US909527A - Composition for antiseptic and other purposes. - Google Patents
Composition for antiseptic and other purposes. Download PDFInfo
- Publication number
- US909527A US909527A US16867303A US1903168673A US909527A US 909527 A US909527 A US 909527A US 16867303 A US16867303 A US 16867303A US 1903168673 A US1903168673 A US 1903168673A US 909527 A US909527 A US 909527A
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- US
- United States
- Prior art keywords
- formic
- formic aldehyde
- aldehyde
- fixed
- composition
- Prior art date
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- Expired - Lifetime
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- 239000000203 mixture Substances 0.000 title description 29
- 230000002421 anti-septic effect Effects 0.000 title description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 46
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 239000003981 vehicle Substances 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 10
- 239000005871 repellent Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- 235000005687 corn oil Nutrition 0.000 description 7
- 239000000346 nonvolatile oil Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- -1 aliphatic ester Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 240000008042 Zea mays Species 0.000 description 3
- 239000002285 corn oil Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 description 2
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229960005233 cineole Drugs 0.000 description 2
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 230000002070 germicidal effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BQJCRHHNABKAKU-KBQPJGBKSA-N morphine Chemical compound O([C@H]1[C@H](C=C[C@H]23)O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4O BQJCRHHNABKAKU-KBQPJGBKSA-N 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical group C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- 235000019737 Animal fat Nutrition 0.000 description 1
- 241001574013 Collogenes Species 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 229960003920 cocaine Drugs 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000013003 healing agent Substances 0.000 description 1
- 230000002439 hemostatic effect Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000003589 local anesthetic agent Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229960005181 morphine Drugs 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 235000019871 vegetable fat Nutrition 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
Definitions
- This invention relates to a new article of manufacture for disinfecting, germicide, antiseptic and medicinal purposes and process of making the same, and it consists of a mixture, compound, or solution of formic aldehyde or its polymerids in a fixed waterrepellent, such asfixed oils or fatty vehicles, which compounds or compositions may or may not be associated with other medicating agents, the object being to produce a fixed, fatty composition of water-repellent nature containing formic aldehyde which may be employed per 86 or as a vehicle for other medicating or medicinal agents
- a solution of formic aldehyde 1n maize oil corn oil
- oil consists largely of glycerol-oleic ester.
- polymerids of formic aldehyde such as paraformaldehyde or trioxymethylene may be dissolved in the oil, preferably by the action of heat, producing compounds not departing from the spirit of my invention, as, upon heating in the formation of the composition, formic aldehyde is generated and the compositionis found to have a like disnal property, and to all lntents and pur poses may be considered, and is herein i11- cluded, as an equivalent composition in accordance with my invention.
- Figure l is a longitudinal vertical Section
- Fig. 2 is a sectional view of an axial stuflingbox through which pass the inlet and outlet pipes for the purpose of heating the contents of the apparatus ,by means of steam;
- Fig. 3 is a View of a perforated pipe through Whlcll the formic aldehyde is introduced into the apparatus.
- This formic aldehyde gas passes first through the check-valve H which provents the oil or other substances in the receptacle A from being forced back into the formic aldehyde reservoir or generating apparatus.
- a pressure 10o the drum A is revolved by means of the cogloo wheel M actuated by the movement of the revolving wheel N.
- the contents are siflilngltaifieplllisly heated by the steam assin' g e p1 the formic aldehyde is introduce through the pipe F, the premire bein maintained preferably at about 20 poun s. After.
- the whole apparatus is axially supported by the stands L through which the ends or hollow trunnions of the receptacle A are supported. It the and formlc aldehyde are thus thoro ymixed and assimilated by the action o heat and with the agitation caused y the revo ution of the drum, thus continually flowing the oil against the-fixed coils X and O.
- eucalyptol I can employ any other medicinal agent as desired, such as menthol, cocaine, morphine, etc., with the fixed oily formic aldehyde vehicle, or I can employ other fats, oils or ali hatic esters as the base for the formic aldehyde vehicle without departing from the spirit ofm invention, and I. intend to. inc ude the ense D and ,prevents the oily base from beco peningthevalvek.
- inert em loyed out this specification and claims has reference to the character of the solvent for I the formic aldehyde and-its character in relation-to the formic aldehyde contmt; and the term .fixdeg oil to'the crude (ii-0:11- worth-al anh us, inert 1 water-1e lent, mineral; vegetable or animal fat or oil, as well as purified products or esters and s intended to include anhydrous, inert, fined water-re nature w 'ch might substances or artific1ally or prepared, it being understood.
- thesubstance is of consists largely of anhy-' amorepermaent com tions of fined oily L syntheh y. thattbeterm non-volatile and permanent character under ordinary atmospheric pressure and temperature; and the term water-repellent designates a composition ordinarily insoluble in or incompatible with water.
- a new anhydrous composition ofmatter consisting of an inert, unctuous, fixed water-repellent vehicle containing formic aldehyde.
- a new anhydrous composition of matter composed of formic aldehyde and an inert fixed ester.
- a new anhydrous com osition of matter composed of formic aldehyde and an inert fixed oxy-acid ester.
- a new anhydrous composition of mat ter composed of formic aldehyde and an inert fixed aliphatic ester.
- a new anhydrous composition of matter substantially consisting of an inert fixed aliphatic ester and formic aldehyde.
- a new composition of matter substantially composed of an inert fixed aliphatic ester, formic aldehyde and a medicating agent.
- a new anhydrous composition of matter consistin of formic aldehyde and an inert fixed oil.
- a new anhydrous composition of matter consisting of inert fixed oil and formic aldehyde.
- composition com rising an inert fixed oily ester containing ormic aldehyde.
- the rocess of maln'ng the new composition of matter herein set forth which consists in mixing a fixed water-repellent ester with gaseous formic aldehyde and exposing the same to intimate association until the formic aldehyde has become associated therewith or occluded therein.
- the rocess of making the new composition ofi matter herein set forth which consists in mixing a fixed water-repellent ester with formic aldehyde under superatmospheric pressure and exposing the same to intimate. association until the formic aldehyde has become associated therewith or 00- cluded therein.
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
H. S. BLAGKMORE. COMPOSITION FOR ANTISEPTIG AND OTHER PURPOSES.
APPLIOATION FILED AUG. 7, 1903.
,nnmnnnnnn VIII/I/I/I/I/l awmhw 4. WMA.
HENRY SPENCER BLAGKMORE, MOUNT VERNON, YORK.
COMPOSITION FOR ANTISEP'IIO AND OTHER PURPOSES.
Specification of Letters Patent.
ratenteama. 1 2, 003
Application filed August 7, 1908. Serial Ho. 168,678.
To all whom it may concern:
Be it known that I, HENRY Srnncnn Bmoxnoas a citizen of the United States, residing at lllount Vernon, in the county of Wcstchester and State of New York, have invented certain new and useful Im rovements in Compositions for Antiseptic and other Purposes; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled in the art to which it appertains to make and usethe same.
This invention relates to a new article of manufacture for disinfecting, germicide, antiseptic and medicinal purposes and process of making the same, and it consists of a mixture, compound, or solution of formic aldehyde or its polymerids in a fixed waterrepellent, such asfixed oils or fatty vehicles, which compounds or compositions may or may not be associated with other medicating agents, the object being to produce a fixed, fatty composition of water-repellent nature containing formic aldehyde which may be employed per 86 or as a vehicle for other medicating or medicinal agents As a specific illustration of my new composition and the manner in which the same is produced I will take, for example, the production of a solution of formic aldehyde 1n maize oil (corn oil) which oil consists largely of glycerol-oleic ester. he manner in which I prefer to produce this fixed water-repellent or oily formic aldehyde solution or compound is to place'the desired fixed oil, such as maize oil, in a proper container and expose it to the presence of for-- mic aldehyde under increased pressure at the same time agitating it, whereby the formic aldehyde becomes absorbed, occluded, or retained therein. When the fixed oil has become saturated with formic aldehyde it is removed, the formic aldehyde content ascertained by test, and the composition diluted with more oil to obtain the percentage content of formic aldehyde desired.
The polymerids of formic aldehyde, such as paraformaldehyde or trioxymethylene may be dissolved in the oil, preferably by the action of heat, producing compounds not departing from the spirit of my invention, as, upon heating in the formation of the composition, formic aldehyde is generated and the compositionis found to have a like disnal property, and to all lntents and pur poses may be considered, and is herein i11- cluded, as an equivalent composition in accordance with my invention.
The apparatus, in which the Solution of formic aldehyde in inert and fixed water repellent vehicles in accordance with my process is made, is illustrated in the accom' panying drawing, in which,
Figure l is a longitudinal vertical Section; 6h
Fig. 2 is a sectional view of an axial stuflingbox through which pass the inlet and outlet pipes for the purpose of heating the contents of the apparatus ,by means of steam;
Fig. 3 is a View of a perforated pipe through Whlcll the formic aldehyde is introduced into the apparatus.
In carrying out my invention for makin a solution of formic aldehyde in maize oif,
I introduce into the revoluble drum A,
maize or corn oil which consists largely of glycerol-oleic ester, through the opening B by removing the cover 6, sufiicient to-fill the drum about two-thirds full. if then place the cover I) over the opening B and malntain the same in a tight or closed position by means of the screw-clamp C. I then open the valves d in the pipes D and pass there- I through and through the coil 0 a current of steam, whereby the maize or corn oil in the drum A becomes heated. As soon as the oil has become heated to about 100 G, I introduce into the oil through the perforated I pipe X formic'aldehyde gas under a pressure of about 20 pounds by opening the valve 1. This formic aldehyde gas passes first through the check-valve H which provents the oil or other substances in the receptacle A from being forced back into the formic aldehyde reservoir or generating apparatus. Connected with the pipe F, through which the formic aldehyde gas under pressure passes to the coil X from which the formic aldehyde gas is discharged through the perforations :0, is a pressure 10o the drum A is revolved by means of the cogloo wheel M actuated by the movement of the revolving wheel N. In the axial ends of the drum A are the stuffing-boxes E and P, the v infectant, germicide, antiseptic, and m dici- 55 e pipes D passingthrough thefixed seccan be seen that tion a of the stuflingx E while the pipe F through which the formic aldehyde 1s intros duced into the a tus passes through the Xftlhe apparatus revolves,.
stufling-box P. the contents are siflilngltaifieplllisly heated by the steam assin' g e p1 the formic aldehyde is introduce through the pipe F, the premire bein maintained preferably at about 20 poun s. After. a suflicient amoimt of formic aldehyde has been introduced into the oil in the apparatus to produce the dedred percentage content, the'apparatus is maintained in a rotary con dition for abouttwo hours whereby the formic aldehyde becomes thoroughly dissolved in or assimilated with the oil by the agitative action of the revolving drum and the fixed steam-heating coil 0 and erforated coil 0: through which the formic-a dehyde is introduced; The revolution of the apparatus is then stop and the oil, charged with formic aldehy e, iswithdrawn through the pipeKb o provid atlts outer endwith aflangez or the purpose of coupling up or clamping to conuits le to aremrvoir for the fixed oil charged wit formic aldehyde. The whole apparatus is axially supported by the stands L through which the ends or hollow trunnions of the receptacle A are supported. It the and formlc aldehyde are thus thoro ymixed and assimilated by the action o heat and with the agitation caused y the revo ution of the drum, thus continually flowing the oil against the-fixed coils X and O.
I have found it of advanta to employ this anhydrous fixed water-repel containing formic aldehyde equivalent as a vehicle for a nts, such, for indzance, w 'ch case it'is found to tion as anantiseptic and application to or its described other medicinal as eucalyptol, in act with satisfachealin agept for suppura su aces r1n :35 about the d ctiol i dgd removal of t e ammatory or suppurating causes and at the'same time a parently acting as a local anesthetic and siereby relieving the pain with which such inflammations are usually accompanied. It is preferable that the formic vehicle, in cases of this kind, should not exceed' one tenth of one per cent., but it can be varied at the tion of the prescriber to meet the exigencies and idiosyncrasies of the case.
Insteadnof eucalyptol I can employ any other medicinal agent as desired, such as menthol, cocaine, morphine, etc., with the fixed oily formic aldehyde vehicle, or I can employ other fats, oils or ali hatic esters as the base for the formic aldehyde vehicle without departing from the spirit ofm invention, and I. intend to. inc ude the ense D and ,prevents the oily base from beco peningthevalvek. The pi e'Kis ressure to other ent composition repellent vehi e aldehyde content of the fixed oily fatty oils or fats, such as olein, or other aliphatic or 'oxy-acyd ester which may be of solid or semi-solid or fluid consistency at o I ressure and temperature, the
a ve Is for other medicating or m agents.
It is found that, aside from the advantages derived. from the employment of the fixed oily formic aldehyde compositions as a vehicle for other medicatinig or agents, that the formic al ehyde con tent oxidized or rancid and the compodtion is und complositions of which may be emplgyl to be of itself of great advantage as a hemostatic and when applied to cuts or wounds a rapid healing agent byreason of its antiseptic and coagulating action upon'the albummous content of theblood or exposed raw surfaces.
I am aware that formic aldehyde has been mixed in its aqueous solution emulsified with lard and with emulsions, such as milk, for the purpose of press the same, and I am also aware that formic aldehyde has been combined with hydrated collogen, such as is contained in gelatin, glues, slnns and hides, to renderthe said substances insoluble or transform them into leather, but it is seen hericr that in these cases the substances produced are not of water-re ent nature masmuch as water may be mixed with and absorbed by the said compositions with freedom, which is not the case with the fixed V oily or fatt formic aldehyde composition as produ b 'my procsm, which-waterdrous fixed aliphatic esters Mae-and not associated wit water in suspension in contradistinctjon from the aforesaid It may be noted that dry formic aldehyde, which is a unites or combines more readily with the fixed oils or ali hatic esters and becomes more with or re- .tained or occluded tl i nent manner and to a larger percen without danger of polymerization than is zfif case with aqueous solutions.
The term inert em loyed out this specification and claimshas reference to the character of the solvent for I the formic aldehyde and-its character in relation-to the formic aldehyde contmt; and the term .fixdeg oil to'the crude (ii-0:11- merci-al anh us, inert 1 water-1e lent, mineral; vegetable or animal fat or oil, as well as purified products or esters and s intended to include anhydrous, inert, fined water-re nature w 'ch might substances or artific1ally or prepared, it being understood.
fixed implies that thesubstance is of consists largely of anhy-' amorepermaent com tions of fined oily L syntheh y. thattbeterm non-volatile and permanent character under ordinary atmospheric pressure and temperature; and the term water-repellent designates a composition ordinarily insoluble in or incompatible with water.
Having now described by invention, what I claim as new and desire to secure by Letters Patent is 1. A new anhydrous composition of matter consisting of an inert, unctuous, fixed Fraser-repellent vehicle, and formic alde- 1y e.
2. A new anhydrous composition ofmatter consisting of an inert, unctuous, fixed water-repellent vehicle containing formic aldehyde.
3. A new anhydrous composition of matter composed of formic aldehyde and an inert fixed ester.
4. A new anhydrous com osition of matter composed of formic aldehyde and an inert fixed oxy-acid ester.
5. A new anhydrous composition of mat ter composed of formic aldehyde and an inert fixed aliphatic ester.
-6. A new anhydrous composition of matter substantially consisting of an inert fixed aliphatic ester and formic aldehyde.
7 A new anhydrous composition of matter com osed of an inert oleic ester and formic a dehyde.
8. A new composition of matter substantially composed of an inert fixed aliphatic ester, formic aldehyde and a medicating agent.
9. A new anhydrous composition of matter consistin of formic aldehyde and an inert fixed oil.
10. A new anhydrous composition of matter consisting of inert fixed oil and formic aldehyde.
11. As a vehicle for medicinal agents, an
'anhydrous composition com rising an inert fixed oily ester containing ormic aldehyde.
12. The rocess of making the new composition of matter herein set forth, which consists in mixing a fixed water-re llent ester with anhydrous formic aldehy e and exposing the same to intimate association until the formic aldehyde has become associated therewith or occluded therein.
13. The rocess of maln'ng the new composition of matter herein set forth which consists in mixing a fixed water-repellent ester with gaseous formic aldehyde and exposing the same to intimate association until the formic aldehyde has become associated therewith or occluded therein.
14. The rocess of making the new composition ofi matter herein set forth which consists in mixing a fixed water-repellent ester with formic aldehyde under superatmospheric pressure and exposing the same to intimate. association until the formic aldehyde has become associated therewith or 00- cluded therein.
In testimony whereof I afiix my signature, in presence of two witnesses.
V ---HENRY SPENCER BLACKMORE. Witnesses:
O. G. VICTOR, WALTER F. Nmzzmn
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16867303A US909527A (en) | 1903-08-07 | 1903-08-07 | Composition for antiseptic and other purposes. |
| US368855A US917706A (en) | 1903-08-07 | 1907-04-18 | Formic-aldehyde-containing composition and process of making the same. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US16867303A US909527A (en) | 1903-08-07 | 1903-08-07 | Composition for antiseptic and other purposes. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US909527A true US909527A (en) | 1909-01-12 |
Family
ID=2977964
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US16867303A Expired - Lifetime US909527A (en) | 1903-08-07 | 1903-08-07 | Composition for antiseptic and other purposes. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US909527A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3339474A (en) * | 1966-01-14 | 1967-09-05 | Whirlpool Co | Apparatus for transporting plant and animal materials |
-
1903
- 1903-08-07 US US16867303A patent/US909527A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3339474A (en) * | 1966-01-14 | 1967-09-05 | Whirlpool Co | Apparatus for transporting plant and animal materials |
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