WO1988000133A1 - Lining material for duct - Google Patents

Lining material for duct Download PDF

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Publication number
WO1988000133A1
WO1988000133A1 PCT/JP1986/000336 JP8600336W WO8800133A1 WO 1988000133 A1 WO1988000133 A1 WO 1988000133A1 JP 8600336 W JP8600336 W JP 8600336W WO 8800133 A1 WO8800133 A1 WO 8800133A1
Authority
WO
WIPO (PCT)
Prior art keywords
tubular
lining material
cloth
woven fabric
adhesive
Prior art date
Application number
PCT/JP1986/000336
Other languages
French (fr)
Japanese (ja)
Inventor
Masakatsu Hyodo
Isaburo Yagi
Original Assignee
Ashimori Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ashimori Kogyo Kabushiki Kaisha filed Critical Ashimori Kogyo Kabushiki Kaisha
Priority to DE19863690685 priority Critical patent/DE3690685T1/de
Priority to PCT/JP1986/000336 priority patent/WO1988000133A1/en
Priority to NO87873635A priority patent/NO873635L/en
Publication of WO1988000133A1 publication Critical patent/WO1988000133A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L55/00Devices or appurtenances for use in, or in connection with, pipes or pipe systems
    • F16L55/16Devices for covering leaks in pipes or hoses, e.g. hose-menders
    • F16L55/162Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe
    • F16L55/165Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section
    • F16L55/1656Devices for covering leaks in pipes or hoses, e.g. hose-menders from inside the pipe a pipe or flexible liner being inserted in the damaged section materials for flexible liners

Definitions

  • the present invention relates to a gas pipe, a water pipe, a sewer pipe, a laying line for a power line, a communication line, and the like, and a lining for a pipe buried mainly underground, such as an oil oil line. More specifically, the present invention relates to a nonwoven fabric having a special shape inside a hermetic tubular woven fabric which has a synthetic resin skin on the outer surface and is inserted into the pipe while being turned upside down by fluid pressure.
  • the present invention relates to a lining material for a pipeline, which has a cloth, and has properties such as a repelling property and a form-retaining property of outside water, as well as a singing property required for a conventional lining material. ,
  • This method does not require excavation of pipes over the entire length, and can be carried out only by forming manholes only at both ends of the pipe section to be lined. Lining j?
  • the work itself can be performed on a long pipeline in a short time, and it can be performed even on a pipeline with many bends. This is an extremely excellent method.
  • the lining used in the construction method is made of thin, flexible plastic tubing, woven or non-woven fabric in a tubular shape, and its outer surface is air-tight and water-tight.
  • Various materials have been proposed, such as a fibrous lining material formed with a material.
  • Japanese Patent Publication No. 55-43890 (British Patent No. 1,449,455) discloses an impermeable membrane on felt and / or fabric and a material made of a flexible foaming agent. A lining material composed of an enclosed flexible resin-absorbing material is disclosed.
  • Japanese Patent Publication No. 58-33098 discloses that this impermeable membrane, which is made of a flat web laminate composed of a resin absorbing layer having an impermeable layer on one side, comes to the outside.
  • a lining j-forest that has a tubular form, both ends are traversed with a thread, and then the entire suturing surface is covered with a sealing rib or coating, and a method for producing the lining.
  • Japanese Patent Application No. 58-1 0236-1 discloses that a tubular woven fabric in which a warp and a weft of synthetic fiber are woven in a tubular form has an internal void inside or outside and has a predetermined thickness. It describes a pipe liner in which a tubular cloth having a high degree of flexibility is laminated and an airtight layer of a synthetic resin is formed on the outer surface thereof.
  • the above-mentioned pipe line method is applied to a pipe for transporting a fluid such as a gas pipe, a water pipe, a sewer pipe, and an oil line
  • a fluid such as a gas pipe, a water pipe, a sewer pipe, and an oil line
  • the lining was required to have no leakage of the transport fluid, flexibility to be able to follow the curved part of the pipeline, strength to withstand the pressure of the internal fluid, durability of the coating, etc.
  • the pipe lining method of the above type the lining material has been required to have various characteristics depending on the environment of the pipeline to be applied, the nature of the land, etc. . At present, the following properties are required for lining materials.
  • the water resistance and hardness of the adhesive are important for the lining material applied to the pipeline to have external water pressure retention. It is also necessary that this adhesive has a sufficient thickness. Therefore, the lining material is required to include a sufficient amount of adhesive.
  • this type of adhesive has been used for epoxy resin and unsaturated. Reester resin, acryl resin, urethane resin, etc. are used, but pipes may be laid in places where groundwater can enter. Therefore, even in water, the curing reaction proceeds without being hindered and achieves adhesion, and even after curing, the adhesive strength is reduced due to the effect of water, and the strength is required. .
  • unsaturated polyester resins and acrylic resins that use peroxide as a curing agent may not cure in the presence of water. , I like it. It is also desirable to use a solvent such as styrene monomer. ⁇ Resin-based resin can be cured in water, but it can be cured. '(' Adjustment of the time required for administration is troublesome, and the monomer content is water-soluble. It is also preferable because it can cause environmental pollution, so the adhesive suitable for the lining material used in this type of pipeline is a epoxy resin, and the curing agent is also a medium However, it is preferable to use aromatic or aliphatic ⁇ liamin because it can be hardened even in water.
  • the lining material supports the pressure of the fluid when the line breaks, so it must be able to withstand that pressure. Also lining! ? When applying the material to the pipe, it is necessary to turn the material inside out.) The fluid pressure must be sufficient to prevent the lining material from breaking down. I do.
  • the conventional lining material described above can satisfy some of these necessary properties, but satisfies all of these properties.
  • the nonwoven fabric itself has a small change in strength, and thus lacks seismic isolation, and lacks any measures to ensure the impregnation with the epoxy resin. Due to the non-woven fabric, the internal resistance is low, and any means can be taken to improve the adhesive strength between the resin film and the fibrous layer.
  • the lining material described in Japanese Utility Model Application Publication No. 56-3619 and Japanese Patent Application Laid-Open No. Sho 56-8229 is basically made of cloth. Significantly, it is possible to further increase the strength by changing the manufacturing method. Therefore, seismic isolation and internal pressure resistance are large, but it is difficult to increase the thickness of the woven fabric. For general clothing, it is not difficult to obtain a thick one by devising the weave.
  • the tubular woven fabric of the lining material is woven in a tubular shape using a circular loom, but the circular loom can form a woven fabric having a complicated structure. As described above, shika must also be woven with great strength and thick, and like a thick garment for clothing, it can be thickened with a core yarn or backing yarn.
  • Thick yarn can be used to increase the thickness, but the rigidity of the yarn makes it difficult to turn it over when applying a lining material to a pipeline, and irregularities on the fabric surface Increases the fluid resistance of the fluid to be transported over a large distance. Also, the use of extra thick yarn has a coarse texture, and the adhesive cannot be held by the fabric itself. For this reason, the external water pressure retention is poor, and no consideration has been given to improving the bonding strength between the fiber layer and the resin film.
  • Another object of the present invention is to use a tubular woven fabric and a tubular nonwoven fabric as the tubular woven fabric, to impregnate the adhesive, to separate the resin film from the tubular fabric, and to remove the tubular fabric from the tubular fabric.
  • Still another object of the present invention is to provide a tubular woven cloth as a tubular cloth.
  • a tubular non-woven fabric having a special shape and structure is used inside the tubular cloth to provide a lining material which satisfies all the characteristics required for a lining material for pipelines.
  • the present inventors have conducted intensive studies in order to further improve the properties of the lining material described in the specification of No. 58-1 0236, No. 1 in the case of Machiton, and a tube having a resin skin on the outer surface.
  • a through hole formed by punching is provided evenly inside the fabric, and a tubular fabric formed by special sewing is introduced.
  • the disadvantages of this lining material have been overcome, and we have succeeded in obtaining a lining material that satisfies all the required characteristics.
  • a tubular lining material having an adhesive applied to the inner surface is passed through the pipe, and the inside of the pipe is turned upside down by the fluid pressure, and the inside lining is turned upside down.
  • the above-mentioned lining used in the method of lining a pipeline, in which the material is bonded to the inner surface of the pipeline with the adhesive interposed between the lining material and the pipeline while the material is pressed against the inner surface of the pipeline.
  • the lining material is made of an airtight tubular woven fabric woven in a tubular shape with a synthetic resin film formed on the outer surface, and a substantially uniform punch inserted inside the woven fabric.
  • a lining material for a pipeline characterized by being formed of a tubular cloth for impregnating an adhesive with a nonwoven fabric having a formed through hole.
  • the non-iron cloth is sufficiently impregnated with an adhesive, for example, an epoxy resin, and the air-tight tubular woven cloth is further passed through the non-iron cloth. Fully impregnate the resin
  • the nonwoven fabric and the woven fabric are integrated to increase the strength and improve the seismic isolation.- At the same time, even when external water is added, the tubular fabric and the nonwoven fabric converge. Provide a means for maintaining the original shape.
  • a conventional lining material particularly a lining material using a tubular woven fabric or a non-woven fabric described in Japanese Patent Application No. 58-102361, is suitable as an adhesive.
  • the non-woven cloth layer functions as a filter, and the adhesive cannot be sufficiently impregnated up to the tubular woven cloth. .
  • an excimer resin since it contains a resin component and a filler, a phenomenon occurs in which the filler is filtered by the nonwoven cloth when passing through the nonwoven cloth, and it is necessary to overcome this drawback. was there.
  • the non-woven cloth has a large number of pores distributed almost uniformly, so that such separation of the components of the adhesive can be prevented.
  • the adhesive-impregnated tubular woven fabric is composed of a single-layer nonwoven fabric or a laminated nonwoven fabric, and its outer diameter is airtight.
  • the inner diameter of the airtight tubular cloth is inserted by an appropriate means in a state of being folded in the length direction, which is larger than the inner diameter of the tubular cloth.
  • at least the nonwoven fabric used as the tubular woven fabric for impregnating the adhesive has a nonwoven fabric that forms the innermost layer of the nonwoven fabric, and the nonwoven fabric has a strip shape, and both sides in the length direction can be measured. It's a sewing method !?
  • This nonwoven fabric is generally formed of synthetic fibers, and the material is It is possible to use Polyamide, Polyester, Acrylic, and Polyurethane. It is particularly preferable to use those manufactured by a conventional method, for example, a dry-sumbon method from the knowledge of the Riestel. Also, is this non-woven cloth 2 to 8 d single? It is desirable that the fabric be insensitive fabric of a riester weft.
  • the thickness of the non-woven fabric can be changed depending on the purpose of use, etc., and is particularly limited.However, the thickness is usually 2 to 8, and the non-woven fabric is subjected to hunting or the like. If the hole to be made has the aforementioned thickness, 2 to 8 mm? 5, the hole distribution is preferably such that the shortest distance between the holes is 15 to 60 dragons.
  • the airtight tubular woven fabric is lined up, it is the one made of the synthetic fiber described in U.S. Pat. No. 4,334,948 or 4,368,091].
  • the outer surface of a tubular woven fabric woven into a tubular shape using weft and weft has a synthetic resin film.
  • Polyamide as synthetic fiber, 10? Riestell, Acryl, and Reurethane types can be used, but the use of Boliester type is preferred because of its high strength. .
  • a non-extensible entangled long fiber yarn of a polyester fiber or the non-extensible entangled long fiber yarn and a ⁇ ester long iron fiber yarn, a
  • the synthetic resin used for the synthetic resin film it is preferable to use a polyester elastomer in consideration of strength, durability, and compatibility with the pig cloth.
  • the adhesive used to impregnate the tubular woven fabric is d Xylic adhesives are preferred, and aromatic or aliphatic ⁇ liamin is preferably used as the curing agent.
  • FIG. 1 is a partially broken perspective view showing a typical ⁇ of the lining material of the present invention!
  • FIG. 2 is a perspective view showing the tubular cloth for adhesive impregnation in FIG. 1
  • FIG. 3 is a perspective view showing a form in which the tubular cloth for adhesive impregnation is extended in the circumferential direction.
  • FIG. 4 is a plan view showing a cross section of a pipeline to which the lining D material of the present invention is applied.
  • FIG. 1 shows the pipe lining according to the present invention! ) Typical aspects of the material
  • the material 1 is shown in a cutaway perspective view.
  • the material 1 is made up of an airtight tubular woven fabric 2 and a nonwoven fabric 6 made of a tubular woven fabric 4 having a synthetic resin film 3 on its outer surface.
  • the tubular woven fabric 5 for adhesive impregnation formed into a tubular shape by sewing with a thread 7 in the longitudinal direction 1, and the tubular woven fabric 5 is inserted into the tubular pig cloth 2.
  • the outer diameter of tubular woven fabric 5 is the inner diameter of tubular woven fabric 2! ? Because of its large size, it is folded at the fold 8 in the length direction, and the non-woven fabric 6 has a large number of substantially uniformly distributed through holes 9.
  • 3 ⁇ 4 The tubular woven fabric 4 of the tubular woven fabric 2 is formed into a tubular shape by the warp a and the weft 3 ⁇ 4 of synthetic fibers.
  • FIG. 2 is a perspective view showing only the tubular woven fabric 5 in FIG. 1]. However, both ends 10 in the longitudinal direction of the non-woven fabric 6 are sewn together by a thread 7 to each other. This is shown in Figure 2.
  • the tubular woven fabric 5 In the folded state, the tubular woven fabric 5 has a shape folded at the fold line 8, so that the both ends 10 are tightened by the thread 7 to form a projection.
  • FIG. 3 is a perspective view of the tubular fabric 5 when used for the liner of a pipeline] 9. In this case, the fold 8 disappears because the tubular woven fabric 5 is stretched in the circumferential direction. As a result, the cross section is circular, and the projections at both ends 1.0 disappear at that time.
  • the composition of the lining material of the present invention will be described more specifically by way of example.
  • the lining material of the present invention is applied to a sewage hume pipe having an inner diameter of 300.
  • the tubular woven fabric 4 is formed by weaving a warp a and a weft into a tubular shape, and the warp a in this case has a d of 1,000 d (the number of filaments is 288). Twisted 6 non-extensible entangled yarns of Riester filament yarn are used, and 320 of them are aligned and used (total of 640 yarns).
  • Tubular An air-tight synthetic resin film 3 is formed on the outer surface of the fabric 4, and this film 3 is generally formed by extruding a colorless polyester resin by an extrusion molding method. J? The outer surface of the tubular woven fabric 4 It is formed by coating directly on the surface. Its thickness is about 0.6 TO] ?, Generally, a thickness of about 0.2 to 1.5 ounces is appropriate. In this way, the airtight tubular fabric 2 is formed. The tubular woven fabric 4 is further shrunk by the treatment by the extruder to form the film 3, and the airtight tubular fabric 2 after the film 3 is formed has a folding width of 40 thighs. there were.
  • the through-hole 9 is formed by a perforation process in the stage before the tubular fabric 5 for impregnating the adhesive is sewn into a tube. 'The diameter of the through hole 9 at this time is about 3.5 mm, and the shortest distance between the through holes is about 2.5 cm from the center of the through hole.
  • This perforation is performed by completely cutting the fibers of non-woven fabric 6 with a conventional etching machine.
  • the nonwoven fabric 6 used at this time was formed to a thickness of about 4 by a conventional method in which a single-filament monofilament of about 5 denier; The basis weight of this non-woven fabric was about 4209-Zm 2 .
  • This non-woven fabric is covered with an over-lock type sewing machine so that the lengthwise ends of the non-woven fabric are not overlapped.
  • an adhesive-impregnated tubular woven fabric 5 In this overlock, one-lock sewing, two nonwoven fabrics each having a predetermined width are overlapped, the ends are sewn with a sewing width of about 10 mm, and the ⁇ -shaped cloth 5 is stretched in the circumferential direction. In this case, both ends are joined and do not overlap each other. Fold this tubular real cloth! ) The width was about 460 mm.
  • This tubular cloth 5 is then inserted inside the tubular cloth 2 by an appropriate method.
  • the lining material 1 in this state is j? As shown in Fig. 1.
  • the adhesive it is preferable to use the above-mentioned aromatic ⁇ liamine as a curing agent. More specifically, in this example, the main agent is eh. Screw-type eho?
  • the curing agent is a modified aromatic polyamine, and the mixed viscosity is 5,000 cps (B type reclaiming viscometer according to paragraphs 6 and 3 of JI SK 6833). Measured at). Calcium carbonate was used as the filler.
  • This adhesive was applied to the inner surface of the lining material in an amount of about 6 / m 2 . Lining with glue applied! The material is then inserted into the pipeline by turning it upside down at fluid pressure by a suitable method known in the art, for example, the reversing lining method described in US Pat. No. 4,334,943. Then, the adhesive is cured by heating with steam or the like. In this case, the pressure required for turning over was 0.8 / en in this example. In this way, the lining 1 was applied to the inner surface of the fume pipe.
  • Fig. 4 is lining like this! The cross section of the fume line is shown.
  • An adhesive layer 11 is provided on the inner surface of the fume tube 10, and a tubular woven fabric 5 and a tubular woven fabric 2 integrally bonded to the adhesive are located thereon.
  • the synthetic resin film forms the innermost layer of the lining material.
  • the lining material of the present invention] 5 material has a tubular woven fabric and has sufficient strength in the longitudinal direction, so that it exhibits seismic isolation. In the seismic isolation test, a 300-millimeter hume pipe of 1 m length was simply joined together, and the specimen with the lining material attached was used as a test specimen.A tensile load was applied to both ends of the specimen.
  • the liner was about 9 ton], and the 9 pieces came off the hume tube.
  • the tensile load was 10.5 ton.
  • cracks occurred in the hume tube in the direction.
  • the inner lining that peeled off from the tube was not damaged and formed a hard eve. Therefore, even if the pipeline is damaged due to an earthquake or the like, the pipes and the lining will be conical, and the lining will be stretched slightly, thereby absorbing energy.
  • the inner lining material alone can sufficiently secure a fluid passage without breaking the lining material.
  • the through-holes are uniformly distributed in the pipe 5 and the cloth 5 is provided in a large number, not only the cloth and the non-woven cloth with the adhesive, but also the pipe through these holes.
  • Fabric 2 is also impregnated with a large amount of adhesive.
  • the presence of this through hole eliminates the above-mentioned filtration phenomenon of the immortalized cloth, and the adhesive component is homogeneously tubular. It has the advantage of being supplied to cloth 2. Accordingly, when the tubular woven fabric 2 and the tubular woven fabric 5 are hardened after being applied to the pipe, they can be integrally bonded to each other to form a thick layer. In this way, there is a through hole.]?
  • a thick fibrous layer is impregnated with a large amount of adhesive, and a rigid pipe is lined with the lining material lined in the pipe line. It can be formed in the entanglement and the lining material will be crushed even if there is already a hole in the pipeline or if there is a new hole and groundwater has entered. As a result, the above-mentioned external water E shape retention can be secured.
  • the thickness force is preferably s 2 to 8 m. If the thickness is smaller than 2 females, it is not sufficient to secure the thickness, and if it is larger than 8, the tubular woven fabric 5 is not uniformly impregnated with the adhesive.
  • the non-fiber fabric is formed by dry-bonding using a 2 to 8 denier '''reestar fibrous weft thread as the tubular cloth 5. It is suitable because of its excellent impregnation and strength. To form the through-holes, it is necessary to use the Thomson's multi-machine method. 1) Cutting the fiber completely and opening it will reduce the permeability and impregnation of the adhesive. It is preferred because it is excellent.
  • the through holes have a size of about 2 to 8 ⁇ ⁇ , and the shortest distance between the through holes is about 1.5 to 6 OTI, so that the holes are formed uniformly over the entire surface. If the through-holes are too small] or too large, the effect of impregnating the tubular woven fabric 2 with the adhesive is small. Also, if the perforations are too large or too small, the strength of the lining material may be reduced. By providing additional holes? On the other hand, the peel strength between the tubular woven fabric and the tubular non-iron fabric is increased, and the integration of the tubular cut fabric and the tubular nonwoven fabric is promoted.
  • the layer thickness of the non-woven fabric should be increased. Since the real world increases in order to increase the number of layers, it is preferable to make the nonwoven fabric double or triple multilayer.
  • each nonwoven fabric layer is set to 2 to 8 baskets, and a through hole is formed in each layer. Furthermore, because of the perforations, the impregnation of the non-woven fabric with the adhesive is sufficient.
  • the folded width of the airtight tubular woven fabric is
  • the inner width of the tubular woven fabric for impregnating the adhesive is 60 plates (293 fiber in outer diameter, and air pressure is 0.5 / c after reversal) Since the outer diameter reaches approximately 300 mm 5 at about z , both the airtight tubular woven fabric and the tubular damp fabric for impregnating the adhesive can be lined without any gaps.
  • the reason why the expandability is good is that the first fold width of the airtight tubular woven fabric is 490 m (approximately ⁇ 2 plates ⁇ ) in which the heat treatment is performed.]?
  • the inner diameter of the pipe is increased by force. ??
  • the diameter of the tubular woven fabric is air-tight and the diameter of the fabric is also large. Furthermore, the diameter of the tubular cloth for the adhesive impregnation is larger than the diameter of the airtight tubular cloth. It is very flexible and keeps the lining material upside down! The fluid pressure of the festival can be kept low.
  • the tubular insulated cloth is formed in multiple layers to secure the thickness, it is possible to sew only the innermost layer to cause heavy damage to the intermediate layer. If the innermost layer is sewn, it is preferable because the nonwoven fabric will be displaced when the lining material is re-tilled, which may cause the generation of seams.
  • the diameter of the non-woven cloth layer is larger than the diameter of the airtight tubular woven cloth, and the larger the diameter of the non-woven cloth is located in the inner layer. This is desirable because the lining material can easily be turned over. However, it is necessary to keep them all slightly smaller than the pipe diameter.
  • the separation strength between the outer surface of the synthetic resin film and the tubular woven fabric can be improved.
  • the adhesion separation strength (180 degree separation) between the tubular fabric and the synthetic resin film is about] It is 0 cm, which is about 5 to 10 mm in strength compared to the case of using a steel wire of all lengths of about 1 to 2 Zcm.
  • the film is less likely to be grown.
  • This phenomenon is due to the fact that the non-extensible entangled long fiber yarn is bulky.
  • the resin forming the film penetrates into the non-extensible entangled long weft thread to achieve an anchor fruit, and the thread escapes because it is a long iron weft thread.
  • the separation strength * is improved.
  • the non-extensible entangled long fiber yarn does not need to be used for both the warp yarn and the long yarn, but the non-extensible entangled long fiber yarn and the ordinary long fiber yarn or short fiber yarn are used. The effect can be exhibited even if it is mixed and twisted.
  • the non-extensible entangled filaments are crimped under wet heat such as steam, whereas ordinary wool-yarns are crimped under dry heat.
  • the thread in the rolled state is fixed at a high temperature to reduce elongation. Therefore, it is a yarn with a shape very similar to a regular wool yarn, but has an elongation of 20% or less and high strength. It is desirable to use vestile fibers for the displacement of woven cloth and non-woven cloth in terms of strength. Polyester is also excellent in chemical resistance and abrasion resistance, and is desirable because durability is added. Similarly, synthetic resin skin!
  • the resin to be used enormously is a ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ ⁇ . ⁇ . If the coating is used without coloring, the resin itself will be transparent, so it will be necessary to check from the outside whether the adhesive has passed through the non-woven cloth and impregnated into the mesh of the tubular woven cloth. This is advantageous because it allows observation.
  • the lining material of the present invention is soft because it has excellent seismic isolation and water pressure retention in addition to the characteristics of the conventional lining forest.
  • ⁇ ⁇ Suitable for reinforcing pipes buried in land or landfills. Also gas pipelines and oil c. It can be used to reinforce various pipelines such as electric lines, water pipes, sewage pipes, and underground power cables.

Abstract

A lining material formed by providing a nonwoven fabric of a special shape on the inner side of a conventional air-tight tubular woven cloth which has a synthetic resin film on the outer surface thereof, and which is adapted to be inserted into a duct as it is turned inside out by a fluid pressure. The lining material according to this invention has various properties required in conventional lining materials of this kind, and also other properties, such as earthquake resistance and shape-retentivity under an external hydraulic pressure, and is suitably used to reinforce various kinds of underground pipes.

Description

明 細 書  Specification
管 路 の 内 張 り 材  Lining material for pipeline
技術分野  Technical field
本発明は ガス導管、 水道管、 下水道管 電力線や通信 線等の敷設管路、 石油 イ ブラ イ ン等の 主と して地中 に埋設された管铬用の、 内張 に関する も のである。 さ らに詳 し く 言えば、 本発明は、 外面に合成樹脂皮槳を 有し流体圧力で裏返されながら前記管路内に挿通される 気密性管状織布の内側に特殊 ¾形状の不 ^布を配設 して ¾ 、 従来の内張 材で必要と される諳性質と共に免 '霉 性お よ び外水 E保形性等の性質を兼備 した前記管路用の 内張 材に関する。 ,  TECHNICAL FIELD The present invention relates to a gas pipe, a water pipe, a sewer pipe, a laying line for a power line, a communication line, and the like, and a lining for a pipe buried mainly underground, such as an oil oil line. More specifically, the present invention relates to a nonwoven fabric having a special shape inside a hermetic tubular woven fabric which has a synthetic resin skin on the outer surface and is inserted into the pipe while being turned upside down by fluid pressure. The present invention relates to a lining material for a pipeline, which has a cloth, and has properties such as a repelling property and a form-retaining property of outside water, as well as a singing property required for a conventional lining material. ,
背景技術 .  Background art.
近年、 前記の よ う 地中埋設管路が老朽化 した場合の 補修、 補強の 目 的で、 これ ら管珞の内面に内張 をする こ とが行 ¾われてお ]? 、 その内張 の方法の一つ と して、 管状の形態の内張 ) 材の内面に接着剤を塗布 してお き、 こ の内張 材を流体圧力で裏返 しるがら管路に挿通進行 させ、 管路と 内張 _り 材と の中間に接着剤を介 して内張 材を管路内面に接着する こ と が行 われている ( 洌えば 米国特許第 4,368,091 号、 米国特許第 4,334,943 号、 特 公昭 58 - 38088 号、 特公昭 58 - 5165 号、 特公昭 59 - 12911 号参照 ) 。 こ の方法は管珞を全長に亘つて掘 起 こす必要がる く 、 内張 ]? すべき 管路部分の両端部のみに マ ン ホ ー ルを形成するだけで実施可能であ 、 ま た内張 j? 作業自体も短時間の間に長い管路に施工する こ とがで き 、 さ らに屈曲の多い管路であっても 施工可能であって、 極めて優れた方法である。 In recent years, for the purpose of repair and reinforcement when the underground pipes are deteriorated as described above, these pipes have been lined on the inner surface. As one of the methods, an adhesive is applied to the inner surface of a tubular lining material, and the lining material is inserted through a pipeline while being turned upside down by fluid pressure. The lining material is adhered to the inner surface of the pipe via an adhesive between the road and the lining material (an example is US Pat. No. 4,368,091 and US Pat. No. 4,334,943). No. 58-38088, Japanese Patent Publication No. 58-5165, and Japanese Patent Publication No. 59-12911). This method does not require excavation of pipes over the entire length, and can be carried out only by forming manholes only at both ends of the pipe section to be lined. Lining j? The work itself can be performed on a long pipeline in a short time, and it can be performed even on a pipeline with many bends. This is an extremely excellent method.
と'ころで、 この種の内張!) 工法にお て使用される 内 張 i? 林と しては、 薄い柔軟 ブ ラ スチ ッ クチュー ブ、 織 布ま たは不镄布を管状形状に し、 その外面に気密 · 水密 性の被覆を形成させた繊維質内張 材等、 種々 の ものが 提案されている。  And at the time, this kind of lining! The lining used in the construction method is made of thin, flexible plastic tubing, woven or non-woven fabric in a tubular shape, and its outer surface is air-tight and water-tight. Various materials have been proposed, such as a fibrous lining material formed with a material.
例えば、 特公昭 55 ― 43890 号( 英国特許第 1,449,455 号 ) 明細書には、 フ ェ ル ト お よび ( ま たは ) 布、 および 可徺性発泡剤か ら る材料上に不透過性膜で囲繞された 可撓性の樹脂吸収材質から構成される内張 ]? 材が開示さ れている。 ま た特公昭 58 - 33098 号明細書には、 不透過 性の層を一方の側に有する樹脂吸収層か らなる平坦 ¾ ゥ エ ブ積層物から な 、 こ の不透過性膜が外側に来る よ う に管状形態と し、 両端面を糸で横断させ、 次いで縫合面 全体に密封 リ ボンま たは被覆を施した内張 j? 林およ びそ の製法が記載されて る。 米国特許第 4,334,943 号お よ び第 4,368,091 号の明細書には合成繊維糸の経糸およ び 緯糸で管状に織成し、 この外部を樹脂で被覆した内張 材が^示されて'いる。 ま たこれ と同様な管状織布の外面 に柔軟 ゴ ム質ま たはブ ラ スチッ ク製の皮膜を形成させ た管路の内張 林が実開昭 56- 3619 号に記載されている。 さ らに特開昭 56 - 8229 号明細書には前記の管路用内張 材の改良を 目的 と した、 锇維を管状に織製 した管状織布 の外面に柔軟 ゴ ム質ま たは ブ ラ ス チ ッ ク製の皮膜を形 成させ、 最小の流体圧力に等 し 圧力を加えた際に外径 が 7 〜 膨張する 内張 _り 材が開示されている。 ま た特 願昭 58 - 1 0236 1 号明細書には、 合成繊維の経糸お よ び緯 糸 を管状に織成 した管状織布の内面ま たは外面に内部に 空隙を有し所定の厚さ を有する管状镄布を積層 し、 その 外面に合成樹脂の気密層を形成させた管路の内張 材が 記載されて る。 For example, Japanese Patent Publication No. 55-43890 (British Patent No. 1,449,455) discloses an impermeable membrane on felt and / or fabric and a material made of a flexible foaming agent. A lining material composed of an enclosed flexible resin-absorbing material is disclosed. Also, Japanese Patent Publication No. 58-33098 discloses that this impermeable membrane, which is made of a flat web laminate composed of a resin absorbing layer having an impermeable layer on one side, comes to the outside. Thus, it describes a lining j-forest that has a tubular form, both ends are traversed with a thread, and then the entire suturing surface is covered with a sealing rib or coating, and a method for producing the lining. The specifications of U.S. Pat. Nos. 4,334,943 and 4,368,091 show a lining which is woven tubular with synthetic fiber warps and wefts and which is coated with a resin on the outside. A similar lining of a tubular woven fabric in which a flexible rubber or plastic coating is formed on the outer surface of a tubular woven fabric is described in Japanese Utility Model Publication No. 56-3619. Further, Japanese Patent Application Laid-Open No. 56-8229 discloses a tubular woven fabric in which a fiber is woven in a tubular shape for the purpose of improving the above-mentioned pipe liner. A flexible rubber or plastic film is formed on the outer surface of the lining, and when the pressure is applied to the minimum fluid pressure, the outer diameter expands 7 to It has been disclosed. Also, Japanese Patent Application No. 58-1 0236-1 discloses that a tubular woven fabric in which a warp and a weft of synthetic fiber are woven in a tubular form has an internal void inside or outside and has a predetermined thickness. It describes a pipe liner in which a tubular cloth having a high degree of flexibility is laminated and an airtight layer of a synthetic resin is formed on the outer surface thereof.
他方、 ガス導管、 水道管、 下水道管、 石油 イ ^ ラ イ ン等の流体輸送用の管路に前記 した形式の管路内張 .り ェ 法を適用する場合、 こ の工法で使用される 内張 甘には 当初、 輸送流体の漏出がな く 、 管路の曲部において も 追 従でき る柔軟性、 内部流体の圧力に耐える強度、 皮膜の 耐久性等が要求されていたが、 こ の形式の管路内張 エ 法が汎用されるに伴い、 適用する管路の環境、 土地の性 質 どに応 じて多様 ¾特性が内張 材に要求さ れる よ う に るつて来た。 現在では内張 材に対 して下記の よ う ¾ 性質が要求される。  On the other hand, when the above-mentioned pipe line method is applied to a pipe for transporting a fluid such as a gas pipe, a water pipe, a sewer pipe, and an oil line, it is used in this method. Initially, the lining was required to have no leakage of the transport fluid, flexibility to be able to follow the curved part of the pipeline, strength to withstand the pressure of the internal fluid, durability of the coating, etc. With the general use of the pipe lining method of the above type, the lining material has been required to have various characteristics depending on the environment of the pipeline to be applied, the nature of the land, etc. . At present, the following properties are required for lining materials.
(1) 免震性  (1) Seismic isolation
流体輸送管路に地震等の大き な外力が加わって、 管路 が破損 した よ う る場合に、 内張 ]? 材が共に破断する こ と な ぐ 管路か ら剝雜し、 それ単独で流体輸送の管機能を維 持 し続ける必要がある。 このためには抗震性と 共に地震 エ ネ ル ギー吸収性を持つこ とが必要である。 本明細書に おいて以下こ の性能を 「免震性」 と 定義する。 こ の免震 性を有するためには、 内張 -り 材の長さ方向の強力が充分 に大き く、 接着剤が剪靳破壌を起こす前に、 内張 _り材が 破断するこ との だけの強度が必要である。 ま た、 こ の よ'う ¾免震性特性を有 して る と、 軟弱地盤や埋立地 な どに埋設された管路で地盤沈下 どに よ 管路自体が 亀裂 . 折損ま たは抜け出 しをおこす場合で も、 管機能が 維持でき、 事態に対応する こ と ができ る。 特に近年では 地震予知技術の進歩に伴 い各地で地震の可能佳が指摘 される よ う になったので、 特にこれらの地震発生が予想 される地帯では、 管路の内張 材に対 してこの免震性は 重要な特性であ る。 When a large external force such as an earthquake is applied to the fluid transport pipeline and the pipeline is damaged, the lining will not be broken together. It is necessary to maintain the pipe function of fluid transportation. For this purpose, it is necessary to have seismic energy absorption as well as anti-seismic properties. In the present specification, this performance is defined as “seismic isolation”. This seismic isolation The lining material has sufficient strength in the longitudinal direction to have the property, and has enough strength to break the lining material before the adhesive causes shear failure. is necessary. In addition, if it has seismic isolation characteristics, the pipeline itself will crack or break due to land subsidence in the pipeline buried in soft ground or landfill. In the event of a disaster, the pipe function can be maintained and responded to the situation. Particularly in recent years, with the advancement of earthquake prediction technology, the possibility of earthquakes has been pointed out in various places, and especially in areas where these earthquakes are expected to occur, the use of pipe linings This seismic isolation is an important characteristic.
(2) 外水圧保形性 (2) External water pressure retention
管路が腐蝕 して孔が生じたと き に、 そこか ら地下水等 が侵入し、 この地下水の水圧に よって内張 材が押 し潰 され、 管内の流路が狭 く なる よ う な こ とがあってはる ら ¾い。 ま た地震等で管路が破断した と き には、 内張!) 材 に直接外圧が掛かるのであ 、 この E力に も 耐える こ と が必要である。 この よ う に、 外方か らの圧力に耐え押 し 潰される こ と な く 流路を確保でき る性能は重要であ ? 、 本明細書において この性質を外水圧保形性と定義する。  When a pipe is corroded and a hole is formed, groundwater or the like intrudes through the hole, and the water pressure of this groundwater causes the lining material to be crushed and the flow path in the pipe to be narrowed. If there is. Also, if the pipeline breaks due to an earthquake or the like, lining! ) Since external pressure is directly applied to the material, it is necessary to withstand this E force. Is it important to have the ability to withstand the pressure from the outside and secure the flow path without being crushed? In the present specification, this property is defined as external water pressure retention.
管路に適用 された内張 材が外水圧保形性を有するた めには、 接着剤の耐水性お よ び硬度が重要である。 さ ら にこの接着剤が充分 厚みを有している こ と も 必要であ る。 従って内張 ) 材と しては、 充分な量の接着剤を包含 でき る ものである こ とが要求される。 従来、 こ の種の接着剤 と しては ェ ボ キ シ系澍脂、 不飽 禾ロ 十? リ エ ス テ ル系樹脂、 ア ク リ ル系澍脂、 ウ レ タ ン系澍 脂等が使用 さ れて る が、 管路を地下水 が侵入 して く る 場所に敷設する こ と も あ る の で水 中 下で も 硬化反応が阻 害 され る こ と な く 進行 して接着を 達成 し、 硬化後におい て も 水の影響でその接着力が低下 し ¾ も のが要求さ れ る。 こ の親点か ら 硬化剤と して過酸化物を 使用する不飽 和 ボ リ エ ス テ ル系樹脂お よ びァ ク リ ル系 m脂は水の共存 下で硬化 し いおそれ も あ 、 好ま し ぐ ¾ い。 ま た ス チ レ ン モ ノ マ ー等の溶剤の使用す る 点で も 望ま し ぐ ¾い。 ま た ゥ レ タ ン 系澍脂は 水中 での硬化が可能であ る が可 '('吏 時間 の調整 ¾ どが面倒であ 、 ま たモ ノ マ ー成分が水 '容 性の場合 も あ 、 環境汚染の 原因に も な るの で好ま し く い。 したがって こ の種の管路に用 る 内張 _り 材に好適 接着剤は ェ ボキ シ系樹脂で あ 、 中 で も 硬化剤 と して 芳香族ま たは脂肪族の ^ リ ア ミ ン を使用 した も のが水中 で も 確実に硬化 させる こ と がで き るの で好ま しい。 The water resistance and hardness of the adhesive are important for the lining material applied to the pipeline to have external water pressure retention. It is also necessary that this adhesive has a sufficient thickness. Therefore, the lining material is required to include a sufficient amount of adhesive. Conventionally, this type of adhesive has been used for epoxy resin and unsaturated. Reester resin, acryl resin, urethane resin, etc. are used, but pipes may be laid in places where groundwater can enter. Therefore, even in water, the curing reaction proceeds without being hindered and achieves adhesion, and even after curing, the adhesive strength is reduced due to the effect of water, and the strength is required. . From this point of view, unsaturated polyester resins and acrylic resins that use peroxide as a curing agent may not cure in the presence of water. , I like it. It is also desirable to use a solvent such as styrene monomer.ゥ Resin-based resin can be cured in water, but it can be cured. '(' Adjustment of the time required for administration is troublesome, and the monomer content is water-soluble. It is also preferable because it can cause environmental pollution, so the adhesive suitable for the lining material used in this type of pipeline is a epoxy resin, and the curing agent is also a medium However, it is preferable to use aromatic or aliphatic ^ liamin because it can be hardened even in water.
と こ ろが、 こ う した ェ ボキ シ系澍脂は粘度を 下け' る こ と が難 し く 、 前述の繊維層 に確実に含浸させ よ う と する には何等かの工夫が必要 と な る。 ま た厚 織維層の全体 に B つてェ ボキ ン系樹脂を含浸 させて も 、 この層全体を 完全に水密性にする のは困難であ 、 外部か らの外水圧 の 適用で 水の滲出現象 も 起る。 その結果、 樹脂皮嫫 も 外 水圧の釤響 を受け、 减維層に対する 剝離強度が低下する 場合には皮嫫が锇維層か ら剝離 し流体の通路を閉塞す る おそれがあ る。 そこで樹脂皮膜 と繊維層 との剝離強変が 大き こ と も 外水 JEに耐える条件の一つと して要求され る。 ま た外水圧保形性は内張 材の厚みに よって左右さ れる'の で多層で繊維層を使用する際には接着剤で完全に —体化.する こ とが必要である。 However, it is difficult to reduce the viscosity of these epoxy resins, and some measures must be taken to ensure that the above-mentioned fiber layer is impregnated. Become. Even if the entire textile layer is impregnated with evoquine-based resin, it is difficult to make the entire layer completely watertight, and water seepage occurs when external water pressure is applied from outside. Phenomena also occur. As a result, the resin skin is also affected by the external water pressure, and if the separation strength with respect to the fibrous layer decreases, the skin separates from the fibrous layer and blocks the fluid passage. There is a risk. Therefore, a large change in the separation between the resin film and the fiber layer is also required as one of the conditions for withstanding the external water JE. In addition, since the external water pressure retention depends on the thickness of the lining material, it is necessary to completely incorporate the adhesive when using multiple fiber layers.
は) 耐内圧力性 A) Internal pressure resistance
流体輸送管路の場合は この管路破断時に内張 -り 材が流 体の圧力を支えるので、 その圧力に耐える こ とができ る も のである こ とが必要である。 ま た内張!? 材を管络に適 用する際、 内張 ]? 材の裏返しに必要 流体圧力に よ .り、 内張 材が破新する も のであってはな らず、 相当の耐 EE 力を必要とする。  In the case of a fluid transport line, the lining material supports the pressure of the fluid when the line breaks, so it must be able to withstand that pressure. Also lining! ? When applying the material to the pipe, it is necessary to turn the material inside out.) The fluid pressure must be sufficient to prevent the lining material from breaking down. I do.
(4) 柔軟性 (4) Flexibility
管路に内張 材を適用する際、 内張 -り 材を流体 E力で 裏返すため、 内張 i) 材 自体が柔軟であって、 裏返しに高 い圧力を要しないこ とが必要であ る。 特に繊維層の厚み が大き い場合の内張 材の裏返しは困難と なるので、 こ の性質は重要であ る。  When applying the lining material to the pipeline, since the lining material is turned over by the fluid E force, it is necessary that the lining material itself is flexible and does not require high pressure to turn it over. You. This property is important because it becomes difficult to turn over the lining material especially when the thickness of the fiber layer is large.
と ころで前述 した従来の内張 _り 材はこれらの必要な性 質の一部を満足する こ とができ るが、 これ ら性質すベて を満足 して 。  The conventional lining material described above can satisfy some of these necessary properties, but satisfies all of these properties.
例えば特公昭 55 - 43890 号お よ び特公昭 58 — 3 3098 号 明細害に記載された内張]? 材は基本的には不銑布を使用 した ものであ ]? 、 この不織布の厚みの調整は可能なため 充分な厚みを持つ内張 ]? 材を得る こ とができ る。 しか し ( マ ) For example, the linings described in JP-B-55-43890 and JP-B-58-333098 are not basically used non-iron cloth.] Adjustment is possible, so a lining with sufficient thickness can be obtained. However (Ma)
な が ら、 不镄布それ 自 体の強 .変が小 さ いため 免震性に欠 如 し、 ェ ボキ シ系澍脂 を確実に 含浸さ せる ための工夫 も 欠如 している 。 不綠布のため耐内 ΙΈ力 も 小さ ぐ 、 ま た澍 脂皮膜と锇維層 と の接着強度向上のために何等の 手段 も 昆 られ る 。  However, the nonwoven fabric itself has a small change in strength, and thus lacks seismic isolation, and lacks any measures to ensure the impregnation with the epoxy resin. Due to the non-woven fabric, the internal resistance is low, and any means can be taken to improve the adhesive strength between the resin film and the fibrous layer.
実開昭 56 - 36 19 号お よ び特開昭 56 — 8229 号の公報に 記載 された内張 .り 材は基本的に綠布 を使用 した も ので あ り 、 こ のため強袞は極めて大 き く 、 製镄組 ^を 変更す る こ と でさ らに強度を 高め る こ と も 可能であ る。 従って免 震性 よ び耐内圧 力性は大 き いが織布の厚みを増大す る こ と が困難で あ る。 一般の衣料用 ¾ どの織物では、 織 .り 钽璣を工夫す る こ と で、 厚い も の を 得る こ と も 困難では ¾い。 しか し が ら、 内張 材の管状織布は環状綠機を 用いて管状に織成 され るが、 環状織機は複雑 ¾組織の織 物を構成す る こ と がで き ¾い。 しカゝ も 前述の よ う に、 大 き い強力を有 しつつ厚 く 織 らねばな ら ず、 衣料用の厚手 織物の よ う に、 芯糸や裏糸 で厚みを増すこ と がで き ¾ い。 太 糸の使用で厚みを 大 き く す る こ と はで き る が、 糸の 剛性のため 内張 材を管路に適用する際に裏返 しが困難 と な 、 ま た織物表面の 凹凸が大 き ぐ なつて輸送 し ょ う と す る流体の流体抵抗を増大 させる。 ま た余 太 糸の 使用は布 目 が粗 く 、 接着剤を布 自 体で 保持で き く な る。 そのため外水圧保形性が悪 く 、 繊維層 と 樹脂皮膜 と の接 .着強度向上について も 何等の考慮が ¾ さ れてい ¾ い ま た特願昭 58— 10236 1 号明細書に記载された内張 _り は前記 した特性のすべてをある程度満足 して るが、 接 着剤の含浸性、 特にエ ^キ シ系樹脂を管状銑布 と しての 不織'布から織布ま で充分に含浸させる手段について何等 工夫が 、 ま た管状織布と樹脂皮膜との剝離強度な ら びに管状織布と管状不銑布と の剝錐強度を増大させる こ と について考慮がなされてい い。 The lining material described in Japanese Utility Model Application Publication No. 56-3619 and Japanese Patent Application Laid-Open No. Sho 56-8229 is basically made of cloth. Significantly, it is possible to further increase the strength by changing the manufacturing method. Therefore, seismic isolation and internal pressure resistance are large, but it is difficult to increase the thickness of the woven fabric. For general clothing, it is not difficult to obtain a thick one by devising the weave. However, the tubular woven fabric of the lining material is woven in a tubular shape using a circular loom, but the circular loom can form a woven fabric having a complicated structure. As described above, shika must also be woven with great strength and thick, and like a thick garment for clothing, it can be thickened with a core yarn or backing yarn. It's awesome. Thick yarn can be used to increase the thickness, but the rigidity of the yarn makes it difficult to turn it over when applying a lining material to a pipeline, and irregularities on the fabric surface Increases the fluid resistance of the fluid to be transported over a large distance. Also, the use of extra thick yarn has a coarse texture, and the adhesive cannot be held by the fabric itself. For this reason, the external water pressure retention is poor, and no consideration has been given to improving the bonding strength between the fiber layer and the resin film. Although the lining described in Japanese Patent Application No. 58-10236-1 satisfies all of the above properties to some extent, the impregnating property of the adhesive, especially the epoxy resin Means for fully impregnating the nonwoven fabric as a tubular pig cloth from the cloth to the woven cloth have been devised. No consideration has been given to increasing the cone strength of these.
こ の よ う な事情か ら、 特頓昭 58— 1 023 61 号明細書に記 載された内張 ]? 材にさ らに改良を加え、 前記したよ う な 内張 材に必要 ¾特性のすべてを満足する改善された内 張 材を開発する点に大き ¾要望があった。 本発明はこ の よ う な現状にかんがみ、 特願昭 58 - 102361 号明細書に 記載された内張 材をさ らに改良する ためになされたも のである。  Under these circumstances, the lining material described in the specification of Tokuton, No. 58-1 023 61] was further improved, and the lining material described above was required. There was a great demand for developing an improved lining material that satisfies all of the above. In view of such circumstances, the present invention has been made to further improve the lining material described in Japanese Patent Application No. 58-102361.
本発明の 目 的は、 従来の管路甩内張 -り 林が具備する柔 軟性、 接着剤含浸性、 耐内圧力性等を損 う こ とな く 、 免 震性お よ び外水 £保形性を兼備 した管路特に地中に埋設 した管路に使用する内張 ]? 材を提供する こ とである。  It is an object of the present invention to provide a seismic isolation and outside water without deteriorating the flexibility, adhesive impregnation property, internal pressure resistance, etc. of a conventional pipeline lining forest. It is intended to provide lining materials used for pipelines having shape retention, especially for pipelines buried underground.
本発明の他の 目的は、 管状織布 と して管状識布 と管状 不織布とを使用 し、 接着剤含浸性、 樹脂皮膜と管状锇布 との剝離強度およ び管状磺布と管状不識布 との剝離強度 を改善して従来の内張 材の具備する特性を損 う こ と な く 免震性およ び外水圧保形性をさ らに具備した管路の内 張 材を提供する こ とである。  Another object of the present invention is to use a tubular woven fabric and a tubular nonwoven fabric as the tubular woven fabric, to impregnate the adhesive, to separate the resin film from the tubular fabric, and to remove the tubular fabric from the tubular fabric. Providing a lining material for pipelines with improved seismic isolation and external water pressure retention without increasing the separation strength from the cloth and without impairing the characteristics of the conventional lining material It is to be.
本発明のさ らに他の 目的は、 管状織布 と して管状殲布 と共に特殊 形状 と 構造を有する管状不織布を管状 布 の内側に使用 し、 管路用内張 材に要求される特性をす ベて満足する内張 -り 材を提供する こ と であ る。 Still another object of the present invention is to provide a tubular woven cloth as a tubular cloth. In addition, a tubular non-woven fabric having a special shape and structure is used inside the tubular cloth to provide a lining material which satisfies all the characteristics required for a lining material for pipelines.
発明の開示  Disclosure of the invention
本発明者 らは待頓昭 58 - 1 0236 1 号明細害に記载の内張 _り 材の特性を さ らに改善するため鋭意研究を重ねた锆杲、 外面に樹脂皮嫫を有する管状綠布の内側に打抜 き に よ つ て形成された透孔がほ 均一に設け られ、 特 縫製に よ って管状の形態に した不锇布 を揷入さ せる こ と に よつ て従来の内張 材の有する欠点が克服され、 要望される 特性をすベて満足する内張 り 材を得る こ と に成功 した。  The present inventors have conducted intensive studies in order to further improve the properties of the lining material described in the specification of No. 58-1 0236, No. 1 in the case of Machiton, and a tube having a resin skin on the outer surface. Conventionally, a through hole formed by punching is provided evenly inside the fabric, and a tubular fabric formed by special sewing is introduced. The disadvantages of this lining material have been overcome, and we have succeeded in obtaining a lining material that satisfies all the required characteristics.
す わち、 本発明に よれば、 内面に接着剤を塗布 した 管状の内張 材を管路内に揷通し、 流体圧力に よ 裏返 し ¾がら管络内を前進させ、 裏返された内張 材を管路 内面に圧着 しなが ら内張 材と管路との間に介在させた 記接着剤に よ 管路内面に接着させる管路の内張 り 方 法に使用する前記内張 _り 材であって、 こ の内張 ]? 材が外 面に合成樹脂皮膜を形成 した管状に織成した気密性管状 織布 と、 その内側に挿入されたほぼ均一に打ち抜 ぐ こ と に よって形成された透孔が設け られた不織布よ る接 着剤含浸用管状識布 と か らな る こ と を特徴 と する管路の 内張 ] 材が提供される。  In other words, according to the present invention, a tubular lining material having an adhesive applied to the inner surface is passed through the pipe, and the inside of the pipe is turned upside down by the fluid pressure, and the inside lining is turned upside down. The above-mentioned lining used in the method of lining a pipeline, in which the material is bonded to the inner surface of the pipeline with the adhesive interposed between the lining material and the pipeline while the material is pressed against the inner surface of the pipeline. The lining material is made of an airtight tubular woven fabric woven in a tubular shape with a synthetic resin film formed on the outer surface, and a substantially uniform punch inserted inside the woven fabric. A lining material for a pipeline characterized by being formed of a tubular cloth for impregnating an adhesive with a nonwoven fabric having a formed through hole.
ま た本発明に よれば、 不銑布に接着剤、 た とえばェ ボ キ シ系樹脂を充分に含浸させ、 さ らに不銑布を通 して気 密性管状織布に も エ ^ キ シ系樹脂を充分に含浸させ、 こ れに よ 不镦布 と織布と を一体化させて強度を増大させ、 免震性を改善する-と共に外水 が加え られた際に も管状 の緣布 と不緣布 とが剝錐し いで原形を保持するための 手段'を提供する。 Further, according to the present invention, the non-iron cloth is sufficiently impregnated with an adhesive, for example, an epoxy resin, and the air-tight tubular woven cloth is further passed through the non-iron cloth. Fully impregnate the resin As a result, the nonwoven fabric and the woven fabric are integrated to increase the strength and improve the seismic isolation.- At the same time, even when external water is added, the tubular fabric and the nonwoven fabric converge. Provide a means for maintaining the original shape.
従来の内張 材、 特に特願昭 58 - 1 0 236 1 号明細書に記 載された管状の織布 よ び不锇布を使用する内張 材で は、 接着剤 と して好適 ¾ェ キ シ系樹脂を不镄布を通し て管状 布に含浸させる際に、 不载布層がフ ィ ル タ ー の 役割を果して接着剤が管状織布ま で充分に含浸でき い 欠点があった。 ェ キ シ系樹脂の場合、 樹脂分と充塡剤 と を含有して るため不緣布を通過する際に充塡剤が不 織布でろ過される現象が生じ、 この欠点を克服する必要 があった。 本発明に よ れば不礅布はほ 均一に分布 した 多数の透孔を有するのでこの よ う な接着剤の成分分離を 防止する こ と ができ る。  A conventional lining material, particularly a lining material using a tubular woven fabric or a non-woven fabric described in Japanese Patent Application No. 58-102361, is suitable as an adhesive. When impregnating a tubular cloth with a xylene resin through a non-woven cloth, the non-woven cloth layer functions as a filter, and the adhesive cannot be sufficiently impregnated up to the tubular woven cloth. . In the case of an excimer resin, since it contains a resin component and a filler, a phenomenon occurs in which the filler is filtered by the nonwoven cloth when passing through the nonwoven cloth, and it is necessary to overcome this drawback. was there. According to the present invention, the non-woven cloth has a large number of pores distributed almost uniformly, so that such separation of the components of the adhesive can be prevented.
本発明の内張 ^材にお て、 接着剤含浸用管状織布は、 単層の不緣布、 ま たは積層された不畿布に よって構成さ れていて、 その外径は気密性管状識布の内径 よ も 大き ぐ 、 長さ方向に折畳んだ状態でこの気密性管状婊布の内 側に適当な手段で挿入される。 ま たこ の接着剤含浸用管 状織布と して使用する不織布は少な く と も その最内層を 搆成する不織布が帯状に長 不锇布を、 その長さ方向の 両緣を緣かが 縫方式に よ ]? 両緣が重な !) 合わない よ う に縫着 し、 管状に形成 してある こ とが特徴である。 こ の 不緣布は一般に合成繊維に よ 形成され、 材質と しては ボ リ ア ミ ド、 ボ リ エ ス テ ル、 ア ク リ ル系、 ホ リ ウ レ タ ン 系の も の を使用す る こ と がで き る のが、 ホ? リ エ ス テ ル識 維か ら慣用の方法、 例えば乾式ス ン ボ ン 法で製造 さ れた も のが特に好適であ る。 ま た こ の不娥布が単锇度 2 〜 8 d の 十? リ エ ス テ ル織維糸の不敏布 であ るの が望ま し い。 不織布の厚さ は使用 する 目 的等に よ って変え る こ と が で き 特に 限定さ れ が、 通常 2 〜 8 であ って、 こ の不镦布に ハ° ン チ ン グ等で作 ら れる透孔は前述の厚みを 有す る場合、 2 〜 8 丽 ?5 であ 、 こ の孔分布は好適には 透孔間の最短距雜が 15〜 60 龍 の間隔 と するのが 良い。 In the lining material of the present invention, the adhesive-impregnated tubular woven fabric is composed of a single-layer nonwoven fabric or a laminated nonwoven fabric, and its outer diameter is airtight. The inner diameter of the airtight tubular cloth is inserted by an appropriate means in a state of being folded in the length direction, which is larger than the inner diameter of the tubular cloth. In addition, at least the nonwoven fabric used as the tubular woven fabric for impregnating the adhesive has a nonwoven fabric that forms the innermost layer of the nonwoven fabric, and the nonwoven fabric has a strip shape, and both sides in the length direction can be measured. It's a sewing method !? The feature is that it is sewn so that it does not fit and is formed in a tubular shape. This nonwoven fabric is generally formed of synthetic fibers, and the material is It is possible to use Polyamide, Polyester, Acrylic, and Polyurethane. It is particularly preferable to use those manufactured by a conventional method, for example, a dry-sumbon method from the knowledge of the Riestel. Also, is this non-woven cloth 2 to 8 d single? It is desirable that the fabric be insensitive fabric of a riester weft. The thickness of the non-woven fabric can be changed depending on the purpose of use, etc., and is particularly limited.However, the thickness is usually 2 to 8, and the non-woven fabric is subjected to hunting or the like. If the hole to be made has the aforementioned thickness, 2 to 8 mm? 5, the hole distribution is preferably such that the shortest distance between the holes is 15 to 60 dragons.
一方、 気密性管状織布は列えば米国特許第 4 , 334 , 948 号ま たは第 4 , 368 , 091 号明細書に記載さ れた搆造の も の で あ ]? 、 合成繊維の経糸お よ び緯糸を使用 して管状に織 製 した管状織布の 外面に合成 ^脂皮膜 を有する。 合成繊 維 と しては ボ リ ア ミ ド、 十? リ エ ス テ ル 、 ア ク リ ル系、 ' リ ウ レ タ ン 系の も のが使用で き るが高い強度を 有する 点 力 ら ボ リ エ ス テ ル系の も のの使用が好ま しい。 管状镄布 と しては ^ リ エ ス テ ル繊維の非伸長性交絡長锇維糸、 ま たは、 こ の非伸長性交絡長繊維糸 と ^ リ エ ス テ ル長鐡維 糸、 あ る いは、 ボ リ エ ス テ ル短繊維糸の混襟糸 を、 経糸 又は緯糸の少な く と も 一方に使用する のが好ま しい。  On the other hand, if the airtight tubular woven fabric is lined up, it is the one made of the synthetic fiber described in U.S. Pat. No. 4,334,948 or 4,368,091]. The outer surface of a tubular woven fabric woven into a tubular shape using weft and weft has a synthetic resin film. Polyamide as synthetic fiber, 10? Riestell, Acryl, and Reurethane types can be used, but the use of Boliester type is preferred because of its high strength. . As the tubular cloth, a non-extensible entangled long fiber yarn of a polyester fiber, or the non-extensible entangled long fiber yarn and a ^ ester long iron fiber yarn, a Alternatively, it is preferable to use a mixed short yarn of a polyester short fiber yarn for at least one of the warp and the weft.
合成樹脂皮膜に使用する 合成樹脂は、 強度、 耐久性等 な らび銑布に対する 相容性 ど を 考慮 して ホ リ エ ス テ ル 弾性 脂を使用す るの が好ま しい。  As the synthetic resin used for the synthetic resin film, it is preferable to use a polyester elastomer in consideration of strength, durability, and compatibility with the pig cloth.
ま た前記の管状織布に含浸させる接着剤 と して はエ ^ キ シ系接着剤が好適であ 、 芳香族ま たは脂肪族 ^ リ ア ミ ンを硬化剤と して使用するのが好ま しい。 The adhesive used to impregnate the tubular woven fabric is d Xylic adhesives are preferred, and aromatic or aliphatic ^ liamin is preferably used as the curing agent.
図面の簡単な説明  BRIEF DESCRIPTION OF THE FIGURES
第' 1 図は本発明の内張 材の代表的な ^を示す一部破 断斜視図であ !) 、 第 2 図は第 1 図における接着剤含浸用 管状繊布を示す斜視図であ 、 第 3 図は接着剤含浸用管 状織布を円周方向に伸長した形態を示す斜視図であ i? 、 第 4 図は本発明の内張 D 材を適用 した管路の断面を示す 靳面図である。  FIG. 1 is a partially broken perspective view showing a typical ^ of the lining material of the present invention! FIG. 2 is a perspective view showing the tubular cloth for adhesive impregnation in FIG. 1, and FIG. 3 is a perspective view showing a form in which the tubular cloth for adhesive impregnation is extended in the circumferential direction. ? FIG. 4 is a plan view showing a cross section of a pipeline to which the lining D material of the present invention is applied.
発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION
次に添付の図面に よ 本発明をさ らに詳細に説明する。 第 1 図は本発明に係る管路の内張!) 材の代表的な態様を Next, the present invention will be described in more detail with reference to the accompanying drawings. Fig. 1 shows the pipe lining according to the present invention! ) Typical aspects of the material
—部破断斜視図に よって示したも のであ 1? 、 内張 ]? 材 1 は合成樹脂の皮膜 3 を外面に有する管状織布 4 か ら る 気密性管状織布 2 ·と不織布 6 を長さ方向に糸 7 で縫着し て管状と した接着剤含浸用管状織布 5 とから構成さ 1、 管状織布 5 は管状銑布 2 の内側に挿入された形態と なつ て る。 管状織布 5 の外径は管状織布 2 の内径 よ !? も 大 き いため長さ方向に折 目 8 にお て折畳んだ状態にな り 、 こ の不綠布 6 にはほぼ均一に分布する透孔 9 が多数 存在する。 ¾:お管状織布 2 の管状綠布 4は合成繊維の経 糸 a およ び緯糸 ¾ によ 管状に緣製されて る。 The material 1 is shown in a cutaway perspective view. The material 1 is made up of an airtight tubular woven fabric 2 and a nonwoven fabric 6 made of a tubular woven fabric 4 having a synthetic resin film 3 on its outer surface. The tubular woven fabric 5 for adhesive impregnation formed into a tubular shape by sewing with a thread 7 in the longitudinal direction 1, and the tubular woven fabric 5 is inserted into the tubular pig cloth 2. The outer diameter of tubular woven fabric 5 is the inner diameter of tubular woven fabric 2! ? Because of its large size, it is folded at the fold 8 in the length direction, and the non-woven fabric 6 has a large number of substantially uniformly distributed through holes 9. ¾: The tubular woven fabric 4 of the tubular woven fabric 2 is formed into a tubular shape by the warp a and the weft ¾ of synthetic fibers.
第 2 図は第 1 図における管状織布 5 のみを示す斜視図 であ ]? 、 不織布 6 の長さ方向の両端部 10は互 に糸 7に よ 緣かが 方式で縫着されて る。 こ の第 2 図に示し た状態では管状織布 5 は折 り 目 8 で折畳んだ形 と なって るため両端部 10は糸 7 で締付け られて突起を作って る。 第 3 図は管路の内張 ]9 に使用 した場合の管状镄布 5 の斜視図であ 、 この場合は管状織布 5 は円周方向に引 伸されるため折 目 8 は消出 して断面は円形と ¾ 、 そ の際両端部 1.0の突起 も 消失 し、 かが ]9縫い方式で縫着 し た特徵を示す。 FIG. 2 is a perspective view showing only the tubular woven fabric 5 in FIG. 1]. However, both ends 10 in the longitudinal direction of the non-woven fabric 6 are sewn together by a thread 7 to each other. This is shown in Figure 2. In the folded state, the tubular woven fabric 5 has a shape folded at the fold line 8, so that the both ends 10 are tightened by the thread 7 to form a projection. FIG. 3 is a perspective view of the tubular fabric 5 when used for the liner of a pipeline] 9. In this case, the fold 8 disappears because the tubular woven fabric 5 is stretched in the circumferential direction. As a result, the cross section is circular, and the projections at both ends 1.0 disappear at that time.
以下に さ らに具体的 ¾例示に よ 本発明の内張 材の 搆成を説明する。 こ の洌では呼称 3 00 の内径の下水道 用 ヒ ュ ー ム管に本発明の内張 材を適用する。 管状織布 4 は、 経糸 a と緯糸 と を管状に織成 した も ので、 こ の 際の経糸 a は、 1 , 000 d ( フ イ ラ メ ン ト数 288 本 ) の十? リ エ ス テ ル フ イ ラ メ ン ト 糸の非伸長性交絡糸を 6 本撚 合わせ、 それを二本引 き揃えた も のを 320 本 ( 合計 640 本 ) 使用 し、 緯糸 には、 同様に非伸長性交絡長繊維糸 1, 000 デニ ー ルを 8 本撚 合わせた糸条を、 10 cm間に 35 本織込んで、 折畳み幅を約 490 TO と な る よ う に織成する。 これを熱処理 して、 折畳み幅約 44 5 OTにま で収縮させる。 この と き の管状織布 4 の厚みは、 約 1 . 8 腿であ 、 縦方 向の引張 j? 強度は l CTi幅当 ]? 約 2 1 0 であ 、 ま た耐圧 力は約 8
Figure imgf000015_0001
であった。
Hereinafter, the composition of the lining material of the present invention will be described more specifically by way of example. In this kiln, the lining material of the present invention is applied to a sewage hume pipe having an inner diameter of 300. The tubular woven fabric 4 is formed by weaving a warp a and a weft into a tubular shape, and the warp a in this case has a d of 1,000 d (the number of filaments is 288). Twisted 6 non-extensible entangled yarns of Riester filament yarn are used, and 320 of them are aligned and used (total of 640 yarns). Next, eighteen non-stretchable entangled long fiber yarns of 1,000 deniers are twisted, and 35 yarns are woven between 10 cm and woven so that the folding width is about 490 TO. This is heat-treated and shrunk to a folding width of about 445 OT . At this time, the thickness of the tubular woven fabric 4 is about 1.8 thighs, the tensile strength in the longitudinal direction is about l CTi width, which is about 210, and the pressure resistance is about 8
Figure imgf000015_0001
Met.
管状:襯布 4 の外面に気密性の合成樹脂皮膜 3 が形成さ れるが、 この皮膜 3 は一般には無色のボ リ エ ス テ ル彈性 樹脂を押出成型法に よ j? 管状織布 4 の外面に直接被覆す る こ と に よ 形成させる。 その厚みは約 0 . 6 TOであ ]? 、 一般に厚みは 0 . 2 〜 1 . 5 衄程度が適当であ る。 こ の よ う に して気密性管状綠布 2 が形成される。 ¾お管状織布 4 は皮膜 3 を形成させる ために押出機に よ る処理に よって さ ら'に収縮 し、 皮膜 3 が形成された後の気密性管状葳布 2 の折畳み巾は 40 腿であった。 Tubular: An air-tight synthetic resin film 3 is formed on the outer surface of the fabric 4, and this film 3 is generally formed by extruding a colorless polyester resin by an extrusion molding method. J? The outer surface of the tubular woven fabric 4 It is formed by coating directly on the surface. Its thickness is about 0.6 TO] ?, Generally, a thickness of about 0.2 to 1.5 ounces is appropriate. In this way, the airtight tubular fabric 2 is formed. The tubular woven fabric 4 is further shrunk by the treatment by the extruder to form the film 3, and the airtight tubular fabric 2 after the film 3 is formed has a folding width of 40 thighs. there were.
接着剤含浸用管状織布 5 は管状に縫着する前の段階で 穿孔処理に よ 透孔 9 を形成させる。 'この際の透孔 9 の 孔径は約 3 . 5 ∞であ 、 透孔間の最短距離は透孔の中心 か らの長さで約 2 . 5 cmである。 この穿孔処理は慣用の ン チ ン グマ シ ン で不镦布 6 の繊維を完全に切断する形で 穿孔する。 この際使用 した不織布 6 は単糸繊袞約 5 デニ ー ルの ;^ リ エ ス テ ル長織維糸を ニ ー ド ル ンチする慣用 法で厚み約 4 に形成させた も のであ る。 この不綠布の 目 付は約 420 9- Zm2 であった。 この不織布をオー バ、 一 口 ッ ク ( 緣かが 縫い ) 方式の ミ シ ン で長さ方向の両緣が 重 ¾ 合わない よ う にォー パー ロ ッ ク方式の ミ シ ン で管 状に縫着させて接着剤含浸用管状織布 5 を形成させた。 このオー バ、 一 ロ ッ ク方式の縫着は、 所定の巾の不織布を 2枚重ね合わせ端部を約 10 歷程度の縫 巾で縫合し、 詧 状璣布 5 を円周方向に引伸 した際両端部が接合した形と なって互 に重 合わない。 この管状不礅布 6 の折!) 巾は約 460 mmで あった。 この管状载布 5 は次 で適当 方法で管状識布 2 の内側に挿入する。 この状態の内張 .り 材 1 は第 1 図に示した とお j? であ る。 The through-hole 9 is formed by a perforation process in the stage before the tubular fabric 5 for impregnating the adhesive is sewn into a tube. 'The diameter of the through hole 9 at this time is about 3.5 mm, and the shortest distance between the through holes is about 2.5 cm from the center of the through hole. This perforation is performed by completely cutting the fibers of non-woven fabric 6 with a conventional etching machine. The nonwoven fabric 6 used at this time was formed to a thickness of about 4 by a conventional method in which a single-filament monofilament of about 5 denier; The basis weight of this non-woven fabric was about 4209-Zm 2 . This non-woven fabric is covered with an over-lock type sewing machine so that the lengthwise ends of the non-woven fabric are not overlapped. To form an adhesive-impregnated tubular woven fabric 5. In this overlock, one-lock sewing, two nonwoven fabrics each having a predetermined width are overlapped, the ends are sewn with a sewing width of about 10 mm, and the 詧 -shaped cloth 5 is stretched in the circumferential direction. In this case, both ends are joined and do not overlap each other. Fold this tubular real cloth! ) The width was about 460 mm. This tubular cloth 5 is then inserted inside the tubular cloth 2 by an appropriate method. The lining material 1 in this state is j? As shown in Fig. 1.
次にこ の内張 _り 材 1 を ヒ ュ ー ム管路内面に適用する方 法について説明する。 Next, apply this lining material 1 to the inner surface of the fume pipe. The method will be described.
先ず内張 材 1 の内面にェ ボキ シ系接着剤を塗布する 内張 材 1 に接着剤を塗布するには内張 ]9 材の内部を排 気 し、 内張 材 1 内に接着剤を注入 し、 その内張 材を ニ ッ プ α — ラ ー間に通 し、 接着剤を絞って内張 -り 材 1 の 全長に均一に行き 亘 らせる。 接着剤には前述 した芳香族 ^ リ ア ミ ン を硬化剤と して使用するのが好ま し 。 さ ら に具体的には、 この例において主剤がェ ヒ。 ビス型のエ ホ? キ ン系樹脂であ 、 硬化剤が変性芳香族ボ リ ア ミ ンであ つて混合粘 ¾ 5, 000 c ps ( J I SK 6 8 33 の 6 、 3 項に準 じ て B 型回耘粘度計で測定 ) の も のであった。 充 ¾剤 と し ては炭酸カ ル シ ウ ム を使用 した。 こ の接着剤を約 6 / m 2の量で内張 ]? 材の内 '面に塗布 した。 接着剤を塗布 した 内張 !) 材は次 で公知の適当 方法、 例えば米国特許第 4, 334, 943 号明細書に記 の反転内張 方法に よ 、 流 体圧力で内張 材を裏返 しなが ら管路内に挿通 して内張 .り 、 次いで水蒸気な どで加熱 して接着剤を硬化させる。 こ の際の裏返 し ( 反転 ) に要する圧力はこの例では 0 . 8 /en であった。 この よ うに して ヒ ュ ー ム管路内面に内 張 1? 材を適用 した。 First, apply an epoxy adhesive to the inner surface of the lining material 1. To apply the adhesive to the lining material 1, evacuate the inside of the lining material 9 and apply the adhesive to the lining material 1. The lining material is injected, and the lining material is passed between the nip α-lines, and the adhesive is squeezed to evenly spread the entire length of the lining material 1. As the adhesive, it is preferable to use the above-mentioned aromatic ^ liamine as a curing agent. More specifically, in this example, the main agent is eh. Screw-type eho? Quin-based resin, the curing agent is a modified aromatic polyamine, and the mixed viscosity is 5,000 cps (B type reclaiming viscometer according to paragraphs 6 and 3 of JI SK 6833). Measured at). Calcium carbonate was used as the filler. This adhesive was applied to the inner surface of the lining material in an amount of about 6 / m 2 . Lining with glue applied! The material is then inserted into the pipeline by turning it upside down at fluid pressure by a suitable method known in the art, for example, the reversing lining method described in US Pat. No. 4,334,943. Then, the adhesive is cured by heating with steam or the like. In this case, the pressure required for turning over was 0.8 / en in this example. In this way, the lining 1 was applied to the inner surface of the fume pipe.
第 4 図はこの よ う に して内張 !) された ヒ ュ ー ム管路の 断面を示す。 ヒ ュ ー ム管 10の内面には接着剤層 11があ 、 その上に この接着剤 と一体に結合 した管状織布 5 およ び 管状織布 2 が位置 している。 こ の際、 合成樹脂の皮膜は 内張 -り 材の最内層を形成する。 本発明の内張 ]5 材は、 管状織布を有して 、 縦方向 に充分な強度を有 しているので、 免震性を発揮する。 免 震性の試験において 1 m 長さの 3 00 Mi ø の ヒ ュ ー ム管を 単に き合わせておき、 それに内張 _り 材を装着 した もの を供試体と し、 その両端に引張 荷重を載荷した と こ ろ、 9 t o n程度で内張 ]9 材がヒ ュ ー ム管よ j9 はがれ出 した。 両管端の開 口 ^が 70龍に った と き、 引張 -り 荷重は 1 0 . 5 t onであった。 ま た ヒ ュ ー ム管には 方向にク ラ ッ クが 生 じた。 ヒ. ユ ー ム管 よ はがれた内張 ]9 针は損傷 してお らず、 硬 イ ブを形成して た。 従って、 地震な どに よ 管路が破瘗されたよ う る場合に も、 管铬と内張 ]? 材 が 錐 し、 内張 材が若干伸びる こ と に よってエネ ル ギ 一 を吸収し、 内張 _り 材が破断する こ と な く 、 内張 -り 材単 独で充分に流体の通路が確保で き る。 Fig. 4 is lining like this! The cross section of the fume line is shown. An adhesive layer 11 is provided on the inner surface of the fume tube 10, and a tubular woven fabric 5 and a tubular woven fabric 2 integrally bonded to the adhesive are located thereon. At this time, the synthetic resin film forms the innermost layer of the lining material. The lining material of the present invention] 5 material has a tubular woven fabric and has sufficient strength in the longitudinal direction, so that it exhibits seismic isolation. In the seismic isolation test, a 300-millimeter hume pipe of 1 m length was simply joined together, and the specimen with the lining material attached was used as a test specimen.A tensile load was applied to both ends of the specimen. At the time of loading, the liner was about 9 ton], and the 9 pieces came off the hume tube. When the opening of both pipe ends was 70 dragons, the tensile load was 10.5 ton. In addition, cracks occurred in the hume tube in the direction. The inner lining that peeled off from the tube was not damaged and formed a hard eve. Therefore, even if the pipeline is damaged due to an earthquake or the like, the pipes and the lining will be conical, and the lining will be stretched slightly, thereby absorbing energy. The inner lining material alone can sufficiently secure a fluid passage without breaking the lining material.
管か ら内張 材を剝す力を応力 と して受け持って る のは基本的に管状織布のたて方向の強さであ 、 この実 験の結果か ら判断すれば、 たて方向の引張 .り 強度が 1 ^ ¾ 120 以上あれば内張 j5 材は破損 しないこ と になる。 そして、 この よ う なたて方向に強 も のを得よ う とする と織布以外の も のは難し と言える。  It is basically the strength in the vertical direction of the tubular woven fabric that bears the force that pushes the lining material from the pipe as stress, and judging from the results of this experiment, the vertical direction If the tensile strength is more than 1 ^ ¾120, the lining j5 will not be damaged. And if you try to get strength in this vertical direction, it can be said that things other than woven cloth are difficult.
本発明の内張 材では管状,载布 5 に透孔が均一に分布 して多敎設けてあ るため、 接着剤を垒布 した餒、 不 布 だけでな く、 これ ら透孔を通して管状弒布 2 に も 多量の 接着剤が含浸される。 ま たこの透孔の存在で前記した不 滅布のろ過現象がな く な 、 接着剤成分が均質に管状威 布 2 に供給さ れる利点が あ る。 従って管络に適用 後に硬 化 させる と 管状織布 2 お よ び管状織布 5 と は一体に接着 して厚 層 を形成で き る。 こ の よ う に、 透孔 が存在する こ と に よ ]? 分厚い硪維層に 多量の接着剤を 含浸 し、 内張 材 を管路に 内張 された状態において、 剛 直 な管 を管 絡内に形成で き 、 管路に既に孔が あいて る場合や、 新 たに孔があ て地下水が侵入 した よ う な場合であ って も、 内張 材が押 し潰 さ れる よ う な こ と が く 、 前述の外水 E保形性を 確保で き る。 充分な 厚みを 有す る ため には、 管状 布 5 を単層 で使用す る場合に厚 さ力 s 2 〜 8 mであ るの が好ま しい。 この厚みが 2 雌 よ も 小 さ い場合は厚 みの確保が不充分 と .り 、 ま た 8 よ も 大 き 場合は 管状織布 5 に接着剤が均質に含浸さ れな 。 ま た管状 ,識 布 5 と しては 2 〜 8 デニ ー ル の' ' リ エ ス テ ル锇維糸 を 用 いて乾式ス ン ボ ン ド法で不纖布 を形成 した も のが接着 剤の含浸性お よ び強度にお て優れて る ので好適であ る。 さ らに透孔の形成には、 ト ム ソ ン の ン チ マ シ ー ン ¾ ど に よ 1? 完全に繊維を切断 して開 口 する も のが接着剤 の透過性 よ び含浸性に優れて るので好適であ る。 In the lining material of the present invention, since the through-holes are uniformly distributed in the pipe 5 and the cloth 5 is provided in a large number, not only the cloth and the non-woven cloth with the adhesive, but also the pipe through these holes.弒 Fabric 2 is also impregnated with a large amount of adhesive. In addition, the presence of this through hole eliminates the above-mentioned filtration phenomenon of the immortalized cloth, and the adhesive component is homogeneously tubular. It has the advantage of being supplied to cloth 2. Accordingly, when the tubular woven fabric 2 and the tubular woven fabric 5 are hardened after being applied to the pipe, they can be integrally bonded to each other to form a thick layer. In this way, there is a through hole.]? A thick fibrous layer is impregnated with a large amount of adhesive, and a rigid pipe is lined with the lining material lined in the pipe line. It can be formed in the entanglement and the lining material will be crushed even if there is already a hole in the pipeline or if there is a new hole and groundwater has entered. As a result, the above-mentioned external water E shape retention can be secured. In order to have a sufficient thickness, when the tubular cloth 5 is used as a single layer, the thickness force is preferably s 2 to 8 m. If the thickness is smaller than 2 females, it is not sufficient to secure the thickness, and if it is larger than 8, the tubular woven fabric 5 is not uniformly impregnated with the adhesive. In addition, the non-fiber fabric is formed by dry-bonding using a 2 to 8 denier '''reestar fibrous weft thread as the tubular cloth 5. It is suitable because of its excellent impregnation and strength. To form the through-holes, it is necessary to use the Thomson's multi-machine method. 1) Cutting the fiber completely and opening it will reduce the permeability and impregnation of the adhesive. It is preferred because it is excellent.
透孔は 2 〜 8 丽 ø 程度の大 き さ で、 透孔間の最短距鱸 を 1 . 5 〜 6 OTI程度 と して全面に亘つて均一に形成す るの が良い。 透孔が小 さす ぎた ]? 、 あ るいは間隔が大 き す ぎ る と 管状織布 2 への接着剤の含浸効果が少 ¾ 。 ま た、 透孔 が大 き す ぎた 、 間隔がせま す ぎる と 内張 材の強 度低下を き たすおそれが生 じる。 さ らに透孔を設ける こ と に よ ? 、 管状織布と管状不銑 布と の間の剥離強度が増 して管状截布と管状不織布と の 一体化を促進させている。 本発明者が不織布に透孔が い も'の と透孔がぁ る も のについて管状織布 2 と 管状緣布 5 との間の密着剝錐強度 ( 180° ) を調べた際、 透孔を有 する も のは 6 〜 7 ¾r / COTであったのに対 し、 透孔のない も のは 3 〜 4 K / cmであった。 It is preferable that the through holes have a size of about 2 to 8 丽 ø, and the shortest distance between the through holes is about 1.5 to 6 OTI, so that the holes are formed uniformly over the entire surface. If the through-holes are too small] or too large, the effect of impregnating the tubular woven fabric 2 with the adhesive is small. Also, if the perforations are too large or too small, the strength of the lining material may be reduced. By providing additional holes? On the other hand, the peel strength between the tubular woven fabric and the tubular non-iron fabric is increased, and the integration of the tubular cut fabric and the tubular nonwoven fabric is promoted. When the present inventor examined the close contact cone strength (180 °) between the tubular woven fabric 2 and the tubular fabric 5 for the nonwoven fabric having the through hole and the through hole, the through hole was determined. Those with porosity were 6-7 ¾r / COT, while those without porosity were 3-4 K / cm.
ま た、 管路の径が大き ぐ な る場合や、 よ ]? 大き い外水 圧を受けるおそれがあ る場合では、 不織布の層厚を増加 すれば よ ぐ、 こ の際単層で厚みを増加するには現界がぁ るので不緣布を二重、 三重の多層にする方が好ま しい。  In addition, when the diameter of the pipeline is large, or when there is a risk of receiving a large external water pressure, the layer thickness of the non-woven fabric should be increased. Since the real world increases in order to increase the number of layers, it is preferable to make the nonwoven fabric double or triple multilayer.
この場合に も 各不織布層の厚みは 2 〜 8 籠と し、 各層 に透孔を形成 してお く のは言 う まで も ¾い。 更に透孔が あるために接着剤に よ る不織布の含浸が充分と ¾ 各不 綠布間で剥錐は起 ]9難い。  Also in this case, it is needless to say that the thickness of each nonwoven fabric layer is set to 2 to 8 baskets, and a through hole is formed in each layer. Furthermore, because of the perforations, the impregnation of the non-woven fabric with the adhesive is sufficient.
前記の実施例においては、 気密性管状織布の折 幅が In the above embodiment, the folded width of the airtight tubular woven fabric is
440 廳 ( 外径で約 280 腿 ? 5 ) であ 、 内側の接着材含浸 用管状織布の折 幅が 60 皿 ( 外径で 293 纖 Φ であつ て、 反転 した後は空気圧力 0.5 /c z 程度で外径約 300 丽 ? 5 にまで達するので気密性管状織布お よび接着材含浸 用管状嶽布も共に、 全 く シ ヮのない状態で内張 する こ と ができ る。 この よ う に膨張性が良いのは、 気密性管状織 布の最初の折幅 490 m (外径で約 Λ2皿 Φ ) を熱処理をす る こ どに よ ]? 小さ く しているので、 小さい正力で管内径 よ ]?大き ぐ膨らむよ う に してあ るこ と と、 接着剤含浸用 管状織布の径 を 気密性管状 ,識布の径 ょ も 大 き ぐ してあ る こ と に よ る 。 更に接 着剤含浸用 管状識布の径 を気密性 管状^布の径 ょ り も 大 き ぐ して あ る こ と が、 気密性管状 ,識布の 巾 で管状織布 と 管状不辙布 と の間 でずれ る こ と が で き 、 柔軟性に富み内張 -り 材を裏返す !祭の流 体圧 力 を低 く 保持で き る。 ま た、 管状不識布 を 多層に し て厚みを確 保す る場合には、 最内層 のみ を縫 . して中間 に位置する .養 を 重侵 さ せて く こ と も で き る 。 最内層 を縫製 して ¾ い場合は、 内張 .り 材の 反耘時に不織布がずれて しま い、 シ ヮ の発生の原因 と ¾ るの で好ま し ぐ い。 さ ら に、 管 状不銑布が多層 を形成 してい る場合は、 不 ^布層の径が 気密性管状織布の 径 よ も 大 き く 、 しか も 内層に位置す る も の程大 き く してお く と 内張 .り 材が反転 しやすいので 望ま しい。 ただ し、 全て管径 よ は幾分小さ く してお く 必要はあ る。 At 440 cafe (about 280 thighs in outer diameter? 5), the inner width of the tubular woven fabric for impregnating the adhesive is 60 plates (293 fiber in outer diameter, and air pressure is 0.5 / c after reversal) Since the outer diameter reaches approximately 300 mm 5 at about z , both the airtight tubular woven fabric and the tubular damp fabric for impregnating the adhesive can be lined without any gaps. The reason why the expandability is good is that the first fold width of the airtight tubular woven fabric is 490 m (approximately Λ2 plates Φ) in which the heat treatment is performed.]? The inner diameter of the pipe is increased by force. ?? This is because the diameter of the tubular woven fabric is air-tight and the diameter of the fabric is also large. Furthermore, the diameter of the tubular cloth for the adhesive impregnation is larger than the diameter of the airtight tubular cloth. It is very flexible and keeps the lining material upside down! The fluid pressure of the festival can be kept low. In addition, when the tubular insulated cloth is formed in multiple layers to secure the thickness, it is possible to sew only the innermost layer to cause heavy damage to the intermediate layer. If the innermost layer is sewn, it is preferable because the nonwoven fabric will be displaced when the lining material is re-tilled, which may cause the generation of seams. In addition, when the tubular non-pigmented cloth forms a multilayer, the diameter of the non-woven cloth layer is larger than the diameter of the airtight tubular woven cloth, and the larger the diameter of the non-woven cloth is located in the inner layer. This is desirable because the lining material can easily be turned over. However, it is necessary to keep them all slightly smaller than the pipe diameter.
ま た、 管状織布に非伸長性交絡長織維糸 を使用する こ と に よ 、 外面の合成樹脂の皮膜 と 管状織布 と の剝離強 度 を 向上 さ せる こ と が で き る。 前記の ^では絰糸、 緯糸 の全てに非伸長性交絡長繊維糸 を使用 した も ので あ るが 管状' 布 と 合成樹脂の皮膜 と の密着剝離強度 ( 1 8 0 度剝 離 ) は約 ] 0 cmであ 、 こ れは、 全て長鐡維糸 を 使用 した も のが約 1 〜 2 Z cmであ る場合 と 比較 して実に約 5 〜 10掊の強度で あ る。 この ため外部すな わ ち管状織布 の側か ら 外水圧 を受けて も皮膜が剝雜す る おそれが く る る。 こ の よ う ¾ 現象は、 非伸長性交絡長繊維糸 が嵩高 の ために、 皮膜を形成 して る樹脂が非伸長性交絡長豭 維糸の内部にま で食い込んで錨幼果を達成 し、 しか も 長 鐡維糸であ る ため、 糸の抜け 出 しがお こ に く く 、 剝離 強度 *向上す る と 考え られる。 Further, by using the non-stretchable entangled long-weft yarn for the tubular woven fabric, the separation strength between the outer surface of the synthetic resin film and the tubular woven fabric can be improved. In the above-mentioned ^, although non-extensible entangled long fiber yarn is used for all of the 絰 yarn and the weft yarn, the adhesion separation strength (180 degree separation) between the tubular fabric and the synthetic resin film is about] It is 0 cm, which is about 5 to 10 mm in strength compared to the case of using a steel wire of all lengths of about 1 to 2 Zcm. For this reason, even if external water pressure is applied from the outside, that is, from the side of the tubular woven fabric, the film is less likely to be grown. This phenomenon is due to the fact that the non-extensible entangled long fiber yarn is bulky. As a result, the resin forming the film penetrates into the non-extensible entangled long weft thread to achieve an anchor fruit, and the thread escapes because it is a long iron weft thread. However, it is considered that the separation strength * is improved.
こ こ で、 非伸長性交絡長繊維糸は、 経糸お よ び瑋糸の 両方に使用する必要は な ぐ 、 非伸長性交絡長镄維糸 と通 常の長繊維糸ま たは短繊維糸 と 混撚 して、 使 ¾ して も その効果は発揮で き る。  Here, the non-extensible entangled long fiber yarn does not need to be used for both the warp yarn and the long yarn, but the non-extensible entangled long fiber yarn and the ordinary long fiber yarn or short fiber yarn are used. The effect can be exhibited even if it is mixed and twisted.
なお、 非伸長性交絡長鐵維は、 通常の ウ ー リ — 糸が乾 熱下で捲縮加工を施すのに対 して、 ス チ ー ム な どの湿熱 下で捲縮加工を行い、 カ ー ル状態 と った糸 を 高温状態 で固定 して伸びを少な ぐ して る 。 故に、 通常の ウ ー リ 一糸 と よ く 似た形状の糸 と な って る が伸 びが 20 %以下 と ってお 、 強度 も 高い。 お織布、 不幾布の ずれ に も ' リ エ ス テ ル繊維を用 るのが強度の 点で望ま し 。 ボ リ エ ス テ ルは耐薬品性、 耐摩耗性に も 秀れ、 耐久性が 加味される 点で も 望ま しい。 同様に合成澍脂の皮!莫に使 用する樹脂も ^ リ エ ス テ ル弾性樹脂であ るのが望ま し ぐ、 強度と 共に耐薬品性、 耐摩耗性が具備される。 ま た皮膜 を着色し な で 使用する と樹脂 自 体が透明 る ため、 接.着 剤が不綠布を通 して管状織布の布 目 に含浸 している か ど う か を外部か ら観察する こ と がで き る ので有利である。  The non-extensible entangled filaments are crimped under wet heat such as steam, whereas ordinary wool-yarns are crimped under dry heat. The thread in the rolled state is fixed at a high temperature to reduce elongation. Therefore, it is a yarn with a shape very similar to a regular wool yarn, but has an elongation of 20% or less and high strength. It is desirable to use vestile fibers for the displacement of woven cloth and non-woven cloth in terms of strength. Polyester is also excellent in chemical resistance and abrasion resistance, and is desirable because durability is added. Similarly, synthetic resin skin! It is desirable that the resin to be used enormously is a エ テ 、 弾 性 弾 性 弾 性 樹脂 弾 性 樹脂 、 、 、 、 、 薬 品. If the coating is used without coloring, the resin itself will be transparent, so it will be necessary to check from the outside whether the adhesive has passed through the non-woven cloth and impregnated into the mesh of the tubular woven cloth. This is advantageous because it allows observation.
産業上の利用町能性  Industrial use
本発明の内張 ir材は従来の内張 _り 林の特性に加えて優 れた免震性お よ び外水圧保形性を 有 して るため、 軟弱 ¾土地ま たは埋立地に埋設 した管路の 補強に特に好適で あ る。 ま た ガス 導管、 石油 ハ。 イ ブ ラ イ ン 、 水道管、 下水 道管を始め と して電力地下 ケ ー ブ ル等各種の管路の補強 に利用する こ と がで き る。 The lining material of the present invention is soft because it has excellent seismic isolation and water pressure retention in addition to the characteristics of the conventional lining forest. 特 に Suitable for reinforcing pipes buried in land or landfills. Also gas pipelines and oil c. It can be used to reinforce various pipelines such as electric lines, water pipes, sewage pipes, and underground power cables.

Claims

請 求 の 範 囲 The scope of the claims
1 . 内面に接着剤を塗布 した管状の内張 材を、 管路内 に挿通 し、 流体圧力に よ 裏返しなが ら管路内を前進 させ、 裏返された内張 材を管路内面に圧着 しなが ら 張 材と管路との間に介在させる前言 P接着剤に よ 管路内面に接着させる管路の内張 ]) 方法に使用する前 記内張 材であって、 この内張 材が外面に合成樹脂 皮膜を形成 した管状に織成 した気密性管状織布と、 そ の内側に挿入されたほぼ均一に打ち抜く こ とに よって 形成された透孔が設け られた不織布よ り ¾ る接着剤含 浸用管状緣布とからなるこ とを特徵とする管路の内張 材。  1. Insert a tubular lining material with an adhesive applied to the inner surface into the pipeline, advance it inside the pipeline while turning it over with fluid pressure, and crimp the inverted lining material to the inner surface of the pipeline However, the above-mentioned lining material used in the method described above, which is used in the method described above, which is interposed between the lining material and the pipe line, and which is adhered to the inner surface of the pipe line with an adhesive P) It is made of an airtight tubular woven fabric woven into a tubular shape with a synthetic resin film formed on the outer surface, and a nonwoven fabric with a through hole formed by punching almost uniformly inside it. A pipe liner characterized by comprising a tubular cloth for adhesive impregnation.
2 . 接着剤含浸用管状織布は、 その外径が気密性管状銑 布の内径よ も 大き く 、 長さ方向に折畳んだ状態で前 記気密性管状綠布の内側に挿入 してある特許請求の範 囲第 1 項記載の管路の内張 材。  2. The adhesive impregnated tubular woven fabric has an outer diameter larger than the inner diameter of the airtight tubular pig cloth, and is inserted inside the airtight tubular cloth in a state of being folded in the longitudinal direction. A lining material for a pipeline according to claim 1.
3 . 接着剤含浸用管状繳布は、 単層の不嶽布、 ま たは積 層された不綠布に よって構成されてい る特許請求の範 囲第 2項記載の管路の内張 材。  3. The liner according to claim 2, wherein the adhesive-impregnated tubular cloth is constituted by a single-layer non-woven cloth or a laminated non-woven cloth. .
4 . 不緣布は、 少な く と もその最内層を構成する不綠布 が、 帯状に長い不銑布を、 その長さ方向の両緣を緣か が 縫方式に よ ]) 両緣が重な 合わない よ う に縫着し、 管状に形成 してあ る特許請求の範囲第 3項記載.の管路 の内張 材。 4. At least the non-woven cloth constituting the innermost layer is a long strip of non-woven cloth, and both sides in the longitudinal direction of the non-woven cloth are stitched.]) 4. The pipe liner according to claim 3, which is sewn so as not to overlap and is formed in a tubular shape.
5 . 不織布が、 単 度 2 〜 8 のボ リ エ ス テ ル轍維糸の 乾式 ス パ ン ボ ン ド不織布で あ る特許請求の範囲第 4 項 記載の管路の内張 材。 5. The non-woven fabric is made of 2 to 8 balls The lining material for a pipeline according to claim 4, wherein the lining material is a dry spunbond nonwoven fabric.
6 . 不織布は、 その厚 さ が 2 〜 8 丽で あ って 、 それに形 成 される透孔は 、 その孔径が 2 〜 8 履 で あ j 、 透孔間 の最短距離が 15〜 60 履の間隔で形成 されてい る特許請 求の節囲第 5 項記載の管路の内張 材。  6. The non-woven fabric has a thickness of 2 to 8 mm, and the through holes formed in it have a diameter of 2 to 8 pairs, and the shortest distance between the through holes is 15 to 60 pairs. The pipe liner according to paragraph 5 of the patent request, which is formed at intervals.
7 . 気密性管状織布は 、 その合成樹脂皮膜に ボ リ エ ス テ ル弾性樹脂 を使用 した も ので あ る特許請求の節囲第 1 項記載の管路の内張 材。  7. The pipe liner according to claim 1, wherein the airtight tubular woven fabric is made of a synthetic resin film made of a polyester elastic resin.
8 . 気密性管状織布は、 その綠布に ボ リ エ ス テ ル辮維の 非伸長性交絡長 維糸、 ま たは こ の非伸長性交絡長繊 維糸 と ボ リ エ ス テ ル長辨維糸 、 ま たは リ エ ス テ ル短 繊維糸の混撚糸 を、 経糸 ま たは緯糸の少 く と も 一方 に使用 して な る特許請求の範囲第 7 項記載の管路の内 張 j? 材。 8. The air-tight tubular woven fabric is made of a non-stretchable entangled long fiber of Boliester braid, or a non-stretchable entangled long fiber of Boliester braid 7. The pipe line according to claim 7, wherein a long-twisted yarn of a long-benth weft or a staple short fiber yarn is used for at least one of a warp and a weft. Lining j?
PCT/JP1986/000336 1986-06-30 1986-06-30 Lining material for duct WO1988000133A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE19863690685 DE3690685T1 (en) 1986-06-30 1986-06-30
PCT/JP1986/000336 WO1988000133A1 (en) 1986-06-30 1986-06-30 Lining material for duct
NO87873635A NO873635L (en) 1986-06-30 1987-08-28 PIPE LINING MATERIAL.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP1986/000336 WO1988000133A1 (en) 1986-06-30 1986-06-30 Lining material for duct

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005075186A1 (en) * 2004-02-09 2005-08-18 Gale Pacific Limited A fabric, and its manufacture and applications therefor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1449455A (en) * 1972-12-08 1976-09-15 Insituform Pipes & Structures Lining of passageways
US4368091A (en) * 1978-12-29 1983-01-11 Tokyo Gas Co. Ltd. Method for providing the inner surface of a pipe with a flexible tubular lining material through a liquid resin under pressure
JPS61143128A (en) * 1984-12-17 1986-06-30 芦森工業株式会社 Inner lining material for duct

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1449455A (en) * 1972-12-08 1976-09-15 Insituform Pipes & Structures Lining of passageways
US4368091A (en) * 1978-12-29 1983-01-11 Tokyo Gas Co. Ltd. Method for providing the inner surface of a pipe with a flexible tubular lining material through a liquid resin under pressure
JPS61143128A (en) * 1984-12-17 1986-06-30 芦森工業株式会社 Inner lining material for duct

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005075186A1 (en) * 2004-02-09 2005-08-18 Gale Pacific Limited A fabric, and its manufacture and applications therefor

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DE3690685T1 (en) 1988-06-01
NO873635D0 (en) 1987-08-28

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