UY23778A1 - POLYPROPYLENE WITH HIGH FUSION RESISTANCE, CONTINUOUS PROCEDURE FOR ITS PRODUCTION AND MOLDED ARTICLE - Google Patents

POLYPROPYLENE WITH HIGH FUSION RESISTANCE, CONTINUOUS PROCEDURE FOR ITS PRODUCTION AND MOLDED ARTICLE

Info

Publication number
UY23778A1
UY23778A1 UY23778A UY23778A UY23778A1 UY 23778 A1 UY23778 A1 UY 23778A1 UY 23778 A UY23778 A UY 23778A UY 23778 A UY23778 A UY 23778A UY 23778 A1 UY23778 A1 UY 23778A1
Authority
UY
Uruguay
Prior art keywords
molecular weight
polypropylene
imparts
production
polymerization vessels
Prior art date
Application number
UY23778A
Other languages
Spanish (es)
Inventor
Luiz Passos Coni Junior Osvaldo
Soares Boaventura Filho Jaime
Maria Fabian Fernandes Helenice
Waldir Illipronte
Original Assignee
Polibrasil S A Ind E Comercio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polibrasil S A Ind E Comercio filed Critical Polibrasil S A Ind E Comercio
Publication of UY23778A1 publication Critical patent/UY23778A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Propileno de elevada resistencia a la fusión de distribución de peso molecular amplia o bimodal, el cual imparte al producto, características reológicas tales como poder conformarse en máquinas normalmente utilizadas para resinas tales como el poliestireno. También se describen los artículos moldeados producidos a partir del propileno de la invención, al igual que un proceso continuo para producir el polipropileno de elevada resistencia a la fusión el cual se obtiene en presencia de sistema catalizado por tipo Ziegler-Natta, utilizando por lo menos dos recipientes de polimerización conectados en serie, llevándose a cabo el control del peso molecular mediante la adición de cantidades discretas de un regulador del peso molecular, tal como el hidrógeno, a por lo menos uno de los distintos recipientes de polimerización, para obtener en el primer recipiente de polimerización una parte de peso molecular superior y en los siguientes recipientes de polimerización, partes del polímero de peso molecular inferior, por medio de lo cual el polímero total exhibe una distribución de peso molecular amplia o bimodal, la cual le imparte al producto propiedades reológicas interesantes.Propylene with high resistance to melting with a wide or bimodal molecular weight distribution, which imparts to the product rheological characteristics such as being able to be shaped in machines normally used for resins such as polystyrene. Molded articles produced from the propylene of the invention are also described, as well as a continuous process to produce polypropylene with high resistance to melting, which is obtained in the presence of a Ziegler-Natta type catalyzed system, using at least two polymerization vessels connected in series, molecular weight control being carried out by adding discrete amounts of a molecular weight regulator, such as hydrogen, to at least one of the different polymerization vessels, to obtain in the first polymerization vessel a higher molecular weight part and in subsequent polymerization vessels parts of the lower molecular weight polymer, whereby the total polymer exhibits a broad or bimodal molecular weight distribution, which imparts to the product interesting rheological properties.

UY23778A 1993-05-13 1994-05-13 POLYPROPYLENE WITH HIGH FUSION RESISTANCE, CONTINUOUS PROCEDURE FOR ITS PRODUCTION AND MOLDED ARTICLE UY23778A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BR9301831A BR9301831A (en) 1993-05-13 1993-05-13 High melt strength polypropylene, molded article and continuous process for the production of high melt strength polypropylene.

Publications (1)

Publication Number Publication Date
UY23778A1 true UY23778A1 (en) 1994-10-24

Family

ID=4056412

Family Applications (1)

Application Number Title Priority Date Filing Date
UY23778A UY23778A1 (en) 1993-05-13 1994-05-13 POLYPROPYLENE WITH HIGH FUSION RESISTANCE, CONTINUOUS PROCEDURE FOR ITS PRODUCTION AND MOLDED ARTICLE

Country Status (7)

Country Link
EP (1) EP0698045A1 (en)
AU (1) AU6921894A (en)
BR (1) BR9301831A (en)
CA (1) CA2162582A1 (en)
UY (1) UY23778A1 (en)
WO (1) WO1994026794A1 (en)
ZA (1) ZA943307B (en)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI944761A0 (en) 1994-10-11 1994-10-11 Borealis Holding As New polypropylene composition with molecular distribution
FI973816A0 (en) 1997-09-26 1997-09-26 Borealis As Polypropen med Hoeg smaeltstyrka
FI980342A0 (en) 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
FI974175A (en) 1997-11-07 1999-05-08 Borealis As Process for producing polypropylene
FI974178A0 (en) 1997-11-07 1997-11-07 Borealis As Polypropensammansaettningar
SG71878A1 (en) * 1997-12-11 2000-04-18 Sumitomo Chemical Co Propylene-based polymer composition and foamed article thereof
US6750302B1 (en) * 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
AU2003267785C1 (en) 2002-09-13 2009-12-24 Replicor, Inc. Non-sequence complementary antiviral oligonucleotides
CN100491458C (en) * 2006-04-20 2009-05-27 中国石油化工股份有限公司 Method of preparing high-performance polypropylene composition
DE102008026712A1 (en) 2007-06-06 2008-12-18 Sumitomo Chemical Co., Ltd. Polypropylene resin composition for oriented film and stretching film, comprises propylene polymer, which is obtained by polymerizing primary propylene containing monomers by forming crystalline propylene polymer component
EP2133389A1 (en) 2008-06-12 2009-12-16 Borealis AG Polypropylene composition
US8916250B2 (en) 2008-10-01 2014-12-23 Borealis Ag Sewage pipe comprising beta nucleated polypropylene material with improved properties
ATE555138T1 (en) 2009-02-04 2012-05-15 Borealis Ag POLYPROPYLENE COMPOSITION WITH HIGH STIFFNESS AND SHOCK RESISTANCE
ATE512195T1 (en) 2009-04-09 2011-06-15 Borealis Ag POLYPROPYLENE COMPOSITION WITH HIGH STIFFNESS AND SHOCK RESISTANCE
EP2348058B1 (en) 2010-01-22 2014-01-01 Borealis AG Heterophasic polypropylene resin and composition
EP2418237A1 (en) 2010-08-12 2012-02-15 Borealis AG Easy tear polypropylene film without notch
EP2743293B1 (en) 2010-08-12 2016-11-30 Borealis AG Easy tear polypropylene film without notch
PL2562215T3 (en) 2011-08-26 2016-09-30 Polypropylene blend for pipes
ES2629896T3 (en) 2012-12-20 2017-08-16 Borealis Ag Polypropylene mixture for pressure pipes
CN107325324B (en) 2016-04-28 2019-08-20 中国石油化工股份有限公司 Fire retardant, fire-resistant antistatic composition and fire-resistant antistatic polypropylene foaming beads
RU2721727C1 (en) 2016-10-12 2020-05-21 Бореалис Аг Composition of beta-nucleated propylene terpolymer with good impact strength
CN108929481B (en) * 2017-05-23 2021-05-11 常州塑金高分子科技有限公司 Composite material for high melt strength foamable injection molding prepared from modified regenerated polypropylene and preparation method thereof
EP3628693A1 (en) 2018-09-28 2020-04-01 Borealis AG Process for producing a heterophasic propylene copolymer having a high xylene cold soluble fraction (xcs)
US11897975B2 (en) 2018-09-28 2024-02-13 Borealis Ag Multi-stage process for producing a C2 to C8 olefin polymer composition
US20230077569A1 (en) * 2020-02-17 2023-03-16 Exxonmobil Chemical Patents Inc. Propylene-based polymer compositions having a high molecular weight tail

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58219207A (en) * 1982-06-15 1983-12-20 Chisso Corp Polypropylene having high rigidity and melt viscoelasticity and preparation thereof
US4940736A (en) * 1988-09-12 1990-07-10 Amoco Corporation Production of low density polypropylene foam
DE4009169A1 (en) * 1990-03-22 1991-09-26 Hoechst Ag METHOD FOR PRODUCING A POLYPROPYLENE MOLDING MATERIAL

Also Published As

Publication number Publication date
WO1994026794A1 (en) 1994-11-24
AU6921894A (en) 1994-12-12
CA2162582A1 (en) 1994-11-24
ZA943307B (en) 1995-02-22
BR9301831A (en) 1994-11-29
EP0698045A1 (en) 1996-02-28

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