US9231381B2

US9231381B2 - Ceramic electrode including a perovskite or spinel structure for an ignition device and method of manufacturing

Info

Publication number: US9231381B2
Application number: US14/526,862
Authority: US
Inventors: William J. Walker, Jr.; James D. Lykowski
Original assignee: Federal Mogul Ignition Co
Current assignee: Federal Mogul Ignition LLC
Priority date: 2008-08-28
Filing date: 2014-10-29
Publication date: 2016-01-05
Anticipated expiration: 2028-08-28
Also published as: US20150048733A1

Abstract

A spark plug and method of construction is provided. The spark plug has a generally annular ceramic insulator extending between a terminal end and a nose end. A conductive shell surrounds at least a portion of the ceramic insulator and a ground electrode having a ground electrode sparking surface is operatively attached to the shell. An elongate center electrode has a body extending between opposite ends. The body of the center electrode is formed of a compacted and sintered conductive or semi-conductive ceramic material. The ceramic material of the body comprises at least one oxide. For example, the body of the center electrode can be formed of a perovskite structure or a spinel structure.

Description

CROSS REFERENCE TO RELATED APPLICATIONS

This U.S. Continuation-in-Part Application claims priority to U.S. Continuation application Ser. No. 13/898,898, filed May 21, 2013, which claims priority to U.S. Divisional patent application Ser. No. 13/243,543, filed Sep. 23, 2011, now U.S. Pat. No. 8,471,450, granted Jun. 25, 2013, and U.S. patent application Ser. No. 12/200,244 filed Aug. 28, 2008, now U.S. Pat. No. 8,044,561, granted Oct. 25, 2011, the entire disclosures of which are hereby incorporated by reference in their entirety.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The invention relates generally to ignition devices for internal combustion engines, and more particularly to electrodes therefor.

2. Related Art

A spark plug is a spark ignition device that extends into the combustion chamber of an internal combustion engine and produces a spark to ignite a mixture of air and fuel. Spark plugs typically have an outer ceramic insulator, which is fabricated and fired separately from other components of the spark plug, a center electrode extending partially through the insulator to a firing tip, and a ground electrode extending from an outer metal shell. A separate resistor component is commonly coupled to an end of the electrode within the insulator opposite the firing end of the electrode. The resistor acts to suppress radio frequency (RF) electromagnetic radiation, which if left unchecked, can affect the transmission of other electrical signals, including inferring with radio signals. Typically, the closer the resistor is located to the firing gap between the spaced center and ground electrode firing ends the better, as this is where the spark is produced, thus being a primary location for the generation of RF electromagnetic radiation.

Recent advancements in engine technology are resulting in higher engine operating temperatures to achieve improved engine efficiency and performance. These higher operating temperatures have an adverse affect on the spark plugs by diminishing their useful life. In particular, the higher temperatures are pushing the spark plug electrodes to the very limits of their material capabilities, and in some cases beyond the limits, thereby resulting in failure of the electrode. Presently, Ni-based alloys, including nickel-chromium-iron alloys specified under UNS N06600, such as those sold under the trade names Inconel 600®, Nicrofer 7615, and Ferrochronin 600®, are in wide use as spark plug electrode materials. These electrodes are typically expected to last up to about 30,000 miles in service, and thereafter, generally need to be replaced.

As is well known, the resistance to high temperature oxidation of these Ni-based nickel-chromium-iron alloys decreases as their operating temperature increases. Since combustion environments are highly oxidizing, corrosive wear including deformation and fracture caused by high temperature oxidation and sulfidation can result and is particularly exacerbated at the highest operating temperatures. At the upper limits of operating temperature (e.g., 1400° F. or higher), tensile, creep rupture and fatigue strength also have been observed to decrease significantly which can result in deformation, cracking and fracture of the electrodes. Depending on the electrode design, specific operating conditions and other factors, these high temperature phenomena may contribute individually and collectively to undesirable growth of the spark plug gap, which increases the voltage required to cause sparking and diminishes performance of the ignition device and associated engine. In extreme cases, failure of the electrode, ignition device and associated engine can result from electrode deformation and fracture resulting from these high temperature phenomena.

Some known attempts to combat failure of electrodes from exposure to the increasing temperatures in high performance engines include fabricating the electrodes from precious metals, such as platinum or iridium. Although the life in service of these electrodes can increase the useful life of the electrode, generally up to about 80,000-100,000 miles, they still typically need to be replaced within the lifetime of the vehicle. Further, these electrodes can be very costly to construct.

Accordingly, there is a need for spark plugs that have electrodes exhibiting an increased useful life in high temperature engine environments; have resistance to high temperature oxidation, sulfidation and related corrosive and erosive wear mechanisms; suppress RF electromagnetic radiation; have sufficient high temperature tensile, creep rupture and fatigue strength; resist cracking and fracture sufficient for use in current and future high temperature/high performance spark ignition devices, and are economical in manufacture.

SUMMARY OF THE INVENTION

One aspect of the invention provides a spark plug having an insulator formed of a first ceramic material and a center electrode. The ceramic insulator extends along a longitudinal axis between a terminal end and a nose end. The center electrode is disposed in a central passage of the insulator and has an elongate body constructed of a second ceramic material, such as a perovskite structure or spinel structure.

In accordance with another aspect of the invention, a method of constructing a spark plug is provided. The method includes compacting a first ceramic material to form an insulator having a central passage extending between a terminal end and a nose end; compacting a second ceramic material, such as a perovskite structure, a spinel structure, or a precursor material that forms a perovskite or spinel structure upon sintering, to form an elongate center electrode; and sintering the compacted ceramic materials of the insulator and the center electrode.

BRIEF DESCRIPTION OF THE DRAWINGS

These and other aspects, features and advantages of ceramic electrode and spark plug constructed in accordance with the present invention will become more readily appreciated when considered in connection with the following detailed description of presently preferred embodiments and best mode, appended claims and accompanying drawings, in which:

FIG. 1 is a cross-sectional view of a spark plug constructed in accordance with one presently preferred aspect of the invention;

FIG. 2 is a cross-sectional view of a spark plug constructed in accordance with another presently preferred aspect of the invention; and

FIG. 3 is a cross-sectional view of a spark plug constructed in accordance with yet another presently preferred aspect of the invention.

DETAILED DESCRIPTION OF ENABLING EMBODIMENTS

Referring in more detail to the drawings, FIG. 1 illustrates a spark ignition device, referred to hereafter as spark plug, generally at 10 used for igniting a fuel/air mixture within an internal combustion engine (not shown). The spark plug 10 has a center electrode 12 constructed of a conductive or semi-conductive ceramic material in accordance with the invention. The ceramic materials used for the center electrode 12 are capable of withstanding the most extreme temperature, pressure, chemical corrosion and physical erosion conditions experienced by the spark plug 10. These conditions include exposure to numerous high temperature chemical reactant species associated with the combustion process which commonly promote oxidation, sulfidation and other high temperature corrosion processes, such as those attributed to calcium and phosphorus in the combustion products, as well as reaction of the plasma associated with the spark kernel and flame front which promote erosion of the spark surface of the electrode 12. The center electrode 12 substantially avoids cyclic thermo-mechanical stresses typically otherwise associated with a mismatch in the thermal expansion coefficients of the common metal alloy electrode materials and associated components of the spark plug 10, such as an insulator 14, given the insulator 14 is also constructed from a ceramic material. Accordingly, the electrode 12 avoids high temperature creep deformation, cracking and fracture phenomena, which typically results in failure of electrodes. In addition, with the center electrode 12 being able to withstand or avoid the aforementioned conditions, a preset spark gap 16 between the center electrode 12 and a ground electrode 18 is able to be substantially maintained over the life of the vehicle. As such, the formation, location, shape, duration and other characteristics of the spark generated across the spark gap 16 is able to be optimized over the useful life of the spark plug 10. In turn, the combustion characteristics of the fuel/air mixture and performance characteristics of the engine in which the spark plug 10 is incorporated is able to be optimized.

The spark plug 10 includes the generally annular insulator 14 formed of a ceramic material, referred to as a first ceramic material, which may include aluminum oxide or another suitable electrically insulating material having a specified dielectric strength, high mechanical strength, high thermal conductivity, and excellent resistance to thermal shock. The insulator 14 may be press molded from a ceramic powder in a green state and then sintered at a high temperature sufficient to densify and sinter the ceramic powder. The insulator 12 has an outer surface which may include a lower portion 19 having a small lower shoulder 21 and a large upper shoulder 23, with a partially exposed upper mast portion 20 extending upwardly from the upper shoulder 23 to which a rubber or other insulating spark plug boot (not shown) surrounds and grips to electrically isolate an electrical connection with an ignition wire and system (not shown). The exposed mast portion 10 may include a series of ribs 22 or other surface glazing or features to provide added protection against spark or secondary voltage flash-over and to improve the gripping action of the mast portion 20 with the spark plug boot. The insulator 14 is of generally tubular or annular construction, including a central passage 24 extending longitudinally between an upper terminal end 26 and a lower core nose end 28. With respect to the embodiment of FIG. 1, the central passage 24 has a varying cross-sectional area, generally greatest at or adjacent the terminal end 26 and smallest at or adjacent the core nose end 28, with a transition shoulder 27 therebetween, although other passage configurations are possible and contemplated to be within accordance of the invention.

The spark plug includes an electrically conductive metal shell 30. The metal shell 30 may be made from any suitable metal, including various coated and uncoated steel alloys. The shell 30 has a generally annular interior surface 32 which surrounds and is adapted for sealing engagement with the outer surface of the lower portion 19 of the insulator 14 and has the ground electrode 18 attached thereto which is maintained at ground potential. While the ground electrode 18 is depicted in a commonly used single L-shaped style, it will be appreciated that multiple ground electrodes of straight, bent, annular, trochoidal and other configurations can be substituted depending upon the intended application for the spark plug 10, including two, three and four ground electrode configurations, and those where the electrodes are joined together by annular rings and other structures used to achieve particular sparking surface configurations. The ground electrode 18 has one or more ground electrode firing or sparking surface 34 on a sparking end 36 proximate to and partially bounding the spark gap 16 located between the ground electrode 18 and the center electrode 12, which also has an associated center electrode sparking surface 38. The spark gap 16 may constitute an end gap, side gap or surface gap, or combinations thereof, depending on the relative orientation of the electrodes and their respective sparking ends and surfaces. The ground electrode sparking surface 34 and the center electrode sparking surface 38 may each have any suitable cross-sectional shape, including round, rectangular, square and other shapes, and the shapes of these sparking surfaces may be different.

The shell 30 is generally tubular or annular in its body section and includes an internal lower compression flange 40 configured to bear in pressing contact against the small mating lower shoulder 21 of the insulator 14 and an upper compression flange 42 that is crimped or formed over during the assembly operation to bear on the large upper shoulder 23 of the insulator 14 via an intermediate packing material 44. The shell 30 may also include an annular deformable region 46 which is designed and configured to collapse axially and radially outwardly in response to heating of the deformable zone 46 and associated application of an overwhelming axial compressive force during or subsequent to the deformation of the upper compression flange 42 in order to hold the shell 30 in a fixed axial position with respect to the insulator 14 and form a gas tight radial seal between the insulator 14 and the shell 30. Gaskets, cement, or other packing or sealing compounds can also be interposed between the insulator 14 and the shell 30 to perfect a gas-tight seal and to improve the structural integrity of assembled spark plug 10.

The shell 30 may be provided with an external tool receiving hexagon 48 or other feature for removal and installation of the spark plug in a combustion chamber opening. The feature size will preferably conform with an industry standard tool size of this type for the related application. Of course, some applications may call for a tool receiving interface other than a hexagon, such as slots to receive a spanner wrench, or other features such as are known in racing spark plug and other applications. A threaded section 50 is formed on the lower portion of the shell 30, immediately below a sealing seat 52. The sealing seat 52 may be paired with a gasket 54 to provide a suitable interface against which the spark plug 10 seats and provides a hot gas seal of the space between the outer surface of the shell 30 and the threaded bore in the combustion chamber opening. Alternately, the sealing seat 52 may be configured as a tapered seat located along the lower portion of the shell 30 to provide a close tolerance and a self-sealing installation in a cylinder head which is also designed with a mating taper for this style of spark plug seat.

An electrically conductive terminal stud 56 is partially disposed in the terminal end 26 of the central passage 24 of the insulator 14 and extends longitudinally from an exposed top post 58 to a bottom end 60 embedded partway down the central passage 24. The top post 58 is configured for connection to an ignition wire (not shown) which is typically received in an electrically isolating boot as described herein and receives timed discharges of high voltage electricity required to fire the spark plug 10 by generating a spark across the spark gap 54.

The bottom end 60 of the terminal stud 56 is preferably reduced in diameter from the central passage 24 and is embedded within a conductive glass seal 62. The conductive glass seal 62 functions to seal the bottom end 60 of terminal stud 40 and the central passage 24 from combustion gas leakage and to electrically establish an electrical connection between the terminal stud 56 and the center electrode 12. Many other configurations of glass and other seals are well-known and may also be used in accordance with the invention. In addition, although not believed necessary in lieu of the construction of the center electrode 12, a resistor layer (not shown), as is known, made from any suitable composition known to reduce electromagnetic interference (“EMI”), could be disposed between the bottom end 60 of the terminal stud 56 and an upper end or head 64 of the center electrode 12. Accordingly, an electrical charge from the ignition system travels through the bottom end 60 of the terminal stud 56, through the glass seal 62, and through the center electrode 12.

The center electrode 12 is partially disposed in central passage 24 of the insulator 14 and has an elongate cylindrical body 63, that extends along a longitudinal axis 66 from its enlarged, radially outwardly flared head 64, which is known in headed pin configurations, wherein the head 64 is encased in the glass seal 62 and generally in abutment with the transition shoulder 27, to its sparking end 39 which projects outwardly from the nose end 28 of the insulator 14 proximate, but spaced from, the sparking surface 34 of the ground electrode 18. The body 63 of the center electrode 12 is constructed as a solid, one-piece, monolithic conductive or semi-conductive ceramic structure, referred to as a second ceramic material, extending continuously and uninterrupted between its head 64 and its sparking end 39. The ceramic structure of the body 63 may be constructed of various grades of material, thereby providing the body 63 with the desired levels of electrical resistance, depending on the application and desired characteristics, such as the desired electrical resistance for suppression of RF electromagnetic radiation. The body 63 is preferably constructed of one of various ceramic materials.

In one embodiment, the body 63 of the center electrode 12 is constructed of at least one oxide. For example, 100 weight percent (wt. %) of the body 63 could consist of the at least one oxide. Alternatively, at least 50 wt. %, or at least 70 wt. %, or at least 90 wt. %, or at least 95 wt. % of the body 63 could consist of the at least one oxide. The at least one oxide used to form the body typically includes oxides of transition metals. In this embodiment, the oxides can include monoxides, such as TiO, VO, NbO, TaO, MnO, FeO, CoO, NiO, CuO, and ZnO; sesquioxides, such as V₂O₃, CrO₃, Fe₂O₃, RhO₃, In₂O₃, Th₂O₃, and Ga₂O₃; and dioxides such as TiO₂, VO₂, CrO₂, MoO₂, WO₂, RuO₂, ReO₂, OsO₂, RhO₂, IrO₂, PbO₂, NbO₂, MbO₂, MnO₂, PtO₂, GeO₂, and SnO₂.

The at least one oxide of the body 63 can also include oxides of two or more metals, which include at least one transition metal. Such oxides include perovskite structures with the general formulation ABO₃, wherein component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; and component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni. Examples of such perovskite structures include LaCrO₃, LaMnO₃, LaFeO₃, LaGaO₃, and LaCoO₃.

In another embodiment, at least a portion of the component A and/or at least a portion of the component B of the perovskite structure can be replaced or substituted with a another component C and/or component D. In other words, some of component A, or all of component A, could be replaced with component C and/or component D; and some of component B, or all of component B, could be replaced with component C and/or component D. In an exemplary embodiment, component C includes at least one of La, Ca, Ba, Sr, Y, and Gd; and is different from component A and B. Component D includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, and Ni; and is different from component A and B. For example, the perovskite structure with the formulation ABO₃could be substituted with the additional component C and/or component D to form a perovskite with the general formulation (A_xC_1−x)BO₃, A(B_yD_1−y)O₃or (A_xB_1−x)(C_yD_1−y)O₃, wherein x is between 0 and 0.5 and y is between 0 and 0.5. A specific example of the alternate perovskite structure is La_1−xSr_xMnO₃, wherein a portion of the La is substituted with Sr. In addition, in certain embodiments, there could be three or more elements that occupy component A, which are each selected from the list of component A above; and/or three or more elements that occupy component B, which are each selected from the list of component B above.

Furthermore, components C and D may include elements selected from a group that have a valence charge different from that of components A and/or B, so that the total amount of oxygen (O) can be greater than or less than 3. For example, the alternate perovskite structure could have the general formulation M_xN_1−yO_3−z, wherein component M comprises component A and at least one other metallic element; component N comprises component B and at least one other metallic element; x is in the range from 0.9 to 1.1; y is in the range from 0.9 to 1.1; and z is in the range from −0.2 to 0.2. In an exemplary embodiment, the at least one other metallic element of component M and/or component N is selected from the following group: La, Ca, Ba, Sr, Y, Gd, Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ni, Cu, Zn, Ag, Ga, Al, and Si. In this embodiment, the valence charge of the other metallic element of component M is different than the valence charge of component A, and the valence charge of the other metallic element of component N is different from the valence charge of component B.

The at least one oxide used to construct the body 63 of the center electrode 12 could alternatively comprise a spinel structure having the general formulation AB₂O₄, wherein component A includes at least one of Li, Co, Mg, Zn, Ni, Fe, Cd, Mn, and Cu; and component B includes at least one of Al, Cr, and Fe. An exemplary spinel structure is nickel ferrite, which is an electrically conducting spinel having the stoichiometric composition NiFe₂O₄. In one embodiment, the performance of the spinel is improved by changing the ratio of Ni and Fe, such that the general formulation of the spinel is Ni_1−xFe_2+xO₄or Ni_1+xFe_2−xO₄, wherein x ranges from 0 to 0.5

In another embodiment, at least a portion of the component A and/or at least a portion of the component B of the spinel structure can be replaced with another component C and/or component D. In other words, some of component A, or all of component A, could be replaced with component C and/or component D; and some or component B, or all of component B, could be replaced with component C and/or component D. In an exemplary embodiment, component C includes at least one of Li, Co, Mg, Zn, Ni, Fe, Cd, Mn, Cu, Mo, W, Cr and V; and component C is different from component A and B. Component D includes at least one of Al, Cr, Fe, Co, Ga and Mo; and component D is different from component A and B. Like the perovskite structures, the spinels can be substituted, in which case the general formulation would be M_xN_2−yO_4−z, wherein M comprises component A and at least one other metallic element; N comprises component B and at least one other metallic element; x ranges from −0.1 to 0.1; y ranges from −0.1 to 0.1; and z ranges from −0.2 to 0.2. In an exemplary embodiment, the at least one other metallic element of component M and/or component N is selected from the following group: Ge, V, Te, Ti, Sb, Nb, Ta, W, Sn, Hf, Zr, Sc, Bi, and In.

The elongate center electrode constructed of the perovskite structure or spinel structure is manufactured by compacting and sintering the ceramic material. In one embodiment, the ceramic material initially provided for compacting and sintering includes at least one of the perovskite structures or spinel structures described above.

In another embodiment, a precursor material is provided which upon sintering forms one of the perovskite structures or spinel structures. The precursor material typically includes common oxides and/or carbonates of the elements listed above. Exemplary precursor materials that can be compacted and sintered to form the center electrode from a perovskite structure include at least one of La₂O₃, CaCO₃, BaCO₃, SrCO₃, Y₂O₃, Gd₂O₃, Sc₂O₃, TiO₂, ZrO₂, HfO₂, Nb₂O₅, Ta₂O₅, MoO₃, Mo₂O₃, WO₃, ReO₃, V₂O₃, Cr₂O₃, MnO₂, Fe₂O₃, FeO, Fe₃O₄, RuO₄, CoO, NiO, and Ni₂O₃. Exemplary precursor materials that can be compacted and sintered to form the center electrode from a spinel structure include at least one of Li₂CO₃, CoO, MgCO₃, MgO, ZnO, NiO, Ni₂O₃, FeO, Fe₂O₃, Fe₃O₄, CdO, MnO₂, CuO, Al₂O₃, Al(OH)₃and Cr₂O₃.

In another exemplary embodiment, the body 63 is constructed of at least one boride, including for example chemical compositions having the formula M_xB_y, where M is a metallic element, X is often 1, and Y is often 1, 2 or 6. Borides have an electrical resistance in the range of 10⁻⁵to 10⁻⁴ohm-cm, and melting points in the range of 1600 to 3200 degrees Celsius. Exemplary borides include Zirconium Boride (ZrB₂; ZrB and ZrB₁₂); Hafnium Boride (HfB₂); Titanium Boride (TiB₂; TiB); Vanadium Boride (VB₂; VB); Tungsten Boride (W₂B₅); Chromium Boride (CrB₂; CrB); Molybdenum Boride beta-MoB, alpha-MoB, Mo₂B₅; Mo₂B; Niobium Boride (NbB₂; NbB); Tantalum Boride (TaB₂; TaB); Lanthanum Hexaboride (LaB₆); Barium Hexaboride (BaB₆); Calcium Hexaboride (CaB₆); Cerium Hexaboride (CeB₆).

In yet another embodiment, the body 63 is constructed of at least one nitride, for example chemical compositions having the formula M_xN_y, where M is a metallic element, N is nitride and X and Y are typically 1. Such nitrides have an electrical resistance in the range of 10⁻⁵to 10⁻⁴ohm-cm, and melting points in the range of 1400 to 3300 degrees Celsius. Exemplary nitrides include Titanium Nitride (TiN); Zirconium Nitride (ZrN); Tantalum Nitride (TaN); Niobium Nitride (NbN); Vanadium Nitride (VN); Hafnium Nitride (HfN).

The body 63 could also be constructed of at least one carbide, for example chemical compositions having the formula M_xC_y, where M is a metallic element, C is carbon and X and Y are typically 1. The carbides typically have an electrical resistance in the range of 10⁻⁵to 10⁻⁴ohm-cm, and melting or sublimation points in the range of 1900 to 4000 degrees Celsius. Exemplary carbides include Tantalum Carbide (TaC); Chromium Carbide (Cr₃C₂); Molybdenum Carbide (MoC; Mo₂C); Tungsten Carbide (WC; W₂C); Zirconium Carbide (ZrC); Titanium Carbide (TiC); Niobium Carbide (NbC); Hafnium Carbide (HfC); Vanadium Carbide (VC); Beryllium Carbide (Be₂C); Silicon Carbide (SiC); and Boron Carbide (B₄C).

In another embodiment, the body 63 is constructed of at least one silicide. For example, the silicide could comprise the formula M_xSi_y, where M is a metallic element, Si is silicon and X is typically 1 and Y is typically 2. The silicides typically have an electrical resistance in the range of 10⁻⁵to 10⁻⁴ohm-cm, and melting points in the range of 1500 to 2500 degrees Celsius. Exemplary silicides include Molybdenum Silicide (MoSi₂); Niobium Silicide (NbSi₂); Titanium Silicide (TiSi₂); Tungsten Silicide (WSi₂; W₅Si₂); Chromium Silicide (CrSi₂; Cr₃Si); Tantalum Silicide (TaSi₂). Other compounds may include ternary silicides, nitrides and carbides, such as Molybdenum Silicide Carbide (Mo₅Si₃C) or Titanium Carbonitride (TiCN), for example.

Accordingly, depending on the level of resistance of the electrode 12 desired and the temperatures to which the electrode 12 is exposed, the appropriate ceramic material can be used in the construction of the electrode 12 as desired. Further, the ceramic material can be provided as a homogeneous material over the entire structure of the center electrode 12.

While the center electrode 12 is illustrated in FIG. 1 having a headed pin configuration due to the flared upper end or head 64, the invention also encompasses all manner of headed arrangements with the head at the opposite end of the electrode (i.e., proximate the sparking end 39). In addition, as illustrated in FIG. 2, wherein reference numerals offset by a factor of 100 are used to identify similar features as described above, an electrode 112 of a spark plug 110 can be constructed as straight cylindrical configuration, thereby being well suited to be formed in an extruding process and co-fired or sintered along with an insulator 114 to permanently bond the electrode 112 to the insulator ceramic material via an as sintered bond represented generally at 72. Accordingly, the insulator 114 and electrode 112 can be constructed as a unitary subassembly that is economical in manufacture. In addition, as illustrated in FIG. 3, wherein reference numerals offset by a factor of 200 are used to identify similar features as described above, an electrode 212 of a spark plug 210 can be constructed as a straight cylindrical configuration having an outer surface with a constant or substantially constant diameter extending over a length sufficient to extend through the entire length of a central passage 224 within an insulator 214 of the spark plug. Accordingly, the central passage 224 of the insulator 214 can be formed as a cylindrical though passage of a constant or substantially constant diameter, and sized for close, pressing receipt of the electrode 212, wherein the opposite ends 264, 239 of the electrode 212 are flush or substantially flush with the opposite terminal and nose ends 226, 228 of the insulator 214. Accordingly, the spark plug 210 does not have the conventional central resistor layer and glass sealing, as the electrode 212 extends completely through the passage 224 and performs the desired electrical resistance, depending on the ceramic material used to construct the electrode 212. Further, as with the electrode 112, the electrode 212 can be co-fired or sintered with the insulator 214 to permanently bond the electrode 212 to the insulator ceramic material via an as sintered bond represented generally at 272. Accordingly, the insulator 214 and electrode 212 can be constructed as a unitary subassembly that is economical in manufacture. It should be recognized that as well as those configurations illustrated, that the diameter of the electrode can be constructed to vary along its length, either in a stepwise, tapered or other manner, as desired. The

center electrode

12, 112, 212 may have any suitable cross-sectional size or shape, including circular, square, rectangular, or otherwise or size. Further, the sparking

end

39, 139, 239 may have any suitable shape. It may have a reduced cross-sectional size, and may have a cross-sectional shape that is different than the other portions of the center electrode. The sparking

surface

38, 138, 238 may be any suitable shape, including flat, curved, tapered, pointed, faceted or otherwise.

The center electrode 12 of the invention may be made using any suitable method for making ceramic articles of the types described, including injection molding and sintering, or pressing and sintering.

Obviously, many modifications and variations of the present invention are possible in light of the above teachings. It is, therefore, to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described.

Claims

What is claimed is:

1. A spark plug comprising:

an insulator formed of a first ceramic material extending along a longitudinal axis and presenting a central passage between a terminal end and a nose end;

a center electrode disposed in said central passage of said insulator;

said center electrode including an elongate body formed of a second ceramic material;

said second ceramic material comprising at least one perovskite structure having the general formulation ABO₃, wherein component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni; and optionally at least a portion of component A and/or at least a portion of component B of the perovskite structure is replaced with component C and/or component D, wherein component C is different from components A and B and includes at least one of La, Ca, Ba, Sr, Y, and Gd; and component D is different from components A and B and includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni.

2. The spark plug of claim 1, wherein at least 50 wt. % of the elongate body consists of the perovskite structure.

3. The spark plug of claim 1, wherein at least a portion of component A and/or at least a portion of component B of the perovskite structure is replaced with component C and/or component D.

4. A spark plug comprising:

a center electrode disposed in said central passage of said insulator;

said center electrode including an elongate body formed of a second ceramic material; and

said second ceramic material comprising at least one of LaCrO₃, LaMnO₃, LaFeO₃, LaGaO₃, and LaCoO₃.

5. A spark plug comprising:

a center electrode disposed in said central passage of said insulator;

said second ceramic material comprising at least one perovskite structure having one of the following formulations: (A_xC_1−x)BO₃, A(B_yD_1−y)O₃, or (A_xB_1−x)(C_yD_1−y)O₃; wherein component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni; x is between 0 and 0.5; and y is between 0 and 0.5.

6. The spark plug of claim 5, wherein the at least one perovskite structure includes La_1−xSr_xMnO₃.

7. A spark plug comprising:

a center electrode disposed in said central passage of said insulator;

said second ceramic material comprising at least one perovskite structure having the general formulation M_xN_1−yO_3−z, wherein component M comprises component A and at least one other metallic element; component A includes at least one of La, Ca, Ba, Sr, Y, and Gd; component N comprises component B and at least one other metallic element; component B includes at least one of Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ga, and Ni; x ranges from 0.9 to 1.1; y ranges from 0.9 to 1.1; and z ranges from −0.2 to 0.2.

8. The spark plug of claim 7, wherein at least 50 wt. % of the elongate body consists of the perovskite structure.

9. The spark plug of claim 7, wherein the at least one other metallic element of component M includes at least one of La, Ca, Ba, Sr, Y, Gd, Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ni, Cu, Zn, Ag, Ga, Al, and Si; and the at least one other metallic element of component N includes at least one of La, Ca, Ba, Sr, Y, Gd, Sc, Ti, Zr, Hf, Nb, Ta, Mo, W, Re, V, Cr, Mn, Tc, Fe, Ru, Co, Rh, Ni, Cu, Zn, Ag, Ga, Al, and Si.

10. The spark plug of claim 9, wherein the at least one other metallic element of component M has a valence charge different from the valence charge of component A; and the at least one other metallic element of component N has a valence charge different from the valence charge of component B.

11. A spark plug comprising:

a center electrode disposed in said central passage of said insulator;

said second ceramic material comprising at least one spinel structure.

12. The spark plug of claim 11, wherein at least 50 wt. % of the elongate body consists of the spinel structure.

13. The spark plug of claim 11, wherein the spinel structure is nickel ferrite having the formulation Ni_1−xFe_2+xO₄or Ni_1+xFe_2−xO₄; and x ranges from 0 to 0.5.

14. The spark plug of claim 13, wherein the nickel ferrite has the formulation NiFe₂O₄.

15. The spark plug of claim 11, wherein the spinel structure has the general formulation AB₂O₄, wherein component A includes at least one of Li, Co, Mg, Zn, Ni, Fe, Cd, Mn, and Cu; component B includes at least one of Al, Cr, and Fe; and optionally at least a portion of component A and/or at least a portion of component B is replaced with component C and/or component D; wherein component C is different from component A and B and includes at least one of Li, Co, Mg, Zn, Ni, Fe, Cd, Mn, Cu, Mo, W, Cr and V; and component D is different from component A and B and includes at least one of Al, Cr, Fe, Co, Ga and Mo.

16. The spark plug of claim 15, wherein the spinel structure has the general formulation M_xN_2−yO_4−z, wherein component M comprises component A and at least one other metallic element; component N comprises component B and at least one other metallic element; x ranges from −0.1 to 0.1; y ranges from −0.1 to 0.1; and z ranges from −0.2 to 0.2.

17. The spark plug of claim 16, wherein the at least one other metallic element of M is selected from the following group: Ge, V, Te, Ti, Sb, Nb, Ta, W, Sn, Hf, Zr, Sc, Bi, and In.

18. The spark plug of claim 16, wherein the at least one other metallic element of N is selected from the following group: Ge, V, Te, Ti, Sb, Nb, Ta, W, Sn, Hf, Zr, Sc, Bi, and In.

19. A method of manufacturing a spark plug, comprising the steps of:

compacting a first ceramic material to form an insulator having a central passage extending between a terminal end and a nose end;

compacting a second ceramic material to form an elongate center electrode, wherein the second ceramic material comprises at least one of a perovskite structure, a spinel structure, and a precursor material that forms a perovskite or spinel structure upon sintering; and

sintering the compacted ceramic materials of the insulator and the center electrode.

20. The method of claim 19, further including the steps of: providing a conductive shell and a ground electrode; attaching the ground electrode to the shell; and disposing the insulator and the center electrode in the shell.