UST887006I4 - Defensive publication - Google Patents

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Publication number
UST887006I4
UST887006I4 US887006DH UST887006I4 US T887006 I4 UST887006 I4 US T887006I4 US 887006D H US887006D H US 887006DH US T887006 I4 UST887006 I4 US T887006I4
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US
United States
Prior art keywords
bis
gelatin
compounds
decadiene
radical
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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Publication of UST887006I4 publication Critical patent/UST887006I4/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/06Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
    • C07D213/16Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
    • C07D213/20Quaternary compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/227Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/255Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/30Hardeners

Definitions

  • Z is a covalent bond or
  • compositions comprising gelatin and the hardener compounds and gelatin-silver halide photographic emulsions containing the hardener compounds are disclosed.

Abstract

COMPOUNDS HAVING THE STRUCTURE:

RCH=CHCO(ZCO)MCH=CHR

WHEREIN Z IS A COVALENT BOND OR A DIVALENT HYDROCARBON RADIAL SUCH AS AN ALKYLENE RADICAL, A CYCLOALKYLENE RADICAL OR AN ARYLENE RADICAL; M=0 TO 1 AND R IS SELECTED FROM ALKOXY, HALO, ARYLTHIO, SECONDARY AND TERTIARY AMINO GROUPS AND -B+X- WHEREIN B+ IS SELECTED FROM AN AMMONIUM SALT RESIDUE SUCH AS TRIALKYLAMMONIUM, DIALKYLHYDRAZINIUM OR A HETEROCYCLIC AMMONIUM SALT RESIDUE HAVING 5-6 ATOMS IN THE HETEROCYCLIC RING, EITHER UNSUBSTITUTED OR SUBSTITUTED AND X- IS AN ACID ANION, SUCH AS CHLORIDE, BROMIDE, FLUORIDE, IODIDE, PERCHLORATE, METHANESULFONATE, BENZENESULFONATE, TOLUENESULFONATE OR FLUOROBORATE, HAVE BEEN FOUND TO EXHIBIT STRONG ACTIVITY AS GELATIN HARDENERS. COMPOSITIONS COMPRISING GELATIN AND THE HARDENER COMPOUNDS AND GELATIN-SILVER HALIDE PHOTOGRAPHIC EMULSIONS CONTAINING THE HARDENER COMPOUNDS ARE DISCLOSED. 3,8-DIOXO-1,9DECADIENE-1,10-BIS(PYRIDINIUM CHLORIDE); 1,10 - DICHLORO1,9-DECADIENE-3,8-DIONE; 1,10- DIPIPERIDINO-1,9-DECADIENE3,8 - DIONE; 3,8-DIOXO-1,9-DECADIENE-1,10-BIS(TRIMETHYLAMMONIUM PERCHLORATE) AND 3-OXO-1,4-PENTADIENE-1,5-BIS (PYRIDINIUM CHLORIDE) ARE REPRESENTATIVE HARDENER COMPOUNDS.

Description

DEFENSIVE PUBLICATION UNITED STATES PATENT OFFICE Published at the request of the applicant or owner in accordance with the Notice of Dec. 16, 1969, 869 0.6. 687. The abstracts of Defensive Publication applications are identified by distinctly numbered series and are arranged chronologically. The heading of each abstract indicates the number of pages of specification, including claims and sheets of drawings contained in the application as originally filed. The files of these applications are available to the public for inspection and reproduction may be purchased for 30 cents a sheet.
Defensive Publication applications have not been examined as to the merits of alleged invention. The Patent Oflice makes no assertion as to the novelty of the disclosed subject matter.
PUBLISHED JUNE 1, 1971 T887,006 KETOVHNYL COMPOUNDS AND PHOTOGRAPHIC HARDENERS Donald M. Burness and Robert A. Silverman, both of Kodak Park Works, Rochester, N.Y. 14650 Filed Apr. 23, 1970, Ser. No. 31,350 lint. Cl. C07c 53/16; G03c ]/30 US. Cl. 96-411 No Drawing. 21 Pages Specification Compounds having the structure:
RCH=CHCO (ZCO CH=CHR wherein Z is a covalent bond or a divalent hydrocarbon radical such as an alkylene radical, a cycloalkylene radical or an arylene radical; m=0 to 1 and R is selected from alkoxy, halo, arylthio, secondary and tertiary amino groups and -B+X- wherein B+ is selected from an ammonium salt residue such as trialkylammonium, di'alkylhydrazinium or a heterocyclic ammonium salt residue having 5-6 atoms in the heterocyclic ring, either unsubstituted or substituted and X- is an acid anion, such as chloride, bromide, fluoride, iodide, perchlorate, methanesulfonate, benzenesulfonate, toluenesulfonate or fiuoroborate, have been found to exhibit strong activity as gelatin hardeners. Compositions comprising gelatin and the hardener compounds and gelatin-silver halide photographic emulsions containing the hardener compounds are disclosed. 3,8-dioxo-l,9- decadiene-1,10-bis(pyridinium chloride); 1,10 dichlorol,9-decadiene-3,8-dione; 1,10 dipiperidino-l,Q-decadiene- 3,8 dione; 3,8-dioXo-1,9-decadiene-l,l0-bis(trimethylammonium perchlorate) and 3-oxo-1,4-pentadiene-1,5-bis (pyridinium chloride) are representative hardener compounds.
US887006D 1970-04-23 1970-04-23 Defensive publication Pending UST887006I4 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US3135070A 1970-04-23 1970-04-23

Publications (1)

Publication Number Publication Date
UST887006I4 true UST887006I4 (en) 1971-06-01

Family

ID=21858951

Family Applications (1)

Application Number Title Priority Date Filing Date
US887006D Pending UST887006I4 (en) 1970-04-23 1970-04-23 Defensive publication

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368208A (en) 1981-04-13 1983-01-11 Mccormick & Company, Inc. Water-soluble curcumin complex
US5800977A (en) * 1996-07-24 1998-09-01 Eastman Kodak Company Hardening a hydrophilic colloid composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4368208A (en) 1981-04-13 1983-01-11 Mccormick & Company, Inc. Water-soluble curcumin complex
US5800977A (en) * 1996-07-24 1998-09-01 Eastman Kodak Company Hardening a hydrophilic colloid composition

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