US937154A - Method of removing tarnish from metals. - Google Patents

Method of removing tarnish from metals. Download PDF

Info

Publication number
US937154A
US937154A US46229508A US1908462295A US937154A US 937154 A US937154 A US 937154A US 46229508 A US46229508 A US 46229508A US 1908462295 A US1908462295 A US 1908462295A US 937154 A US937154 A US 937154A
Authority
US
United States
Prior art keywords
metals
tarnish
metal
electrolyte
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US46229508A
Inventor
Marshall H Keyt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US46229508A priority Critical patent/US937154A/en
Application granted granted Critical
Publication of US937154A publication Critical patent/US937154A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25FPROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
    • C25F1/00Electrolytic cleaning, degreasing, pickling or descaling

Definitions

  • the method consists in immersing the metal from which the tarnish is to be removed in an electrolytein which is im-' mersed a metal of .a more positive electrical character.
  • the method is applicable in brightening all kinds of metals, but for the purpose of illustration it Will be described in the removal of tarnish from silver.
  • the invention further consists in a novel construction of apparatus for carrying out the method.
  • F-igures l and 2 represent apparatus suitable for carrying out the steps of the process, Fig. 1 being a sectional perspective view and Fig. 2a modified form of apparatus.
  • a receptacle of any suitable type - and B a metal plate or sheet therein, the metal being.
  • ' C designates the electrolyte, a solution containing carbonate of soda, bicarbonate
  • the preferred proportions of the ingredients are: two parts, by weight,'. of the carbonate; two parts of thebicarbonateyand one part of the sulfate. These ingredients are intimately mixed and preferably oured into. .the water? Within the receptac e forming the solution, the water being preferably at the boiling point to produce the best results.
  • the silver or other metal to be brightened is immersed in the electrolyte, and the tarnish disappears in practice' veryshortly after the immersion is effected, inmost instances merely a dipping of the article being required; As understood, an electrolytic act ras an @FFEQE.
  • ren'ioving the tarnish from silverware such as knives, forks, and-the like. It comprises a receptacle D, made entirely of zinc, and a holder for the articles or utensils E in, the
  • the method may be carried out in brightening metals of all kinds, and it is to be understood that other. metals than 'zinc may be employed as the constantly-immersed electrode.
  • Zinc is Y preferable, however, as the reaction is more
  • the reference-letter A (Fig. 1) designates rapid, with theresultthat the time required for carrying out the processis reduced to'a minimum.
  • soda salts have been employed heretofore as the active agent of an electrolyte, but the particular combination of salts set forthaboveis 'believed to be novel and superior to any other" composition heretofore used in that it. is capable of effecting a rapid reaction, and the electrolyte remains active for a maximum period of time.
  • the metalto be brightened in an electrolyte consisting of sodium carbonate, sodium bi f
  • an electrolyte consisting of sodium carbonate, sodium bi f

Description

WE, W 7
' M. H. KEYT. METHOD OF REMOVING TARNISH mom METALS.
I APPLIOATION FILED NOV. 12, 1908.
937,154, Patented Oct; 19, 1909.
///)/I/I//I/////////II/7// W'z'in esse; [27%]: For
Man 52 421.11. r
of soda, and sodium. sulfate.
, MET-iron or Rumor me TARNISH FROM METALS.
To all whom it may concem: I
Be it known that I, hlARSHALL H. KEYT, a citizen of the United States of America, re-
siding at Chicago, in the county of Cook.
and State of Illinois,'have invented certain new and useful Improvements in Methods of Removing Tarnish from Metals, of which forth.
Primarily, the method consists in immersing the metal from which the tarnish is to be removed in an electrolytein which is im-' mersed a metal of .a more positive electrical character. The method is applicable in brightening all kinds of metals, but for the purpose of illustration it Will be described in the removal of tarnish from silver.
The invention further consists in a novel construction of apparatus for carrying out the method.
In the draWings,F-igures l and 2 represent apparatus suitable for carrying out the steps of the process, Fig. 1 being a sectional perspective view and Fig. 2a modified form of apparatus.
a receptacle of any suitable type,- and B a metal plate or sheet therein, the metal being.
preferably zinc.
' C designates the electrolyte, a solution containing carbonate of soda, bicarbonate The preferred proportions of the ingredients are: two parts, by weight,'. of the carbonate; two parts of thebicarbonateyand one part of the sulfate. These ingredients are intimately mixed and preferably oured into. .the water? Within the receptac e forming the solution, the water being preferably at the boiling point to produce the best results. The silver or other metal to be brightened is immersed in the electrolyte, and the tarnish disappears in practice' veryshortly after the immersion is effected, inmost instances merely a dipping of the article being required; As understood, an electrolytic act ras an @FFEQE.
' jplraits irntn*iixfigur'r, or (intense, ILLINois.
:3 Specification of lietters'rateiit; Application filed November 12, 1908. Serial No. 462,295.
' Patented Get. 19, race.
Within the bath. To obtain satisfactory resuits it is essential that the tarnish upon the metal having the higher-positive electrical characteristics be removed andthe metal k ept bright during the carrying out of. the method.
In Fig. 2 a'niodilied form of apparatus is illustrated-especially designed for use i=3. ren'ioving the tarnish from silverware, such as knives, forks, and-the like. It comprises a receptacle D, made entirely of zinc, and a holder for the articles or utensils E in, the
form of a U-shaped tray, the major portion I gut. the necessity of the hands of the operator eing' placed within the electrolyte. As previously pointed out, the method may be carried out in brightening metals of all kinds, and it is to be understood that other. metals than 'zinc may be employed as the constantly-immersed electrode. Zinc is Y preferable, however, as the reaction is more The reference-letter A (Fig. 1) designates rapid, with theresultthat the time required for carrying out the processis reduced to'a minimum.
Attention is further. directed to the fact that whereas the electrolytic action will take place upon merely dipping the metal to be brightened within theelectrolyte, the operation is materially hastened by bringing the tarnished metal into direct contact with the positive electrode after immersion. The construction of apparatus shown in Fig. 2 of the drawings is especially applicable for this purpose, the articles being adapted to contact directly with the zinc tray, or may contactone with another and finally with a tray.
Iam aware that soda salts have been employed heretofore as the active agent of an electrolyte, but the particular combination of salts set forthaboveis 'believed to be novel and superior to any other" composition heretofore used in that it. is capable of effecting a rapid reaction, and the electrolyte remains active for a maximum period of time.
What I claim as my invention is,-
the metalto be brightened in an electrolyte consisting of sodium carbonate, sodium bi f The herein-described process for removing electrical contact with the more positive tarnlsh from metals, cons1st1ng 1n lmmerslng metal. 10
In testimony whereof I aflix my signature in presence of two Witnesses.
carbonate, and sodium sulfate, in solution, MARSHALL H. KEYT.
in which is immerseda metal of a more posi- Witnesses: tive electrical character, and in bringing the NELLIE KINsELLA,
metal 'to be brightened after immersion into I HARRY W. GALVIl\.
US46229508A 1908-11-12 1908-11-12 Method of removing tarnish from metals. Expired - Lifetime US937154A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US46229508A US937154A (en) 1908-11-12 1908-11-12 Method of removing tarnish from metals.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US46229508A US937154A (en) 1908-11-12 1908-11-12 Method of removing tarnish from metals.

Publications (1)

Publication Number Publication Date
US937154A true US937154A (en) 1909-10-19

Family

ID=3005575

Family Applications (1)

Application Number Title Priority Date Filing Date
US46229508A Expired - Lifetime US937154A (en) 1908-11-12 1908-11-12 Method of removing tarnish from metals.

Country Status (1)

Country Link
US (1) US937154A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4353786A (en) * 1981-06-22 1982-10-12 S. C. Johnson & Son, Inc. Electrolytic silver tarnish removal method
GB2176499A (en) * 1985-05-14 1986-12-31 Howard Marc Gold Article and method for tarnish removal

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4353786A (en) * 1981-06-22 1982-10-12 S. C. Johnson & Son, Inc. Electrolytic silver tarnish removal method
GB2176499A (en) * 1985-05-14 1986-12-31 Howard Marc Gold Article and method for tarnish removal

Similar Documents

Publication Publication Date Title
US2468006A (en) Electrolytic cleaning of metal
JP4592683B2 (en) Electrolyte for electrochemical polishing of metal surfaces
Mohan et al. Electropolishing of stainless steel—a review
US2211400A (en) Pickling solution for copper-base alloys
US937154A (en) Method of removing tarnish from metals.
US3622470A (en) Continuous plating method
US2311139A (en) Process for the electrolytic cleaning of metals
US3489625A (en) Process for metal surface conditioning
US2542779A (en) Electropolishing composition and process
US3087874A (en) Electropolishing of titanium base alloys
US2834659A (en) Chemical polishing of metals
US2616845A (en) Electrolytic polishing apparatus
US1085768A (en) Process of preventing oxidation of metals during annealing.
USRE13880E (en) Method of removing tarnish from metals
US1376366A (en) Solution or bath for use in electrically preparing stencil-plates, die-plates, and the like
US2588566A (en) Electrolytic process for stripping copper
US2706171A (en) Stripping chromium plating from zinc electrolytically
US3164464A (en) Method of introducing magnesium into galvanizing baths
US3201286A (en) Method of boronizing
US3006827A (en) Method of pickling titanium and compositions used therein
US2920023A (en) Electrolytic cleaning of metal and composition therefor
US2561065A (en) Composition for and process of removing metallic coatings
US2801961A (en) Tarnish remover
US2601864A (en) Composition for and method of descaling metal parts
US660116A (en) Process of separating tin from tin-scrap.