US995038A - Acid ferric phosphor tartrate. - Google Patents
Acid ferric phosphor tartrate. Download PDFInfo
- Publication number
- US995038A US995038A US45158708A US1908451587A US995038A US 995038 A US995038 A US 995038A US 45158708 A US45158708 A US 45158708A US 1908451587 A US1908451587 A US 1908451587A US 995038 A US995038 A US 995038A
- Authority
- US
- United States
- Prior art keywords
- phosphor
- tartrate
- acid
- ferric
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title description 14
- XTKHWUVETDADPA-UHFFFAOYSA-N OC(C(C(O)=O)O)C(O)=O.OC(C(C(O)=O)O)C(O)=O.OC(C(C(O)=O)O)C(O)=O.P.P Chemical compound OC(C(C(O)=O)O)C(O)=O.OC(C(C(O)=O)O)C(O)=O.OC(C(C(O)=O)O)C(O)=O.P.P XTKHWUVETDADPA-UHFFFAOYSA-N 0.000 title description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 229910052742 iron Inorganic materials 0.000 description 9
- 239000003513 alkali Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical class [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical class OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000011975 tartaric acid Substances 0.000 description 5
- 235000002906 tartaric acid Nutrition 0.000 description 5
- 239000005955 Ferric phosphate Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229940032958 ferric phosphate Drugs 0.000 description 4
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 4
- 229910000399 iron(III) phosphate Inorganic materials 0.000 description 4
- -1 Iron Phosphor Tartrate Chemical compound 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 3
- 239000001488 sodium phosphate Substances 0.000 description 3
- 239000001433 sodium tartrate Substances 0.000 description 3
- 229960002167 sodium tartrate Drugs 0.000 description 3
- 235000011004 sodium tartrates Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical class OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 159000000014 iron salts Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- JURLZXLBRBMGSF-UHFFFAOYSA-N C(C(O)C(O)C(=O)O)(=O)O.[P] Chemical compound C(C(O)C(O)C(=O)O)(=O)O.[P] JURLZXLBRBMGSF-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- VRWKTAYJTKRVCU-UHFFFAOYSA-N iron(6+);hexacyanide Chemical compound [Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] VRWKTAYJTKRVCU-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/08—Esters of oxyacids of phosphorus
- C07F9/09—Esters of phosphoric acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
Definitions
- the water-insoluble iron salts of phosphoric acid are dissolved by the so-called vegetable acids, as tartaric acid (H. Quartaroli, U/wmz'sches UemmZbZatt 1905, page 1609). It was observed that in this solution iron salts of the complex phosphor-tartaric acid are formed, similar to those of the known borotartaric acid (Arc/Liv (Zcr Pharmaeie 190, 1868, pages 5% and also,
- the acid ferric phosphor-tartrate is diflicultly soluble in water and diluted acids, but dissolves in strong acids and can be precipitated therefrom by means of alkali.
- alkali Upon neutralization with alkali, water-soluble alkali double salts are formed which by an excess of alkali are separated in-the warm state as reddish-brown precipitates. They resemble ferric hydroxid in appearance, but dissolve in pure water and contain tartaric acid and phosphoric acid in chemical combination. Ammonia, like the alkalis, dissolves more slowly, but in excess does not cause precipitation. The solution remains unchanged also upon addition of ferrocyanid of potassium.
- the dry ferric phosphor-tartrate is of yellowish-green appearance, turns grayish-blue upon exposure to light, and is tasteless and odorless.
- the organic substance Upon heating in the open air, the organic substance is first charred, then glows, and leaves oxid of iron and phosphate of iron ashes. Heated with concentrated sulfuric acid, the salt is decomposed and carbonic acid and Specification of Letters Patent.
- Example I Upon treating 2 molecular proportions of ferric phosphate, obtained by precipitating a solution of 400 parts sodium phosphate (Na I-IPOQ by means of chlorid of iron solution containing 270 parts chlorid of iron (Fe Cl with a solution of 3n1olecular pro ortions of acid sodium tartrate (obtained rom 220 parts tartaric and 85 parts sodium carbonate), the yellow ferric phosphate in the warm state, when stirred, is liquefied and changed to the greenish-yellow mass of ferric phosphor-tartrate which, washed with water and dried in a dark place, will form a greenish-yellow powder.
- Example II Upon adding to the solution of 100 parts disodium phosphate in 1000 parts water, 220 parts tartaric acid and 85 parts sodium carbonate, while heating up and stirring, and adding to this solution of readily soluble sodium phosphor tartrate 270 parts ferric chlorid dissolved in 500 parts water, the greenish-yellow, acid ferric phosphor-tartrate is promptly precipitated, which is then filtered, washed with water, pressed and dried in a dark place.
- the order of procedure in mixing the ingredients is the following: After treating a solution of disodium phosphate (Na I-IPO with chlorid of iron (Fe CI phosphate of iron is precipitated; but if the tartaric acid or acid sodium tartrate is added, the mentioned phosphate of iron is changed to the greenish ferric phosphor tartrate as described in Example I.
- Process of manufacturing acid ferric phosphor-tartrate consisting in (1) treating ferric phosphate with acid sodium tartrate in the ratio of 2 molecules of the former to 3 of the latter, and (2) treating the solution of the alkali phosphor-tartrate with chlorid of iron.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
Description
CARL SORGER, OF NIEDERLAHNSTEIN-ON-THE-RHINE, GERMANY.
ACID FERRIC PHOSPHOR TAR-IRATE.
No Drawing.
To all whom it may concern:
Be it known that I, CARL SoRcnR, doctor of philosophy, a subject of the King of Prussia, residing at Niederlahnstein-on-the Rhine, (formerly at Frankfort-on-the-Main,) Germany, have invented a certain new and useful Process of Manufacturing Iron Phosphor Tartrate, of which the following is a specification.
The water-insoluble iron salts of phosphoric acid are dissolved by the so-called vegetable acids, as tartaric acid (H. Quartaroli, U/wmz'sches UemmZbZatt 1905, page 1609). It was observed that in this solution iron salts of the complex phosphor-tartaric acid are formed, similar to those of the known borotartaric acid (Arc/Liv (Zcr Pharmaeie 190, 1868, pages 5% and also,
J ahresbem'cht "fiber die Fortscimittc (fer O/zemz'e con F. Fittz'ca an clas Jain 1879 (publ.. 1881), page 665). The acid iron phosphor tartrate can be precipitated from the solution by neutralizing the excess of acid with some alkali. However, it is more advisable to treat the precipitated ferric phosphate with the acid alkali salts of tartaric acid, or chlorid of iron with phosphor-tartaric alkali. The chemical formula could so far not be ascertained.
The acid ferric phosphor-tartrate is diflicultly soluble in water and diluted acids, but dissolves in strong acids and can be precipitated therefrom by means of alkali. Upon neutralization with alkali, water-soluble alkali double salts are formed which by an excess of alkali are separated in-the warm state as reddish-brown precipitates. They resemble ferric hydroxid in appearance, but dissolve in pure water and contain tartaric acid and phosphoric acid in chemical combination. Ammonia, like the alkalis, dissolves more slowly, but in excess does not cause precipitation. The solution remains unchanged also upon addition of ferrocyanid of potassium. The dry ferric phosphor-tartrate is of yellowish-green appearance, turns grayish-blue upon exposure to light, and is tasteless and odorless. Upon heating in the open air, the organic substance is first charred, then glows, and leaves oxid of iron and phosphate of iron ashes. Heated with concentrated sulfuric acid, the salt is decomposed and carbonic acid and Specification of Letters Patent.
Application filed September 3, 1908.
Patented June 13, 1911.
Serial No. 451,587. (Specimens) carbon monoxid are generated, while the solution turns brown. These properties characterize the substance as a new. chemical body. It possesses great therapeutic value which is still enhanced by the presence of phosphoric acid.
Example I: Upon treating 2 molecular proportions of ferric phosphate, obtained by precipitating a solution of 400 parts sodium phosphate (Na I-IPOQ by means of chlorid of iron solution containing 270 parts chlorid of iron (Fe Cl with a solution of 3n1olecular pro ortions of acid sodium tartrate (obtained rom 220 parts tartaric and 85 parts sodium carbonate), the yellow ferric phosphate in the warm state, when stirred, is liquefied and changed to the greenish-yellow mass of ferric phosphor-tartrate which, washed with water and dried in a dark place, will form a greenish-yellow powder.
Example II: Upon adding to the solution of 100 parts disodium phosphate in 1000 parts water, 220 parts tartaric acid and 85 parts sodium carbonate, while heating up and stirring, and adding to this solution of readily soluble sodium phosphor tartrate 270 parts ferric chlorid dissolved in 500 parts water, the greenish-yellow, acid ferric phosphor-tartrate is promptly precipitated, which is then filtered, washed with water, pressed and dried in a dark place.
The order of procedure in mixing the ingredients is the following: After treating a solution of disodium phosphate (Na I-IPO with chlorid of iron (Fe CI phosphate of iron is precipitated; but if the tartaric acid or acid sodium tartrate is added, the mentioned phosphate of iron is changed to the greenish ferric phosphor tartrate as described in Example I.
Claim of patent:
Process of manufacturing acid ferric phosphor-tartrate, consisting in (1) treating ferric phosphate with acid sodium tartrate in the ratio of 2 molecules of the former to 3 of the latter, and (2) treating the solution of the alkali phosphor-tartrate with chlorid of iron.
CARL SORGER.
Witnesses HEI RIoH JUNG, Gnone BERTENBREITER.
Copies of this patent may be obtained for five cents each, by addressing the Commissioner of Patents, Washington, D. G.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45158708A US995038A (en) | 1908-09-03 | 1908-09-03 | Acid ferric phosphor tartrate. |
| US565392A US995383A (en) | 1908-09-03 | 1910-06-06 | Acid ferric arsen-tartrate. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45158708A US995038A (en) | 1908-09-03 | 1908-09-03 | Acid ferric phosphor tartrate. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US995038A true US995038A (en) | 1911-06-13 |
Family
ID=3063371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US45158708A Expired - Lifetime US995038A (en) | 1908-09-03 | 1908-09-03 | Acid ferric phosphor tartrate. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US995038A (en) |
-
1908
- 1908-09-03 US US45158708A patent/US995038A/en not_active Expired - Lifetime
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