USRE35163E - Water-wettable drilling mud additives containing uintaite - Google Patents
Water-wettable drilling mud additives containing uintaite Download PDFInfo
- Publication number
- USRE35163E USRE35163E US07/993,290 US99329092A USRE35163E US RE35163 E USRE35163 E US RE35163E US 99329092 A US99329092 A US 99329092A US RE35163 E USRE35163 E US RE35163E
- Authority
- US
- United States
- Prior art keywords
- softening point
- additive
- uintaite
- iaddend
- iadd
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/14—Clay-containing compositions
- C09K8/18—Clay-containing compositions characterised by the organic compounds
- C09K8/22—Synthetic organic compounds
Definitions
- Canadian Patent 972,141 to Sullivan discloses a well drilling fluid containing ground particles of uintaite (gilsonite) pre-coated with a non-ionic surfactant to make the particles water-wettable.
- Preferred surfactants are phosphate esters-derived from the group consisting of polyoxyethylene ethers of organic compounds containing at least 6 carbon atoms and having a reactive hydrogen and condensed with at least 3 mols of ethylene oxide.
- a process for using this composition in well drilling operation is also disclosed.
- Softening points of uintaite generally depend on the source or vein where the uintaite is mined.
- the high softening point uintaite has a softening point of at least 360° F., preferably 375° F., or higher.
- Preferred high softening point uintaite has a softening point of from about 370 to 390° F.
- the lower or low softening point uintaite has a softening point of about 330° F, or lower.
- Preferred low softening point uintaite has a softening point of from 290-330° F., preferably about 325° F.
- the softening points of the two uintaites are preferably at least 40° F. apart, more preferably about 50° F. apart or more.
- upgraded uintaite could be used to replace or partially replace the low softening point uintaite.
- Uintaite can be upgraded by solvent extraction or precipitate to give lower softening point products.
- Preferred weight ratios of the high softening point uintaite to the lower or low softening point uintaite are in the range of 4:1 to 1:2, more preferably in the range of 3:1 to 1:1, and most preferably about 2:1.
- the mixture of uintaites is made up of about a 2:1 mixture of Gilsonite® HM, having a softening point of about 380° F, and Gilsonite® Select, having a softening point of about 325° F.
- the ratio of Gilsonite® HM to Gilsonite® Select to lignite is about 2 to about 1 to about 1.
- Preferred surfactants are highly lipophilic non-ionic surfactants.
- ⁇ highly lipophilic ⁇ surfactant is meant a surfactant that has a strong affinity for a hydrocarbon phase, rather than water.
- the relative contribution of the non-polar lipophilic tail to the polar hydrophilic head is high.
- Preferred surfactants have at least 80% of their molecular weight in the hydro-phobic or lipophilic tail, preferably about 90% or more.
- Non-ionic surfactants having HLB values below about 3 include high molecular weight fatty alcohols, such as cholesterol and lanolin alcohols; ethoxylated polyoxypropylene glycols, such as Alkatronic PGP 33-1 and PGP 18-1; ethoxylated amines, such as those sold by Tomah Products Inc.; block copolymers of propylene oxide and ethylene oxide, such as those in the Tetronic series; and ethoxylated ethylene diamine polyoxypropylene compounds, such as Alkatronic EDP 38-1 and EDP 28-1. Mixtures of surfactants are also envisioned.
- high molecular weight fatty alcohols such as cholesterol and lanolin alcohols
- ethoxylated polyoxypropylene glycols such as Alkatronic PGP 33-1 and PGP 18-1
- ethoxylated amines such as those sold by Tomah Products Inc.
- block copolymers of propylene oxide and ethylene oxide such as those in the Tetron
- A Pluronic L-101, a 10% ethylene oxide polyoxypropylene-polyoxyethylene block copolymer, MW TM 3800; BASF Wyandotte, New Jersey.
- HTHP high temperature/high pressure
- Berea core test provided data that could be used to discriminate between various additives. The procedure of this test is described in SPE Paper 17203 to Davis & Tooman, presented Feb. 28-Mar. 2, 1988, pp. 235-246. Additives were tested in a caustic water-based drilling mud. The tests indicate that temperature and pressure influence the depth of intrusion of different softening point uintaites. It is desirable to obtain some intrusion, but not a deep depth of intrusion, i.e., about 1 mm of intrusion. In addition, some intrusion of the material is necessary. (See page 243, Table #6, PE 17203.)
- additive E is superior to the other drilling mud additives tested, performing effectively over a wide temperature range.
- This additive is superior at both low temperatures and high temperatures when compared to asphalts and additives containing a single softening point uintaite.
- the continuing good performance of this additive depends on using the fight surfactants, that is those with strong affinities for the unitaite, such as Pluronic L-101.
- the FSCOT chromatograms of the solvent extract of a drilling mud sample containing our additive showed low levels of hydrocarbons all the way out to the C-40 components.
- the heavy-end components (C-28 to C-38) show the familiar FSCOT pattern of uintaite. Any surfactant in the sample is generally represented by the lighter hydrocarbons (C-8 to C-20) in the chromatogram.
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
- Treatment Of Sludge (AREA)
- Lubricants (AREA)
- Earth Drilling (AREA)
- Drilling And Exploitation, And Mining Machines And Methods (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
Description
______________________________________ Preferred Most Preferred Component Range, % Range, % ______________________________________ High softening point uintaite 30-70 45-55 Low softening point uintaite 15-40 20-30 Causticized lignite 15-40 20-30 Lipophilic surfactant 0.1-10 1-5 ______________________________________
TABLE I ______________________________________ Weight retained on Sieve.sup.(1) 1% Diesel 3% Diesel ______________________________________ Additive X 7.8 13.4 Additive Y 7.7 11.9 Gilsonite ® HM + Pluronic 4.2 7.4 L-101 Product from Example 10 3.9 4.9 ______________________________________ .sup.(1) Weight in grams on Tyler 65mesh sieve.
TABLE II __________________________________________________________________________ Screening Tests for Drilling Mud Surfactants.sup.(1) Dynamic Storage Amt. Wettability.sup.(2), Stability.sup.(3), Rewettability.sup.(4), Surfactant % sec. sec. sec. Flash Pt., (5), °F. __________________________________________________________________________ None -- Failed A 3 7.8 4.8 7.9 460 B 5 Failed C 5 Failed D 5 Failed E 3 *17.4 F 3 3.4 Failed G 3 2.8 Failed H 3 *11.0 I 3 Failed J 3 Failed K 3 Failed L 3 7.2 Failed M 3 8.2 Failed N 3 *29.5 Failed O 3 *48.0 P 3 2.9 Failed 300 Q 3 2.9 *27.3 Failed 300 R 3 2.8 10.3 Failed 300 S 3 3.4 Failed +400 T 3 3.1 Failed +400 U 3 6.8 Failed V 3 6.6 Failed W 3 4.1 Failed __________________________________________________________________________ .sup.(1) *Indicates failure. .sup.(2) See Example 2. .sup.(3) See Example 3. .sup.(4) See Example 4. .sup.(5) See Example 7.
______________________________________ % Retained on Tyler Mesh Sieves (Cumulative) Criteria 35 Mesh 65 Mesh 100 Mesh 200 Mesh ______________________________________ A Trace 1% max 3% max 20% max B 0 0 1.0 max 5-10% max ______________________________________
______________________________________ Mud Makeup ______________________________________ KCl-Polymer Seawater-Polyanionic Cellulose ______________________________________ 1 bbl deionized water 1 bbl deionized water 10.5 ppb KCl 14.7 gm sea salt 0.5 ppb PHPA 1 ppb lime 0.5 ppb polyanionic 10 ppb attapulgite clay cellulose 0.25 ppb PHPA KOH to pH 9.0-9.5 0.5 ppb polyanionic cellulose KOH to pH 9.0-9.5 ______________________________________ Chrome Lignosulfonate KOH-Lime ______________________________________ 1 bbl deionized water 1 bbl deionized water 15 ppb bentonite clay 15 ppb bentonite clay 6 ppb chrome lignosulfonate 4 ppb KOH 3 ppb lignite 8 ppb lignite 2 ppb NaOH 8 ppb calcium lignosulfonate pH 9.5-10.0 .25 ppb carboxymethyl cellulose 6 ppb lime pH 11.5-12.5 ______________________________________ ppb = lbs/barrel PHPA = partially hydrolyzed polyacrylamide
TABLE III ______________________________________ Borehole Stability Test Results (Fraction) HM:Select: Test Borehole Percent Composition Lignite Temp. °F. Size (inches) Washout ______________________________________ A 0:1:0 125 1.30 4 B .5:.5:0 125 1.30 4 B .5:.5:0 180 1.50 20 C .5:0:.5 125 1.60 28 C .5:0:.5 180 1.27 2 C .5:0:.5 250 1.50 20 D .4:.4:.2 180 1.30 4 D .4:.4:.2 250 2.30 84 E .5:.25:.25 125 1.30 4 E .5:.25:.25 250 1.30 4 F Sulfonated 180 1.40 12 Asphalt G 1:0:0 180 1.45 16 ______________________________________
TABLE IV ______________________________________ Field Trial Results.sup.(1) Our Additive Additive Z.sup.(2) ______________________________________ Interval Used (ft.) 4500-8400 4620-9080 Avg. Hole Angle 21° 50° Bit Size (in.) 121/4" 97/8" Mud Weight (lbs/gal) 9.7-10.7 9.4-10.1 Additive Conc. (lbs/bbl) 2.0-2.5 2.0-4.0 Total Amount of 6500 20,650 Additive Used (lbs.) Avg. Hole Size from 14.2 13.1 Caliper (in.) % Washout 16 33 ______________________________________ .sup.(1) The well lithology was a mixture of sand and shale. .sup.(2) Additive Z is a combination of two commercially available additives containing uintarte, used sequentially. If recommended, an emulsifier was added during addition.
Claims (31)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/993,290 USRE35163E (en) | 1989-02-24 | 1992-12-18 | Water-wettable drilling mud additives containing uintaite |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/315,017 US5030365A (en) | 1989-02-24 | 1989-02-24 | Water-wettable drilling mud additives containing uintaite |
US07/993,290 USRE35163E (en) | 1989-02-24 | 1992-12-18 | Water-wettable drilling mud additives containing uintaite |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/315,017 Reissue US5030365A (en) | 1989-02-24 | 1989-02-24 | Water-wettable drilling mud additives containing uintaite |
Publications (1)
Publication Number | Publication Date |
---|---|
USRE35163E true USRE35163E (en) | 1996-02-27 |
Family
ID=23222504
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/315,017 Ceased US5030365A (en) | 1989-02-24 | 1989-02-24 | Water-wettable drilling mud additives containing uintaite |
US07/993,290 Expired - Lifetime USRE35163E (en) | 1989-02-24 | 1992-12-18 | Water-wettable drilling mud additives containing uintaite |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/315,017 Ceased US5030365A (en) | 1989-02-24 | 1989-02-24 | Water-wettable drilling mud additives containing uintaite |
Country Status (10)
Country | Link |
---|---|
US (2) | US5030365A (en) |
EP (1) | EP0460067B1 (en) |
JP (1) | JPH04505026A (en) |
CN (1) | CN1046176A (en) |
AT (1) | ATE136049T1 (en) |
BR (1) | BR9007162A (en) |
CA (1) | CA2046879A1 (en) |
DE (1) | DE69026248T2 (en) |
RU (1) | RU2072383C1 (en) |
WO (1) | WO1990010043A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6514916B1 (en) | 2000-09-12 | 2003-02-04 | R. L. Clampitt & Associates, Inc. | Process for making sulfonated uintaite and well fluid additives including sulfonated uintaite |
US20050272623A1 (en) * | 2001-10-09 | 2005-12-08 | Kostka Stanley J | Wetting of water repellent soil by low HLB EO/PO block copolymers and enhancing solubility of same |
EP2487141A1 (en) * | 2011-02-11 | 2012-08-15 | Services Pétroliers Schlumberger | Self-adaptive cements |
US10266745B2 (en) | 2017-02-03 | 2019-04-23 | Saudi Arabian Oil Company | Anti-bit balling drilling fluids, and methods of making and use thereof |
Families Citing this family (16)
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US5120708A (en) * | 1991-03-06 | 1992-06-09 | Baker Hughes Incorporated | Non-poluting anti-stick water-base drilling fluid modifier and method of use |
US5378280A (en) * | 1993-06-07 | 1995-01-03 | Phillips Petroleum Company | Composition comprising leonardite, clay and lime and process therewith |
US5502030A (en) * | 1993-10-18 | 1996-03-26 | Phillips Petroleum Company | Liquid additive comprising a sulfonated asphalt and processes therefor and therewith |
US6242389B1 (en) | 1997-04-14 | 2001-06-05 | Bp Chemicals Limited | Ethers |
WO2000026322A1 (en) * | 1998-10-29 | 2000-05-11 | Sun Drilling Products, Inc. | High pressure high temperature (hpht) fluid loss control aid for drilling fluids |
CN1305966C (en) * | 2005-08-08 | 2007-03-21 | 倪红霞 | High efficiency anti-collapse asphalt powder for well drilling liquid |
CN100349984C (en) * | 2005-09-30 | 2007-11-21 | 西北师范大学 | Danty composition modified asphalt and its preparing method |
CA2905948C (en) | 2013-03-14 | 2022-01-11 | Board Of Regents Of The University Of Nebraska | Methods, systems, and devices relating to robotic surgical devices, end effectors, and controllers |
CN103265816B (en) * | 2013-05-07 | 2016-03-09 | 北京探矿工程研究所 | Low-softening-point emulsified asphalt for drilling fluid and preparation method thereof |
CN104559239B (en) * | 2013-10-22 | 2017-01-18 | 中国石油化工股份有限公司 | Asphalt composition particles with high softening point and preparation method thereof |
CN104559247B (en) * | 2013-10-22 | 2016-11-23 | 中国石油化工股份有限公司 | A kind of high softening point bitumen granule and preparation method thereof |
AU2013404956A1 (en) | 2013-11-08 | 2016-04-07 | Halliburton Energy Services, Inc. | Copolymer surfactants for use in downhole fluids |
CN105585864B (en) * | 2014-10-22 | 2017-10-03 | 中国石油化工股份有限公司大连石油化工研究院 | A kind of latex modified asphalt composition grain and preparation method thereof |
CN106147729B (en) * | 2015-04-21 | 2018-08-14 | 中国石油化工股份有限公司 | A kind of oil base drilling fluid and preparation method thereof |
US10722319B2 (en) | 2016-12-14 | 2020-07-28 | Virtual Incision Corporation | Releasable attachment device for coupling to medical devices and related systems and methods |
CN110628398B (en) * | 2019-10-08 | 2022-08-19 | 中石化华东石油工程有限公司 | Water-based drilling fluid for shale gas well and production method thereof |
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-
1989
- 1989-02-24 US US07/315,017 patent/US5030365A/en not_active Ceased
-
1990
- 1990-02-16 AT AT90904117T patent/ATE136049T1/en not_active IP Right Cessation
- 1990-02-16 WO PCT/US1990/000940 patent/WO1990010043A1/en active IP Right Grant
- 1990-02-16 RU SU905001613A patent/RU2072383C1/en active
- 1990-02-16 JP JP2504391A patent/JPH04505026A/en active Pending
- 1990-02-16 EP EP90904117A patent/EP0460067B1/en not_active Expired - Lifetime
- 1990-02-16 CA CA002046879A patent/CA2046879A1/en not_active Abandoned
- 1990-02-16 BR BR909007162A patent/BR9007162A/en unknown
- 1990-02-16 DE DE69026248T patent/DE69026248T2/en not_active Expired - Fee Related
- 1990-02-24 CN CN90100979A patent/CN1046176A/en active Pending
-
1992
- 1992-12-18 US US07/993,290 patent/USRE35163E/en not_active Expired - Lifetime
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Cited By (40)
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US6514916B1 (en) | 2000-09-12 | 2003-02-04 | R. L. Clampitt & Associates, Inc. | Process for making sulfonated uintaite and well fluid additives including sulfonated uintaite |
US20050272623A1 (en) * | 2001-10-09 | 2005-12-08 | Kostka Stanley J | Wetting of water repellent soil by low HLB EO/PO block copolymers and enhancing solubility of same |
US20050288389A1 (en) * | 2001-10-09 | 2005-12-29 | Kostka Stanley J | Wetting of water repellent soil by low HLB EO/PO block copolymers and enhancing solubility of same |
US7541386B2 (en) * | 2001-10-09 | 2009-06-02 | Aquatrols Corporation Of America, Inc. | Wetting of water repellent soil by low HLB EO/PO block copolymers and enhancing solubility of same |
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US8800656B2 (en) | 2011-02-11 | 2014-08-12 | Schlumberger Technology Corporation | Self-adaptive cements |
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Also Published As
Publication number | Publication date |
---|---|
RU2072383C1 (en) | 1997-01-27 |
DE69026248T2 (en) | 1996-08-22 |
AU5195590A (en) | 1990-09-26 |
EP0460067A4 (en) | 1992-03-25 |
ATE136049T1 (en) | 1996-04-15 |
EP0460067A1 (en) | 1991-12-11 |
AU636334B2 (en) | 1993-04-29 |
CN1046176A (en) | 1990-10-17 |
WO1990010043A1 (en) | 1990-09-07 |
BR9007162A (en) | 1991-11-26 |
US5030365A (en) | 1991-07-09 |
EP0460067B1 (en) | 1996-03-27 |
JPH04505026A (en) | 1992-09-03 |
DE69026248D1 (en) | 1996-05-02 |
CA2046879A1 (en) | 1990-08-25 |
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