USRE14167E - Nathan sttlzberger - Google Patents
Nathan sttlzberger Download PDFInfo
- Publication number
- USRE14167E USRE14167E US RE14167 E USRE14167 E US RE14167E
- Authority
- US
- United States
- Prior art keywords
- catalyst
- nickel
- carrier
- metal
- catalytically active
- Prior art date
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 38
- 239000003054 catalyst Substances 0.000 description 32
- 230000001603 reducing Effects 0.000 description 31
- 239000000969 carrier Substances 0.000 description 30
- 229910052751 metal Inorganic materials 0.000 description 30
- 239000002184 metal Substances 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 25
- 230000003197 catalytic Effects 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- 229910052759 nickel Inorganic materials 0.000 description 19
- 239000000126 substance Substances 0.000 description 16
- 238000006722 reduction reaction Methods 0.000 description 15
- 150000002739 metals Chemical class 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 238000006555 catalytic reaction Methods 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000002244 precipitate Substances 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- 229910052763 palladium Inorganic materials 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910052914 metal silicate Inorganic materials 0.000 description 3
- 239000003638 reducing agent Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001376 precipitating Effects 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 229940032158 sodium silicate Drugs 0.000 description 2
- 235000019794 sodium silicate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 206010010071 Coma Diseases 0.000 description 1
- JJCFRYNCJDLXIK-UHFFFAOYSA-N Cyproheptadine Chemical compound C1CN(C)CCC1=C1C2=CC=CC=C2C=CC2=CC=CC=C21 JJCFRYNCJDLXIK-UHFFFAOYSA-N 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N Hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 241001237728 Precis Species 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000009937 brining Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000001721 combination Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Definitions
- the mode generally em loyed was to endeavor to saturate such su stances with plete, minute and much simpler method of finely dividing and spreading a catalytically elficient substance over an inert material containing, for example, silicon, silica or other compounds containing silicon, is by utilizing a chemical compound containing silicon and such substance, which is to be used as a catalyzer.
- the resultant product which is to be catalytically employed, will be most intimately distributed among the silicon-containing substance.
- the product described in the following example even when brought to an impalpable powder of velvety feel, appears under the microscope black, due to its nickel-contents, in every particle.
- nickel silicate with small amountsv and other modi cations come under the scope of this invention, the fundamental idea of which is the utilization of a chemical combination per se or in mixture containing for exam le silicon and a metal, which is catalytica 1y efiicient.
- the claims cover not only the particularly specified ingredient (silicate, silicates, silica impregnated with metal, etc.), but also all mixtures of same with substances, as will not destroy the use of product as a catalyst.
- free from anti-catalytic material in claims: 1, 2 and 3 is meant, free from anticatalytic material and such amounts of same, as will destroy the catalytic action of the product.
- hydrogen in the following claims' also includes mixtures containing this element, as Well as all such other processes, which are efiective reducing agents in consequence of their hydrogen contents.
- the invention is characterized, as a 'process, by the reduction of a chemical compound of a metal possessing catalytic action and elements, such as those of an acid nature, forming a carrier or promoter therefor; and, as a product, by the unitary or atomistic nature of the reduced compound, the carrier not only being unitary with the catalytically active metal or metal compound, but serving as a promoter of the catalytic action.
- the carrier not only being unitary with the catalytically active metal or metal compound, but serving as a promoter of the catalytic action.
- I 1 A process of making a. catalyst, which comprises reducing a silicate of a catalytic metal with a reducing agent free from anti-' catalytic material.
- Process of making a catalyst consists mg in reducing nickel silicate by means of hydrogen.
- V V the precipitate to convert the metals into a catalytically active 7 state; substantially I as described.
- said catalyzer being of a homogeneous nature and of uniform appearance under the microscope; substantially as described.
- a catalyst comprising a chemical compound of a metal possessing catal tic action and a promotor therefor, reduce to a catalytically active state; substantially as described.
- a catalyst comprising a chemical compound of a metal possessing catalytic.
- a catalyst of a unitary nature comprising a reduction product of a chemical compound of a metal possessin catalytic action and a carrier therefor, said catalyst .being of uniform appearance under the "microscope; substantia ly as described.
- a catalyst comprising a reduction product of a chemical compound of nickel with elements formin nickel when subjecte stantially as described.
- a catalyst comprising a chemical compound of a metal possessing catalytic action and a carrier, re uced to a catalytically active state, said carrier beingof an acid nature; substantial as described.
- a catalyst adapt for use in the hydrogenation of oil comprising a reduction product of a chemical compound of nickel and a co-precipitated carrier therefor, said catalyzer being of a homogeneous nature and of uniform appearance under the microscope; substantially as described.
- a catalyst comprising a reduction product of a chemical compound containing nickel in a-black metallic state and a co- Erecipitated carrier therefor, said catalyzer eing of a homogeneous nature and of uniform appearance under the microscope; substantially as described.
- a catalyst of a unitary nature comprising a chemical compound of nickel and a promoter therefor, reduced to a catalytica 1y active state; substantially as described.
- a catalyst comprising co-precipitated metals possessing catalytic action and a coprecipitated carrier containing silicon, said co-precipitated product being reduced to a catalytically active state; substantially as described.
- a catalyst comprising co-precipitated nickel and palladium and a co-precipitated carrier therefor, said co-precipitated product being reduced to a catalytically active state;. substantially as described.
- a catalyst comprising co-precipitated nickel and palladium and a co-preci itated carrier therefor, said co-precipitate -prodnot being reduced to a catalytically active state, and said carrier being of an acid nature; substantially as described.
- a catalyst comprising precipitated silicate of nickel reduced to a black catalytically active state.
- a catalyst COmPIISIIIg a chemical compound containing silicon and a metal possessing catalytic action, reduced to a catalytically active state.
- the step which comprises bringing together the reacting materials in the presence of a catalytically active reduction product of a chemical compound of a metal pomessing catalytic action and elements forming. a carrier therefor.
- the step which comprises bringing together the reactin materials in the presence of a catalyticall y active reduction product of eo-precipitated nickel and elements of an acid nature forming a carrier therefor.
- the step which comprises bringing together the reacting materials in the presence of a catalytically active reduction product of a precipitated metal silicate.
- the step which comprises bringing together hydrogen and oil to be hydrogenated in the ⁇ presence of a catalytically active reduction product of a precipitated metal silicate.
- the step which comprises bringing together the reacting materials in the presence of a catalytically active reduction product of precipitated nickel silicate.
Description
NATHAN SULZBERGER, OF NEW YORK, N. Y.
CATALYZER AND PROCESS Specification of Reissued Letters Patent.
OF MAKING SAME AND FOR EFFECTING CATALYTIC REACTIONS THEBEWITH.
Reissued July 18, 1916.
Ho Drawing. Original No. 1,143,332, dated June 15, 1915, Serial No. 820,874. Application for reissue filed Kay 4, 1916. Serial No. 95,509.
To all whom it may concern:
Be it known that I, NATHAN SULzBEncnR, a citizen of the'United States, residing at New York city, in the county and State of 5 New York, have invented certain new and useful Improvements in Catalyzers and Processes of Making Same and for Effect ing Catalytic Reactions Therewith, of whiclr the following is a specification.
In all cases where catalyzers have been used, it has been found that their efliciency is increased, when such catalyzers are most finely distributed in the medium, which is to be treated. One of the methods for accomplishing such fine distribution is to impregnate an inert substance with the substance which is to be used as a catalyzer. -As such inert substances have been proposed among others, kieselguhr, kaolin, asbestos and the like. The mode generally em loyed was to endeavor to saturate such su stances with plete, minute and much simpler method of finely dividing and spreading a catalytically elficient substance over an inert material containing, for example, silicon, silica or other compounds containing silicon, is by utilizing a chemical compound containing silicon and such substance, which is to be used as a catalyzer. By this method, since the original molecule contained both substances, the resultant product, which is to be catalytically employed, will be most intimately distributed among the silicon-containing substance. Thus the product described in the following example, even when brought to an impalpable powder of velvety feel, appears under the microscope black, due to its nickel-contents, in every particle.
As an illustration, I cite the following:
. An aqueous solution of a nickel-salt was treated with a solution of sodium-silicate. The precipitate was filtered ofl', dried and SubJected to a current of hydrogen, while be ng heated. A black powder was obtamed. This substance wasused as a catalyzer, for instance, in hydrogenating oils, with which it can readily be mixed, remainmg well in suspension, to which fact may be due that the product likely contains silicic acld also in a colloidal condition.
Various modifications of the above described illustration of my invention may be employed. Thus, in some cases, the reduction of the. metal-silicate .may be accomplished in solution by means, for instance,
of hydrazin or some other reducing agent. 1
Mixture of substances, as, for instance, of
silicates: nickel silicate with small amountsv and other modi cations come under the scope of this invention, the fundamental idea of which is the utilization of a chemical combination per se or in mixture containing for exam le silicon and a metal, which is catalytica 1y efiicient.
The claims cover not only the particularly specified ingredient (silicate, silicates, silica impregnated with metal, etc.), but also all mixtures of same with substances, as will not destroy the use of product as a catalyst. By the term free from anti-catalytic material in claims: 1, 2 and 3, is meant, free from anticatalytic material and such amounts of same, as will destroy the catalytic action of the product. The word hydrogen in the following claims' also includes mixtures containing this element, as Well as all such other processes, which are efiective reducing agents in consequence of their hydrogen contents.
-It will be noted that the invention is characterized, as a 'process, by the reduction of a chemical compound of a metal possessing catalytic action and elements, such as those of an acid nature, forming a carrier or promoter therefor; and, as a product, by the unitary or atomistic nature of the reduced compound, the carrier not only being unitary with the catalytically active metal or metal compound, but serving as a promoter of the catalytic action. I believe it to be entirely new in the art, as above indicated, to thus produce a unitary catalyzer by reduction of a chemical compound of the metal or metals possessing catalytic action and a carrier or solid promoter therefoiz' I claim:
I 1. A process of making a. catalyst, which comprises reducing a silicate of a catalytic metal with a reducing agent free from anti-' catalytic material.
2. A process of making a catalyst, which- 7 metal by means of hydrogen.
5. Process of making a catalyst, consisting in reducing a silicate of catalytic metals by means'of hydrogen. p
6. Process of making a catalyst, consists mg in reducing nickel silicate by means of hydrogen.
7. Process of making a catalyst, consist ing in precipitating a soluble salt of a metal possessin catalytic action with a soluble alkali sillcate, and reducing the precipitate,
to a catalytically active form.
8. Process of making a catalyst, consist-. ing in precipitating a soluble nickel salt.
with sodium silicate, and reducing the precipitate to a catalytically active form. p
9. Product possessing catalytic action containing silica finely impregnated with metals possessing catalytic action, such im-- pregnatecl silica being of uniform appearance under the microscope.
10. The method of preparing a catalyst, which comprises reducin a chemical compound of a metal possessmg catalytic action and elements forming a solid promoter therefor; substantially as described.
11. The method of preparing a catalyst, which comprises co-precipitating a metal possessing catalytic action and a carrier therefor in-the form of a chemical compound, and reducing the compound; substantially as described.
12. The method of preparing a catalyst, which comprises reducing a chemical compound of nickel and elements forming a solid promoter therefor; substantially as described.
13. The method of preparing a catalyst which comprises co-precipitating nickel and a carrier therefor in the form of a chemical compound, and reducing the compound; substantially as described.
14. The method of preparing a catalyst which comprises co-precipitating nickel and a carrier therefor in the form of a chemical compound, and reducing the compound to a uniform black product; substantially as described;
15. The method of preparing a catalyst, which comprises co-precipitating a metal possessing catalytic action and a carrier therefor of an acid nature in the form of a chemical compound, and reducing the preand elements forming a promoter therefor; v
substantially as described. 18. The method of preparing a catalyst,
which comprises reducing chemical com-..
pounds of metals possessing catalytic action .1. and elements forming a promoter therefor, at least one metal being in chemical com bination with elements of the promoter,
substantially as described.
The method of preparing a catalysjh i which comprises co-precipitating metals.
possessing catalytic action, and a carrier therefor of an acid nature, one at least .of 0:0; the metals being in chemical combination;
elements of the carrier, and reducing; V the precipitate to convert the metals into a catalytically active 7 state; substantially I as described. V V
20. The method of preparing a catalyst, which comprises co-precipitating nickeland palladium and a carrier therefor, one at least of the metals being in chemical combination with elements of the carrier, and reducing 119 the precipitate to convert the metals into a catalytically active state; substantially as described.
21. The method of preparing a catalyst,
which comprises co-precipitating nickel and 1 5 palladium and a carrier therefor of an acid nature, one at least of the metals being in chemical combination with elements of the carrier, and reducing the precipitate to convert the nickel and palladium into a catalyt- 12o ically active state without complete reduc tion of the carrier; substantially as described.
22. The method of preparing a catalyst,
which comprises co-precipitating a metal 25' possessing catalytic action and elements forming a carrier therefor in the form of a chemical compound, and reducing the precipitate toa catalytically active state.
23. The method of preparing a catalyst, 13o
which comprises reducing preci itated silicate of nickel to a black catalytically active material of homogeneous appearance under the microscope.
24. The method of preparing a catalyzi;i
- tate'd carrier therefor, said catalyzer being of a homogeneous nature and of uniform appearance under the microscope; substantially as described.
26. A catalyst comprising a chemical compound of a metal possessing catal tic action and a promotor therefor, reduce to a catalytically active state; substantially as described.
27. A catalyst comprising a chemical compound of a metal possessing catalytic.
action and a promoter therefor, reduced to a catalytically active metallic state; substantially as described.
28. A catalyst of a unitary nature comprising a reduction product of a chemical compound of a metal possessin catalytic action and a carrier therefor, said catalyst .being of uniform appearance under the "microscope; substantia ly as described.
29. A catalyst comprising a reduction product of a chemical compound of nickel with elements formin nickel when subjecte stantially as described.-
30. A catalyst comprising a chemical compound of a metal possessing catalytic action and a carrier, re uced to a catalytically active state, said carrier beingof an acid nature; substantial as described.
31. A catalyst adapt for use in the hydrogenation of oil comprisinga reduction product of a chemical compound of nickel and a co-precipitated carrier therefor, said catalyzer being of a homogeneous nature and of uniform appearance under the microscope; substantially as described.
32. A catalyst comprising a reduction product of a chemical compound containing nickel in a-black metallic state and a co- Erecipitated carrier therefor, said catalyzer eing of a homogeneous nature and of uniform appearance under the microscope; substantially as described.
33. A catalyst of a unitary nature comprising a chemical compound of nickel and a promoter therefor, reduced to a catalytica 1y active state; substantially as described.
to reduction; sub- 34. A catalyst of a unitary nature coma carrier for the a carrier therefor, reduced to a catalytically active state, said carrier being of an acid 1 nature; substantially as described.
35. A catalyst comprising co-precipitated metals possessing catalytic action and a coprecipitated carrier containing silicon, said co-precipitated product being reduced to a catalytically active state; substantially as described.
36. A catalystcomprising co-precipitated nickel and palladium and a co-precipitated carrier therefor, said co-precipitated product being reduced to a catalytically active state;. substantially as described.
37. A catalyst comprising co-precipitated nickel and palladium and a co-preci itated carrier therefor, said co-precipitate -prodnot being reduced to a catalytically active state, and said carrier being of an acid nature; substantially as described. 38. A catalyst comprising precipitated silicate of nickel reduced to a black catalytically active state.
39. A catalyst COmPIISIIIg a chemical compound containing silicon and a metal possessing catalytic action, reduced to a catalytically active state.
40. In the art'of effecting catalytic reactions, the step which comprises bringing together the reacting materials in the presence of a catalytically active reduction product of a chemical compound of a metal pomessing catalytic action and elements forming. a carrier therefor.
41. In the art of effecting catalytic reactions, the step which comprises bringing together the reactin materials in the presence of a catalyticall y active reduction product of eo-precipitated nickel and elements of an acid nature forming a carrier therefor."
42. In the art of efiecting catalytic reactions, the step which comprises bringing together the reacting materials in the presence of a catalytically active reduction product of a precipitated metal silicate.
43. In the art of effecting catalytic reactions, the step which comprises bringing together hydrogen and oil to be hydrogenated in the {presence of a catalytically active reduction product of a precipitated metal silicate.
44. In the art of effecting catalytic reactions, the step which 'comprises brin ing together hydrogen and oil to be by rogenated in the presence of a catalytically active reduction product of precipitated nickel silicate.
45. In the art of effecting catalytic reactions, the step which comprises bringing together the reacting materials in the presence of a catalytically active reduction product of precipitated nickel silicate.
' NATHAN SULZBERGER.
Family
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