantially identical to the step of introducing liglit to the control fluid, or visa-versa. That is, the Control Fluid and On-line Fluid are both passed by the light source as a flowing fluid within a conduit; or, the Control Fluid and On-line Fluid are both held within a container of similar configuration and make-up, which container moves past the light source; or, for example, the Control Sample and On-line Sample are each held within a container of similar con- figuration and make-up and the light source is moved past the container.
  • the same optical instrument is utilized to obtain control data as is utilized to obtain On-line data in order to promote uniformity of resultant data, although in less acceptable, alternate embodiments, different but substantially similar apparatuses are utilized to acquire the control data and On-line data, respectively.
  • light is i ntroduced to the On-line Fluid and the non-absorbed light is collected, as much as possible, by the appropriate collectors 14, by the same method of transmittance, reflectance, or transf lectance as utilized in acquiring control data.
  • the collected light is then separated at the appropriate light channelling and filter assembly 16 such that the collected light at each of the profiling wavelengths is isolated.
  • the intensity of tlie collected light at each of the profiling wavelengths is detected by the respective detector 22 (Fig. 6) and, preferably, converted to an electrical signal representative of the respective intensity. Since it is desired to pass judgment on this On-line Fluid as to the presence or absence of contaminants, there is no step corresponding to the "revise control fluid sample" step C6 of Fig. 3.
  • the intensity of collected light at each profiling wavelength is recorded at a plurality of points in time ("data acquisition points") over a prescribed period of time (“data acquisit ion per iod" ) , i n a manner s imi l ar to the correspond i ng s tep in the acquisition of control data.
  • the acquired, On-line data is processed by the processing device 26a to provide a plurality of mathematical inter-relationships among the light intensity data associated with respective, profiling wavelengths for the On-line Fluid.
  • the processing provides a number of inter-relationships which correspond to inter-relationships of the processed Control Data, such as, but limited lo, one or more of the peak intensities, maximum of average intensities, Sum of intensities, first normalization of data to one (or to each) of the profiling wavelengths, second normalization, and plotting of the same.
  • the processing steps are performable, in alternate embodiments, at a later step, ie. in conjunction with the comparing steps ("E").
  • the next step in Fig. 1 is to compare processed control and Online data (Step E).
  • This comparison is performed, in alternate embodiments, by manual and visual techniques or, in preferred embodiments by a device 26b, such as a computer, functioning as a comparator.
  • One method, being a perferred method, of comparing the processed On-line data to the processed control data is to compare the plotted signatures for processed On-line data to the topographies For corresponding, processed control data. Utilizing the various, known techniques of "category theory", the comparator 26b (or user) seeks to "fit" the On-line data signature in the corresponding control data topography. If the On-line signature "fits", it is determined (step F) that only non-contaminant is present.
  • the On-line signature does not "fit", it is determined that substance other than (or in addition to) the non-contaminant are present in the On-line Fluid.
  • the preferred method requires that the signature of eacli of the interrelationships derived from the On-line data (signature of Figs. 12A- 12D, Figs. 15A-15C) "fit” the topographies of the corresponding inter-relationships from the control data or "fit” predicted topographies of control data which are based on the control data via known methods of interpolation. If any one of the On-line data signatures does not "fit" the corresponding data topography, the On- line Fluid is determined to contain contaminants.
  • step Gl if it is determined that only non-contaminants are present in the On-line Fluid, the apparatus of the present invention provides a control signal which dictates a "positive action" with respect to the On-line Fluid and/or its related container.
  • the positive action translates into, for example but not limited to, "keep the container", or "divert fluid flow to awaiting packaging".
  • step G2 if it is determined that something other than (or in addition to) non-contaminants is present in the On-line Fluid, the apparatus of the present invention provides an output signal which dictates a "negative action".
  • Such negative action translates into, for example but not limited to, command to a reject mechanism to "reject the container” or "divert fluid flow to purge the On-line Fluid".
  • the "refillable container species” comprises a unique application of the method and apparatus of the present invention to identify, tag, and provide a signal for a rejection mechanism to discard clear or tinted plastic bottles, which plastic bottles were being returned to a bottling plant for refilling, and which bottles have been contaminated by any foreign substances; that is, had been used to store substances other than the product (the non-contaminant) with which the container had been originally filled.
  • the "flying brand species” comprises a unique application of the apparatus and method of tlie present invention for determining whether or not the fluid flowing through a piping system is that exact fluid which the user intended to be pumping through the conduits. The intended fluid is the non-contaminant and any other fluid is the "contaminant”.
  • the flying brand change species also has application in determining when fluid flowing through a piping system has changed from fluid #1 to fluid #2.
  • fluid #2 is the "non- contaminant"
  • fluid #1 or any substance other than fluid #2, is the contaminant.
  • Tlie apparatus of the present invention associated with the refillable container species is shown in schematic form in Fig. 6.
  • the apparatus of the present invention associated with the flying brand change species is shown, in schematic form, in Fig. 6A. It is noted that the apparatus of both species are similar and, therefore, the common apparatus will be discussed below and ref erence, when appropriate, will be made to the distinguishing aspects of the apparatus for each species.
  • the apparatus of the present invention comprises an illuminator module 30 and an emitter module 32 which cooperate to function as the light source 12.
  • the illuminator module 30 is powered by a 5-volt, 3 amp power supply producing a 5 watt, light output from a quartz-halogen lamp 34, which light output is collected through collector lens 35 and focused by focusing lens 36 at the collecting end of a quartz, quartz-glass fiber optic cable 37, through which the collected and focused light is transmitted to the emitter module 32.
  • the emitter module 32 comprises an aspherical, micro-lensed light source, which focuses a coll imated, white light beam at the wall 39 of the fluid retaining medium 40, 40' and through the tested fluid 43 (control fluid or On-line Fluid).
  • the apparatus is provided for the collection of transmitted light, rather than reflected or transflected.
  • the liglit emitted from the emitting module 32 also passes through the opposite wall 41 of the fluid retaining medium 40, 40'.
  • Non-absorbed light which is successfully transmitted through the fluid retaining medium 40, 40' and the fluid 43 is collected, as much as possible, at a collector module 45. It is between the emitter module 32 and collector module
  • the fluid retaining medium 40 of the refillable container species is a bottle 40 or other container.
  • the apparatus of the refillable container species includes a bollle (or other container) holding and conveyor assembly
  • the containers 40 comprise an integral component of the invented apparatus itself, functioning as the optical cell by integrating the container into the optics.
  • the emitter module 32 of the residue detect species is adjustably mounted relative to the conveyor assembly 46 and fluid container 40 (as depicted by adjusting legs 31, 33) in order to adjustably direct the emitted light at and through the container and fluid 43 within the container. (See Fig. 9).
  • the flying brand species comprises, between the emitter module 32 and collector module 45 a fluid conduit (pipe) 40' which is the fluid retaining medium.
  • the tested fluid 43 is pumped through the conduit 40'.
  • the fluid conduit 40' is provided with transparent walls (observation ports) 48 at the section of conduit which is in line with the emitter module 32 and collector module 45, in order that emitted light from the emitter module passes through the transparent walls of the conduit, through the tested fluid 43 and on to the collector module 45.
  • transparent walls (observation ports) 48 at the section of conduit which is in line with the emitter module 32 and collector module 45, in order that emitted light from the emitter module passes through the transparent walls of the conduit, through the tested fluid 43 and on to the collector module 45.
  • the collector module 45 functions as tlie collector 14 (Fig. 5) of the invented apparatus and includes a collector lens 44 which collects, as much as possible, and focuses the transmitted light (or, in alternate embodiments, the reflected or transflected light) onto the collecting end of a second, quartz, quartz-glass fiber optic cable 17.
  • This fiber optic cable 17 is devided (see previous discussion) into "n" segments 18-1...18-n, each of which carries light lo one of "n” filter modules 20-1...20-n.
  • Each filter module 20 includes a narrow band-pass quartz filter 49-1...49-n which fillers Ihe collected light carried by the respective cable segment 18-1...18-n into filtered light at one of the chosen, profiling wavelengths.
  • each filter module 20-1...20-n Associated with each filter module 20-1...20-n is a photodiode light detector 51 and an amplifier 52.
  • the photodiode 51 and amplifier 52 provide the function of the detector 22 and signal conditioning amplifier 24 (see Fig. 5) by converting the detected, filtered light to a voltage output directly proportional to its intensity.
  • the amplifier 52 is an 8261FET amplifier with feed-back and compensation resistors which cooperates with the photodiode 51 to provide a O-N volt output signal which is directed along output cable 54 to a terminal 56a-56d at a terminal strip 55 for access by the recording device 26.
  • the recording device comprises a high-speed data acquisition system.
  • DAS Data Acquisition System
  • DT2800 board manufactured by Data Translation, and ASYST 1.53 Scientific Software package, compatible with the IBM ® PC/AT with 8007 math co-processor.
  • the DAS board 28 fits into a standard card slot of the IBM ® AT or XT.
  • the DAS digitizes the O-N volt analog signals from the filter/amplifier modules 20/24 utilizing direct memory access.
  • the processing device 26a calculates the chosen mathematical relationships among the data for each and all profiling wavelengths.
  • the light source 12 of these disclosed embodiments emits light continuously, during operation of the system, from the emitter module 32.
  • the emitted light is continuously collected at the collector module 45 and conveyed to separate filter modules 20-1...20-n, where the filtered light at each of the profiling wavelengths ( ⁇ 1 - ⁇ n) is converted to an electrical signal (that is, a voltage).
  • a voltage potential is always present, during operation of the system, at each of the terminals 56a-56d of the terminal strip 55.
  • the voltages which are always present at the terminals 56a-56d are looked-at (or "acquisitioned") by the recording device 26 at intervals. These intervals define the data acquisition points and the data acquisition period ("AP"). See, for example, Figs. 7 and 7A.
  • the signatures of Figs. 7 and 7A are defined by plotting the data acquired at each acquisition point.
  • the refillable container species includes a trigger device 58 which, in the disclosed embodiment, includes an electrical switch 59 (i.e. a microswitch) activated by a trigger wire 60. (See Fig. 8.)
  • the trigger device 58 is mounted at the conveyor assembly 46 at a point stationary relative to the emitter module 32 and collector module 45.
  • Alignment is such that, as a container 40 enters the path of the emitted light, the container strikes the trigger wire 60 thus closing switch 59.
  • the closed switch 59 is a signal to the recording device 26 to begin acquisitioning voltage data from the terminals 56a-56d.
  • the recording device 26 functioning as a data acquisition system, systematically acquires and records the voltage data from each terminal 56a-56d at a plurality of points in time.
  • the DT2000 DAS board 28 looks at terminal 56a, then 56b, then 56c, then 56d to acquire a first data point for each profiling wavelength; the DAS board looks again at terminal 56a, then 56b, then 56c, then 56d to acquire a second data point for each profiling wavelength; and so on, until the container 40 leaves engagement with the trigger wire 60 at which time the data acquisition period ends as to that container.
  • trigger wire 60 As another container 40 engages the trigger wire 60, data as to each profiling wavelength is again acquired and recorded at a plurality of points in time over a data acquisition period for that container. It is within the scope of the present invention to provide other forms of trigger devices 58, such as, but not limited to, capacitive or proximity sensors, or optical devices like an electric eye, or timed triggers which activate Data acquisition automatically at intervals coordinated with the speed of the conveyor assembly 46. In the flying brand species, data acquisition periods are preferably triggered by automatic timing or manual triggering, but not limited thereto.
  • data is acquired for each profiling wavelength in a sequential manner; that is, from terminal 56a, then 56b, then 56c, then 56d, wait time, then repeat.
  • t lie staggered acquisition periods "AP" of Figs. 7 and 7A.
  • data is acquired for each of the profiling wavelengths simultaneously at each data acquisition point; that is, from 56a, 56b, 56c, 56d simultaneously, record, wait time, repeat.
  • processing steps of the preferred embodiment are accomplished through operation of a software program by the processing device 26a. Once the mathematical relationships to be calculated have been chosen, the particular software program can be readily provided by one with ordinary skill in the art.
  • the comparing step of the preferred embodiment is accomplished by manual (visual) comparison of On-line Data to Control Data or, more preferably, by a computer device 26b executing appropriate software to function as a comparator. In either event, the preferred comparison involves determining the amount of deviation by which the processed On-line Data deviates from the corresponding, processed Control Data. If a processed On-line Data point deviates from the corresponding, Control Data point by more than a chosen, acceptable deviation, the data is determined not to "fit", for example, (compare
  • Example I In this example, the method of the present invention is utilized with the apparatus of the Refillable Container Species of Fig. 6 to determine if returned bottles contain contaminant.
  • STEP A - Non-contaminants are selected lo be a family of nonalcoholic beverages such as a cola, lemon-lime, orange, diet cola. Water is chosen as a nonconlaminant liquid.
  • STEP B - Using Spectrographic analysis as indicated with respect to Fig. 2, four profiling wavelengths have been determined to satisfactorily identify (or "Profile") and distinguish each of the non-contaminants. These profiling wavelengths are designated as ⁇ 1 , ⁇ 2 , ⁇ 3 , and ⁇ 4 . Appropriate filters 49-1..49-4 are placed in the filter modules 20-1...20- 4.
  • Control Fluid is defined as a solution of a selected beverage from the family of non-contaminants ("Beverage 1")' and water in concentration of 5% beverage to water, at, for example, ambient temperature and placed in a clear, previously unused, plastic bottle of the type being returned.
  • STEP C2-C5 - Control Data is acquired for the Control Sample as detailed above, with respect to Fig. 6.
  • the data in the example is taken over time. That is, 100 different readings (data acquisition points) are taken of the intensity at each profiling wavelength over the data acquisition period. In this example, the data acquisition period is approximately 50 milli-seconds and the data acquisition points were every 500 micro-seconds.
  • the plotted Control Data see Fig. 10A.
  • each control sample is passed through the light source, and control data is collected, a number of times (i.e. 25 times) to acquire an average value at each acquisition point and, thus, an average profile and average signature in order to compensate for possible equipment inconsistencies and inconsistencies in container orientation.
  • Control Sample is revised and Control Data is acquired for the revised sample. This step is repeated for numerous revised samples.
  • the revisions of this example include changing concentration such that Control Data is acquired on Control Samples of 3.7%, 2.5%, 1.2%, 0.6% and 0.3% beverage lo water, respectively, all at ambient temperalure. (See plotted Control Data of Figs. 10B-10F.) Revisions of this example do not include changing temperatures at each of the concentration levels.
  • STEP C7 - The acquired Control Data is processed to provide a series of topographies of processed Control Data as depicted by the plots of Figs. 11A - 11D.
  • STEP D1 - The On-line Fluid of this example is defined (prepared) by introducing water into each of the returned bottles 40 on the conveyor assembly 46 thus defining, in each bottle, an unknown fluid (such as a solution or mixture) of water and some unknown substance(s).
  • an unknown fluid such as a solution or mixture
  • On-line Fluid in accordance with the above described procedures, as the conveyor moves the bottles past the trigger device 50 and the emitted light beam.
  • the On-line data of each bottle oT On-line Fluid is acquired over time as was the Control Data.
  • On-line data for one bottle of On-line Fluid see Fig. 12.
  • STEP D6 The acquired On-line Data for the respective bottle of On-line Fluid is processed in the same manner as the Control Data to provide processed, On-1 ine Data as depicted by the plots of Figs. 12A - 12D.
  • STEP E The processed, On-line Data is compared to the processed, Control Data to "fit" within chosen deviations.
  • one comparison is made between the peak to peak distances of the processed, On-line Data (Figs. 12A, 12B) and of each signature within the respective topography (Figs.11A,
  • STEP F The On-Line fluid in each bottle is, thus, determined to be contaminated or not.
  • signal is, for example, directed to a reject mechanism 63 to remove the specific bottle from the conveyor assembly 46.
  • Example II Example II.
  • the method of the present invention is utilized with the apparatus of the Flying Brand Species of Fig. 6A to determine iF a fluid within the fluid conduit 40', at the point of the observation port 48, is the intended fluid (that is, the STEP A -
  • the non-contaminant is identified to be a particular nonalcoholic beverage ("Beverage 4").
  • Other substances which will purposely be pumped througii tlie conduit from time lo time, such as Beverage 1, Beverage 2, Beverage 3 are, for purpose of this example, considered to be "Contaminants" since they are not the "intended fluid".
  • profiling wavelengths are ascertained which are determined lo satisfactorily identify and distinguish the normal contaminants and non-contaminant. These profiling wavelengths are designated as ⁇ 1 , ⁇ 2 , ⁇ 3 , ⁇ 4 .
  • Appropriate filters 49-1...49-4 are placed in the filter modules 20-1...20-4.
  • SIEP C1 - The Control Fluid is defined as 100% pure Beverage 4, and placed in the clean, purged. conduit.
  • STEP C7 The acquired Control Data is processed to provide topographies of processed, Control Data as depicted by the plots of Figs. 14A-14C.
  • STEP D1 - During daily operation of the bottling facility, fluid is piped through the conduit 40' (preparation of the On-Line Fluid) on its way to consumer packaging 62 (see
  • SIEP D2-D5 - On-line Data is acquired as to On-line Fluid in the conduit at any given time by automatically or manually activating the DAS Board 28, and, thus, the Data acquisition function of the apparatus of Fig. 6A, in accordance with the above described procedures.
  • the data was acquired over a specific data acquisition period as was the Control Data.
  • On-line Data for one acquisition period, see Fig. 15.
  • STEP D6 The acquired On-line Data for the Fluid at the observation port 48 at the given acquisition period is processed in the same manner as the Control Data to provide processed, On-line Data as depicted by the plots of Figs. 15A- 15C.
  • STEP E The processed, On-line Data is compared to the processed Control Data to "fit" within chosen deviations. In this example, one comparison is made between the peak to peak distances oT the processed, On-line Data (Fig. 14A) and of each signature within the topography of processed Control Data
  • FIG. 15A Another comparison is made between the slope of the first normalized and second normalized, processed data of the On-line Fluid (Figs. 14B, 14C) and tlie slope of corresponding processed Control Data (Figs. 15B, 15C).
  • the On-line Fluid passing the observation port 48 is determined to be contaminated since it does not "fit" the control data; that is the fluid is not the 100% pure Beverage 4.
  • STEP G - Signal is directed to a flow control device 63' to channel the On-line Fluid away from the consumer packaging 62, for example to a waste drain 64 or alternate containers 64.
  • a flow control device 63' to channel the On-line Fluid away from the consumer packaging 62, for example to a waste drain 64 or alternate containers 64.
  • the resultant, filtered light at each of the profiling wavelengths is constantly monitored to record the intensity of light al each wavelength. If at any time during the data acquisition period, there is a change in intensity at one or more of the wavelengths, (see Fig. 16) which change exceeds a predetermined maximum, the apparatus of the present invention automatically determines that a change has occurred in the fluid 43 pumped through the conduit 40'. Upon such determination, appropriate flow controls are activated in accordance with a preplanned sequence.
  • all control samples and on-Line samples are retained in containers 40 (reference the refillable container species) of a similar tint or color.
  • one or more signal wavelengths are defined which correspond to the wavelengths of the tints of colored bottles other than the tint of the bottles used in the control samples. For example, if control samples were retained in clear bottles, one signal wavelength would correspond to the green tint of a lemon-lime beverage container, etc.
  • the subject container is automatically routed in accordance with a preplanned control scheme, thus minimizing inaccuracies as to the relative intensities of the profiling wavelengths due to the container tint.
  • collected, stored and processed control data includes data relating to control samples retained in various, differently tinted containers 40.
  • the apparatus of the present invention Upon detection of appropriate absorption in one of the signal wavelengths during, acquisition of On-Line data, the apparatus of the present invention selectively compares the processed On-Line data to processed control data from control samples retained in containers of the corresponding tint.
  • a "servo channel" wavelength is defined at a point along the spectrum where absorption/scattering curves of all of the identified non-contaminants and selected contaminants are substantially similar.
  • the Servo Channel is utilized to provide a method of compensating for intensity wavelength spectrum shifts.
  • the instrument (practicing the apparatus of the present invention) is periodically calibiated to a known standard (for example, D1 water) by acquiring light intensity data at each of the profiling wavelengths and at the Servo wavelength, for the known standard.
  • the intensity value for data acquired during this calibration step (the "pre-use value") is compared to the known value for the standard at each wavelength to calculate a gain factor ("G") for each profiling wavelength, and also for the Servo Channel.
  • G gain factor
  • LG known value/pre-use value.
  • the instrument is the placed in use to acquire control data and/or on-Line data in accordance with the present invention.
  • the actual data value of intensity acquired at the Servo Channel is compared to the expected value at the Servo Channel to calculate a gain factor prime ("G"') lo be applied universally to data at all wavelengths. That is, the "expected value" at the Servo Channel is the actual data acquired at the Servo Channel multiplied by the gain factor ("G").

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Abstract

Un procédé et un appareil permettent d'identifier et de distinguer des fluides et de reconnaître des contaminations d'un fluide au moyen d'une analyse spectrographique d'échantillons témoins de fluides connus, suivie de l'analyse spectrographique de fluides inconnus afin de générer des signatures optiques, des empreintes digitales et/ou des profils de données et des données traitées concernant l'intensité relative de la lumière à des longueurs d'ondes sélectionnées. La comparaison des différentes signatures, empreintes digitales et/ou profils fournit des informations qui permettent de déterminer si des fluides inconnus sont contaminés ou non. Une commande appropriée d'une opération peut alors être effectuée et/ou mise en ÷uvre.
PCT/US1989/001818 1988-04-13 1989-04-28 Systeme de contrôle et/ou d'identification de fluides WO1990013810A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/US1989/001818 WO1990013810A1 (fr) 1988-04-13 1989-04-28 Systeme de contrôle et/ou d'identification de fluides

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US18116088A 1988-04-13 1988-04-13
PCT/US1989/001818 WO1990013810A1 (fr) 1988-04-13 1989-04-28 Systeme de contrôle et/ou d'identification de fluides

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2704650A1 (fr) * 1993-04-27 1994-11-04 Savoie Universite Procédé et dispositif pour la détection et l'identification instantanées d'une entité.
EP1241467A2 (fr) * 2001-03-14 2002-09-18 Hitachi Engineering Co., Ltd. Appareil d'inspection et système d'inspection des corps étrangers dans des conteneurs remplis avec un liquide
WO2021069033A1 (fr) * 2019-10-11 2021-04-15 Gunther Krieg Dispositif et procédé d'identification de substances dans la composition fluide

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300689A (en) * 1978-01-16 1981-11-17 Hoffmann-La Roche Inc. Dual wavelength spectrophotometer for ampoule leak detection and content inspection
US4367041A (en) * 1980-08-25 1983-01-04 Micromeritics Instrument Corporation Chromatograph detection system

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4300689A (en) * 1978-01-16 1981-11-17 Hoffmann-La Roche Inc. Dual wavelength spectrophotometer for ampoule leak detection and content inspection
US4367041A (en) * 1980-08-25 1983-01-04 Micromeritics Instrument Corporation Chromatograph detection system

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2704650A1 (fr) * 1993-04-27 1994-11-04 Savoie Universite Procédé et dispositif pour la détection et l'identification instantanées d'une entité.
WO1994025837A1 (fr) * 1993-04-27 1994-11-10 Universite De Savoie Dispositif integre pour la detection et l'identification instantanees d'une entite
US5528363A (en) * 1993-04-27 1996-06-18 Universite De Savoie Integrated device for instantaneous detection and identification of an entity
EP1241467A2 (fr) * 2001-03-14 2002-09-18 Hitachi Engineering Co., Ltd. Appareil d'inspection et système d'inspection des corps étrangers dans des conteneurs remplis avec un liquide
EP1241467A3 (fr) * 2001-03-14 2002-12-11 Hitachi Engineering Co., Ltd. Appareil d'inspection et système d'inspection des corps étrangers dans des conteneurs remplis avec un liquide
US6937339B2 (en) 2001-03-14 2005-08-30 Hitachi Engineering Co., Ltd. Inspection device and system for inspecting foreign matters in a liquid filled transparent container
WO2021069033A1 (fr) * 2019-10-11 2021-04-15 Gunther Krieg Dispositif et procédé d'identification de substances dans la composition fluide

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