USH2133H1 - Fireproof protection integrating fabrication system for composite structures - Google Patents

Fireproof protection integrating fabrication system for composite structures Download PDF

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Publication number
USH2133H1
USH2133H1 US09/822,308 US82230801A USH2133H US H2133 H1 USH2133 H1 US H2133H1 US 82230801 A US82230801 A US 82230801A US H2133 H USH2133 H US H2133H
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US
United States
Prior art keywords
substrate
barrier
composite structure
forming
fabrication
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US09/822,308
Inventor
Usman A. K. Sorathia
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US Department of Navy
US Office of Naval Research ONR
Original Assignee
US Department of Navy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by US Department of Navy filed Critical US Department of Navy
Priority to US09/822,308 priority Critical patent/USH2133H1/en
Assigned to CHIEF OF NAVAL RESEARCH OFFICE OF COUNSEL reassignment CHIEF OF NAVAL RESEARCH OFFICE OF COUNSEL ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SORATHIA, USMAN A.K.
Application granted granted Critical
Publication of USH2133H1 publication Critical patent/USH2133H1/en
Abandoned legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/003Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0012Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
    • B29K2995/0016Non-flammable or resistant to heat

Definitions

  • the present invention relates generally to fabrication of composite structures in such a manner as to endow it with protective properties.
  • Composite structures having a substrate made of a structural material such as glass/vinyl ester are presently utilized for shipboard use. Because of flammability concerns in regard to such structures, passive fire protection has been proposed involving attachment of insulation blankets by means of self tapping screws. Installation of such fire protection for composite structures is both labor intensive and costly, especially in Newcastle shipboard types of seawater environments. It is therefore an important object of the present invention to provide less costly and less labor intensive fire protection for the foregoing referred to types of composite structures.
  • a protective barrier layer is applied to such substrate with a fire resisting agent such as phenolic resin, water or an oil-based intumescent coating.
  • a fire resisting agent such as phenolic resin, water or an oil-based intumescent coating.
  • the barrier layer in its position or place is permeated or infused in situ with the phenolic resin before attachment by adhesive bonding to the substrate.
  • the substrate is formed at the same time the barrier layer is infused with the phenolic resin so that it attaches the barrier layer to the substrate without use of adhesive.
  • FIG. 1 is a partial section view through a composite structure with which the present invention is associated in accordance with certain embodiments
  • FIG. 2 is a partial section view of a composite structure in accordance with other embodiments.
  • FIG. 3 is a block diagram of the procedure associated with fabrication of the composite structures illustrated in FIGS. 1 and 2 , so as to provide it with damage preventing protection from fire under shipboard use.
  • FIG. 1 illustrates a composite structure 10 which is to be utilized for example on a Navy marine vessel.
  • Such composite structure 10 includes a substrate 12 that is solid as shown, made of a structural material such as glass/vinyl ester preferred for shipboard use.
  • a fire protective barrier layer 14 is attached to the substrate 12 by a suitable bonding adhesive 16 , such as a phenolic or silicone adhesive.
  • the barrier layer 14 includes a core 18 formed by an intumescent mat or felt, protectively covered by a water proofing skin 20 such as an aluminum foil.
  • a fire resisting agent is introduced into such barrier 14 before its adhesive bonding attachment to the substrate 12 .
  • Such fire resisting agent is either phenolic resin or water, or an oil-based intumescent coating infused into the mat core 18 .
  • the barrier layer 14 may be formed from other materials into which the fire resisting agent, such as the phenolic resin, is introduced in-situ by scrimping so as to provide protection from damage from fire and high temperature conditions during normal use of the composite structure, as well as to resist water and solvent damage.
  • the fire resisting agent such as the phenolic resin
  • FIG. 2 illustrates a composite structure 10 ′ fabricated in accordance with other embodiments of the present invention.
  • Such composite structure 10 ′ includes a substrate 12 ′ of a composite type having a core 22 made of balsawood or foam.
  • a fireproof barrier layer 14 ′ protectively covers the substrate 12 ′, made of an intumescent mat into which phenolic resin is infused in-situ during fabrication or formation of the underlying substrate 12 ′ so as to be attached thereto without use of the bonding adhesive 16 .
  • FIG. 3 diagrammatically summarizes the procedures involved, resulting in formation 26 of a fireproof panel pursuant to the present invention.
  • Such procedures include formation 28 of the protective barrier from a barrier layer 30 , such as the barrier layers 14 or 14 ′, into which the fire resisting agent 32 is introduced, either before adhesive bonding to the substrate or during its formation 34 to avoid use of the adhesive bonding, before completing formation 26 of the composite structure as diagrammed in FIG. 3 .

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Mathematical Physics (AREA)
  • Building Environments (AREA)
  • Laminated Bodies (AREA)

Abstract

A composite structure having a substrate is protectively covered during fabrication by a barrier layer, such as an intumescent mat or felt, into which a fire resisting agent such as phenolic resin or water, or oil based intumescent coating is infused in-situ before attachment to the substrate and completion of composite structure fabrication. The barrier layer is infused in-situ with the phenolic resin before attachment by adhesive bonding to the substrate or infusion is performed during formation of the underlying substrate layer so as to achieve attachment without adhesive.

Description

The present invention relates generally to fabrication of composite structures in such a manner as to endow it with protective properties.
BACKGROUND OF THE INVENTION
Composite structures having a substrate made of a structural material such as glass/vinyl ester are presently utilized for shipboard use. Because of flammability concerns in regard to such structures, passive fire protection has been proposed involving attachment of insulation blankets by means of self tapping screws. Installation of such fire protection for composite structures is both labor intensive and costly, especially in Naval shipboard types of seawater environments. It is therefore an important object of the present invention to provide less costly and less labor intensive fire protection for the foregoing referred to types of composite structures.
SUMMARY OF THE INVENTION
In accordance with the present invention, during fabrication of a composite structure having a solid substrate made of a preferred shipboard material such as glass/vinyl ester or a sandwich type substrate, a protective barrier layer is applied to such substrate with a fire resisting agent such as phenolic resin, water or an oil-based intumescent coating. According to certain embodiments, the barrier layer in its position or place is permeated or infused in situ with the phenolic resin before attachment by adhesive bonding to the substrate. According to other embodiments, the substrate is formed at the same time the barrier layer is infused with the phenolic resin so that it attaches the barrier layer to the substrate without use of adhesive.
BRIEF DESCRIPTION OF DRAWING
A more complete appreciation of the invention and many of its attendant advantages will be readily appreciated as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawing wherein:
FIG. 1 is a partial section view through a composite structure with which the present invention is associated in accordance with certain embodiments;
FIG. 2 is a partial section view of a composite structure in accordance with other embodiments; and
FIG. 3 is a block diagram of the procedure associated with fabrication of the composite structures illustrated in FIGS. 1 and 2, so as to provide it with damage preventing protection from fire under shipboard use.
DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
Referring now to the drawing in detail, FIG. 1 illustrates a composite structure 10 which is to be utilized for example on a Navy marine vessel. Such composite structure 10 includes a substrate 12 that is solid as shown, made of a structural material such as glass/vinyl ester preferred for shipboard use. A fire protective barrier layer 14 is attached to the substrate 12 by a suitable bonding adhesive 16, such as a phenolic or silicone adhesive.
With continued reference to FIG. 1, the barrier layer 14 includes a core 18 formed by an intumescent mat or felt, protectively covered by a water proofing skin 20 such as an aluminum foil. A fire resisting agent is introduced into such barrier 14 before its adhesive bonding attachment to the substrate 12. Such fire resisting agent is either phenolic resin or water, or an oil-based intumescent coating infused into the mat core 18.
As an alternative, the barrier layer 14 may be formed from other materials into which the fire resisting agent, such as the phenolic resin, is introduced in-situ by scrimping so as to provide protection from damage from fire and high temperature conditions during normal use of the composite structure, as well as to resist water and solvent damage.
FIG. 2 illustrates a composite structure 10′ fabricated in accordance with other embodiments of the present invention. Such composite structure 10′ includes a substrate 12′ of a composite type having a core 22 made of balsawood or foam. A fireproof barrier layer 14′ protectively covers the substrate 12′, made of an intumescent mat into which phenolic resin is infused in-situ during fabrication or formation of the underlying substrate 12′ so as to be attached thereto without use of the bonding adhesive 16.
It will be apparent from the foregoing description, that the protective barrier layer 14 or 14′ covers either a solid type substrate 12 or a composite core type substrate 12′ and that the fire resisting agent is introduced in-situ, for example by infusion of the phenolic agent, either before attachment of the barrier layer by bonding adhesive 16 or during formation of the substrate to avoid use of such bonding adhesive for attachment purposes. FIG. 3 diagrammatically summarizes the procedures involved, resulting in formation 26 of a fireproof panel pursuant to the present invention. Such procedures include formation 28 of the protective barrier from a barrier layer 30, such as the barrier layers 14 or 14′, into which the fire resisting agent 32 is introduced, either before adhesive bonding to the substrate or during its formation 34 to avoid use of the adhesive bonding, before completing formation 26 of the composite structure as diagrammed in FIG. 3.
Obviously, other modifications and variations of the present invention may be possible in light of the foregoing teachings. It is therefore to be understood that within the scope of the appended claims the invention may be practiced otherwise than as specifically described.

Claims (3)

1. In a process for protective fabrication of a composite structure to be exposed to seawater environments, the improvement residing in a sequence of steps including: a) forming a barrier; b) introducing a fire resisting agent into the barrier after said forming thereof: c) forming a substrate; and d) attaching the barrier to the substrate in underlying relation thereto before completing the fabrication of the composite structure; wherein said introducing of the fire resisting agent comprises: infusion into the barrier.
2. In a process for protective fabrication of a composite structure to be exposed to seawater environments, the improvement residing in a sequence of steps including: a) forming a barrier, b) introducing a fire resisting agent into the barrier after said forming thereof: c) forming a substrate; and d) attaching the barrier to the substrate in underlying relation thereto before completing the fabrication of the composite structure; wherein said attaching of the barrier to the substrate is performed by providing an adhesive between the barrier and the substrate.
3. In a process for protective fabrication of a composite structure to be exposed to seawater environments, the improvement residing in a sequence of steps including: a) forming a barrier; b) introducing a fire resisting agent into the barrier after said forming thereof: c) forming a substrate; and d) attaching the barrier to the substrate in underlying relation thereto before completing the fabrication of the composite structure; wherein said introducing of the fire resisting agent is performed by infusion thereof into the barrier during said forming of the substrate to effect said attaching of the barrier to the substrate without using an adhesive.
US09/822,308 2001-03-29 2001-03-29 Fireproof protection integrating fabrication system for composite structures Abandoned USH2133H1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US09/822,308 USH2133H1 (en) 2001-03-29 2001-03-29 Fireproof protection integrating fabrication system for composite structures

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US09/822,308 USH2133H1 (en) 2001-03-29 2001-03-29 Fireproof protection integrating fabrication system for composite structures

Publications (1)

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USH2133H1 true USH2133H1 (en) 2005-11-01

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110308161A1 (en) * 2010-06-22 2011-12-22 Cox Architects Pty Ltd Fire shutter
US8601760B2 (en) * 2007-01-19 2013-12-10 Balco, Inc. Fire barrier
US8844195B2 (en) 2010-06-22 2014-09-30 Cox Architects Pty Ltd Fire shutter

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5270105A (en) 1992-09-21 1993-12-14 The United States Of America As Represented By The Secretary Of The Navy Fireproof barrier system for composite structure
US20010031350A1 (en) * 1999-12-28 2001-10-18 Day Stephen W. Fiber reinforced composite cores and panels

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5270105A (en) 1992-09-21 1993-12-14 The United States Of America As Represented By The Secretary Of The Navy Fireproof barrier system for composite structure
US20010031350A1 (en) * 1999-12-28 2001-10-18 Day Stephen W. Fiber reinforced composite cores and panels

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Publication entitled "Fire Protection of Glass/Vinyl Ester Composites for Structural Applications" by U. Sorathia and C. Beck for 41st Internation SAMPE Symposium dated 24-28, 1996 pp. 687-697.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8601760B2 (en) * 2007-01-19 2013-12-10 Balco, Inc. Fire barrier
US20110308161A1 (en) * 2010-06-22 2011-12-22 Cox Architects Pty Ltd Fire shutter
US8844195B2 (en) 2010-06-22 2014-09-30 Cox Architects Pty Ltd Fire shutter

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Owner name: CHIEF OF NAVAL RESEARCH OFFICE OF COUNSEL, VIRGINI

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SORATHIA, USMAN A.K.;REEL/FRAME:011732/0074

Effective date: 20010328

STCF Information on status: patent grant

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