USH1002H - Microwave absorbing material - Google Patents

Microwave absorbing material Download PDF

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Publication number
USH1002H
USH1002H US07/509,670 US50967090A USH1002H US H1002 H USH1002 H US H1002H US 50967090 A US50967090 A US 50967090A US H1002 H USH1002 H US H1002H
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United States
Prior art keywords
absorbing material
percent
weight
microspheres
range
Prior art date
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Abandoned
Application number
US07/509,670
Inventor
Harold T. Hahn
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US Department of Navy
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Individual
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Filing date
Publication date
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Priority to US07/509,670 priority Critical patent/USH1002H/en
Assigned to UNITED STATES OF AMERICA, THE, AS REPRESENTED BY THE DEPARTMENT OF THE NAVY reassignment UNITED STATES OF AMERICA, THE, AS REPRESENTED BY THE DEPARTMENT OF THE NAVY ASSIGNMENT OF ASSIGNORS INTEREST. SUBJECT TO LICENSE RECITED Assignors: HAHN, HAROLD T.
Application granted granted Critical
Publication of USH1002H publication Critical patent/USH1002H/en
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01QANTENNAS, i.e. RADIO AERIALS
    • H01Q17/00Devices for absorbing waves radiated from an antenna; Combinations of such devices with active antenna elements or systems

Definitions

  • This invention pertains to a material for absorbing microwave radiation.
  • Microwave absorbing materials are known in the prior art, but these are generally iron-filled and thus dense. Prior art material also tend to be unstable in a high radiation environment.
  • hollow carbon microspheres in the range of sizes between 90 and 350 microns outside diameter are mixed uniformly in a matrix of flexible silicone such that the microspheres are 27 to 34 percent by weight of the absorbing material.
  • the material is strongly absorbent in the range of frequencies 2500 to 6000 MHz.
  • An important advantage of the present invention is the material is stock resistant, flexible and stable in thickness of 0.2 inches or greater.
  • FIG. 1 shows plots of standing wave ratios as a function of frequency for varying thicknesses of the preferred embodiment of the material of the invention.
  • the material according to the invention is formed by embedding hollow carbon microspheres in a suitable matrix material, such as a flexible silicone or an inflexible epoxy.
  • a suitable matrix material such as a flexible silicone or an inflexible epoxy.
  • the carbon microspheres have a preferable diameter between 90 and 350 microns.
  • Carbon microspheres are available from Kureha Chemical Industries Co., Ltd., Tokyo, Japan and Versar, Inc., Springfield, Va.
  • Suitable flexible silicone matrix materials include Dow-Coming RTV 3112, Dow-Coming Sylgard 184, and General Electric Silicone 566A.
  • Sylgard 184 is preferred because it (a) has a good radiation resistance, (b) has low shrinkage during curing, (c) bonds well to a substrate, and (d) needs no post-cure before use.
  • compositions containing from 27 weight percent microspheres to 34 percent by weight microspheres are best. Although compositions over this range have been tested and found satisfactory, the composition containing 30.0 percent by weight carbon spheres in Sylgard 184 is preferred. This composition has a satisfactory mechanical integrity and flexibility in thicknesses of 0.2 inches and greater.
  • the density of the preferred embodiment is 0.48 g/cm 3 . In a thickness of 0.22 inches, this corresponds to 0.55 pounds per square foot.

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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A microwave absorbing material for the range 2500-6000 MHz is formed by using hollow carbon microspheres in the range of sizes between 90 and 350 microns outside diameter mixed unformly in a matrix of flexible silicone such that the microspheres are 27 to 34 percent by weight of the absorbing material. An important advantage of the present invention is the material contains no iron, is shock resistant, flexible and stable in thicknesses of 0.2 inches or greater.

Description

FIELD OF THE INVENTION
This invention pertains to a material for absorbing microwave radiation.
BACKGROUND OF THE INVENTION
Microwave absorbing materials are known in the prior art, but these are generally iron-filled and thus dense. Prior art material also tend to be unstable in a high radiation environment.
OBJECTIVES OF THE INVENTION
It is therefore a primary objective of the present invention to provide a stable low-density material for absorbing microwave energy in the 2500 to 6000 MHz band.
SUMMARY OF THE INVENTION
These objects of the invention and other objects, features and advantages to become apparent as the specification progresses are accomplished by the invention according to which, briefly stated, hollow carbon microspheres in the range of sizes between 90 and 350 microns outside diameter are mixed uniformly in a matrix of flexible silicone such that the microspheres are 27 to 34 percent by weight of the absorbing material.
List of Advantages of the Invention
The material is strongly absorbent in the range of frequencies 2500 to 6000 MHz.
An important advantage of the present invention is the material is stock resistant, flexible and stable in thickness of 0.2 inches or greater.
For many applications, the most important advantage is its low density compared to iron-loaded composites.
These and further objectives, constructional and operational characteristics, and advantages of the invention will no doubt be more evident to those skilled in the art from the detailed description given hereinafter which illustrates a preferred embodiment by way of non-limiting example.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 shows plots of standing wave ratios as a function of frequency for varying thicknesses of the preferred embodiment of the material of the invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
The material according to the invention is formed by embedding hollow carbon microspheres in a suitable matrix material, such as a flexible silicone or an inflexible epoxy. The carbon microspheres have a preferable diameter between 90 and 350 microns. Carbon microspheres are available from Kureha Chemical Industries Co., Ltd., Tokyo, Japan and Versar, Inc., Springfield, Va. Suitable flexible silicone matrix materials include Dow-Coming RTV 3112, Dow-Coming Sylgard 184, and General Electric Silicone 566A. Sylgard 184 is preferred because it (a) has a good radiation resistance, (b) has low shrinkage during curing, (c) bonds well to a substrate, and (d) needs no post-cure before use. Compositions containing from 27 weight percent microspheres to 34 percent by weight microspheres are best. Although compositions over this range have been tested and found satisfactory, the composition containing 30.0 percent by weight carbon spheres in Sylgard 184 is preferred. This composition has a satisfactory mechanical integrity and flexibility in thicknesses of 0.2 inches and greater.
When backed by a metal plate, i.e., shorted, 0.026 inches thick material of the preferred embodiment displayed the followings standing wave ratios (SWR):
______________________________________                                    
        MHz  SWR                                                          
______________________________________                                    
        2600 3.84                                                         
        3000 2.03                                                         
        3400 1.39                                                         
        3800 1.67                                                         
        4200 2.18                                                         
        4600 2.70                                                         
        5000 3.28                                                         
        5400 3.82                                                         
        6000 4.30                                                         
______________________________________                                    
The density of the preferred embodiment is 0.48 g/cm3. In a thickness of 0.22 inches, this corresponds to 0.55 pounds per square foot.
Another embodiment containing 33.1 percent by weight carbon spheres in RTV 3112 with a thickness of 0.267 inches provided the following standing wave ratios:
______________________________________                                    
        MHz  SWR                                                          
______________________________________                                    
        2400 2.25                                                         
        2600 1.52                                                         
        2800 1.31                                                         
        3000 1.61                                                         
        3200 2.02                                                         
        3400 1.98                                                         
        3600 1.88                                                         
        3800 1.98                                                         
        4000 2.10                                                         
        5000 3.65                                                         
______________________________________                                    
Another embodiment containing 32.9 percent by weight carbon sphere in Silicone 566A with a thickness of 0.263 inches yielded the following standing wave ratios:
______________________________________                                    
        MHz  SWR                                                          
______________________________________                                    
        2400 2.24                                                         
        2600 1.61                                                         
        2800 1.42                                                         
        3000 1.60                                                         
        3200 1.90                                                         
        3400 2.25                                                         
        3600 2.60                                                         
        3800 2.93                                                         
        4000 3.29                                                         
______________________________________                                    
This invention is not limited to the preferred embodiment and alternatives heretofore described, to which variations and improvements may be made, without departing from the scope of protection of the present patent and true spirit of the invention, the characteristics of which are summarized in the following claims.

Claims (3)

What is claimed is:
1. A microwave absorbing material for the range 2500 to 6000 MHz, comprising:
a matrix of flexible silicone, forming 66 to 73 percent by weight of the absorbing material,
hollow carbon microspheres having a range of sizes between 90 and 350 microns outside diameter, said microspheres being mixed uniformly into said matrix to form 27 to 34 percent by weight of the absorbing material.
2. The material of claim 1 wherein said matrix material comprises approximately 70 percent by weight of the absorbing material and said hollow carbon microspheres comprise approximately 30 percent by weight of the absorbing material.
3. The material of claim 2 wherein said material is formed into sheets of thickness 0.2 inches or greater.
US07/509,670 1990-04-16 1990-04-16 Microwave absorbing material Abandoned USH1002H (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US07/509,670 USH1002H (en) 1990-04-16 1990-04-16 Microwave absorbing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/509,670 USH1002H (en) 1990-04-16 1990-04-16 Microwave absorbing material

Publications (1)

Publication Number Publication Date
USH1002H true USH1002H (en) 1991-12-03

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030062641A1 (en) * 2001-08-16 2003-04-03 Niraj Vasishtha Microencapsulation using electromagnetic energy and core and shell materials with different dielectric constants and dissipation factors
US20030062722A1 (en) * 2001-08-21 2003-04-03 Linhart Georg Peter Hose line with a connection sleeve
US7869216B2 (en) 2008-08-25 2011-01-11 Honeywell International Inc. Composite avionics chassis
CN117353046A (en) * 2023-12-05 2024-01-05 南昌大学 A hollow multi-layer composite electromagnetic wave-absorbing material and its preparation method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2877286A (en) 1955-06-13 1959-03-10 Cs 13 Corp Radiant energy shielding device
US2996710A (en) 1945-09-20 1961-08-15 Du Pont Electromagnetic radiation absorptive article
US3951904A (en) 1973-03-07 1976-04-20 Kureha Kagaku Kogyo Kabushiki Kaisha Electromagnetic wave absorbing material containing carbon microspheres
US4003840A (en) 1974-06-05 1977-01-18 Tdk Electronics Company, Limited Microwave absorber
US4112179A (en) 1975-12-10 1978-09-05 Maccalous Joseph W Method of coating with ablative heat shield materials
US4116906A (en) 1976-06-09 1978-09-26 Tdk Electronics Co., Ltd. Coatings for preventing reflection of electromagnetic wave and coating material for forming said coatings

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2996710A (en) 1945-09-20 1961-08-15 Du Pont Electromagnetic radiation absorptive article
US2877286A (en) 1955-06-13 1959-03-10 Cs 13 Corp Radiant energy shielding device
US3951904A (en) 1973-03-07 1976-04-20 Kureha Kagaku Kogyo Kabushiki Kaisha Electromagnetic wave absorbing material containing carbon microspheres
US4003840A (en) 1974-06-05 1977-01-18 Tdk Electronics Company, Limited Microwave absorber
US4112179A (en) 1975-12-10 1978-09-05 Maccalous Joseph W Method of coating with ablative heat shield materials
US4116906A (en) 1976-06-09 1978-09-26 Tdk Electronics Co., Ltd. Coatings for preventing reflection of electromagnetic wave and coating material for forming said coatings

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030062641A1 (en) * 2001-08-16 2003-04-03 Niraj Vasishtha Microencapsulation using electromagnetic energy and core and shell materials with different dielectric constants and dissipation factors
US6881482B2 (en) 2001-08-16 2005-04-19 Southwest Research Institute Microencapsulation using electromagnetic energy and core and shell materials with different dielectric constants and dissipation factors
US20030062722A1 (en) * 2001-08-21 2003-04-03 Linhart Georg Peter Hose line with a connection sleeve
US7869216B2 (en) 2008-08-25 2011-01-11 Honeywell International Inc. Composite avionics chassis
CN117353046A (en) * 2023-12-05 2024-01-05 南昌大学 A hollow multi-layer composite electromagnetic wave-absorbing material and its preparation method
CN117353046B (en) * 2023-12-05 2024-06-04 南昌大学 A hollow multilayer composite electromagnetic absorbing material and preparation method thereof

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Owner name: UNITED STATES OF AMERICA, THE, AS REPRESENTED BY T

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. SUBJECT TO LICENSE RECITED;ASSIGNOR:HAHN, HAROLD T.;REEL/FRAME:005279/0803

Effective date: 19900412

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