US979434A - Apparatus for use in the manufacture of artificial-silk and like threads. - Google Patents

Apparatus for use in the manufacture of artificial-silk and like threads. Download PDF

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US979434A
US979434A US50076209A US1909500762A US979434A US 979434 A US979434 A US 979434A US 50076209 A US50076209 A US 50076209A US 1909500762 A US1909500762 A US 1909500762A US 979434 A US979434 A US 979434A
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spindle
stem
frame
pump
nozzle
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US50076209A
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James Clayton
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Samuel Courtauld and Co Ltd
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Samuel Courtauld and Co Ltd
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/06Wet spinning methods

Definitions

  • This invention relates pr ncipally to ap paratus whereby artificial silk, and like threads, are produced by precipitating mat-.
  • ter such as a viscous preparation of cellu lose, such as viscose, (we will, for the purose of description, refer to it as viscose)
  • a viscous preparation of cellu lose such as viscose
  • viscose a viscous preparation of cellu lose
  • perforatlons n a nozzle to form a number of filaments which are twisted together to hitherto and whereby the spinning, or twistpositive gearing driving the the action of the pump ing, of the filaments into thread is eificiently effected as the filaments issue from the orifices in the forming nozzle into the setting medium, or bath.
  • the stem, or spindle is carried on a swinging frame
  • the pump is also so mounted on the said frame that it can be swung thereon to disengage the gear which drives it and so stop when desiredindependently of the swinging of the said frame, so that, while the frame can-be swung to' put the stem, or spindle, in and out of gear without affecting the driving of the pump, when desired both can be put into and out of ear simultaneously.
  • the said frame carries the filter and the various parts are erforated for the passage of the viscose mm the viscose pipe to the pump and from the pump through the filter and frame to the stem, or s indle, and thence to the nozzle.
  • the thread w ich is formed by the spinning
  • a winding reel or the equivalent, provided with means for. driving it and preferably also with means for 1aying the thread as it is wound, and the said reel,
  • the driving means. for the'75 the stem, or spindle, and the reel, are geared together so that they have the required relative speeds, which can be altered ifvdesired by change wheels.
  • ment is preferably such as to include a numher of devices as described, arranged in two rows back to back.
  • Figure 1 is an end elevation, Flg. 2 a
  • Fig. 4 1s a sec tion of one of the rotatable nozzles and lts stem, or spindle, and means for supplyin viscose thereto, and of one of the pumps an the driving gear in connection with the said ump and stem, or-"spindle.
  • Fig. 5 is an end view of the frame carrying the pump and stem, or spindle
  • Fig. 6 is a section showing a pum and stem, orspindle, in position in such ame and the supportin bracket.
  • Fig. 7 is a longitudinal section s lowing the gear by which the stems, or spindles, are driven.
  • the arrangement illustrated shows two baths with six arrangements of nozzles and pumps in connection with each. but it 18 side elevation (with some of the pumps and to be understood that one bath, or any number of baths, and one pumand nozzle, or
  • any-number of pumps an nozzles can be used with each bath.
  • a suitable framework 1 On a suitable framework 1, are carried two setting baths 2, parallel with each other, and outward of these baths are standards 3, for a driving shaft 4, each shaft 4 carrying friction wheels 5, one for drivin eachstem, or spindle, of the squirting nozz es, as hereinafter described.
  • brackets 6 carrying a pumpdriving shaft 7, geared at the end, preferably by change gear 8 (see Fig. 1) to the driving shaft 4.
  • worms 9 On this pump-driving shaft 7 are worms 9, one for each pump.
  • a pipe 10 for the supply of viscose runs along each side of the machine and to each of these pipes 10, opposite each of the worms 9,
  • the sa-id'frame preferably consisting of two arms, 12 and 13, .and two cross-pieces 14 and 15.
  • the said frame can be swung on, or in,- the said bearings as centers.
  • bearings respectively in one of the said arms (that marked 13) and'in the bracket 11, secured to the viscose supply pipe 10, is carried the pump 16, so that it can be swung in these bearings as centers.
  • the arms 13 each carry a filter 17.
  • the upper cross-piece 14, between the arms 12 and 13, carries, in a clamp 18, one end of the casing 33, with a bearing for one end of the stem, or spindle, 19, terminating in the nozzle 20, through which the viscose is squirted into the bath.
  • the stem, or spindle, 19 of the nozzle 20 carries around it, preferably near the ,midpart of its length, a quick-threaded worm 21, which engages with a worm-wheel 22, carried on a spindle 23, mounted in bearings 24 (preferably ball bearings) carried by a casing 25, which is secured to the lower cross-piece between the aforesaid arms 12 and 13.
  • the said worm-wheel 22 has formed on, or fixed to, it a friction wheel 26 which, when the frame is swung toward the bath, bears against the corresponding friction wheel 5, carried by the driving shaft 4.
  • bracket 11 which carries the aforesaid frame, through the erforations 29, to the pump 16, and there rom through a perforation 30 in one of the arms and through the filter17, and therefrom through a perforation 31 in the upper cross-piece 14 of the frame into a chamber 32 in a piece 41 rease in the casing 33 which piece carries the adjustable bearing for one end of the stem, or spindle, of the nozzle, and thence by the lateral perforations 34, in the said bearing of the stem, or spindle, into the longitudinal perforation 35 in the stem, or spindle, which thus communicates at one end with the said chamber 32, and, at the other end, with the nozzle 20.
  • the stem, or spindle, 19 which carries the nozzle may be carried in bearings in its casing in any suitable way,'for example, as shown in Fig.4, the end of the casing nearest the nozzle 20 may have a ball-seating 36, secured to it, and another ball-seating 37 secured to the stem, or spindle, 19, antifriction balls being interposed between these seatings, andthe end of the stem, or spindle, 19, at which the viscose enters may be made with a conical seating 38, into which enters a correspondingly coned end 39 of a screw 40, perforated to a sufiicient extent to form a continuation of the perforation 35, in the stem, or spindle, to the chamber 32, through the transverse perforations 34, the said screw 40 being screwed through the piece 41 in the end of the casing 33 of the stem, or spindle, so that the bearing can be readily adjusted.
  • the baths2the framework of the machine carries standards 45 with bearings in which a reel-driving shaft 46 is mounted, this shaft 46 being driven by gearing 47 and 48 (connected by the inclined shaft 49) from one of the driving shafts 4 from which one series of the rotary nozzles and stems, or spindles, and pumps derive motion as aforesaid.
  • gearing 47 and 48 connected by the inclined shaft 49
  • the driving is effected by making the extensions from alternate standards 45 in the form of hollow casings, as shown in Fig. 3, and carrying a short spindle 5.6 at the outer end of each such casing.
  • the ends of the said short spindle which project from the casing each carry a friction, or gear, wheel 60 driving two adjacent reels by contact, or engagement, with friction, or gear, wheels 61 on the axes of the said reels.
  • the driving frame, a perforated bearing piece'opening shown at 62) may be operated in proximity with each reel for properly laying the of the reels atone side is effected through I. an intermediate wheel so that the reels on the respective sides rotate in opposite directions.
  • thread-layers such as those thread-being wound thereon.
  • the thread layers 62 are shown as being caused to swing by means of an eccentric 66 on the inclined shaft 49, the said eccentric being connected by a strap and rod 67 to a bar 68 to which the said thread-layers 62 are connected in any suitable manner.
  • the arrangement described for winding directly onto reels may be varied, for instance the thread may be wound onto bobbins driven as described withregard to the reels, or the thread may be coiled in suitable receptacles, by a coiling arrangement, or be otherwise dealt with to prepare it for subsequent treatment.
  • Trays may be arranged in any suitable position (as at 63 for-instance) to catch any viscose which may drop from the-nozzles, or be expelled therefrom, when they are out of the bath, and in getting the devices into working order before the nozzles are introduced into the bath.
  • 'At 64 are shown the fast and loose pulleys and band-shifting arrangements for starting and stopping the apparatus at each side.
  • the invention may be applied to one, or any'required number, of squirting nozzles, baths, pumps, and reels, in series, arranged in any convenient positions.
  • a frame having a pivoted uprightchanneled to convey the solution of viscose or the like, a hollow stem carried by said into said hollowstem through a concd end bearing, a carrier for said bearing piece mounted on said frame and through which said bearing piece is threaded and havmg a channel communicating with said uprightat one end and with the vpassage through said bearing piece at the other end, n1 combination with means for rapidly rotating said stem, the operation of said means being determined by the position of said pivoted frame, substantially as described.
  • rotatable nozzle carried by a hollow stem, or spindle, provided with means whereby it is driven at some portions of its length between its ends, and means for introducing the said matter at the end of the said-stem, or spindle, opposite to that at which the nozzle is fixed, mounting the rotatable hollow stem, or spindle, on a.
  • the nozzle can be swung into position for use, or into convenient position for inspection, or other purpose, while at the same time the said gearing is engaged and disen aged by the movement of the swinging rame, in combination with a pump driven by gear in connection with the gear which drives the rotatable hollow stem, or spindle, of the nozzle, the said pumipr being mounted on centers within the ame carrying the said rotatable hollow stem, or If spindle, and coincident with the centers on whichthe said frame turns, and the gearing being arranged so that the said frame can be swung to bring the stem, or spindle, into and out of connection with the driving gear independently of the pump, substantially as hereinbefore described.
  • each frame carrying a rotatable stem, or spindle, provided with gear and arranged so that it can be engaged with, and disengaged from, the driving means by swinging the said frame, a pump carried on the same center line as that of each swinging frame and provided with ear arranged so that the stems, or spind es, and

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)

Description

V J. CLAYTON. APPARATUS FOR USE IN THE MANUFACTURE OI ARTIFICIAL SILK'AND LIKE THREADS.
APPLICATION FILED 5111117, 1909.
0 1 9 11 7h 2 am e D I m n w a P ATTORNE YS J. GLAYTON.
APPARATUS FOR- USE IN THE MANUFACTURE OF ARTIFICIAL SILK AND LIKE THREADS.
I APPLICATION FILED JUNE 7, i909. 979,434., Patented Dec.27, 1910.
5 anus-sum z.
WITNESSES MM i//i% #170 R NEWS v LOLAYTON. APPARATUS FOR'USE IN THE MANUFACTURE OF ARTIFICIAL SILK AND LIKE THREADS.
APPLICATION FILED JUNE 7, 1909.
Patented Dec. 27, 1910 5 BEBETHHEET 3.
221E NTlogL W W/ Z/f/ Q' AT OKNE VS J. CLAYTON. mmmus ron van n: THE mnumowunn or AMI-mom SILK AND 1.11m mumps.
APPLIUATION FILED JUNE 7, 1909. r 'j9 434 Patented De0.27,1910
6 SHEETS-SHEET 4.
a N v \I WITNES ES INVENTOR J. CLAYTON. APPARATUS FOR USE IN THE MANUFACTURE OF ARTIFICIAL SILK AND LIKE THREADS.
APPLICATION FILED JUNE 7, 1909.
Patented 1390.27, 1910.
QYQAQB 5 BHEETSBHEET 5.
. TED STAWENT OFFICE.
JAMES CLAYTON, F COVENTRY, ENGLAND, ASSIGNOR TO SAMUEL' COURTAUIJ) 00., LIMITED, 01 LONDON, .ENGLAND. I
APPARATUS FOR USE IN THE MANUFACTURE OF ARTIFICIAL-SILK LIKE a f THREADS.
Specification ot Letters Patent. Application filed June 7, 1909. Serial No. 500,762.
Patented Dec. 27, 1910.
To all whom it may concern:
Be it known that I, JAMES CLAYTON, of 12 Mlddleborough road, Coventry, in the county of Warwick, England, have invented new and useful Improvements" in Apparatus for Use in the Manufacture of Artificial- Silk and Like Threads, of which the following is a specification.
This invention relates pr ncipally to ap paratus whereby artificial silk, and like threads, are produced by precipitating mat-.
ter, such as a viscous preparation of cellu lose, such as viscose, (we will, for the purose of description, refer to it as viscose), into a setting medium, or bath, through. perforatlons n a nozzle to form a number of filaments which are twisted together to hitherto and whereby the spinning, or twistpositive gearing driving the the action of the pump ing, of the filaments into thread is eificiently effected as the filaments issue from the orifices in the forming nozzle into the setting medium, or bath. Attempts have before been made to effect the spinning, or twisting, of filaments of viscose as they issue from the forming nozzle, but the means hitherto devised for the purpose have not been suitable for practical application and have not been successful. It is necessary, in the apparatus to which this invention relates, that rapid rotation shall be imparted to the'hoh low stem, or spindle,'carryin the nozzle by hollow stem, or spindle, at some portion of its length between the two ends, and that the viscose shall be supplied at the end opposite to that at which the nozzle is fixed.
According to this invention, the stem, or spindle, is carried on a swinging frame,
capable of being turned in a bracket secured to the viscose supply.pipe,-so as to bring the nozzle into convenient position for inspection, or other purpose, and at'the same time put out of gear the wheels which trans-.
mit motion to drive the stem, or spindle. The pump is also so mounted on the said frame that it can be swung thereon to disengage the gear which drives it and so stop when desiredindependently of the swinging of the said frame, so that, while the frame can-be swung to' put the stem, or spindle, in and out of gear without affecting the driving of the pump, when desired both can be put into and out of ear simultaneously. The said frame carries the filter and the various parts are erforated for the passage of the viscose mm the viscose pipe to the pump and from the pump through the filter and frame to the stem, or s indle, and thence to the nozzle. The thread w ich is formed by the spinning,
of the stem, or spindle, and nozzle, is led over suitable guides to a winding reel, or the equivalent, provided with means for. driving it and preferably also with means for 1aying the thread as it is wound, and the said reel,
or the equivalent, is mounted so that it can, by any suitable device, be put out of gear with the driving means and removed and replaced by another reel, or the equivalent,
or twisting, of the filaments, by the rotation 65 as required. The driving means. for the'75 the stem, or spindle, and the reel, are geared together so that they have the required relative speeds, which can be altered ifvdesired by change wheels. The arrangepump,
ment is preferably such as to include a numher of devices as described, arranged in two rows back to back.
The following is a description (with ref-- erence to the aeeompanylng drawings) of a construction and arrangement of appara-,
tus in accordance with this invention, but
the invention is not limited to the precise details hereinafter described.
Figure 1 is an end elevation, Flg. 2 a
adjuncts removed), and Fig. 3 a transverse section, of theapparatus. Fig. 4 1s a sec tion of one of the rotatable nozzles and lts stem, or spindle, and means for supplyin viscose thereto, and of one of the pumps an the driving gear in connection with the said ump and stem, or-"spindle. This and the ollowin figures are drawn to a larger scale. ig. 5 is an end view of the frame carrying the pump and stem, or spindle, and Fig. 6 is a section showing a pum and stem, orspindle, in position in such ame and the supportin bracket. Fig. 7 is a longitudinal section s lowing the gear by which the stems, or spindles, are driven.
The arrangement illustrated shows two baths with six arrangements of nozzles and pumps in connection with each. but it 18 side elevation (with some of the pumps and to be understood that one bath, or any number of baths, and one pumand nozzle, or
any-number of pumps an nozzles, can be used with each bath.
On a suitable framework 1, are carried two setting baths 2, parallel with each other, and outward of these baths are standards 3, for a driving shaft 4, each shaft 4 carrying friction wheels 5, one for drivin eachstem, or spindle, of the squirting nozz es, as hereinafter described. Below this shaft 4 and its standards project brackets 6 carrying a pumpdriving shaft 7, geared at the end, preferably by change gear 8 (see Fig. 1) to the driving shaft 4. On this pump-driving shaft 7 are worms 9, one for each pump. A pipe 10 for the supply of viscose runs along each side of the machine and to each of these pipes 10, opposite each of the worms 9,
on the pump-driving shaft 7, are fixed continuations 11 of the bracket 6, these continuations having bearings by which a frame is carried, as shown clearly in Fig. 6,
- the sa-id'frame preferably consisting of two arms, 12 and 13, .and two cross-pieces 14 and 15. The said frame can be swung on, or in,- the said bearings as centers. In bearings, respectively in one of the said arms (that marked 13) and'in the bracket 11, secured to the viscose supply pipe 10, is carried the pump 16, so that it can be swung in these bearings as centers. The arms 13 each carry a filter 17. The upper cross-piece 14, between the arms 12 and 13, carries, in a clamp 18, one end of the casing 33, with a bearing for one end of the stem, or spindle, 19, terminating in the nozzle 20, through which the viscose is squirted into the bath.
The stem, or spindle, 19 of the nozzle 20 carries around it, preferably near the ,midpart of its length, a quick-threaded worm 21, which engages with a worm-wheel 22, carried on a spindle 23, mounted in bearings 24 (preferably ball bearings) carried by a casing 25, which is secured to the lower cross-piece between the aforesaid arms 12 and 13. The said worm-wheel 22 has formed on, or fixed to, it a friction wheel 26 which, when the frame is swung toward the bath, bears against the corresponding friction wheel 5, carried by the driving shaft 4. When the pump 16 is swung toward the bath, the worm-wheel 27 of the pump engages with one of the worms 9 carried by the pump-driving shaft 7 and then viscose is pumped from the viscose pipe 10, through a perforation in the said pipe and through a perforation 28 (Fig. 6) in the bracket 11, which carries the aforesaid frame, through the erforations 29, to the pump 16, and there rom through a perforation 30 in one of the arms and through the filter17, and therefrom through a perforation 31 in the upper cross-piece 14 of the frame into a chamber 32 in a piece 41 rease in the casing 33 which piece carries the adjustable bearing for one end of the stem, or spindle, of the nozzle, and thence by the lateral perforations 34, in the said bearing of the stem, or spindle, into the longitudinal perforation 35 in the stem, or spindle, which thus communicates at one end with the said chamber 32, and, at the other end, with the nozzle 20. The stem, or spindle, 19 which carries the nozzle may be carried in bearings in its casing in any suitable way,'for example, as shown in Fig.4, the end of the casing nearest the nozzle 20 may have a ball-seating 36, secured to it, and another ball-seating 37 secured to the stem, or spindle, 19, antifriction balls being interposed between these seatings, andthe end of the stem, or spindle, 19, at which the viscose enters may be made with a conical seating 38, into which enters a correspondingly coned end 39 of a screw 40, perforated to a sufiicient extent to form a continuation of the perforation 35, in the stem, or spindle, to the chamber 32, through the transverse perforations 34, the said screw 40 being screwed through the piece 41 in the end of the casing 33 of the stem, or spindle, so that the bearing can be readily adjusted.
Between, and above, the baths2the framework of the machine carries standards 45 with bearings in which a reel-driving shaft 46 is mounted, this shaft 46 being driven by gearing 47 and 48 (connected by the inclined shaft 49) from one of the driving shafts 4 from which one series of the rotary nozzles and stems, or spindles, and pumps derive motion as aforesaid. Extending outward from each side of the upper end of .each of the standards 45, which support the ing connection with the driving gear, and
remain stationary. The driving is effected by making the extensions from alternate standards 45 in the form of hollow casings, as shown in Fig. 3, and carrying a short spindle 5.6 at the outer end of each such casing. Secured to this spindle 56, inside the casing, is a chain-wheel 57, driven by a chain 58 from a chain-wheel 59 of a series of such wheels on the shaft carried by the e standards as aforesaid. The ends of the said short spindle which project from the casing each carry a friction, or gear, wheel 60 driving two adjacent reels by contact, or engagement, with friction, or gear, wheels 61 on the axes of the said reels. The driving frame, a perforated bearing piece'opening shown at 62) may be operated in proximity with each reel for properly laying the of the reels atone side is effected through I. an intermediate wheel so that the reels on the respective sides rotate in opposite directions.
Any suitable thread-layers (such as those thread-being wound thereon. The thread layers 62 are shown as being caused to swing by means of an eccentric 66 on the inclined shaft 49, the said eccentric being connected by a strap and rod 67 to a bar 68 to which the said thread-layers 62 are connected in any suitable manner.
The arrangement described for winding directly onto reels may be varied, for instance the thread may be wound onto bobbins driven as described withregard to the reels, or the thread may be coiled in suitable receptacles, by a coiling arrangement, or be otherwise dealt with to prepare it for subsequent treatment.
The various parts which it is desirable to protect from acid and to shield so as to avoid danger of accident to operatives may be inclosed in any suitable casings, either as indicated in the drawings, or in any other suitable manner, and open where necessary to allow gearing to engage.
Trays may be arranged in any suitable position (as at 63 for-instance) to catch any viscose which may drop from the-nozzles, or be expelled therefrom, when they are out of the bath, and in getting the devices into working order before the nozzles are introduced into the bath.
'At 64 are shown the fast and loose pulleys and band-shifting arrangements for starting and stopping the apparatus at each side.
5 are stops for preventing the frames turning too far and for supporting them when the nozzles are raised from the baths.
The invention may be applied to one, or any'required number, of squirting nozzles, baths, pumps, and reels, in series, arranged in any convenient positions.
\Vhat I claim is:
1. In apparatus for the purpose described, a frame having a pivoted uprightchanneled to convey the solution of viscose or the like, a hollow stem carried by said into said hollowstem through a concd end bearing, a carrier for said bearing piece mounted on said frame and through which said bearing piece is threaded and havmg a channel communicating with said uprightat one end and with the vpassage through said bearing piece at the other end, n1 combination with means for rapidly rotating said stem, the operation of said means being determined by the position of said pivoted frame, substantially as described.
2. In apparatus for use in the manufacture of artificial silk and like threads by projecting matter through perforations 111 'a rotatable nozzle carried by a hollow stem, or spindle, provided with means whereby it is driven at some portions of its length between its ends, and means for introducing the said matter at the end of the said-stem, or spindle, opposite to that at which the nozzle is fixed, mounting the rotatable hollow stem, or spindle, on a.
swinging frame and arranging the gearing by which the stem, or spindle, is rotated,-
so that the nozzle can be swung into position for use, or into convenient position for inspection, or other purpose, while at the same time the said gearing is engaged and disen aged by the movement of the swinging rame, in combination with a pump driven by gear in connection with the gear which drives the rotatable hollow stem, or spindle, of the nozzle, the said pumipr being mounted on centers within the ame carrying the said rotatable hollow stem, or If spindle, and coincident with the centers on whichthe said frame turns, and the gearing being arranged so that the said frame can be swung to bring the stem, or spindle, into and out of connection with the driving gear independently of the pump, substantially as hereinbefore described.
3. Inapparatus for the pur ose described for use in the manufacture o artificial silk and like threads by projecting matter through perforations in a rotatable 'nozzie carried by a hollow stem, or spindle, provided with means whereby it is driven at some portions of its length between its ends, and means for introducing the said matter at the end of the said stem, or spindle, oppo site to that at which the nozzle, is fixed, mounting the rotatable hollow stem, or spin: dle, on a swinging frame andarranging the gearing by which the stem or spindle is rotated, so that the nozzle can be swung into position for use, or into convenient position for inspection, or other purpose, while :at the same time the said gearing is engaged and disengaged by the movement of the swinging frame, in combination with a pump carried by said frame for supplying viscose to said hollow stem and means for driving the said pump.
4. For the aforesaid purpose, the combination of a hollow stem, or spindle, mounted on a sw nging frame, gearing, by
whichthe said stem, or spindle, is rotated, so arranged that the said gear is put int-.0 and out of operating connection by turning the swinging frame on its axis, a pump driven by gear in connection with the gear which drives the aforesaid hollow stem, or spindle, so that the frame can be turned to put the stem, or spindle, out of, and into, driving engagement independently of the pump, and a winding reel, or the equivalent, and means for driving it at a speed in proper relation to the speed of the stem, or spindle, and pump, and for stopping it when required, substantially as hereinbefore de scribed.
5. For the aforesaid urpose, the combination of a recipitating vessel, or precipitating vesse s, series of swinging frames and driving means running along in proximity thereto, each frame carrying a rotatable stem, or spindle, provided with gear and arranged so that it can be engaged with, and disengaged from, the driving means by swinging the said frame, a pump carried on the same center line as that of each swinging frame and provided with ear arranged so that the stems, or spind es, and
pumps can be vswung into and out of gear with the driving means independently of each other, and series of reels arranged in double line and driven in pairs by gear which will drive the reels at the proper when desired, all substantially as hereinbefore described. a Y
In testimony whereof have signed my name to this specification 1n the presence of two subscribing witnesses.
JAMES CLAYTON.
Witnesses:
FREDERICK THOMAS Wool),
GEORGE KELMAN.
US50076209A 1909-06-07 1909-06-07 Apparatus for use in the manufacture of artificial-silk and like threads. Expired - Lifetime US979434A (en)

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