US947067A - Method of treating nickel-copper alloys. - Google Patents
Method of treating nickel-copper alloys. Download PDFInfo
- Publication number
- US947067A US947067A US45552208A US1908455522A US947067A US 947067 A US947067 A US 947067A US 45552208 A US45552208 A US 45552208A US 1908455522 A US1908455522 A US 1908455522A US 947067 A US947067 A US 947067A
- Authority
- US
- United States
- Prior art keywords
- nickel
- metal
- copper alloys
- solution
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 7
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 title description 6
- 229910000881 Cu alloy Inorganic materials 0.000 title description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 20
- 239000002184 metal Substances 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 229910052759 nickel Inorganic materials 0.000 description 10
- 239000002253 acid Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000005242 forging Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical class [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000021110 pickles Nutrition 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/10—Other heavy metals
Definitions
- My invention relates to nickel copper alloys and has for its object the removalof 10 the oxids of nickel and copperwhich form' thereon.
- a. pickle consisting of-a solution containing a ferric 26 iron salt.
- a free acid preferably sulfuric acid and water.
- Ferric salt preferably ferric.
- - ferric salt if desired may be soluble in orm' when introduced into the bath.
- the combination ofthe free acid in the. solution and the ferric salt act efl'ectiv'ely to remove the oxide of nickel and copper present on the surface of the metal, and a so i 5 act to prevent the; reprecipitatio'n by the o the copper dissolved from th Oxidnickel back upon the metal; a p
- the herein described method of treating nickel co per alloys for the removal of the oxids 0 which consists in immersing the metal m a 1 7.
- the herein described method'of treating nickel copper alloys for the removal of the oxide 0 nickel and 'co per, which consistsin immersing the meta in a tank as containing] a solution of a free acid and water, adding a fer'ricsalt thereto,";heating the": solution to, 150 F., andjhereafter re-' moving the metal and washing the same;
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Description
UNITED STATESPATENT OFFICE,"
JOHN FAIBFIELD THOMPSON, OF BAYONNE, NEW JERSEY, ASSIGNOB 1'0 INTERNA- TIONAL mcxnr.
.Jnnsnr.
company, or new YORK, n. 'Y., n conrona'rron or nnw .Jmnrnon on 'rnna'rmo nIcKnL-corrnn ALI-6Y8. I
No Drawing.
Specification of Letters latent. Patented J an, 18,1910, Application filed September a0, 1908." Serial No. 455,522. i
To all whom it may conc em:
Be it known that, I, JOHN FAIRFIELD THoMrsoN, of Bayonne, county of Hudson, and State of New Jersey have invented a new and useful Method 0 .-.Treat ing Nickel- Copper Alloys, of which the following is a specification. y v
My invention relates to nickel copper alloys and has for its object the removalof 10 the oxids of nickel and copperwhich form' thereon.
In rolling or forgin an ingot ofa copper nickel alloythe meta 'is first heated 1n a furnace and then drawn out and rolled or i forged into the desired shape. -Both during the heatin in the furnace and during the exposure'o the heatedmetalto the air during the rolling or forging operation the metal becomes covered with a coating of the oxids of the two metals. To remove the oxide of nickel andcopper,
especially those formed during the heating a and rolhngcor forging, I employ a. pickle. consisting of-a solution containing a ferric 26 iron salt. In the hue and has been rolled or for e merse it in a tank filled with a so ution con- 30 taining a free acid, preferably sulfuric acid and water. Ferric salt, preferably ferric.
sulfate, is then added to the-solution. The
- ferric salt if desired may be soluble in orm' when introduced into the bath.) The bath sa-is then heated to preferably about 150 F. c at: which temperature I have obtained the most satisfactory results.- The metal is allowedto remain in the bath until the oxids.
upon the metal are absorhedfin the solution; 4oand is then removed and washed.
The combination ofthe free acid in the. solution and the ferric salt act efl'ectiv'ely to remove the oxide of nickel and copper present on the surface of the metal, and a so i 5 act to prevent the; reprecipitatio'n by the o the copper dissolved from th Oxidnickel back upon the metal; a p
It Wlll be seen by those skilled in the art that many variations may be madein mv o process without departing from its spirit "and scope, since. a What I claim' is: I V
' 1. The-method of pickling nickel copper tank containing --and water, adding a ferric salt thereto, heat- Y substantially as described.
' alloys which consists intreating them with a heated acid solution containing a ferric iron salt; substantial] 'as described. j,- I 4. The herein described method of treat- 65 'ing nickel co per alloys for therinoval'of the oxide 0 nickel .and to per thereon, which consists in immersing t e metal m a a solution of a free acid ing the solution and thereafter removing,
the metal-and washing the same; substantially as described;
5.- The herein described m thod of treating nickel co per alloys for he removal of the. oxide 0 nickel and-copper vthereon,
which consists in immersing the'metal in a w t f tank containing, a solution of sulfuric acid referred form of operation, after the metal as been treated in the pro e;
and water, adding a; ferric'salt thereto, heat ing the solution and thereafter removing the metaland washing the same; substantially as described.
6. The herein described method of treating nickel co per alloys for the removal of the oxids 0 which consists in immersing the metal m a 1 7. The herein described method'of treating nickel copper alloys for the removal of the oxide 0 nickel and 'co per, which consistsin immersing the meta in a tank as containing] a solution of a free acid and water, adding a fer'ricsalt thereto,";heating the": solution to, 150 F., andjhereafter re-' moving the metal and washing the same;
. In testimony whereof, I have hereunto set-my'handr JOHN FAIRFIELD TIOIPSON. Witnesses? j Heana'a'r H. Cm, Tnos. H. Bun.
nickel and copper thereon, as, v
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45552208A US947067A (en) | 1908-09-30 | 1908-09-30 | Method of treating nickel-copper alloys. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45552208A US947067A (en) | 1908-09-30 | 1908-09-30 | Method of treating nickel-copper alloys. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US947067A true US947067A (en) | 1910-01-18 |
Family
ID=3015487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US45552208A Expired - Lifetime US947067A (en) | 1908-09-30 | 1908-09-30 | Method of treating nickel-copper alloys. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US947067A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3646946A (en) * | 1969-01-06 | 1972-03-07 | Olin Mathieson | Copper alloy cleaning process |
| US3728155A (en) * | 1969-01-06 | 1973-04-17 | Olin Corp | Copper alloy cleaning process |
| US4361445A (en) * | 1978-09-13 | 1982-11-30 | Olin Corporation | Copper alloy cleaning process |
| DE4237021C1 (en) * | 1992-11-02 | 1994-02-10 | Poligrat Gmbh | Means for pickling the surface of chromium-nickel steels and chrome steels and use of the agent |
-
1908
- 1908-09-30 US US45552208A patent/US947067A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3646946A (en) * | 1969-01-06 | 1972-03-07 | Olin Mathieson | Copper alloy cleaning process |
| US3728155A (en) * | 1969-01-06 | 1973-04-17 | Olin Corp | Copper alloy cleaning process |
| US4361445A (en) * | 1978-09-13 | 1982-11-30 | Olin Corporation | Copper alloy cleaning process |
| DE4237021C1 (en) * | 1992-11-02 | 1994-02-10 | Poligrat Gmbh | Means for pickling the surface of chromium-nickel steels and chrome steels and use of the agent |
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