WO1986003137A1 - Mixing tee check valve and method - Google Patents

Mixing tee check valve and method Download PDF

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Publication number
WO1986003137A1
WO1986003137A1 PCT/US1985/002276 US8502276W WO8603137A1 WO 1986003137 A1 WO1986003137 A1 WO 1986003137A1 US 8502276 W US8502276 W US 8502276W WO 8603137 A1 WO8603137 A1 WO 8603137A1
Authority
WO
WIPO (PCT)
Prior art keywords
inlets
valve
outlet
seal
inlet
Prior art date
Application number
PCT/US1985/002276
Other languages
French (fr)
Inventor
Lev J. Leytes
Harry A. Penhasi
Original Assignee
Beckman Instruments, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beckman Instruments, Inc. filed Critical Beckman Instruments, Inc.
Publication of WO1986003137A1 publication Critical patent/WO1986003137A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/105Mixing heads, i.e. compact mixing units or modules, using mixing valves for feeding and mixing at least two components
    • B01F25/1051Mixing heads, i.e. compact mixing units or modules, using mixing valves for feeding and mixing at least two components of the mixing valve type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/105Mixing heads, i.e. compact mixing units or modules, using mixing valves for feeding and mixing at least two components

Definitions

  • This invention relates generally to mixing valves with independent inlet ports that feed a common outlet and particularly to a fluid pressure actuated valve for mixing liquids in a DNA synthesizer and in other systems in which fluids are mixed.
  • Prior mixing valves require either manual control or employ electrical or pneumatic actuators to control the positions of valve seals relative to corresponding valve seats to switch the valve between inlets.
  • Manually controlled mixing valves are incompatible with the concept of modern automated systems.
  • Prior electrically or pneumatically controlled mixing valves typically require secondary control circuits that must be either manually controlled or include secondary control system to insure proper operation.
  • Such prior mixing valves are of necessity complicated and expensive, and they are often unreliable in providing the desired control of fluids to be mixed.
  • the electrically actuated mixing valves includes a compact solenoid operated mixing valve with a small dead volume.
  • This device has the disadvantage of requiring an electrical signal for actuation, which creates the danger of fire or explosion when used to control the flow of highly flammable fluids.
  • the control system for the solenoid is expensive and does not have the desired degree of reliability for use in analytical instrumentation.
  • a mixing control valve arrangement sometimes used in hydraulic drives of heavy machinery and equipment includes two ordinary check valves connected together with a T-shaped conduit. This arrangement is unsatisfactory for scientific analytical instrumentation because of the large dead volume in the conduit, -and the intermixing of the fluids in the two input legs.
  • the present invention overcomes the deficiencies of the prior art by providing a compact mixing valve that requires no expensive external control system, provides increased reliability of operation, has zero dead volume and that poses no safety hazard from fire, explosion or excessive pressure build-up.
  • the present invention includes a housing having at least two inlet ports and one outlet port that intersect at a valve chamber.
  • a valve core within the valve chamber includes passages in fluid communication with the inlet and outlet ports. The passages intersect at a valve cavity within the valve core.
  • An elastomeric seal is retained within the valve cavity and sealingly engaged with the portions of the valve core around the passages in the absence of fluid pressure in the inlets. Injection of a pressurized fluid in one of the inlets causes the seal to move away from both the corresponding inlet passage and the outlet passage so that the pressurized fluid flows from the pressurized inlet port to the outlet port.
  • Application of a pressurized fluid to a first one of the inlet ports compresses the seal around the other inlet port to provide a tighter seal than existed before application of pressure to the first port.
  • the present invention includes a method of mixing fluids comprising the steps of forming a housing having at least a first inlet, a second inlet, and an outlet such that the first and second inlets and the outlet intersect at a valve chamber for selectively transferring fluids from one of the first and second inlets to the outlet; placing a pressure-controlled seal in the valve chamber to prevent fluid flow from the first and second inlets when the pressure in the first and second inlets is below a predetermined value; and pressurizing one of the first and second inlets with a fluid to break the seal between the pressurized inlet and the valve.
  • Figure 1 is a plan view of a mixing valve according to the present invention.
  • Figure 2 is a cross sectional view of the mixing valve of Figure 1 taken along line 2-2;
  • Figure 3 is a fragmentary cross sectional view taken along line 3-3 of Figure 2;
  • Figure 4 is a fragmentary view illustrating deformation of a seal included in Figures 1-3 when a pressurized fluid is applied to an inlet port;
  • Figure 5 is an end view of a seal included in the mixing valve of Figures 1-4.
  • a mixing valve 10 includes a housing 12 having, for example, a pair of inlets 14 and 16 and an outlet 18 therein.
  • a valve core 20 is positioned in a chamber 22, which may be conveniently centrally positioned within the housing 12.
  • the housing 12 may be formed of any suitably rigid material by conventional techniques, such as casting, machining or molding to include the inlets 14 and 16 and the outlet 18.
  • the valve core 20 is shown as a separate component of the valve 10, the core 20 may be integrally formed with the housing 12, in which case the housing 12 should be formed of a material that is chemically inert with respect to the fluids to be transferred with the valve 10.
  • the valve core 20 is inserted into the housing 12 through an opening 24, best shown in Figure 2, at a side 26 of the housing 12. As shown i Figure 1 and 2, a cover 28 retains the valve core 20 within the chamber 22. A pair of screws 30 and 32 are suitable for retaining the cover upon the housing 12.
  • the valve core 20 is dimensioned to fit within the chamber 22 so that when the cover 28 is secured to the housing 12, the valve core 20 is restrained against movement relative to the housing 12.
  • the valve core 20 includes a first passage 34 in fluid communication with the inlet 14, a second passage 35 in fluid communication with the inlet 16, and a third passage 36 in fluid communication with the outlet 18.
  • the passages 34-36 intersect at a core cavity 38 that may be conveniently centrally located in the core 20.
  • the core cavity 38 may be conveniently formed as a passage through the core 20.
  • a pair of plugs 40 and 42 seal opposite ends of the core cavity 38 to prevent undesired fluid flow therefrom.
  • a seal 44 that is preferably formed of an inert elastomer is inserted into the core cavity 38 before the ends thereof are plugged.
  • the seal 44 Is preferably tubular, having a void 45 therein, although other configurations, such as a hollow sphere, function satisfactorily.
  • the cover 28 is secured to the housing to retain the plugs to complete the assembly of the valve 10.
  • the plugs 40 and 42 retain the seal 44 therebetween so that the elastomeric seal 44 contacts the core 20 to seal the inlets 14, 16 and the outlet 18, as best shown in Figure 3.
  • the elastic resilience of the seal causes both inlet ports 14 and 16 to be sealed.
  • the seal 44 has a side 46 that becomes exposed to fluid pressure.
  • the side 46 deflects inwardly toward the hollow region of the tubular seal 44 away from sealing engagement with the inlet 14 and the outlet 18 to allow liquid to flow through the inlet 14 and the passage 34 into the core cavity 38 and out through the passage 36 to the outlet 18.
  • Figure 4 shows the compression of the seal 44 as being linear. In actual practice the compression of the seal 44 could form a configuration different from that illustrated.
  • the seal 44 Upon removal of fluid pressure from the side 46 of the seal 44, the seal 44 expands against the core 20 around the passage 34 to prevent fluid flow from the inlet 14 into the core cavity 38, thus terminating fluid flow between the inlet 14 and the outlet 18.
  • Fluid pressure in the inlets 14 and 16 controls the entire operation of the valve 10.
  • the valve 10 has no dead volume of fluid that remains to flow to the outlet 18 after the seal has closed one of the passages.
  • the valve 10 prevents the accumulation of potentially dangerous pressures in the inlets 14, 16 and supply lines (not shown) that may be connected thereto because a sufficiently high pressure in an inlet will open the seal 44 to permit fluid flow and relief of the high fluid pressure. If both inlets 14 and 16 should become highly pressurized, the seal 44 will compress inwardly and permit fluid flow form both inlets 14 and 16 to the outlet 18. Proper selection of the dimensions of the core cavity a-nd the dimension sand the elasticity of the seal 44 provide control of the fluid pressure required to open the seal when one or both of the inlets 14, 16 are pressurized.
  • valve 10 It is also necessary that the materials that will become wetted with fluids being mixed in the valve 10 be inert to the fluids to be transferred through the valve 10.
  • materials that are inert with respect to the fluids being transferred are well-known in the art and is also required with prior art mixing valves.
  • polymeric substances well- known in the art that are suitable for forming the wetted components of the valve 10, such as the interior of the inlets 14, 16, the outlet 18, the passages 34-36, the valve chamber 22, the core cavity 38, and the plugs 40, 42.
  • the core 20 may be satisfactorily formed of a fluoropoly er plastic material sold under the name KEL-F, a trademark of the 3M Company.
  • the plugs 40, 42 may be formed of a fluoro ⁇ arbon material sold under the name TEFLON, a trademark of E. I. Du Pont Nemours.
  • the seal 44 may be formed of a perfluoroelastomer sold under the name KALREZ, a trademark of E. I. DuPont Nemours.
  • the seal 44 may also be formed of any other suitable elastomer and coated with teflon or other similar substance.
  • the housing 12 may be formed of aluminum, in which case the inlets 14, 16 and the outlet 18 must include suitable fittings 52-54, respectively, that are inert to the fluids to be transferred.
  • the fittings 52- 54 may be threadedly engaged in the housing and should sealingly engage the core 20 to prevent leakage.
  • the fittings may be secured in the housing by any other suitable means.

Abstract

A mixing valve includes a housing having inlet ports (14, 16) and an outlet port (18) that intersect at a valve chamber. A valve core (20) within the valve chamber includes passages (34-36) in fluid communication with the inlet and outlet ports. The passages intersect at a cavity (38) within the valve core. An elastomeric seal (44) retained within the cavity sealingly engages the valve core around the passages in the absence of fluid pressure in the inlets. Injection of a pressurized fluid in one of the inlets causes the seal to move away from both the corresponding inlet passage to permit fluid flow from the pressurized inlet port to the outlet port and compresses the seal around the other inlet port to provide a tighter seal than existed before application of pressure to the first port.

Description

MIXING TEE CHECK VALVE AND METHOD Background of the Invention
This invention relates generally to mixing valves with independent inlet ports that feed a common outlet and particularly to a fluid pressure actuated valve for mixing liquids in a DNA synthesizer and in other systems in which fluids are mixed.
Mixing valves with independent inlet ports feeding a common outlet are well-known. Prior mixing valves require either manual control or employ electrical or pneumatic actuators to control the positions of valve seals relative to corresponding valve seats to switch the valve between inlets. Manually controlled mixing valves are incompatible with the concept of modern automated systems. Prior electrically or pneumatically controlled mixing valves typically require secondary control circuits that must be either manually controlled or include secondary control system to insure proper operation. Such prior mixing valves are of necessity complicated and expensive, and they are often unreliable in providing the desired control of fluids to be mixed.
The electrically actuated mixing valves includes a compact solenoid operated mixing valve with a small dead volume. This device has the disadvantage of requiring an electrical signal for actuation, which creates the danger of fire or explosion when used to control the flow of highly flammable fluids. The control system for the solenoid is expensive and does not have the desired degree of reliability for use in analytical instrumentation.
A mixing control valve arrangement sometimes used in hydraulic drives of heavy machinery and equipment includes two ordinary check valves connected together with a T-shaped conduit. This arrangement is unsatisfactory for scientific analytical instrumentation because of the large dead volume in the conduit, -and the intermixing of the fluids in the two input legs.
Summary of the Invention
The present invention overcomes the deficiencies of the prior art by providing a compact mixing valve that requires no expensive external control system, provides increased reliability of operation, has zero dead volume and that poses no safety hazard from fire, explosion or excessive pressure build-up.
The present invention includes a housing having at least two inlet ports and one outlet port that intersect at a valve chamber. A valve core within the valve chamber includes passages in fluid communication with the inlet and outlet ports. The passages intersect at a valve cavity within the valve core. An elastomeric seal is retained within the valve cavity and sealingly engaged with the portions of the valve core around the passages in the absence of fluid pressure in the inlets. Injection of a pressurized fluid in one of the inlets causes the seal to move away from both the corresponding inlet passage and the outlet passage so that the pressurized fluid flows from the pressurized inlet port to the outlet port. Application of a pressurized fluid to a first one of the inlet ports compresses the seal around the other inlet port to provide a tighter seal than existed before application of pressure to the first port.
The present invention includes a method of mixing fluids comprising the steps of forming a housing having at least a first inlet, a second inlet, and an outlet such that the first and second inlets and the outlet intersect at a valve chamber for selectively transferring fluids from one of the first and second inlets to the outlet; placing a pressure-controlled seal in the valve chamber to prevent fluid flow from the first and second inlets when the pressure in the first and second inlets is below a predetermined value; and pressurizing one of the first and second inlets with a fluid to break the seal between the pressurized inlet and the valve. Brief Description of the Drawings
Figure 1 is a plan view of a mixing valve according to the present invention;
Figure 2 is a cross sectional view of the mixing valve of Figure 1 taken along line 2-2;
Figure 3 is a fragmentary cross sectional view taken along line 3-3 of Figure 2;
Figure 4 is a fragmentary view illustrating deformation of a seal included in Figures 1-3 when a pressurized fluid is applied to an inlet port; and
Figure 5 is an end view of a seal included in the mixing valve of Figures 1-4.
Description of the Preferred Embodiment
Referring to Figures 1 and 2, a mixing valve 10 includes a housing 12 having, for example, a pair of inlets 14 and 16 and an outlet 18 therein. A valve core 20 is positioned in a chamber 22, which may be conveniently centrally positioned within the housing 12.
The housing 12 may be formed of any suitably rigid material by conventional techniques, such as casting, machining or molding to include the inlets 14 and 16 and the outlet 18. Although the valve core 20 is shown as a separate component of the valve 10, the core 20 may be integrally formed with the housing 12, in which case the housing 12 should be formed of a material that is chemically inert with respect to the fluids to be transferred with the valve 10.
The valve core 20 is inserted into the housing 12 through an opening 24, best shown in Figure 2, at a side 26 of the housing 12. As shown i Figure 1 and 2, a cover 28 retains the valve core 20 within the chamber 22. A pair of screws 30 and 32 are suitable for retaining the cover upon the housing 12. The valve core 20 is dimensioned to fit within the chamber 22 so that when the cover 28 is secured to the housing 12, the valve core 20 is restrained against movement relative to the housing 12.
The valve core 20 includes a first passage 34 in fluid communication with the inlet 14, a second passage 35 in fluid communication with the inlet 16, and a third passage 36 in fluid communication with the outlet 18. The passages 34-36 intersect at a core cavity 38 that may be conveniently centrally located in the core 20. The core cavity 38 may be conveniently formed as a passage through the core 20. As shown in Figure 2, a pair of plugs 40 and 42 seal opposite ends of the core cavity 38 to prevent undesired fluid flow therefrom. A seal 44 that is preferably formed of an inert elastomer is inserted into the core cavity 38 before the ends thereof are plugged. Referring to Figure 5, the seal 44 Is preferably tubular, having a void 45 therein, although other configurations, such as a hollow sphere, function satisfactorily. After the seal 44 and the plugs 40 and 42 are properly positioned, the cover 28 is secured to the housing to retain the plugs to complete the assembly of the valve 10. The plugs 40 and 42 retain the seal 44 therebetween so that the elastomeric seal 44 contacts the core 20 to seal the inlets 14, 16 and the outlet 18, as best shown in Figure 3.
Referring to Figures 3 and 4, initially the elastic resilience of the seal causes both inlet ports 14 and 16 to be sealed. When a pressurized liquid is delivered to the inlet port 14, for example, the seal 44 has a side 46 that becomes exposed to fluid pressure. The side 46 deflects inwardly toward the hollow region of the tubular seal 44 away from sealing engagement with the inlet 14 and the outlet 18 to allow liquid to flow through the inlet 14 and the passage 34 into the core cavity 38 and out through the passage 36 to the outlet 18. For convenience of illustration, Figure 4 shows the compression of the seal 44 as being linear. In actual practice the compression of the seal 44 could form a configuration different from that illustrated.
While pressurized fluid is applied to the side 46 of the seal 44, a side 48 of the seal opposite the side 46 becomes compressed against the portion of the core 20 around the passage 35 to tighten the seal to prevent cross leakage between the inlets 14 and 16.
Upon removal of fluid pressure from the side 46 of the seal 44, the seal 44 expands against the core 20 around the passage 34 to prevent fluid flow from the inlet 14 into the core cavity 38, thus terminating fluid flow between the inlet 14 and the outlet 18.
Application of fluid pressure to the side 48 of the seal through the inlet 16 and the passage 35 deforms the seal 44 away from engagement with the passage 35. If the pressure in the inlet 16 becomes sufficiently high, the seal disengages from the portion of the core 20 around the passage 35 to place the inlet 16 in fluid communication with the outlet 18.
Fluid pressure in the inlets 14 and 16 controls the entire operation of the valve 10. The valve 10 has no dead volume of fluid that remains to flow to the outlet 18 after the seal has closed one of the passages. The valve 10 prevents the accumulation of potentially dangerous pressures in the inlets 14, 16 and supply lines (not shown) that may be connected thereto because a sufficiently high pressure in an inlet will open the seal 44 to permit fluid flow and relief of the high fluid pressure. If both inlets 14 and 16 should become highly pressurized, the seal 44 will compress inwardly and permit fluid flow form both inlets 14 and 16 to the outlet 18. Proper selection of the dimensions of the core cavity a-nd the dimension sand the elasticity of the seal 44 provide control of the fluid pressure required to open the seal when one or both of the inlets 14, 16 are pressurized. It is also necessary that the materials that will become wetted with fluids being mixed in the valve 10 be inert to the fluids to be transferred through the valve 10. The necessity of using materials that are inert with respect to the fluids being transferred is well-known in the art and is also required with prior art mixing valves. There are many polymeric substances well- known in the art that are suitable for forming the wetted components of the valve 10, such as the interior of the inlets 14, 16, the outlet 18, the passages 34-36, the valve chamber 22, the core cavity 38, and the plugs 40, 42.
For illustration only rather than for limitation it has been found that certain materials provide satisfactory results in constructing the valve 10. For example, the core 20 may be satisfactorily formed of a fluoropoly er plastic material sold under the name KEL-F, a trademark of the 3M Company. The plugs 40, 42 may be formed of a fluoroσarbon material sold under the name TEFLON, a trademark of E. I. Du Pont Nemours. The seal 44 may be formed of a perfluoroelastomer sold under the name KALREZ, a trademark of E. I. DuPont Nemours. The seal 44 may also be formed of any other suitable elastomer and coated with teflon or other similar substance. The housing 12 may be formed of aluminum, in which case the inlets 14, 16 and the outlet 18 must include suitable fittings 52-54, respectively, that are inert to the fluids to be transferred. The fittings 52- 54 may be threadedly engaged in the housing and should sealingly engage the core 20 to prevent leakage. The fittings may be secured in the housing by any other suitable means. Although the present invention has been described •with reference to a specific preferred embodiment, it is to be understood that modifications from the exemplary preferred embodiment may be made without departing from the scope and spirit of the invention as defined in the appended claims. Although the illustrated preferred embodiment includes two inlets and one outlet, it is contemplated that the valve 10 of the present invention could include any number of inlets and outlets.

Claims

What is claimed is:
1. A valve for mixing fluids, comprising: a housing having at least a first inlet, a second inlet and an outlet, said first and second inlets and said outlet intersecting at a valve chamber where said first and second inlets may be selectively placed in fluid communication with said outlet; seal means positioned within said valve chamber for preventing fluid communication of said first and second inlets with said outlet when the fluid pressure in said first and second inlets is below a predetermined value and for deforming upon application of a pressurized fluid having fluid pressure greater than said predetermined value to one of said first and second inlets to permit fluid flow from said pressurized inlet to said outlet and for preventing from flowing from the other of said first and second inlets to either of said outlet or to_ said pressurized inlet.
2. The valve of claim 1 wherein said seal means is formed of an elastomeric material that is inert to the fluids being transferred from said pressurized inlet to said outlet.
3. The valve of claim 2 wherein said elastomeric material is formed to have a void therein.
4. The valve of claim 1 further including: a valve core retained within said valve chamber, said valve core having a first passage in fluid communication with said first inlet, a second passage in fluid communication with said second inlet, and a third passage in fluid communication with said outlet, said valve core including a core cavity where said first, second and third passages intersect to selectively provide fluid flow paths from said first and second passages to said third passage; an elastomeric seal retained within said core cavity to control fluid flow from said first and second passages to said third passage in response to application of pressurized fluid to said first and second inlets.
5. The valve of claim 3 wherein said elastomeric material is formed to have a void therein.
6. The valve of claim 3 further including: a pair of plugs positioned adjacent opposite sides of said elastomeric seal; and means for compressing said elastomeric seal to form fluid tight seals around said first and second passages to prevent fluid flow from said first and second inlets to said outlet.
7. The valve of claim 6 wherein said compressing means includes: a pair of plugs mounted on opposite sides of said elastomeric seal; and cover means mounted to said housing for retaining said plugs in compression against said elastomeric seal.
8. A method for selectively placing one of a plurality of fluid inlets in fluid communication with an outlet, comprising the steps of: forming a housing having at least a first inlet, a second inlet, and an outlet such that said first and second inlets and said outlet intersect at a valve chamber for selectively transferring fluids from one of said first and second inlets to said outlet; placing a pressure-controlled seal in said valve chamber to prevent fluid flow from said first and second inlets when the pressure in said first and second inlets is below a predetermined valve; and pressurizing one of said first and second inlets with a fluid to break the seal between said pressurized inlet and said valve chamber to permit fluid flow from said pressurized inlet to said outlet.
9. The method of claim 8 further including the step of forming said seal of an elastomeric material.
10. The method of claim 9 further including the step of forming said seal to have a void therein.
11. The method of claim 8 further including the steps of: placing a valve core having passages in fluid communication with each said inlets and said outlet inside said valve chamber; placing said seal inside said valve core; and applying compression to said seal to prevent fluid communication from said first and second inlets to said outlet.
12. The method of claim 11 further including the step of forming said seal of* an elastomeric material.
13. The method of claim 12 further including the step of forming said elastomeric material to have a void therein.
PCT/US1985/002276 1984-11-29 1985-11-15 Mixing tee check valve and method WO1986003137A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US67612684A 1984-11-29 1984-11-29
US676,126 1984-11-29

Publications (1)

Publication Number Publication Date
WO1986003137A1 true WO1986003137A1 (en) 1986-06-05

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ID=24713323

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1985/002276 WO1986003137A1 (en) 1984-11-29 1985-11-15 Mixing tee check valve and method

Country Status (4)

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EP (1) EP0202323A1 (en)
JP (1) JPS62500919A (en)
CA (1) CA1269909A (en)
WO (1) WO1986003137A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107456936A (en) * 2017-08-28 2017-12-12 江苏合海集团股份有限公司 A kind of reactor with filler device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3369496A (en) * 1966-03-04 1968-02-20 Case Co J I Flow control valve for concrete pump
FR2074037A5 (en) * 1969-12-18 1971-10-01 Agfa Gevaert Ag
FR2244561A1 (en) * 1973-09-21 1975-04-18 Spengler Willi Viscous syrup and water blender - has hollow pistons in bores in housing under spring load
GB2119269A (en) * 1982-04-28 1983-11-16 Amco Plastics Ltd Fluid mixing device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3369496A (en) * 1966-03-04 1968-02-20 Case Co J I Flow control valve for concrete pump
FR2074037A5 (en) * 1969-12-18 1971-10-01 Agfa Gevaert Ag
FR2244561A1 (en) * 1973-09-21 1975-04-18 Spengler Willi Viscous syrup and water blender - has hollow pistons in bores in housing under spring load
GB2119269A (en) * 1982-04-28 1983-11-16 Amco Plastics Ltd Fluid mixing device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107456936A (en) * 2017-08-28 2017-12-12 江苏合海集团股份有限公司 A kind of reactor with filler device

Also Published As

Publication number Publication date
JPS62500919A (en) 1987-04-16
CA1269909A (en) 1990-06-05
EP0202323A1 (en) 1986-11-26

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