WO1984004274A1

WO1984004274A1 - Devolatilizing mixing extruder

Info

Publication number: WO1984004274A1
Application number: PCT/US1984/000578
Authority: WO
Inventors: Peter Hold; Marc A Rizzi
Original assignee: Usm Corp
Priority date: 1983-04-29
Filing date: 1984-04-16
Publication date: 1984-11-08
Also published as: ES8505856A1; PT78479B; JPS60501202A; CA1219717A; BR8406852A; MX160356A; IT8420689A0; AU559621B2; US4491417A; DD231314A5; EP0151580B1; ES532543A0; IT1176132B; EP0151580A1; IL71612A0; DE3479198D1; EP0151580A4; KR840009046A; AU2826684A; IN160460B

Abstract

An extruder (10) including a devolatilizing section (14) having helical channels (28) formed in the barrel (26) and having a cylindrical rotor (31) closing the inner sides of the channel (28). Material is fed onto the rotor surface (36) which rotates and forms the material into one or more rolling banks (65) engaging only the upstream flank (34) of the channels (28) and the rotor surface (36). Helical vent slots (40) pass through the barrel (26) into each channel (28) at the downstream flanks (33) not occupied by the rolling bank (65).

Description

DEVOLATILIZING MIXING EXTRUDER

FIELD OF THE INVENTION

This invention relates to equipment for devoiati!izing and mixing polymers in processing equipment such as for plasticating and extruding.

DESCRIPTION OF THE PRIOR ART

There is shown in U.S. Patent No. 3023456 a typical extruding machine which is also adapted to remove unwanted volatile material generated during the plastication of typical polymers and similar materials. In the patent, vents in a screw barrel are arranged at portions of the plasticating screw having reduced pressure so that volatiles are free to pass out or be drawn fr i the vents. In such machines, the screws for transporting the a rial have portions of varying root diameter alternately to create reduced pressure for devolat lizing and to pressurize the material for feeding and/or extrusion. It is known also to vary the pitch of the screw threads for the same purpose. Obviously, such devolatil zing screws are costly to manufacture due to their complexity.^" Since the pressure of the polymer is continuously varied the forces and energy costs involved are high.

Other devolatilizing equipment are known in which the fluid material is heated to "boil- off" the volatiles, and to agitate the material to present new surfaces to encourage devolatilizing the material is also cascaded in a chamber of reduced pressure. However, such equipment is also costly and energy intensive. Accordingly, it is a general object of the invention to provide devolatilizing equipment which is simple in construction and is less energy intensive and is less costly to operate. According to one feature of the invention a barrel has a bore in which helical channels extend from one end of a devolatilizing section to the other. The bore also receives a cylindrical rotor coaxially related to a feed section and output section. The arrangement is such that the feed efficiency of the devolat lizing section is substantially greater than the feed section and greatly reduces energy requirements since usually only two and no more than three surfaces of the unit engage the material rather than the usual four.

According to another feature, the material is fed by the surface of a rotor along one flank of the fixed helical channel in a rolling bank which occupies only half or less of the width of the channel. Helical vents extend through the barrel into the channel adjacent the other flank of the channel which is free of the material . According to a further feature barriers are placed in the channels to spread the material across the channel to seal successive portions of the channel. Clearance cuts in the lands of the bore between adjacent channels at the up stream side of the barrier direct at least part of the material into preceding or succeeding channels for additional mixing of the materials and any additives such as fillers or fibers.

SUMMARY OF THE INVENTION

The present invention provides a novel devolatilizing apparatus which includes a barrel having a bore in which helical channels are formed and in which a cylindrical rotor rotates. A feed section feeds fluid polymer material onto the rotor surface in streams divided according to the multiplicity of the channels. The vector of forces applied to the material by the rotor cause the material to form a rolling bank against the upstream flank of each channel with the bank flowing down stream along the flank. The rolling bank typically engages only two surfaces of the passage, i.e. one flank of the channel and the surface of the rotor. Helical slots pass through the barrel into the channel at the downstream flank not occupied by the rolling bank for drawing volatiles from the material .

DESCRIPTION OF THE DRAWINGS

FIG. 1 is a longitudinal schematic section through an elementary extruder in which the invention is embodied; FIG. 2 is a schematic flattened view generated by unwrapping the extruder barrel from a rotor;

FIG. 3 is a section on lines 111—111 of FIG. 1;

FIG. 4 is an oblique section through the devolatilizing section of the extruder and following a helical channel; FIG. 5 is a schematic flattened view generated by unwrapping part of the barrel shown in FIG. 4;

FIG. 6 is a view similar to FIG. 4 showing an alternate form of the invention;

FIG. 7 is a section on lines VII-VII of FIG. 6; FIG. 8 is a section showing a portion of the apparatus seen in FIG. 1 in enlarged scale;

FIG. 9 is a view substantially on lines IX-IX of FIG. 8 but extending through the entire barrel; and

FIGS. 10, 11 and 12 are views similar to FIG. 2 showing alternate forms of the invention.

DESCRIPTION OF THE PREFERRED EMBODIMENT

A typical machine in which the invention may be embodied comprises an extruder 10 shown in elemental form in FIG. 1. As shown, the extruder has a feed section 12, a devolatilizing section 14, and a pressurizing section 16 which leads to an outlet 18.

The feed section 12 may be adapted to receive solid pellets of polymer to be processed through an inlet 20 in a barrel 21 which is heated to the extent necessary for melting and plasticating by a feed screw 22, or the inlet may receive previously melted or otherwise liquified polymers which are to be fed by the screw 22. A gear pump or other suitable polymer processing mechanism (not shown) could be substituted for the feed section 12 without departing from the scope of the invention defined by the appended claims¹. The general function of the feed section required to illustrate the invention is to supply fluid material to the upstream end of the devolatilizing section 14. Likewise, the pressurizing/extruding section 16 shown as having a screw 24 may take other forms so long as the polymer, having passed through the devolatilizing section 14

~r is transported therefrom and/or pressurized for subsequent processing such as extrusion through the outlet 18.

The devolatil zing section 14 comprises a barrel 26 having one or a multiple of helical channels 28 formed in a bore 30 of the barrel and extending from one end of the barrel to the other. The channels 28 are shown in FIG. 1 as triple flighted but other multiples or even single flights could be used without departing from the invention. A rotor 31 on which the screws 22 and 24 are carried is driven by a source of rotary power (not shown) but which may be of any suitable type of rotary motor such as hydraulic or electrical motors. The rotor also has a cylindrical section 32

CMPI which rotates in the bore with a running but substantially close fit therewith. The surface 36 of the section 32 closes the inward open sides of the channels 28 to form helical passages 29 bounded by the side flanks 33, 34 and the root 35 of the channels and by the • surface 36 of the rotor section 32.

To explain the operation of the devolatilizing section 14, the barrel 26 is shown in FIG. 2 as unwrapped from the rotor 32 exposing the channels 28. The molten or otherwise fluid polymer is fed by the screw 22 to the channels 1, 2 and 3 in substantially equal amounts as shown in FIG. 2. The feeding capability of the devolatilizing section has proven to have such efficiency that the polymer is taken away from the feed section with the channels typically half full_, or less. The velocity of the surface 36 of the rotor section 32 as it is rotated in the bore 30 of the barrel is shown schematically in Fig. 2 as a vector Vb. Due to the helical disposition of the channels this results in a cross channel velocity vector of Vx and a downstream velocity vector of Vz. The net effect of these forces on the polymer entering the channels typically forms a rolling bank 65 (see also FIG. 8) of material engaging only the flanks 34 of the channels and the surface 36 of the rotor.

Obviously, the force applied by vector Vx holds the rolling banks against the flanks 34 while the force vector Vz moves the banks along the flanks 34 toward the discharge ends of the passages at the section 16 of the extruder. It should be noted that in a screw devoiati!i∑er the liquid polymer always contacts at least three walls even when operated in a "starved condition" with partially full flight channels. This is due to the fact that the material is constantly scraped from the fixed barrel bore and runs down the flanks of the screw channels and across the roots of the channels. However, with the apparatus of the invention the material is carried by the surface of the moving rotor and engaged by the fixed flank of the helical channel so as to move downstream along the flank in a rolling bank 65 which engages only the moving surface 36 of the rotor and the flank 34 of the fixed helical channel. Thus, the resistance to flow acting on the polymer is considerably less where the material engages only two surfaces rather than for three or four surface contact in a moving screw channel. This has been proven experimentally by placing a transparent member over the open side of a plurality of channels. A medium viscosity mixture of silicon oil was fed into the channels and the two surface contact described above was observed.

At appropriate locations, the upper side of the barrel is provided with helical openings 40 which extend through the barrel into each channel adjacent the flanks 33.^' As most graphically^" seen in FIG. 2, the width of the openings 40 is one half oY less of the width of each channel so that the rolling banks 65 of polymer do not engage the openings, although volatiles generated during processing of the polymer are free to escape through the openings. Suitable manifolds 42 (FIG. 1) may extend across several openings to provide

•r a desired vacuum level for adjacent channels or each opening may be individually connected to such a vacuum by means not shown. Since the polymer banks are constantly rotating, the material is constantly agitated exposing fresh surfaces from which the volatiles may be drawn. With the arrangement shown, it is possible to apply different vacuum levels progressively to the polymer banks. To this end, each channel is provided with at least one barrier 44 (FIGS. 2 and 3) which extends through openings 45 in the barrel and may be adjusted radially to vary a clearance 46 between the inner end of the barrier and the surface 36 of the rotor. The adjustment may be accomplished by changing shims 48 (FIG. 3) or by other suitable threaded adjustments (not shown). The clearance 46 extends across the channel and is adapted to accommodate passage of the polymer in the channel without a significant build-up of pressure on the material. In this way a sea! is provided by the material filling the clearance to isolate successive parts of the channel without significantly impeding progress of polymer along the channel or causing undesirable build-up of polymer near the openings 40.

Depending on the viscosity of the polymer being processed it will be possible with some materials, to eliminate the barriers 44. With lower viscosity materials, the material will tend to sag and build-up and fill the passage at the underside of the rotor. This is shown graphically in FIGS. 4 and 5 where the rolling bank 65 is shown at the upper side of the rotor 32 in its reduced size adjacent the opening 40. As the bank passes the horizontal at about point A, the material starts to spread across the passage until it fills the entire passage at point B and acts to sea! the passage. At about point C the material tends to shrink back against the flank 34 and assume its original form at about point D. The simple explanation of this action is that for the material to climb uphill from the

•r lowest point in the passage, the gravimetric force on the material has to be overcome by sufficient pressure on the material. A partly filled channel (of a screw) is not capable of generating pressure. At this point the fixed helical channels act in a manner similar to a moving screw channel. It is also possible to enhance the channel filling action for sealing purposes without barriers by inserting a suitably contoured profile member 50 in the channel as seen in FIGS. 6 and 7.

Referring to FIGS. 8 and 9, there is shown a means for controlling the transfer of material from the feed section 12 into the devolatilizing section 14 so as to equalize the amounts of material fed to each channel. As shown, the feed section 12 is provided with a flange 52 secured to a mating fl nge 53 of the barrel 26 by bolts 54. As best. seen in FIG. 8, the flange 52 is provided with an annular recess 56 which receives a ring 58 having three equally spaced slots 60 which lead from the end of feed screw 22 to the upstream ends of the passages 29. By appropriate rotational adjustment of the ring 58 (see also Fig. 9), the effective length of the slots 60 can be varied at least to the extent of the thickness of the land between adjacent passages. By the throttling action of the slots equal streams of polymer can be directed into each of the passages 29 onto the rotating surface 36 of the rotor 32. As above described, the polymer in each passage forms a rolling bank 65 which usually engages only the flank 34 and the surface 36 of the rotor. For mixing the material being devolatili∑ed in the section 14, the lands of the bore 30 between adjacent channels are provided with clearance cuts 62 extending upstream from barriers 64 as seen in FIG. 10. If l ttle or no clearance is provided between the inner end of the barrier and the surface 36 of the rotor, the material in the channel will be forced into the next adjacent downstream channel. If, however, such barrier clearance is provided, part of the material will continue along the channel and part will pass into the downstream channel as seen in FIG. 11. Referring to FIG. 12 another alternative arrangement is shown in which the upstream land is provided with a clearance cut so that the material is caused to flow back into the upstream channel for additional mixing and/or devolatilizing. By provision of means to introduce additives such as other liquids or solids such as fillers and fibers' (e.g. glass fibers, sisal Kevlar, nylon or polyester fibers), the stream splitting and back mixing capabilities described above can cause the mixing of materials introduced with the devolatiϋzed polymer.

While preferred embodiments have been described it should be apparent that a variety of elements could be substituted for those described without departing from the scope of the invention defined by the appended claims.

Claims

Cl aims

1. Devoiatizing apparatus, characterized in that it comprises a barrel housing (26) having an axial bore (30) in the surface of which is formed at least one helical channel (28), a cylindrical rotor (32) coaxially mounted in the bore (30) and closing the open side of the channel (28) to form a helical passage (29), means (58) for directing fluid plastic into one end of the passage (29), the rotor (32) being rotated for moving the plastic against and along one side of the passage (29) in a rolling bank (65), a port (40) extending through the housing (26) and into an unoccupied part of the passage (29) adjacent the rolling bank (65) for withdrawing volatiles.

2. Apparatus according to claim 1, characterized in that the directing means (58) includes at least one or more openings (60) entering the passage (29) adjacent the upstream side.

3. Apparatus according to claim 2, characterized in that the directing means (58) is rotatably adjustable to vary the effective size of the opening (60) to vary the amount of plastic admitted to the passage (29).

4. Apparatus according to claim 1, characterized in that multi-flighted channels (28) are formed in the surface of the bore (30) and the cylindrical rotor (32) closes the open sides of the channels (28) to form adjacent multi-flighted helical passages (29).

5. Apparatus according to claim 4, characterized in that the directing means (58) has a number of openings (60) equal to the number of passages (29).

6. Apparatus according to claim 5, characterized in that the directing means (58) is rotatably adjustable to vary the effective sizes of the openings (60) to vary the amount of plastic admitted to each passage (29).

7. Apparatus according to claim 1, characterized in that the channel (28) is provided with at least one barrier (44; 64) at least partially closing the passage (29) to spread the plastic across the width of the passage (29) for sealing the passage.

8. Apparatus according to claim 7, characterized in that a land in the bore (30) between adjacent turns of the passage (29) is provided with a clearance (62) adjacent the barrier (44; 64) at the downstream side (33) of the passage (29) for directing at least part of the plastic in the passage (29) into the next adjacent downstream turn of the passage (29).

9. Apparatus according to claim 7, characterized in that a land in the bore (30) between adjacent turns of the passage (29) is provided with a clearance (62) adjacent the barrier (44; 64) at the upstream side (34) of the passage (29) for directing at least part of the plastic in the passage into the next adjacent upstream turn of the passage (29).

10. Apparatus according to claims 7, 8 and 9, characterized in that the clearance (46) between the end of the barrier (44; 64) and the rotor surface (36) is variable.

11. Apparatus according to claims 1 and 4, characterized in that a contoured member (50) is received, extends across and along a portion of a single turn of a channel (28) reducing the size of the channel (28) to cause the plastic in the passage (29) to be spread so as to fill the passage (29).

12. Apparatus according to claims 1 and 4, characterized in that the speed of the rotor (32) and the fluid plastic directing means (58) are coordinated so that each passage (29) is only partly filled thereby causing the fluid plastic to be rolled along one flank (34) of the channel (28) contacting only that flank (34) and the rotor surface (36).