WO1990010888A1

WO1990010888A1 - Variable density optical filter

Info

Publication number: WO1990010888A1
Application number: PCT/US1990/001018
Authority: WO
Inventors: Duane A. Haven
Original assignee: Greyhawk Systems, Inc.
Priority date: 1989-03-03
Filing date: 1990-03-05
Publication date: 1990-09-20

Abstract

A light scattering liquid crystal transducer in which the degree of light scattering is controlled by impressing an electric field (60) across the cell (42) during and immediately after the application of a high-energy short duration thermal pulse (V1) applied to the entire viewed region of the cell (42). This allows full gray scale to be achieved as a function of applied voltage.

Description

VARIABLE DENSITY OPTICAL FILTER

BACKGROUND OF THE INVENTION

Field of the Invention. The present invention relates to thermo optic cell image projection systems. More specifically, the present invention relates to applying a uniform variable electric field across the thermo optic cell to produce a uniform variable darkening of the thermo optic cell.

Summary of the Prior Art. Liquid crystal cells are useful in display, optical processing, printing and related image projection applications. In these applications they serve as light valves or light modulators which control the flow of light from a light source to a receiver or receiv¬ ing surface. When suitable spatial electronic addressing means is incorporated in a liquid crystal light valve system, spatially varying patterns can be written on the liquid crystal layer. The liquid crystal cell then becomes a spatial light modulator. When suitable illumination optics, typically including a light source and optical con¬ denser, and suitable projecting optics, typically including a projection lens with appropriate aperture, are included in a liquid crystal light valve system, the liquid crystal cell then becomes an electronic slide which determines and controls the image projected onto a display screen, photo¬ sensitive detector array or photosensitive writing medium for display, optical processing, and printing applications, respectively. The spatial variations of the image on the liquid crystal cell virtually always correspond to differences in the molecular orientation (different textures) of the liquid crystal in different areal regions of the liquid crystal layer. The spatially varying differences in molecular orientation are converted into spatially varying light intensity variations by means of suitable polarizing optics or suitable apertures to selectively pass and block scattered or refracted light from these spatially different regions. The various possibilities have been reviewed in detail (see F.J. Kahn, "The Molecular Physics of Liquid Crystal Devices," Physics Today, May 1982).

In one mode of operation the entire image area of the liquid crystal cell is switched, typically by electrical or thermal means, into a texture with uniform order (or dis¬ order) thereby providing a uniform image background. One or more spatially varying images with different textures are then superposed, by the spatial addressing means, onto the uniform image background in order to create an image on the liquid crystal cell, and hence on the receiving sur¬ face, with the desired spatial variations in intensity and contrast.

Referring to Figure 1, cross sectional view of a typical prior art liquid crystal cell 10 is shown. The cell 10 is filled with liquid crystal 20. A suitable liquid crystal is smectic A liquid crystal. The crystal is contained on two sides by a first and second electrode 16 and 18. The electrodes 16 and 18 are substantially parallel plates made of transparent material. A suitable material for the electrodes is indium-tin-oxide. The elec¬ trodes 16 and 18 serve to allow application of an electric field in a direction essentially normal to the liquid crystal layer while allowing projection light to be trans¬ mitted through the liquid crystal layer. Adjacent the electrodes 16 and 18 are alignment layers 17 and 19 that serve as dielectric layers for electrical blocking and/or liquid crystal molecular alignment. The liquid crystal cell 10 is further comprised of a first and second plane of glass 12 and 14. Among other things, the glass permits the passage of light, supports the electrodes, and provides integrity to the liquid crystal cell.

In the image projection system context, liquid crystal cell image projection systems incorporate means for creat¬ ing an image on a liquid crystal cell and then use the created images as a mask for projection exposure of photo- sensitive media for photolithographic processing such as fabrication of printed wiring boards. One of the initial steps in producing an image on a liquid crystal cell involves forming a uniform texture of scattering centers. Scattering centers refer to the characteristic of the liquid crystal material in the cell 10. Scattering centers scatter and depolarize light. Conversely, liquid crystal regions without scattering centers transmit light without deflecting it or depolarizing it. A uniform texture of scattering centers is a microscopic volume of liquid crystal cell 10 which scatters incident light.

The uniform texture of scattering centers is then "drawn" on by a laser beam to create an image. The laser beam forms an image in the uniform texture of scattering centers by creating non-scattering regions wherever it is impinged. The process of impinging laser light on the uniform texture of scattering centers to produce non- scattering centers is known in the art, (F. J. Kahn, "Locally Erasable Ther o-Optic Smectic Liquid Crystal Stor¬ age Displays," U.S. Patent 3,796,999 dated March 12, 1974).

Following creation of an image either by producing scattering centers within a non-scattering region, or by creating non-scattering regions within a uniformly darkened background, it is necessary to erase or refresh the liquid crystal cell in order to prepare it for generation of subsequent images. The prior art contains two methods of rapidly produc¬ ing large area uniform scattering textures by methods other than laser-scanning which is relatively slow. Both of these methods involve the use of electrical energy and as will be discussed below, are not capable of producing the uniform variable darkening required in high resolution applications. In the first method, an electrical current pulse through the electrode is used to generate heat in the liquid crystal, the electrode heating method. In the second method, an electrical current pulse through the liquid crystal is used to create a turbulent material flow in the liquid crystal, the current-turbulence method. In the first method (see File A-44550, allowed July 1, 1988) a signal from a voltage source 22 is applied across one of the electrodes. This method is illustrated in Figure 1 where the voltage signal from the source 22 is applied across the electrode 18. In this embodiment, short electrical pulses are used to thermally induce a uniform texture of scattering centers over the substantially large surface area of the cell 10. The result, in an image pro¬ jection system, is that the short electrical pulses result in a fast darkening of the receiving surface. The electri¬ cal current sent through the electrode 18 produces thermal energy which raises the temperature of the liquid crystal material 20. Also, because it is a short pulse, the energy does not have time to spread. This lack of spreading facilitates rapid cooling which is responsible for the creation of uniform scattering centers. Physically, the liquid crystal is heated to a temperature at which it is an isotropic state. It then cools rapidly, quenching in some of the disorder of the isotropic state and thereby produces a high density of scattering centers.

In an alternate embodiment of the prior art, the elec¬ trical pulses are applied across the liquid crystal 20. In this embodiment, following the work of Tani (C. Tani, Applied Physics Letters 19, 241-2, October 1, 1973. "Novel Electro-Optical Storage Effect in a Certain Smectic Liquid Crystal") , a dc electric field applied across a thin layer of smectic A liquid crystal causes a current to flow in the liquid crystal. The current produces a turbulent flow of the liquid crystal analogous to the well-known dynamic scattering effect in nematic liquid crystals. This turbu- lence can produce a high density of optical scattering centers in smectic liquid crystal cells with appropriate conductivity and appropriate orienting layers on the substrates, and can also be produced by low frequency ac voltages as well a dc voltages. See for example, W.A. Crossland and S. Canter, "An Electrically Addressed Smectic Storage Device," SID '85 Digest, pp. 124-126 (1985) and W.A. Crossland, J.H. Morrissy, and B. Needham, "Method for Preparing and Operating a Smectic Liquid Crystal Display Cell Having Indefinite Storage Properties, U.S. Patent 4,139,273 (February 13, 1979).

There are two significant problems, however, with these two methods of creating and erasing uniform texture of scattering centers. Generally speaking, the first of these relates to producing images of high resolution. The second relates to degradation of the liquid crystal cell caused by electrical stresses.

Addressing the first problem, the generation of uniform texture of scattering centers produces a relativ¬ ely constant magnitude of scattering. Basically, the liquid crystal material is heated to a high temperature by the electric pulse. As the cell cools the disorder created by the electrically induced thermal pulse is quenched into the cell. This level of disorder is responsible for uni¬ form texture of scattering centers, but it produced a constant level of darkening. That constant level of darkening is too dark for high resolution application or too light for adequate contrast with the created image.

In high resolution applications it is desirable to have a lighter background, ie., a background with less scattering effect. This allows for thinner lines to be drawn on the liquid crystal cell. Given the dark back- ground of the electrically created cell, a thin line drawn across the screen is obscured by the closely and densely surrounding scattered centers. Thus, it is desirable to efficiently control the magnitude (or density) level of the cell in the darkening process.

Control of the level of darkening may be accomplished by reducing or increasing the amount of energy (electrical or optical) required to obtain the desired level of darken¬ ing. However, the scattering centers produced by any level of input energy have been shown (see F.J. Kahn et al, "A Paperless Plotter Display System Using a Laser Smectic Liquid-Crystal Light Valve," SID 87 Digest, pp. 254-257), to lie in a layer immediately adjacent to the surface where the conversion of optical or electrical energy into the terminal pulse takes place. The thickness of this layer is proportional to the level of input energy. That is, low energy produces a thin layer with few scattering centers (low optical density) and high energy produces a thick layer with many scattering centers (high optical density) .

Since the generation of scattering centers is subject to many variables including the resistivity of electrodes, concentration of additives and dopants and local environ¬ mental variations, it is not practical to generate thin layers with the good uniformity of darkening required for fine lines and high resolution. The preferred operating mode would be to apply energy sufficient to allow darkening of the cell to an initial level considered to be a maximum required for any image. Then by imposing the electric field reduce the optical density as required to produce thin, high resolution lines with the highest possible contrast.

In the current-turbulence method, the liquid crystal typically must have conducting additives or dopants in it, in order to allow enough current flow to create the scat- tering center inducing turbulence. The passage of current through the liquid crystal, however, typically results in electrochemical processes which cause the devices to fail. Thus other dopants, such as redox dopants, must be added to the liquid crystal to counteract these electrochemical processes and extend lifetime.

Additionally, processes must be developed to distri¬ bute these dopants uniformly through the liquid crystal cell and special low resistance contacts or busbars (re¬ quiring expensive and yield reducing patterning steps in the fabrication process) . Electrodes must be provided in order to minimize voltage drops that would result in non- uniform current distribution and undesirable heating. Thus, implementing either of these methods results in considerable additional expense in fabrication of the liquid crystal cells.

Finally, to erase the previously applied background darkening together with the overlaying image requires application of an electric field. Erasure of scattering centers by application of an electric field during slow cooling of the liquid crystal is well known in the art. However, this process is too slow for practical use. Erasure of scattering centers by scanning with a laser is described by Fredric J. Kahn, in U.S. Patent No. 3,796,999 issued March 12, 1974. This is a pointwise erasure process and is also slow.

Fast erasure of a darkened background together with the overlaying image is described in reference Fredric J. Kahn et al, "A Paperless Plotter Display System Using a Laser Smectic Liquid-Crystal Light Valve," SID 87 Digest, pp. 254-257. The technique uses very high electrical fields ranging from 10-15V/micrometer. This high field causes electrical and electro-chemical stress which reduces the life of the liquid crystal cell. SUMMARY OF THE INVENTION

Accordingly, it an object of the present invention to provide an image projection system capable of high resolu¬ tion imaging.

It is another object of the present invention to provide an image projection system wherein the background level of scattering can be varied uniformly to promote higher resolution of imaged features.

It is still another object of the present invention to provide an image projection system wherein the amount of electric current passed through the thermo optic cell is greatly reduced, thereby significantly extending the life of the thermo optic cell.

The attainment of these and related objects may be achieved through use of the novel variable uniform density optical filter herein disclosed. A variable uniform density optical filter in accordance with this invention has a light scattering liquid crystal transducer in which the degree of light scattering is controlled by impressing an electric field across the cell during and immediately after the application of a high-energy short duration thermal pulse applied to the entire viewed region of the cell. This allows full gray scale or shade to be achieved as a function of applied voltage.

The attainment of the foregoing and related objects, advantages and features of the invention should be more readily apparent to those skilled in the art, after review of the following more detailed description of the inven¬ tion, taken together with the drawings, in which:

BRIEF DESCRIPTION OF THE DRAWINGS

Figure 1 illustrates alternative darkening embodiments of the prior art.

Figure 2a-e is an illustration of the preferred embodiment.

Figure 3a-e is an illustration of the preferred embodiment.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT Referring to Figure 2, a liquid crystal cell arrange¬ ment 40 is illustrated. The use of liquid crystal cells in projection systems is well known in the art, see pending U.S. Patent No. 4,799,770, entitled "Liquid Crystal Cell for Image Projection and Method of Operating Same," by Frederic J. Kahn, issued January 24, 1989. Liquid crystal cells fall within the class of thermo optic cells. Thermo optic cells are cells whose optical properties are effected by temperature. In general, a thermo optic cell can be used for the projection system of the preferred embodiment.

In the projection context light is either transmitted through or reflected off of the cell 42 on to an image receiving surface (not shown) . The image impinged on the image receiving surface is created by the light that was either transmitted through or reflected off of the cell 42, respectively. The extent to which the individual crystal centers in the cell scatter light determines the overall transmission or reflection properties of a cell. The following text is addressed primarily toward transmissive liquid crystal cell, but could equally be applied to reflective cell.

Liquid crystal material is provided internal to the liquid crystal cell 42. In general, liquid crystal is a material that possesses properties of molecular ordering useful in the construction of light modulation devices. The anisotropic liquid crystal molecules will align to properly prepared surfaces and exhibit ordering within the bulk material. They will also align to applied electric fields. Material exhibiting positive dielectric anisotropy will align with the molecular axis parallel to the applied field. A liquid crystal representative of the present inven¬ tion will possess phases and degrees of ordering that are temperature dependant. That is, the smectic phase at lower temperature, will be more solid like than the nematic cholesteric phase at a higher temperature. In the iso¬ tropic phase, the material will essentially have no ordering in the bulk, but the molecules will still respond to an externally applied electric field. Indeed, since the material in the isotropic phase has no intrinsic ordering to overcome, the electric field required to orient the molecules will be lower than in the nematic or smectic phases.

It has been shown that when these described materials are cooled from the isotropic phase, the resultant smectic phase has two metastable configurations. If the material is cooled under conditions where a sufficiently high elec¬ tric field is applied, the smectic phase will be homeotro- pically aligned and will transmit light without distortion. If no field is applied, and the material is rapidly cooled, a light scattering texture is formed. Upon this texture of scattered centers an image can then be created. This is usually done with a laser light, but alternative methods, known in the art, are available.

As stated in the previous section, however, prior art devices used to erase or modify the light scattering texture require substantially high electric fields in the order of 10-15V/micrometer. This substantially high electric field greatly increases the risk of developing a short across the liquid crystal cell 42 and reduces the cell lifetime through electrochemical degradation. The present invention solves this problem by greatly reducing the amount of electric field which need be applied across the cell 42 to obtain desired scattering texture to the range of l-5V/micrometer. The present invention also greatly increases the resolution at which image created on the cell 42 (or "object" in the optic projection context) can be reproduced at the image receiving surface, as will be discussed below.

Voltage pulses V-^, Figure 2b, is applied across the transparent conductor 44 of the cell 40. The pulse V_]_ is sufficient magnitude to quickly heat the transparent con¬ ductor 44 and the adjacent liquid crystal 46 from a first temperature to a second temperature. Figure 2c. The rapid heating and cooling of the liquid crystal will form scat¬ tering centers in accord with the teachings of U.S. Patent 4,799,770 issued to Frederic J. Kahn for a "Liquid Crystal Cell for Image Projection and Method of Operating Same".

At the completion of the voltage pulse Vτ_, second voltage pulses V2, Figure 2d, are impressed across the cell using as electrodes, transparent conductors, 52, 44. This voltage results in an electric field essentially normal to the plane of electrodes 52, 44. As earlier described, liquid crystal materials of positive dielectric anisotropy will tend to align parallel to this applied field but will be prevented from doing so until the second temperature is reached or exceeded. The degree of ordering within the liquid crystal is directly proportional to the magnitude of the electric field.

The field is maintained until the liquid crystal has cooled to the first temperature. This causes the level of light scattering as determined by the magnitude of the electric field to be maintained. Referring to Figure 2e, a magnitude of electric field of IV/micrometer will cause only small change in the level of light scattering ob¬ tained, resulting in a relatively dark background. A 5 volts/micrometer will induce no scattering to form as the liquid crystal cools to the first temperature. Inter¬ mediate levels of electric field will result in inter¬ mediate levels of light scattering.

The weaker the applied electric field the greater the darkening of the cell, or in other words, the greater the accumulation of a uniform texture of scattering centers. Conversely, the stronger the applied field the greater the degree of ordering of the liquid crystal resulting in a lighter texture of scattering centers. This ability to vary background intensity or, the texture of light scatter¬ ing centers is crucial to producing high resolution images.

Essentially, when a fine feature, for instance 3/1000 inch, is written on a dark background, that background level generated by the prior art normal thermal pulse dark- ening methods, the feature is obscured by the pervading darkness of the background. Thus, drawing a circuit board connection of 3/1000 of an inch would produce a significant threat of the line not being drawn properly and a resulting open circuit arising in the circuit.

By being able to lighten the overall darkness of the background more precisely, minimum features can be drawn with more exacting detail. The range of electric field applied to the cell during cooling, to produce the desired lighter background is l-5V/micrometer. It may be applied during the thermal pulse and remain thereafter. The elec¬ tric field serves to freeze a certain amount of disorder injected by the thermal pulse. The specific amount of the disorder frozen is determined by the magnitude of the electrical field.

Referring to Figure 3a-e, another method of inducing the thermal pulse of the preferred embodiment is shown. The arrangement 62 is essentially the same as arrangement 40 except an optical source is used to generate the thermal pulse. The use of optical sources to provide thermal pulse darkening is discussed in more detail in pending U.S. patent application. Serial No. , entitled PULSE

OPTICAL DARKENING, filed March 3, 1989, by Frederic J. Kahn. An optical pulse can generate a sufficient thermal pulse on its own or dopants can be placed in the liquid crystal and/or surrounding material to facilitate thermal absorption and conversion. The transparent substrates 54 and 56 support and pro¬ tect the inner layers of the cell 62 while unobstructively transmitting light. The light source 68, comprised of a flash tube 70 and reflective optics 72, impinges optical energy, Figure 3b, upon the cell 42 which is converted to thermal energy heating the cell 42, Figure 3c. As the cell 42 cools, an electric field, Figure 3d, is applied to the cell 62 by the electrical source 60 through the electrodes 44 and 52 producing the above described results; those results being variable uniform background scattering, Figure 3e.

In summary, the present invention provides for a controlled optical density background field on which subsequent images may be written. The preferred writing method is with a laser beam.

It should also be apparent to those skilled in the art that various changes in form and details of the invention as shown and described may be made. It is intended that such changes be included within the spirit and scope of the claims appended hereto.

Claims

WHAT IS CLAIMED IS:

1. A thermo optic cell assembly of the type including a layer of liquid crystal material, comprising: means for inducing, by heating and cooling, scattering centers in said liquid crystal material; and means for controlling the degree of formation of said scattering centers ranging from a complete background of scattering centers to a clear background.

2. The apparatus of claim 1 wherein the scattering center control means comprises an electrical field generating means for applying an electric field across the layer of liquid crystal material as said material undergoes cooling from a first temperature induced by said heating means to a second lower temperature.

3. The apparatus as in claim l wherein said liquid crystal material is heated by electrical means.

4. The apparatus as in claim 1 wherein said liquid crystal material is heated by optical means.

5. The apparatus as in claim 2 wherein said electrical field is applied during the heating and of said liquid crystal material and for a predetermined period as the crystal material is cooled.

6. A thermo optic cell assembly of the type including a layer of liquid crystal material bonded by transparent electrodes, comprising: means for inducing, by heating and cooling, scattering centers in said liquid crystal material; and means for applying an electric field between said transparent electrodes as said liquid crystal material is heated and cooled to thereby control the number of scatter¬ ing centers formed during cooling of said liquid crystal material.

7. Apparatus as in claim 6 wherein said liquid crystal material is heated by applying electrical heating energy to one of said conductive layers.

8. The apparatus as in claim 6 wherein means are provided for applying optical energy to said liquid crystal material to heat the material.

9. The method of operating a thermo optic cell assembly of the type including liquid crystal material and to form a variable density filter wherein said material is maintained at a first temperature, including the steps of: providing thermal energy to heat said liquid crystal material to a second temperature and allowing said liquid crystal material to cool to said first temperature; and aligning said liquid crystal material during the heating and the cooling cycles to control the number of scattering centers found during cooling.

10. The method as in claim 9 wherein said aligning step comprises applying an electric field across liquid crystal material as said cell cools from said second temperature to said first temperature.

11. The method of claim 10 wherein the intensity of said electric field is controlled to control the number of scattering centers formed during the cooling cycle.

12. The method as in claim 9 wherein the liquid crystal material is heated by electric heating.

13. The method as in claim 9 wherein the liquid crystal material is aligned is heated by optical means.

14. The method as in claim 10 when the electric field is applied simultaneously with the heating pulse, whereby the amount of electric field that is needed to modulate scattering is reduced thereby causing less stress to the cell and prolonging the life of the cell.