USRE24366E - comstock - Google Patents

Description

Oct. 1, 1957 G. E. coMsTQcK an Re 24,365

asmFoRcEn CERAMIC BODY or REVOLUTION origina; Filed sept. 12. 1951 United States Patent O REINFORCED CERAMIC BODY or REVOLUTION George E. Comstock, 3d, Huntington, N. Y., assignor to Norton Company, Worcester, Mass., a corporation of Massachusetts Original No. 2,745,437, dated May 15, 1956, Serial No. 246,305, September 12, 1951. Application for reissue May 24, 1957, Serial No. 662,962

13 Claims. (Cl. 13S-64) The invention relates to cylinders and other bodies of revolution, for use as bearings, liners, sleeves, molds, cams, guides, and the like and a method of making them.

One object of the invention is to provide cylinders, etc. for use as bearings, etc. of ceramic material, which are strongly reinforced. Another object of the invention is to provide a facile and economical method for making such cylinders, etc. Another object is to provide cylinder liners for internal combustion engines which will increase the useful lives of the engines many fold. Another object of the invention is to provide superior pump liners. Another object is to provide bearings of long life and adequate load carrying capacity. Another object is to provide nozzles of many types, of superior resistanceA to Wear and to erosion and of great strength.

Another object of the invention is to provide an inexpensive method of reinforcing ceramic cylinders and other bodies of revolution. Another object is to provide avmethod of the type indicated which accurately aligns a ceramic part and a metal reinforcing part. Another object is to provide a method of manufacturing a plurality of cylindrical or liner portions of ceramic material precisely aligned with respect to each other and reinforced with metal parts. Another object is to reinforce ceramic pieces axially as well as radially.

Another object is to provide a three-component article in which one component is a wear resisting part, another component is a reinforcing part and the third component permits one or both of the other components to be irregular while mating perfectly with each and perfectly transmitting stress from the reinforcing component to the wear resisting component. Another object is to provide a twocomponent article in which one component is a Wear resisting part and the other component is a reinforcing part and which permits the wear resisting part to be irregular while mating perfectly with it and perfectly transmitting stress thereto.

Other objects will be in part obvious or in part pointed out hereinafter.

In the accompanying drawings illustrating a plurality of articles made in accordance with this invention and illustrating also several embodiments of the method of the invention,

Figure l is a vertical sectional view of a reinforced ceramic sleeve for use for example as a bearing showing also the assembly for its manufacture,

Figure 2 is a sectional view similar to Figure 1 illustrating another embodiment of the invention,

Figure 3 is another vertical sectional view illustrating the manufacture of a pair of aligned bearings and the product resulting from such manufacture,

Figure 4 is a sectional view similar to Figures l and 2 illustrating still another embodiment of the invention,

Figure 5 is a vertical sectional View of a centrifugal mold and the assembly for the manufacture of a rein- Re. 24,366 Reissued Oct. 1, 1957 ICC forced ceramic sleeve for use for example as a bearing or a cylinder liner or for other purposes as indicated in the objects,

Figure 6 is a fragmentary end elevation of the mold of Figure 5.

The ceramic body of revolution may be made by sintering relatively pure refractory material or it may be made by mixing granular refractory material with clay or clays with or without a ux, pressing in a mold, thereafter firing the pressed body in a kiln to vitrify the clay or clays. This ceramic body of revolution according to the invention is made of refractory ceramic material having high compressive strength, at least 100,000 pounds per square inch, and the major portion thereof is material selected from the group consisting of silicates, other oxides and carbides. This refractory material should have a hardness of at least 7 (quartz) on Mohss scale.

In a preferred example of the manufacture of this ceramic body out of oxide material I may use aluminum oxide powder produced by the Bayer process consisting of alumina to the extent of 99.5%. I first ball mill this with iron balls until the particle size is in the neighborhood of 3 microns and I` then wash this powder by decanting with dilute hydrochloric acid until it is comparatively free from iron picked up from the iron balls and from the mill. Thereafter I wash the powder with distilled water and stop when the pH of the wash water is approximately 3, as it is advantageous to have the powder slightly acidic. I then suspend this tine alumina in water and cast it in plaster molds in the conventional manner following which the cast material is dried and removed from the mold and then fired in a kiln at a top temperature of 1825 C. for a few minutes. At this temperature the alumina particles sinter together and the whole mass shrinks to a dense material with a specific gravity of about 3.7. Thereafter the working surface of this ceramic body of revolution is internally ground with a diamond grinding wheel to produce a smooth and reflective surface.

In place of slip casting the ball milled alumina it can, after the acid treatment and washing above described, be pressed into the desired shape, usually a cylinder, in a steel mold under pressures from 2 to 10 tons per square inch.

Articles made as above described have a hardness of 9 on Mohss scale and when reinforced as will hereinafter be described they make excellent bearings, liners, sleeves, molds, cams, guides and the like. However, I

have found that for many practical purposes it is unnecessary to use oxide material of such high purity as is the Bayer process alumina nor is it necessary to tire it at such a high temperature. Thus to the alumina I can add some clay or clays and mold and tire such mixtures. As an example I take what is known as regular alumina, which is made by reducing bauxite in an electric furnace and is usually about A1203, ball mill this material to produce particles between 2 and 25 microns in size, acid treat the ball milled alumina and then wash it as above described, then mix it with 10% of kaolin (which is a variety of clay) and a small amount of water to make the mix moldable, then mold the cylinder or other shape and fire the molded piece at a temperature of about l650 C. thereby obtaining articles of a hardness of at least 8 on Mohss scale. The article is then internally ground, and a very smooth and true reflective surface can be imparted thereto with a diamond grinding wheel.

I can also add to such a mixture a flux such as a compound of magnesium or calcium, thus lowering the tiring temperature. Thus by adding for example up to 3% of lime ormagnesia the firing temperature will be lowered to about 1600 C. Lime and magnesia can Vbe used in admixture with each other. A typical analysis of a body ofrevolution made as above described'i's given in Table I.

In case clay is used' in substantial quantityan appreciable amount ofimullite will appear in the finished. ar-

ticle. It will be seen that by increasing the quantity ofV clayv in proportion to the alumina, a. gradual transition will occur i'n the finishedV article from substantially 100% alpha alumina to 100%V mullite and IT have found that all mixtures are useful for my bodies, though for the more severe applications, the compositions with high, alpha alumina are preferred.

It should be mentioned that another practical means of fabricating the bodies. is. by hot pressing the molding powder in a graphite mold at apressure of roughly 2500 pounds per square inch and a temperature between 1200" and 1700 C., the temperature being chosen to suit the particular composition.

If to the ball milled alumina above I had added magnesium oxide alone, the rst effect would have been to inhibit the grain growth of the aluminumoxide although the body would have sintered. satisfactorily. Many experiments have shown that bodies containing from V2 to 11/2% magnesia and as a consequence sintering to much. ner crystal structures are stronger and therefore more suitable for my purposes than when magnesia is absent. When the magnesium oxide content reaches approximately l1/2%, micro crystals ofmagnesium spinel are observable in the fired product. As the amount of magnesia is increased above this point, the volume of spinel crystals in the mass increases very rapidly until the whole structure is converted to spinel at a magnesia content of 10%, although the stoichiometric proportion of magnesia in magnesium spinel is 28%. The explanation is that at a high temperature of firing, such as cone 35, alpha alumina is soluble in magnesium spinel to such an extent that although the crystal structure is not changed, the alumina content may be as high as 90%.

This high alumina spinel is very abrasion resistant and in some applications is as good as sintcred alpha alumina. In some cases it is superior due to the isotropic nature ofthe spinel. As more magnesia is usedin the mixture, the spinel approaches the theoretical composition andthe hardness declines but is still sufficient, when` there is n extra alumina, to be highly satisfactoryl for many applications. Magnesium spinel is MgOAlzzOsL and it can. be made in the electric furnace.

The ceramic portion of my article can also be made of mullite. Mullite is 3Al2O3-2SiOz and can be. made. in the` electric furnace. The ceramic portion of thearticle can be made of zirconia or stabilized zirconia. Stabilized zirconia is zirconia, ZrO2, stabilized with from 3% to 6% of lime CaO or magnesia MgO. The Way to synthesize fused stabilized zirconia with from 3% to 6% of lime in solid solution. in the zirconia is fully set forth in U. S. Letters Patent No. 2,535,526 granted December 26, 1950, on application of Ballard and Marshall. The-correct definition of material described in that patent and including also zirconia stabilized with magnesia or with other oxide is-stabilized zirconia the crystals of which are predominantly cubic. Unstabilized zirconia is monoclinic in crystal habit. Ceramic bodies of revolution made out of any magnesium spinel, mullite and stabilized zirconia, the crystals of which are predominantly cubic should be made in the manner already explained for` making such components out ofaluminum oxide.

The patent literature is replete withexamples of ceramic compositions the principal component of which is alumina many of'which are quite satisfactory for the manufacture of the ceramic body of revolution of my invention. The following table identifies particular patents describing compositions the principal component of which is alumina, all of which compositions are satisfactory for my purpose, and the table includes a brief identification of an illustrative embodiment of the component with which the alumina is.. bondedl or iny some cases gives anillustrative embodimentof the total composition.

Table II Inventor Patent No. Date Brief Description F. B. Norton 187,167 'Feb 6, Corundum bonded 1877. with clay and feldspar. Saunders and-White-. l, 240, 490- Sept: 18, Alumina containing,v

. 1917. zirconia bonded with vitried clay. Jeppson and Dietz 1, 292, 953 .T an. 28, Graded particles of 1919. A1203 bonded with ball clay, slipy clay and ieldspar. Purdy, Beecher and 1, 394,442 Oct. 18, Sintered magnesium Klein. 1921. aluminum spinel with an excess of l alumina. M. C. Booze 1, 616, 525 Feb. 8, Sillirnanite.

1927. Saunders,A Milligan 1,829, 761 Nov. 3, Combination of oxides.

and Beecher. 1931 Ball clay 31%. v Feldspar 52%. Milliganand Quick... 1, 910,031 May 23, Flint 8%.

1933. Whiting 6%.

Magnesia 3%. Slip clay 75 parts. Milligan and Armil, 987,861 Ian. 15, Ball clay 25 parts.

tage. 1935. Aluminum phosphate 20 parts. O. W. Saxe 2, 118, 798 M1324, 1% of bentonite.

The ceramic body of revolution can be made of a hard carbide. Silicon carbide has a hardness considerably in excess of 9 (corundum) on Mohs scale. By bonding silicon carbide with clay or other ceramic bonds. very hard' and wear-resistant :articles can be made. Selfbonded silicon carbide is known, the process of manufacture of which consists in recrystallizing the silicon carbide granules but I prefer to use ceramic bonded silicon carbide for the ceramic portion of my article as stronger and denser bodies principally of silicon carbide can be made by bonding the silicon carbide granules with ceramic materials rather than by the recrystallization process. The following table identifies patents dealing with ceramic bonded silicon carbide compositions and briefly identities an illustrative embodiment of such composition in the same manner as Table II.

Table III Inventor Plaltant Date Brief Description to 15 a. Boron oxide 5% to 25%. A aline metal oxide Dec. 19, Feldspar 60%-75%.

Beecher, Klein and Greenwood.

Milligan and Lombard.

July 14,

Oct. 4, 1938.

Miblligm and Lom- 2,158,034

May 9, ar

Lombard and Milligan.

2, 332, 241 Oct. 19.

oro carbide can be hot molded to make ceramic pieces of adequate strength and great hardness. No extraneous materials are used, tine particles of boron carbide being hot pressed in graphite molds to produce the desired articles and the ceramic component of my inventioii can be made of such molded boron carbide. Boron carbide, BiC, has a hardness even greater than that of silicon carbide and is said to be second only to the diamond in hardness of all materials known. The synthesis of boron carbide and how to mold it are described in v arious patents to the late R. R. Ridgway particularly Nos. 1,897,214; 2,155,682; 2,123,158; 2,037,786; 2,121,744 and 2,125,588.

VThe ceramic component of my invention can also be made of any of the carbides which are now used to make cutting tools, that is to say out of tungsten carbide, titanium carbide or tantalum carbide, or out of mixtures of two of the foregoing or all three thereof. Cutting tools and portions thereof are now made out of these carbides by taking the powder or powders thereof and mixing such powder or powders with a lesser amount of bonding metal of the iron group, to wit, cobalt, nickel and iron of which cobalt seems to be preferred. After the powders are thoroughly mixed a quantity thereof is charged into a suitable mold or die and a piece is pressed therefrom subsequent to which the piece is sintered. All of this is well known and has been described in many patents so Ineed not further particularize thereon. Similarly chromium carbide and zirconium carbide can be used to make hard and strong articles, such carbides being likewise bonded with a metal of the iron group usually cobalt.

Referring now to Figure 1 a ceramic cylinder 10 made out of ceramic material within the foregoing disclosure has a ground internal surface 11 and is located on a refractory plate 12 having a raised cylindrical portion 13 just fitting the bore of the cylinder and having also a raised circular lip 14 inside of which fits, with a snug t, asteel sleeve 15. I place this assembly in a suitable furnace and raise it to a temperature just above the melting 'point of a metal or alloy selected in accordance with considerations to be hereinafter described. I then remove the assembly from the furnace and pour the metal, which I have previously melted, into the space between the steel sleeve 15 and the ceramic cylinder 10. Allowing the assembly to cool, the molten metal eventually freezes to form an intermediate sleeve 16 of metal or alloy. It will now be seen that the exterior of the ceramic cylinder 10 can be rough, that is to say unground and just as it was when the piece was formed, and the interior of the steel sleeve 15 can be rough, that is to say having a surface resulting from a casting operation or possibly from a simple machining operation such as with a lathe and nevertheless the three parts will mate perfectly. As the three parts or components cool down to room temperature the steel sleeve 15 shrinks and so does the intermediate sleeve 16 and while the ceramic cylinder 10 also shrinks its coeicient of expansion is less than that of the metal components and so the ceramic cylinder 10 is placed under high compression which gives it the ability to withstand heavy internal stresses. The foregoing is an example and the sleeve 15 does not have to be made of steel in all cases, it can be made of bronze, or aluminum or other metal of adequate strength having a melting point above the melting point of the'metal or alloy selected to form the intermediate sleeve 16.

Figure 2 is illustrative of another embodiment of the invention. The ceramic cylinder 10 is mounted in an open mold 20 having the shape of a crucible with a central hole 21 in a at bottom portion 22, and a plug 23 extends for a short distance into the bore of the cylinder 10, which has the ground internal surface 11, for the purpose of accurately centering the cylinder 10. The mold 20 can be a tamped piece made out of refractory cement, such as 100 parts of alumina cement, 3 parts of monoaluminum orthophosphate and 2 parts of water.

After tamping the piece is air dried and is then ready forv use. The plug 23 is preferably made of Agraphite so as to be readily removable fromvthe bore of the cylinder 10. This assembly is mounted on a refractory plate 24 and is then placed in a furnace and raised to a temperature not too far below [that] the melting point of a particular steel selected to form a sleeve 25. The requirement in this case is that the molten metal shall not crack the ceramic cylinder 10 by heat shock and if the latter is heated to about 800 C. it is usually safe but higher temperatures are safer. perature it is removed from the furnace and molten steel is poured into the space between the cylindrical wall of the crucible 20 and the ceramic cylinder 10 and the assembly is allowed to cool whereupon eventually the steel freezes and later on contracts and when room temperaj ture is reached the sleeve 25 exerts great compressive force against the ceramic cylinder 10. Here again it will be seen that it is unnecessary to grind the exterior of the ceramic cylinder 10 yet the components 10 and 25 mate perfectly. Instead of making the sleeve 25 out of steel it can be made out of other metal or alloy such as bronze or brass in which case the preheating of the assembly canV be to a lower temperature.

Since some of the molten steel or other metal will penetrate between the bottom of the ceramic cylinder 10 and the bottom portion 22 of the crucible 20 and since the specilic gravity of steel is much higher than that of the ceramic material I hold the cylinder 10 down in any suitable way such as by laying a straight steel. bar, not shown, diametrically across the top of the as sembly of Figure 2, and in order that it shall not crack. the hot ceramic cylinder 10 this steel bar should be` heated to a dull red. This precaution should preferably also be taken in other embodiments of the invention'V although the portion 13 will sometimes hold down thecylinder 10. The graphite plug 23 cannot be relied upon. for this purpose since the cylinder 10 expands away from it during the heating.

Another embodiment of the invention is illustrated in Figure 3. A machine element 27 preferably made of steel but which might be made of bronze or other metal may be a connector or a bracket or the like. It has a pair of arms 28 terminating in hub portions 29 in which are intermediate sleeves 30 made of lower' melting point metal and in compression against ceramic'v bearings 31 made out of ceramic material within the foregoing disclosure. This composite article can be made by providing a jig 32 having semi-circular shoulders 33 to fit the outside of the hub portions 29 and having a central bore 34 in which is located an arbor 35 held in position by a screw 36 in threaded engagement with the jig 32 and engaging a cut-out 39 in the arbor 35 which aligns the ceramic bearings 31. This assembly may conveniently be mounted on a refractory plate 40 and is placed in a furnace and heated to a temperature above the melting point of the metal which will form the intermediate sleeves 30. When the assembly is removed from the furnace, metal is poured between the upper ceramic bearing 31 and the upper hub portion 29 and it runs downs through a hole 41 in the jig 32 into the space between the lower ceramic bearing 31 and the lower hub portion 29 and nally fills both the lower and the upper spaces and then, upon cooling, the same action as hereinbefore mentioned occurs, namely that the metal lfreezes to form the intermediate sleeves 30 and the hub portions 29.contract (tending to do so faster than the bearings 31) to place the bearings 31 under high compression. cooled, the screw 36 is loosened, the arbor 30 is removed, the jig 32 is given a tap to break the gate formed in the hole 41 and then the jig 32 is removed. The ceramic bearings 31 were internally ground before assembly but, as inthe other cases, were not or did not have to be externally ground nor was it necessaryto` When the assembly has reached the desired tem- When the assembly has grind vthe bores i'n thel hub portions 29forfto linishv theml pression againstit andv has integral flange portions 47:' exerting axial compression upon it: The metall supportv 46V may be composed? of anym metal orealloyJ but prefer; ably of a fairly hard metal or alloy which will not deform to-relieve thecompression. Desirably the metal support 46 is made of steel or cast iron but brass or bronze can also be used. This support 46 is likewisev made by casting metal around` the ceramic cylinder'.

For making the bearingl of Figure 4 I utilize an openV mold 20- already described having a central hole 21 in which tits the large end of ak two-diameter graphite core 49 thev smaller diameter of which lits the bore of the cylinder 45 so-that the cylinder 4S is supported by the core 49. Also in the bore of the cylinder 45 is the smally end-l of aV second two-diameterl graphite core 50' upon which, after the assembly has been heated, I place diametricall'y across the top of the assembly a heated steel bar as already described, thereby to hold the cylinder 45 down. The assembly is placed upon a refractory plate 51 and put into a furnace wherein the assembly is heated to a temperature not too far below the melting point of the molten metal, whereupon the assembly is removed from the furnacev and the metal is poured to form the support 46. Then the assembly is allowed to cool and the metal freezes and cools down and as it does so it contracts against the periphery of the ceramic cylinder and also against the ends thereof exerting high compressive force thereon. The graphite cores 49 and 50 can -readily be machined out of the bore of the article.

which can then be given a nal internal finishing as by grinding.

The sleeves 16 and 30 are compression transmitting sleeves whereas the sleeves 25 and 46 themselves generate the compression. Accordingly whereas the sleeves 25 and'46 should be fairly thick it is desirable that the sleeves 16 and 30 be thin otherwise the complete article may be somewhat weakened. Since the sleeves-16 and 30 are thin the molten metal which is to form them will prematurely freeze unless the assembly is at orA above.

the melting point of the metal being poured. This is why in the embodiments of Figures l and 3 the assembly should be heated to above themelting point of the metal. to be` poured so vthat at the actual time of pouring the ceramic cylinders .and 31 and the outsidemetal parts 15, 29 and 32v will be at least as hot as'the melting point of the metal being poured.

Because the assemblies of Figures l and 3 vare heated to just above the melting point of the metal to be poured and because these assemblies include metal parts it is` desirable to use low melting point metal for the sleeves 16 and 36. On the other hand strong metal should be used for the sleeves 25 and 46 and for many practical purposes steel and iron are preferred but bronze and brass and in some cases aluminum can be used. For rocket nozzles I may prefer to use titanium metal which has a melting point of 1800 C. in which case the ceramic piece, which in that case might be a cone or a Venturi shape, should be able to withstand such a v temperature. Molded boron carbide can withstand 1800 C. and lso can sintered alumina made out of 99.5% Bayer alumina as hereinbefore described. I give in the following table a number of examples of metals and alloys, both low melting point and tough metals, which can beused in accordance with this invention, it being understood that many other metals and alloys are also suitable forfuse in the present invention, this-table` giving merelyarepresentative list.

Table 1V ALUMINUM ALLOYS g Melting Formula. Common Name or Point;

Trademark Degrees.

Centigrade 94 A14 Cu .5 Mg .5 Mn Alclad 17 ST 540 90A-1 10 Mg llt/llagnalium-- Egg A130 M agua iu.rn 95 Al 5 Si g Aluminum-Silicon 600 BIZMUTH ALLOY 60 B140 Cd 144 COPPER ALLOYS 59 Cu 1.0 Al 1.0 Fe 0.22 Mn .09 Manganese vBronze 890 S Balance Zn. Y 50 n 50 Zn ASSIM 50-50 Brazing 705 oy. 47 Cu 42 Zn 11 Ni WhiteBrazing Rod 750 IRON ALLOYS 97.15 Fe 2.0 C .85 Si White Cast Iron.. 1, 870 f 1.0-2.75 Si 2.7-3.6 C Balance Fe Gray Iron 1, 200

LEAD ALLOYS .8 P .2 As Lead Shot 327 9g b Battery Plates- 300 Antimonial Lead 260 "Magn i 270 250v Aluminum Solder-. 310 Chemical Lead 327 Plumbers Solder 275 84.7 Pb4 Sn 11.3 S Stereotype Metal 260 MAGNESIUM ALLOYS 92 Mg 8 AL. Dow'metal" A 600 88 Mg 12 Al. Dowmetal B 575 Mg 15 Al.-. Dowmeta1" C 590 SILVER ALLOYS STEEL ALLOYS 0.20 C 19 Cr 9 Ni Balance-Fe Tpe SCFI Cast Stain- 1,450

ess ee 99.80 Fe .20 C Low Carbon Steel 1, 500 .2-.5 C .l5-1.0 Mn .2-.7 Si .05 P Medium Carbon Cast 1,.450

max. .06 S max. Balance Fe. Steel.

TIN ALLOYS` 90 Sn 10 Sb Brittanie. 255 S0 SI1 20 Sb 320 97 Sn 3 Cu Rhine Metal 300 ZINC ALLOYS 96 Zn 4 Al .05 Mg Zamak" 3; 380' Zn 4 Al 1 Cu .05 Mg. Zamak 5. 380 93 Zn 4 A13 Cu .05 Mg. "Za-mak 2 380 17.5 Zn 82.5 Cd High" temp. solder- 275 v I may also make a reinforced ceramic body of revoluand having .airemovable end plate S6 also made oli-'steelVVV n-which is'r a central pouringhole 5'7".l The mold body.

9 55 is a hollow cylinder ground on the inside and having an end Wall 58 and therefore has the shape of a crucible. 'I'he removable end plate 56 is a disc with a central hole.

,Located in holes 59 in the end wall 58 are pins 60 which project into the mold 55 andare tapered at the inside ends. Located in holes 61 in the end plate 56 are pins 62 which project beyond the inside face of the plate and are tapered at the inside ends. The pins 60 and 62 are made of steel and are welded in the holes. Those portions of the holes 59 `and 61 outside of the pins 60 and 62 can be used for Spanner Wrenches to assemble and to disassemble the parts. Preferably I further provide on the cylindrical surfaces of the mold mody 55 and of the end plate 56 additional holes 63 and 64 also for spanner wrenches.

Headed pins 65 extend into the annular end of the mold body 55 and are firmly fixed in position by taper pins 66 extending therethrough. Referring now to Figure 6 there are a number of holes 67 through the end plate 56, the holes 67 being larger in diameter than the heads of the pins 65, being equal in number to the pins 65 and being located radially and circumferentially in the end plate 56 the same as the pins 65 are located in the annular end of the mold body 55. Slots 68 in the end plate 56 extend arcuately from the holes V67 in the same direction of rotation and around the slots 68 and the holes 67 are inclined portions 69 which are at a level well in from the face of the plate 56 adjacent the holes 67 and gradually approach and finally merge with the face of the plate 56 near the ends of the slots 68. The foregoing features constitute multiple bayonet locks for quickly securing and removing the end plate 56 to and from the mold body 55 by the aid of Spanner wrenches.

I further provide a pair of rather larger diameter parallel steel shafts 70 (only one shown) spaced apart at any convenient instance so that the mold body can rest thereon as indicated in Figure 5. These shafts 70 are journalled in suitable bearings, not shown, and at least one but preferably both are rotatably driven by adjustable speed mechanism. If both of the shafts 70 are driven they are geared together to rotate at the same angular velocity and in the same direction. The speed of the shaft or shafts 70 should be variable from very slow, say 60 R. P. M. to a top speed which depends on the size of the mold and is calculated to yield a substantial centrifugal force on the metal being cast. Usually a centrifugal force equivalent to g (g=gravity=32 feet per second per second) will be sufficient though a greater force may be provided. As vz=Gr where G is centrifugal force in feet per second per second and v is linear velocity in feet per second and r is radius in feet it turns out that G=l2 g (in round numbers) where the inside diameter of the mold is one tenth of a foot and the mold is rotating at 600 R. P. M.

For the manufacture of a composite article by centrifugal casting with the apparatus of Figures 5 and 6 I first preheat the mold body 55 to a temperature of about 600 C. and preheat a ceramic cylinder 71 to 1000 C., place the mold body 55 on the shafts 70 which should at that time be stationary, insert the cylinder 71 in the mold body 55, quickly secure the removable end plate 56 to the mold body 55, pour molten cast iron through the central pouring hole 57 until it barely overflows, then start the shafts 70 rotating slow-ly and gradually accelerate the angular velocity thereof to the maximum. The ceramic cylinder 71 lloats in the molten cast iron and the taper pins 60 and 62 urge it towards a central position in the mold. When centrifugal force has built up to a little over 1 g at the locus of the pins 60 and 62 the molten iron 72 assumes the shape of a cylinder and in this molten iron the ceramic cylinder 71 oats, that is to say it will assume a position coaxial with the axis of rotation of the mold because, being lighter than the iron, the centrifugal eld which is similar to a gravitational field, puts it in a position of stable equilibrium in the center of thev rotating mold. The rotation of the mold is continued at an angular velocity which will yield well over l g as a matter of precaution and in order to eliminate air bubbles and reduce oscillations of the melt and gradually the cast iron 72 starts to freeze. The rotation is continued until all of the metal has frozen whereupon the shafts 70 are stopped, the end plate 56 is removed, and the formed composite piece constituting a ceramic lcylinder 71 embeddedin a piece of cast iron in compression against it axially and radially is removed from the mold 55. The foregoing can be accomplished because cast iron has a lower melting point than steel as shown in Table IV.

A discussion of the theory and practice of centrifugal molding of ferrous metals will be found in U. S. Patent No. 2,400,495. The description herein given is to be taken as illustrative.

The steel of those listed in Table IV which I prefer for the embodiments of Figures 2, 4 and 5 is the medium carbon cast steel. The iron which I prefer is white cast iron. The brass which I prefer for these embodiments is, of those listed in Table IV, the white brazing rod alloy. I have only listed one bronze in Table IV but many others could be used for the embodiments of Figures 2, 4 and 5. The low melting point alloys which I prefer for the embodiments of Figures 1 and 3 are the zinc alloys listed but if the articles in use will be heated to high temperatures I prefer the Sil Fos silver alloy and the 50-50 brazing alloy.

In the embodiments of Figures 2 and 4 where the sleeve 25 and metal support 46 are cast in situ, the equation for the interference t is simple, being where i is the diametral interference per unit diameter, b is the linear coefficient of expansion of the cast body such as the sleeve 25 or the metal support 46, c is the linear coefficient of expansion of the ceramic piece 10 or 45 and Td is the temperature difference between room temperature and the melting point of the metal that is cast. Thus some steels have a coefficient of expansion in degrees centigrade of 12 l06 and ceramic pieces of the nature herein described frequently have a coefficient of expansion of about 7 106 and assuming the melting point of the steel is around 1400 C. above room temperature, the equation is This interference can be withstood by many steels and also by ceramic pieces of reasonable thickness. So far as steels are concerned, press fitting practice has produced interference fits much greater than 7 mils per inch, for example as high as 25 mils per inch. In the practicing of my invention I will not have interference ts of greater than 10 mils per inch because of the limitations in the possible values of Td.

Where metal is cast between an outer metal sleeve and an inner ceramic piece as in the embodiments of Figures 1 and 3, the equation is (2) i=(b-c)Td- (2e/D)(fXTd+V/3) where i, b, c, and Td are as above identified, e is the radial thickness of the cast intermediate sleeve 16 or 30, D is the mean diameter of such cast intermediate sleeve, f is the coeicient of linear expansion of such cast intermediate sleeve, and V is the volumetric contraction per unit volume of the metal forming the intermediate sleeve on freezing.

As an example of the application of the above equation let us assume an assembly which is one and one-half inches in diameter made by casting an intermediate sleeve .050 inch thick of stereotype metal having a melting point of about 260 C. and having a volume contraction on freezing of 2.0% and a coefficient of expansion of 3'0 10iv per degree centigrade and' having an outer- This figure of 0.3 mil per inch is a low interference t which, however, is adequate for some purposes and is about the lowest interference t of practical use in accordance with this invention.

It must be understood that the foregoing calculations assume no plastic flow or deformation or extrusion or the like of the metal being cast. To a certain extent one or more of these phenomena will always occur. Calculations thereon would however be extremely intricate and in some cases practically impossible. It is sufiicient for the practicing of the invention to bear in mind that the interference fit should be as great as possible provided the central ceramic sleeve has a reasonable wall thickness which ordinarily should noty be less than one-tenth of its diameter but preferably in most cases not thinner than one-lifth of its diameter. However it is preferable in most cases not to design a composite article in accordance with this invention to have an interference fit of greater than 7 mils per inch and indeed it is difficult t-o create greater interference lits. It will be noticed from the long equation above that increasing the wall thickness of the intermediate cast metal sleeves decreases the interference lit wherefore in most cases the design will call for very thin intermediate sleeves.

However Equation 2 is for cases where the intermediate sleeve is made of metal of relatively low strength or of little thickness or both and in case the intermediate sleeve envelopes the ends of the ceramic body, in which case it should be of strong metal and of reasonable thickness, Equation l should be used applying ity to the intermediate sleeve. In borderline cases involving an intermediate sleeve having a melting pointabove 500 C., the equation yielding the greater value of iis the one to apply.

In the claims I refer to the parts 15, 16, 25, 29, 30, 46, 47 and 72 generically as kenvelopes and they are said to be mating with and in compressionV against something inside and/ or enveloping it and in axial compression against it. I use the word comminuted in its proper sense to include granular material, that is to say a mass of particles of aluminum oxide, silicon carbide, etc. the individual particles of which are large enough to be visible and also a mass of clay or the like which indeed consists of individual particles but which particles are so small that they cannot be seen by the naked' eye. Since in accordance with the foregoing disclosure the ceramic bodies of revolution can be made by sintering the various oxides, etc. on the one hand and can be made by fusing impalpably fine clay on the other hand, the starting material for the manufacture of ceramic body of revolution is generically described as comminuted material. I have specified generically that the ceramic piece is at a temperature not lower than 300 C. below the melting point of the metal being castbecause if this precaution is observed the ceramic body of revolution will not be fractured. However, as heretofore stated, in certain embodiments of the method of this invention the ceramic body of revolution is, at a temperature at least as high as that of the molten metal being cast. If itis possible to make an article meeting the requirements by casting with metal having a melting point not higher than 750 C., I prefer to use such metal as it simplifies the manufacturing operation.

It will thus be seen that there has been provided by this invention reenforced ceramic bodies of revolution and methods of making the same iny accordance with which the various objects hereinbefore set forth together with many thoroughly practical advantages areV successfully achieved. It willfurthery be seen that the outerportion of the article, whether it is formed by casting metal or whetherit is. apre-formed outer metal' body, need not be cylindrical nor of any particular shape on the outside although it is so in the examples except in the case of the embodimentV of Figure 3'. As various possible embodiments might be made of the mechanical features of the above invention and as the art herein described might be varied in various parts, all withouty departing from the scope of the invention, it is to be understood that all matter hereinbefore set forth orshown in the accompanying drawings is to be interpreted as illustrative and not in a limiting sense.

I claim:

l. A composite article comprising an inner ceramic body of revolution having a compressive strength greater than 100,000'pounds per square-inch and a hardness of at least 7 on Mohss scale, the'major portion of the material of said body beingselected from the group consisting of silicates, other oxides and carbides, a metal envelope mating with and in compression against said inner ceramic body, said metal having a melting point between C. andl800 C., said compressionbeingon a calculated interference iit basis from; .3 mil tol l0 mils per inch, and an outer metalenvelope surrounding and mating with said envelope mating with the inner ceramic body, said outer metal envelope ybeing of metal having a higher melting point than the metalV ofthe envelope mating with the inner ceramic body and said outer metal envelope being in compression against said envelope mating with the inner ceramic body with acompression which on a calculated interference t basis isfrom .3 mil to.10-mils per inch.

2. A composite article according to claim l in which the metal of the envelope matingwith the inner ceramic body has a meltingl point of from 140 C. to 750 C.

3'. A `composite article according to claim l in which the outer metal envelope is made of ferrous metal selected from the group consisting of cast irons andl steels.

4. A composite article according to claim 3 in which the metal of the envelope mating with the inner ceramic body has a melting point yof from 140 C. to 750 C.

5. A composite article comprising' an inner ceramic hollow body of revolution having a rough [irregular] unground external surface and having a compressive strength greater than 100,000 pounds per square inch and a hardness of at least 7 on Mohss scale, the major portion of the material of said body being selected from the group consisting of silicates, other oxides and carbides, and a metal envelope mating with and in compression against said inner ceramic body, said metal having a melting point between 140 C. and 1800 C., said compression being on a calculated interference lit basis from .3 mil to l0 mils per inch, and said metal envelope at least partially enveloping, the ends of the ceramic body and said metal envelope lbeing in axial compression against said ends of said ceramic body with a compression which on a calculated interference lit is from .3 mil to l0 mils per inch.

6. A composite article according to claim 5 in which the metal envelope is made of ferrous metal selected from the group consisting of cast irons and steels.

7. A composite article comprising an inner crystalline ceramic body having a ground internal surface of revolation and having a rough ungroiind external surface and having a compressive strength greater than 100,000 pounds per square inch and a hardness of at least 7 on Mohss scale,` the major portion of the material of said body being selected from the group consisting of silicates, other oxides and carbides, and an outer metal envelope cast into mating Contact with and in compression against said inner ceramic body, said metal having n melting point between 435 C. and 1800 C., said compression being on a calculated interference fit basis from .3 mil to 10 mils per inch.

8. A composite article according to claim 7 in which the outer metal envelope is made of ferrous metal selected Lirom the group consisting of cast irons and steels.

9. A composite article according to claim 8 in which the crystalline ceramic body is made of alumina.

10. A composite article according to claim 7 in which the outer metal envelope is made of copper alloy selected from the group consisting of bronze and brass.

11. A composite article according to claim 10 in which the crystalline ceramic body is made of alumina.

12. A composite article according to claim 7 in which the outer metal envelope is made of metal selected from the group consisting of aluminum and its alloys.

13. A composite article according to claim 12 in which the crystalline ceramic body is made of alumina.

References Cited in the le of this patent or the original patent UNITED STATES PATENTS 939,833 Harlow Nov. 9, 1909 1,181,603 McClean May 2, 1916 1,362,773 Brewster Dec. 21, 1920 1,665,445 Conrad Apr. 10, 1928 14 Arkema et al Feb. 12, Ford Aug. 6, Comstock May 23, Harris Sept. 12, Scharschu Nov. 27, De Bats Mar. 2, Lillienfeld Sept. 24, Keller et al Oct. 15, Maris Mar. 7, Andre Mar. 7, Osenberg Sept. 9, Cottrell Apr. 9, Fairbank Dec. 2, Corbin Aug. 10, Wilcox Feb. 22, Bird May 31, Leckie Sept. 27, Fairbank Mar. 14, Watkins Jan. 9, Goetzel et al. Jan. 1, Grolee Apr. 22, Goetzel et al. Sept. 30, Mulligan et al. June 2,

FOREIGN PATENTS Great Britain Nov. 3,

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