USRE28195E - Porous-ceramic exhaust oxidation catalyst - Google Patents
Porous-ceramic exhaust oxidation catalyst Download PDFInfo
- Publication number
- USRE28195E USRE28195E US28195DE USRE28195E US RE28195 E USRE28195 E US RE28195E US 28195D E US28195D E US 28195DE US RE28195 E USRE28195 E US RE28195E
- Authority
- US
- United States
- Prior art keywords
- glycol
- polyolefin
- porous ceramic
- plasticizer
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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Classifications
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
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- B01D—SEPARATION
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
- B01D53/8646—Simultaneous elimination of the components
- B01D53/865—Simultaneous elimination of the components characterised by a specific catalyst
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- B01D—SEPARATION
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
- B01D53/8646—Simultaneous elimination of the components
- B01D53/8653—Simultaneous elimination of the components characterised by a specific device
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
- C04B30/02—Compositions for artificial stone, not containing binders containing fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/0615—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles
- C04B38/062—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles the burned-out substance being formed in situ, e.g. by polymerisation of a prepolymer composition containing ceramic powder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/054—Precipitating the polymer by adding a non-solvent or a different solvent
- C08J2201/0542—Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/506—Method of making inorganic composition utilizing organic compound, except formic, acetic, or oxalic acid or salt thereof
- Y10S502/507—Synthetic resin, natural resin, polysaccaride, or polypeptide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24149—Honeycomb-like
Definitions
- ABSTRACT OF THE DISCLOSURE I. Method of preparing temperature resistant exhaust oxidation catalysts suitable for use in land vehicle exhaust systems comprising a porous ceramic base impregnated with suitable oxidizing agents and the resulting catalysts.
- the porous ceramic base is prepared from a ceramic powder filled, plasticized polyolefin.
- This invention is a porous ceramic structure impregmated with suitable exhaust oxidation agents which is suitable for removing pollutants from land vehicle exhaust fumes and the preparation of the catalyst.
- This invention is also the method of producing the impregnated porous ceramic structure.
- the catalyst for treating exhaust gas must become etficient within a very few minutes after engine start-up and must maintain its activity throughout the various modes of engine operation.
- a catalytic converter must maintain its catalytic activity for a period of not less than 1 year and preferably for over 12,000 miles of engine operation.
- the problem of excessively high temperatures which are obtained when high concentrations of pollutants are being oxidized must also be solved in this system. It is not unusual for catalyst temperatures to reach 1,600 F. or higher. A normal catalytic system cannot withstand thermal degradation of the catalyst.
- a catalyst must be active initially to be acceptable for use in an auto exhaust catalytic system. It is not suflicient that a catalyst will have a good activity after the engine is warmed up and the catalyst bed is at a temperautre high enough to cause exhaust vapors passing through the bed to be oxidized to carbon dioxide and water.
- FIG. 3 shows the ceramic powder tilled. plasticized polyolefin after it has been fabricated into a plastic sheet containing ribs.
- FIG. 4 shows the final product obtained when the polyolefin material shown in FIG. 3 is rolled up and the process of this invention is followed.
- FIG. 8 shows how a ceramic ponder filled. plasticizcd polyolefin material is arranged to produce the linal product shown in FIG. 9. After the product of FIG. 9 is impregnated with the oxidizing catalyst it still has the same of the final fired product, e.g., that of HO. 9.
- porous ceramic structure produced by the herein disclosed method can be impregnated with exhaust catalysts used to remove pollutants from land vehicle exhaust fumes.
- a porous ceramic structure can be easily prepared from a starting material comprising a ceramic powder, a polyolefin, and a plasticizer.
- references made to polyolefin are generally to high molecular weight polyethylene.
- the components of the composition carTvary in the following amounts and stiL. provide a workable plastic composition: polyolefin 5-67 percent by volume, plasticizer -80 percent by volume, and filler 15-80 percent by volume or polyolefin 10-70 percent by weig plasticizer 10-70 percent by weight and filler -90 percent by weight.
- preferable ranges are polyolefin 5- percent by volume, plasticizer 20-60 percent by volume, and filler 20-50 percent by volume.
- the high molecular weight polymer confers strength and flexibility to the initial composition.
- the plasticizer of course, also provides flexibility, but its primary role is to increase the melt index and thus produce a processable compound and to provide porosity for the combustion step and to facilitate the initial dispersion of filler into the matrix.
- a wide variety of inexpensive, finely divided ceramic materials is available for use as fillers.
- the following types are included as examples but are not limiting in this category: (a) metal oxides and hydroxides, especially those of silicon and aluminum such as tit-alumina, (b) metal silicates and aluminates; naturally occurring clays, mica, etc.; precipitated silicates, synthetic zeolites, etc., (c) titanates, zirconates, and compositions useful for making capacitors and piezoelectric devices, and (d) ferrite and garnet compositions useful in ferromagnetic devices.
- the fillers which are preferred include rnullite (JAl O 'ZSiO synthetic mullite compositions, zirconmullite, spinel, and c rdierite (ZMgO'ZAl O -SSiO). It has been found that fillers of very high surface area require more plasticizer to be processable in the plastic than fillers of less surface area and are very efiective in retaining the oil, but generally give products with unmeasurably low melt indices. Additionally, ceramic powders of high surface area cannot be compounded to as high a filler loading capacity as those of a low surface area. Such fillers can be used in combination with fillers of low surface area to help retain the plasticizer.
- plasticizer is intended to define a material which performs fiveafunc figs.
- the addition of the plasticizer will improve the proTEfiibility of the composition, i.e., lower the melt viscosity, or reduce the amount of power input which is required to compound and to fabricate the composition.
- the melt index is an indication of the processibility of the composition, the melt index increasing as the molecular weight and viscosity decrease.
- a torque decrease indicates a lower melt viscosity and improved compounding ease (faster mixing cycle, and lower power requirements).
- the second function of the plasticizer is to improve the flexibility of the interim plastic composition. The improved flexibility is reflected in such lllLLllll'Cl lcf'.
- the iltlsilcizer is its utility in the production of the final poi-wiry.
- the plasticizer is eventually rcmoietl lll. viscosity of the material is then increased.
- Fifth. rc;uo..1l of plasticizer facilitates removing gaseous combustion products which are produced ⁇ thcn the polcolctin is burned-off.
- the plasticizer is the component of the polyolefin/fillerr'plasticizcr composition thit i eu-ic-t to extract.
- the extraction can be performed till water or llll any number of commercially avtilable organic .ll' cllls with the particular solvent depending upon the particular plasticizer used. It is especially advantageous. nouetcr. to use a plasticizer which is soluble in water. B thing .1 water soluble plasticizer, the extraction process will be more economical due to the low cost and relutitc safety of water in comparison to that of organic soirmh. The extraction process will also be much safer as there uill be no fire or toxicity hazards encountered.
- hydrocarbons paraffin oil low polymers such as polyisobutylene and polybutadiene.
- glycol. glycol ethers and esters b. glycerin, glycerol monoacetate. etc.
- diethylene glycol diethylcnc glycol etlicl's and esters. triethylene glycol, etc.
- polyethylene glycols (molecular weight range 400 to 20,000)
- trimethylene glycol tetramethylene glycol, 2, 3- butylene glycol, etc.
- alkyl phosphates e.g., triethyl phosphate
- Water soluble polymeric materials such as polyvinyl alcohols, partially hydrolyzed pjolyvinyl acetate. polyacrylic acid, and polyvinyl pyrrolidone.
- plasticizers such as a water soluble and a water insoluble plasticizer with a suitable filler and high density polyethylene.
- melt index is a measure of polyethylene flow at standard conditions of temperature, pressure, and time through an orifice of defined diameter and length as specified in ASTMD 1238-GST condition F (Measuring Flow Rates of Thermoplastics by Extrusion Plastometer).
- the rate of extrusion in g./l0 minutes is the melt index, and it is used to indicate the average molecular weight of a polymer.
- high-load melt index (HLMI) is meant melt index determined by the procedure of ASTM-D-l238-65 Condition E, except that a weight of 211,600 g. is used.
- the high molecular weight polyethylene can be blended with standard commercial lower molecular weight polyethylene, bearing in mind the fact that if the overall molecular weight of the blended polymer becomes too low, the interim plastic product is apt to become brittle.
- the following mixing procedure was also found to be satisfactory.
- the polyolefin was added to the mixing chamber which was preheated to 180 C.
- the filler was added, followed by the plasticizer.
- portions of the plasticizer were added to bring the torque down liefore the rest of the filler was added.
- Generally minutes was allowed to melt the polymer and add the filler. It was found that when the filler is added as a dry powder it frequently accumulates in dead spots on the blades or in the mixing chamber. For this reason, a method of double compounding" is used. This is accomplished by recovering all the material from the plastograph. and then replacing it in the plastograph to get the material from the dead spots adequately dispersed.
- composition by mixing the components in any order. Generally the components are mixed in the plastograph at 30 to 200 RPM until the mix appears to be uniform.
- the final product blends can vary in overall composition according to the desired porosity in the final prodnet. It has been determined that the greater the overall surface area of the filler, the more plasticizer that can be incorporated. Further. the relative proportions of the ingredients can vary greatly, depending both upon the desired physical properties of the intermediate product and the final product.
- the polyolefin/filler/plasticizer blends were normally pressed in standard fashion common to the art on a hydraulic press into 0.020 inch (nominal thickness) sheets at l25-l75 C. for about 3 minutes at about 500 psi.
- the only property of interest in the intermediate plastic property is sulficient flexibility and strength to be subjected to the forming, fusing (where indicated), and extraction steps necessary before burning and firing.
- the method of shaping, pressing (or fabricating), is directly related to the type of porous ceramic structure which is desired.
- a smooth filled thermoplastic sheet is rolled up as in FIG. 1 and then subjected to the process of the invention.
- the resulting ceramic body (FIG. 2) is then high in microporosity and is readily impregnated with oxidation catalysts.
- the filled polyolefin sheet is prepared with integral ribs as shown in FIG. 3. Following the preparation of the filled polyolefin it can be prepared as shown in FIG. 3 by any of several methods of fabricating such as molding, extrusion embossing or calendering. The sheet can then be rolled up as in FIG. 4. The ribs 1 can be toward the inside or the outside of the roll. The ribs whose shape can be continuous, discontinuous, cylindrical (like tufting in a carpet) etc. act as spacers to provide macroporosity. This type of shaping will produce a honeycombed ceramic structure exhibiting both micro and macroporosity. The microporosity is achieved as the polyolefin is eventually burned out.
- a slightly different honeycomb structure can be obtained by rolling the sheet at any angle of less than 90 (FIG. 6) when a polyolefin material having integral ribs (2, 2) on both sides (FIG. 5, wherein the ribs on each side of the sheet are not parallel in order to avoid "nest ing of the ribs on contacting sides) is used.
- a micro-macro porous ceramic body assures a turbulent flow of gas and is particularly well-suited to serve as a catalyst support having a high capacity for contacting a gas such as exhaust fumes from an automobile, in accordance with the instant invention.
- the plasticizcr is then extracted.
- This can be accomplished by any solvent in which the plasticizcr is soluble.
- a plasticizer such as mineral oil
- hexane is a suitable solvent.
- a water soluble plasticizer such as diethylene glycol
- water is a suitable solvent.
- the removal of the plasticizer results in the formation of a microporous structure. in addition to providing greater surface area. the extraction of the plasticizer prior to burning off the polyolefin is of great value since the formation of the micropores aids in removing gaseous combination products which are formed when the polyolefin is burned off.
- the structure is heated to above the degradation temperature of the thermoplastic so as to completely burn oil the polyolefin.
- the degradation temperature will. of course, vary with the choice of polyolefin.
- a temperature in the range of at least 240 to 260 C. is greatly preferred to initiate degradation.
- the structure begins to turn black and at about 700 C. the structure begins to turn white, indi cating that the thermoplasic has entirely burned off.
- the resulting porous ceramic body appears identical in shape to the original plastic structure except that a slight linear shrinkage. 15-20 percent. takes place.
- the method of impregnation is not critical, but rather any method which is capable of placing the catalytic components within the porous structure is sufficient. Further, the particular catalytic components used are not specific to this invention. Any of the various catalytic components suitable for removing air polluting fumes from auto gases are operable.
- Catalyst 1 Catalytic Components-40?; CuO, 4.0%-
- a particularly suitable method of impregnating these catalytic components onto the porous material is that described in U.S. Pat. No. 3,455,843 wherein the cdpperpalladium is impregnated into the porous structure by means of a copper-palladium solution followed by impregnation with the chromia (Cr O by vacuum impregnation (Catalyst 1).
- the components of Catalyst 2 are therein impregnated into the porous structure by immersing the structure in a copper-manganesc-palladiurn salt solution.
- a porous ceramic structure containing the catalytic components of Catalyst 3 was thereby prepared.
- SLMI Melt Index
- This composition was then labeled Plastic A" and was then pressed to a 12 mil sheet in a hydraulic press with tons force, then repressed in a mold to give a ribbed sheet with a 6 mil backweb, and about mil wide with a taper, mil high ribs spaced one-eighth inch apart. From the ribbed sheet, strips were cut 30 mm. wide by 8 inches, and these were rolled up tightly with the ribs in the direction of the axis of the roll, forming a honey comb-like cylinder. This was inserted into a tight fitting, glass tube, and heated to heat-seal the consecutive layers of the spiral roll of ribbed sheet at about 150 C.
- the cylinder was then cooled and immersed in hexane for 30 minutes to extract substantially all the mineral oil,
- the honeycombed porous ceramic body (designated Ceramic body A) which resulted appeared identical in shape to the original plastic structure, but the dimensions were slightly smaller. The body had good physical strength and was hard enough to scratch ordinary glass.
- Weight percent can readily be converted to volume percent by dividing a given component by its density and recalculating on a percentage basis.
- the components in weight percent can be converted to volume percent as follows:
- EXAMPLE 2 Another sample of Composition A" was used to prepare another sample of Plastic A which was then pressed to a 20 mil sheet in a hydraulic press with 20 tons force. then repressed in a mold to give a ribbed sheet with 6 mil backweb and ribs on opposite sides of the sheet, crossing at each 25 mils wide (tapered) and 30 mils high. and spaced one-eighth inch apart. From the ribbed sheet strips were cut at 45 angles to both ribs 30 mils wide by 8 inches, and these strips were rolled up. Fusing was then accomplished by passing hot air through the strip as in Example I. The fused structure was then cooled and immersed in hexane for 30 minutes to extract the plasticizer, dried and heated in a furnace first to about 250 C..
- Example 1 The honeycombed porous ceramic body (designated Ceramic Body B") which resulted appeared identical to the original plastic structure, but the dimensions were slightly smaller. This body also had good physical strength and was hard enough to scratch ordinary glass.
- EXAMPLE 3 Another sample of Composition A was used to prepare another sample of Plastic A" which was then made into a foamable material (designated Plastic Foam A) by the addition of 0.25 percent of a chemical blowing agent, azo-bis-formamide.
- the foamable material was heated at 200 C. at which temperature the foaming agent decomposes.
- the foamed material was then water-cooled and fused as in Example 1.
- the plasticizer, mineral oil was then extracted by dipping the shaped material into hexane for 30 minutes. After drying at room temperature for 30 minutes, the shaped material was heated in a furnace to about 250 C., then 700 C. and finally to 1,450 C. as in Example 1 to burn off the polyethylene and to sinter the ceramic powder and cooled slowly.
- the porous ceramic body (designated Ceramic Body C") which resulted appeared identical in shape to the original foamed structure except that the dimensions were slightly smaller. This ceramic body provided additional pore volume and was less dense than Ceramic Bodies A and B.
- EXAMPLE 4 Another sample of Composition A was used to prepare a sample of Plastic A which was pressed to a 20 mil sheet in a hydraulic press with 20 tons force and then pressed between two crossed. grooved press platens to produce a sample of plastic net. The net was cut. rolled up. and then fused together by heating at a temperature of about (50 C. to form a three-dimensional net structure which was then cooled to room temperature. Extraction of the plasticizer and heating to burn off the polyethylene and sinter the ceramic structure took place as in Example I.
- the porous ceramic body (designated Ceramic Body D") was of low density (48 lbs./ft. had a large surface. and without straight paths. The body also had good physical strength and was hard enough to scratch ordinary glass.
- Example l was repeated except that a high molecular weight ethylene-butene copolymer commercially'available from Allied Chemical Company (0 standard load melt index, 1.8 high load melt index. 0.943 density, a reduced solution viscosity of 4.0 and a molecular weight of about 180,000) was used in place of polyethylene in Example 5.
- Hifax 1901. a high density linear pol'y'ethylene (0 standard load melt index. and a molecular weight of about 2 million) was used in place of the polyethylene. In each case. ceramic bodies were obtained exhibiting good strength.
- Example 7 a mullite composition of 75 percent by weight raw kyanite (-325 mesh, Al O -SiO and 25 percent by weight South Carolina kaolin (commercially available from Huber Corp.) was used in place of the a-alumina.
- Example 8 a mullite composition of 75 percent by weight calcined mullite (325 mesh, a 70 percent alumina bauxite-clay calcine) and 25 percent by weight South Carolina kaolin (Huber Corp.) was used in place of the tit-alumina; and in Example 9 a mullite composition of 85 percent calcined mullite (-325 mesh.
- EXAMPLE [0 in this example a zircon-mullite composition of 50 percent calcined mullite (-325 mesh. a 70 percent alumina bauxite-clay calcined). percent ground zircon (325 mesh) and 25 percent South Carolina clay was used in place of the tit-alumina of Example 1. The rest of the procedure was the same as Example 1 except that the sintering temperature was 1,2251,350 C. A ceramic body of good strength was obtained.
- Example 1 was repeated except that in place of a-alumina. a spine] (commercially available from W. R. Grace & Co.) prepared from the decomposition of high purity magnesium aluminate was used. The sintering temperature was 1.225-l.350 C. and a porous ceramic body of good strength was obtained.
- a spine commercially available from W. R. Grace & Co.
- cordierite is a zeolite of the formula 2MgO-2Al O -5SiO
- the following cordierite compositions were prepared and used as the ceramic powder in the plastic composition.
- Example 12 EXAMPLES l2-l5
- a cordierite composition was prepared by admixing percent by weight Florida kaolin and 50 percent by weight sierralite (a relatively pure prochlorite commercially available from United Sierra Div. Cyprus Mines Corp.). The mixture was substituted for the a-alumina of Example I. The remaining procedure of Example 1 was followed. The resulting good strength.
- porous ceramic body was sintered at l 2(l()-l.225 C. in Example 13 the procedure of Example 1 was followed except that a cordierite composition was prepared from percent by weight Florida kaolin and 25 percent by weight tale. The porous ceramic body which was obtained after sintering at L300 C. was of good strength.
- Example 14 a cordierite composition of 72.5 percent by weight Florida kaolin, 22 percent by weight talc, and 5.5 percent by weight magnesium carbonate was substituted for the tit-alumina of Example 1. The rest of the procedure of Example l was followed except that sintering took place at l.275-l.300 C. and a strong porous ceramic body was obtained. In Example 15 the a-alumina of Example I was replaced with a cordierite composition prefaced by admixing 68 percent by weight Florida kaolin.
- Example 1 15 percent by weight talc. and 17 percent by weight magnesium carbonate. The rest of the procedure of Example 1 was followed and a strong porous ceramic body was obtained.
- Example 1 was repeated except that the plasticizer. mineral oil. was replaced by the following plasticizers: glycerin (Example 16). diethylene glycol (Example 17), dipropylene glycol (Example 18). and polyacrylic acid (Example 19). In each case the plasticizer was extracted with water and the end product was a strong porous ceramic material.
- plasticizer mineral oil. was replaced by the following plasticizers: glycerin (Example 16). diethylene glycol (Example 17), dipropylene glycol (Example 18). and polyacrylic acid (Example 19).
- the plasticizer was extracted with water and the end product was a strong porous ceramic material.
- EXAMPLE 20 This example is intended to show the importance of the plasticizer in the filled polyolefin.
- a filled plastic material was prepared from 66.7 percent by volume percent by weight) tit-alumina and 33.3 percent by volume (10 percent by weight) particle form linear polyethylene of O melt index.
- the procedure of Example l (except. of course, for the plasticizer extraction step) was repeated.
- the resulting ceramic structure was distorted, one end was bubbly, and there was a hole through the center of the structure.
- Example 2 The same composition as used in Example 1, except that in place of the high molecular weight polyethylene a normal molecular weight polyethylene having a standard load melt index of 2.0 was utilized to attempt to prepare a porous ceramic structure. When the structure was burned to remove the polyethylene, the polyethylene melted and prevented the formation of any ceramic body.
- EXAMPLE 22 The same composition as that used in Example 1 was used. except that it was made'into a sheet without ribs. When fusion took place the entire material fused giving a cylindrical structure containing micropores. but not any macropores. The porous ceramic structure was very strong and hard enough to scratch glass.
- activity graphs were prepared wherein the horizontal axis represented temperatures ranging from 350 to 850 F. and the vertical axis represented the amount of conversion of the base component of; the feed composition. With reference to the whole area of the rectangle formed with base 350-850 F. and altitude C -100% conversion," the ratio of the area on the graph beneath the plotted line to the whole area, times 100, was referred to as the percentage of activity.
- An ideal catalyst would, of course, have a "percentage of activity of 100. For the particular catalytic component used in this example the percentage of activity was obtained as follows:
- polyolefin is selected from the group consisting of polyethylene, copolymers of polyethylene, and polypropylene, the plasticizer is mineral oil and the plasticizer is removed by contacting the fused structure with hexane.
- soluble metal salts include salts selected from the group consisting of copper, chromium, manganese, and palladium salts and mixtures thereof.
Abstract
1. A PROCESS FOR PREPARING AN ENGINE EXHAUST CATALYST COMPRISING THE FOLLOWING STEPS: A. HOMOGENEOUSLY BLENDING A COMPOSITION CONSISTING ESSENTIALLY OF 15-80 VOLUME PERCENT OF A POLYOLEFIN HAING A MOLECULAR WEIGHT OF AT LEAST 150,000 AND A STANDARD LOAD MELT INDEX OF SUBSTANTIALLY ZERO, 5-67 VOLUME PERCENT OF A CERAMIC FILLER, SELECTED FROM THE GROUP CONSISTING OF ALUMINUM, MULLITE, ZIRCON MULLITE, MAGNESIUM ALUMINATE SPINEL AND CORDIERITE AND 15-80 VOLUME PERCENT OF A PLASTICIZER; SELECTED FROM THE GROUP CONSISTING OF MINERAL OILS DETHYLENE GLYCOL, PROPYLENE GLYCOL, DIPROPYLENE GLYCOL GLYCERINE, AND A GLYCEROL MONOACETATE, TRIMERTHYLENE GLYCOL, TETRAMETHYLENE GLYCOL, 2,3BUTYLENE GLYCOL, TRIETHYL PHOSPHATE, POLYVINYL ALCOHOL, AND POLYVINYL PYRROLIDONE, B. HEATING SAID COMPOSITION TO AOUT 125* TO 175*C., MOLDING TO FORM A PLASTIC SHEET AND IMPRESSING RIBS THEREON, C. ROLLING SAID PLASTIC SHEET SO THAT SAID RIBS CONTACT SAID SHEET, HEAATING TO ABOUT 150*CC. TO JUST BELOW THE BURN OFF POINT TO FUSE THE CONTACTING AREAS TOGETHER THERMOPLASTICALLY, D. EXTRACTING SAID PLASTICIZER WITH WATER OR AN ORGANIC SOLVENT, E. REMOVING SAAID POLYOLEFIN BY HEATING TO 240* TO 700*C. TO FORM A POROUS CERAMIC STRUCTURE, AND TO BURN OFF THE POLYOLEFIN AND, F. FIRING SAID POROUS CERAMIC STRUCTURE AT A TEMPERATURE OF 1,300* TO 1,450*C. (FOR ABOUT 2 HOURS) FOR A TIME SUFFICIENT TO SINTER SAID POROUS CERAMIC STRUCTURE, G. IMPREGNATING THE POROUS CERAMIC STRUCTURE WITH SOLUTIONS OF SOLUBLE SATS OF METALS EXHIBITING CATALYTIC ACTIVITY FOR CONVERTING ENGINE EXHAUST GASES AND HEATING TO CONVERT THE METALS TO THE ACTIVE FORM.
Description
Oct. 8, 1974 F. J. SERGEYS -CERAIIC EXHAUST OXIDATION CATALYST Original Filed Oct. 22, 1970 POROUS 2 Sheets-Shoo Oct. 8, 1974 F. J. szassvs POROUS*CERAHIC EXHAUST OXIDATION CATALYST Original Filed Oct. 22, 1970 IIIIIIIIIIFIIIFIL! t!| 1.:IIIrItI lvltl!l I I III lglgtg g g lll IVFIIII IIII ammllllll llg lI1-my llrmlallmliilmlam-mi l-$-'-1-l-:Milli-1!!!! FIG. 8
2 Shuts-Shoot FIG. .9
United States Patent Original No. 3,755,204, dated Aug. 28, 1973, Ser. No.
82,918, Oct. 22, 1970. Application for reissue Feb. 6, 1974, Ser. No. 440,220
Int. Cl. B01jJ1/08,11/40 US. Cl. 252-455 R 4 Claims Matter enclosed in heavy brackets appears in the original patent but forms no part of this reissue specification; matter printed in italics indicates the additions made by reissue.
ABSTRACT OF THE DISCLOSURE I. Method of preparing temperature resistant exhaust oxidation catalysts suitable for use in land vehicle exhaust systems comprising a porous ceramic base impregnated with suitable oxidizing agents and the resulting catalysts. The porous ceramic base is prepared from a ceramic powder filled, plasticized polyolefin.
Reference is made to copending application Ser. No. 83,020. filed Oct. 22, 1970 and now abandoned, inventor Christian B. Lundsager, of common ownership herewith, directed to the method of preparing the aforesaid ceramic base used in making the catalysts of this invention.
This invention is a porous ceramic structure impregmated with suitable exhaust oxidation agents which is suitable for removing pollutants from land vehicle exhaust fumes and the preparation of the catalyst. This invention is also the method of producing the impregnated porous ceramic structure.
The problem of air pollution is not a new one. However, the problem has become aggravated in many cities in recent years. The air in most cities contains substantial quantities of both oxides of nitrogen and the products of incomplete combustion of organic fuels. In the presence of sunlight, photolysis of the oxides of nitrogen leads to the formation of measurable quantities of ozone. The ozone, in turn, reacts with various organic pollutants to form compounds which can cause the many undesirable manifestations of smog, such as eye irritation, visiuiiity reduction and plant damage.
When meterorological conditions prevent the rapid dispersion of pollutants a smog condition results. Furthermore, it is now known that in many cities a major portion or organic pollutants are derived from unburned or partially burned gasoline in auto exhaust.
Another pollutant of much concern is carbon monoxide which is undesirable because of its toxic nature. This, too. is derived mainly from exhaust emissions.
Almost since the advent of the automobile and diesel engine powered vehicles, attempts have been made to solve the problem by rendering harmless and unobjectionable the noxious fumes which are the by-products of internal combustion engines. Various devices and filters using elementary catalytic materials, and since the l920s, various modifications of filters and mufiiers, have been designed in an attempt to solve this problem. To date, none have met with success compete enough for practical applications. One of the most diificult problems to overcome is the fact that although a given purification system appears to work initially within a short period of time it becomes thoroughly contaminated and consequently useless. It does not seem feasible to install catalytic systems which must be periodically reice moved and rejuvenated because of the cost of such a system and such treatment.
Several investigators have realized that the on'y practical way to treat exhaust fumes to reduce hydrocarbon and carbon monoxide pollution is to oxidize the hydrocarbons to carbon dioxide and water and to oxidize the carbon monoxide to carbon dioxide.
A wide selection of oxidation catalysts has been produced in the past varying both in the chemical composition and physical structure. With respect to chemical composition. the ability of a Wide variety of metals and metal oxides, either alone or in combination, to catalyze the complete oxidation of hydrocarbons has been noted.
To be sufficiently efiicient in the removal of hydrocarbons and carbon monoxide from internal combustion engine exhaust gases and to meet the standards of maxi mum emission currently under consideration in the legislatures of the various states. the catalyst for treating exhaust gas must become etficient within a very few minutes after engine start-up and must maintain its activity throughout the various modes of engine operation. A catalytic converter must maintain its catalytic activity for a period of not less than 1 year and preferably for over 12,000 miles of engine operation. The problem of excessively high temperatures which are obtained when high concentrations of pollutants are being oxidized must also be solved in this system. It is not unusual for catalyst temperatures to reach 1,600 F. or higher. A normal catalytic system cannot withstand thermal degradation of the catalyst.
In this connection, the problem of conversion of carbon monoxide at the low temperatures obtained in a catalytic mufiier system at the start-up period of the engine operation is particularly troublesome. A catalyst must be active initially to be acceptable for use in an auto exhaust catalytic system. It is not suflicient that a catalyst will have a good activity after the engine is warmed up and the catalyst bed is at a temperautre high enough to cause exhaust vapors passing through the bed to be oxidized to carbon dioxide and water.
The catalytic systems which have been devised to give satisfactory results for carbon monoxide conversion frequently suffer from relatively poor conversion of hydro carbons. Since the ideal catalytic system gives a good conversion of both of these exhaust gas components, this problem is of prime importance.
An additional difliculty in the preparation of auto exhaust catalysts and the design of suitable muttiers for the integration of the exhaust catalyst into the conversion system is the problem caused by the presence of oxides of lead and particles of metallic lead in the exhaust. This lead results from the conversion of tetraethyl lead which is still the most commonly used gasoline antiknock additive. In the preparation of gasolines, a quantity of tetraethyl lead is added to the gasoline at the refinery to impart anti-knock properties to the fuel. In addition to the tetraethyl lead, various compounds such as ethylene bromide. for example, are added, which convert the lead to volatile compounds which have an appreciable vapor pressure and are thus carried out of the engine into the exhaust system. The presence of these compounds causes problems with catalytic systems in that these lead salts, in addition to physically coating the individual catalyst particies. cause decreased attrition resistance by deterioration and breakdown of these particles.
Another difiiculty in the removal of pollutants from auto exhaust fumes is the expensive method of producing porous ceramic bodies of sutficient number to meet todays needs and which are able to withstand the temperatures to which they are necessarily subjected in the exhaust systems of land vehicles.
The u e of organic bindeis for ceramic ponders is a well established commercial practice. Attempts to u e fillers in a similar manner to e\tend or reinforce the more crystalline polyolefins. however. have met with failure. Brittle products are generally obtained even with moderate filler concentrations. Previous attempts hzne been made to produce polyethylenefifiller blends using conventional inert fillers alone. Occasionally, these blends are found to have greater tensile strength than the unfilled polymer but when the polyethylene is heated it tends to have a low viscosity and is therefore not easily workable.
On the whole, reported studies of polyolefin (especially polyethylene)/filler blends indicate that satisfactory products are rarely obtained. Small amounts of some inorganic materials can be blended into polyethylene as pigments, but serve no other purpose.
With the advent of high molecular weight polyolefins (at least 150,000) there was a renewed ,interest in the area of organic binders for ceramic powders. However, these high molecular weight polyolefins were of little improvement since they could not be shaped conveniently by thermoplastic rr-" ads because of their high viscosities. Attempts to load the high molecular weight polyolefins with fillers, particularly ceramic powders further aggravated this condition.
More recently, however, it has been found that 'it is possible to provide a low cost, tough, flexible polyolefin/filler composition. A process for preparing such a composition is described in Australian Pat. No. 277,98l and Great Britain Pat. No. 1,044,502. The latter patent discloses a method of producing a composition containing (i) a polyolefin of molecular weight sufiiciently high to give it a standard load melt index of substantially zero (ii) an inert filler, e.g., ceramic powder, and (iii) a plasticizer. The composition described therein comprises 10- 80 percent by volume polyolefin, 5-60 percent by volume filler material, and 15-85 percent by volume plasticizer.
The former patent, Australia Pat. No. 277,981 discloses a similar method of producing a composition which comprises 5-95 percent by volume polyolefin, 5-50 percent by volume filler, and 5-40 percent by volume plasticizer.
Attempts to form ceramic structures have also met with little success because in the early stages of firing the structures became distorted or even cracked. Attempts to overcome this difiiculty have been unsuccessful. Various mixtures of thermoplastic binders have been found to be entirely unsuccessful.
Porous ceramic structures are used for catalyst supports, absorption drying, separation of liquid phases, etc. Generally, porous ceramics are either prepared by one of two methods. The first method consists of firing an alumina silicate with a small amount of fiux to form a slight glassy bond. In the other method alumina grain is fired with a ceramic material which melts and holds the grain together. Although both of these methods produce ex cellent porous ceramics, both are time consuming and production is slow.
Porous ceramic structures which are used in filtration processes allow cleaning without halting flow of the material being cleaned. Cleaning is often accomplished, in the case of organic materials, by ignition to 1,200"- l,600 F. without damage, and also by mechanical brushing. In chemical processing gas is forced through a cata lytic porous structure enabling the purified gas to pass through the structure and the porous ceramic structure to retain the contaminants. However, in all cases there exists the slowness of production of the porous structure.
Attempts to prepare porous ceramic articles have met with failure in that there has been an absence of success in preparing a sturdy porous ceramic article from a ceramic powder filled. plasticized thermoplastic.
It is accordingly an object of this invention to provide a method for producing porous ceramic bodies containing 4 land vehicle e\hanst oxitli/ing a ents capable of removing pollutants from a vehicles exhaust tumes.
It is t'urthcr an object of this invention to produce a porous cataly t containing ceramic structure from a flexible low-co t polyolelin material. It is a further object of this lfHfi'filiOll to produce a porous c ramic ctt|alyst from a highly filled pulyolcfin material containing a plasticizer. lt is it further object of this invention to produce a porous ceramic article uitable for use as a catalyst support by the steps of (it preparing a composition comprising a ceramic filler. a plasticizer. and a polyolcfin material. til) shaping the material. (iii! extracting the plasticizer. tiv) burning the shaped matciial to remove the poiyoclin. t' v) tiring the ceramic material which remains, and (vi) impregnating the ceramic material with an oxilation catalyst.
it is a further object to produce a porous ceramic exhaust catalyst. More specifically. it is an object to provide a low-cost, easy to make. porous ceramic automobile exhaust catalyst. Further objects will be apparent from the following description of this invention.
FIG. I shows the ceramic powder filled. plasticized polyolefin which has been rolled tip prior to removal of the plasticizer and polyolefin.
FIG. 2 shows the finished product of this invention which is obtained after the process of this invention has been completed (only the sintered ceramic material remains).
FIG. 3 shows the ceramic powder tilled. plasticized polyolefin after it has been fabricated into a plastic sheet containing ribs.
FIG. 4 shows the final product obtained when the polyolefin material shown in FIG. 3 is rolled up and the process of this invention is followed.
FIG. 5 shows a sheet of ceramic powder filled. plasticized polyolelin material having ribs on both sides.
FIG. 6 shows the resulting product when FIG. 5 is rolled and the process of this invention is followed.
FIG. 7 shows the product obtained when a foamed polyolefin material is used.
FIG. 8 shows how a ceramic ponder filled. plasticizcd polyolefin material is arranged to produce the linal product shown in FIG. 9. After the product of FIG. 9 is impregnated with the oxidizing catalyst it still has the same of the final fired product, e.g., that of HO. 9.
SUMMARY OF THE INVENTION This invention is a novel method of producing porous ceramic catalyst-containing structures suitable for auto exhaust systems. The method comprises shaping a filled polyolefin material containing a plasticizer, extracting the plasticizer, burning-off the polyolefin, firing the porous shaped ceramic structure, and impregnating the structure with an engine exhaust oxidizing agent. This invention facilitates production of porous ceramic structures containing suitable passages thereby increasing the effectiveness of contacting a gas or liquid with a catalyst supported on the structure. Various shaped ceramic exhaust catalyst structures can easily be prepared by the utilization of this method.
More specifically, I have found that a porous ceramic structure produced by the herein disclosed method can be impregnated with exhaust catalysts used to remove pollutants from land vehicle exhaust fumes.
DETAILED DESCRIPTION OF THE INVENTION As shown in Christian B. Lundsager U.S. Ser. No 83.020 supra, it has been found that a porous ceramic structure can be easily prepared from a starting material comprising a ceramic powder, a polyolefin, and a plasticizer.
Since the instant invention requires the porous structure of the Lundsager invention as a starting base for subsequent catalytic impregnation, the Lnndsagcr structure (and its method of preparation) will here be described in detail: see especially Examples l-Z2.
It is to be understood that the references made to polyolefin are generally to high molecular weight polyethylene.
More specifically a po'yolefin of very high molecular weight (e.g., at least 150,000) is a good binder for ceramic powder and can tolerate high filler loadings without becoming brittle when a plasticizer is present. This is quite unlike conventiona thermoplastics. eg, polyethylene having a molecular weight of around 60000 to 100.000 which yields brittle products at relatively low filler concentrations. plasticizers must be incorporated into these highly filled blends to provide good flow characteristics and to facilitate mixing without causing excessive loss of flexibility. Tough, flexible compositions therefore, can be produced from a three component system consisting of (l) a high molecular w ght polyolefin; (2) a filler: and (3) a plasticizer.
Each of the above stated components is essential for attainment of desirable performance of the binder system. The components of the composition carTvary in the following amounts and stiL. provide a workable plastic composition: polyolefin 5-67 percent by volume, plasticizer -80 percent by volume, and filler 15-80 percent by volume or polyolefin 10-70 percent by weig plasticizer 10-70 percent by weight and filler -90 percent by weight. However, preferable ranges are polyolefin 5- percent by volume, plasticizer 20-60 percent by volume, and filler 20-50 percent by volume. The high molecular weight polymer confers strength and flexibility to the initial composition. The plasticizer, of course, also provides flexibility, but its primary role is to increase the melt index and thus produce a processable compound and to provide porosity for the combustion step and to facilitate the initial dispersion of filler into the matrix.
A wide variety of inexpensive, finely divided ceramic materials is available for use as fillers. The following types are included as examples but are not limiting in this category: (a) metal oxides and hydroxides, especially those of silicon and aluminum such as tit-alumina, (b) metal silicates and aluminates; naturally occurring clays, mica, etc.; precipitated silicates, synthetic zeolites, etc., (c) titanates, zirconates, and compositions useful for making capacitors and piezoelectric devices, and (d) ferrite and garnet compositions useful in ferromagnetic devices.
More specifically, the fillers which are preferred include rnullite (JAl O 'ZSiO synthetic mullite compositions, zirconmullite, spinel, and c rdierite (ZMgO'ZAl O -SSiO It has been found that fillers of very high surface area require more plasticizer to be processable in the plastic than fillers of less surface area and are very efiective in retaining the oil, but generally give products with unmeasurably low melt indices. Additionally, ceramic powders of high surface area cannot be compounded to as high a filler loading capacity as those of a low surface area. Such fillers can be used in combination with fillers of low surface area to help retain the plasticizer.
As used herein, the terminology plasticizer" is intended to define a material which performs fiveafunc figs. First, the addition of the plasticizer will improve the proTEfiibility of the composition, i.e., lower the melt viscosity, or reduce the amount of power input which is required to compound and to fabricate the composition. As explained more fully hereinafter, the melt index is an indication of the processibility of the composition, the melt index increasing as the molecular weight and viscosity decrease. Similarly, a torque decrease indicates a lower melt viscosity and improved compounding ease (faster mixing cycle, and lower power requirements). The second function of the plasticizer is to improve the flexibility of the interim plastic composition. The improved flexibility is reflected in such lllLLllll'Cl lcf'. tion at failure. the elongation at sic'd :01111. pact. and tension impact. Tho third fur :tion ot the iltlsilcizer is its utility in the production of the final poi-wiry. Fourth, when the plasticizer is eventually rcmoietl lll. viscosity of the material is then increased. Fifth. rc;uo..1l of plasticizer facilitates removing gaseous combustion products which are produced \thcn the polcolctin is burned-off. The plasticizer is the component of the polyolefin/fillerr'plasticizcr composition thit i eu-ic-t to extract. The extraction can be performed till water or llll any number of commercially avtilable organic .ll' cllls with the particular solvent depending upon the particular plasticizer used. It is especially advantageous. nouetcr. to use a plasticizer which is soluble in water. B thing .1 water soluble plasticizer, the extraction process will be more economical due to the low cost and relutitc safety of water in comparison to that of organic soirmh. The extraction process will also be much safer as there uill be no fire or toxicity hazards encountered.
Examples of the numerous suitable plasticizers are the following:
a. chlorinated hydrocarbons b. miscellaneous plasticizers sulfonarnidc. countarone-indene, asphalt, etc.
c. hydrocarbons paraffin oil. low polymers such as polyisobutylene and polybutadiene.
Examples of the numerous suitable vtutcr soluble plasticizers are:
a. glycol. glycol ethers and esters b. glycerin, glycerol monoacetate. etc.
c. diethylene glycol, diethylcnc glycol etlicl's and esters. triethylene glycol, etc.
d. polyethylene glycols (molecular weight range 400 to 20,000)
e. propylene glycol, dipropylene glycol f. polypropylene glycol (molecular weight range 200 to 1,200)
g. trimethylene glycol, tetramethylene glycol, 2, 3- butylene glycol, etc.
h. alkyl phosphates (e.g., triethyl phosphate) i. Water soluble polymeric materials. such as polyvinyl alcohols, partially hydrolyzed pjolyvinyl acetate. polyacrylic acid, and polyvinyl pyrrolidone.
It is also possible to use various combinations of the above mentioned plasticizers, such as a water soluble and a water insoluble plasticizer with a suitable filler and high density polyethylene.
Most of the work was carried out using commercial particle form high molecular weight polyethylene, having a standard load (2,160 g.) melt index of 0.0, a high load (21,600 g.) melt index of 1.8, a. density of 0.95. and a viscosity of 4.0 measured as 0.02 grams of polymer in g. Decalin at C. This polymer can be prepared by the method given in US. Pat. No. 2,825,721 using an ammonium fluoride treated chromium oxide catalyst. When the term particle form is used herein, it refers to the aforesaid polymer. However, any commercially available polyethylene having a standard load melt index of substantially 0 is entirely satisfactory. Many of the illustrations to be described used polyethylene having a standard load melt index of 0.00, a high load melt index of 0.01, and a viscosity of 9.3 measured as 0.02 grams of polymer in 100 g. Deca- 1111.
It is noteworthy that melt index is a measure of polyethylene flow at standard conditions of temperature, pressure, and time through an orifice of defined diameter and length as specified in ASTMD 1238-GST condition F (Measuring Flow Rates of Thermoplastics by Extrusion Plastometer). The rate of extrusion in g./l0 minutes is the melt index, and it is used to indicate the average molecular weight of a polymer. The lower the molecular weight of a polymer, the more rapidly it extrudes, and therefore, melt index increases as molecular weight decreases. By high-load melt index" (HLMI) is meant melt index determined by the procedure of ASTM-D-l238-65 Condition E, except that a weight of 211,600 g. is used.
However, it has been found that in addition to high molecular weight particle-form high density (0.93-0.97) polyethylene, high molecular weight low density polyethylene, high molecular weight polypropylene, and high molecular weight particle form ethylene-butylene copolymer can also be used to give entirely satisfactory results.
Further, depending upon the desired physical properties of the final product, the high molecular weight polyethylene can be blended with standard commercial lower molecular weight polyethylene, bearing in mind the fact that if the overall molecular weight of the blended polymer becomes too low, the interim plastic product is apt to become brittle.
The technique which was employed to produce the composition can be described as follows. In ,most cases the various components were premixed at room temperature in a dough-mixer." However, in some cases the filler and plasticizer were slurried together-at room temperature in a volatile solve"? which was, evaporated before the materials were combined with the polyethyl ene. The polyethylene/filler/plasticizer "dry blends (in some cases a dough, in others a powder) were then mixed in a Brabender Plastograph.
The following mixing procedure was also found to be satisfactory. The polyolefin was added to the mixing chamber which was preheated to 180 C. When the polyolefin fiuxed, the filler was added, followed by the plasticizer. In those areas Where the initial portions of the filler produced extremely high torque, portions of the plasticizer were added to bring the torque down liefore the rest of the filler was added. Generally minutes was allowed to melt the polymer and add the filler. It was found that when the filler is added as a dry powder it frequently accumulates in dead spots on the blades or in the mixing chamber. For this reason, a method of double compounding" is used. This is accomplished by recovering all the material from the plastograph. and then replacing it in the plastograph to get the material from the dead spots adequately dispersed.
It is possible to produce the composition by mixing the components in any order. Generally the components are mixed in the plastograph at 30 to 200 RPM until the mix appears to be uniform.
The final product blends can vary in overall composition according to the desired porosity in the final prodnet. It has been determined that the greater the overall surface area of the filler, the more plasticizer that can be incorporated. Further. the relative proportions of the ingredients can vary greatly, depending both upon the desired physical properties of the intermediate product and the final product.
The polyolefin/filler/plasticizer blends were normally pressed in standard fashion common to the art on a hydraulic press into 0.020 inch (nominal thickness) sheets at l25-l75 C. for about 3 minutes at about 500 psi. The only property of interest in the intermediate plastic property is sulficient flexibility and strength to be subjected to the forming, fusing (where indicated), and extraction steps necessary before burning and firing.
The method of shaping, pressing (or fabricating), is directly related to the type of porous ceramic structure which is desired.
In one embodiment a smooth filled thermoplastic sheet is rolled up as in FIG. 1 and then subjected to the process of the invention. The resulting ceramic body (FIG. 2) is then high in microporosity and is readily impregnated with oxidation catalysts.
In another particular embodiment the filled polyolefin sheet is prepared with integral ribs as shown in FIG. 3. Following the preparation of the filled polyolefin it can be prepared as shown in FIG. 3 by any of several methods of fabricating such as molding, extrusion embossing or calendering. The sheet can then be rolled up as in FIG. 4. The ribs 1 can be toward the inside or the outside of the roll. The ribs whose shape can be continuous, discontinuous, cylindrical (like tufting in a carpet) etc. act as spacers to provide macroporosity. This type of shaping will produce a honeycombed ceramic structure exhibiting both micro and macroporosity. The microporosity is achieved as the polyolefin is eventually burned out.
A slightly different honeycomb structure can be obtained by rolling the sheet at any angle of less than 90 (FIG. 6) when a polyolefin material having integral ribs (2, 2) on both sides (FIG. 5, wherein the ribs on each side of the sheet are not parallel in order to avoid "nest ing of the ribs on contacting sides) is used. Such a micro-macro porous ceramic body assures a turbulent flow of gas and is particularly well-suited to serve as a catalyst support having a high capacity for contacting a gas such as exhaust fumes from an automobile, in accordance with the instant invention.
It is possible to provide additional pore volume in ii porous ceramic structure by foaming the filled polyolefin composition. (The foaming can be accomplished by the addition of any known foaming agent to the filled. plasticized polyolefin composition.) Such a composition can then be fabricated into any foamed shape by normal plastic processing means and later developed into a porous ceramic structure (FIG. 7).
In yet another embodiment nets of filled polyolefin (FIG. 8) (as hereinafter described) can be fused together (FIG. 9) to form a three-dimensional network which. when converted into a microporous ceramic is useful as a support for a catalyst in gas contacting catalytic processes. This structure is readily impregnated with catalysts in accordance with this invention. This method produces a low density ceramic structure with a large surface and having no straight paths through the structure, thereby providing a tortuous path and a highly turbulent fiow of gas. The interim fused structure can be prepared by layering net or rolling up of net. both prior to fusing the adjacent layers.
Following fusion the plasticizcr is then extracted. This can be accomplished by any solvent in which the plasticizcr is soluble. For example, when using a plasticizer such as mineral oil, hexane is a suitable solvent. When a water soluble plasticizer such as diethylene glycol is used. water is a suitable solvent. The removal of the plasticizer results in the formation of a microporous structure. in addition to providing greater surface area. the extraction of the plasticizer prior to burning off the polyolefin is of great value since the formation of the micropores aids in removing gaseous combination products which are formed when the polyolefin is burned off.
After the plasticizer has been extracted the structure is heated to above the degradation temperature of the thermoplastic so as to completely burn oil the polyolefin. The degradation temperature will. of course, vary with the choice of polyolefin. For the high viscosity linear poly ethylene that I prefer to use, a temperature in the range of at least 240 to 260 C. is greatly preferred to initiate degradation.
At a temperature of about 240 C. (when polyethylene is the polyolefin) the structure begins to turn black and at about 700 C. the structure begins to turn white, indi cating that the thermoplasic has entirely burned off.
When the thermoplastic is completely burnt off. the temperature is increased to that in which the particular powder sinters into a monolithic structure, still retaining the microporosity. When using the preferred ceramic pouder, a-alumina. a temperature of about l.300-l. (I is recommended. The temperature is held at the sintering point for about 2 hours and then the structure is tlliO\\Cd to cool slowly to room temperature. The cooling time is generally about 34 hours.
The resulting porous ceramic body appears identical in shape to the original plastic structure except that a slight linear shrinkage. 15-20 percent. takes place.
In addition to the basic procedure heretofore described i.e. mold. roll, heat the structure to just below the burn off point to fuse thermop'astically, extract the plasticizer, burn off the polyolefin. and fire the ceramic structure, variations of this procedure also result in excellent porous ceramics.
The method of impregnation is not critical, but rather any method which is capable of placing the catalytic components within the porous structure is sufficient. Further, the particular catalytic components used are not specific to this invention. Any of the various catalytic components suitable for removing air polluting fumes from auto gases are operable.
Some of the useful catalytic compositions are disclosed in US. Pat. Nos. 3.288.558; 3.295.918; 3.?04,l50; 3.322,- 491; 3.338,666; 3,346,328; 3,455,843 and 3,470,105. These catalytic compositions include the following catalytic components in percentages by weight of the tgtal catalyst structure.
Catalyst 1 Catalytic Components-40?; CuO, 4.0%-
Cr O 0.02% Pd. Catalyst 2 Catalytic Components8% CuO; 12.0%
MrlO 0.02% Pd. Catalyst 3 Catalytic Components4% CuO, 6% MnO;,,
Of course, other catalytic compositions are also useful.
A particularly suitable method of impregnating these catalytic components onto the porous material is that described in U.S. Pat. No. 3,455,843 wherein the cdpperpalladium is impregnated into the porous structure by means of a copper-palladium solution followed by impregnation with the chromia (Cr O by vacuum impregnation (Catalyst 1). The components of Catalyst 2 are therein impregnated into the porous structure by immersing the structure in a copper-manganesc-palladiurn salt solution. When this is followed by impregnation with the chromia by vacuum impregnation, a porous ceramic structure containing the catalytic components of Catalyst 3 was thereby prepared.
The following examples will aid in further explaining the invention.
EXAMPLE 1 An alumina filled polyethylene composition designated Composition A and containing the following components, 8.6 grams particle form linear polyethylene of Melt Index (SLMI), 76.8 grams tit-alumina, and 28.8 grams of a mineral oil with approximately 80 percent saturates (viscosity: ssu at 100 F.=547, refractive index=l.4932 1:0.0003, and special gravity at C.=0.90360.9071) available commercially as Shellflex 411 was prepared by compounding the raw materials in a Brabender Plastograph at 170 C. This composition was then labeled Plastic A" and was then pressed to a 12 mil sheet in a hydraulic press with tons force, then repressed in a mold to give a ribbed sheet with a 6 mil backweb, and about mil wide with a taper, mil high ribs spaced one-eighth inch apart. From the ribbed sheet, strips were cut 30 mm. wide by 8 inches, and these were rolled up tightly with the ribs in the direction of the axis of the roll, forming a honey comb-like cylinder. This was inserted into a tight fitting, glass tube, and heated to heat-seal the consecutive layers of the spiral roll of ribbed sheet at about 150 C.
The cylinder was then cooled and immersed in hexane for 30 minutes to extract substantially all the mineral oil,
then dried and heated in a furnace in an oxidizing atmosphere first to about 250 C. (over a period of about 2 hours) when degradation began as evidenced by the black color of the structure. The temperature was slowly decreased and about 2 hours later and at about 700 C. the structure turned white, indicating that the burn off of the 10 polyethylene was complete. The temperature was then slowly increased and about 2 hours later the temperature reached 1.450 where it was held for about 2 hours to sinter the remaining ceramic powder and cooled slowly (about 4 hours).
The honeycombed porous ceramic body (designated Ceramic body A) which resulted appeared identical in shape to the original plastic structure, but the dimensions were slightly smaller. The body had good physical strength and was hard enough to scratch ordinary glass.
Weight percent can readily be converted to volume percent by dividing a given component by its density and recalculating on a percentage basis. Thus, in Example 1, the components in weight percent can be converted to volume percent as follows:
Volume Wt. percent+ in propor- Component density tional parts Volume percent Polynthylene B.6-:l 8.6 a-alurninn 76.8+4= 10.2 Mineral oil 28.8+1 28.8
Total 56. 6 10'). 0
1 An approximation.
EXAMPLE 2 Another sample of Composition A" was used to prepare another sample of Plastic A which was then pressed to a 20 mil sheet in a hydraulic press with 20 tons force. then repressed in a mold to give a ribbed sheet with 6 mil backweb and ribs on opposite sides of the sheet, crossing at each 25 mils wide (tapered) and 30 mils high. and spaced one-eighth inch apart. From the ribbed sheet strips were cut at 45 angles to both ribs 30 mils wide by 8 inches, and these strips were rolled up. Fusing was then accomplished by passing hot air through the strip as in Example I. The fused structure was then cooled and immersed in hexane for 30 minutes to extract the plasticizer, dried and heated in a furnace first to about 250 C.. then to about 700 C. and finally to 1,450 C., as in Example 1. The honeycombed porous ceramic body (designated Ceramic Body B") which resulted appeared identical to the original plastic structure, but the dimensions were slightly smaller. This body also had good physical strength and was hard enough to scratch ordinary glass.
EXAMPLE 3 Another sample of Composition A was used to prepare another sample of Plastic A" which was then made into a foamable material (designated Plastic Foam A) by the addition of 0.25 percent of a chemical blowing agent, azo-bis-formamide. The foamable material was heated at 200 C. at which temperature the foaming agent decomposes. The foamed material was then water-cooled and fused as in Example 1. The plasticizer, mineral oil, was then extracted by dipping the shaped material into hexane for 30 minutes. After drying at room temperature for 30 minutes, the shaped material was heated in a furnace to about 250 C., then 700 C. and finally to 1,450 C. as in Example 1 to burn off the polyethylene and to sinter the ceramic powder and cooled slowly. The porous ceramic body (designated Ceramic Body C") which resulted appeared identical in shape to the original foamed structure except that the dimensions were slightly smaller. This ceramic body provided additional pore volume and was less dense than Ceramic Bodies A and B.
EXAMPLE 4 Another sample of Composition A was used to prepare a sample of Plastic A which was pressed to a 20 mil sheet in a hydraulic press with 20 tons force and then pressed between two crossed. grooved press platens to produce a sample of plastic net. The net was cut. rolled up. and then fused together by heating at a temperature of about (50 C. to form a three-dimensional net structure which was then cooled to room temperature. Extraction of the plasticizer and heating to burn off the polyethylene and sinter the ceramic structure took place as in Example I.
The porous ceramic body (designated Ceramic Body D") was of low density (48 lbs./ft. had a large surface. and without straight paths. The body also had good physical strength and was hard enough to scratch ordinary glass.
EXAMPLES 5 AND 6 Example l was repeated except that a high molecular weight ethylene-butene copolymer commercially'available from Allied Chemical Company (0 standard load melt index, 1.8 high load melt index. 0.943 density, a reduced solution viscosity of 4.0 and a molecular weight of about 180,000) was used in place of polyethylene in Example 5. In Example 6. Hifax 1901. a high density linear pol'y'ethylene (0 standard load melt index. and a molecular weight of about 2 million) was used in place of the polyethylene. In each case. ceramic bodies were obtained exhibiting good strength.
Various other fillers as explained herein were used in place of a a-alumina of Example I. Some of the partiipularly good ceramic powders adaptable of this invention were the following:
EXAMPLES 7-9 In Example 7 a mullite composition of 75 percent by weight raw kyanite (-325 mesh, Al O -SiO and 25 percent by weight South Carolina kaolin (commercially available from Huber Corp.) was used in place of the a-alumina. In Example 8 a mullite composition of 75 percent by weight calcined mullite (325 mesh, a 70 percent alumina bauxite-clay calcine) and 25 percent by weight South Carolina kaolin (Huber Corp.) was used in place of the tit-alumina; and in Example 9 a mullite composition of 85 percent calcined mullite (-325 mesh. a 70 percent alumina bauxite-clay calcine) and percent Jackson ball clay (commercially available from Kentucky- Tenn. Clay Corp.) was used in place of the tit-alumina. In each case the sintering temperature was about 1,225- 1.35011. With each ceramic powder a ceramic body of good strength was obtained.
EXAMPLE [0 In this example a zircon-mullite composition of 50 percent calcined mullite (-325 mesh. a 70 percent alumina bauxite-clay calcined). percent ground zircon (325 mesh) and 25 percent South Carolina clay was used in place of the tit-alumina of Example 1. The rest of the procedure was the same as Example 1 except that the sintering temperature was 1,2251,350 C. A ceramic body of good strength was obtained.
EXAMPLE 11 Example 1 was repeated except that in place of a-alumina. a spine] (commercially available from W. R. Grace & Co.) prepared from the decomposition of high purity magnesium aluminate was used. The sintering temperature was 1.225-l.350 C. and a porous ceramic body of good strength was obtained.
Another preferred ceramic powder is that commonly referred to as cordierite, which is a zeolite of the formula 2MgO-2Al O -5SiO The following cordierite compositions were prepared and used as the ceramic powder in the plastic composition.
12 EXAMPLES l2-l5 In Example 12 a cordierite composition was prepared by admixing percent by weight Florida kaolin and 50 percent by weight sierralite (a relatively pure prochlorite commercially available from United Sierra Div. Cyprus Mines Corp.). The mixture was substituted for the a-alumina of Example I. The remaining procedure of Example 1 was followed. The resulting good strength. porous ceramic body was sintered at l 2(l()-l.225 C. in Example 13 the procedure of Example 1 was followed except that a cordierite composition was prepared from percent by weight Florida kaolin and 25 percent by weight tale. The porous ceramic body which was obtained after sintering at L300 C. was of good strength. In Example 14 a cordierite composition of 72.5 percent by weight Florida kaolin, 22 percent by weight talc, and 5.5 percent by weight magnesium carbonate was substituted for the tit-alumina of Example 1. The rest of the procedure of Example l was followed except that sintering took place at l.275-l.300 C. and a strong porous ceramic body was obtained. In Example 15 the a-alumina of Example I was replaced with a cordierite composition prefaced by admixing 68 percent by weight Florida kaolin.
15 percent by weight talc. and 17 percent by weight magnesium carbonate. The rest of the procedure of Example 1 was followed and a strong porous ceramic body was obtained.
EXAMPLES 16-19 Example 1 was repeated except that the plasticizer. mineral oil. was replaced by the following plasticizers: glycerin (Example 16). diethylene glycol (Example 17), dipropylene glycol (Example 18). and polyacrylic acid (Example 19). In each case the plasticizer was extracted with water and the end product was a strong porous ceramic material.
EXAMPLE 20 This example is intended to show the importance of the plasticizer in the filled polyolefin. A filled plastic material was prepared from 66.7 percent by volume percent by weight) tit-alumina and 33.3 percent by volume (10 percent by weight) particle form linear polyethylene of O melt index. The procedure of Example l (except. of course, for the plasticizer extraction step) was repeated. The resulting ceramic structure was distorted, one end was bubbly, and there was a hole through the center of the structure.
EXAMPLE 2! This example illustrates the necessity of using a high molecular weight polyolefin.
The same composition as used in Example 1, except that in place of the high molecular weight polyethylene a normal molecular weight polyethylene having a standard load melt index of 2.0 was utilized to attempt to prepare a porous ceramic structure. When the structure was burned to remove the polyethylene, the polyethylene melted and prevented the formation of any ceramic body.
EXAMPLE 22 The same composition as that used in Example 1 was used. except that it was made'into a sheet without ribs. When fusion took place the entire material fused giving a cylindrical structure containing micropores. but not any macropores. The porous ceramic structure was very strong and hard enough to scratch glass.
EXAMPLE 23 Three Ceramic Bodies A," three Ceramic Bodies B." three Ceramic Bodies C," three Ceramic Bodies D were each impregnated with the following catalytic components: 4.64% Cr O 6.96% MnO 4.64% CuO, and 0.02% Pd (percentages are by weight). The method of impregnation was that described heretofor.
, about 300 F. The temperature was increased 50 at about 15 minute intervals over a total period of 3 hours. The results are given in the following Table 1:
TABLE 1 Percent Percent conv. conv.
HG Temperature aaeeeeeessss. GQWOZOMCGMFQWW Percent of C0 and HC removed from the feed compositto d steam.
For purposes of determining the effectiveness of the product of this invention it was decided to measure the amount of catalytic activity, hereafter referred to as activity. Activity graphs were prepared wherein the horizontal axis represented temperatures ranging from 350 to 850 F. and the vertical axis represented the amount of conversion of the base component of; the feed composition. With reference to the whole area of the rectangle formed with base 350-850 F. and altitude C -100% conversion," the ratio of the area on the graph beneath the plotted line to the whole area, times 100, was referred to as the percentage of activity. An ideal catalyst would, of course, have a "percentage of activity of 100. For the particular catalytic component used in this example the percentage of activity was obtained as follows:
CO 59.1 HC 27.8
It was also found that the temperature for a percent conversion of CO was 316 F. and for HC the temperature was 506" F. The temperature necessary for 50 percent conversion was 530" F. for CO and 765 F. for HC.
These results are comparable to those obtained when ther forms of catalyst are used for auto exhaust control.
con mullite, magnesium aluminate spinel and cordierite, and 15-80 volume percent of a plasticizer: selected from the group consisting of mineral oils diethylene glycol, propylene glycol, dipropylene glycol glycerine, and a glycerol monoacetate, trimethylene glycol, tetramethylene glycol, 2.3- butylene glycol, triethyl phosphate, polyvinyl alcohol, and polyvinyl pyrrolidone,
b. heating said composition to about to 175 C. molding to form a plastic sheet and impressing ribs thereon,
c. rolling said plastic sheet so that said ribs contact said sheet, heating to about C. to just below the burn ofl point to fuse the contacting areas together thermoplastically,
d. extracting said plasticizer with water or an organic solvent,
e. removing said polyolefin by heating to 240 to 700 C. to form a porous ceramic structure, and to burn off the polyolefin and,
f. firing said porous ceramic structure at a temperature of 1,3001 to l,450 C. [for about 2 hours] for a time sufiicient to sinter said porous ceramic structure,
g. impregnating the porous ceramic structure with solutions of soluble salts of metals exhibiting catalytic activity for converting engine exhaust gases and heating to convert the metals to the active form.
2. The process according to claim 1 wherein said polyolefin is selected from the group consisting of polyethylene, copolymers of polyethylene, and polypropylene, the plasticizer is mineral oil and the plasticizer is removed by contacting the fused structure with hexane.
3. The process according to claim 1 wherein the soluble metal salts include salts selected from the group consisting of copper, chromium, manganese, and palladium salts and mixtures thereof.
4. The process according to claim 3 wherein the solutions contain a sufficient quantity of metal salts to prepare a catalyst containing about 4 to 10 percent CuO. about 4 percent Cr O 0 to 12 percent MnO; and 0.02 percent Pd.
References Cited The following references, cited by the Examiner. are of record in the patented file of this patent or the original patent.
UNITED STATES PATENTS 3,125,618 3/1964 Levinson 264-63 3,285,873 11/1966 Bailey 264-63 X 3,362,783 11/1968 Leak 252-477 R 3,377,269 4/1968 Bloch 252-477 R 3,437,605 4/1969 Keith 252477 R 3,467,602 9/1969 Koester 252477 R 3,533,753 10/1970 Berger 26459 X CARL F. DEES, Primary Examiner US. Cl. X.R.
252-465, 466 PT, 477 R
Claims (1)
1. A PROCESS FOR PREPARING AN ENGINE EXHAUST CATALYST COMPRISING THE FOLLOWING STEPS: A. HOMOGENEOUSLY BLENDING A COMPOSITION CONSISTING ESSENTIALLY OF 15-80 VOLUME PERCENT OF A POLYOLEFIN HAING A MOLECULAR WEIGHT OF AT LEAST 150,000 AND A STANDARD LOAD MELT INDEX OF SUBSTANTIALLY ZERO, 5-67 VOLUME PERCENT OF A CERAMIC FILLER, SELECTED FROM THE GROUP CONSISTING OF ALUMINUM, MULLITE, ZIRCON MULLITE, MAGNESIUM ALUMINATE SPINEL AND CORDIERITE AND 15-80 VOLUME PERCENT OF A PLASTICIZER; SELECTED FROM THE GROUP CONSISTING OF MINERAL OILS DETHYLENE GLYCOL, PROPYLENE GLYCOL, DIPROPYLENE GLYCOL GLYCERINE, AND A GLYCEROL MONOACETATE, TRIMERTHYLENE GLYCOL, TETRAMETHYLENE GLYCOL, 2,3BUTYLENE GLYCOL, TRIETHYL PHOSPHATE, POLYVINYL ALCOHOL, AND POLYVINYL PYRROLIDONE, B. HEATING SAID COMPOSITION TO AOUT 125* TO 175*C., MOLDING TO FORM A PLASTIC SHEET AND IMPRESSING RIBS THEREON, C. ROLLING SAID PLASTIC SHEET SO THAT SAID RIBS CONTACT SAID SHEET, HEAATING TO ABOUT 150*CC. TO JUST BELOW THE BURN OFF POINT TO FUSE THE CONTACTING AREAS TOGETHER THERMOPLASTICALLY, D. EXTRACTING SAID PLASTICIZER WITH WATER OR AN ORGANIC SOLVENT, E. REMOVING SAAID POLYOLEFIN BY HEATING TO 240* TO 700*C. TO FORM A POROUS CERAMIC STRUCTURE, AND TO BURN OFF THE POLYOLEFIN AND, F. FIRING SAID POROUS CERAMIC STRUCTURE AT A TEMPERATURE OF 1,300* TO 1,450*C. (FOR ABOUT 2 HOURS) FOR A TIME SUFFICIENT TO SINTER SAID POROUS CERAMIC STRUCTURE, G. IMPREGNATING THE POROUS CERAMIC STRUCTURE WITH SOLUTIONS OF SOLUBLE SATS OF METALS EXHIBITING CATALYTIC ACTIVITY FOR CONVERTING ENGINE EXHAUST GASES AND HEATING TO CONVERT THE METALS TO THE ACTIVE FORM.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
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US8292670A | 1970-10-22 | 1970-10-22 | |
US8302070A | 1970-10-22 | 1970-10-22 | |
US8291870A | 1970-10-22 | 1970-10-22 | |
US44022074A | 1974-02-06 | 1974-02-06 |
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Publication Number | Publication Date |
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USRE28195E true USRE28195E (en) | 1974-10-08 |
Family
ID=27491747
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00082918A Expired - Lifetime US3755204A (en) | 1970-10-22 | 1970-10-22 | Porous ceramic-exhaust oxidation catalyst |
US28195D Expired USRE28195E (en) | 1970-10-22 | 1974-02-06 | Porous-ceramic exhaust oxidation catalyst |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00082918A Expired - Lifetime US3755204A (en) | 1970-10-22 | 1970-10-22 | Porous ceramic-exhaust oxidation catalyst |
Country Status (7)
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US (2) | US3755204A (en) |
BE (1) | BE774365A (en) |
CA (3) | CA973691A (en) |
DE (1) | DE2152498A1 (en) |
FR (1) | FR2113089A5 (en) |
GB (1) | GB1349400A (en) |
NL (1) | NL7114554A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5417938A (en) * | 1988-09-02 | 1995-05-23 | Sulzer Brothers Limited | Device for carrying out catalyzed reactions |
Families Citing this family (47)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1412142A (en) * | 1972-01-14 | 1975-10-29 | Foseco Int | Gas reactors |
JPS5137634B2 (en) * | 1972-01-18 | 1976-10-16 | ||
US3963504A (en) * | 1972-07-05 | 1976-06-15 | W. R. Grace & Co. | Porous ceramic structure |
US3953176A (en) * | 1973-05-22 | 1976-04-27 | Texas Instruments Incorporated | Catalytic converter |
GB1491445A (en) * | 1973-11-08 | 1977-11-09 | Atomic Energy Authority Uk | Catalyst bodies and methods of manufacturing such bodies |
US3904551A (en) * | 1973-12-19 | 1975-09-09 | Grace W R & Co | Process for preparing an auto exhaust catalytic converter |
US3910850A (en) * | 1973-12-19 | 1975-10-07 | Grace W R & Co | Contoured monolithic substrate |
US3932310A (en) * | 1974-03-07 | 1976-01-13 | W. R. Grace & Co. | Reduction firing of ceramics composited with organic binders |
US3983283A (en) * | 1974-03-18 | 1976-09-28 | Corning Glass Works | Honeycombed structures having open-ended cells formed by interconnected walls with longitudinally extending discontinuities |
JPS5144913B2 (en) * | 1974-10-03 | 1976-12-01 | ||
US3985846A (en) * | 1975-04-16 | 1976-10-12 | W. R. Grace & Co. | Ceramic firing process |
US4054702A (en) * | 1976-03-05 | 1977-10-18 | W. R. Grace & Co. | Monolith design |
JPS5351327A (en) * | 1976-10-20 | 1978-05-10 | Matsushita Electric Ind Co Ltd | Catalytic type exhaust purifier |
WO1981000970A1 (en) * | 1979-10-03 | 1981-04-16 | Acurex Corp | Catalyst compositions,their method of formulation and combustion processes using the catalyst compositions |
US4337028A (en) * | 1980-05-27 | 1982-06-29 | The United States Of America As Represented By The United States Environmental Protection Agency | Catalytic monolith, method of its formulation and combustion process using the catalytic monolith |
US4628042A (en) * | 1983-06-20 | 1986-12-09 | Engelhard Corporation | Porous mullite |
JPS6078707A (en) * | 1983-10-07 | 1985-05-04 | 日本碍子株式会社 | Ceramic honeycomb structure and manufacture thereof and rotary heat accumulation type ceramic heat exchange body utilizing said structure and extrusion molding die for said heat exchange body |
JPH0643140Y2 (en) * | 1985-03-05 | 1994-11-09 | 株式会社ブリヂストン | Breathable insulation |
DE3521766A1 (en) * | 1985-06-19 | 1987-01-02 | Basf Ag | HONEYCOMB CATALYST, ITS PRODUCTION AND USE |
US4716064A (en) * | 1985-10-31 | 1987-12-29 | Air Products And Chemicals, Inc. | Composite stiff lightweight structure and method for making same |
US4902216A (en) * | 1987-09-08 | 1990-02-20 | Corning Incorporated | Extrusion die for protrusion and/or high cell density ceramic honeycomb structures |
US5028650A (en) * | 1988-01-27 | 1991-07-02 | W. R. Grace & Co.-Conn. | Boron nitride sheets |
US4920640A (en) * | 1988-01-27 | 1990-05-01 | W. R. Grace & Co.-Conn. | Hot pressing dense ceramic sheets for electronic substrates and for multilayer electronic substrates |
US5149475A (en) * | 1988-07-28 | 1992-09-22 | Ngk Insulators, Ltd. | Method of producing a honeycomb structure |
JP2581774B2 (en) * | 1988-07-28 | 1997-02-12 | 日本碍子株式会社 | Ceramic honeycomb structure and method of manufacturing the same |
ATE106856T1 (en) * | 1989-03-10 | 1994-06-15 | Grace W R & Co | BORON NITRIDE COATINGS. |
IT1232749B (en) * | 1989-04-12 | 1992-03-05 | I R T I Istituto Di Ricerca E | EXHAUST GAS PURIFIER WITH CATALYTIC ACTIVITY AND SILENCER FOR INTERNAL COMBUSTION ENGINES |
US5229080A (en) * | 1990-06-29 | 1993-07-20 | Ngk Insulators, Ltd. | Resistance adjusting type heater and catalytic converter |
US5229079A (en) * | 1990-06-29 | 1993-07-20 | Ngk Insulators, Ltd. | Catalytic converter for use in automotive exhaust emission control |
JP2818473B2 (en) * | 1990-06-29 | 1998-10-30 | 日本碍子株式会社 | Catalytic converter for automotive exhaust gas purification and automotive exhaust gas purification method |
US5234668A (en) * | 1990-07-25 | 1993-08-10 | Ngk Insulators, Ltd. | Catalytic converter for use in automotive exhaust emissions control |
US5660778A (en) * | 1995-06-26 | 1997-08-26 | Corning Incorporated | Method of making a cross-flow honeycomb structure |
DE69620080T2 (en) * | 1995-08-30 | 2002-09-12 | Haldor Topsoee As Lyngby | Process and catalytic unit for the treatment of exhaust gas in diesel engines |
DE19533486A1 (en) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodal and polymodal catalyst supports and catalysts with narrow pore size distributions and their manufacturing processes |
DE19533484A1 (en) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodal and polymodal catalyst supports and catalysts with narrow pore size distributions and their manufacturing processes |
US5897915A (en) * | 1996-10-28 | 1999-04-27 | Corning Incorporated | Coated substrates, method for producing same, and use therefor |
DE59807201D1 (en) * | 1997-08-22 | 2003-03-20 | Deutsch Zentr Luft & Raumfahrt | FROM FLUID-FLOWABLE, POROUS BODY WITH THIS PULLING CHANNELS AND METHOD FOR PRODUCING THE BODY |
EP1027304B1 (en) * | 1997-10-03 | 2005-07-13 | Corning Incorporated | Method for firing ceramic honeycomb bodies |
US6544589B2 (en) | 2001-08-20 | 2003-04-08 | Northrop Grumman Corporation | Method of controlling drying stresses by restricting shrinkage of ceramic coating |
US7141204B2 (en) * | 2002-12-18 | 2006-11-28 | Corning Incorporated | Method of forming ceramic articles |
JP4161948B2 (en) * | 2004-08-23 | 2008-10-08 | トヨタ自動車株式会社 | Heat generation system and heat supply method |
US8318627B2 (en) * | 2005-08-10 | 2012-11-27 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for preparation of a catalyst carrier |
WO2007096986A1 (en) * | 2006-02-24 | 2007-08-30 | Ibiden Co., Ltd. | End face heating apparatus, method of drying end face of honeycomb assembly, and process for producing honeycomb structure |
US8257659B2 (en) * | 2007-07-02 | 2012-09-04 | Cummins Filtration Ip, Inc. | Prevention of face-plugging on aftertreatment devices in exhaust |
US9566562B1 (en) * | 2012-08-21 | 2017-02-14 | Superior Technical Ceramics Corporation | High-temperature open-cell porous ceramic |
JP5735046B2 (en) * | 2013-06-18 | 2015-06-17 | コバレントマテリアル株式会社 | Insulation |
DE102015211582B4 (en) * | 2014-06-24 | 2018-03-01 | Coorstek Kk | thermal insulation material |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3125618A (en) * | 1964-03-17 | Method of molding and a ceramic binder formulation | ||
GB1006518A (en) * | 1963-03-21 | 1965-10-06 | Doulton & Co Ltd | Improvements in or relating to moulding ceramic material |
US3362783A (en) * | 1963-12-23 | 1968-01-09 | Texaco Inc | Treatment of exhaust gases |
US3377269A (en) * | 1964-06-15 | 1968-04-09 | Universal Oil Prod Co | Oxidation catalyst comprising variable density activator |
US3437605A (en) * | 1965-01-26 | 1969-04-08 | Engelhard Ind Inc | Method of preparing a supported catalyst |
DE1517993A1 (en) * | 1965-10-29 | 1969-02-13 | Heinz Berger | Process for the manufacture of catalysts |
US3467602A (en) * | 1966-10-24 | 1969-09-16 | Air Prod & Chem | Preparing porous refractory oxides by adding and removing polypropylene microspheres |
-
1970
- 1970-10-22 US US00082918A patent/US3755204A/en not_active Expired - Lifetime
-
1971
- 1971-09-28 CA CA123,868A patent/CA973691A/en not_active Expired
- 1971-09-28 CA CA123,869A patent/CA972344A/en not_active Expired
- 1971-09-28 CA CA123,870A patent/CA973692A/en not_active Expired
- 1971-10-21 DE DE19712152498 patent/DE2152498A1/en active Pending
- 1971-10-21 FR FR7137928A patent/FR2113089A5/fr not_active Expired
- 1971-10-22 NL NL7114554A patent/NL7114554A/xx unknown
- 1971-10-22 BE BE774365A patent/BE774365A/en unknown
- 1971-10-22 GB GB4920371A patent/GB1349400A/en not_active Expired
-
1974
- 1974-02-06 US US28195D patent/USRE28195E/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5417938A (en) * | 1988-09-02 | 1995-05-23 | Sulzer Brothers Limited | Device for carrying out catalyzed reactions |
Also Published As
Publication number | Publication date |
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US3755204A (en) | 1973-08-28 |
CA973692A (en) | 1975-09-02 |
CA972344A (en) | 1975-08-05 |
BE774365A (en) | 1972-02-14 |
FR2113089A5 (en) | 1972-06-23 |
CA973691A (en) | 1975-09-02 |
GB1349400A (en) | 1974-04-03 |
NL7114554A (en) | 1972-04-25 |
DE2152498A1 (en) | 1972-05-25 |
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