UST956004I4 - Ethylene polymers - Google Patents

Ethylene polymers Download PDF

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Publication number
UST956004I4
UST956004I4 US05/664,984 US66498476A UST956004I4 US T956004 I4 UST956004 I4 US T956004I4 US 66498476 A US66498476 A US 66498476A US T956004 I4 UST956004 I4 US T956004I4
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US
United States
Prior art keywords
comonomer
copolymer
copolymers
carbon atoms
transition metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US05/664,984
Inventor
Denis George Harold Ballard
Eric Jones
John Christopher Padget
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Application granted granted Critical
Publication of UST956004I4 publication Critical patent/UST956004I4/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)

Abstract

a copolymer of ethylene with at least one other mono-α-olefine is prepared and is characterized as having a density in the range 918 to 940 Kg/m3, an apparent viscosity (A) at 200° C and a shear rate of 100 sec1 of 0.5 × 103 to 3.0 × 103 Nsm2 and a viscosity at 200° C and a stress of 103 N/m2 of 2 Ae.sup.(1.6A 10 ) to 10,000 A.
The copolymer from which the film is formed is preferably one in which the comonomer contains at least 5 carbon atoms; the comonomer may contain up to 12 carbon atoms. Hexene-1 is the preferred comonomer and can be present in the copolymer in an amount of 6.5 to 16.5%, by weight.
The copolymers are readily processed and can be formed into films which combine good stiffness and good impact properties.
The copolymers are conveniently prepared using supported transition metal benzyl compounds followed by a total work-up of the polymerization mixture. In particular, a process for forming the copolymers includes copolymerizing ethylene and the comonomer in the presence of a transition metal olefine polymerization catalyst and separating a polymeric product having an annealed characteristic set forth above.
US05/664,984 1975-03-07 1976-03-08 Ethylene polymers Pending UST956004I4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9563/76A GB1543908A (en) 1975-03-07 1975-03-07 Ethylene polymers
UK9563/75 1975-03-07

Publications (1)

Publication Number Publication Date
UST956004I4 true UST956004I4 (en) 1977-03-01

Family

ID=9874413

Family Applications (1)

Application Number Title Priority Date Filing Date
US05/664,984 Pending UST956004I4 (en) 1975-03-07 1976-03-08 Ethylene polymers

Country Status (14)

Country Link
US (1) UST956004I4 (en)
JP (1) JPS51115589A (en)
AR (1) AR220665A1 (en)
AU (1) AU499836B2 (en)
BE (1) BE839327A (en)
CA (1) CA1075400A (en)
DE (1) DE2609527A1 (en)
ES (1) ES445850A1 (en)
FR (1) FR2303030A1 (en)
GB (1) GB1543908A (en)
IN (1) IN144345B (en)
IT (1) IT1056940B (en)
NL (1) NL7602398A (en)
ZA (1) ZA761399B (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5952643B2 (en) * 1977-01-27 1984-12-20 三井化学株式会社 ethylene copolymer
JPS54154489A (en) * 1978-03-31 1979-12-05 Union Carbide Corp Product molded from ethylene hydrocarbon copolymer
JPS5573712A (en) * 1978-11-29 1980-06-03 Nippon Oil Co Ltd Preparation of copolymer
ZA802850B (en) * 1979-06-18 1981-05-27 Union Carbide Corp High tear strength polymers
US4359561A (en) 1979-06-18 1982-11-16 Union Carbide Corporation High tear strength polymers
US4363904A (en) 1979-06-18 1982-12-14 Union Carbide Corporation High tear strength polymers
JPS5641213A (en) * 1979-09-10 1981-04-17 Asahi Chem Ind Co Ltd Ethylene-alpha-olefin copolymer powder for powder molding
JPS5721408A (en) * 1980-07-11 1982-02-04 Asahi Chem Ind Co Ltd Fine ethylene/alpha-olefin copolymer powder suitable as hot melt adhesive for cloth

Also Published As

Publication number Publication date
ES445850A1 (en) 1977-05-01
FR2303030A1 (en) 1976-10-01
JPS51115589A (en) 1976-10-12
ZA761399B (en) 1977-02-23
FR2303030B1 (en) 1979-04-06
NL7602398A (en) 1976-09-09
IT1056940B (en) 1982-02-20
BE839327A (en) 1976-09-08
IN144345B (en) 1978-04-29
GB1543908A (en) 1979-04-11
DE2609527A1 (en) 1976-09-16
AR220665A1 (en) 1980-11-28
AU1176976A (en) 1977-09-15
AU499836B2 (en) 1979-05-03
CA1075400A (en) 1980-04-08

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