USRE23093E - Refrigeration - Google Patents

Refrigeration Download PDF

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USRE23093E
USRE23093E US23093DE USRE23093E US RE23093 E USRE23093 E US RE23093E US 23093D E US23093D E US 23093DE US RE23093 E USRE23093 E US RE23093E
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liquid
absorber
conduit
tube
gases
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
    • F25B43/00Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
    • F25B43/04Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat for withdrawing non-condensible gases
    • F25B43/046Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat for withdrawing non-condensible gases for sorption type systems

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  • This invention relates to refrigeration, and more particularly to refrigeration systems of the absorption type.
  • the auxiliary absorber is relatively small compared to the part of the system from which the non-condensible gases are withdrawn in order that such gases may be localized in a small space.
  • the absorption liquid By bringing the withdrawn non-condensible gases into intimate contact with absorption liquid, refrigerant vapor accompanying the gases withdrawn from the main absorber is absorbed into solution, whereby the non-condensible gases are deprived of as much refrigerant vapor as possible.
  • the absorption liquid after being utilized to absorb refrigerant Vapor from the noncondensible gases, is employed to transfer the gases to a part of the system from which the gases may be exhausted to the atmosphere from time to time by a suitable vacuum pump.
  • Fig. 1 more or less diagrammatically illustrates a refrigeration system embodying the invention
  • FIGS. 2 and 3 are enlarged fragmentary views of parts shown in Fig. 1 to illustrate the invention more clearly;
  • FIGs. 4 and 5 are fragmentary views similar to Fig. 2 illustrating modifications of the invention.
  • the invention isl embodied in a two-pressure absorption refrigeration system like that described in United States Letters Patent No. 2,282,503 of A. R. Thomas and P. P. Anderson, Jr., granted May 12, 1942.
  • a system of this type operates at low pressures and includes a generator or vapor expeller I Il, a condenser II, an evaporator I2 and an absorber I4 which are interconnected in such a manner that the pressure differential in the system is maintained by liquid columns.
  • the disclosure in the aforementioned Thomas and Anderson patent may be considered as being incorporated in this application, and, if desired, reference may be made thereto for a detailed description of the refrigeration system.
  • the generator includes an outer shell l5 Within which are disposed a plurality of vertical riser tubes I6 having the lower ends con. nected to receive liquid from a space II and the upper ends extending into and above the bottom of a vessel I8.
  • the space I9 within shell I5 forms a chamber to which steam is supplied through a conduit 20 from a suitable source of supply, so that full length heating of the tubes I6 is effected.
  • a vent 2I is provided at the upper end of shell I9, and a conduit 22 is connected to the bottom part of the shell for draining condensate from the space I9.
  • the system operates at a partial vacuum and contains a Water solution of refrigerant in absorbent liquid such as, for example, a water solution of lithium chloride or lithium bromide.
  • absorbent liquid such as, for example, a water solution of lithium chloride or lithium bromide.
  • the water vapor discharged from the upper ends of the tubes or risers I6 separates from the raised absorption liquid in the vessel I8 and ows through a conduit 23 into condenser II.
  • the condensate formed in condenser Il flows through a U-tube 24 into a chamber 25 and from the latter through a tube 26 into evaporator I2.
  • the evaporator I2 may include a plurality of horizontal banks of tubes 21 disposed one above the other and having heat transfer iins 28 secured thereto to provide a relatively extensive heat transfer surface.
  • the liquid flowing to evaporator I2 is divided in any suitable manner for ilow through the uppermost bank or tubes 21.
  • the dividing of liquid may be effected by a liquid distributing trough 29 into which the liquid flows from the tube 26.
  • the water flows to successively lower tubes through suitable end connections which are open to permit escape of vapor from the tubes. Any excess liquid reirigerant is discharged from the lowermost tubes 21.
  • the water supplied to tubes 21 evaporates therein to produce a refrigerating or cooling eiect with consequent absorption of heat from the surroundings, as from a stream of air flowing over the exterior surfaces of the tubes 21 and fins 28.
  • the vapor formed in tubes 21 passes out into end headers 30 which are connected at their lower ends to absorber I4. Any vapor formed in chamber 25 passes through a conduit 3
  • absorber I4 refrigerant vapor is absorbed into absorption liquid entering through a conduit 32.
  • the entering absorption liquid flows into a vessel 33 in which 'liquid is distributing laterally of a plurality of vertically disposed pipe banks 34 arranged alongside of each other.
  • the liquid flows from vessel 33 through conduits 35 into a plurality of liquid holders and distributors 36 which extend lengthwise of and above the uppermost branches of the pipe banks 34.
  • Absorption liquid is siphoned over the Walls of the liquid holders 36 onto the uppermost pipe sections.
  • the water vapor formed in evaporator I2 passes through the headers 3l) into the absorber I4 where it is absorbed by absorption liquid.
  • Absorption liquid flows from absorber I4 through a conduit 31, a rst group of passages in liquid heat exchanger 38, conduit 39, vessel 4I), and conduit 4I into the bottomspace I1 of generator III. Water vapor is expelled out of solution in generator ID by heating, and liquid is raised by gas or vapor lift action in riser tubes I6, as explained above.
  • the upper part of vessel 4l is connected by conduit 43 to vessel I8, so that the pressure in f vessel 40 is equalized with the pressure in the upper part of generator ID and condenser II.
  • conduit ⁇ 45 may be connected to condenser II, so that the same cooling medium ⁇ is utilized to effect cooling of both the condenser II and absorber I4. From condenser II the cooling medium flows through a conduit 45 to waste.
  • the system operates at low pressures with the generator III and condenser II operating at one pressure and evaporator I2 and absorber I4 operating at a lower pressure, the pressure differential therebetween being maintained lby 'liquid columns.
  • the liquid column formed in tube 24 maintains the pressure differential between condenser II and evaporator I2.
  • the liquid column in conduit 31 maintains the pressure differential between the outlet of absorber I4 and generator I0, and the liquid column formed in conduit 32 and connected parts including conduit 42 maintains the pressure differential between the inlet of the absorber and the upper part of the generator IU.
  • the liquid columns may form in conduits 31, 42 and downleg of tube 24 to the level m, y and a, for example.
  • the conduits are of such size that restriction to gas flow is effected without appreciably restricting flow of liquid.
  • non-condensible gases may collect in the system, and in condenser II such gases ilow toward the dead-end or bottom part of the condenser.
  • a liquid trap 41 is provided in U-tube 24. Liquid formed in condenser II flows into trap 41, and, when the trap is completely filled with liquid to the level c, the liquid is siphoned from the trap into the downleg of U-tube 24. The gas in the downleg of U-tube 24, in the region between the trap 41 and the liquid level at 2, is trapped by the liquid siphoned from the liquid trap 41.
  • an improved auxiliary absorber 41 is provided for removing refrigerant vapor from non-condensible gases Withdrawn from the main absorber I4, so that positive ilow of non-condensible gases from absorber I4 is effected and at the same time such gases vwill be deprived of as much refrigerant vapor as possible.
  • the auxiliary absorber 41 is considerably smaller than the main absorber I4 in order to localize the non-condensible gases, and includes an outer shell 48 into the upper part of which the gases pass through a conduit 49 from the bottom part of absorber I4.
  • a tube 5U' having top and bottom closure members 5I and 52, respectively, as shown most clearly in Fig. 2.
  • Concentrically arranged within tube 5D and spaced therefrom is a cylindrical screen 53 having the ends thereof fitting over shoulders formed on the closure members 5
  • a liquid d'eilecting plate 54 which vis ixed to an extension of the top closure member 5I, is positioned above a small opening or restriction 55 formed in the top closure member.
  • the top closure member 5I serves as an inlet for absorption liquid which is introduced into the auxiliary absorber through a conduit 56. As shown 4in Fig. 1 the upper end A of conduit 56 is connected to the upper part of conduit 32 through which absorption liquid fiows to the upper part of absorber I4.
  • a cooling coil 51 is disposed about and in thermal contact with tube 5D.
  • the lower end of coil 51 is connected by a conduit 58 to conduit 44, and the upper end thereof is connected by a con duit 59 to conduit 45.
  • a part of the cooling water flowing to the main absorber I4 through conduit 44 is diverted into coil 51 of the auxiliary absorber 41.
  • the cooling water passing from the upper end of coil 51 joins cooling Water in conduit 45 passing from the upper part of the main absorber I4.
  • conduit 64 to the conduit 31 through which absorption liquid flows from the outlet of absorber I4.
  • conduit 56, auxiliary absorber 41, vertical tube 6I, lower end of the tube 63 and conduit 64 constitute a by-pass between the conduits 32 and 31 constituting separate paths of flow for absorption solution between the absorber I4 and generator III.
  • the by-pass will receive absorption liquid from the conduit 32 at the low pressure prevailing in the absorber I4 and will deliver absorption liquid to the conduit 31 at the high pressure prevailing in the generator Il).
  • conduit 63 To the upper end of conduit 63 is connected a vessel 65, as shown in Fig. l.
  • the vertical conduit 63 and vessel 65 constitute the part to which ⁇ non-condensible gases are transferred from absorber I4, as which will be described presently.
  • a vacuum pump 66 may be connected by a conduit 61 to the vessel 65 for withdrawing non-condensible gases from the system.
  • a suitable valve 68 is provided in conduit 61 to maintain the system at a low pressure.
  • non-condensible gases may collect in generator I 0 and condenser Il forming the high pressure side of the system. Such gases are swept by the refrigerant vapor flowing from generator I0 into condenser I I and are carried to the far end of the condenser at the region to which the tube 24 is connected. It is for this reason that trap 41 is provided in the downleg of tube 24 to transfer non-condensible gases from condenser II to evaporator I2, as explained above.
  • the non-condensible gases collecting in the evaporator I2 and absorber I4, which form the low pressure side of the system, are carried to the bottom part of the absorber. This downward movement is imparted to the non-condenslble gases by the high velocity refrigerant vapor flowing into the absorber.
  • the average velocity of the refrigerant vapor escaping from the evaporator I2 to absorber I4 under ordinary operating conditions is about
  • the high velocity refrigerant vapor forces the non-condensible gases to the bottom of the absorber midway between the headers 30.
  • the auxiliary absorber 41 is utilized to establish positive iiow of the gases withdrawn from absorber I4 and also remove as much refrigerant vapor as possible from the withdrawn gases.
  • the absorption liquid diverted from conduit 32 into conduit 56 flows by gravity to the auxiliary absorber into the cylindrical screen 53 therein. Liquid passes through screen 53 into the annular space between the screen and the tube 50, and is discharged through the orifice or opening 55.
  • the screen 53 removes foreign matter from the absorption liquid flowing into auxiliary absorber 41 to prevent clogging of the perennial 55, and the perennial 55 restricts iiow of liquid therethrough to limit the rate at which liquid is diverted from conduit 32 into the auxiliary absorber 41.
  • the tube 6I may be referred to as a fall tube pump and is of such size that iiow of liquid is not appreciably restricted, and yet the internal diameter is such that gas and liquid cannot pass each other while flowing downwardly through the tube.
  • a fall tube pump having an internal diameter of about 0.180 has operated in a satisfactory manner to trap small quantities of gas between slugs of liquid.
  • conduit 63 and vessel 65 As the quantity of non-condensible gases transferred to conduit 63 and vessel 65 increases, the liquid level in conduit 63 falls due to the gases displacing liquid therefrom. The liquid displaced from conduit 63 passes through conduit 64 into conduit ⁇ 31.
  • the vacuum pump 66 may be used as desired to exhaust non-condensible gases from conduit 63 and vessel 65 into the atmosphere.
  • the non-condensible gases cannot accumulate in other parts of the system such as the condenser I I and absorber I4, for example, and occupy the blanket ofi space in these parts that otherwise would be occupied by refrigerant vapor. Further, objectionable increase of pressure in the condenser and absorber that would result with accumulation of non-condensible gases in these parts is avoided by con stantly removing and transferring the gases to a part of the system like that formed by conduit 63 and vessel 65.
  • the non-condensible gases in the system By transferring the non-condensible gases in the system to vertical conduit 63 and vessel 65, such gases are removed from all parts of the system actively participating in the production of refrigeration and collected in a single place which might be referred to as an inactive part.
  • the non-condensible gases accumulating in the inactive part formed by conduit 63 and vessel G5 can reach a pressure considerably greater than that existing in the active parts in both the high and lower pressure sides of the system.
  • the pressures in the high and lower pressure sides of the system are about 56 and 9 mm. Hg, respectively. Under these conditions the pressure in vessel 4U above the liquid level e therein is- 56 mm. Hg, the pressure existing in the high pressure side of the system.
  • the .maximum pressure that can prevail in vessel 65 and conduit B3 is reached when the liquid falls to the minimum level s in conduit 63.
  • This maximum pressure in conduit 63 in the System referred to above is about 100 mm. Hg, and this pressure is balanced on the high pressure side of the system by the pressure above the liquid level e in vessel 40 and the liquid column extending downwardly from vessel 4i) through conduit 39 and one group of passages in liquid heat exchanger 38 to which the lower end of vertical conduit 53 is connected.
  • the pressure in the high pressure side oi the system is about 56 mm.
  • the non-condensible gases can be trapped in conduit '63 and vessel B5 to a max-- imum pressure of about 100 mm. Hg, and at the same time the trapped gases do not adversely affect the normal operation of nor impair the eiiiciency of the refrigeration system.
  • cooling water diverted from conduit 44 through conduit 58 is introduced into vthe lower end of a hollow cylinder or tube 50a extending upwardly within shell 48a.
  • the cooling water passes from the upper curved end oi tube 50a into the upper end of acoil 51a disposed about and in thermal .contact with the tube.
  • the lower end of coil 51a is connected by conduit 59 to conduit 45 in the same manner as in the first embodiment described above and shown in Fig. 1.
  • Fig. -5 differs from that illustrated in Fig. 4 in that a solid helical member 51o is disposed about and in thermal contact with tube Elib, and the cooling water .cirf culates entirely within the tube.
  • the cooling Water diverted from conduit rMI through conduit 58 enters a conduit 1I which is more or less a continuation of conduit 58 and extends upwardly within the tube 50h.
  • the cooling water is discharged from the upper end of conduit 'II ad jacent the closed upper end of tube v501i and ilows down over the exterior surface of conduit 1I and through the tube 5B1).
  • the cooling water passes from the lower end of tube 50h into conduit 59,.
  • Fig. 5 the non-condensible gases enter the auxiliary absorber Hb through conduit 49 and come in Contact with absorption liquid entering through conduit 56.
  • the absorption liquid strikes the upper vclosed end of tube 50h and flows downwardly ⁇ along the helical member A51h to provide a relatively extensive liquid surface.
  • Refrigerant vapor accompanying the non-condensible gases is absorbed into absorption liquid, and the resulting heat of absorption is transferred to cooling water flowing downwardly within tube 50h.
  • auxiliary absorber like the absorbers 41, 41a and .41h described above, refrigerant vapor is eiectively removed from the noncondensible gases, so that substantially .no refrigerant vapor accompanies the non-condenslble gases trapped in the upper end 'of fall tube pump 6I.
  • substantially no refrigerant vapor entering the iall tube pump 6I practically no absorption of refrigerant into absorbent takes place in the fall tube pump to produce .objectionable noises and undesirable slowing down -of the rate at which gas is transferred from absorber I4 to vertical conduit 63.
  • the auxiliary ⁇ absorbers serve to effect withdrawal of non-condensible gases at a maximum .rate into the fall .tube pump 6I.
  • the absorption liquid diverted into the auxiliary absorbers 41, 41a and Mb is weak in refrigerant while the absorbent in the bottom of the main absorber I4 is rich in refrigerant, the vapor pressure of refrigerant in the auxiliary absorbers is less than that at .the bottom of the main absorber. This slight pressure differential promotes positive ow of non-l condensible gases from the main absorber I4 through conduit 49 to the auxiliary absorber.
  • the helical member of the auxiliary absorber over which the absorption liquid. flows, fits snugly against a cylindrical part.
  • liquid disturbances are created as liquid descends from one turn onto a part of the cylindrical wall and from the latter onto the next successively lower turn. In this way fresh liquid surfaces are constantly provided to improve absorption of Vrefrigerant vapor into absorbent.
  • the auxiliary absorber 41 is especially effective in that a relatively extensive liquid film is formed on coil 51 with which the gases come in contact.
  • the heat of absorption resulting from absorption of refrigerant vapor into solution is transferred from the liquid film directly through the coil 51 to the cooling water flowing therein.
  • absorption liquid flowing over the exterior surface of tube 50 increases the effective gas and liquid contact surface.
  • the heat of absorption resulting from absorption of refrigerant vapor into solution at-the outside surface of tube 50 is also transferred to cooling water within the coil 51.
  • the coil throughout its length is in heat exchange relation with tube 50. so that effective precooling of absorption liquid within tube 50 is effected before such liquid is discharged through the orifice 55 and flows over the exterior surface of the coil 51.
  • the auxiliary absorbers 41a and 41h likewise are effective in producing a positive flow of noncondensible gases throu'rh conduit 49.
  • the cooling water in the embodiments illustrated in Figs. 4 and 5 flows in heat exchange relation with absorption liquid along substantially the entire length of the path of fiow of the absorbent.
  • the heat of absorption resulting from absorption of refrigerant vapor at the surfaces of coil 51a and exterior surface of tube 50a is immediately taken up by cooling water flowing within the tube 50a and also through the coil 51a.
  • the coil 57a isarranged in thermal contact with tube 59a in such a manner that the bottom end of the coil is in heat exchange relation with the end of the tube 50a which is the coolest and into which the cooling liquid is introduced through conduit 58.
  • auxiliary absorber 41h illustrated in Fig. 5 the heat of absorption resulting from absorption of refrigerant vapor at the liquid film formed on helical coil 51h and at the exterior surface of tube 501:, is immediately taken up by cooling liquid flowing downwardly through tube 50h.
  • the cooling water leaving the tube through conduit 49 is in heat exchange relation with liquid entering conduit 1
  • the auxiliary absorbers 41a. and 41h are maintained at as low a temperature as possible. In this way refrigerant vapor is effectively absorbed into solution and the non-condensible gases removed from the auxiliary absorbers 41a and 41h will be deprived of as much refrigerant vapor as possible.
  • a refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is disposed an upright annular member, a helical member fitting snugly about said annular member in direct contact therewith and extending lengthwise thereof, and means to flow absorption liquid onto' an upper partof said helical member, said annular member and helical member forming a path of flow for absorption liquid in which liquid descends from one turn of said helical member onto a part of said annular kwall and from the latter onto the next successively lower turn of said helical member, so that fresh liquid surfaces are constantly being provided with which non-condensible gases from said first ab-' sorber come in contact for removing refrigerant vapor accompanying such gases.
  • a refrigeration system operable below atrn'oseV pheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber come prising a casing providing a chamber within which is disposed a vertically extending wall member, means bearing against said wall member and forming a plurality of horizontally disposed barriers at different levels, means to flow absorption liquid onto one of said barriers at the upper part of said wall member, said wall member and barriers forming a relatively extensive gas and liquid contact surface with-absorption liquid passing from one barrier onto a part of said wall member and from the latter onto the next successively lower barrier, so that fresh liquid surfaces are constantly being provided with which non-condensible gases from said first absorber come in Contact for removing refrigerant vapor accompanying such gases.
  • a refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is located a vertically disposed hollow cylindrical member, a helical coil disposed about and extending lengthwise of'said cylindrical member, means for introducing a cooling medium to the lower part of said cylindrical member, the upper end of said coil being connected to the upper part of said cylindrical member so that cooling medium ows downwardly through said coili and means to flow absorption liquid onto an upper part of said coil, said coll and cylindrical member forming a path of flow for absorption liquid in which liquid descends from one turn of said coil onto a part of said cylindrical member and from the latter onto the next successively lower Iturn of said coil, so that fresh liquid surf-aces are constantly being provided with which 'non-condenslble gases from said first absorber come
  • a refrigeration system operable below atmospheric pressure and comprising a plurality 'of parts including a first absorber interconnected for circulation of absorption liquid and refrigeiant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is disposed an upright hollow cylindrical member, a helical element snugly tting about and extending lengthwise of said member, means for circulating cooling medium within said cylindrical member, and means to flow absorption liquid onto an upper part of said element, said helical element and cylindrical member forming a path of flow for absorption liquid in which liquid descends from one turn of said element onto a part of said cylindrical member and from the latter onto the next successively lower turn of said element.
  • a refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for Icirculation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is located a vertically disposed hollow cylindrical member, a tube extending upwardly within said member and terminating in the upper part thereof, means for supplying cooling mea dium to 'said tube, said cylindrical member having an outlet for the cooling medium in the lower part thereof, a helical element snugly fitting about and extending lengthwise of said member, and means to flow absorption liquid onto an ⁇ upper Ipart of said element, said element and cylindrical member forming a path of flow for absorption liquid in which liquid descends from one turn of said element onto a part rof said cylindrical member land from the latter onto the next successively lower turn of said element.
  • a refrigeration system operable below atmospheric pressure and having a plurality of active parts, said active parts being interconnected for circulation of absorption liquid and refrigerant, and means including an absorber for withdrawing non-condensible gas from one of said active parts, 'said absorber having a vertically disposed cylindrical wall, a vertically extending pipe coil directly contacting a surface of said wall, said absorber being connected to receive non-condensible gas from said one active part, and means for flowing absorption liquid onto an upper part of said coil, said cylindrical 'wall and coil forming a path of flow for absorption liquid in which liquid descends from one turn of said coil onto a part of said surface and from the latter onto the next successively lower turn of said coil.
  • a refrigeration system operable below atmospheric pressure and comprising a plurality of active parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, a vertically extending tube embodied in the system and through which absorption liquid flows, the upper end of Said tube being in communication with said first absorber, and means including said tube for withdrawing noncondensible gas from said rst absorber, said means including an auxiliary absorber for localizing the non-oonde'nsible gas flowing from said first absorber and for removing therefrom accompanying refrigerant Vapor, said auxiliary absorber including a vertically dis-posed cylindrical wall and a pipe coil directly contacting a surface of s-uch wall, and means for flowing absorption liquid onto an upper part of said coil, the refrigerant vapor accompanying the non-condensible gas from said first absorber being absorbed into absorption liquid in said auxiliary absorber whereby gas substantially free of refrigerant is en- 13 trained by absorption liquid at the -upper end oi
  • an absorption refrigeration system comprising a plurality of elements including an absorber interconnected to provide a closed circuit for the circulation of a refrigerant and absorption liquid, an auxiliary absorber connected to the absorber for receiving non-condensible gases therefrom, conduit means for flowing absorption liquid weak in refrigerant through the auxiliary absorbery said auxiliary absorber utilizing the absorption liquid to absorb refrigerant vapor and create a relative partial vacuum lwhereby to cause flow of the gases from the absorber to the auxiliary absorber, means for supplying a cooling medium to the auxiliary absorber to remove the heat of absorption, and means utilizing the flow of absorption solution for withdrawing non-condensible gases from the auxiliary absorber.
  • an absorption refrigeration system comprising a generator and condenser operable at one pressure and an evaporator and absorber operable at a lower pressure, means interconnecting the elements to provide a closed circuit for the circulation of a refrigerant and absorption liquid and maintain the pressure differential, an auxiliary absorber connected to the low pressure side of the system to receive non-condensible gases therefrom, conduit means for flowing absorption liquid weak in refrigerant through the auxiliary absorber, said auxiliary absorber utilizing the absorption liquid to absorb refrigerant vapor to cause a flow of the gases thereto, means for supplying a cooling medium to the auxiliary absorber to remove the heat of absorption, and means utilizing the flow of absorption solution for withdrawing non-condensible gases from the auxiliary absorber.
  • an absorption refrigeration system comprising a generator and condenser operable at one pressure and an evaporator and absorber operable at a lower pressure, means interconnecting the elements to provide a closed circuit for the circulation of a refrigerant and absorption solution and maintain the pressure diiferential, said last named means providing separate paths of flow between the generator and absorber for absorption liquid Weak in refrigerant and absorption liquid strong in refrigerant, a by-pass connected -between the separate paths of flow to cause absorption liquid weak in refrigerant to ow therethrough, an auxiliary absorber in the bypass and connected to the low presure side of the system to receive non-condensible gases therefrom, said auxiliary absorber utilizing the absorption liquid owing therethrough for absorbing refrigerant vapor to cause a flow of gases thereto, means for supplying a cooling medium to the auxiliary absorber to remove the heat of absorption, and a fall tube pump in the by-pass for withdrawing the non-condensible gases from the auxiliary

Description

C. A. ROSWELL March 22,1949,
REFRIGERATION 1 t e e h S S t e e n.. s 2 3 4 9 l 2 l .n
m, j. d f e INVEN OR ATTORNEY l Re. 23,093
2 Sheets-Sheet 2 MATTORNEY REFRIGERAT I ON C. A. ROSWELL March 22, 1949.
Original Filed April- 2, 1943 Reissued Mar. 22, 1949 23,093 REFRIGERATION Charles Alfred Roswell, Relay, Md., assignor to Servel, Inc., New York, N. Y., a corporation of Delaware Original No. 2,384,861, dated September 18, 1945, Serial No. 481,519, April 2, 1943. Application for reissue December 1, 1948, Serial No. 62,841
(Cl. (i2-119) 12 claims. 1
This invention relates to refrigeration, and more particularly to refrigeration systems of the absorption type.
It is an object of the invention to provide an improvement in refrigeration systems for transferring and removing non-condensible gases from one part, such as an absorber, for example, to another part of the system. More specically, it is an object to provide an improved auxiliary absorber for establishing positive flow oi non-condensible gases from an active part, such as the main absorber, for example, and to divert into such auxiliary absorber a part of the absorption liquid flowing to the main absorber. The auxiliary absorber is relatively small compared to the part of the system from which the non-condensible gases are withdrawn in order that such gases may be localized in a small space.
By bringing the withdrawn non-condensible gases into intimate contact with absorption liquid, refrigerant vapor accompanying the gases withdrawn from the main absorber is absorbed into solution, whereby the non-condensible gases are deprived of as much refrigerant vapor as possible. The absorption liquid, after being utilized to absorb refrigerant Vapor from the noncondensible gases, is employed to transfer the gases to a part of the system from which the gases may be exhausted to the atmosphere from time to time by a suitable vacuum pump.
The invention, together with the above and other objects and advantages thereof, will be better understood from the following description taken in connection with the accompanying drawings forming a part of this speciiication, and of which:
Fig. 1 more or less diagrammatically illustrates a refrigeration system embodying the invention;
Figs. 2 and 3 are enlarged fragmentary views of parts shown in Fig. 1 to illustrate the invention more clearly; and
Figs. 4 and 5 are fragmentary views similar to Fig. 2 illustrating modifications of the invention.
Referring to Fig. 1, the invention isl embodied in a two-pressure absorption refrigeration system like that described in United States Letters Patent No. 2,282,503 of A. R. Thomas and P. P. Anderson, Jr., granted May 12, 1942. A system of this type operates at low pressures and includes a generator or vapor expeller I Il, a condenser II, an evaporator I2 and an absorber I4 which are interconnected in such a manner that the pressure differential in the system is maintained by liquid columns. The disclosure in the aforementioned Thomas and Anderson patent may be considered as being incorporated in this application, and, if desired, reference may be made thereto for a detailed description of the refrigeration system.
In Fig. l the generator includes an outer shell l5 Within which are disposed a plurality of vertical riser tubes I6 having the lower ends con. nected to receive liquid from a space II and the upper ends extending into and above the bottom of a vessel I8. The space I9 within shell I5 forms a chamber to which steam is supplied through a conduit 20 from a suitable source of supply, so that full length heating of the tubes I6 is effected. A vent 2I is provided at the upper end of shell I9, and a conduit 22 is connected to the bottom part of the shell for draining condensate from the space I9. l
The system operates at a partial vacuum and contains a Water solution of refrigerant in absorbent liquid such as, for example, a water solution of lithium chloride or lithium bromide. When steam is supplied through conduit 2D to space I9 at atmospheric pressure, heat is supplied to tubes I6 for expelling water vapor from solution. The absorption liquid is raised by gas or vapor lift action, the expelled Water vapor forming a central core within an upwardly rising annulus of 'the liquid. In vapor-liquid lifts of this character the expelled water vapor rises more rapidly than the liquid. and the liquid follows the vapor along the inside walls of the tubes I6.
The water vapor discharged from the upper ends of the tubes or risers I6 separates from the raised absorption liquid in the vessel I8 and ows through a conduit 23 into condenser II. The condensate formed in condenser Il flows through a U-tube 24 into a chamber 25 and from the latter through a tube 26 into evaporator I2.
The evaporator I2 may include a plurality of horizontal banks of tubes 21 disposed one above the other and having heat transfer iins 28 secured thereto to provide a relatively extensive heat transfer surface. The liquid flowing to evaporator I2 is divided in any suitable manner for ilow through the uppermost bank or tubes 21. For example, the dividing of liquid may be effected by a liquid distributing trough 29 into which the liquid flows from the tube 26. The water flows to successively lower tubes through suitable end connections which are open to permit escape of vapor from the tubes. Any excess liquid reirigerant is discharged from the lowermost tubes 21.
The water supplied to tubes 21 evaporates therein to produce a refrigerating or cooling eiect with consequent absorption of heat from the surroundings, as from a stream of air flowing over the exterior surfaces of the tubes 21 and fins 28. The vapor formed in tubes 21 passes out into end headers 30 which are connected at their lower ends to absorber I4. Any vapor formed in chamber 25 passes through a conduit 3| into one of the headers 30 and mixes with vapor formed in the evaporator I2, so that disturbances in the evaporator due to vapor flashing of incoming liquid are avoided.
In absorber I4 refrigerant vapor is absorbed into absorption liquid entering through a conduit 32. The entering absorption liquid flows into a vessel 33 in which 'liquid is distributing laterally of a plurality of vertically disposed pipe banks 34 arranged alongside of each other. The liquid flows from vessel 33 through conduits 35 into a plurality of liquid holders and distributors 36 which extend lengthwise of and above the uppermost branches of the pipe banks 34. Absorption liquid is siphoned over the Walls of the liquid holders 36 onto the uppermost pipe sections.
Liquid drips from each horizontal pipe section onto the next lower pipe section, so that all of the pipe sections are wetted with a film of liquid.
The water vapor formed in evaporator I2 passes through the headers 3l) into the absorber I4 where it is absorbed by absorption liquid. Absorption liquid flows from absorber I4 through a conduit 31, a rst group of passages in liquid heat exchanger 38, conduit 39, vessel 4I), and conduit 4I into the bottomspace I1 of generator III. Water vapor is expelled out of solution in generator ID by heating, and liquid is raised by gas or vapor lift action in riser tubes I6, as explained above.
The absorption liquid in vessel I8, from which refrigerant has been expelled from solution, Hows through a conduit 42, another group of passages in liquid heat exchanger 38 and conduit 32 into the upper part of absorber I4. This circulation of absorption liquid is effected by raising liquid in the vertical riser tubes I6 by vapor lift action, so that liquid can flow from generator I to absorber I4 and return from the latter back to the generator by force of gravity.
The upper part of vessel 4l) is connected by conduit 43 to vessel I8, so that the pressure in f vessel 40 is equalized with the pressure in the upper part of generator ID and condenser II.
upper end of the pipe banks through a conduit` 45. AThe conduit 45 may be connected to condenser II, so that the same cooling medium `is utilized to effect cooling of both the condenser II and absorber I4. From condenser II the cooling medium flows through a conduit 45 to waste.
The system operates at low pressures with the generator III and condenser II operating at one pressure and evaporator I2 and absorber I4 operating at a lower pressure, the pressure differential therebetween being maintained lby 'liquid columns. Thus, the liquid column formed in tube 24 maintains the pressure differential between condenser II and evaporator I2. The liquid column in conduit 31 maintains the pressure differential between the outlet of absorber I4 and generator I0, and the liquid column formed in conduit 32 and connected parts including conduit 42 maintains the pressure differential between the inlet of the absorber and the upper part of the generator IU. In operation, the liquid columns may form in conduits 31, 42 and downleg of tube 24 to the level m, y and a, for example. The conduits are of such size that restriction to gas flow is effected without appreciably restricting flow of liquid.
During operation of the refrigeration system non-condensible gases may collect in the system, and in condenser II such gases ilow toward the dead-end or bottom part of the condenser. To transfer and remove non-condensible gases from condenser II to the lower pressure side of the system, a liquid trap 41 is provided in U-tube 24. Liquid formed in condenser II flows into trap 41, and, when the trap is completely filled with liquid to the level c, the liquid is siphoned from the trap into the downleg of U-tube 24. The gas in the downleg of U-tube 24, in the region between the trap 41 and the liquid level at 2, is trapped by the liquid siphoned from the liquid trap 41. Immediately after liquid has siphoned from the liquid trap 41, gas passses from the bottom part of condenserd II through the trap 41 into the downleg of U-tube 24. When liquid passing from .condenser II again reaches the level c in the trap 41, liquid is again siphoned into the downleg of the tube 24. In this manner gas' passing from condenser II into the downleg of the tube 24, before the liquid seal is formed in trap 41, is 'segregated by the liquid subsequently siphoned into the downleg of the tube.
The gas segregated between the successive bodies of liquid siphoned from trap 41 is compressed by the siphoned liquid and passes through the U-tube 24 from condenser II to evaporator I2. In this way non-condensible gases collecting in the upper part of generator I'U and condenser II' are transferred from these parts of the system to the evaporator I2 and absorber I4.
In accordance with this invention an improved auxiliary absorber 41 is provided for removing refrigerant vapor from non-condensible gases Withdrawn from the main absorber I4, so that positive ilow of non-condensible gases from absorber I4 is effected and at the same time such gases vwill be deprived of as much refrigerant vapor as possible. The auxiliary absorber 41 is considerably smaller than the main absorber I4 in order to localize the non-condensible gases, and includes an outer shell 48 into the upper part of which the gases pass through a conduit 49 from the bottom part of absorber I4.
Within the shell 48 is disposed a tube 5U' having top and bottom closure members 5I and 52, respectively, as shown most clearly in Fig. 2. Concentrically arranged within tube 5D and spaced therefrom is a cylindrical screen 53 having the ends thereof fitting over shoulders formed on the closure members 5| and 52. A liquid d'eilecting plate 54, which vis ixed to an extension of the top closure member 5I, is positioned above a small opening or restriction 55 formed in the top closure member. The top closure member 5I serves as an inlet for absorption liquid which is introduced into the auxiliary absorber through a conduit 56. As shown 4in Fig. 1 the upper end A of conduit 56 is connected to the upper part of conduit 32 through which absorption liquid fiows to the upper part of absorber I4.
A cooling coil 51 is disposed about and in thermal contact with tube 5D. The lower end of coil 51 is connected by a conduit 58 to conduit 44, and the upper end thereof is connected by a con duit 59 to conduit 45. With this arrangement a part of the cooling water flowing to the main absorber I4 through conduit 44 is diverted into coil 51 of the auxiliary absorber 41. The cooling water passing from the upper end of coil 51 joins cooling Water in conduit 45 passing from the upper part of the main absorber I4.
To the bottom part of shell 46 is connected the upper curved or rounded portion 60 of a vertically extending tube 6I. The lower end of tube 6I is connected at 62 to the bottom part of a vertical conduit 63. The bottom part of conduit 63 in turn is connected by a short conduit 64 to the conduit 31 through which absorption liquid flows from the outlet of absorber I4. It will be observed from the foregoing description that the conduit 56, auxiliary absorber 41, vertical tube 6I, lower end of the tube 63 and conduit 64 constitute a by-pass between the conduits 32 and 31 constituting separate paths of flow for absorption solution between the absorber I4 and generator III. It also will be observed that the by-pass will receive absorption liquid from the conduit 32 at the low pressure prevailing in the absorber I4 and will deliver absorption liquid to the conduit 31 at the high pressure prevailing in the generator Il).
To the upper end of conduit 63 is connected a vessel 65, as shown in Fig. l. The vertical conduit 63 and vessel 65 constitute the part to which `non-condensible gases are transferred from absorber I4, as which will be described presently. A vacuum pump 66 may be connected by a conduit 61 to the vessel 65 for withdrawing non-condensible gases from the system. A suitable valve 68 is provided in conduit 61 to maintain the system at a low pressure.
During operation of the refrigeration system, non-condensible gases may collect in generator I 0 and condenser Il forming the high pressure side of the system. Such gases are swept by the refrigerant vapor flowing from generator I0 into condenser I I and are carried to the far end of the condenser at the region to which the tube 24 is connected. It is for this reason that trap 41 is provided in the downleg of tube 24 to transfer non-condensible gases from condenser II to evaporator I2, as explained above.
The non-condensible gases collecting in the evaporator I2 and absorber I4, which form the low pressure side of the system, are carried to the bottom part of the absorber. This downward movement is imparted to the non-condenslble gases by the high velocity refrigerant vapor flowing into the absorber. In a refrigeration system like that described and having an ice melting capacity of ve tons, for example, the average velocity of the refrigerant vapor escaping from the evaporator I2 to absorber I4 under ordinary operating conditions is about |30 feet per second. Thus, the high velocity refrigerant vapor forces the non-condensible gases to the bottom of the absorber midway between the headers 30.
In removingand transferring non-condensible gases from absorber I4 to vertical conduit 63 and vessel 65 associated therewith, the auxiliary absorber 41 is utilized to establish positive iiow of the gases withdrawn from absorber I4 and also remove as much refrigerant vapor as possible from the withdrawn gases. The absorption liquid diverted from conduit 32 into conduit 56 flows by gravity to the auxiliary absorber into the cylindrical screen 53 therein. Liquid passes through screen 53 into the annular space between the screen and the tube 50, and is discharged through the orifice or opening 55. The screen 53 removes foreign matter from the absorption liquid flowing into auxiliary absorber 41 to prevent clogging of the orice 55, and the orice 55 restricts iiow of liquid therethrough to limit the rate at which liquid is diverted from conduit 32 into the auxiliary absorber 41.
Under the small pressure head of liquid in conduit 56, absorption liquid spouts upwardly from orifice 55 and strikes the deiiecting plate 54. This causes the liquid to flow downwardly over the top closure member 5I onto the surface of the uppermost turn of coil 51. Both the edges of the deilecting plate 54 and top closure member 5I are more or less in vertical alignment with the uppermost turn of coil 51, so that liquid will readily drip from the plate 54 and closure member 5I onto the coil 51. The liquid flows over the exterior surface of coil 51 and forms a liquid film thereon to provide a relatively extensive liquid surface.
The non-condensible gases passing from the bottom of main absorber I4 through conduit 49 into the auxiliary absorber 41 come in intimate contact with the film of absorption liquid on the coil 51. Refrigerant vapor accompanying the non-condensible gases is absorbed into absorption liquid, and the heat liberated with such absorption or refrigerant vapor is transferred to the cooling water flowing through coil 51.
'I'he absorption liquid in the bottom part of the auxiliary absorber 41 enters the upper rounded or bent portion 6D of vertical tube 6I until the portion 66 is completely filled with liquid and sealed from the gases in the bottom part of the auxiliary absorber. When the liquid level rises suiciently in the bent portion 5U of the tube 6I, the small quantity of liquid therein is siphoned into the downwardly depending straight portion of the tube. When liquid siphons from the bent portion 60 of tube 6I, the liquid level falls in the bottom part of the auxiliary absorber 41 sufoiently so that non-condensible gases can pass into the bent portion 6D. When the liquid level in the bottom part of the absorber 41 again rises suiciently, the upper bent portion 60 is closed off and a small quantity of liquid is again siphoned into the tube 6I. In this way small quantities of non-condensible gases are withdrawn from the bottom part of the auxiliary absorber 41 and trapped between successive bodies or slugs of liquid formed at the upper bent portion 60 of the tube 6 I.
The tube 6I may be referred to as a fall tube pump and is of such size that iiow of liquid is not appreciably restricted, and yet the internal diameter is such that gas and liquid cannot pass each other while flowing downwardly through the tube. When a solution of lithium bromide of about 55% concentration by weight is employed in a system of the type described, a fall tube pump having an internal diameter of about 0.180 has operated in a satisfactory manner to trap small quantities of gas between slugs of liquid.
The gas trapped betweenslugs of liquid in tube 6I is compressed as the liquid and gas pass downwardly in the tube. From the lower end of capas 7 tube 6I the trapped gas is discharged into the bottom of conduit 63 which is of considerably greater size than tube 6I, so that the gas bubbles will freely pass upwardly through liquid therein. as diagrammatically shown in Fig. 3.
As the quantity of non-condensible gases transferred to conduit 63 and vessel 65 increases, the liquid level in conduit 63 falls due to the gases displacing liquid therefrom. The liquid displaced from conduit 63 passes through conduit 64 into conduit `31. The vacuum pump 66 may be used as desired to exhaust non-condensible gases from conduit 63 and vessel 65 into the atmosphere.
By transferring the non-condensible gases in the system into the conduit 63 and vessel 65, several advantages result. First, the non-conden sible gases cannot accumulate in other parts of the system such as the condenser I I and absorber I4, for example, and occupy the blanket ofi space in these parts that otherwise would be occupied by refrigerant vapor. Further, objectionable increase of pressure in the condenser and absorber that would result with accumulation of non-condensible gases in these parts is avoided by con stantly removing and transferring the gases to a part of the system like that formed by conduit 63 and vessel 65.
By transferring the non-condensible gases in the system to vertical conduit 63 and vessel 65, such gases are removed from all parts of the system actively participating in the production of refrigeration and collected in a single place which might be referred to as an inactive part. The non-condensible gases accumulating in the inactive part formed by conduit 63 and vessel G5 can reach a pressure considerably greater than that existing in the active parts in both the high and lower pressure sides of the system. For example, in the system like that referred to above and having an ice melting capacity of about five tons, and in which a solution of lithium bromide of about 55% concentration by weight is employed, the pressures in the high and lower pressure sides of the system are about 56 and 9 mm. Hg, respectively. Under these conditions the pressure in vessel 4U above the liquid level e therein is- 56 mm. Hg, the pressure existing in the high pressure side of the system.
The .maximum pressure that can prevail in vessel 65 and conduit B3 is reached when the liquid falls to the minimum level s in conduit 63. This maximum pressure in conduit 63 in the System referred to above is about 100 mm. Hg, and this pressure is balanced on the high pressure side of the system by the pressure above the liquid level e in vessel 40 and the liquid column extending downwardly from vessel 4i) through conduit 39 and one group of passages in liquid heat exchanger 38 to which the lower end of vertical conduit 53 is connected. Thus, while the pressure in the high pressure side oi the system is about 56 mm. Hg, the non-condensible gases can be trapped in conduit '63 and vessel B5 to a max-- imum pressure of about 100 mm. Hg, and at the same time the trapped gases do not adversely affect the normal operation of nor impair the eiiiciency of the refrigeration system.
The 4auxiliary absorber 41a illustrated in Fig. 4 diners from that shown in Fig. 2 and described above in that the screen 53a and orice or metering device 55a are located outside of shell 48a in a separate housing 1D. In Fig. 4 cooling water diverted from conduit 44 through conduit 58 is introduced into vthe lower end of a hollow cylinder or tube 50a extending upwardly within shell 48a. The cooling water passes from the upper curved end oi tube 50a into the upper end of acoil 51a disposed about and in thermal .contact with the tube. The lower end of coil 51a is connected by conduit 59 to conduit 45 in the same manner as in the first embodiment described above and shown in Fig. 1.
In the embodiment illustrated in F18; 4 diverted absorption liquid discharged from the lower end of conduit. 56 strikes the upper closed end of tube 50a at which region the non-condensible gases enter through conduit 49 from the main absorber I4. The absorption liquid ows along the coil 51a and forms a liquid nlm therein to provide a relatively extensive liquid ,surface with which the gases come in contact. Refrigerant vapor accompanying the non-condensibleV gases is absorbed into the. absorption liquid and in vthis way is removed from the gases. The heat liberated with absorption of refrigerant vapor into solution is transferred to the cooling water owing through coil 51a. From auxiliary absorber 41a the non-condensible gases are transferred through the fall tube pump 6I to the conduit 53 and vessel in the same .manner as in the rst embodiment described above.
The embodiment shown in Fig. -5 differs from that illustrated in Fig. 4 in that a solid helical member 51o is disposed about and in thermal contact with tube Elib, and the cooling water .cirf culates entirely within the tube. In Fig. 5 the cooling Water diverted from conduit rMI through conduit 58 enters a conduit 1I which is more or less a continuation of conduit 58 and extends upwardly within the tube 50h. The cooling water is discharged from the upper end of conduit 'II ad jacent the closed upper end of tube v501i and ilows down over the exterior surface of conduit 1I and through the tube 5B1). The cooling water passes from the lower end of tube 50h into conduit 59,.
In Fig. 5 the non-condensible gases enter the auxiliary absorber Hb through conduit 49 and come in Contact with absorption liquid entering through conduit 56. The absorption liquid strikes the upper vclosed end of tube 50h and flows downwardly `along the helical member A51h to provide a relatively extensive liquid surface. Refrigerant vapor accompanying the non-condensible gases is absorbed into absorption liquid, and the resulting heat of absorption is transferred to cooling water flowing downwardly within tube 50h.
By providing an auxiliary absorber like the absorbers 41, 41a and .41h described above, refrigerant vapor is eiectively removed from the noncondensible gases, so that substantially .no refrigerant vapor accompanies the non-condenslble gases trapped in the upper end 'of fall tube pump 6I. With substantially no refrigerant vapor entering the iall tube pump 6I, practically no absorption of refrigerant into absorbent takes place in the fall tube pump to produce .objectionable noises and undesirable slowing down -of the rate at which gas is transferred from absorber I4 to vertical conduit 63. Hence, the auxiliary `absorbers serve to effect withdrawal of non-condensible gases at a maximum .rate into the fall .tube pump 6I. In addition, since the absorption liquid diverted into the auxiliary absorbers 41, 41a and Mb is weak in refrigerant while the absorbent in the bottom of the main absorber I4 is rich in refrigerant, the vapor pressure of refrigerant in the auxiliary absorbers is less than that at .the bottom of the main absorber. This slight pressure differential promotes positive ow of non-l condensible gases from the main absorber I4 through conduit 49 to the auxiliary absorber. When both refrigerant vapor and non-condensible gases enter the fall tube pump and refrigerant is absorbed into solution in the latter, noncondensible gases pass from the main absorber at an extremely slow rate approaching a more or less stagnant flow similar to fio-w of gases by diffusion. However, by removing refrigerant vapor from the non-condensible gases in the auxiliary absorber and causing the gases to flow from the main absorber to a region of slightly lower pressure in the auxiliary absorber, extremely rapid flow of non-condensible gases from the main absorber is effected.
In each embodiment illustrated and described, the helical member of the auxiliary absorber, over which the absorption liquid. flows, fits snugly against a cylindrical part. With this arrangement liquid disturbances are created as liquid descends from one turn onto a part of the cylindrical wall and from the latter onto the next successively lower turn. In this way fresh liquid surfaces are constantly provided to improve absorption of Vrefrigerant vapor into absorbent.
The auxiliary absorber 41 is especially effective in that a relatively extensive liquid film is formed on coil 51 with which the gases come in contact. The heat of absorption resulting from absorption of refrigerant vapor into solution is transferred from the liquid film directly through the coil 51 to the cooling water flowing therein. In addition, absorption liquid flowing over the exterior surface of tube 50 increases the effective gas and liquid contact surface. The heat of absorption resulting from absorption of refrigerant vapor into solution at-the outside surface of tube 50 is also transferred to cooling water within the coil 51. Further, the coil throughout its length is in heat exchange relation with tube 50. so that effective precooling of absorption liquid within tube 50 is effected before such liquid is discharged through the orifice 55 and flows over the exterior surface of the coil 51. By providing an arrangement in which the absorption liquid is kept at as low a temperature as possible the more effectively is refrigerant vapor absorbed into solution, and the non-condensible gases passing into the tube 6I will be deprived of as much refrigerant vapor as possible.
The auxiliary absorbers 41a and 41h likewise are effective in producing a positive flow of noncondensible gases throu'rh conduit 49. As in the auxiliary absorber 41, the cooling water in the embodiments illustrated in Figs. 4 and 5 flows in heat exchange relation with absorption liquid along substantially the entire length of the path of fiow of the absorbent. Thus, in the Fig 4 the heat of absorption resulting from absorption of refrigerant vapor at the surfaces of coil 51a and exterior surface of tube 50a is immediately taken up by cooling water flowing within the tube 50a and also through the coil 51a. Morevover, the coil 57a isarranged in thermal contact with tube 59a in such a manner that the bottom end of the coil is in heat exchange relation with the end of the tube 50a which is the coolest and into which the cooling liquid is introduced through conduit 58.
Similarly, in the auxiliary absorber 41h illustrated in Fig. 5, the heat of absorption resulting from absorption of refrigerant vapor at the liquid film formed on helical coil 51h and at the exterior surface of tube 501:, is immediately taken up by cooling liquid flowing downwardly through tube 50h. By positioning conduit 1| within tube 50h in the manner illustrated, the cooling water leaving the tube through conduit 49 is in heat exchange relation with liquid entering conduit 1|' through conduit 58. By effectively cooling auxiliary absorbers 41a. and 41h in the manner just described, the auxiliary absorbers are maintained at as low a temperature as possible. In this way refrigerant vapor is effectively absorbed into solution and the non-condensible gases removed from the auxiliary absorbers 41a and 41h will be deprived of as much refrigerant vapor as possible.
While several embodiments of the invention have been shown and described, it will be apparent to those skilled in the art that various modifications and changes may be made without departing from the spirit and scope of the invention, as pointed out in the following claims.
What is claimed is:
l. A refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is disposed an upright annular member, a helical member fitting snugly about said annular member in direct contact therewith and extending lengthwise thereof, and means to flow absorption liquid onto' an upper partof said helical member, said annular member and helical member forming a path of flow for absorption liquid in which liquid descends from one turn of said helical member onto a part of said annular kwall and from the latter onto the next successively lower turn of said helical member, so that fresh liquid surfaces are constantly being provided with which non-condensible gases from said first ab-' sorber come in contact for removing refrigerant vapor accompanying such gases.
2. A refrigeration system operable below atrn'oseV pheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber come prising a casing providing a chamber within which is disposed a vertically extending wall member, means bearing against said wall member and forming a plurality of horizontally disposed barriers at different levels, means to flow absorption liquid onto one of said barriers at the upper part of said wall member, said wall member and barriers forming a relatively extensive gas and liquid contact surface with-absorption liquid passing from one barrier onto a part of said wall member and from the latter onto the next successively lower barrier, so that fresh liquid surfaces are constantly being provided with which non-condensible gases from said first absorber come in Contact for removing refrigerant vapor accompanying such gases.
3. A refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber, a hollow cylindrical member within said chamber having top and bottom closure plates, a helical coil fitting snugly about said cylindrical member in direct contact therewith and extending lengthwise thereof, an annular screen within and spaced from said cylindrical member, means for introducing absorption liquid within said annular screen, said top closure plate having an opening through which liquid is discharged upwardly from Within said cylindrical member, means including a plate positioned above said cylindrical member for deflecting liquid discharged through the opening onto said coil, said cylindrical member and coil forming a downward path of flow for absorption liquid, and means for flowing a cooling medium through said coil.
4. A refrigeration system operable below atmos'pheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising' a casing' providing a chamber within which is disposed an upright hollow cylinder, a helical coil fitting snugly about said cylinder in direct contact therewith and extending lengthwise thereof, means to flow a cooling medium through said helical coil, and means to flow absorption liquid onto an upper part of said coil, said cyl- Inder and coil forming a path of iiow for absorption liquid yin which liquid descends from one partof said coil onto a part of said cylinder and from the latter onto the next successively lower .turn of the coil, so that fresh liquid surfaces are constantly being provided with which non-condensible gases fro-m said first absorber come in contact for removing refrigerant vapor accompanying such gases.
5. A refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is located a vertically disposed hollow cylindrical member, a helical coil disposed about and extending lengthwise of'said cylindrical member, means for introducing a cooling medium to the lower part of said cylindrical member, the upper end of said coil being connected to the upper part of said cylindrical member so that cooling medium ows downwardly through said coili and means to flow absorption liquid onto an upper part of said coil, said coll and cylindrical member forming a path of flow for absorption liquid in which liquid descends from one turn of said coil onto a part of said cylindrical member and from the latter onto the next successively lower Iturn of said coil, so that fresh liquid surf-aces are constantly being provided with which 'non-condenslble gases from said first absorber come in contact for removing refrigerant vapor accompanying such gases.
6. A refrigeration system operable below atmospheric pressure and comprising a plurality 'of parts including a first absorber interconnected for circulation of absorption liquid and refrigeiant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is disposed an upright hollow cylindrical member, a helical element snugly tting about and extending lengthwise of said member, means for circulating cooling medium within said cylindrical member, and means to flow absorption liquid onto an upper part of said element, said helical element and cylindrical member forming a path of flow for absorption liquid in which liquid descends from one turn of said element onto a part of said cylindrical member and from the latter onto the next successively lower turn of said element.
'7. A refrigeration system operable below atmospheric pressure and comprising a plurality of parts including a first absorber interconnected for Icirculation of absorption liquid and refrigerant, and means including an auxiliary absorber for withdrawing non-condensible gases from said first absorber, said auxiliary absorber comprising a casing providing a chamber within which is located a vertically disposed hollow cylindrical member, a tube extending upwardly within said member and terminating in the upper part thereof, means for supplying cooling mea dium to 'said tube, said cylindrical member having an outlet for the cooling medium in the lower part thereof, a helical element snugly fitting about and extending lengthwise of said member, and means to flow absorption liquid onto an`upper Ipart of said element, said element and cylindrical member forming a path of flow for absorption liquid in which liquid descends from one turn of said element onto a part rof said cylindrical member land from the latter onto the next successively lower turn of said element.
8. A refrigeration system operable below atmospheric pressure and having a plurality of active parts, said active parts being interconnected for circulation of absorption liquid and refrigerant, and means including an absorber for withdrawing non-condensible gas from one of said active parts, 'said absorber having a vertically disposed cylindrical wall, a vertically extending pipe coil directly contacting a surface of said wall, said absorber being connected to receive non-condensible gas from said one active part, and means for flowing absorption liquid onto an upper part of said coil, said cylindrical 'wall and coil forming a path of flow for absorption liquid in which liquid descends from one turn of said coil onto a part of said surface and from the latter onto the next successively lower turn of said coil.
9. A refrigeration system operable below atmospheric pressure and comprising a plurality of active parts including a first absorber interconnected for circulation of absorption liquid and refrigerant, a vertically extending tube embodied in the system and through which absorption liquid flows, the upper end of Said tube being in communication with said first absorber, and means including said tube for withdrawing noncondensible gas from said rst absorber, said means including an auxiliary absorber for localizing the non-oonde'nsible gas flowing from said first absorber and for removing therefrom accompanying refrigerant Vapor, said auxiliary absorber including a vertically dis-posed cylindrical wall and a pipe coil directly contacting a surface of s-uch wall, and means for flowing absorption liquid onto an upper part of said coil, the refrigerant vapor accompanying the non-condensible gas from said first absorber being absorbed into absorption liquid in said auxiliary absorber whereby gas substantially free of refrigerant is en- 13 trained by absorption liquid at the -upper end oi' said tube.
10. In an absorption refrigeration system comprising a plurality of elements including an absorber interconnected to provide a closed circuit for the circulation of a refrigerant and absorption liquid, an auxiliary absorber connected to the absorber for receiving non-condensible gases therefrom, conduit means for flowing absorption liquid weak in refrigerant through the auxiliary absorbery said auxiliary absorber utilizing the absorption liquid to absorb refrigerant vapor and create a relative partial vacuum lwhereby to cause flow of the gases from the absorber to the auxiliary absorber, means for supplying a cooling medium to the auxiliary absorber to remove the heat of absorption, and means utilizing the flow of absorption solution for withdrawing non-condensible gases from the auxiliary absorber.
11. In an absorption refrigeration system comprising a generator and condenser operable at one pressure and an evaporator and absorber operable at a lower pressure, means interconnecting the elements to provide a closed circuit for the circulation of a refrigerant and absorption liquid and maintain the pressure differential, an auxiliary absorber connected to the low pressure side of the system to receive non-condensible gases therefrom, conduit means for flowing absorption liquid weak in refrigerant through the auxiliary absorber, said auxiliary absorber utilizing the absorption liquid to absorb refrigerant vapor to cause a flow of the gases thereto, means for supplying a cooling medium to the auxiliary absorber to remove the heat of absorption, and means utilizing the flow of absorption solution for withdrawing non-condensible gases from the auxiliary absorber.
12. In an absorption refrigeration system comprising a generator and condenser operable at one pressure and an evaporator and absorber operable at a lower pressure, means interconnecting the elements to provide a closed circuit for the circulation of a refrigerant and absorption solution and maintain the pressure diiferential, said last named means providing separate paths of flow between the generator and absorber for absorption liquid Weak in refrigerant and absorption liquid strong in refrigerant, a by-pass connected -between the separate paths of flow to cause absorption liquid weak in refrigerant to ow therethrough, an auxiliary absorber in the bypass and connected to the low presure side of the system to receive non-condensible gases therefrom, said auxiliary absorber utilizing the absorption liquid owing therethrough for absorbing refrigerant vapor to cause a flow of gases thereto, means for supplying a cooling medium to the auxiliary absorber to remove the heat of absorption, and a fall tube pump in the by-pass for withdrawing the non-condensible gases from the auxiliary absorber.
CHARLES ALFRED RO-SWELL.
No references cited.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2959935A (en) * 1958-01-16 1960-11-15 Carrier Corp Purging arrangement for absorption refrigeration systems
US3120113A (en) * 1960-12-12 1964-02-04 Trane Co Absorption refrigeration system
US3138005A (en) * 1962-03-28 1964-06-23 Carrier Corp Purge arrangements
US5060487A (en) * 1991-04-18 1991-10-29 Gas Research Institute Absorption refrigeration system purge pump apparatus
US5081851A (en) * 1991-04-18 1992-01-21 Gas Research Institute Absorption refrigeration system purge subsystem
US5176008A (en) * 1991-07-10 1993-01-05 Steenburgh Leon R Jr Refrigerant reclaim method and apparatus

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2959935A (en) * 1958-01-16 1960-11-15 Carrier Corp Purging arrangement for absorption refrigeration systems
US3120113A (en) * 1960-12-12 1964-02-04 Trane Co Absorption refrigeration system
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