US994931A - Method of waterproofing fabrics. - Google Patents

Method of waterproofing fabrics. Download PDF

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Publication number
US994931A
US994931A US1909506734A US994931A US 994931 A US994931 A US 994931A US 1909506734 A US1909506734 A US 1909506734A US 994931 A US994931 A US 994931A
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fabric
liquid
temperature
moisture
fluid
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Pierre O Keilholtz
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/03Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite
    • C04B35/04Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on magnesium oxide, calcium oxide or oxide mixtures derived from dolomite based on magnesium oxide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • H01B13/065Insulating conductors with lacquers or enamels
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2221Coating or impregnation is specified as water proof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2475Coating or impregnation is electrical insulation-providing, -improving, or -increasing, or conductivity-reducing

Definitions

  • My invention consists of a method for the elimination of the bound and free moisture and contained air present in fabrics composed of cotton, paper and other materials, and the substitution for the moisture and free air of a liquid which will cause the fabric to be Waterproof; that is to say, which will so fill the voids, interstices and capillaries of the fabric as to prevent the reabsorption of moisture or air, thus rendering the fabric non-hygroscopic and irisulating it if it be used for electrical purposes.
  • textile a combination of textiles, a structure made of metal or metal and textile; in fact, everything'from which it is desired to extract air and moisture and to fill the voids formerly occupied by the air and moisture with a liquid which will serve for waterproofing and insulating purposes.
  • a cotton textile fabric is composed of strandsof cotton, the structure consisting of longitudinal strands interlacing with lateral strands.
  • the strands cannot be woven so tightly that the fabric will have no voids or interstices and the coarser the fabric-that is, the larger the strands-the greater will be the interstices.
  • the interstices formed by the intersection of the strands may be considered as voids of the first order-of magnitude.
  • the strands consist of a bundle of fibers twisted together. Several strands may be combined to form a larger strand; The spaces betweenthe adjacent fibers composing the strands andthe spaces between the strands of a single yarn may be considered as voids of a second order of magnitude.
  • the fibers themselves consist of flattened tube-like structures and "the spaces within the fibers, the interior of the tub s, may be considered as voids of a thlrd order of magnitude. It w1ll be readily pereeivedthat the surface of a cotton fabric is of enormous extent when "the internal and external spaces of the fibers composing the fabric are considered.
  • the superficial energy of a solid and liquid in contact in cases where the liquid does not dissolve the solid depends upon the nature and extent of the surface. When the liquid dissolves the-solid, the surface disappears andthere is no superficial energy. It is known that the molecular activity or energy of a liquid is greatest very close to its surface. It is probable that this increase .of energy is sensible'within a distance of one-thousandth of a millimeter or less from the surface. It is also known that the superficial tension or energy decreases with an increase of temperature and in the case of water becomes nil at the temperature of boiling water. At this temperature the moisture in the fabric is no longer bound, but is freed. It is also known that the viscosity of liquids descreases with an increase of temperature and the heavy oils and vacuum.
  • resin oil are a few of the weatl1erproofing substances that have been successively employed. Some of these substances solidify at a temperature considerably above normal. WVith these substances the surface tension ,of the water-proofing or insulating liquid and the solid or fabric will be maximum at the temperature at which the liquid becomes so nearly solid as to cease to flow under the influence of surface tension.
  • liquid filler which is fluid at ordinary temperatures, because with such a fluid the highest degree of surface tension will be utilized; but some of the substances which solidify at higher temperature possess qualities which are valuable and it may in some cases be desirable to use them.
  • the general mode of application of the process consists of heating the structure to expel moisture and contained air to a tem- I if desired, or coated with another compound which hardens quickly, for the purpose of retaining the liquid filler in the larger interstices.
  • Air pressure may be applied to assist the surface tension of the fabric and liquid and thewhole allowed to cool to-.
  • the process-of treating fabrics to render them moisture-proof which consists of firs heating the fabric to a temperature and at a pressure sufiicient to expel the moisture and contained air, and then submerging the fabric in a suitable fluid, and then cooling the fabric and the fluid, the fabric remaining submerged, to a temperature which is normal or below normal, and at which the surface tension of the fluid and fabric is substantially maximum and then removing the fabric from the fluid.
  • the process of treating fibrous fabrics to render them moisture-proof which consists of first heating them to a temperature and at a pressure sufficient to expel the moisture and contained air without impairing the strength of the fabric, and then submerging the fabric in an insulating fluid, and then cooling the fabric and fluid to a temperature which is normal or below normal, and at which the surface tension of the fluid and fabric becomes substantially maximum, and then removing the fabric from the fluid.
  • the structure to expel moisture and contained air, and then while hot submerging the structure in a bath of hot liquid insulating fluid which will remain fluid at ordinary temperatures, and then cooling the structure and fluid, the structure remaining submerged, until the associated substances reach normal temperatures, whereby the surface tension becomes maximum, and then removing the structure from the liquid.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)

Description

UNITED STATES PATENT OFFICE.
PIERRE KEILHOLTZ, OF BAI'J'IIIIJHIIORE, MARYLAND.
METHOD OF WATERPROOFING FABRICS.
No Drawing.
Specification of letters Patent. Patented J une 13, 1911. Application filed July 9, 1909. Serial No. 506,734.
To all ad/1.0m it may concern:
Be it known that I, PIERRE O. KEILHOLTZ, citizen of the United States of America, residing at the city of Baltimore, State of Maryland, have invented certain new and useful Improvements in Methods of Waterproofing Fabrics, of which the following is a specification.
My invention consists of a method for the elimination of the bound and free moisture and contained air present in fabrics composed of cotton, paper and other materials, and the substitution for the moisture and free air of a liquid which will cause the fabric to be Waterproof; that is to say, which will so fill the voids, interstices and capillaries of the fabric as to prevent the reabsorption of moisture or air, thus rendering the fabric non-hygroscopic and irisulating it if it be used for electrical purposes.
In order that the method may be fully understood, the following explanation is made, reference being had to a cotton textile fabric as an example,-but by'the word fabric I desire to be understood any fabricated structure: a thread, a yarn, a
textile, a combination of textiles, a structure made of metal or metal and textile; in fact, everything'from which it is desired to extract air and moisture and to fill the voids formerly occupied by the air and moisture with a liquid which will serve for waterproofing and insulating purposes.
As is well known, a cotton textile fabric is composed of strandsof cotton, the structure consisting of longitudinal strands interlacing with lateral strands. The strands cannot be woven so tightly that the fabric will have no voids or interstices and the coarser the fabric-that is, the larger the strands-the greater will be the interstices.
, The interstices formed by the intersection of the strands may be considered as voids of the first order-of magnitude. The strands consist of a bundle of fibers twisted together. Several strands may be combined to form a larger strand; The spaces betweenthe adjacent fibers composing the strands andthe spaces between the strands of a single yarn may be considered as voids of a second order of magnitude. The fibers themselves consist of flattened tube-like structures and "the spaces within the fibers, the interior of the tub s, may be considered as voids of a thlrd order of magnitude. It w1ll be readily pereeivedthat the surface of a cotton fabric is of enormous extent when "the internal and external spaces of the fibers composing the fabric are considered.
The superficial energy of a solid and liquid in contact in cases where the liquid does not dissolve the solid depends upon the nature and extent of the surface. When the liquid dissolves the-solid, the surface disappears andthere is no superficial energy. It is known that the molecular activity or energy of a liquid is greatest very close to its surface. It is probable that this increase .of energy is sensible'within a distance of one-thousandth of a millimeter or less from the surface. It is also known that the superficial tension or energy decreases with an increase of temperature and in the case of water becomes nil at the temperature of boiling water. At this temperature the moisture in the fabric is no longer bound, but is freed. It is also known that the viscosity of liquids descreases with an increase of temperature and the heavy oils and vacuum. Particularly is this true of electrical structures which consist of insulated wire, the layers of which are further insulated from each other by layers of insulation. This insulation also insulates thermally., In my proeess I distribute the heat throughout the mass of an electrical structure or fabric by heating the wires of such structure electrically, and thus avoid unequal and excessive local heating. 'The structures may-be heated otherwise, but it is apparent that the process will take longer and not be so effective. The fabric or structure is then placed in a vacuum chamber which is exhausted. vaporization will take place at a temperature corresponding to the pressure.
As above-stated, the superficial tension decooling or liberate it in heating.
creases with an increase of temperature. The viscosity decreases with an increase of temperature and the strength of the fabric decreases with an increase of temperature above the boiling point of water; therefore it is essential, in order that the voids of the second and third magnitude heretofore described shall be completely filled, that the filling material shall be liquid and its fluidity such that it can penetrate these minute spaces at a temperature which will not deteriorate the strengh of the fiber and will be drawn into capillary spaces by the surface tension existing between the solid and the liquid. i
In some of the arts it is important that structures composed in whole or in part of fibrous material shall not respond to changes of humidity or absorb moisture in Textile fabrics aier cardboard ro 3e. cord clothing, insulated wire, electric structures, cotton belting, etc., are a few examples of such structures, which are responsive to the hygrometric quality of the atmosphere. Substances which are fluid, insoluble in water and possess a superficial tension for the solid with which they are in contact, are suitable weather-proofing or water-proofing agents. In some cases, oxidizable oils are employed. Varnishes, boiled linseed oil, cottonseed oil,
resin oil, are a few of the weatl1erproofing substances that have been successively employed. Some of these substances solidify at a temperature considerably above normal. WVith these substances the surface tension ,of the water-proofing or insulating liquid and the solid or fabric will be maximum at the temperature at which the liquid becomes so nearly solid as to cease to flow under the influence of surface tension.
In some cases it will be best to use a liquid filler which is fluid at ordinary temperatures, because with such a fluid the highest degree of surface tension will be utilized; but some of the substances which solidify at higher temperature possess qualities which are valuable and it may in some cases be desirable to use them.
' The general mode of application of the process consists of heating the structure to expel moisture and contained air to a tem- I if desired, or coated with another compound which hardens quickly, for the purpose of retaining the liquid filler in the larger interstices.
The preferred method of impregnating I.
structure. Air pressure may be applied to assist the surface tension of the fabric and liquid and thewhole allowed to cool to-.
gether, the structure remaining submerged, with the result that the most minute voids, as well as the coarser ones of the fabric, will. be completely filled with the insulating liquid and this liquid once in these minute capillary voids will remain there and pre vent the re-absorption of moisture or air, unless it evaporates, which is prevented as above described.
I am aware. that cables composed of conductors covered with hygroscopic materials, such as paper and jute, have been dried electrically in a vacuum chamber and then sealed in a lead sheath or envelop. Also that cables interred in conduits have been dried electrically, the lead sheath being used as a vacuum chamber and a vacuum pump connected to the lead sheath producing the necessary degree of exhaustion. Also that insulated conductors and electrical structures have been boiled at high temperatures in a liquid insulation to remove the moisture, but none of these methods employ my process. I believe I am the first who has attempted to impregnate a fabric or structure composed in whole or in part of fibrous materials at a temperature which will not impair the strength of the fibrous material with a substance that completely fills all the voids or spaces, capillary and intersticial,
by using one of requisite fluidity at a temperature at which the surface tension of maximum.
I do not intend to limit myself to anapplication of my process to the insulation of electric structures or electric insulating material of any sort, because my process is applicable to the impregnation of any fabric with any suitable waterproofing material or insulating liquid for the purpose of rendering the fabric non-hygroscopic.
What I claim and desire to secure by Let-- ters Patent is: I
1. The process-of treating fabrics to render them moisture-proof, which consists of firs heating the fabric to a temperature and at a pressure sufiicient to expel the moisture and contained air, and then submerging the fabric in a suitable fluid, and then cooling the fabric and the fluid, the fabric remaining submerged, to a temperature which is normal or below normal, and at which the surface tension of the fluid and fabric is substantially maximum and then removing the fabric from the fluid.
2. The process of treating fibrous fabrics to render them moisture-proof, which consists of first heating them to a temperature and at a pressure sufficient to expel the moisture and contained air without impairing the strength of the fabric, and then submerging the fabric in an insulating fluid, and then cooling the fabric and fluid to a temperature which is normal or below normal, and at which the surface tension of the fluid and fabric becomes substantially maximum, and then removing the fabric from the fluid.
3. The process of treating fabrics made from hygroscopic fibers to render them nonhygroscopic, which-consists of first treating the fabric under conditions adapted to expel moisture and contained air without impairing the strength of the fabric, and then submerging the fabric while hot in a bath of suitable liquid, fluid at ordinary temperatures, and then cooling the structure while submerged and the liquid to a. normal temperature or one lower than normal whereby the surface tension of the liquid and fabric becomes substantially maximum and then removing the fabric from the liquid.
4. The process of insulating an electric structure containing conductors and insulating fabric, which consists of first heating.
the structure to expel moisture and contained air, and then while hot submerging the structure in a bath of hot liquid insulating fluid which will remain fluid at ordinary temperatures, and then cooling the structure and fluid, the structure remaining submerged, until the associated substances reach normal temperatures, whereby the surface tension becomes maximum, and then removing the structure from the liquid.
5. The process of insulating an electric structure containing conductors and insulating fabric, which consists of first heating the structure to a temperature and at pressure necessary to expel moisture and air, and then while hot submerging the structure in a bath of liquid insulating fluid which will remain fluid at ordinary temperatures, and heating to increase the fluidity of the liquid, and then cooling the liquid and the fabric, the fabric remaining submerged, until a temperature which is normal or below normal is reached, whereby the surface tension between the liquid and the fabric becomes substantially maximum and then removing the fabric from the liquid.
6. The process of treating fibrous fabrics to render them non-hygroscopic, which consists of first heating the structure at a temperature and pressure to expel moisture and permit the withdrawal of contained air, and then submerging the fabric in a bath of liquid weatherproofiing compound, heating to increase the fluidity of the liquid, and then cooling the fabric and liquid, the fabric remaining submerged, until a normal tempera ture or one below normal at which the surface tension between the liquid and the fabric becomes substantially maximum is reached and then removing the fabric from the liquid.
7. The method of insulating electric structures by substituting hygroscopic moisture held in capillaries and upon the surfaces of the fibrous materials composing in part such structure and air contained in the interstices, by an insulating liquid, which consists in assembling the structure with green insulating material, heating the structure and
US1909506734 1909-07-09 1909-07-09 Method of waterproofing fabrics. Expired - Lifetime US994931A (en)

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