WO1981003324A1 - Materiau et procede permettant d'obtenir de l'hydrogene par dissociation de l'eau - Google Patents

Materiau et procede permettant d'obtenir de l'hydrogene par dissociation de l'eau Download PDF

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Publication number
WO1981003324A1
WO1981003324A1 PCT/US1981/000676 US8100676W WO8103324A1 WO 1981003324 A1 WO1981003324 A1 WO 1981003324A1 US 8100676 W US8100676 W US 8100676W WO 8103324 A1 WO8103324 A1 WO 8103324A1
Authority
WO
WIPO (PCT)
Prior art keywords
aluminum
mercury
sodium
amalgam
water
Prior art date
Application number
PCT/US1981/000676
Other languages
English (en)
Inventor
E Anderson
Original Assignee
E Anderson
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E Anderson filed Critical E Anderson
Priority to AU72980/81A priority Critical patent/AU7298081A/en
Publication of WO1981003324A1 publication Critical patent/WO1981003324A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C30/00—Alloys containing less than 50% by weight of each constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C7/00—Alloys based on mercury
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • This invention relates to a material for and method of effecting the decomposition/dissociation of water to form hydrogen.
  • the water is reacted with an amalgam of sodium, aluminum and mercury to form hydrogen and a metallic hydroxide believed to be Na 3 AL(OH) g .
  • the material found as suitable for generation of hydrogen from water without spontaneous combus ⁇ tion of the resultant evolved hydrogen comprises an amalgam of (1) an alkali metal such as lithium, sodium, potassium, cesium or combinations thereof, (2) aluminum and (3) mercury.
  • the particle size of the sodium and aluminum is such as to facilitate formation of an amalgam.
  • the amalgam has been prepared utilizing sodium of about 1/4 inch diameter and aluminu within the range of about 10 to about 100 mesh.
  • the particle si of either the alkali metal or the aluminum is not critical for proper mixing or blending, but the presence of impurities advers effect such mixing.
  • the weight ratio of alkali- metal to mercury may be fro about 1:100 to about 100:1 and the weight ratio of alkali metal to aluminum may be from about 1:100 to 100:1.
  • the weight ratio of alkali metal to mercury is from about 3:1 to about 1:4.5 and the weight ratio of alkali metal to aluminum is from about 1:4 to about 3:1.
  • the water reacts with the alkal metal, e.g., sodium, and the aluminum liberating hydrogen to form Na,AL(0H) fi .
  • the reaction of the water with the amalgam is substantially different from the reaction of the alkali metal component of the amalgam with water.
  • the heat generated by reaction of equivalent amounts of alkali metal in the form of th amalgam is. substantially less than where the alkali metal alone ' is reacted with water. Accordingly, spontaneous combustion of the hydrogen in an oxidizing environment as well as the formatio of a highly stable sodium product is avoided where the amalgam o the invention is employed in place of the alkali metal alone.
  • the process may be depicted as follows:
  • amalgam of sodium, aluminum and mercury is prepare utilizing any known procedure for amalgamation with the added important proviso that an inert atmosphere be maintained during amalgamation.
  • Amalgamation may be facilitated by utilization of an elevated temperature preferably around 200° C. — 10° C.
  • the amalgam is preferably maintained at this elevated temperature fo about 10 minutes where 100 grams are being processed and the tim is extended about a minute for each additional 100 gram aliquot.
  • the resulting amalgam is cooled, generally to room temperature, utilizing an inert atmosphere.
  • an inert atmosphere for this purpose, either helium or nitrogen are satisfactory. Cooling is preferably effected in a dessicator to insure that no water contacts the amalgam.
  • the amalgam solidifies and may be contacted with water by submersion, by spraying the water thereupon, by impinging water in the form of steam thereon or in any other manner.
  • 35.144 parts by weight of sodium, 13.749 parts by weig of aluminum and 51.107 parts by weight of mercury are formed into an amalgam under an inert atmosphere of nitrogen at an elevated temperature of 200° C. in graphite crucible.
  • the resulting amalgam is cooled to room temperature in a dessicator under an inert nitrogen atmosphere. Thereafter, the amalgam is formed which is a solid but which will liquefy upon agitation.
  • amalgam should be prepared in an inert gas atmosphere to prevent premature hydrox ⁇ ide formation.
  • the amalgam is placed in a suitable container with one surface thereof exposed. Water is sprayed upon the exposed surface or alternatively the exposed surface may be covered entirely with a layer of water. It is necessary that the amalga be placed within a container because in the course of contact of the amalgam with water the heat generated during the course of hydrogen generation transforms the amalgam to liquid form. The amalgam regardless of how it is contacted with water will not cause an explosion.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

Materiau et procede permettant de produire de l'hydrogene par decomposition de l'eau. Le materiau consiste en un amalgame d'un metal alcalin, de mercure et d'aluminium et l'hydrogene est produit en mettant l'eau en contact avec ce materiau.
PCT/US1981/000676 1980-05-23 1981-05-20 Materiau et procede permettant d'obtenir de l'hydrogene par dissociation de l'eau WO1981003324A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU72980/81A AU7298081A (en) 1980-05-23 1981-05-20 Material and method for obtaining hydrogen by dissociation ofwater

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15274880A 1980-05-23 1980-05-23
US152748 1980-05-23

Publications (1)

Publication Number Publication Date
WO1981003324A1 true WO1981003324A1 (fr) 1981-11-26

Family

ID=22544259

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1981/000676 WO1981003324A1 (fr) 1980-05-23 1981-05-20 Materiau et procede permettant d'obtenir de l'hydrogene par dissociation de l'eau

Country Status (2)

Country Link
EP (1) EP0052139A1 (fr)
WO (1) WO1981003324A1 (fr)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR337722A (fr) * 1903-12-14 1904-04-22 Narcisse Alfred Helouis Système d'éclairage à incandescence par application des alliages d'aluminium et autres alliages équivalents
GB190903188A (en) * 1909-02-09 1909-09-30 George William Johnson Improvements in Means for the Preparation of Pure Hydrogen.
GB191211838A (en) * 1912-05-18 1913-02-06 Sadamasa Uyeno Improvements relating to the Generation of Hydrogen.
US2083648A (en) * 1932-02-25 1937-06-15 Ig Farbenindustrie Ag Preparation of alkali metal hydroxide solutions
US2837408A (en) * 1954-06-29 1958-06-03 Olin Mathieson Process and apparatus for the catalytic decomposition of alkali metal amalgams
US3540854A (en) * 1967-05-26 1970-11-17 United Aircraft Corp Metal-water fueled reactor for generating steam and hydrogen
US3833357A (en) * 1970-11-24 1974-09-03 Oronzio De Nora Impianti A process for decomposing alkali metal amalgams into mercury, hydrogen and alkali metal hydroxide solutions
US3985866A (en) * 1974-10-07 1976-10-12 Hitachi Shipbuilding And Engineering Co., Ltd. Method of producing high-pressure hydrogen containing gas for use as a power source
WO1979001031A1 (fr) * 1978-05-04 1979-11-29 Anderson Energy Systems Inc Materiau et procede de dissociation de l'eau
US4182748A (en) * 1978-05-04 1980-01-08 Horizon Manufacturing Corporation Material and method for obtaining hydrogen and oxygen by dissociation of water
US4207095A (en) * 1978-05-04 1980-06-10 Horizon Manufacturing Corporation Material and method for obtaining hydrogen by dissociation of water

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR337722A (fr) * 1903-12-14 1904-04-22 Narcisse Alfred Helouis Système d'éclairage à incandescence par application des alliages d'aluminium et autres alliages équivalents
GB190903188A (en) * 1909-02-09 1909-09-30 George William Johnson Improvements in Means for the Preparation of Pure Hydrogen.
GB191211838A (en) * 1912-05-18 1913-02-06 Sadamasa Uyeno Improvements relating to the Generation of Hydrogen.
US2083648A (en) * 1932-02-25 1937-06-15 Ig Farbenindustrie Ag Preparation of alkali metal hydroxide solutions
US2837408A (en) * 1954-06-29 1958-06-03 Olin Mathieson Process and apparatus for the catalytic decomposition of alkali metal amalgams
US3540854A (en) * 1967-05-26 1970-11-17 United Aircraft Corp Metal-water fueled reactor for generating steam and hydrogen
US3833357A (en) * 1970-11-24 1974-09-03 Oronzio De Nora Impianti A process for decomposing alkali metal amalgams into mercury, hydrogen and alkali metal hydroxide solutions
US3985866A (en) * 1974-10-07 1976-10-12 Hitachi Shipbuilding And Engineering Co., Ltd. Method of producing high-pressure hydrogen containing gas for use as a power source
WO1979001031A1 (fr) * 1978-05-04 1979-11-29 Anderson Energy Systems Inc Materiau et procede de dissociation de l'eau
US4182748A (en) * 1978-05-04 1980-01-08 Horizon Manufacturing Corporation Material and method for obtaining hydrogen and oxygen by dissociation of water
US4207095A (en) * 1978-05-04 1980-06-10 Horizon Manufacturing Corporation Material and method for obtaining hydrogen by dissociation of water

Also Published As

Publication number Publication date
EP0052139A1 (fr) 1982-05-26

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