US994322A - Case-hardening. - Google Patents

Case-hardening. Download PDF

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US994322A
US994322A US41660208A US1908416602A US994322A US 994322 A US994322 A US 994322A US 41660208 A US41660208 A US 41660208A US 1908416602 A US1908416602 A US 1908416602A US 994322 A US994322 A US 994322A
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carbon
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/74Methods of treatment in inert gas, controlled atmosphere, vacuum or pulverulent material

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  • This invention relates principally to. casehardening'steel and iron articles, especially small articles in bulk.
  • the principal object of the invention is to provide means for producing expeditiously and at low cost case-hardened shells or crusts upon metal articles, especially where it' is desired to leave the articles with relatively soft exteriors for subsequent working with tools, etc.
  • I heat the articles in a suitable retort, and introduce therein a carbon or hydro-carbon in a fluid form and greatly thinned by an inert gas consisting wholly or largely of carbonmonoxid or of carbon-monoxid and hydrogen.
  • I produce the carbon-monoxid in a gas producer by passing a current of compressed air through a body of incandescent charcoal in the producer,.and lead the resultant gases, 2'.
  • the apparatus also preferably comprises an annealing retort, which corresponds generally in structure and mechanical operation to the case-hardening retort, and is con nected to the gas-producer by means of a by-pass around the oil tank, so that annealing and case-hardening may be carried on simultaneously, and so that both retorts may be used for annealing, when desired, by simply first draining the oil tank, so that the gases may pass from the producer through the first retort without taking up any carburizing fluid.
  • an annealing retort which corresponds generally in structure and mechanical operation to the case-hardening retort, and is con nected to the gas-producer by means of a by-pass around the oil tank, so that annealing and case-hardening may be carried on simultaneously, and so that both retorts may be used for annealing, when desired, by simply first draining the oil tank, so that the gases may
  • Fig. 2 is a sectional side elevation
  • Fig. 3 a rear elevation of a water back preferably provided in the door framing at the lower part of the gas producer; although the use of water or steam is optional.
  • Air'under pressure is supplied from a pump or blower 1 through a pipe 2 to an inlet 3 atthe bottom of a gas producer 4, the latter usually in the form of an upright cylindrical body and containing a fire chamber 5,-provided with a refractory lining and surmounting a grate 6, upon which rests a body of incandescent charcoal 7.
  • the carbon-monoxid, nitrogen, and other products of combustion pass up through an outlet 8 and a horizontal outlet 9, and thence down through a vertical pipe 10 havinga ing a body of coke 13 resting upon a grate 14, and cleaned by a spray of water 15 ad mitted into the top ofthe scrubber through a supply pipe 16.
  • the gas passes from the upper part of the scrubber through a pipe 17 down to a tank 18 containing naphtha or other hydro-carbon liquid 19, said liquid supplied from any suitable vessel 20, and the supply being regulated by a valve 21.
  • the bottom ofthe pipe 17 terminates at the bottom of the tank 18 in the form of a spray 22, so that gas bubbles pass up through the naphtha I and escape drawings, Figure 1' communication 11 with the lower end of a scrubber 12 of the usual type and containfrom the tank through a pipe 23 which opens into the top of the tank.
  • the pipe 23 is connected by a gland at- 24: to a pipe 25 leading into a revoluble retort 26 mounted within a furnace 27 having controlled burn ers 28 for air and gas,- and also having a of the general construction illustrated in my acts as a carrier for the carburizing vapor taken up from the oil tank.
  • articles case-hardened by this method have relatively soft cases or shells, so that they may be readily cut by tools or filed or drilled, or otherwise operated upon or treated, mechanically or otherwise.
  • the blower 1 or other apparatus supplies pressure to force the current steadily or uniformly through the entire apparatus and out from the vent 29. Moreover, the air supplied by the blower is converted into nitrogen and carbon-monozid, the carbon ionoxid performing the function already set forth, and the nitrogen being itself a valuable agent in the process of case-hardening.
  • the pipe 23 may be provided with a pressure gage 31, and the tank 18 may be provided with a gage glass 32 and a petcock 33 for draining the tank.
  • the outlet 8 communicates with the top of the fire chamber 5 in the gas-producer 4, and is arranged centrally of said chamber, to induce an even consumption of the charcoal 7 therein.
  • Said outlet is surmounted by a hopper 34 for the fuel, a gate 35 being provided between the hopper and the outlet 8.
  • a gate 35 being provided between the hopper and the outlet 8.
  • In the side of the latter is formed or provided 'a short horizontal pipe 36 from which the pipe 9 leads; and a vent 37 also leads from 36 up to a chimney.
  • a gate or valve 38 in the ipe 9 is closed and a valve 39 in the pipe 3 is opened when the charcoal 7 is being ignited; and after such ignition 39 is closed and 38 is opened.
  • the outlet 36 has been connected directly to the side of the retort at its upper end; but this has been found to cause uneven combustion of the fuel charge, and to be otherwise objectionable.
  • These objections are overcome by connecting the part 36 to the pipe 8 above the body of the producer, and arranging the pipe 8 at the middle of the fire chamber, as shown.
  • a water back in the form of a receptacle 40 may be cast upon the inner side of the framing 41 of the usual door 42 in the bottom of the gas producer, said receptacle 40 having at its upper portion openings 43 into the fire chamber of the gas-producer.
  • the water is supplied from a feed glass 44 through a pipe 45; a valve 46 being provided to regulate the flow of the water; the parts 44, 45, 46 resembling in construction the usual sight feed for supplying oil to steam engines, etc.
  • the water back 40 becomes sufficiently heated to vaporize the water 49 therein, and the vapor passes up through and is decomposed by the incandescent charcoal, the oxygen uniting with the carbon to form carbon-monoxid, and the hydrogen mixing with the products of combustion and thinning the same, thus reducing the cost of the carrier for the carburizing fluid, and gaining other advantages.
  • a safety valve 47 controlled by a weight 48 may be provided upon the end of the pipe 3, to afford a vent in case of explosion within the apparatus.
  • the apparatus also preferably includes a second retort 50 in a furnace 51, corresponding to the described parts 26 and 27, and connected to the pipe 17 by means of a bypass 52 around the oil tank 18.
  • the gas from the gas producer (either with or without the steam-produced gases), may be caused to flow slowly through the retort 50 while the articles therein are being annealed, to avoid liability of oxidizing the articles, the carbon-monoxid, nitrogen and hydrogen being inert or neutral.
  • a valve 53 in the by-pass 52 may be closed, and a valve 54 in the pipe 23 may be opened when the case hardening retort 26 is in operation; and 54 may be closed and 53 opened when the retort 50 is in operation, or both valves 53 and 54 may be left open when it is desired to case harden and anneal at the same time. If it is desired to anneal simultaneously in both retorts 50 and 26, it is only necessary to leave open both valves 53 and 54, first draining the oil from the tank 18, so that the annealing gas passing through said tank shall not take up any carburizing fluid.
  • retort having a vent, means connected there-- to for compressing air and producing carbon-monoxid and nitrogen therefrom, and an intermediate oil tank through which the gases from the gas producing means pass on their way to the retort; the connection .being continuous from said compressing former to force the carburizing gas to flow through the retort.
  • a case-hardening retort having a vent, means'connected thereto for producing carbon monoxid and nitrogen from air, including means for compressing the air, an intermediate oil tank through which the gases from the gas-producing means pass on their way to the retort, and a scrubber between the oil tank and the gasproducing means; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
  • connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
  • a carburizing retort having a vent, of a gas-producer, means for compressing air and supplying it to be converted into carbon monoxid and nitrogen, means independent of said air compressing means for also generating steam in the gas-producer to pass through its fire chamber, and means between the gas-pro ducer and the retort for charging the resultant gas with carburizing fluid; the connection being continuous from said compressing meansto said vent, to enable the former to force the carburizing gas to flow through the retort.
  • the combination with an apparatus for producing carbon-monoxid including means for compressing air, of a retort provided with heating means and connected to said producing apparatus, an oil tank connected between the producing means and the retort, so that thecarbon-monoxid passes through the oil in flowing to the retort, and a retort provided with heating means and connected to said producing apparatus by means of a by-pass around said tank; valves being provided one in said by-pass and one between the first retort and the by-pass; said air-compressing means being in open communication with both of said retorts, to force the gas therethrough.
  • a retort rovi e wit heatin means and connected to said producing pparatus by ADOLPH MAOHLET' means of a by-pass around said tank; valves Witnesses: being provided one in said by-pass and one SAMUEL R. OGDEN, between the first retort and the by-pass; JOHN J. Soo'rr.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)

Description

A. W. MAGHLET.
CASE HARDENING.
2111011131011 FILED FEB. 1a, 1908.
994,322, Patented June 6, 1911.
$258818.- I QQ nvmvrom ATTORNEY UNITED sT tpEs PATENT OFFICE CASE-HARDENING.
Specification of Letters Patent.
Patented June 6, 1911.
Application filed February 18, 1908. SeIiaI No. 416,802.
To all whom it may concern:
Be itknown that I, AooLrrr W. MACHLET,
I a citizen of the United States, residing in Elizabeth, in the county of Union and State of New Jersey, have invented certainnew and useful Improvements in Case-Hardening, of which the following is a specification.
This invention relates principally to. casehardening'steel and iron articles, especially small articles in bulk.
The principal object of the invention is to provide means for producing expeditiously and at low cost case-hardened shells or crusts upon metal articles, especially where it' is desired to leave the articles with relatively soft exteriors for subsequent working with tools, etc. To these ends, I heat the articles in a suitable retort, and introduce therein a carbon or hydro-carbon in a fluid form and greatly thinned by an inert gas consisting wholly or largely of carbonmonoxid or of carbon-monoxid and hydrogen. I produce the carbon-monoxid in a gas producer by passing a current of compressed air through a body of incandescent charcoal in the producer,.and lead the resultant gases, 2'. 6., carbon-monoxid, nitrogen, etc, through a body of naphtha or oil, whereby the gases become charged with hydro-carbon vapor, and pass slowly through the retort. The hydro-carbon vapor is the oarburizing agent. When desired, steam may be introduced or generated in the fire-chamber of the gas-producer, in which it is decomposed, the oxygen uniting with the carbon to form additional carbon-monoxid, and the hydrogen (itself inert) serving to thin the carbon-monoxid.
The apparatus also preferably comprises an annealing retort, which corresponds generally in structure and mechanical operation to the case-hardening retort, and is con nected to the gas-producer by means of a by-pass around the oil tank, so that annealing and case-hardening may be carried on simultaneously, and so that both retorts may be used for annealing, when desired, by simply first draining the oil tank, so that the gases may pass from the producer through the first retort without taking up any carburizing fluid.
In the accompanying is a diagrammatic elevation of an apparatus for carrying out the several features of. my invention. Fig. 2 is a sectional side elevation, and Fig. 3 a rear elevation of a water back preferably provided in the door framing at the lower part of the gas producer; although the use of water or steam is optional.
Air'under pressure is supplied from a pump or blower 1 through a pipe 2 to an inlet 3 atthe bottom of a gas producer 4, the latter usually in the form of an upright cylindrical body and containing a fire chamber 5,-provided with a refractory lining and surmounting a grate 6, upon which rests a body of incandescent charcoal 7.
The carbon-monoxid, nitrogen, and other products of combustion pass up through an outlet 8 and a horizontal outlet 9, and thence down through a vertical pipe 10 havinga ing a body of coke 13 resting upon a grate 14, and cleaned by a spray of water 15 ad mitted into the top ofthe scrubber through a supply pipe 16. Y The gas passes from the upper part of the scrubber through a pipe 17 down to a tank 18 containing naphtha or other hydro-carbon liquid 19, said liquid supplied from any suitable vessel 20, and the supply being regulated by a valve 21. The bottom ofthe pipe 17 terminates at the bottom of the tank 18 in the form of a spray 22, so that gas bubbles pass up through the naphtha I and escape drawings, Figure 1' communication 11 with the lower end of a scrubber 12 of the usual type and containfrom the tank through a pipe 23 which opens into the top of the tank. The pipe 23 is connected by a gland at- 24: to a pipe 25 leading into a revoluble retort 26 mounted within a furnace 27 having controlled burn ers 28 for air and gas,- and also having a of the general construction illustrated in my acts as a carrier for the carburizing vapor taken up from the oil tank. I have also found that articles case-hardened by this method have relatively soft cases or shells, so that they may be readily cut by tools or filed or drilled, or otherwise operated upon or treated, mechanically or otherwise.
The blower 1 or other apparatus, supplies pressure to force the current steadily or uniformly through the entire apparatus and out from the vent 29. Moreover, the air supplied by the blower is converted into nitrogen and carbon-monozid, the carbon ionoxid performing the function already set forth, and the nitrogen being itself a valuable agent in the process of case-hardening.
The pipe 23 may be provided with a pressure gage 31, and the tank 18 may be provided with a gage glass 32 and a petcock 33 for draining the tank.
The outlet 8 communicates with the top of the fire chamber 5 in the gas-producer 4, and is arranged centrally of said chamber, to induce an even consumption of the charcoal 7 therein. Said outlet is surmounted by a hopper 34 for the fuel, a gate 35 being provided between the hopper and the outlet 8. In the side of the latter is formed or provided 'a short horizontal pipe 36 from which the pipe 9 leads; and a vent 37 also leads from 36 up to a chimney. A gate or valve 38 in the ipe 9 is closed and a valve 39 in the pipe 3 is opened when the charcoal 7 is being ignited; and after such ignition 39 is closed and 38 is opened. Heretofore, the outlet 36 has been connected directly to the side of the retort at its upper end; but this has been found to cause uneven combustion of the fuel charge, and to be otherwise objectionable. These objections are overcome by connecting the part 36 to the pipe 8 above the body of the producer, and arranging the pipe 8 at the middle of the fire chamber, as shown.
If desired, a water back in the form of a receptacle 40 may be cast upon the inner side of the framing 41 of the usual door 42 in the bottom of the gas producer, said receptacle 40 having at its upper portion openings 43 into the fire chamber of the gas-producer. The water is supplied from a feed glass 44 through a pipe 45; a valve 46 being provided to regulate the flow of the water; the parts 44, 45, 46 resembling in construction the usual sight feed for supplying oil to steam engines, etc. The water back 40 becomes sufficiently heated to vaporize the water 49 therein, and the vapor passes up through and is decomposed by the incandescent charcoal, the oxygen uniting with the carbon to form carbon-monoxid, and the hydrogen mixing with the products of combustion and thinning the same, thus reducing the cost of the carrier for the carburizing fluid, and gaining other advantages.
Excellent results in ordinary work are gained without steam or hydrogen, thus rendering the water back undesirable except in unusual cases.
A safety valve 47 controlled by a weight 48 may be provided upon the end of the pipe 3, to afford a vent in case of explosion within the apparatus.
The apparatus also preferably includes a second retort 50 in a furnace 51, corresponding to the described parts 26 and 27, and connected to the pipe 17 by means of a bypass 52 around the oil tank 18. The gas from the gas producer, (either with or without the steam-produced gases), may be caused to flow slowly through the retort 50 while the articles therein are being annealed, to avoid liability of oxidizing the articles, the carbon-monoxid, nitrogen and hydrogen being inert or neutral. A valve 53 in the by-pass 52 may be closed, and a valve 54 in the pipe 23 may be opened when the case hardening retort 26 is in operation; and 54 may be closed and 53 opened when the retort 50 is in operation, or both valves 53 and 54 may be left open when it is desired to case harden and anneal at the same time. If it is desired to anneal simultaneously in both retorts 50 and 26, it is only necessary to leave open both valves 53 and 54, first draining the oil from the tank 18, so that the annealing gas passing through said tank shall not take up any carburizing fluid.
Variations may be resorted to within the scope of the invention, and portions of the improvements may be used without others.
Having thus described my invention, I claim:
1. The combination with an apparatus for compressing air and producing carbon-monoxid therefrom, of a case-hardening retort having a vent and provided with heating means and connected to said producing apparatus, and an oil tank connected between the producing means and the retort, to cause the carbon-monoxid to pass through the oil in flowing to the retort; the connection being contiuous from said air compressing apparatus to said vent, to enable the former to force the carburizing gas to flow through the retort.
retort having a vent, means connected there-- to for compressing air and producing carbon-monoxid and nitrogen therefrom, and an intermediate oil tank through which the gases from the gas producing means pass on their way to the retort; the connection .being continuous from said compressing former to force the carburizing gas to flow through the retort.
5. The combination of an oil tank, a gas producer, means for compressing air and supplying it to said gas-producer to be converted into carbonmonoxid and nitrogen, a pipe leading from said gas-producer and having an outlet within the oil tank near the bottom'thereof, acase-hardening retort -provided with heating means and having a vent, and a pipe leading from the upper part of said oil tank to said retort; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
6. The combination of an oil tank, a gasproducer having an outlet into the lower portion of the oil tank, means for compressing air and supplying it to said gas ducer, and a case-hardening retort provided with heating means and having a constricted vent and in communication with the oil tank at the upper portion thereof; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
7. The combination of a case-hardening retort having a vent, means'connected thereto for producing carbon monoxid and nitrogen from air, including means for compressing the air, an intermediate oil tank through which the gases from the gas-producing means pass on their way to the retort, and a scrubber between the oil tank and the gasproducing means; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
8. The combination of a case-hardening retort having a constricted vent, a gas-producer in communication with said retort, an oil tank between said gas-producer and said retort, and a scrubber between the oil tank and the gas-producer; means being provided to supply air under pressure to the gas-producer to be converted thereby in carbon monoxid and nitrogen, to flow through said retort.
9. The combination with a case-hardening retort having a vent, of an apparatus connected thereto for compressing airand converting it into carbon-monoxid and nitrogen, and supplying it to the retort, and means for supplying hydro-carbon vapor to the retort simultaneously with the gas; the connection being continuous from said compressing meansto said vent, to enable the former to force the carburizing gas to flow through the retort.
10. Thecombination with a case-hardening retort having a vent, of an, apparatus connected thereto for compressing air and converting it into carbon-monoxid and nitrogen and supplying it to the retort, and
means for charging the gas with hydroable the former to force the carburizing gas to flow through the retort.
11. The combination with an apparatus, inclusive of a device for compressing air, for producing carbon-monoxid and hydrogen from air, of a case-hardening retort having a vent and provided with heating means and connected to said producing apparatus, and an oil tank connected between the producing means and the retort, to cause the carbon-monoxid and nitrogen to pass through the oil in flowing to the retort; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
12. The combination with an apparatus, inclusive of a device for compressing air, for producing carbon-monoxid and nitrogen from air, of a case-hardening retort having a vent and rovided with heating means and connected to said. producing apparatus, an oil tank connected between the producing means and the retort, to cause the carbon-monoxid and nitrogen to pass through the oil in flowing to the retort, and means independent of said compressing means, for
simultaneously supplying hydrogen to said retort; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
\ 13. The combination with a carburizing retort having a vent, of a gas-producer, means for compressing air and supplying it to be converted into carbon monoxid and nitrogen, means independent of said air compressing means for also generating steam in the gas-producer to pass through its fire chamber, and means between the gas-pro ducer and the retort for charging the resultant gas with carburizing fluid; the connection being continuous from said compressing meansto said vent, to enable the former to force the carburizing gas to flow through the retort.
14. The combination of a case-hardening retort having a constricted vent, a gas-producer connected thereto, means for compressing and supplying air to said gas-pro ducer, means independent of said air-compressing means for generating steam in said gas-producer and passing it through the firechamber thereof, and an intermediate oil tank through which the gases from the gas producer pass on their way to the retort; the connection being continuous from said compressing means to said vent, toenable the former to force the carburizing gas to .flow through the retort.
15. The combination of a case-hardening retort having a constricted vent, a gas-producer connected thereto, means for producing steam in the gas-producer to mingle with the gas, and an intermediate oil tank through which the gas from the gas-producer passes on its way to the retort; the gas-producer connected to a source of supply of air under pressure independently of said steam-producing means.
16. The combination with a retort, of a gas-producer connected thereto, means for compressing air and supplying it to the gasproducer, means for supplying carburizing fluid to the retort simultaneously with the gas from the gas-producer, means independent of said air-compressing means for producing steam in the gas-producer to mingle with the as, and means for regulating the amount 0 steam produced; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
17. The combination with a retort, of a gas-producer connected thereto, means for compressing air and supplying it to the gasproducer, means for supplying carburizing fluid to the retort simultaneously with the gas from'the gas-producer; the fire-chamber of the gas-producer having a water receptacle in which steam originates to pass through the incandescent mass in .the gas producer, and a regulatable water feed to supply the same; the connect-ion being continuousfrom said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
18. The combination of a case-hardening said com ressing means to said vent, to enable the ormer to force the carburizing gas to flow through the retort.
19. The combination with a case-hardening retort having a vent, of means for producing carburizing gas from fuel and air, including means for compressing the air, means for thinning the gas and passing it through the retort, and means for simultaneously supplying carburizing fluid to the retort; the connection being continuous from said compressing means to said vent, to enable the former to force the carburizing gas to flow through the retort.
20. The combination of an annealing retort having a constricted vent, a gas-producer in communication with said retort, and a scrubber between the retort and the gas producer; means being provided to compress air and conduct it to the gas-producer, to be converted into the products of incomplete combustion and to flow through said retort; the connection being continuous from said compressin means to said vent, to enable the former to orce the carburizing gas to flow through the retort.
21. The combination with an apparatus for producing carbon-monoxid, including means for compressing air, of a retort provided with heating means and connected to said producing apparatus, an oil tank connected between the producing means and the retort, so that thecarbon-monoxid passes through the oil in flowing to the retort, and a retort provided with heating means and connected to said producing apparatus by means of a by-pass around said tank; valves being provided one in said by-pass and one between the first retort and the by-pass; said air-compressing means being in open communication with both of said retorts, to force the gas therethrough.
22. The combination with an apparatus for producing carbon-monoxid, including means for compressing air, of a retort provided with heating means and connected to said producing apparatus, an oil tank conmeans being provided for drainin the oil 10 nected between the producing means and the tank; said air-compressing means eing in retort, so that the carbon-monoxid passes open communication with both of said rethrough the oiiiig flowling to the retort, and torts, to force the gas therethrough.
a retort rovi e wit heatin means and connected to said producing pparatus by ADOLPH MAOHLET' means of a by-pass around said tank; valves Witnesses: being provided one in said by-pass and one SAMUEL R. OGDEN, between the first retort and the by-pass; JOHN J. Soo'rr.
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