WO1984004752A1 - Melanges de polyetherimide et de polycarbonate - Google Patents
Melanges de polyetherimide et de polycarbonate Download PDFInfo
- Publication number
- WO1984004752A1 WO1984004752A1 PCT/US1983/000790 US8300790W WO8404752A1 WO 1984004752 A1 WO1984004752 A1 WO 1984004752A1 US 8300790 W US8300790 W US 8300790W WO 8404752 A1 WO8404752 A1 WO 8404752A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- accordance
- polyetherimide
- polycarbonate
- blends
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
Definitions
- This invention relates to a class of blends containing a polyetherimide and a thermoplastic polycarbonate.
- the blends exhibit a higher heat distortion temperature, an improved flexural strength and tensile strength over the polycarbonate component alone and have a higher impact strength than that associated with the polyetherimide component of the blends.
- the blends may exhibit good flame resistance.
- the blends of the invention include a polyetherimide of the formula:
- a represents a whole number in excess of 1, e.g., 10 to 10,000 or more, the group is selected from:
- R' being hydrogen, lower alkyl or lower alkoxy, preferably the polyetherimide includes the latter -O-A group where R' is hydrogen such that the polyetherimide is of the formula:
- X is a member selected from the class consisting of divalent radicals of the formulas,
- R is a divalent organic radical selected from the class consisting of (1) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (2) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C (2-8) alkylene terminated polydiorganosiloxane, and (3) divalent radicals included by the formula
- polyetherimides for the purposes of the present invention include those where -O-A and Z respectively are:
- R is selected from:
- Polycarbonates for use in the blends of the invention can be generally defined as high molecular weight, thermoplastic, aromatic polymers and include homopolycarbonates and copolycarbonates and mixtures thereof which have average molecular weights of about 8,000 to more than 200,000, preferably of about 20,000 to 80,000 and an I.V. of 0.40 to 1.0 dl/g as measured in methylene chloride at 25°C.
- These polycarbonates are derived from dihydric phenols and carbonate precursors and generally speaking, contain recurring structural units of the formula;
- Y is a divalent aromatic radical of the dihydric phenol employed in the polycarbonate producing reaction.
- Suitable dihydric phenols for producing polycarbonates include the dihydric phenols such as, for example, 2,2-bis(4-hydroxyphenyl)propane, bis(4hydroxyphenyl) methane, 2,2-bis(4-hydroxy-3methylphenyl)propane, 4, 4-bis(4-hydroxyphenyl)heptane, 2,2-(3,5,3',5'-tetrachloro-4, 4'-dihydroxyphenyl)propane, 2, 2-( 3, 5, 3 ',5'-tetrabromo-4,4'-dihydroxyphenyl)propane, and (3,3'-dichloro-4,4'-dihydroxydiphenyl)methane.
- Other dihydric phenols which are also suitable for use in the preparation of the above polycarbonates are disclosed in U.S. Patent Nos. 2,999,835, 3,038,365, 3,
- the carbonate precursor employed can be either a carbonyl halide, a carbonate ester or a haloformate.
- the carbonyl halides which can be employed are carbonyl bromide, carbonyl chloride and mixtures thereof.
- Typical of the carbonate esters which can be employed are diphenyl carbonate, a di-(halophenyl) carbonate such as di-(chlorophenyl)carbonate, di-(bromopneny1)carbonate, di-(trichlorophenyl)carbonate, di-(tribromophenyl) carbonate, etc., di-(alkylphenyl) carbonate such as di- (tolyl)carbonate, etc., di-(naphthyl)carbonate, di- (chloronaphthyl)carbonate, etc., or mixtures thereof.
- the suitable haloformates include bis-haloformates of dihydric phenols (bischloroformates of hydroquinone, etc.) or glycols (bishaloformates of ethylene glycol, neopentyl glycol, polyethylene glycol, etc.). While other carbonate precursors will occur to those skilled in the art, carbonyl chloride, also known as phosgene, is preferred. Also included in the polycarbonates are the polymeric materials derived from a dihydric phenol, a dicarboxylic acid and carbonic acid. These are disclosed in U.S. Patent No. 3,169,121 which is incorporated herein by reference.
- polyetherimides can be obtained by any of the methods well known to those skilled in the art including the reaction of any aromatic bis (ether anhydrides) of the formula
- Aromatic bis (ether anhydride)s of the above formula include, for example, 2,2- (bis[4-(2,3dicarboxyphenoxy)phenyl] propane dianhydride; 4,4'bis(2,3-dicarboxyphenoxy)diphenyl ether dianhydride;
- aromatic bis(ether anhydride)s also included by the above formula are shown by Koton, M.M.; Plorinski, F.S.; Bessonov, M.I.; Rudakov, A.P. (Institute of Heteroorganic Compounds, Academy of Sciences, U.S.S.R.), U.S.S.R. 257,010, Nov. 11, 1969, Appl. May 3, 1967.
- dianhydrides are shown by M.M. Koton, F.S. Florinski, Zh Org. Khin, 4(5), 774 (1968).
- Organic diamines of the above formula include, for example, m-phenylenediamine, p-phenylenediamine, 4,4'- diaminodiphenyl propane, 4,4'-diaminodiphenylmethane, benzidine, 4,4'-diaminodiphenyl sulfide, 4,4'- diaminodiphenyl sulfone, 4, 4'-diaminodiphenyl ether, 1,5- diaminoaphthalene, 3,3'-dimethylbenzidine, 3,3'- dimethoxybenzidine, 2, 4-bis ( ⁇ -amino-t-butyl)toluene, bis (p- ⁇ -amino-t-butylphenyl)ether, bis(p- ⁇ -methyl-o- aminophenyl)benzene, 1, 3-diamino-4-isopropylbenzene, 1,2- bis(3-amino ⁇ rop ⁇ xy)ethane, m
- the reactions can be advantageously carried out employing well-known solvents, e.g., odichlorobenzene, m-cresol/toluene, etc., in which to effect interaction between the dianhydrides and the diamines, at temperatures of from about 100 to about 250 °C.
- the polyetherimides can be prepared by melt polymerization of any of the aforementioned dianhydrides with any of the aforementioned diamine compounds while heating the mixture of the ingredients at elevated temperatures with concurrent intermixing.
- melt polymerization temperatures between about 200° to 400°C. and preferably 230° to 300 °C. can be employed. Any order of addition of chain stoppers ordinarily employed in melt polymerization can be employed.
- the conditions of the reaction and the proportions of ingredients can be varied widely depending on the desired molecular weight, intrinsic viscosity, and solvent resistance.
- equimolar amounts of diamine and dianhydride are employed for high molecular weight polyetnerimides, however, in certain instances, a slight molar excess (about 1 to 5 mol percent) of diamine can be employed resulting In the production of polyetherimides having terminal amine groups.
- useful polyetherimides have an intrinsic viscosity [ ] greater than 0.2 deciliters per gram, preferably 0.35 to 0.60, or 0.7 deciliters per gram or even higher when measured in m-cresol at 25°C.
- the polycarbonates of the subject blends can be manufactured by known processes, such as, for example, by reacting a dihydric phenol with a carbonate precursor such as diphenyl carbonate or phosgene in accordance with methods set forth in the above-cited literature and U.S. Patent Nos. 4,018,750 and 4,123,436, or by transesterification processes such as are disclosed in U.S. Patent No. 3,153,008, as well as other processes known to those skilled in the art.
- the aromatic polycarbonates are typically prepared by employing a molecular weight regulator, an acid acceptor and a catalyst.
- the molecular weight regulators which can be employed include phenol, cyclohexanol, methanol, para-tertiary-butyl-phenol, etc.
- phenol is employed as the molecular weight regulator.
- the acid acceptor can be either an organic or an inorganic acid acceptor.
- a suitable organic acid acceptor is a tertiary amine and includes such materials as pyridine, triethylamine, dimethylaniline, tributylamine, etc.
- the inorganic acid acceptor can be one which can be either a hydroxide, a carbonate, a bicarbonate, or a phosphate of an alkali or alkali earth metal.
- the catalysts which can be employed are those that typically aid the polymerization of the monomer with phosgene.
- Suitable catalysts include tertiary amines such as triethylamine, tripropylamine, N,N- dimethylaniline, quaternary ammonium compounds such as, for example, tetraethylammonium bromide, cetyl triethyl ammonium bromide, tetra-n-heptylammonium iodide, tetra-n- propyl ammonium bromide, tetramethyl-ammonium chloride, tetramethyl ammonium hydroxide, tetra-n-butyl ammonium iodide, benzyltrimethyl ammonium chloride and quaternary phosphonium compounds such as, for example, n- butyltriphenyl phosphonium bromide and methyltriphenyl phosphonium bromide.
- branched polycarbonates wherein a polyfunctional aromatic compound is reacted with the monomer and carbonate precursor to provide a thermoplastic randomly branched polycarbonate.
- the polyfunctional aromatic compounds contain at least three functional groups which are carboxyl, carboxylic anhydride, haloformyl, or mixtures thereof.
- Illustrative polyfunctional aromatic compounds which can be employed include trimellitic anhydride, trimellitic acid, trimellityl trichloride, 4-chloroformyl phthalic anhydride, pyromellitic acid, pyromellitic dianhydride, mellitic acid, mellitic anhydride, trimesic acid, benzophenonetetracarboxylic acid, benzophenoetetracarboxylic anhydride, and the like.
- the preferred polyfunctional aromatic compounds are timellitic anhydride and trimellitic acid or their acid halide derivatives.
- blends of a polyetherimide and a polycarbonate are generally obtainable in all proportions of the polymers relative to each other.
- the polyetherimide and carbonate components of the blend may be mixed in weight ratios of 1:99 to 99:1 relative to each other and such a range of mixtures may be combined with the thermoplastic component in weight ratios of 1:99 to 99:1. It may be generally desirable to include a minimum amount of, for example, about 2%, of each of the components to achieve the desired properties for the blend.
- blends of the subject invention may exhibit, depending on the blend ratio of the components, one or more of the properties of high tensile and/or flexural strength, good impact strength and high heat distortion temperature. It is contemplated that the blends of the present invention may also include other additive materials such as fillers, stabilizers, plasticizers, flexibilizers, surfactant agents, pigments, dyes, reinforcements, flame retardants and diluents in conventional amounts. It is also contemplated that the blends of the invention may include two or more polyetherimides in combination with one or more polycarbonates or two or more polycarbonates in combination with one or more polyetherimides.
- Blends of the present invention may vary considerably. Prior art blending techniques are generally satisfactory. A preferred method comprises blending the polymers and additives such as reinforcements in powder, granular or filamentous form, extruding the blend, and chopping the extrudate into pellets suitable for molding by means conventionally used to mold normally solid thermoplastic compositions.
- the subject blends have application in a wide variety of physical shapes and forms, including the use as films, molding compounds, coatings, etc. When used as films or when made into molded products, these blends, including laminated products prepared therefrom, not only possess good physical properties at room temperature but they retain their strength and excellent response to workloading at elevated temperatures for long periods of time. Films formed from the blends of this invention may be used in application where films have been used previously.
- the blends of the present invention can be used in automobile and aviation applications for decorative and protective purposes, and as high temperature electrical insulation for motor slot liners, transformers, dielectric capacitors, cable and coil wrappings (form wound coil insulation for motors), and for containers and container linings.
- the blends can also be used in laminated structures where films or solutions of the blend are applied to various heat- resistant or other type of materials such as asbestos, mica, glass fiber and the like, the sheets superimposed one upon the other, and thereafter subjecting the sheets to elevated temperatures and pressures to effect flow and cure of the resinous binder to yield cohesive laminated structures. Films made from the subject blends can also serve in printed circuit applications.
- solutions of the blends herein described can be coated on electrical conductors such as copper, aluminum, etc., and thereafter the coated conductor can be heated at elevated temperatures to remove the solvent and to effect curing of the resinous composition thereon.
- an additional overcoat may be applied to such insulated conductors including the use of polymeric coatings, such as polyamides, polyesters, silicones, polyvinylformal resins, epoxy resins, polyimides, polytetrafluoroethylene, etc.
- polymeric coatings such as polyamides, polyesters, silicones, polyvinylformal resins, epoxy resins, polyimides, polytetrafluoroethylene, etc.
- blends include their use as binders for asbestos fibers, carbon fibers, and other fibrous materials in making brake linings.
- molding compositions and molded articles may be formed from the polymer blends of the invention by incorporating such fillers as asbestos, glass fibers, talc, quartz, powder, finely divided carbon, and silica into the blends prior to molding.
- Shaped articles may be molded under heat, or under heat and pressure, in accordance with practices well-known in the art.
- Polyetherimide-polycarbonate blends according to the invention were prepared and tested for various mechanical properties.
- the polyetherimide used in preparing the blend was of the structural formula: and the polycarbonate was a commercial polycarbonate sold under the trademark Lexan by the General Electric Company, Pittsfield, Massachusetts.
- the polyetherimide alone had the physical properties set forth in Table I.
- the two polymers were melt blended in a weight ratio of about 95 parts polyetherimide to about 5 parts polycarbonate and the blend viscosity meaured on an Instron capillary rheometer at about 300 °C and a shear rate of about one sec. -1 .
- various physical properties of the blend such as glass transition temperature (Tg), oxygen index (01), tensile strength and elongation were measured. The results of these measurements are also set forth in Table I.
- Example I The procedure of Example I was repeated with the exception that about 90 parts of polyetherimide and about 10 parts of polycarbonate were formulated to produce the blend according to the invention.
- the properties of the blend are set forth in Table I.
- Example I The procedure of Example I was repeated with the exception that about 85 parts of polyetherimide and about 15 parts of polycarbonate, were formulated to produce the blend according to the invention.
- the properties of the blend are set forth in Table I.
- a polyetherimide-polycarbonate blend according to the invention was prepared, the blend then molded into test specimens and the specimens tested for various physical properties.
- the polyetherimide for the blend was prepared from the reaction product of essentially equimolar amounts of 2, 2-bis[4-(3, 4-dicarboxyphenoxy)pheny1] propane dianhydride and m-phenylene diamine produced at elevated temperature of about 250° to about 300 °C. and under a nitrogen atmosphere.
- the polymer was extruded at about 300 °C. to form a strand and mechanically chopped into pellets.
- a test specimen injection molded from the pellets had the physical properties set forth in Table II.
- the polycarbonate used in the blend was a bisphenol A type polycarbonate sold under the trademark LEXAN 141 by the General Electric Company, Pittsfield, Massachusetts.
- This polycarbonate prepared by reacting 2,2-bis(4-hydroxyphenyl)propane, (bisphenol-A) and phosgene in the presence of an acid acceptor and a molecular weight regulator, has an intrinsic viscosity of about 0.57 dl/g.
- Various physical properties of this polycarbonate are set forth in Table II.
- the polymers were mixed in a weight ratio of about 10 parts polyetherimide and about 90 parts polycarbonate and then extruded in a 28mm Werner & Pfleiderer extruder having a temperature profile varying from about 570° to 615°F.
- the resulting extrudate was comminuted into pellets and the pellets injection molded into test specimens at a temperature of about 550 °F.
- Impact strength of the specimen was measured according to the notched and unnotched Izod test and the Gardner impact test and the results are set forth in Table II.
- the heat distortion temperature, tensile properties and flexural properties of the blend were also measured and are set forth in Table II.
- Example IV The procedure of Example IV was repeated with the exception that about 30 parts of polyetherimide and about 70 parts of polycarbonate, were formulated to produce the blend according to the invention and the blend was injection molded at a temperature of about 575° to 590 °F. to produce test specimens.
- the results of the notched and unnotched Izod and Gardner impact tests as well as the heat distortion temperature tensile properties and flexural properties for the blend are detailed in Table II.
- Example IV The procedure of Example IV was repeated with the exception that about 50 parts of polyetherimide and about 50 parts of polycarbondate, were formulated to produce the blend according to the invention and the blend was injection molded at about 575° to 620 °F. to produce test specimens.
- the results of the notched and unnotched Izod and Gardner impact tests, as well as the heat distortion temperature, flexural properties and molding pressure for the blend are given in Table II.
- Example IV The procedure of Example IV was repeated with the exception that about 70 parts of polyetherimide, and about 30 parts of polycarbonate were formulated to produce the blend according to the invention and the blend was extruded at about 620° to 650 °F and injection molded at about 650 °F. to produce test specimens.
- the results of the notched and unnotched Izod and Gardner impact tests, as well as the heat distortion temperature, tensile properties and flexural properties for the blend are detailed in Table II.
- Example VIII The procedure of Example VIII was repeated with the exception that about 90 parts of polyetherimide, and about 10 parts of polycarbonate were formulated to produce the blend according to the invention.
- the results of the notched and unnotched Izod and Gardner impact tests, as well as the heat distortion, tensile properties and flexural properties for the blend are detailed in Table II.
- the blends of the invention had a lower melt viscosity than the polyetherimide component alone which thereby allows the blends to be processed at a lower temperature.
- the blends appeared to be one phase systems with no delamination or phase separation in the molded specimens although the specimens were actually a two- phase system as evidenced by two glass transition temperatures.
- all the specimens were generally opaque in appearance.
- some of the unnotched Izod values are not absolute values since the test specimens twisted or bent out of the path of the hammer upon impact rather than breaking and thus these values only represent impact strength values relative to the other specimens tested.
- a polyetherimide - polyester carbonate blend according to the invention was prepared, the blend molded into test specimens, and the specimens tested for physical properties and for flame resistance.
- the polyetherimide for the blend was prepared from the reaction product of essentially equimolar amounts of 2,2-bis [4-(3,4-dicarboxyphenoxy)phenyl] propane dianhydride and m-phenylene diamine.
- a test specimen injection molded from the polyetherimide had the physical properties and the flame characteristics as set forth in Tables III and IV.
- the polyester carbonate was derived from bisphenol A, isophthalic acid and a carbonate precursor with a
- the polyester carbonate alone had the physical properties and the flame characteristics as are set forth in Tables III and IV.
- the two polymers were mixed in a weight ratio of about 25 parts polyetherimide and 75 parts polyester carbonate and extruded in a Werner & Pfleiderer extruder having a temperature of about 680 °F.
- the resulting extrudate was comminuted into pellets and the pellets injection molded into test specimens at a temperature of about 680 °F. Impact strength of a specimen was measured according to the notched Izod test, ASTM D-256, and the results are set forth in Table III.
- the heat distortion temperature, flexural strength and flexural modulus of the blend were also measured and are given in Table III.
- flame resistance characteristics of the blend are set forth in Table IV as determined by the test set forth in Bulletin No. 94 of the Underwriters Laboratory (UL-94).
- Example IX The procedure of Example IX was repeated with the exception that about 50 parts of polyetherimide and about 50 parts of polyester carbonate were formulated to produce the blend according to the invention.
- the results of the notched Izod impact test as well as the heat distortion temperature, flexural strength, and flexural modulus for the blend are detailed in Table III.
- the flame resistance characteristics of the blend are set forth in Table IV.
- Example IX The procedure of Example IX was repeated with the exception that about 75 parts of polyetherimide and about 25 parts of polyester carbonate were formulated to produce the blend according to the invention.
- the results of the notched Izod impact test as well as the heat distortion temperature, flexural strength, and flexural modulus for the blend are detailed in Table III.
- the flame resistance characteristics of the blend are set forth in Table IV.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Mélanges formés (a) d'un polyéthérimide et (b) d'un polycarbonate thermoplastique. Lesdits mélanges possèdent un point de déformation à chaud ainsi qu'une résistance à la flexion et à la traction supérieurs à ceux du composant polycarbonate seul, et possèdent en outre une résilience supérieure à celle qui est associée au composant polyéthérimide des mélanges. Lesdits mélanges présentent de plus une bonne résistance à l'inflammation.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1983/000790 WO1984004752A1 (fr) | 1983-05-23 | 1983-05-23 | Melanges de polyetherimide et de polycarbonate |
JP50217283A JPS60501413A (ja) | 1983-05-23 | 1983-05-23 | ポリエ−テルイミド−ポリカ−ボネ−トブレンド |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US1983/000790 WO1984004752A1 (fr) | 1983-05-23 | 1983-05-23 | Melanges de polyetherimide et de polycarbonate |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1984004752A1 true WO1984004752A1 (fr) | 1984-12-06 |
Family
ID=22175171
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1983/000790 WO1984004752A1 (fr) | 1983-05-23 | 1983-05-23 | Melanges de polyetherimide et de polycarbonate |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPS60501413A (fr) |
WO (1) | WO1984004752A1 (fr) |
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0186927A2 (fr) * | 1984-12-31 | 1986-07-09 | General Electric Company | Mélanges de polymères contenant un polyétherimide et carbonate de polyphtalate |
EP0187416A2 (fr) * | 1984-12-31 | 1986-07-16 | General Electric Company | Mélanges de polyterephtalatecarbonate, de polyétherimide et de polyester |
EP0224696A2 (fr) * | 1985-10-28 | 1987-06-10 | General Electric Company | Mélanges ignifugés de polyétherimide et de polycarbonate |
EP0256761A2 (fr) * | 1986-08-07 | 1988-02-24 | Amoco Corporation | Mélange d'un polymère contenant un amide et/ou un imide et d'un polyarylate |
US4782114A (en) * | 1986-10-03 | 1988-11-01 | Dexter Corporation | Compatibilizing agent for polycarbonate and polyamide polymer blends |
WO1989005332A1 (fr) * | 1986-11-03 | 1989-06-15 | General Electric Company | Melanges de resines polyetherimides ignifuges |
US5019625A (en) * | 1987-09-10 | 1991-05-28 | Dexter Corporation | Compatibilizing agent for polycarbonate and polyamide polymer blends |
US5051483A (en) * | 1988-11-14 | 1991-09-24 | General Electric Company | Flame resistant polyetherimide resin blends |
US5187228A (en) * | 1986-10-03 | 1993-02-16 | Dexter Corporation | Stabilizer for compatibilized polycarbonate and polyamide polymer blends |
EP0704487A1 (fr) * | 1994-09-30 | 1996-04-03 | General Electric Company | Compositions de polyester carbonate |
EP0711810A1 (fr) * | 1994-11-14 | 1996-05-15 | General Electric Company | Compositions résistantes à l'autoclave à partir de résines de poly(ester carbonate) et polyétherimide |
EP0949634A1 (fr) * | 1997-10-14 | 1999-10-13 | The Furukawa Electric Co., Ltd. | Fil isole a plusieurs couches et transformateurs fabriques avec ledit fil |
US6296935B1 (en) | 1996-08-22 | 2001-10-02 | The Furukawa Electric Co., Ltd. | Multilayer insulated wire and transformer using the same |
WO2006065560A1 (fr) * | 2004-12-13 | 2006-06-22 | General Electric Company | Préparation thermoplastique, objets réalisés à partir de ladite préparation, et méthode de fabrication desdits objets |
US7649040B2 (en) | 2002-04-11 | 2010-01-19 | Sabic Innovative Plastics Ip B.V. | Flame retardant fiber reinforced composition with improved flow |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4816527A (en) * | 1987-08-20 | 1989-03-28 | General Electric Company | Polycarbonate-siloxane polyetherimide copolymer blends |
JP2766843B2 (ja) * | 1991-04-18 | 1998-06-18 | 三井化学株式会社 | ポリカーボネート樹脂組成物 |
US5387639A (en) * | 1992-10-23 | 1995-02-07 | General Electric Company | Ductile blends of polyester-carbonate or polyarylates and polyetherimide resins |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3946090A (en) * | 1973-04-26 | 1976-03-23 | Bayer Aktiengesellschaft | Flame-resistant polycarbonate molding compositions |
US4225687A (en) * | 1979-07-23 | 1980-09-30 | General Electric Company | Novel halobisphenolethylene polycarbonate-polyetheramide-imide blends |
US4250279A (en) * | 1979-12-26 | 1981-02-10 | Union Carbide Corporation | Polyarylate blends with polyetherimides |
-
1983
- 1983-05-23 WO PCT/US1983/000790 patent/WO1984004752A1/fr unknown
- 1983-05-23 JP JP50217283A patent/JPS60501413A/ja active Granted
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3946090A (en) * | 1973-04-26 | 1976-03-23 | Bayer Aktiengesellschaft | Flame-resistant polycarbonate molding compositions |
US4225687A (en) * | 1979-07-23 | 1980-09-30 | General Electric Company | Novel halobisphenolethylene polycarbonate-polyetheramide-imide blends |
US4250279A (en) * | 1979-12-26 | 1981-02-10 | Union Carbide Corporation | Polyarylate blends with polyetherimides |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0187416A2 (fr) * | 1984-12-31 | 1986-07-16 | General Electric Company | Mélanges de polyterephtalatecarbonate, de polyétherimide et de polyester |
EP0186927A3 (fr) * | 1984-12-31 | 1987-05-13 | General Electric Company | Mélanges de polymères contenant un polyétherimide et carbonate de polyphtalate |
EP0187416A3 (fr) * | 1984-12-31 | 1987-05-27 | General Electric Company | Mélanges de polyterephtalatecarbonate, de polyétherimide et de polyester |
EP0186927A2 (fr) * | 1984-12-31 | 1986-07-09 | General Electric Company | Mélanges de polymères contenant un polyétherimide et carbonate de polyphtalate |
EP0224696A2 (fr) * | 1985-10-28 | 1987-06-10 | General Electric Company | Mélanges ignifugés de polyétherimide et de polycarbonate |
EP0224696A3 (fr) * | 1985-10-28 | 1988-03-23 | General Electric Company | Mélanges ignifugés de polyétherimide et de polycarbonate |
EP0256761A3 (fr) * | 1986-08-07 | 1989-05-31 | Amoco Corporation | Mélange d'un polymère contenant un amide et/ou un imide et d'un polyarylate |
EP0256761A2 (fr) * | 1986-08-07 | 1988-02-24 | Amoco Corporation | Mélange d'un polymère contenant un amide et/ou un imide et d'un polyarylate |
EP0324790A1 (fr) * | 1986-10-03 | 1989-07-26 | The Dexter Corporation | Agent de compatibilite pour des melanges polymeres de polycarbonate et de polyamide |
US4782114A (en) * | 1986-10-03 | 1988-11-01 | Dexter Corporation | Compatibilizing agent for polycarbonate and polyamide polymer blends |
EP0324790A4 (en) * | 1986-10-03 | 1990-09-26 | The Dexter Corporation | Compatibilizing agent for polycarbonate and polyamide polymer blends |
US5187228A (en) * | 1986-10-03 | 1993-02-16 | Dexter Corporation | Stabilizer for compatibilized polycarbonate and polyamide polymer blends |
WO1989005332A1 (fr) * | 1986-11-03 | 1989-06-15 | General Electric Company | Melanges de resines polyetherimides ignifuges |
US5019625A (en) * | 1987-09-10 | 1991-05-28 | Dexter Corporation | Compatibilizing agent for polycarbonate and polyamide polymer blends |
US5051483A (en) * | 1988-11-14 | 1991-09-24 | General Electric Company | Flame resistant polyetherimide resin blends |
EP0704487A1 (fr) * | 1994-09-30 | 1996-04-03 | General Electric Company | Compositions de polyester carbonate |
EP0711810A1 (fr) * | 1994-11-14 | 1996-05-15 | General Electric Company | Compositions résistantes à l'autoclave à partir de résines de poly(ester carbonate) et polyétherimide |
US6296935B1 (en) | 1996-08-22 | 2001-10-02 | The Furukawa Electric Co., Ltd. | Multilayer insulated wire and transformer using the same |
EP0949634A1 (fr) * | 1997-10-14 | 1999-10-13 | The Furukawa Electric Co., Ltd. | Fil isole a plusieurs couches et transformateurs fabriques avec ledit fil |
EP0949634A4 (fr) * | 1997-10-14 | 2006-03-29 | Furukawa Electric Co Ltd | Fil isole a plusieurs couches et transformateurs fabriques avec ledit fil |
US7649040B2 (en) | 2002-04-11 | 2010-01-19 | Sabic Innovative Plastics Ip B.V. | Flame retardant fiber reinforced composition with improved flow |
WO2006065560A1 (fr) * | 2004-12-13 | 2006-06-22 | General Electric Company | Préparation thermoplastique, objets réalisés à partir de ladite préparation, et méthode de fabrication desdits objets |
US7279594B2 (en) | 2004-12-13 | 2007-10-09 | General Electric Company | Thermoplastic composition, articles thereof, and method of making the articles |
Also Published As
Publication number | Publication date |
---|---|
JPS60501413A (ja) | 1985-08-29 |
JPH0374268B2 (fr) | 1991-11-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4548997A (en) | Polyetherimide-polycarbonate blends | |
US4673708A (en) | Impact modified polyetherimide-polycarbonate blends | |
US4908418A (en) | Ternary polymer blends | |
US4387193A (en) | Blends of polyetherimides and organopolysiloxane-polycarbonate block copolymers | |
US5387639A (en) | Ductile blends of polyester-carbonate or polyarylates and polyetherimide resins | |
US4687819A (en) | Polyterephthalatecarbonate-polyetherimide-polyester blends | |
US4629759A (en) | Flame retardant polyetherimide-polycarbonate blends | |
US4816527A (en) | Polycarbonate-siloxane polyetherimide copolymer blends | |
US4908419A (en) | Polyetherimide-polyarylate, blends | |
US4141927A (en) | Novel polyetherimide-polyester blends | |
US4923933A (en) | Polycarbonate/polyphthalate carbonate blends exhibiting good flame resistance | |
WO1984004752A1 (fr) | Melanges de polyetherimide et de polycarbonate | |
US4871817A (en) | Polyetherimide-liquid crystal polymer blends | |
EP0618945B1 (fr) | Melanges thermoformables ignifuges de resines copolymeres | |
US4395518A (en) | Polyetherimide-acrylate copolymer blends | |
EP0117327A1 (fr) | Compositions ternaires de polymères | |
EP0186927A2 (fr) | Mélanges de polymères contenant un polyétherimide et carbonate de polyphtalate | |
EP0158733A1 (fr) | Mélanges polyéthérimide-polyestercarbonate | |
EP0131643B1 (fr) | Mélange polyéthérimide-polycarbonate | |
US4814396A (en) | Blends of polycarbonate resins and polyetherimide ester resins | |
EP0704487A1 (fr) | Compositions de polyester carbonate | |
EP0117326A1 (fr) | Mélanges de polyétherimides et de polyarylates | |
CA1230696A (fr) | Melanges de polyetherimide et de polycarbonate | |
EP0158732A1 (fr) | Copolymères polyétherimide-polyéthersulfoneimide | |
CA1312982C (fr) | Melanges de polymeres ternaires contenant un polyetherimide, un carbonate de polyphtalate et un polymere de compose aromatique et de vinyle modifie par le caoutchouc |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Designated state(s): JP |