US991232A - Explosive. - Google Patents
Explosive. Download PDFInfo
- Publication number
- US991232A US991232A US37748907A US1907377489A US991232A US 991232 A US991232 A US 991232A US 37748907 A US37748907 A US 37748907A US 1907377489 A US1907377489 A US 1907377489A US 991232 A US991232 A US 991232A
- Authority
- US
- United States
- Prior art keywords
- explosive
- dynamite
- nitrate
- ammonia
- chlorate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 18
- DVARTQFDIMZBAA-UHFFFAOYSA-O ammonium nitrate Chemical compound [NH4+].[O-][N+]([O-])=O DVARTQFDIMZBAA-UHFFFAOYSA-O 0.000 description 8
- 235000012054 meals Nutrition 0.000 description 6
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000003245 coal Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 2
- 235000018783 Dacrycarpus dacrydioides Nutrition 0.000 description 2
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 2
- 239000000006 Nitroglycerin Substances 0.000 description 2
- 235000008578 Pinus strobus Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229960003711 glyceryl trinitrate Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241001463064 Junea Species 0.000 description 1
- 240000007263 Pinus koraiensis Species 0.000 description 1
- 240000007320 Pinus strobus Species 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
Definitions
- the invention relates to high explosives equaling in strength the higher per cents. of standard dynamite.
- Black powder for blasting purposes is not of suflicient strength for most rock work, and is not capable of throwing out the tougher kinds of coal and slate often accompanying the same. It also shatters the softer grades of coal and renders much of it unsalable. It emits an offensive gas and causes such an obscuring smoke as toseriously interfere with the workmen. It also is liable by its excessive flame to set off any damp or explosive gasthat may be lurking in themine, causing. often great destruction to life and property. It is also more or less dangerous with respect .to transporting and storing, as it may be easily set off by a spark or fire.
- Dynamite as generally known and used is open to many objections. It freezes at fortyfive degrees temperature, and when frozen will not explode or detonate, and is practi- The thawing of it out is attended often with great inconvenience and hazard. In hot weather, the nitroglycerin in 'dvnamite is likely to exude from the absorbent, which makes it exceedingly dangerous to handle or transport. If not properly made and thoroughly neutralized, which is very likely to lee-the case because of unaware or careless employees, decomposition is likely to set in, which has frequently been the cause of most frightful accidents.
- Dyna mite is also liable to be detonated by a sad den jolt or shock, and as a result serious accidents often happen with the best grades of dynamite, apparently without cause or explanation. All of these objectionable features are intensified as the per cents. of strength of dynamite are increased, so that when it is made to contain a large amount of nitroglycerin, reaching as high as seventyfive or eighty per cent. or more, it exudes Specification of Letters Patent.
- This formula gives a strength of about sixty per cent. dynamite, the quantities of each being equal.
- the nitrate of ammonia has great explosive force because of its capacity for rapid and extensive production of gas, while the combination of chlorate of potassium and mirbane oil is capable of great explosive force because easily susceptible of detonation.
- the mirbane oil or the pasty condition of the explosive due to its use serves as a protection to the nitrate of ammonia, Which rapidly deteriorates when exposed to .the atmosphere. precaution, however, it is preferred to pack this explosive, when prepared and ready for use, in hermeticallysealed cases.
- the Wood meal is added to lighten the mixture, to furnish necessary carbon and to quicken the flame by aiding in its rapid distribution. Wood meal prepared from White pine is preferred.
- the solids consisting of the nitrate of ammonia, chlorate of potassium and Wood meal, after being pulverized, are thrown together in a mixer in approximately the proportions above designated, then the ten per cent. of nitro-benzene is poured over the mass, and all are thoroughly Worked into one substance, after which the explosive is packed in cartridges, ready for use. When used it is fired by means of a primer as in the use of dynamite.
- An explosive compound consisting of a As a further mixture of nitrate of ammonia, chlorate of potassium, mirbane oil, and Wood meal.
- An explosive compound containing the following ingredients in substantially the proportions indicated, nitrate of ammonia fifty per cent, chlorate of potassiumthirty per cent, mirbaneoil ten per cent, and Wood meal ten per cent.
- An explosive compound consistin of nitrate of ammonia, chlorate of potassium, finely divided cellulose, and mirbane oil all in a thoroughly intermixed mass.
- An explosive compound consisting of nitrate of ammonia, potassium chlorate,
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
' which the following is a full, clear, and
' cally useless.
. ED srarns rnrnn'r carton.-
GERSHOM IVIOOBE PETERS, CINCINNATI, AND MILTON FLETCHER LINDSLEY, 0F KINGS MILLS, OHIO, ASSIGNORS TO THE KING POWDER COMPANY, OF CINCINNATI,
0310, A conronarronor omo.
nxrrosrvn.
No Drawing.
To all whom it may concern:
Be it known that we, Gnns oM M. lnrnns, residing at Cincinnati, county of Hamilton, and State of Ohio, and MILTON F. LINDSLEY, residing at Kings Mills, county of lVarren, and State of Ohio, both citizens of, the Uited States, have invented certain new and useful Improvements in Explosives, of
exact specification.
The invention relates to high explosives equaling in strength the higher per cents. of standard dynamite.
Black powder for blasting purposes is not of suflicient strength for most rock work, and is not capable of throwing out the tougher kinds of coal and slate often accompanying the same. It also shatters the softer grades of coal and renders much of it unsalable. It emits an offensive gas and causes such an obscuring smoke as toseriously interfere with the workmen. It also is liable by its excessive flame to set off any damp or explosive gasthat may be lurking in themine, causing. often great destruction to life and property. It is also more or less dangerous with respect .to transporting and storing, as it may be easily set off by a spark or fire.
Dynamite as generally known and used is open to many objections. It freezes at fortyfive degrees temperature, and when frozen will not explode or detonate, and is practi- The thawing of it out is attended often with great inconvenience and hazard. In hot weather, the nitroglycerin in 'dvnamite is likely to exude from the absorbent, which makes it exceedingly dangerous to handle or transport. If not properly made and thoroughly neutralized, which is very likely to lee-the case because of ignorant or careless employees, decomposition is likely to set in, which has frequently been the cause of most frightful accidents. Dyna mite is also liable to be detonated by a sad den jolt or shock, and as a result serious accidents often happen with the best grades of dynamite, apparently without cause or explanation. All of these objectionable features are intensified as the per cents. of strength of dynamite are increased, so that when it is made to contain a large amount of nitroglycerin, reaching as high as seventyfive or eighty per cent. or more, it exudes Specification of Letters Patent.
Patented May 2, mil.
Application filed June (i, 1907. Serial No. 377,489.
more readily, is more sensitive, and is much more powerful in its destructive energy.
It is the object of our invention to furnish "an improved explosive equaling in strength the higher per cents. of dynamite, which will at the same time be safe to handle and transport, and which will not freeze or exude, or spontaneously detonate.
Aside from the risks and liabilities in handling and in using dynamite, it is objectionable for many kinds of work, as, for example, coal mining, as it is too violent and is found to shatter too much of the coal; also in close mining or tunnel work the air becomes speedily impregnated with offensive and poisonous gases from the explosive materials, making it impossible or dangerous at't-imes for men to work. It is also found that the shocks from such explosives are so severe that they stir up all the latent gases in the mines, and also cause secondary explosions of a serious nature; and a farther object of the invention is to produce an improved form of explosive equaling in strength the higher per cents. of dynamite, but in which these objectionable features last mentioned are reduced to the minimum. To accomplish. this purpose'a combination of three ingredients, which have heretofore been used to some extent. in certain combina tions in the production of explosive compounds, is used. These ingredients consist of nitrate of ammonia, chlorate of potassium, and mirbane oil. To these'ingredients a certain amount of any suitable cellulose fiber as wood meal preferably made from white pine is added in order to lighten up themass and aid in the rapid transmission of heat Making a total of 100 per cent.
This formula gives a strength of about sixty per cent. dynamite, the quantities of each being equal. The nitrate of ammonia has great explosive force because of its capacity for rapid and extensive production of gas, while the combination of chlorate of potassium and mirbane oil is capable of great explosive force because easily susceptible of detonation. The mirbane oil or the pasty condition of the explosive due to its use serves as a protection to the nitrate of ammonia, Which rapidly deteriorates when exposed to .the atmosphere. precaution, however, it is preferred to pack this explosive, when prepared and ready for use, in hermeticallysealed cases. The Wood meal is added to lighten the mixture, to furnish necessary carbon and to quicken the flame by aiding in its rapid distribution. Wood meal prepared from White pine is preferred. The solids, consisting of the nitrate of ammonia, chlorate of potassium and Wood meal, after being pulverized, are thrown together in a mixer in approximately the proportions above designated, then the ten per cent. of nitro-benzene is poured over the mass, and all are thoroughly Worked into one substance, after which the explosive is packed in cartridges, ready for use. When used it is fired by means of a primer as in the use of dynamite.
We claim:
' 1. An explosive compound consisting of a As a further mixture of nitrate of ammonia, chlorate of potassium, mirbane oil, and Wood meal.
2. An explosive compound containing the following ingredients in substantially the proportions indicated, nitrate of ammonia fifty per cent, chlorate of potassiumthirty per cent, mirbaneoil ten per cent, and Wood meal ten per cent.
8. An explosive compound consistin of nitrate of ammonia, chlorate of potassium, finely divided cellulose, and mirbane oil all in a thoroughly intermixed mass.
4:. An explosive compound consisting of nitrate of ammonia, potassium chlorate,
finely divided cellulose, all intermixed With mirbane oil. to render the mass plastic.
In testimony whereof We have signed our names to this specification, 1n the presence of subscribing Witnesses, on this 3d day of JuneA D. 1907.
' GERSHOM MOORE PETERS. MILTON FLETCHER LINDSLEY.
I Witnesses: I
ELDON R. JAMES, A. W. BEEKLEY, ED FROHLIGER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37748907A US991232A (en) | 1907-06-06 | 1907-06-06 | Explosive. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37748907A US991232A (en) | 1907-06-06 | 1907-06-06 | Explosive. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US991232A true US991232A (en) | 1911-05-02 |
Family
ID=3059568
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US37748907A Expired - Lifetime US991232A (en) | 1907-06-06 | 1907-06-06 | Explosive. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US991232A (en) |
-
1907
- 1907-06-06 US US37748907A patent/US991232A/en not_active Expired - Lifetime
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